JP6221696B2 - Light emitting device manufacturing method and light emitting device - Google Patents

Description

  The present invention relates to a method for manufacturing a light emitting device in which a phosphor layer is formed on the surface of a light emitting element, and the light emitting device.

  In general, a light-emitting device using a light-emitting element is known to be small, power efficient, and emit bright colors. Since the light-emitting element according to this light-emitting device is a semiconductor element, the light-emitting element is characterized by not only less fear of ball breakage but also excellent initial drive characteristics and resistance to repeated vibration and on / off lighting. Because of such excellent characteristics, light emitting devices using light emitting elements such as light emitting diodes (LEDs) and laser diodes (LDs) are used as various light sources.

Here, for example, as a method for producing a white LED, the most prevalent method is to use a yellow phosphor that emits blue light from the LED element as an excitation light for an LED element that emits blue light. It is the method of apply | coating to.
As a method of forming a phosphor on the surface of such an LED element, a phosphor layer (wavelength conversion layer) of a light-emitting device is formed by a spray coating method, so that a uniform thickness (uniform phosphor) is formed on the LED element. A technique for forming a (distributed) phosphor layer is disclosed (for example, see Patent Document 1).

  A light emitting device in which a phosphor layer is formed can obtain light distribution characteristics close to a point light source by forming the phosphor layer in the very vicinity of the light emitting element. When the light emitting device is used as a point light source, the point light source has a merit that it is easy to design an application product incorporating the light emitting device because the light emitting area is small. Therefore, the light-emitting device used as a point light source is expected to be developed in many fields including the lighting field.

International Publication No. 2013/054658

  However, in the light emitting device, for example, when the phosphor layer is formed by a spray coating method, the phosphor is widely attached on the substrate on which the light emitting element is mounted. Even if the phosphor is applied so as to concentrate on the light emitting element as much as possible, the phosphor adheres to the base material around the light emitting element. For this reason, if the phosphor layer is simply formed on the surface of the light emitting element by spraying, the phosphor emits light at a portion other than the surface of the light emitting element, so that the point light source property is lost and the light emitting device is not easily used as a point light source. There was a problem.

  This invention makes it a subject to provide the manufacturing method of a light-emitting device excellent in point light source property, and a light-emitting device in view of this problem.

  In order to solve the above problems, a method of manufacturing a light emitting device according to the present invention includes a die bonding step of mounting a light emitting element on a substrate, and a phosphor on the surface of the light emitting element and the substrate after the mounting. A phosphor layer forming step of forming a phosphor layer by spraying, and a coating for forming a coating layer containing at least one of a light-reflective material and a light-shielding material on the surface of the phosphor layer on the substrate And a layer forming step.

  The light-emitting device according to the present invention includes a phosphor comprising a substrate, a light-emitting element mounted on the substrate, and a plurality of layers formed with a substantially uniform thickness on the surface of the light-emitting element and the substrate. And a coating layer containing at least one of a light-reflective material and a light-shielding material that covers the phosphor layer on the substrate.

According to the method for manufacturing a light emitting device according to the present invention, it is possible to manufacture a light emitting device in which the phosphor in the vicinity of the light emitting element does not emit light. Thereby, the light-emitting device excellent in point light source property can be manufactured.
According to the light emitting device of the present invention, the phosphor in the vicinity of the light emitting element does not emit light, and the light emitting device having excellent point light source property can be obtained.

It is the schematic which shows typically the form with which the light-emitting device based on this invention was schematic, (a) is a top view, (b) is XX sectional drawing of (a). It is a schematic diagram for demonstrating the pulse type spray using a pulse type spray apparatus. It is sectional drawing which shows typically the form with which the light-emitting device which concerns on other embodiment of this invention was outlined. It is the schematic which shows typically the form with which the light-emitting device which concerns on other embodiment of this invention was schematic, (a) is a top view, (b) is YY sectional drawing of (a). It is sectional drawing which shows typically the form with which the light-emitting device which concerns on other embodiment of this invention was outlined.

  Hereinafter, a method for manufacturing a light emitting device and a form of the light emitting device according to the present invention will be described with reference to the drawings. Note that the size, positional relationship, and the like of the members shown in each drawing may be exaggerated for clarity of explanation. Further, in the following description, the same name and reference sign indicate the same or the same member in principle, and the detailed description is omitted as appropriate.

≪Light emitting device≫
First, the light emitting device of the present invention will be described.
As shown in FIGS. 1A and 1B, here, the light emitting device 100 is provided on the base 1, the conductive members 2a and 2b provided on the base 1, and the conductive members 2a and 2b. The bumps 3a and 3b thus formed, the light emitting element 10 provided on the bumps 3a and 3b, the phosphor layer 40 provided on the surface of the light emitting element 10 and the surface of the substrate (mounting substrate) 20, and the mounting substrate 20 And a coating layer 50 that covers the phosphor layer 40. Here, the base substrate 1 and the conductive members 2a and 2b constitute the mounting substrate 20. For easy understanding of the configuration of the present invention, the phosphor layer 40 and the coating layer 50 shown in FIG. 1B are not shown in FIG.

(Mounting board)
As shown in FIGS. 1A and 1B, the mounting board 20 is a board on which electronic components such as the light emitting element 10 are mounted. Here, the base board 1 and the base board 1 are provided. Conductive members 2a and 2b.
As shown in FIG. 1A, the mounting substrate 20 (or the base material 1) is formed in a rectangular flat plate shape here. In addition, the size and shape of the mounting substrate 20 (or the base material 1) are not particularly limited, and can be appropriately selected according to the purpose and application such as the number of light emitting elements 10 and the arrangement interval.

[Base material]
The base material 1 is a member on which electronic components such as the light emitting element 10 are mounted via the conductive members 2a and 2b.
As the material of the base material 1, it is preferable to use an insulating material, and it is preferable to use a material that hardly transmits light emitted from the light emitting element 10 or external light. Moreover, it is preferable to use a material having a certain degree of strength. Specific examples include ceramics (Al ₂ O ₃ , AlN, etc.) or a resin, or a member provided with an insulating layer on the surface of a metal plate. Among ceramics, low-temperature sintered ceramics (LTCC) can be preferably used because it easily increases the light reflectance.

[Conductive member]
The conductive members 2a and 2b are members for electrically connecting the outside and electronic components such as the light emitting element 10 and supplying electric current (power) from the outside to these electronic components.
The material of the conductive members 2a and 2b can be appropriately selected depending on the material used as the base material 1 described above, the manufacturing method of the light emitting device 100, and the like. For example, metals such as copper, aluminum, gold, silver, tungsten, iron, and nickel, or iron-nickel alloys, phosphor bronze, iron-containing copper, molybdenum, and the like can be given.

  The conductive members 2a and 2b also have a function as a heat dissipation path. In order to improve heat dissipation, it is preferable to provide with a wide area. For example, when the substrate 1 is rectangular, it is preferable to provide it with a wide width in the short direction of the substrate 1. In FIG. 1A, a wide width is provided in the vertical direction on the paper surface.

[bump]
The bumps 3a and 3b are members that electrically connect the electrodes of the light emitting element 10 and the conductive members 2a and 2b.
A conventionally well-known thing should just be used as a bump, For example, a stud bump and a plating bump are mentioned. As a material of the stud bump, Au or an alloy thereof is often used. As the material of the plating bump, only Au or a laminated structure in which the surface is Au based on Cu or Ni is used. The thickness of the bumps 3a and 3b is, for example, 10 μm to 20 μm.

[Light emitting element]
The light emitting element 10 has, for example, positive and negative electrode pads on the surface opposite to the light emitting surface (the surface on the side where the bumps 3a and 3b are connected in FIG. 1B), and the bumps 3a and 3b are interposed therebetween. It is connected to the conductive members 2a and 2b and mounted on the base material 1 (on the mounting substrate 20). Here, the n-side electrode is connected to the conductive member 2a that is the negative electrode via the bump 3a, and the p-side electrode is connected to the conductive member 2b that is the positive electrode via the bumps 3b and 3b. The light emitting surface is a surface on the light extraction direction side of the light emitting device 100 on the side opposite to the surface facing the base material 1 when mounted on the mounting substrate 20.

As the light emitting element 10, a light emitting diode having a shape having a side portion on the upper surface, for example, a substantially rectangular parallelepiped shape, and having a semiconductor layer including an n layer, a p layer, and an active layer for emitting light on a growth substrate can be used. The light emitting element 10 can be selected to have an arbitrary wavelength. For example, as the light emitting element 10 of blue (light having a wavelength of 430 nm to 490 nm) and green (light having a wavelength of 490 nm to 570 nm), ZnSe, nitride semiconductor (In _X Al _Y Ga _1-XY N, 0 ≦ X , 0 ≦ Y, X + Y ≦ 1), GaP, or the like can be used. As the red light emitting element 10 (light having a wavelength of 620 nm to 750 nm), GaAlAs, AlInGaP, or the like can be used.

Note that in the case of the light emitting device 100 using a fluorescent material, a nitride semiconductor (In _X Al _Y Ga _1- XYN, 0 ≦ X that can emit light with a short wavelength that can efficiently excite the fluorescent material). , 0 ≦ Y, X + Y ≦ 1) are preferably used. The emission wavelength can be variously selected by adjusting the material of the active layer and its mixed crystal. Furthermore, the light emitting element 10 made of a material other than these can also be used. Note that the component composition, emission color, size, number, and the like of the light-emitting element 10 to be used can be appropriately selected depending on the purpose.
The light-emitting element 10 preferably has a light-transmitting substrate such as sapphire on the light extraction surface side. Further, the light-emitting element 10 that outputs not only visible light but also ultraviolet rays and infrared rays may be used.
The light emitting device 100 can be a white LED element by combining a blue light emitting element and a yellow phosphor.

  In the present invention, the light emitting element 10 may be configured not to have a growth substrate. For example, after a semiconductor layer consisting of an n layer, an active layer and a p layer is grown on a growth substrate, it is grown by, for example, a laser lift-off method, a metric method (MeTRe method) or a chemical lift-off method. The substrate may be peeled off from the semiconductor layer and removed.

[Phosphor layer]
The phosphor layer 40 is a layer containing a phosphor formed on the surfaces of the light emitting element 10 and the mounting substrate 20, and covers the surfaces of the light emitting element 10 and the mounting substrate 20. The phosphor layer 40 only needs to be formed on the surface of the light emitting element 10, but as described in the background art section, the phosphor layer 40 is inevitably formed on the surface of the mounting substrate 20. . For this reason, the phosphor layer 40 is also formed on the surface of the mounting substrate 20 other than the portion where the light emitting element 10 is placed. However, the smaller the area of the phosphor layer 40 on the mounting substrate 20, the better.

The phosphor layer 40 is formed, for example, by applying a slurry obtained by mixing a phosphor, a resin, and a solvent by spraying. The phosphor layer 40 may be mixed with a resin or the like, or may be formed only of a phosphor. In FIG. 1B, the phosphor layer 40 includes a resin (not shown). When the phosphor layer 40 contains a resin, the phosphor is easily fixed to the surface of the light emitting element 10.
As thickness of a fluorescent substance layer, 10-200 micrometers is mention | raise | lifted, for example.
The phosphor constituting the phosphor layer 40 is a fluorescent member that emits light having a different wavelength by absorbing at least part of the light from the light emitting element 10 as a wavelength conversion member.

As the phosphor material, for example, an yttrium aluminum garnet (YAG) phosphor, a nitride phosphor or an oxynitride phosphor mainly activated by a lanthanoid element such as Eu or Ce is used. Can do. For example, in a blue light emitting element, a combination with a silicate phosphor of YAG phosphor, LuAG phosphor, M ₂ SiO ₄ : Eu (M is Sr, Ca, Ba, etc.) emitting green to yellow, In order to enhance color rendering properties, phosphors that emit red light include SCASN phosphors such as (Sr, Ca) AlSiN ₃ : Eu, CASN phosphors such as CaAlSiN ₃ : Eu, SrAlSiN ₃ : Eu, A KSF phosphor or the like is used in a combination or blending ratio suitable for a desired color tone.

  The phosphor layer 40 is composed of a plurality of layers formed with a substantially uniform thickness on the surfaces of the light emitting element 10 and the mounting substrate 20. As will be described later, since the phosphor layer 40 is formed by spraying, it has a structure in which a plurality of layers are laminated. The number of layers can be, for example, 1 to 20, and the thickness of one layer can be, for example, 5 to 20 μm. In addition, although it is preferable that the thickness of each layer which comprises the fluorescent substance layer 40 is uniform, the unevenness | corrugation resulting from the fine difference of an error grade and the particle size of fluorescent substance may be sufficient. However, there is no problem even if the thickness of each layer constituting the phosphor layer 40 is different. By forming the phosphor layer 40 by laminating a plurality of layers, the color tone yield can be improved.

  Further, the phosphor layer 40 covers the surface of the light emitting element 10 and is provided on a portion of the surface of the mounting substrate 20 where the light emitting element 10 is not mounted. Here, the “part where the light emitting element 10 is not mounted” refers to a part other than directly below the light emitting element 10 on the surface of the mounting substrate 20. That is, it is a portion that corresponds to the outside of the light emitting element 10 in plan view.

[Coating layer]
The coating layer 50 is a light-reflective and / or light-shielding layer, and covers the phosphor layer 40 on the mounting substrate 20.
The covering layer 50 contains one or more of a light-reflective material and a light-shielding material that reflect at least part of the light from the light emitting element 10. Examples of the light reflective material include SiO ₂ , Al ₂ O ₃ , TiO ₂ , ZrO ₂ , BaSO ₄ , and MgO. One or more of these may be used as the light reflective material. Examples of the light-shielding material include carbon black and dark resin material. One or more of these may be used as the light shielding material.
In addition to the light-reflective material and / or the light-shielding material, the coating layer 50 can contain a binder, a colorant, a light diffusing agent, and a filler as desired.
The covering layer 50 can be formed of a single member, or can be formed as a plurality of layers of two or more layers.

Here, the coating layer 50 is provided on the surface of the phosphor layer 40 on the conductive members 2a and 2b. Here, the coating layer 50 is provided at a position closer to the light emitting element 10 in the phosphor layer 40 provided on the mounting substrate 20. That is, the covering layer 50 is provided so as to be positioned around the light emitting element 10. In addition, the periphery of the light emitting element 10 means the vicinity of the light emitting element 10 and refers to a part where a phosphor on the mounting substrate 20 is prevented from emitting light and a desired point light source property can be obtained.
By providing the coating layer 50 on the surface of the phosphor layer 40 on the conductive members 2a and 2b, it is possible to prevent the phosphor from emitting light in the vicinity of the light emitting element 10 other than the surface of the light emitting element 10, and the point light source property is excellent. It becomes a light emitting device. Moreover, when the coating layer 50 is light reflective, the reflectance in the vicinity of the light emitting element 10 is improved. These effects are further improved by providing the covering layer 50 closer to the light emitting element 10. The thickness of the coating layer 50 is, for example, 10 to 30 μm. Note that the thickness of the coating layer 50 is not necessarily larger than the thickness of the bumps 3a and 3b.
The covering layer 50 is preferably an insulating material when formed on the conductive members 2a and 2b.
The light emitting element 10, the phosphor layer 40, and the coating layer 50 described above are preferably sealed with a sealing member 60 such as a translucent resin as shown in FIG. 3, for example. The sealing member 60 may have any shape, and a substantially rectangular parallelepiped, a hemispherical shape, a shape in which a plurality of hemispheres are combined, or the like can be used depending on characteristics required for the light emitting device.

  According to the above-described light emitting device 100 of the present invention, when the light emitting device 100 is driven, the light traveling upward from the light emitting element 10 is extracted to the outside above the light emitting device 100. . Further, the light traveling downward or laterally is reflected and scattered by the coating layer 50, the surface of the substrate 1, the conductive members 2a and 2b, the resist film, etc., and taken out outside the light emitting device 100. become. Further, the light emission of the phosphor in the vicinity of the light emitting element 10 can be reduced, and the point light source property can be improved. Furthermore, when the coating layer 50 is light reflective, the reflectance in the vicinity of the light emitting element 10 can be improved, and the light extraction efficiency can be improved.

≪Method for manufacturing light emitting device≫
Next, a method for manufacturing a light emitting device according to the present invention will be described with reference to FIGS.

The manufacturing method of the light emitting device 100 according to the present invention includes a die bonding step, a phosphor layer forming step, and a coating layer forming step in this order. Here, a substrate preparation step is included before the die bonding step.
Hereinafter, each step will be described. Note that details of each member of the light-emitting device are as described in the above-described light-emitting device, and thus description thereof will be omitted as appropriate.

<Board preparation process>
The substrate preparation step is a step of preparing a substrate (mounting substrate) 20 including the conductive members 2 a and 2 b, for example, a step of forming the conductive members 2 a and 2 b on the base material 1. The conductive members 2a and 2b may be formed by a conventionally known method. For example, the conductive members 2a and 2b are formed by plating, vapor deposition, sticking to the base material 1, or the like. In the case of sticking to the base material 1, the base material 1 and the conductive members 2a and 2b can be bonded with an adhesive such as a resin. The conductive members 2a and 2b may be formed by etching or the like after the material of the conductive members 2a and 2b is formed on one surface of the substrate 1.

<Die bonding process>
The die bonding process is a process of mounting the light emitting element 10 on the mounting substrate 20. In this die bonding process, the light emitting element 10 is mounted on the upper surfaces of the conductive members 2a and 2b.
The mounting method of the light emitting element 10 is not particularly limited, and may be performed by a commonly used method. For example, the light emitting element 10 and the conductive members 2a and 2b may be joined with solder such as Au—Sn or Sn—Ag—Cu, or an epoxy resin containing a conductive member.

  In the present embodiment, the n-side electrode of the light emitting element 10 and the conductive member 2a are connected via the bump 3a, and the p-side electrode of the light emitting element 10 and the conductive member 2b are connected via the bumps 3b and 3b. Mount with flip chip to connect. Specifically, the bumps 3a and 3b are bonded to the electrode pads of the light emitting element 10 and the conductive members 2a and 2b by ultrasonic bonding.

<Phosphor layer forming step>
The phosphor layer forming step is a step of forming a phosphor layer 40 containing a phosphor on the surfaces of the light emitting element 10 and the mounting substrate 20 by spraying after the light emitting element 10 is mounted.
As a method of forming the phosphor layer 40, formation by spray (spray method) is used. If the spray method is used, the phosphor layer 40 can be formed in a substantially uniform thickness on the surfaces of the light emitting element 10 and the mounting substrate 20. Note that when a slurry containing a phosphor is used as a material to be applied, the material is prevented from being scattered and sprayed easily, and the phosphor easily adheres uniformly to the light emitting element 10.

As the spray method, it is preferable to use a pulse spray method (hereinafter, referred to as a pulse spray method as appropriate). The pulse spray method is a technique in which a resin mixed with particles such as phosphors is intermittently discharged (sprayed in a pulse manner) by air pressure to form a uniform particle layer.
In the case of continuous application, which is a normal spray method, the amount of application increases and the material is likely to scatter, so it is necessary to increase the nozzle speed. On the other hand, since the pulse spray method is intermittent discharge, the amount of application per unit time is small, the nozzle can be moved slowly, and the application liquid can be easily applied to the side surface and the minimal space of the light emitting element 10.

  In addition, the pulse spray method is capable of (1) uniform film formation even if the target application surface is uneven, (2) high adhesion of the coating solution, and application to the side and side of the light emitting element. Easy to do, (3) Color tone correction (application while measuring color tone) is possible, (4) Wide selection of materials regardless of the type of phosphor, (5) High light quality, color tone A coating film having excellent stability can be formed (for example, the range of color variation of the manufactured light emitting device is 2 tones of color tone MacAdam (a light emitting device having substantially no color variation can be mass-produced within 3 steps of McAdam)). And the like.

Next, with reference to FIG. 2, the outline of a pulse type spray apparatus (pulse spray apparatus) will be described.
As shown in FIG. 2, the pulse spray device 30 mainly includes syringes 31 and 32 for storing the slurry SL, a pipe 33 for connecting the syringes 31 and 32, and a spray nozzle 34 for injecting the slurry SL. .

In the syringes 31 and 32, a slurry SL in which phosphor particles, a resin, and a solvent are mixed is stored. In addition, an air compressor (not shown) for sending air is connected to the syringes 31 and 32, whereby the compressed gases 31 b and 32 b are kept at a predetermined pressure inside the syringes 31 and 32. .
In addition, plungers 31a and 32a are provided in the syringes 31 and 32 between the slurry SL and the compressed gases 31b and 32b. Since the plungers 31a and 32a separate the slurry SL from the compressed gases 31b and 32b, the dissolution of the compressed gases 31b and 32b into the slurry SL can be reduced.
A pipe 33 as a liquid passage is connected to the spray nozzle 34. An air compressor (not shown) for sending air is connected to the spray nozzle 34. The angle of the spray nozzle 34 can be adjusted, and the spray nozzle 34 can be inclined with respect to the mounting table 70.

  When spraying, first, air is sent from the air compressor to the syringe 31 at a predetermined pressure with the discharge valve of the spray nozzle 34 closed. The slurry SL filled in the syringe 31 is pressurized by this air feeding, and is pumped toward the syringe 32 through the pipe 33 which is a flow path. Thereafter, similarly, when air is fed into the syringe 32 at a predetermined pressure, the slurry SL filled in the syringe 32 is pressurized and fed toward the syringe 31 via the pipe 33 serving as a flow path. By repeating this, the slurry SL is stirred while moving between the syringes 31 and 32. Thereby, sedimentation of particles having a large specific gravity can be suppressed, and the state in which the particles are dispersed in the slurry SL can be maintained.

  When applying the slurry SL, the discharge valve of the spray nozzle 34 is opened, and air is intermittently sent from the air compressor to the spray nozzle 34 at a predetermined pressure. When this air is being sent in, the slurry SL can be intermittently discharged by opening a valve provided between the air compressor and the spray nozzle 34. As a result, the slurry SL is intermittently ejected together with air from the tip of the spray nozzle 34 and sprayed (reference numeral SP) on the light emitting element 10.

Hereinafter, a method for forming a phosphor layer using the pulse spray method will be described with reference to FIG.
First, a slurry (phosphor slurry) in which phosphors are mixed is prepared. As the phosphor slurry, a mixture of a phosphor, a resin, and a solvent can be used. For example, the phosphor slurry is a mixture of a phosphor, a silicone resin, and n-heptane. The mixing ratio of the phosphor slurry is preferably a mass ratio of phosphor: resin: solvent = 2-40: 5-20: 10-200.
With such a blending ratio, it is easier to spray, and the phosphor is more likely to adhere uniformly to the light emitting element. It should be noted that such a blending ratio can also be suitably applied to spray methods other than the pulse spray method.
Next, the phosphor slurry sufficiently stirred and mixed is put into the syringes 31 and 32 of the pulse spray device 30. Then, the phosphor slurry is moved between the syringes 31 and 32, stirred, and applied by pulse spray. At that time, the phosphor slurry is applied while moving the spray nozzle 34 so that the phosphor slurry can be applied as evenly as possible to the upper and side surfaces of the light emitting element 10.
Thus, after apply | coating a fluorescent substance slurry, resin is temporarily hardened and the layer of fluorescent substance is formed. On the layer, a phosphor slurry is applied in the same manner and temporarily cured to form a second phosphor layer. This is repeated, and the phosphor layer is laminated to a thickness that provides a desired emission color. In this way, the phosphor layer 40 composed of a plurality of layers is formed.

<Coating layer forming step>
The covering layer forming step is a step of forming a covering layer 50 including one or more of a light reflecting material and a light blocking material on the surface of the phosphor layer 40 on the mounting substrate 20.
The method for forming the coating layer 50 is not particularly limited, but it is preferably formed by, for example, an electrodeposition coating method (electrodeposition method) or an electrostatic coating method.

Here, the coating layer forming step when the electrodeposition coating method is used will be described in detail.
In the electrodeposition coating method, the mounting substrate 20 on which the light emitting element 10 is mounted and the other electrode are mounted in an electrodeposition tank containing a solution in which a light-reflective and / or light-shielding material is suspended. A counter electrode serving as an electrode is immersed, and a voltage is applied between the electrodes. Note that a voltage having a polarity different from the polarity with which the light-reflective and / or light-shielding material is charged is applied to the mounting substrate 20 side. As a result, the light reflective and / or light shielding material is electrophoresed and adheres to the surface of the phosphor layer 40 on the conductive members 2 a and 2 b in the mounting substrate 20. At this time, if the light emitting element 10 is an insulator, the light reflective and / or light shielding material does not adhere to the light emitting element 10. On the other hand, when the light emitting element 10 is a conductor, the light emitting element 10 may be masked or another method described later may be used. The thickness of the coating layer 50 can be controlled by adjusting the amount of coulomb determined by the current and time passed between the electrodes.
Although the solvent used for this electrodeposition coating method is not specifically limited, Alcohol solvents, such as IPA (isopropyl alcohol), can be used conveniently.

  The formation of the coating layer 50 is not limited to the electrodeposition coating method and the electrostatic coating method, and a centrifugal sedimentation method or a spray method can also be used. Moreover, it can also use combining the above-mentioned method. In particular, when the coating layer 50 is formed in a portion where the conductive members 2a and 2b are not formed, a centrifugal sedimentation method or a spray method is used. Further, by using a mask, it is possible to prevent the coating layer 50 from being formed at an unnecessary portion.

As mentioned above, although embodiment of this invention was described, this invention is not limited to the said embodiment, It can change in the range which does not deviate from the meaning of this invention.
That is, the light emitting device manufacturing method and the light emitting device embodiment described above exemplify the light emitting device manufacturing method and the light emitting device for embodying the technical idea of the present invention. It is not limited to the manufacturing method or form. Moreover, the member etc. which are shown by a claim are not specified as the member of embodiment. In particular, the dimensions, materials, shapes, relative arrangements, and the like of the components described in the embodiments are not intended to limit the scope of the present invention only to the extent that there is no specific description. It is just an example.
Hereinafter, other embodiments of the present invention will be described.

[Other embodiment 1]
As shown in FIG. 3, in the light emitting device 100A, the conductive members 2a and 2b and the light emitting element 10 are joined by joining members 80a and 80b.
In the light emitting device 100 described above, the light emitting element 10 is placed on the conductive members 2a and 2b via the bumps 3a and 3b. However, as shown in FIG. 3, the light emitting element 10 may be mounted on the conductive members 2a and 2b by eutectic bonding or resin bonding using the bonding members 80a and 80b.
Examples of the eutectic bonding material include an alloy containing Au and Sn as main components, an alloy containing Au and Si as main components, and an alloy containing Au and Ge as main components. Of these, AuSn is particularly preferable. Further, as a material for resin bonding, a resin containing a conductive material may be used.

[Other embodiment 2]
As shown in FIGS. 4A and 4B, the light emitting device 100 </ b> B is formed such that the substrate (mounting substrate) 20 surrounds the mounting portion A on which the light emitting element 10 is mounted and the mounting portion A. And a groove part G. Here, the mounting substrate 20 is composed of the base material 1 (1a, 1b, 1c) and the conductive members 2a, 2b, 2c. Further, in order to show the configuration of the present invention in an easy-to-understand manner, the illustration of the phosphor layer 40 and the coating layer 50 illustrated in FIG. 4B is omitted in FIG. Here, the periphery of the mounting portion A is a portion in the vicinity of the light emitting element 10 that surrounds the four sides of the light emitting element 10. In the present embodiment, the part of the base material 1 c is also around the light emitting element 10 and is included in the vicinity of the light emitting element 10.

  As described above, in the light emitting device 100B, since the groove portion G is formed in the mounting substrate 20 around the light emitting element 10, the periphery of the light emitting element 10 is less likely to emit light, and the point light source property is more excellent. . In addition, the light emitting device 100B has excellent point light source properties and the light reflecting property of the covering layer 50 because the covering layer 50 is formed on the upper surface of the phosphor layer 40 on the base material 1c around the groove portion G. In this case, the reflectance in the vicinity of the light emitting element 10 is improved.

  The area of the upper surface of the mounting portion A is not particularly specified, and may be equal to or less than the area of the lower surface of the light emitting element 10. Further, the size of the groove G is not particularly defined, and may be appropriately adjusted according to the size of the light emitting element 10 or the size of the mounting substrate 20. As an example, the depth is 100 to 500 μm and the width is 10 to 100 μm. The shape of the groove part G is not particularly specified, and may be, for example, a shape surrounding the mounting part A in an annular shape. Further, the groove part G may be provided intermittently around the mounting part A, or may be provided at a part of the periphery of the mounting part A. Further, the position of the groove part G may be adjusted as appropriate so that the periphery of the light emitting element 10 is more difficult to emit light. Further, the coating layer 50 may be formed from the inside of the groove part G to the upper surface of the mounting part A. Thereby, while being excellent in point light source property, when the coating layer 50 is light-reflective, it can be set as the light-emitting device which the reflectance of the light emitting element 10 vicinity improved.

  Such a mounting substrate 20 can be produced in a substrate preparation process. Such a mounting substrate 20 is formed by laminating the base material 1b for the mounting portion A and the base material 1c on the outer periphery on the base material 1a serving as a base, and the conductive members 2a, 2b and the base material 1c on the base material 1b. It can be manufactured by providing the conductive member 2c. What is necessary is just to adhere | attach the base materials to laminate | stack by joining members, such as resin and a solder paste, for example. In addition, a part of one base material may be removed to form the groove G, and then the conductive members 2a, 2b, and 2c may be formed. Alternatively, the groove portion G can be formed by removing a part of the mounting substrate 20 before forming the groove portion G.

  A conductive member 2c is formed on the substrate 1c, and a coating layer 50 is formed on the surface of the phosphor layer 40 on the conductive member 2c. Here, the coating layer 50 is also formed on the end of the phosphor layer 40 on the conductive member 2c on the groove G side. However, even if the coating layer 50 is formed only on the surface of the phosphor layer 40 on the conductive member 2c, the effect of the present invention is not so much affected. Furthermore, the coating layer 50 may be formed on the bottom surface of the groove part G. The conductive members 2a and 2b on the base material 1b and the conductive member 2c on the base material 1c may be non-conductive.

[Other embodiment 3]
Further, in the light emitting device 100B described above, a light reflective member may be embedded in the groove portion G. As shown in FIG. 5, in the light emitting device 100 </ b> C, a light reflective member 90 is embedded in the groove G (see FIG. 4). In such a form, since the phosphor attached to the groove G does not emit light, the point light source is more excellent. In addition, the light reflecting member 90 is more excellent in point light source properties, and the reflectance in the vicinity of the light emitting element 10 is further improved.

The light reflecting member 90 can be embedded by a light reflecting member embedding step of embedding the light reflecting member in the groove G after the phosphor layer forming step. The light reflecting member can be embedded by injecting the light reflecting member into the groove G. The light reflecting member 90 may be embedded after the phosphor layer forming step and before the covering layer forming step, or after the covering layer forming step. When the coating layer 50 is formed in the groove G, the light reflective member may cover the coating layer 50.
The light-reflecting member 90 is formed by, for example, a resin discharge device (not shown) that can be moved (moved) in the vertical direction or the horizontal direction with respect to the mounting substrate 20 above the fixed mounting substrate 20. (See JP 2009-182307 A).

As a material of the light reflecting member 90, an insulating material is preferably used. Moreover, in order to ensure a certain amount of strength, for example, a thermosetting resin, a thermoplastic resin, or the like can be used. More specifically, a phenol resin, an epoxy resin, BT resin, PPA, a silicone resin, etc. are mentioned. In addition, a reflective member (for example, TiO ₂ , Al ₂ O ₃ , ZrO ₂ , MgO) or the like that hardly absorbs light from the light-emitting element 10 and has a large refractive index difference with respect to the base resin is used in the base resin. By dispersing this powder, light can be reflected efficiently.

[Others]
For example, a metal member that improves the efficiency of light reflection in the conductive members 2a and 2b may be provided on the surfaces of the conductive members 2a and 2b. The material of the metal member is not particularly limited. For example, only silver, or an alloy of silver and a metal having high reflectivity such as copper, gold, rhodium, or a multilayer using these silver or each alloy. A film or the like can be used. As a method for providing the metal member, a plating method, a sputtering method, a vapor deposition method, a method for bonding a thin film, or the like can be used.

  Moreover, you may provide the resist film which protects the base material 1 and the electroconductive members 2a and 2b on the surface of the base material 1 and / or the electroconductive members 2a and 2b. The resist film is preferably a reflective film that increases the light reflectance. As such a material, a white insulating material such as a silicone resin containing titanium oxide can be used. A printing method can be suitably used for forming the resist film.

  In addition, the light emitting devices 100, 100 </ b> B, and 100 </ b> C may include an unillustrated underfill between the upper surface of the substrate 1 and the light emitting element 10. By providing the underfill, optical characteristics such as light extraction efficiency are improved, heat dissipation of the light emitting devices 100, 100B, and 100C is improved, and thermal expansion and mechanical stress between the light emitting element 10 and the base material 1 are increased. It can be relaxed. Therefore, the reliability of the light emitting devices 100, 100B, and 100C can be improved. The underfill material is, for example, a thermosetting resin such as a silicone resin or an epoxy resin.

The light emitting devices 100, 100B, and 100C may include a protective element that protects the light emitting element 10 such as a Zener diode. Thereby, the electrostatic breakdown of the light emitting element 10 can be prevented. Since the protective element needs to be electrically connected to the conductive members 2a and 2b, the step of mounting the protective element is preferably performed before the phosphor layer forming step and the covering layer forming step. The protective element may be covered with the phosphor layer 40 and / or the covering layer 50. Thereby, the light absorption by the protective element can be reduced, and the light extraction efficiency of the light emitting device can be increased. The protective element may be mounted by a combination of die bonding and wire bonding, and may be flip chip mounted. However, in order to make it difficult to inhibit light emission from the light emitting element 10, it is flip chip mounted without using a wire. It is preferable.
The protective element is preferably formed at a position separated from the light emitting element 10. Thereby, since the phosphor layer 40 is difficult to adhere to the protective element, the height of the covering member formed on the phosphor layer 40 can be kept low, and the light emission from the light emitting element 10 is hardly inhibited. be able to. As such a configuration, for example, a configuration in which the conductive members 2a and 2b have an extending portion extending from the vicinity of the light emitting element 10 and a protective element is mounted on the extending portion can be mentioned.

In addition, in the above-described embodiment, the light emitting devices 100, 100A, 100B, and 100C include the bumps 3a and 3b or the joining members 80a and 80b. However, a light emitting device that does not include these may be used as the light emitting device. Moreover, although the mounting board | substrate 20 was set as the structure which consists of the base material 1 and electroconductive member 2a, 2b, the mounting board | substrate may be comprised only with electroconductive member 2a, 2b.
In addition, about the other form mentioned above, it can be set as the form similar to the electrically-conductive members 2a and 2b also about the electrically-conductive member 2c of the light-emitting devices 100B and 100C.

  In addition, in the manufacturing method of a light-emitting device, when performing this invention, you may include processes other than an above-described process between each process, or before and behind. For example, other processes such as a substrate cleaning process for cleaning the substrate, an unnecessary object removing process for removing unnecessary substances such as dust, and a mounting position adjusting process for adjusting the mounting position of bumps and light emitting elements may be included. Good.

1, 1a, 1b, 1c Base material 2a, 2b, 2c Conductive member 3a, 3b Bump 10 Light emitting element 20 Mounting substrate 30 Pulse type spray device (pulse spray device)
31, 32 Syringe 31a, 32a Plunger 31b, 32b Compressed gas 33 Pipe 34 Spray nozzle 40 Phosphor layer 50 Coating layer 60 Sealing member 70 Mounting table 80a, 80b Joining member 90 Light reflecting member 100, 100A, 100B, 100C Light-emitting device A Mounting part G Groove part SL Slurry SP Spray

Claims (7)

A die bonding step of mounting the light emitting element on the mounting portion of the substrate having a mounting portion on which the light emitting element is mounted and a groove formed around the mounting portion ;
After the mounting, a phosphor layer forming step of forming a phosphor layer containing a phosphor on the surface of the light emitting element and the substrate by spraying;
A coating layer forming step of forming a coating layer containing at least one of a light-reflective material and a light-shielding material on the surface of the phosphor layer on the substrate;
A method of manufacturing a light emitting device, comprising: a light reflecting member embedding step of embedding a light reflecting member in the groove portion up to a height of the covering layer on the substrate after the phosphor layer forming step . Said spray in the phosphor layer formation step, the manufacturing method of the light emitting device according to Der Ru請 Motomeko 1 intended for applying a slurry containing the phosphor. The slurry containing the phosphor in a weight ratio, phosphor: Resin: solvent = 2 to 40: 5 to 20: 10-200 manufacturing method of a light-emitting device according to Der Ru請 Motomeko 2. Method for producing a spray in the phosphor layer forming step, the light-emitting device according to any one of claims 3 to 請 Motomeko 1 Ru spray der pulsed. The substrate comprises a substrate, and a conductive member provided on the substrate, either the coating layer, from 請 Motomeko 1 you formed by electrodeposition coating method or the electrostatic coating method according to claim 4 A method for manufacturing a light-emitting device according to claim 1. A substrate having a mounting portion on which the light emitting element is mounted, and a groove formed around the mounting portion ;
A light emitting device mounted on the mounting portion of the substrate;
A phosphor layer comprising a plurality of layers formed with a substantially uniform thickness on the surface of the light emitting element and the substrate;
A coating layer containing at least one of a light-reflective material and a light-shielding material that coats the phosphor layer on the substrate;
A light-emitting device comprising: a light-reflecting member embedded in the groove portion up to a height of the covering layer on the substrate .   The light emitting device according to claim 6, wherein the phosphor layer includes phosphor: resin in a mass ratio of 2-40: 5-20.

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