JP6232783B2 - Reinforcing method for vehicle door not provided with reinforcement and vehicle door not provided with reinforcement - Google Patents

Reinforcing method for vehicle door not provided with reinforcement and vehicle door not provided with reinforcement Download PDF

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JP6232783B2
JP6232783B2 JP2013137764A JP2013137764A JP6232783B2 JP 6232783 B2 JP6232783 B2 JP 6232783B2 JP 2013137764 A JP2013137764 A JP 2013137764A JP 2013137764 A JP2013137764 A JP 2013137764A JP 6232783 B2 JP6232783 B2 JP 6232783B2
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幸一 西浦
幸一 西浦
裕之 杉浦
裕之 杉浦
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Starlite Co Ltd
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本発明は、レインフォースメントを備えてない車両用ドアの補強方法及びレインフォースメントを備えてない車両用ドアに係わり、更に詳しくはレインフォースメントを備えてない車両用ドアの外装材に対して耐衝撃性、剛性、防振性等を付与する補強方法及び車両用ドアに関するものである。 The present invention relates to a vehicle door which is not provided with a reinforcement method and reinforcement of a vehicle door having no reinforcement, more particularly with respect to exterior materials of a vehicle door having no reinforcement The present invention relates to a reinforcing method for imparting impact resistance, rigidity, vibration proofing, and the like, and a vehicle door.

車両のボディやドア等の上部構造体に用いる外装材は、薄い鋼板をプレス加工して立体的に形成し、それ自体で剛性を持たせている。そして、車両の側面からの衝撃に対して乗員を保護するために、外装材の内側に沿って金属製の補強部材が設けられている。この補強部材として、インパクトバーやレインフォースメントが付設されている。   An exterior material used for an upper structure such as a vehicle body or a door is three-dimensionally formed by pressing a thin steel plate and has rigidity by itself. And in order to protect a passenger | crew with respect to the impact from the side surface of a vehicle, the metal reinforcement member is provided along the inner side of an exterior material. As this reinforcing member, an impact bar and a reinforcement are attached.

例えば、特許文献1に示すように、ドアのアウタパネルの内側でバンパーの高さ位置にインパクトバーとレインフォースメントが併設された車両のドア構造が開示されている。それにより、他の車両との衝突の際に、アウタパネルが内側へ大きく凹むのをインパクトバーとレインフォースメントで防ぎ、乗員を保護することができる。ドア以外にも乗員の座部に対応するボディの側面や天井部分にも、外装材の内側に補強部材を設け、外装材の耐衝撃性を高めることもある。また、特許文献2には、複数のインパクトバーを備えるドアのアウタパネルの内側面に沿って衝撃吸収部材を添設した車両の側部衝撃吸収構造が開示されている。この衝撃吸収部材の例として、低発泡ウレタン、トリムのリブ増強やハニカム構造体、金属箔や紙や樹脂シート等で形成される筒状衝撃吸収材が挙げられている。   For example, as shown in Patent Document 1, a vehicle door structure in which an impact bar and a reinforcement are provided at the height of a bumper inside an outer panel of a door is disclosed. Thereby, in the event of a collision with another vehicle, the outer panel can be prevented from being greatly recessed inward by the impact bar and the reinforcement, and the occupant can be protected. In addition to the door, a reinforcing member may be provided on the inner side of the exterior material on the side or ceiling of the body corresponding to the seat of the occupant to enhance the impact resistance of the exterior material. Further, Patent Document 2 discloses a vehicle side impact absorbing structure in which an impact absorbing member is attached along an inner surface of an outer panel of a door having a plurality of impact bars. Examples of the impact absorbing member include a low impact urethane, a rib reinforcement of a trim, a honeycomb structure, a cylindrical impact absorbing material formed of a metal foil, paper, a resin sheet, or the like.

近年、自動車の上部構造体に用いる鋼板は、車体の軽量化を図るために厚さ0.6〜0.8mmの薄い鋼板が使用され、更に高張力鋼板を使用してより薄く軽量化する傾向にあり、平均的には100kgの軽量化により燃費約1km/リットルの節減になり、排出ガスも削減できるとされる。しかし、車両の外装材を薄くすればその分だけ軽量化を図れても、耐衝撃性を確保するために、剛性の高い金属製補強部材を用いる必要があったので、補強部材が軽量化の妨げになっていた。   In recent years, steel sheets used for the superstructure of automobiles have been used to reduce the weight of the car body by using thin steel sheets with a thickness of 0.6 to 0.8 mm, and using high-tensile steel sheets to reduce the thickness and weight. Therefore, on average, the weight reduction of 100 kg reduces the fuel consumption by about 1 km / liter, and the exhaust gas can also be reduced. However, even if the vehicle exterior material is made thinner, it is necessary to use a highly rigid metal reinforcing member in order to ensure impact resistance, even if the weight can be reduced by that much. It was a hindrance.

特許文献3には、自動車車体鋼板の内側に貼り付けて剛性を補強するための補強シートが開示されている。この補強シートは、未加硫シートに拘束層を積層したものであり、自動車車体鋼板に未加硫シート側が接するように重ね合わせて貼り付けた後、自動車製造ラインにおけるオーブンを通過する等の方法により加熱・焼成され、架橋硬化することにより、該鋼板と強固に接着して積層体を形成するのである。しかし、補強シートは、予め所定の複雑な形状に裁断する必要があり、作業性が非常に悪く、またゴム材であるので補強効果が十分でない。   Patent Document 3 discloses a reinforcing sheet that is attached to the inside of an automobile body steel plate to reinforce rigidity. This reinforcing sheet is obtained by laminating a constraining layer on an unvulcanized sheet, and is a method in which an uncured sheet side is laminated and pasted so that the unvulcanized sheet side is in contact with an automobile body steel plate and then passed through an oven in an automobile production line By being heated and fired by this, and cured by cross-linking, it is firmly bonded to the steel sheet to form a laminate. However, the reinforcing sheet needs to be preliminarily cut into a predetermined complicated shape, and the workability is very poor, and since it is a rubber material, the reinforcing effect is not sufficient.

一方、ポリウレア樹脂は、硬化時間が早く、耐久性、防水性、耐薬品性を備え、伸び率も280%以上あるので、土木、建築分野でコンクリート面に吹き付けて防水処理するために使用されている。例えば、屋上駐車場の床面、トンネル、地下タンク、水泳用プール、水路等の内面に形成している。また、防錆効果も高いので船舶での使用実績もある。   Polyurea resin, on the other hand, has a fast curing time, durability, waterproofness, chemical resistance, and elongation of 280% or more, so it is used for waterproofing by spraying on concrete surfaces in civil engineering and construction fields. Yes. For example, it is formed on the inner surface of a floor surface of a rooftop parking lot, a tunnel, an underground tank, a swimming pool, a waterway, and the like. In addition, since it has a high anti-rust effect, it has been used on ships.

特開2010−137754号公報JP 2010-137754 A 特開2009−173140号公報JP 2009-173140 A 特開2001−038842号公報JP 2001-038842 A

そこで、本発明が前述の状況に鑑み、解決しようとするところは、レインフォースメントを備えてない車両用ドアの外装材に対して、耐衝撃性、剛性、防振性等を付与することが可能であるとともに、全体として軽量化、コストダウンを図ることが可能なレインフォースメントを備えてない車両用ドアの補強方法及びレインフォースメントを備えてない車両用ドアを提供する点にある。 Accordingly, the present invention is in view of the circumstances described above, it is an attempt to solve, for the exterior material of a vehicle door having no reinforcement, impact resistance, stiffness, to impart vibration damping property and the like as well as a possible, it is to provide an light weight, vehicle door which is not provided with a reinforcement method and reinforcement of a vehicle door having no reinforcement that can reduce the cost as a whole.

本発明は、前述の課題解決のために、厚さ0.6〜0.8mmの鋼板からなる外装材の内面の下側にインパクトバーを設け、上側にレインフォースメントを備えてない車両用ドアの補強方法であって、
前記外装材の内面に、それぞれ独立した原料供給ホースから供給されたイソシアネートと、硬化剤としてアミノ基を有するポリアミンとを衝突混合スプレーガンで塗布し、該内面に沿ってポリウレア樹脂の補強層を形成し、該ポリウレア樹脂は、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であり、
前記車両用ドアを、前記外装材の外面を上方に向けて両側を支持して水平に静置し、その中央部に、表面をポリウレア樹脂で被覆したコンクリートブロックからなる11kgの重りを2mの高さから落下させる落下衝撃試験により、全体的な凹みが無い結果を得ることを特徴とするレインフォースメントを備えてない車両用ドアの補強方法を構成した(請求項1)。
In order to solve the above-mentioned problems, the present invention provides a vehicle door provided with an impact bar on the lower side of the inner surface of an exterior material made of a steel plate having a thickness of 0.6 to 0.8 mm and not provided with a reinforcement on the upper side. A reinforcing method of
On the inner surface of the exterior material, an isocyanate supplied from an independent raw material supply hose and a polyamine having an amino group as a curing agent are applied with a collision mixing spray gun to form a polyurea resin reinforcement layer along the inner surface. and, the polyurea resin is strain (elongation) of 2% when the tensile stress is above 10 MPa, the breaking stress Ri der least 20 MPa,
The vehicle door is placed horizontally with the outer surface of the exterior material facing upward and supporting both sides, and an 11 kg weight consisting of a concrete block whose surface is covered with polyurea resin is placed at a height of 2 m. the drop impact test by dropping from a, to constitute a reinforcing method of a vehicle door having no reinforcement, characterized in that to obtain the results overall dent is not (claim 1).

また、本発明は、厚さ0.6〜0.8mmの鋼板からなる外装材の内面の下側にインパクトバーを設け、上側にレインフォースメントを備えてない車両用ドアであって、
前記外装材の内面に沿って、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であるポリウレア樹脂の補強層を設け、
前記車両用ドアを、前記外装材の外面を上方に向けて両側を支持して水平に静置し、その中央部に、表面をポリウレア樹脂で被覆したコンクリートブロックからなる11kgの重りを2mの高さから落下させる落下衝撃試験により、全体的な凹みが無い結果を得ることを特徴とするレインフォースメントを備えてない車両用ドアを構成した(請求項2)。
Further, the present invention is that the impact bar to the underside of the inner surface of the outer package made of steel plate having a thickness of 0.6~0.8mm provided a vehicle door having no reinforcement to the upper,
Along the inner surface of the outer member, the strain (elongation) of 2% when the tensile stress is above 10 MPa, the reinforcing layer of the polyurea resin breaking stress is more than 20MPa provided,
The vehicle door is placed horizontally with the outer surface of the exterior material facing upward and supporting both sides, and an 11 kg weight consisting of a concrete block whose surface is covered with polyurea resin is placed at a height of 2 m. A vehicle door without a reinforcement, which is characterized by obtaining a result having no overall dent by a drop impact test for dropping, is constructed (claim 2).

以上にしてなる本発明のレインフォースメントを備えてない車両用ドアの補強方法は、厚さ0.6〜0.8mmの鋼板からなる外装材の内面の下側にインパクトバーを設け、上側にレインフォースメントを備えてない車両用ドアの補強方法であって、前記外装材の内面に、それぞれ独立した原料供給ホースから供給されたイソシアネートと、硬化剤としてアミノ基を有するポリアミンとを衝突混合スプレーガンで塗布し、該内面に沿ってポリウレア樹脂の補強層を形成し、該ポリウレア樹脂は、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であり、前記車両用ドアを、前記外装材の外面を上方に向けて両側を支持して水平に静置し、その中央部に、表面をポリウレア樹脂で被覆したコンクリートブロックからなる11kgの重りを2mの高さから落下させる落下衝撃試験により、全体的な凹みが無い結果を得るので、補強層を形成した内面とは反対側の外側から加わる衝撃に対して、衝撃力が作用して凹む範囲ではポリウレア樹脂の補強層に引張り応力が作用し、その外側周辺では圧縮応力が作用するが、ポリウレア樹脂は初期弾性率が非常に高いので外装材の変形を弾性的に防止し、また衝撃力を吸収することができ、耐衝撃性に非常に優れている。 Reinforcing method of a vehicle door having no reinforcement of the present invention obtained by the above, the impact bar provided below the inner surface of the outer package made of steel plate having a thickness of 0.6 to 0.8 mm, the upper side A method for reinforcing a vehicle door that does not include reinforcement, and is a collision-mixing spray of isocyanate supplied from an independent raw material supply hose and a polyamine having an amino group as a curing agent on the inner surface of the exterior material. was applied by gun, to form a reinforcing layer of polyurea resin along the inner surface, the polyurea resin is strain (elongation) of 2% when the tensile stress is above 10 MPa, the breaking stress Ri der than 20 MPa, the vehicle The door is placed horizontally with the outer surface of the exterior material facing upward and supporting both sides, and a concrete block whose surface is covered with polyurea resin at the center. The drop impact test for dropping a weight of 11kg consisting click from a height of 2m, therefore obtain results overall dent is not, an impact applied from the outside of the opposite side of the formed internal surface a reinforcing layer, impact Tensile stress acts on the reinforcement layer of polyurea resin in the area where the force acts, and compressive stress acts on the outer periphery, but polyurea resin has an extremely high initial modulus of elasticity, so that deformation of the exterior material is made elastic. It can prevent and absorb impact force, and is very excellent in impact resistance.

また、ポリウレア樹脂は、イソシアネートと、アミノ基を有する硬化剤とがウレア結合して生成されるが、その反応は非常に早く、数秒で接触硬化するので、後工程を直ちに行うことができ、生産効率が良くなる。また、ポリウレア樹脂は、ポリウレタン樹脂に比べて結合力が強く、加水分解しないため、耐水・耐食・耐薬品性に優れている。   Polyurea resin is produced by urea bonding of isocyanate and amino group-containing curing agent, but the reaction is very fast and can be contact-cured in a few seconds, so the subsequent process can be performed immediately and produced. Efficiency is improved. In addition, the polyurea resin has a stronger binding force than the polyurethane resin and does not hydrolyze, so it has excellent water resistance, corrosion resistance, and chemical resistance.

本発明のレインフォースメントを備えてない車両用ドアは、厚さ0.6〜0.8mmの鋼板からなる外装材の内面の下側にインパクトバーを設け、上側にレインフォースメントを備えてない車両用ドアであって、前記外装材の内面に沿って、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であるポリウレア樹脂の補強層を設け、前記車両用ドアを、前記外装材の外面を上方に向けて両側を支持して水平に静置し、その中央部に、表面をポリウレア樹脂で被覆したコンクリートブロックからなる11kgの重りを2mの高さから落下させる落下衝撃試験により、全体的な凹みが無い結果を得るので、全体として耐衝撃性を損なわず軽量化を図ることができ、具体的には、前記外装材の内面の下側に設けたインパクトバーと併用してポリウレア樹脂の補強層を設けたので、従来構造のものより更に耐衝撃性を高めることができる。また、外装材の広い面積にわたってポリウレア樹脂の補強層を形成することにより、防振性、防音性を高めることができ、また金属製の補強部材が存在しない箇所での剛性、耐衝撃性を新たに付与することができる。 Vehicle door having no reinforcement of the present invention, the impact bar provided below the inner surface of the outer package made of steel plate having a thickness of 0.6 to 0.8 mm, does not have a reinforcement in the upper A vehicular door provided with a polyurea resin reinforcing layer having a tensile stress of 10 MPa or more and a breaking stress of 20 MPa or more when the strain (elongation) is 2% along the inner surface of the exterior material. The outer surface of the exterior material is horizontally supported with both sides facing upward, and an 11 kg weight consisting of a concrete block whose surface is covered with polyurea resin is dropped from a height of 2 m at the center. the drop impact test, since obtaining the overall dent is not a result, it is possible to reduce the weight without deteriorating the impact resistance as a whole, in particular, provided on the lower side of the inner surface of the outer member Is provided with the reinforcing layer of the polyurea resin in combination with Npakutoba, it can be enhanced further impact resistance than those of the conventional structure. In addition, by forming a polyurea resin reinforcement layer over a large area of the exterior material, vibration and sound insulation can be improved, and rigidity and impact resistance at locations where there are no metal reinforcement members have been added. Can be granted.

内装部材を取り除いた状態の市販ドアの側面図である。It is a side view of the commercial door of the state which removed the interior member. 同じく金属製補強部材の1本を除去した状態のドアの側面図である。It is a side view of the door of the state which similarly removed one metal reinforcement member. 図2の外装材の内面にポリウレア樹脂の補強層を形成した状態のドアの側面図である。FIG. 3 is a side view of the door in a state where a polyurea resin reinforcing layer is formed on the inner surface of the exterior material of FIG. 2. 外装材とポリウレア樹脂の補強層の積層構造を示す部分断面図である。It is a fragmentary sectional view which shows the laminated structure of an exterior material and the reinforcement layer of a polyurea resin. 各種グレードのポリウレア樹脂とウレタン樹脂のひずみ−応力図である。It is a strain-stress diagram of various grades of polyurea resin and urethane resin. 図5のひずみが小さい領域の拡大図である。FIG. 6 is an enlarged view of a region with a small strain in FIG. 5. 各種グレードのポリウレア樹脂とウレタン樹脂の貯蔵弾性率とtanδのグラフである。It is a graph of the storage elastic modulus and tan-delta of polyurea resin and urethane resin of various grades.

次に、添付図面に示した実施形態に基づき、本発明を更に詳細に説明する。図1〜図4は、ドアの外装材の内面にポリウレア樹脂の補強層を設ける実施形態を示し、図5〜図7には各種グレードのポリウレア樹脂の特性をウレタン樹脂と比較して示している。   Next, the present invention will be described in more detail based on the embodiments shown in the accompanying drawings. 1 to 4 show an embodiment in which a polyurea resin reinforcing layer is provided on the inner surface of a door exterior material, and FIGS. 5 to 7 show the characteristics of various grades of polyurea resin in comparison with urethane resin. .

本発明で対象とする車両用外装材としては、厚さ0.6〜0.8mmの鋼板からなる台車フレームに取付ける上部構造体、具体的にはボディ(側面板、ルーフ、床板を含む)、ドア、フード、トランクリッド、バンパー等が挙げられ、その他に車両に付属する剛構造の荷台材料、コンテナ等、基本的に薄い金属材料からなるものである。更に、炭素繊維強化樹脂で車両の外装材を構成する場合もある。   As a vehicle exterior material to be used in the present invention, an upper structure to be attached to a carriage frame made of a steel plate having a thickness of 0.6 to 0.8 mm, specifically a body (including a side plate, a roof, and a floor plate), Examples include doors, hoods, trunk lids, bumpers, and the like, and they are basically made of a thin metal material such as a rigid load carrier material or container attached to a vehicle. Furthermore, the exterior material of a vehicle may be comprised with a carbon fiber reinforced resin.

前記車両の外装材の内側には、耐衝撃性を高める金属製補強部材が適所に配置されている。これら補強部材としては、ドアインパクトバー、フロントバンパービーム、リアバンパービーム、クロスメンバー、フロントピラーレインフォース、センターピラーレインフォースおよびサイドシルなどがある。   Inside the exterior material of the vehicle, a metal reinforcing member for improving impact resistance is disposed at a proper position. These reinforcing members include a door impact bar, a front bumper beam, a rear bumper beam, a cross member, a front pillar reinforcement, a center pillar reinforcement, and a side sill.

本発明で使用するポリウレア樹脂は、イソシアネートと、アミノ基を有する硬化剤とからなり、硬化剤として特にポリアミンを用いたものである。ポリウレア樹脂は、イソシアネートと、アミノ基を有する硬化剤とを混合することによって、ウレア結合が生成する反応によって硬化する。このウレア結合の生成反応は、数秒と非常に速いため、成形金型による通常の成形は困難である。そのため、それぞれ独立した原料供給ホースから供給されたイソシアネートと、アミノ基を有する硬化剤とを衝突混合スプレーガンで塗布する方法で基材表面に塗膜を形成する。   The polyurea resin used in the present invention comprises an isocyanate and a curing agent having an amino group, and particularly uses a polyamine as the curing agent. A polyurea resin is cured by a reaction in which a urea bond is formed by mixing an isocyanate and a curing agent having an amino group. Since the urea bond formation reaction is very fast, such as several seconds, it is difficult to perform normal molding using a molding die. Therefore, a coating film is formed on the surface of the substrate by a method in which an isocyanate supplied from an independent raw material supply hose and a curing agent having an amino group are applied by a collision mixing spray gun.

一般的なポリウレア樹脂の特徴としては、硬化が早く空気中の湿気や水分の影響を受け難いこと、低温でも硬化が早く且つ良好な塗膜を形成できること、耐薬品性に優れていること、基材表面に対する接着性に優れていること、伸び率が280%以上ありクラック等に十分に追従して密着性を維持できること挙げられる。   The characteristics of general polyurea resins are that they cure quickly and are not easily affected by moisture and moisture in the air, that they can cure quickly and form a good coating film even at low temperatures, and that they have excellent chemical resistance. It is excellent in the adhesiveness with respect to the material surface, and has an elongation of 280% or more, and can sufficiently follow the cracks and maintain the adhesion.

ポリウレア樹脂には幾つかのグレードがあり、それぞれ特性は異なるので、車両の外装材の補強として最適なグレードのもの選択して用いる必要がある。本実施形態で使用するポリウレア樹脂は、引張り特性として、初期弾性率ならびに弾性限界の応力が高く、且つ伸びが大きくて降伏強度が高い樹脂が好適である。具体的には、LINE−X社製、商品名:PAXCON XS−350のポリウレア樹脂を用いた。   There are several grades of polyurea resin, each having different characteristics. Therefore, it is necessary to select and use an optimum grade for reinforcement of a vehicle exterior material. The polyurea resin used in the present embodiment is preferably a resin having high initial elastic modulus and elastic limit stress, large elongation, and high yield strength as tensile properties. Specifically, a polyurea resin manufactured by LINE-X, trade name: PAXCON XS-350 was used.

図1は、自動車の市販されているドア1を、内装部材を取り除いた状態で内側から見た側面図である。ドア1の外装材2は、アウタパネルとも呼ばれ、その内側には両側部にわたって上下に金属製の補強部材3,4が付設され、外側からの耐衝撃性を持たせている。上側の補強部材3はレインフォースメント、下側の補強部材4はインパクトバーと呼ばれることもある。実験のため同じドア1を2つ用意し、一方のドア1は図2に示すように上側の補強部材3を除去した。そして、図3に示すように、前記補強部材3を除去したドア1の外装材2の内面に、全面にわたってポリウレア樹脂を塗布して所定厚さの補強層5を設けた。図4は、その一部の断面を示し、外装材2の鋼板と補強層5のポリウレア樹脂が積層された単純な構造となっている。   FIG. 1 is a side view of a commercially available door 1 of an automobile viewed from the inside with an interior member removed. The exterior material 2 of the door 1 is also called an outer panel, and metal reinforcement members 3 and 4 are attached to the inner side of the door 1 on both sides to give impact resistance from the outside. The upper reinforcing member 3 may be called a reinforcement, and the lower reinforcing member 4 may be called an impact bar. Two same doors 1 were prepared for the experiment, and the upper reinforcing member 3 was removed from one door 1 as shown in FIG. Then, as shown in FIG. 3, a polyurea resin was applied over the entire inner surface of the exterior member 2 of the door 1 from which the reinforcing member 3 had been removed to provide a reinforcing layer 5 having a predetermined thickness. FIG. 4 is a partial cross-sectional view showing a simple structure in which the steel plate of the exterior material 2 and the polyurea resin of the reinforcing layer 5 are laminated.

前記車両用外装材2の内面に、ポリウレア樹脂の補強層5を形成するには、それぞれ独立した原料供給ホース(図示せず)から供給されたイソシアネートと、アミノ基を有する硬化剤(ポリアミン)とを、衝突混合スプレーガン(図示せず)で塗布する。塗布すると直ちに、イソシアネートとポリアミンとがウレア結合を生成して硬化する。   In order to form the polyurea resin reinforcing layer 5 on the inner surface of the vehicle exterior material 2, an isocyanate supplied from an independent raw material supply hose (not shown), a curing agent having an amino group (polyamine), and Is applied with an impact mixing spray gun (not shown). Immediately upon application, the isocyanate and polyamine form a urea bond and cure.

本発明の効果を確認するために、落下衝撃試験を行った。図1のオリジナル状態のドア(オリジナルドア)と、図3の上側の補強部材3を除去し、内面にポリウレア樹脂の補強層5を形成したドア(ポリウレア樹脂補強ドア)を、それぞれ外装材2の外面を上方に向けて樹脂製パレットで両側を支持して水平に静置する。そして、コンクリートブロックの表面を落下衝撃時の破砕を防ぐためにポリウレア樹脂で被覆した11kgの重りを用意し、2mの高さから前記ドアの中央部に落下させた。これらの落下衝撃試験をビデオ撮影して分析した。   In order to confirm the effect of the present invention, a drop impact test was performed. The door in the original state (original door) in FIG. 1 and the door (polyurea resin reinforced door) formed by removing the upper reinforcing member 3 in FIG. The outer surface is faced upwards, and both sides are supported by a resin pallet and left to stand horizontally. And the 11 kg weight which covered the surface of the concrete block with the polyurea resin in order to prevent the fracture | rupture at the time of a drop impact was prepared, and it was dropped from the height of 2 m to the center part of the said door. These drop impact tests were videotaped and analyzed.

その結果、オリジナルドアは、コンクリートブロックが衝突した瞬間に、外装材2が約140mm凹み、その後、若干復元するが、全体的に約80mmの凹みが残った。それに対して、ポリウレア樹脂補強ドアは、コンクリートブロックが衝突した瞬間に、外装材2が約30mm凹んだが、その後完全に元の形状に復元して全体的な凹みは全く無く、ブロックが当たった部分に約0.3mmの凹みが残っただけであった。   As a result, at the moment when the concrete block collided with the original door, the exterior material 2 was recessed by about 140 mm, and after that, it was slightly restored, but an overall recess of about 80 mm remained. On the other hand, in the case of the polyurea resin reinforced door, the exterior material 2 was recessed about 30 mm at the moment when the concrete block collided, but then it was completely restored to its original shape and there was no overall dent, and the block hit the part. Only a recess of about 0.3 mm remained.

次に、本実施形態で使用したLINE−X社製、商品名:PAXCON XS−350と他のグレード(PX−100、PX−2100、SE−500)と参考にウレタン樹脂の特性を比較した結果を図5〜図7に示す。   Next, the product of LINE-X used in the present embodiment, product name: PAXCON XS-350 and other grades (PX-100, PX-2100, SE-500) and the result of comparing the characteristics of the urethane resin with reference. Is shown in FIGS.

貯蔵弾性率E’は、引張試験モードで測定した複素弾性率の実部であり、試料の硬さを表している。tanδは、損失正接であり、分子運動が始まる温度でピークが生じ、この温度がガラス転移温度に相当する。   The storage elastic modulus E ′ is the real part of the complex elastic modulus measured in the tensile test mode, and represents the hardness of the sample. Tan δ is a loss tangent, and a peak occurs at a temperature at which molecular motion begins, and this temperature corresponds to the glass transition temperature.

<1.引張試験>
ポリウレア樹脂:XS−350は、弾性変形の限界応力(降伏強さ)が高く、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であることが分かる。その他のグレードのポリウレア樹脂はあまり高くない(SE−500は不明)。また、ウレタン樹脂は、弾性変形の限界応力が小さい反面、破断応力が30MPaを超え、そのときの伸びも約380%と大きい。つまり、ウレタン樹脂は、小さな応力でもひずみが大きくなり、柔らかくゴムのような特性である。ポリウレア樹脂:PX−100及びPX−2100はほぼ同じ挙動を示している。XS−350は、特に高い応力限界及びひずみ(伸び)の大きさが、優れた耐衝撃性を示している。
<1. Tensile test>
It can be seen that the polyurea resin: XS-350 has a high elastic deformation limit stress (yield strength), and has a tensile stress of 10 MPa or more and a breaking stress of 20 MPa or more when the strain (elongation) is 2%. Other grades of polyurea resin are not very expensive (SE-500 is unknown). The urethane resin has a small elastic deformation limit stress, but has a breaking stress exceeding 30 MPa, and the elongation at that time is as large as about 380%. That is, the urethane resin has a large distortion even under a small stress, and is soft and rubbery. Polyurea resins: PX-100 and PX-2100 show almost the same behavior. XS-350 exhibits excellent impact resistance, particularly due to its high stress limit and strain (elongation).

<2.粘弾性試験>
ポリウレア樹脂:PX−100及びPX−2100は、引張試験と同様、ほぼ同じ挙動である。tanδピークが80℃付近と、190℃付近に2つ認められる。また、−15℃付近にショルダーが見られる。ポリウレア樹脂:XS−350は、−15℃付近および80℃付近に小さくてブロードなピークがあり、200℃以上に大きなピークがありそうである。ポリウレア樹脂:SE−500は、160℃付近に大きなピークがあり、−40℃付近にごく小さなピークが認められる。それに対して、ウレタン樹脂は、10℃より若干低温で大きなピークがある。
<2. Viscoelasticity test>
Polyurea resin: PX-100 and PX-2100 behave substantially the same as in the tensile test. Two tan δ peaks are observed around 80 ° C and around 190 ° C. Moreover, a shoulder is seen at around -15 ° C. Polyurea resin: XS-350 has small and broad peaks at around −15 ° C. and around 80 ° C., and a large peak at 200 ° C. or more. Polyurea resin: SE-500 has a large peak in the vicinity of 160 ° C. and a very small peak in the vicinity of −40 ° C. In contrast, urethane resin has a large peak at a slightly lower temperature than 10 ° C.

以上のことから、ポリウレア樹脂:PX−100及びPX−2100は、比較的柔らかで転移点の低い2種類のセグメントで構成され、ポリウレア樹脂:XS−350は、上記のセグメントが含まれているが、その量はごく少なく、これらより硬くて転移点の高いセグメントが主成分として存在すると推測できる。また、ポリウレア樹脂:SE−500は、剛直な構造と、少量のPX−100及びPX−2100よりは転移点の低いセグメントから構成されていると推測できる。   From the above, the polyurea resin: PX-100 and PX-2100 are composed of two types of segments that are relatively soft and have a low transition point, and the polyurea resin: XS-350 includes the above-mentioned segments. , The amount is very small, and it can be inferred that a segment that is harder than these and has a high transition point exists as a main component. In addition, it can be inferred that polyurea resin: SE-500 is composed of a rigid structure and a segment having a lower transition point than a small amount of PX-100 and PX-2100.

以上により、ポリウレア樹脂はウレタン樹脂よりも耐衝撃性に優れ、更に複数あるポリウレア樹脂のグレードのうち、XS−350が最も優れた耐衝撃性を備えていることが理解できる。   From the above, it can be understood that the polyurea resin has better impact resistance than the urethane resin, and XS-350 has the most excellent impact resistance among a plurality of polyurea resin grades.

1 ドア、
2 外装材、
3 補強部材、
4 補強部材、
5 ポリウレア樹脂の補強層。
1 door,
2 exterior materials,
3 Reinforcing members,
4 Reinforcing members,
5 Reinforcing layer of polyurea resin.

Claims (2)

厚さ0.6〜0.8mmの鋼板からなる外装材の内面の下側にインパクトバーを設け、上側にレインフォースメントを備えてない車両用ドアの補強方法であって、
前記外装材の内面に、それぞれ独立した原料供給ホースから供給されたイソシアネートと、硬化剤としてアミノ基を有するポリアミンとを衝突混合スプレーガンで塗布し、該内面に沿ってポリウレア樹脂の補強層を形成し、該ポリウレア樹脂は、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であり、
前記車両用ドアを、前記外装材の外面を上方に向けて両側を支持して水平に静置し、その中央部に、表面をポリウレア樹脂で被覆したコンクリートブロックからなる11kgの重りを2mの高さから落下させる落下衝撃試験により、全体的な凹みが無い結果を得ることを特徴とするレインフォースメントを備えてない車両用ドアの補強方法。
A method for reinforcing a vehicle door that is provided with an impact bar on the lower side of an inner surface of an exterior material made of a steel plate having a thickness of 0.6 to 0.8 mm, and does not include a reinforcement on the upper side,
On the inner surface of the exterior material, an isocyanate supplied from an independent raw material supply hose and a polyamine having an amino group as a curing agent are applied with a collision mixing spray gun to form a polyurea resin reinforcement layer along the inner surface. and, the polyurea resin is strain (elongation) of 2% when the tensile stress is above 10 MPa, the breaking stress Ri der least 20 MPa,
The vehicle door is placed horizontally with the outer surface of the exterior material facing upward and supporting both sides, and an 11 kg weight consisting of a concrete block whose surface is covered with polyurea resin is placed at a height of 2 m. A method for reinforcing a vehicle door without a reinforcement, characterized in that a drop impact test is performed to obtain a result having no overall dent .
厚さ0.6〜0.8mmの鋼板からなる外装材の内面の下側にインパクトバーを設け、上側にレインフォースメントを備えてない車両用ドアであって、
前記外装材の内面に沿って、ひずみ(伸び)が2%のとき引張り応力が10MPa以上、破断応力が20MPa以上であるポリウレア樹脂の補強層を設け、
前記車両用ドアを、前記外装材の外面を上方に向けて両側を支持して水平に静置し、その中央部に、表面をポリウレア樹脂で被覆したコンクリートブロックからなる11kgの重りを2mの高さから落下させる落下衝撃試験により、全体的な凹みが無い結果を得ることを特徴とするレインフォースメントを備えてない車両用ドア。
The thickness of the impact bar to the underside of the inner surface of the outer package made of steel 0.6~0.8mm provided a vehicle door having no reinforcement to the upper,
Along the inner surface of the outer member, the strain (elongation) of 2% when the tensile stress is above 10 MPa, the reinforcing layer of the polyurea resin breaking stress is more than 20MPa provided,
The vehicle door is placed horizontally with the outer surface of the exterior material facing upward and supporting both sides, and an 11 kg weight consisting of a concrete block whose surface is covered with polyurea resin is placed at a height of 2 m. A vehicle door without a reinforcement, characterized in that a drop impact test is performed to obtain a result without an overall dent .
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