JP6218177B2 - Resin composition and method for producing the same - Google Patents

Description

  The present invention relates to a resin composition containing a modified ethylene-vinyl alcohol copolymer and a polyamide resin, a method for producing the same, and a use thereof.

  An ethylene-vinyl alcohol copolymer (hereinafter sometimes abbreviated as EVOH) is excellent in transparency, gas barrier properties, aroma retention, solvent resistance, oil resistance, etc. It is used in a wide range of applications including various packaging containers such as containers, fuel containers, pharmaceutical packaging containers, industrial chemical packaging containers, and agricultural chemical packaging containers. When used as a packaging container, it may be subjected to treatment such as boil sterilization or retort sterilization after filling the contents such as food, but because EVOH is hydrophilic, a large amount of water enters the EVOH. Since voids are generated in the packaging material and whiten, the appearance is impaired. Further, since EVOH is a very hard and brittle resin, when EVOH is used as a material, it has a disadvantage that it is inferior in the bending resistance of the entire container. In recent years, improvement in bending resistance is also desired.

  Patent Documents 1 and 2 describe a resin composition comprising a copolyamide having EVOH and caproamide as main structural units, and describes that they are excellent in stretchability, gas barrier properties and hot water resistance. However, the bending resistance is insufficient in practice, and there is a problem that the appearance deteriorates after retorting.

  Patent Document 3 discloses modified EVOH and polyamide copolymerized with 3,4-dihydroxy-1-butene units produced by copolymerization of ethylene, vinyl acetate and 3,4-diacetoxy-1-butene and then saponification The resin composition which consists of is described, and it is described that it is excellent in retort resistance, gas barrier property, and pinhole resistance after retort. However, since 3,4-diacetoxy-1-butene has the same polymerization reactivity as vinyl acetate, most of it remains after polymerization when the copolymer is taken out at a low polymerization rate. For this reason, there has been a problem that the load of cleaning and wastewater treatment is increased and the production cost is unavoidable.

Japanese Patent Laid-Open No. 54-078749 Japanese Patent Laid-Open No. 54-077875 JP 2006-124669 A

  The present invention has been made to solve the above-described problems, and includes a modified ethylene-vinyl alcohol copolymer and polyamide that are excellent in barrier properties, retort resistance, and flex resistance, and also in productivity. A resin composition is provided. Moreover, the suitable use of such a resin composition is provided. Furthermore, the suitable manufacturing method of such a resin composition is provided.

  The above problem is represented by the following formula (I), the contents (mol%) of a, b and c with respect to all monomer units satisfy the following formulas (1) to (3), and the following formula (4) The modified ethylene-vinyl alcohol copolymer (A) having a saponification degree (DS) defined by) of 90 mol% or more and polyamide (B) as essential components, and having an ethylene unit content of 20 to 60 This can be solved by providing a resin composition containing, as an optional component, an unmodified ethylene-vinyl alcohol copolymer (C) having a saponification degree of 80 mol% or more by mol%.

[In Formula (I), R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and the alkyl group contains a hydroxyl group, an alkoxy group or a halogen atom. But you can. X, Y and Z each independently represent a hydrogen atom, a formyl group or an alkanoyl group having 2 to 10 carbon atoms. ]

18 ≦ a ≦ 55 (1)
0.01 ≦ c ≦ 20 (2)
[100− (a + c)] × 0.9 ≦ b ≦ [100− (a + c)] (3)
DS = [(total number of moles of hydrogen atoms among X, Y and Z) / (total number of moles of X, Y and Z)] × 100 (4)

At this time, the weight ratio [B / (A + C)] of the polyamide (B) to the total weight of the modified ethylene-vinyl alcohol copolymer (A) and the unmodified ethylene-vinyl alcohol copolymer (C) is 5/95 to The weight ratio (C / A) of the unmodified ethylene-vinyl alcohol copolymer (C) to the modified ethylene-vinyl alcohol copolymer (A) is 0/100 to 90/10. Is preferred. It is also preferred that R ¹ , R ² , R ³ and R ^{4 of the} modified ethylene-vinyl alcohol copolymer (A) are hydrogen atoms. It is also preferable that X, Y and Z of the modified ethylene-vinyl alcohol copolymer (A) are each independently a hydrogen atom or an acetyl group.

The oxygen permeation rate of the resin composition at 20 ° C. and 65% RH is preferably 100 cc · 20 μm / m ² · day · atm or less. A preferred embodiment of the resin composition is a barrier material.

  An extruded product having a layer made of the resin composition is a preferred embodiment of the present invention. An extrusion molded product in which a layer made of the resin composition and a layer made of another thermoplastic resin are laminated is also a preferred embodiment of the present invention.

  The problem is that a modified ethylene-vinyl ester copolymer represented by the following formula (IV) is obtained by radical polymerization of ethylene, a vinyl ester represented by the following formula (II), and an unsaturated monomer represented by the following formula (III). After obtaining a polymer, saponifying it to produce a modified ethylene-vinyl alcohol copolymer (A) and then mixing with the polyamide (B), the method for producing the resin composition It is also solved by providing.

Wherein (II), ^{R 5} represents a hydrogen atom or an alkyl group having 1 to 9 carbon atoms. ]

[In formula (III), R ¹ , R ² , R ³ and R ⁴ are the same as in formula (I). R ⁶ and R ⁷ each independently represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms. ]

[In formula (IV), R ¹ , R ² , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁷ , a, b and c are the same as in formulas (I) to (III). ]

  The resin composition of the present invention containing a modified ethylene-vinyl alcohol copolymer and polyamide is excellent in barrier properties, retort resistance and flex resistance, and also in productivity. Therefore, it can be used for various applications utilizing such characteristics. Moreover, according to the manufacturing method of this invention, the said resin composition can be manufactured efficiently.

2 is a ¹ H-NMR spectrum of a modified EVAc obtained in Synthesis Example 1. 2 is a ¹ H-NMR spectrum of a modified EVOH obtained in Synthesis Example 1.

  The resin composition of the present invention is represented by the following formula (I), the content (mol%) of a, b and c with respect to all monomer units satisfies the following formulas (1) to (3), and A modified ethylene-vinyl alcohol copolymer (A) having a saponification degree (DS) defined by the following formula (4) of 90 mol% or more and a polyamide (B) as essential components, unmodified ethylene- A vinyl alcohol copolymer (C) is included as an optional component.

[In Formula (I), R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and the alkyl group contains a hydroxyl group, an alkoxy group or a halogen atom. But you can. X, Y and Z each independently represent a hydrogen atom, a formyl group or an alkanoyl group having 2 to 10 carbon atoms. ]

18 ≦ a ≦ 55 (1)
0.01 ≦ c ≦ 20 (2)
[100− (a + c)] × 0.9 ≦ b ≦ [100− (a + c)] (3)
DS = [(total number of moles of hydrogen atoms among X, Y and Z) / (total number of moles of X, Y and Z)] × 100 (4)

  The modified EVOH (A) does not include the monomer unit by having a monomer unit having a 1,3-diol structure in the main chain of the copolymer in addition to the ethylene unit and the vinyl alcohol unit. Since the crystallinity is lower than that of EVOH, the bending resistance can be improved. Moreover, since the crystallization speed is also reduced as compared with EVOH not containing the monomer unit, the interlayer adhesion of the multilayer structure having a layer made of the modified EVOH (A) can also be improved. Furthermore, this modified EVOH (A) can reduce the decrease in barrier properties due to the decrease in crystallinity due to the strong hydrogen bonding force of the 1,3-diol structure. As will be described later, this modified EVOH (A) can be produced at a low cost.

  By including the modified EVOH (A) and the polyamide (B), the resin composition of the present invention can improve retort resistance and flex resistance while minimizing a decrease in barrier performance. Has major features.

In the formula (I), R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms. R ¹ , R ² , R ³ and R ⁴ may be the same group or different. The structure of the alkyl group is not particularly limited, and may partially have a branched structure or a cyclic structure. The alkyl group may contain a hydroxyl group, an alkoxy group or a halogen atom. R ¹ , R ² , R ³ and R ⁴ are preferably a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and more preferably a hydrogen atom. Preferred examples of the alkyl group include linear or branched alkyl groups such as methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, tert-butyl group, and pentyl group. Can be mentioned.

  In the formula (I), X, Y and Z each independently represent a hydrogen atom, a formyl group or an alkanoyl group having 2 to 10 carbon atoms. When X, Y or Z is a hydrogen atom, the formula (I) has a hydroxyl group, and when X, Y or Z is a formyl group or an alkanoyl group, the formula (I) has an ester group. . The alkanoyl group is preferably an alkanoyl group having 2 to 5 carbon atoms, and an acetyl group, a propanoyl group, a butanoyl group, and the like are preferred. Among these, an acetyl group is particularly preferable. X, Y and Z are preferably all hydrogen atoms or a mixture containing hydrogen atoms.

  The monomer unit containing X is usually obtained by saponifying a vinyl ester. Therefore, X is preferably a mixture of a hydrogen atom and a formyl group or an alkanoyl group having 2 to 10 carbon atoms. Considering the availability of the monomer (vinyl acetate) and the production cost, it is particularly preferable that X is a mixture of a hydrogen atom and an acetyl group.

  On the other hand, the monomer unit containing Y and Z can be produced by copolymerization of an unsaturated monomer unit having a 1,3-diester structure and then saponification, or a 1,3-diol structure. It can also be produced by copolymerizing the unsaturated monomer unit as it is. Therefore, both Y and Z may be a hydrogen atom alone, or a mixture of a hydrogen atom and a formyl group or an alkanoyl group having 2 to 10 carbon atoms, more preferably a mixture of a hydrogen atom and an acetyl group. It may be.

In the modified EVOH (A) of the present invention, the content (mol%) of a, b and c with respect to all monomer units satisfies the following formulas (1) to (3).
18 ≦ a ≦ 55 (1)
0.01 ≦ c ≦ 20 (2)
[100− (a + c)] × 0.9 ≦ b ≦ [100− (a + c)] (3)

  a shows the content rate (mol%) of the ethylene unit with respect to all the monomer units, and is 18-55 mol%. When the ethylene unit content is less than 18 mol%, the melt moldability of the resin composition of the present invention deteriorates. a is preferably 22 mol% or more. On the other hand, when the ethylene unit content exceeds 55 mol%, the barrier property of the resin composition of the present invention is insufficient. a is preferably 50 mol% or less.

  c represents the content (mol%) of the monomer unit containing Y and Z shown at the right end in the formula (I) with respect to all monomer units, and 0.01 to 20 mol %. When c is less than 0.01 mol%, the resin composition of the present invention has insufficient bending resistance and secondary processability. c is preferably 0.1 mol% or more, and more preferably 0.5 mol% or more. On the other hand, when c exceeds 20 mol%, the crystallinity of the modified EVOH (A) is extremely lowered, and thus the barrier property of the resin composition of the present invention is lowered. c is preferably 10 mol% or less, and more preferably 5 mol% or less.

b shows the content rate (mol%) of the vinyl alcohol unit and the vinyl ester unit with respect to all the monomer units. This satisfies the following formula (3).
[100− (a + c)] × 0.9 ≦ b ≦ [100− (a + c)] (3)

That is, in the modified EVOH (A), 90% or more of the monomer units other than the ethylene unit and the monomer unit containing Y and Z shown at the right end in the formula (I) are vinyl alcohol units or vinyl. It is an ester unit. When the formula (3) is not satisfied, the gas barrier property of the resin composition of the present invention is insufficient. Preferably, the following formula (3 ′) is satisfied, and more preferably, the following formula (3 ″) is satisfied.
[100− (a + c)] × 0.95 ≦ b ≦ [100− (a + c)] (3 ′)
[100− (a + c)] × 0.98 ≦ b ≦ [100− (a + c)] (3 ″)

The degree of saponification (DS) defined by the following formula (4) in the modified EVOH (A) is 90 mol% or more.
DS = [(total number of moles of hydrogen atoms among X, Y and Z) / (total number of moles of X, Y and Z)] × 100 (4)

  Here, “the total number of moles of hydrogen atoms among X, Y and Z” indicates the number of moles of hydroxyl groups, and “the total number of moles of X, Y and Z” is the total number of moles of hydroxyl groups and ester groups. Indicates. If the degree of saponification (DS) is less than 90 mol%, the resin composition of the present invention will not only provide sufficient barrier performance, but also will have insufficient thermal stability, and gels and blisters will occur during thermoforming. It becomes easy. The saponification degree (DS) is preferably 95 mol% or more, more preferably 98 mol% or more, and even more preferably 99 mol% or more.

  The saponification degree (DS) of the modified EVOH (A) can be obtained by a nuclear magnetic resonance (NMR) method. The content of the monomer units represented by a, b and c can also be obtained by the NMR method. The modified EVOH (A) is usually a random copolymer. The fact that it is a random copolymer can be confirmed from NMR and melting point measurement results.

  A suitable melt flow rate (MFR) (under 190 ° C. and 2160 g load) of the modified EVOH (A) is 0.1 to 30 g / 10 minutes, more preferably 0.3 to 25 g / 10 minutes, and further preferably Is 0.5 to 20 g / 10 min. However, those having a melting point near 190 ° C. or exceeding 190 ° C. were measured under a load of 2160 g and at a plurality of temperatures above the melting point, and in a semi-logarithmic graph, the reciprocal absolute temperature was plotted on the horizontal axis and the logarithm of MFR on the vertical axis, The value is extrapolated to 190 ° C.

  Here, when the modified EVOH (A) is composed of a mixture of two or more different types of modified EVOH (A), the content, saponification degree, and MFR of the monomer units represented by a, b, and c are as follows: The average value calculated from the weight ratio is used.

  The production method of the modified EVOH (A) is not particularly limited. For example, a modified ethylene-vinyl ester copolymer represented by the following formula (IV) by radical polymerization of ethylene, a vinyl ester represented by the following formula (II), and an unsaturated monomer represented by the following formula (III) The method of saponifying it after obtaining is mentioned.

In formula (II), R ⁵ represents a hydrogen atom or an alkyl group having 1 to 9 carbon atoms. The number of carbon atoms of the alkyl group is preferably 1 to 4. Examples of the vinyl ester represented by the formula (II) include vinyl formate, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl isobutyrate, vinyl pivalate, vinyl versatate, and vinyl caproate. From the economical viewpoint, vinyl acetate is particularly preferred.

In formula (III), R ¹ , R ² , R ³ and R ⁴ are the same as in formula (I). R ⁶ and R ⁷ each independently represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms. The number of carbon atoms of the alkyl group is preferably 1 to 4. Examples of the unsaturated monomer represented by the formula (III) include 2-methylene-1,3-propanediol diacetate (1,3-diacetoxy-2-methylenepropane), 2-methylene-1,3-propanediol. Examples include dipropionate and 2-methylene-1,3-propanediol dibutyrate. Among these, 2-methylene-1,3-propanediol diacetate is preferably used from the viewpoint of easy production. In the case of 2-methylene-1,3-propanediol diacetate, R ¹ , R ² , R ³ and R ⁴ are hydrogen atoms, and R ⁶ and R ⁷ are methyl groups.

In the formula (IV), R ¹ , R ² , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁷ , a, b and c are the same as those in the formulas (I) to (III). The modified ethylene-vinyl ester copolymer thus obtained is then saponified.

  Further, instead of the unsaturated monomer represented by the above formula (III), an unsaturated monomer represented by the following formula (V) may be copolymerized. Only the unit derived from the unsaturated monomer represented by (II) is saponified.

In formula (V), R ¹ , R ² , R ³ and R ⁴ are the same as in formula (I). Examples of the unsaturated monomer represented by the formula (V) include 2-methylene-1,3-propanediol.

  Since the unsaturated monomer represented by the formula (III) and the formula (V) used in the present invention has high copolymerization reactivity with the vinyl ester monomer, the copolymerization reaction easily proceeds. Therefore, it is easy to increase the amount of modification and the degree of polymerization of the resulting modified ethylene-vinyl ester copolymer. In addition, even if the polymerization reaction is stopped at a low polymerization rate, the amount of unreacted unsaturated monomer remaining at the end of the polymerization is small, which is excellent in terms of environment and cost. In this respect, the unsaturated monomer represented by the formula (III) and the formula (V) has one carbon atom having a functional group at the allylic position, such as allyl glycidyl ether or 3,4-diacetoxy-1-butene. It is only better than other monomers. Here, the unsaturated monomer represented by the formula (III) has higher reactivity than the unsaturated monomer represented by the formula (V).

  A modified ethylene-vinyl ester copolymer is produced by copolymerizing ethylene, a vinyl ester represented by the above formula (II), and an unsaturated monomer represented by the above formula (III) or (V). The polymerization method used may be batch polymerization, semi-batch polymerization, continuous polymerization, or semi-continuous polymerization. Moreover, as a polymerization method, well-known methods, such as a block polymerization method, a solution polymerization method, a suspension polymerization method, and an emulsion polymerization method, are employable. A bulk polymerization method or a solution polymerization method in which polymerization proceeds in a solvent-free or solvent such as alcohol is usually employed. In order to obtain a modified ethylene-vinyl ester copolymer having a high degree of polymerization, the use of an emulsion polymerization method is one of the options.

  Although the solvent used in the solution polymerization method is not particularly limited, alcohol is preferably used. For example, lower alcohols such as methanol, ethanol, and propanol are more preferably used. The amount of solvent used in the polymerization reaction solution may be selected in consideration of the viscosity average polymerization degree of the target modified EVOH (A) and the chain transfer of the solvent. The weight ratio (solvent / total monomers) is selected from the range of 0.01 to 10, preferably 0.05 to 3.

  The polymerization initiator used when copolymerizing ethylene, the vinyl ester represented by the above formula (II), and the unsaturated monomer represented by the above formula (III) or (V) is a known polymerization. The initiator is selected from azo initiators, peroxide initiators, and redox initiators depending on the polymerization method. Examples of the azo initiator include 2,2′-azobisisobutyronitrile, 2,2′-azobis (2,4-dimethylvaleronitrile), and 2,2′-azobis (4-methoxy-2,4). -Dimethylvaleronitrile). Examples of the peroxide initiator include percarbonate compounds such as diisopropyl peroxydicarbonate, di-2-ethylhexyl peroxydicarbonate, diethoxyethyl peroxydicarbonate; t-butylperoxyneodecanate, α -Perester compounds such as cumylperoxyneodecanate and acetyl peroxide; acetylcyclohexylsulfonyl peroxide; 2,4,4-trimethylpentyl-2-peroxyphenoxyacetate and the like. Potassium persulfate, ammonium persulfate, hydrogen peroxide, or the like may be used in combination with the above initiator. The redox initiator is, for example, a polymerization initiator in which the peroxide initiator is combined with a reducing agent such as sodium hydrogen sulfite, sodium hydrogen carbonate, tartaric acid, L-ascorbic acid, or longalite. The amount of the polymerization initiator used varies depending on the polymerization catalyst and cannot be determined unconditionally, but is adjusted according to the polymerization rate. The amount of the polymerization initiator used is preferably 0.01 to 0.2 mol% and more preferably 0.02 to 0.15 mol% with respect to the vinyl ester monomer. The polymerization temperature is not particularly limited, but is suitably about room temperature to 150 ° C, preferably 40 ° C or higher and lower than the boiling point of the solvent used.

  When ethylene is copolymerized with the vinyl ester represented by the above formula (II) and the unsaturated monomer represented by the above formula (III) or (V), the effect of the present invention is not inhibited. If present, it may be copolymerized in the presence of a chain transfer agent. Examples of the chain transfer agent include aldehydes such as acetaldehyde and propionaldehyde; ketones such as acetone and methyl ethyl ketone; mercaptans such as 2-hydroxyethanethiol; phosphinic acid salts such as sodium phosphinate monohydrate and the like. . Of these, aldehydes and ketones are preferably used. The amount of the chain transfer agent added to the polymerization reaction solution is determined according to the chain transfer coefficient of the chain transfer agent and the degree of polymerization of the target modified ethylene-vinyl ester copolymer. 0.1-10 mass parts is preferable with respect to a mass part.

  The modified ethylene-vinyl ester copolymer thus obtained can be saponified to obtain the modified EVOH (A) used in the present invention. At this time, the vinyl ester unit in the copolymer is converted into a vinyl alcohol unit. In addition, the ester bond derived from the unsaturated monomer represented by the formula (III) is simultaneously hydrolyzed and converted into a 1,3-diol structure. Thus, different types of ester groups can be simultaneously hydrolyzed by a single saponification reaction.

  As a saponification method of the modified ethylene-vinyl ester copolymer, a known method can be adopted. The saponification reaction is usually performed in a solution of alcohol or hydrous alcohol. The alcohol preferably used at this time is a lower alcohol such as methanol or ethanol, and particularly preferably methanol. The alcohol or hydrous alcohol used in the saponification reaction may contain other solvents such as acetone, methyl acetate, ethyl acetate, and benzene as long as the weight is 40% by weight or less. The catalyst used for the saponification is, for example, an alkali metal hydroxide such as potassium hydroxide or sodium hydroxide, an alkali catalyst such as sodium methylate, or an acid catalyst such as mineral acid. The temperature at which saponification is performed is not limited, but a range of 20 to 120 ° C. is preferable. When a gel-like product is precipitated as the saponification proceeds, the product is pulverized, washed and dried to obtain a modified EVOH (A).

  The modified EVOH (A) used in the present invention is represented by ethylene, the vinyl ester represented by the above formula (II), and the above formula (III) or (V) as long as the effects of the present invention are not inhibited. It may contain structural units derived from other ethylenically unsaturated monomers that are copolymerizable with unsaturated monomers. Examples of such ethylenically unsaturated monomers include α-olefins such as propylene, n-butene, isobutylene, and 1-hexene; acrylic acid and salts thereof; unsaturated monomers having an acrylate group. Methacrylic acid and salts thereof; unsaturated monomer having a methacrylic ester group; acrylamide, N-methylacrylamide, N-ethylacrylamide, N, N-dimethylacrylamide, diacetone acrylamide, acrylamide propanesulfonic acid and salts thereof; Acrylamidepropyldimethylamine and salts thereof (eg, quaternary salts); methacrylamide, N-methylmethacrylamide, N-ethylmethacrylamide, methacrylamidepropanesulfonic acid and salts thereof, methacrylamidepropyldimethylamine and salts thereof (eg Grade salt); methyl vinyl ether, ethyl vinyl ether, n-propyl vinyl ether, i-propyl vinyl ether, n-butyl vinyl ether, i-butyl vinyl ether, t-butyl vinyl ether, dodecyl vinyl ether, stearyl vinyl ether, 2,3-diacetoxy-1-vinyl Vinyl ethers such as oxypropane; vinyl cyanides such as acrylonitrile and methacrylonitrile; vinyl halides such as vinyl chloride and vinyl fluoride; vinylidene halides such as vinylidene chloride and vinylidene fluoride; allyl acetate, 2, Allyl compounds such as 3-diacetoxy-1-allyloxypropane and allyl chloride; unsaturated dicarboxylic acids such as maleic acid, itaconic acid and fumaric acid and salts or esters thereof; vinyltrimethoxy And vinyl silane compounds such as silane; isopropenyl acetate and the like.

  Specific examples of the polyamide (B) used in the present invention include polycapramide (nylon 6), poly-ω-aminoheptanoic acid (nylon 7), poly-ω-aminononanoic acid (nylon 9), polyundecanamide (nylon 11). ), Polylauryl lactam (nylon 12), polyethylenediamine adipamide (nylon 26), polytetramethylene adipamide (nylon 46), polyhexamethylene adipamide (nylon 66), polyhexamethylene sebacamide (nylon) 610), polyhexamethylene dodecamide (nylon 612), polyoctamethylene adipamide (nylon 86), polydecamethylene adipamide (nylon 106), caprolactam / lauryl lactam copolymer (nylon 6/12), caprolactam / Ω-aminononanoic acid co-polymer Body (nylon 6/9), caprolactam / hexamethylene diammonium adipate copolymer (nylon 6/66), lauryl lactam / hexamethylene diammonium adipate copolymer (nylon 12/66), ethylene diammonium adipate / hexamethylene Diammonium adipate copolymer (nylon 26/66), caprolactam / hexamethylenediammonium adipate / hexamethylenediammonium sebacate copolymer (nylon 6/66/610), ethylenediammonium adipate / hexamethylenediammonium adipate / Hexamethylene diammonium sebacate copolymer (nylon 26/66/610), polyhexamethylene isophthalamide (nylon 6I), polyhexamethylene terephthala (Nylon 6T), hexamethylene isophthalamide / hexamethylene terephthalamide copolymer (nylon 6I / 6T), 11-aminoundecanamide / hexamethylene terephthalamide copolymer, polynonamethylene terephthalamide (nylon 9T), poly Examples include decamethylene terephthalamide (nylon 10T), polyhexamethylene cyclohexyl amide, polynonamethylene cyclohexyl amide, or polyamides modified with aromatic amines such as methylene benzylamine and metaxylene diamine. Moreover, metaxylylene diamine ammonium adipate and the like can be mentioned.

  The degree of polymerization of the polyamide (B) is preferably 1.7 to 5.0, more preferably 2.0 to 5.0, as a relative viscosity measured according to JIS K6810.

  As a polymerization method for the polyamide (B), a melt polymerization, an interfacial polymerization, a solution polymerization, a bulk polymerization, a solid phase polymerization, or a combination of these can be employed. Moreover, as a polyamide raw material, (epsilon) -caprolactam is preferable from the point that more favorable boil resistance and retort resistance are obtained.

  In the resin composition of the present invention, unmodified EVOH (C) may be blended as an optional component in addition to the modified EVOH (A) and the polyamide (B), which are essential components. Here, the unmodified EVOH (C) used in the present invention is a monomer unit containing Y and Z shown at the right end in the formula (I) (shown by the formula (III) or (V)). EVOH which does not contain a structural unit derived from an unsaturated monomer), and general-purpose EVOH which has been widely used conventionally can be used.

  The ethylene unit content of unmodified EVOH (C) is 20 to 60 mol%. When the ethylene unit content is less than 20 mol%, the melt moldability of the resin composition of the present invention deteriorates. The ethylene unit content is preferably 22 mol% or more, and more preferably 24 mol% or more. On the other hand, when the ethylene unit content exceeds 60 mol%, the barrier property of the resin composition of the present invention is insufficient. The ethylene unit content is preferably 55 mol% or less, and more preferably 50 mol% or less.

  The degree of saponification of unmodified EVOH (C) is 80 mol% or more. The degree of saponification is the proportion of saponified vinyl copolymer units. When the saponification degree is less than 80 mol%, the gas barrier property of the resin composition of the present invention becomes insufficient. The degree of saponification is preferably 95 mol% or more, and more preferably 99 mol% or more.

  Unmodified EVOH (C) is ethylene, vinyl ester represented by the above formula (II), and unsaturated monomer represented by the above formula (III) or (V) as long as the effects of the present invention are not inhibited. It may contain a small amount of structural units derived from other ethylenically unsaturated monomers that can be copolymerized with the polymer. As other ethylenically unsaturated monomers, those exemplified in the description of the modified EVOH (A) can be used. The content of structural units derived from other ethylenically unsaturated monomers is usually 10% or less of the total monomer units, preferably 5% or less, more preferably 2%. It is as follows. It is further preferable that the structural unit derived from other ethylenically unsaturated monomers is not substantially contained.

  The preferred melt flow rate (MFR) of unmodified EVOH (C) (at 190 ° C. under a load of 2160 g) is 0.1 to 30 g / 10 minutes, more preferably 0.3 to 25 g / 10 minutes, even more preferred. Is 0.5 to 20 g / 10 min. However, those having a melting point near 190 ° C. or exceeding 190 ° C. were measured under a load of 2160 g and at a plurality of temperatures above the melting point, and in a semi-logarithmic graph, the reciprocal absolute temperature was plotted on the horizontal axis and the logarithm of MFR on the vertical axis, The value is extrapolated to 190 ° C.

  In the resin composition of the present invention, the weight ratio [B / (A + C)] of the polyamide (B) to the total weight of the modified EVOH (A) and the unmodified EVOH (C) is 5/95 to 95/5, The weight ratio (C / A) of unmodified EVOH (C) to modified EVOH (A) is preferably 0/100 to 90/10. When the weight ratio [B / (A + C)] is less than 5/95, the flex resistance of the resin composition may be insufficient. The weight ratio [B / (A + C)] is more preferably 8/92 or more. On the other hand, when the weight ratio [B / (A + C)] exceeds 95/5, the retort resistance may be insufficient. The weight ratio [B / (A + C)] is more preferably 92/8 or less. In addition, when the weight ratio (C / A) is 0/100, that is, when the unmodified EVOH (C) is not included, the production cost of the resin composition may increase. From this viewpoint, the weight ratio (C / A) is more preferably 10/90 or more. On the other hand, when the weight ratio (C / A) exceeds 90/10, the bending resistance may be insufficient. The weight ratio (C / A) is more preferably 80/20 or less.

  The resin composition of the present invention can contain other additives. For example, thermoplastic resins other than EVOH and polyamide, plasticizers, lubricants, stabilizers, surfactants, colorants, ultraviolet absorbers, antistatic agents, drying agents, crosslinking agents, metal salts, fillers, various fibers, etc. A reinforcing agent or the like can be blended. The content of the thermoplastic resin other than the modified EVOH (A), the polyamide (B), and the unmodified EVOH (C) is usually 10% by weight or less of the total thermoplastic resin contained in the resin composition.

  Especially, it is preferable that the resin composition of this invention contains an alkali metal salt. By containing an alkali metal salt, interlayer adhesion when laminated with other resins is improved. The cationic species of the alkali metal salt is not particularly limited, but sodium salt or potassium salt is preferable. The anionic species of the alkali metal salt is not particularly limited. It can be added as a carboxylate, carbonate, bicarbonate, phosphate, hydrogen phosphate, borate, hydroxide or the like.

  It is also preferable that the resin composition of the present invention contains a phosphoric acid compound. By containing the phosphoric acid compound in this way, coloring during melt molding can be prevented. The phosphoric acid compound used for this invention is not specifically limited, Various acids, such as phosphoric acid and phosphorous acid, its salt, etc. can be used. The phosphate may be contained in any form of a first phosphate, a second phosphate, and a third phosphate, but the first phosphate is preferable. The cationic species is not particularly limited, but is preferably an alkali metal salt. Among these, sodium dihydrogen phosphate and potassium dihydrogen phosphate are preferable.

  The resin composition of the present invention may contain a boron compound. Thus, by containing a boron compound, the torque fluctuation at the time of heat-melting can be suppressed. The boron compound used in the present invention is not particularly limited, and examples thereof include boric acids, boric acid esters, borates, and borohydrides. Specific examples of boric acids include orthoboric acid, metaboric acid, and tetraboric acid. Examples of boric acid esters include triethyl borate and trimethyl borate. Examples include alkali metal salts of acids, alkaline earth metal salts, and borax. Among these compounds, orthoboric acid (hereinafter sometimes simply referred to as boric acid) is preferable.

The resin composition of the present invention preferably has an oxygen transmission rate at 20 ° C. and 65% RH of 100 cc · 20 μm / m ² · day · atm or less. The oxygen transmission rate is more preferably 10 cc · 20 μm / m ² · day · atm or less.

  The method for producing the resin composition of the present invention is not particularly limited. It is preferable that the modified EVOH (A) is produced and then mixed with the polyamide (B). At this time, when the unmodified EVOH (C) is further mixed, the modified EVOH (A), the polyamide (B) and the unmodified EVOH (C) may be mixed simultaneously, or two of them may be mixed. The other one may be mixed after mixing in advance. The mixing method is not particularly limited, but is usually mixed in a molten state. The method of melt mixing is not particularly limited, and an extruder, an intensive mixer, a Banbury mixer, a kneader, or the like can be used. At this time, the above-mentioned various additives can be simultaneously added and kneaded.

  When an alkali metal salt, a phosphoric acid compound or a boron compound is added to the resin composition of the present invention, at least one of the modified EVOH (A) and the unmodified EVOH (C) is replaced with an alkali metal salt, phosphoric acid. A method of mixing both resins after contacting with an aqueous solution containing a compound or a boron compound is preferable. In this case, after making it contact with the aqueous solution containing those components with respect to any one of modified | denatured EVOH (A) and unmodified | denatured EVOH (C), it can also mix with the other resin which does not contain those components. However, in order to obtain a stable addition effect, it is preferable to mix both resins after bringing both resins into contact with an aqueous solution.

  A preferred embodiment of the resin composition of the present invention is a barrier material. The resin composition of the present invention has excellent barrier properties against fuels such as gasoline and various chemicals in addition to gases such as oxygen.

  The method for molding the resin composition of the present invention is not particularly limited. Although it can also shape | mold using the solution of a resin composition, melt-molding is preferable. Examples of the melt molding method include methods such as extrusion molding, injection molding, inflation molding, press molding, and blow molding. Among these, extrusion molding is a suitable molding method, and various extruded products can be obtained. Moreover, since the film and sheet having a layer made of the resin composition of the present invention are required to be flexible and are often stretched after melt molding, they are suitable for using the resin composition of the present invention. It is. Here, the film and the sheet may be a single-layer product made of the resin composition of the present invention, or may be a multilayer structure including another thermoplastic resin layer.

  In many cases, the molded article made of the resin composition of the present invention is used as a multilayer structure in which a layer made of the resin composition and a layer made of another thermoplastic resin are laminated. In particular, a configuration in which the resin composition layer of the present invention is used as an intermediate layer, and other thermoplastic resins are arranged in outer layers on both sides thereof is preferable. It is also preferable that the resin composition layer and another thermoplastic resin layer are bonded via an adhesive resin layer. The resin composition layer of the present invention bears barrier properties, and the thickness is usually 3 to 250 μm, preferably 10 to 100 μm. On the other hand, the thermoplastic resin used in the outer layer is not particularly limited, and is appropriately selected in consideration of required performance and applications such as moisture permeability, heat resistance, heat sealability, and transparency. The thickness of the entire multilayer structure is not particularly limited, but is usually 15 to 6000 μm. Suitable embodiments of such multilayer structures include multilayer films or sheets, co-extrusion blow molded containers, co-injection blow molded containers, and the like.

  Other thermoplastic resin layers laminated with the layer comprising the resin composition of the present invention include polyolefins such as polyethylene, polypropylene, ethylene-vinyl acetate copolymer, ethylene- (meth) acrylate ester copolymer; polyamide Polyester, polystyrene, polyvinyl chloride, acrylic resin, polyvinylidene chloride, polyacetal, polycarbonate, and the like.

  The multilayer structure can be obtained by various production methods, and a coextrusion method, a dry lamination method, a sand lamination method, an extrusion lamination method, a coextrusion lamination method, a solution coating method, and the like can be employed. Among these, the co-extrusion method is a method in which the resin composition of the present invention and another thermoplastic resin are simultaneously extruded from an extruder, laminated in a molten state, and discharged into a multilayer film from a die outlet. In the case of forming a film by the coextrusion method, a method in which the adhesive resin layer is sandwiched between the resin composition layer of the present invention and another thermoplastic resin layer is preferable. As the adhesive resin, it is preferable to use a polyolefin having a carboxyl group, a carboxylic anhydride group or an epoxy group. Such an adhesive resin is excellent in adhesiveness with the resin composition of the present invention and adhesiveness with other thermoplastic resins not containing a carboxyl group, a carboxylic anhydride group or an epoxy group.

  Examples of the polyolefin containing a carboxyl group include a polyolefin copolymerized with acrylic acid or methacrylic acid. At this time, as represented by an ionomer, all or a part of the carboxyl groups contained in the polyolefin may be present in the form of a metal salt. Examples of the polyolefin having a carboxylic anhydride group include polyolefins graft-modified with maleic anhydride or itaconic acid. Moreover, as polyolefin resin containing an epoxy group, the polyolefin which copolymerized glycidyl methacrylate is mentioned. Among these polyolefins having a carboxyl group, a carboxylic acid anhydride group, or an epoxy group, polyolefins modified with a carboxylic acid anhydride such as maleic anhydride, particularly polyethylene and polypropylene are preferable from the viewpoint of excellent adhesiveness.

  In addition, it is preferable that the resin composition layer is an intermediate layer and a polyolefin layer is disposed on the inside thereof from the viewpoint of improving the appearance after retort, and a polyamide layer is disposed adjacent to at least one surface of the resin composition layer. It is preferable that the gas barrier performance immediately after the retort is improved.

  The melt-formed product thus obtained can be further subjected to secondary processing. A molded article containing the resin composition of the present invention is also excellent in secondary processability. Examples of the secondary processing method include uniaxial stretching, biaxial stretching, stretch blow molding, thermoforming, and rolling. A film or sheet stretched at a high magnification is a preferred embodiment of the present invention. A thermoformed product is also a preferred embodiment of the present invention. Prior to the secondary processing, crosslinking by radiation irradiation or the like may be performed. A heat shrink film or a heat shrink sheet is also a preferred embodiment of the present invention. This can be produced by leaving the residual stress of the film or sheet stretched as described above without relaxing. The melt-molded product to be subjected to the secondary processing may be a single-layer product made of the resin composition of the present invention, or may be a multilayer structure including another thermoplastic resin layer.

  The molded product of the present invention thus obtained is excellent in barrier properties, flex resistance and secondary processability, and thus is molded into various shapes such as films, cups, bottles, etc., and is suitably used as various containers. be able to. Among them, a useful application is a retort container. The resin composition of the present invention is suitable as a retort container because of its excellent retort resistance and excellent flex resistance.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to this Example.

Synthesis example 1
(1) Synthesis of modified ethylene-vinyl alcohol copolymer (modified EVAc) Vinyl acetate (formula (II)) was added to a 50 L pressure reaction vessel equipped with a jacket, a stirrer, a nitrogen inlet, an ethylene inlet and an initiator inlet. In which R ⁵ is a methyl group (hereinafter referred to as VAc) 21 kg, methanol (hereinafter referred to as MeOH) 2.1 kg, 2-methylene-1,3-propanediol diacetate (in formula (III), R 5 ¹ , R ² , R ³ and R ⁴ are hydrogen atoms, and R ⁶ and R ⁷ are methyl groups: the same compound as 1,3-diacetoxy-2-methylenepropane (hereinafter referred to as MPDAc) After raising the temperature to 60 ° C., nitrogen was bubbled for 30 minutes to replace the inside of the reaction vessel with nitrogen. Next, ethylene was introduced so that the reaction vessel pressure (ethylene pressure) was 4.2 MPa. After adjusting the temperature in the reaction vessel to 60 ° C., 16.8 g of 2,2′-azobis (2,4-dimethylvaleronitrile) (“V-65” manufactured by Wako Pure Chemical Industries, Ltd.) was used as an initiator. Polymerization was started by adding as a methanol solution. During the polymerization, the ethylene pressure was maintained at 4.2 MPa and the polymerization temperature was maintained at 60 ° C. After 4.5 hours, the polymerization was stopped by cooling when the polymerization rate of VAc reached 34%. After the reaction vessel was opened to remove ethylene, nitrogen gas was bubbled to completely remove ethylene. Subsequently, unreacted VAc is removed under reduced pressure, and then MeOH is added to a modified ethylene-vinyl acetate copolymer into which a structural unit derived from MPDAc has been introduced by copolymerization (sometimes referred to as modified EVAc in this specification). A 20% by mass MeOH solution was added.

(2) Saponification of modified EVAc 4715 g of a 20 wt% MeOH solution of modified EVAc obtained in (1) was charged into a 10 L reaction vessel equipped with a jacket, a stirrer, a nitrogen inlet, a reflux condenser and a solution addition port. The temperature was raised to 60 ° C. while blowing nitrogen into the solution, and a MeOH solution having a sodium hydroxide concentration of 2N was added at a rate of 14.7 mL / min for 2 hours. After completing the addition of the sodium hydroxide MeOH solution, the saponification reaction was allowed to proceed by stirring for 2 hours while maintaining the system temperature at 60 ° C. Thereafter, 254 g of acetic acid was added to stop the saponification reaction. Thereafter, 3 L of ion-exchanged water was added while heating and stirring at 80 ° C., and MeOH was allowed to flow out of the reaction vessel to precipitate a modified ethylene-vinyl alcohol copolymer (hereinafter referred to as modified EVOH). The modified EVOH precipitated by decantation was collected and pulverized with a mixer. The obtained modified EVOH powder was put into a 1 g / L acetic acid aqueous solution (bath ratio 20: 20 L of aqueous solution with respect to 1 kg of powder) and washed with stirring for 2 hours. This was drained, and further poured into a 1 g / L aqueous acetic acid solution (bath ratio 20), followed by stirring and washing for 2 hours. The liquid which had been drained was poured into ion-exchanged water (bath ratio 20), and the operation of stirring and washing for 2 hours to drain the liquid was repeated 3 times for purification. Next, the solution was dehydrated after being immersed in 10 L of an aqueous solution containing 0.5 g / L of acetic acid and 0.1 g / L of sodium acetate for 4 hours, and then dried at 60 ° C. for 16 hours to obtain a crude dried product of modified EVOH. Of 503 g.

(3) Manufacture of modified EVOH hydrous pellets In a 3 L stirring tank equipped with a jacket, a stirrer and a reflux condenser, 758 g of a crude EVOH dry product obtained by repeating (2) twice, 398 g of water and 739 g of MeOH were charged, and 85 The solution was heated to 0 ° C. and dissolved. This solution is extruded through a 4 mm diameter glass tube into a mixed solution of water / MeOH = 90/10 cooled to 5 ° C. to precipitate it into a strand, and this strand is cut into a pellet with a strand cutter to modify EVOH. Water-containing pellets were obtained. The moisture content of the resulting modified EVOH hydrous pellets was measured using a halogen moisture meter “HR73” manufactured by Mettler.
”Was 55% by mass.

(4) Production of modified EVOH composition pellets 1577 g of the modified EVOH hydrous pellets obtained in (3) above was charged into a 1 g / L aqueous acetic acid solution (bath ratio 20) and washed with stirring for 2 hours. This was drained, and further poured into a 1 g / L aqueous acetic acid solution (bath ratio 20), followed by stirring and washing for 2 hours. After draining, the acetic acid aqueous solution was renewed and the same operation was performed. Purified by repeating the operation of washing with acetic acid aqueous solution and removing the liquid into ion-exchanged water (bath ratio 20), stirring and washing for 2 hours, and removing the liquid three times. A modified EVOH hydrous pellet from which the residue was removed was obtained. The water-containing pellet is poured into an aqueous solution (bath ratio 20) having a sodium acetate concentration of 0.525 g / L, an acetic acid concentration of 0.8 g / L, and a phosphoric acid concentration of 0.007 g / L, and is immersed for 4 hours with periodic stirring. It was. This was drained and dried at 80 ° C. for 3 hours and at 105 ° C. for 16 hours to obtain modified EVOH composition pellets containing acetic acid, sodium salt and phosphate compound.

(5) Content of each structural unit in modified EVAc Content of ethylene unit in modified EVAc (a mol% in formula (IV)), content of structural unit derived from vinyl acetate (b mol in formula (IV) %) And the content of MPDAc-derived structural units (c mol% in formula (IV)) were calculated by ¹ H-NMR measurement of the modified EVAc before saponification.

First, a small amount of the MeOH solution of the modified EVAc obtained in (1) was sampled, and the modified EVAc was precipitated in ion exchange water. The precipitate was collected and dried at 60 ° C. under vacuum to obtain a dried modified EVAc. Next, the obtained dry product of modified EVAc was dissolved in dimethyl sulfoxide (DMSO) -d ₆ containing tetramethylsilane as an internal standard substance, and ¹ H-NMR of 500 MHz (manufactured by JEOL Ltd .: “GX-500”). )) And measured at 80 ° C.

FIG. 1 shows the ¹ H-NMR spectrum of the modified EVAc obtained in Synthesis Example 1. Each peak in the spectrum is assigned as follows.
0.6-1.0 ppm: methylene proton (4H) in the terminal site ethylene unit
1.0 to 1.85 ppm: methylene proton (4H) of intermediate site ethylene unit, main chain site methylene proton (2H) of structural unit derived from MPDAc, methylene proton of vinyl acetate unit (2H)
1.85-2.1 ppm: MPDAc-derived structural unit methyl proton (6H) and vinyl acetate unit methyl proton (3H)
2.4-2.6 ppm: DMSO
3.7-4.1 ppm: side chain site methylene proton (4H) of structural unit derived from MPDAc
4.4 to 5.3 ppm: methine proton of vinyl acetate unit (1H)

According to the above attribution, the integral value of 0.6 to 1.0 ppm is x, the integral value of 1.0 to 1.85 ppm is y, the integral value of 3.7 to 4.1 ppm is z, and 4.4 to 5. When the integrated value of 3 ppm is w, the content of ethylene units (a: mol%), the content of vinyl ester units (b: mol%) and the content of structural units derived from MPDAc (c: mol%) are Are calculated according to the following equations.
a = [(2x + 2y−z−4w) / (2x + 2y + z + 4w)] × 100
b = [8w / (2x + 2y + z + 4w)] × 100
c = [2z / (2x + 2y + z + 4w)] × 100

  As a result of calculation by the above method, the ethylene unit content (a) was 32.0 mol%, the vinyl ester unit content (b) was 64.1 mol%, and the MPDAc-derived structural unit content (c) was It was 3.9 mol%. The values of a, b and c in the modified EVAc are the same as the values of a, b and c in the modified EVOH after saponification treatment.

(6) Saponification degree of modified EVOH The modified EVOH after saponification was similarly subjected to ¹ H-NMR measurement. The crude dried product of the modified EVOH obtained in the above (2), tetramethylsilane as an internal standard material was dissolved in dimethyl sulfoxide (DMSO) -d ₆ containing tetrafluoro acid (TFA) as an additive, the 500 MHz ¹ Measurement was performed at 80 ° C. using 1 H-NMR (manufactured by JEOL Ltd .: “GX-500”). FIG. 2 shows the ¹ H-NMR spectrum of the modified EVOH obtained in Synthesis Example 1. Since the peak intensity of 1.85 to 2.1 ppm is greatly reduced, in addition to the ester group contained in vinyl acetate, the ester group contained in the MPDAc-derived structural unit is also saponified into a hydroxyl group. It is clear. The degree of saponification was calculated from the peak intensity ratio of methyl protons (1.85 to 2.1 ppm) of vinyl acetate units and methine protons (3.15 to 4.15 ppm) of vinyl alcohol units. The degree of saponification of the modified EVOH was 99.9 mol% or more.

(7) Melting point of modified EVOH About the modified EVOH composition pellet obtained in (4) above, the temperature was raised from 30 ° C. to 215 ° C. at a rate of 10 ° C./minute according to JIS K7121, and then 100 ° C./minute. The sample was rapidly cooled to −35 ° C. and measured again at a rate of temperature increase of 10 ° C./min from −35 ° C. to 195 ° C. (differential scanning calorimeter (DSC) “RDC220 / SSC5200H” manufactured by Seiko Instruments Inc.). . Indium and lead were used for temperature calibration. The melting peak temperature (Tpm) was determined from the 2nd run chart according to the above JIS, and this was taken as the melting point of the modified EVOH. The melting point was 151 ° C.

(8) Sodium salt content and phosphate compound content in the modified EVOH composition 0.5 g of the modified EVOH composition pellets obtained in (4) above was placed in a Teflon (registered trademark) pressure vessel, and concentrated therein. Nitric acid (5 mL) was added and decomposed at room temperature for 30 minutes. After 30 minutes, the lid was covered, and decomposition was performed by heating at 150 ° C. for 10 minutes and then at 180 ° C. for 5 minutes with a wet decomposition apparatus (manufactured by Actac Co., Ltd .: “MWS-2”), and then cooled to room temperature. This treatment liquid was transferred to a 50 mL volumetric flask and diluted with pure water. About this solution, the contained metal was analyzed with the ICP emission spectroscopic analyzer ("OPTIMA4300DV" manufactured by PerkinElmer Co., Ltd.), and the contents of sodium element and phosphorus element were determined. The sodium salt content was 150 ppm in terms of sodium element, and the phosphate compound content was 10 ppm in terms of phosphate radical.

Synthesis example 2
Polymerization was carried out in the same manner as in Synthesis Example 1 (1) except that the amount of MeOH was 6.3 kg, the ethylene pressure was 3.7 MPa, the amount of initiator was 4.2 g, and MPDAc was not charged. It was. After 4 hours, when the polymerization rate of VAc reached 44%, the reaction was cooled to stop the polymerization. Subsequently, an unmodified EVOH composition pellet containing a sodium salt of 135 ppm in terms of sodium element and a phosphate compound content of 11 ppm in terms of phosphate radical was produced by the same treatment as in Synthesis Example 1. The results evaluated in the same manner as in Synthesis Example 1 are summarized in Table 1.

Synthesis example 3
Polymerization was conducted in the same manner as in Synthesis Example 1 (1) except that the amount of initiator was 8.4 g and the amount of MPDAc charged was 0.5 kg. After 6 hours, when the polymerization rate of VAc reached 52%, the reaction was cooled to stop the polymerization. Subsequently, the results of producing and evaluating modified EVOH composition pellets in the same manner as in Synthesis Example 1 are summarized in Table 1.

Synthesis example 4
Modified EVAc was synthesized in the same manner as in Synthesis Example 3 to obtain a methanol solution of modified EVAc. Subsequently, a saponification treatment was performed in the same manner as in (2) of Synthesis Example 1 except that a MeOH solution of sodium hydroxide was added at a rate of 3.7 mL / min. Subsequently, the results of producing and evaluating modified EVOH composition pellets in the same manner as in Synthesis Example 1 are summarized in Table 1.

Synthesis example 5
In Synthesis Example 1 (1), the amount of MeOH is 1.1 kg, the ethylene pressure is 3.8 MPa, the amount of MPDAc is 2.0 kg, and 16.8 g of initiator is added 5 hours after the start of polymerization. Polymerization was carried out in the same manner except that. After 10 hours, when the polymerization rate of VAc reached 9%, it was cooled and the polymerization was stopped. Subsequently, the results of producing and evaluating modified EVOH composition pellets in the same manner as in Synthesis Example 1 are summarized in Table 1.

Synthesis Example 6
The same as in Synthesis Example 1 (1) except that the amount of MeOH was 1.1 kg, the amount of initiator was 16.8 g, the ethylene pressure was 6.0 MPa, and the amount of MPDAc charged was 1.1 kg. Polymerization was carried out by the method. After 4 hours, the polymerization was stopped by cooling when the polymerization rate of VAc reached 22%. Subsequently, the results of producing and evaluating modified EVOH composition pellets in the same manner as in Synthesis Example 1 are summarized in Table 1.

Example 1
(1) Production of Film 90 parts by weight of the modified EVOH composition pellet obtained in Synthesis Example 1 and nylon 6 pellet “SF1018A” (polyamide (B): hereinafter abbreviated as “nylon 6”, manufactured by Ube Industries, Ltd .: relative viscosity [Ηr] 3.0, melting point 221 ° C.) 10 parts by weight were dry-blended, and then melt-kneaded in a twin-screw extruder and pelletized. Using the obtained pellets, a 20 mm extruder “D2020” (D (mm) = 20, L / D = 20, compression ratio = 2.0, screw: full flight) manufactured by Toyo Seiki Seisakusho Co., Ltd. A single-layer film was formed under the above conditions to obtain a single-layer film made of the resin composition.
Cylinder temperature: Supply unit 200 ° C, compression unit 220 ° C, weighing unit 220 ° C
Die temperature: 240 ° C
Screw rotation speed: 40-100rpm
Discharge amount: 0.4 to 1.5 kg / hour Take-up roll temperature: 80 ° C.
Take-up roll speed: 0.8 to 3.2 m / min Film thickness: 20 μm

(2) Oxygen transmission rate measurement The monolayer film of 20 μm thickness obtained in (1) above was conditioned for 3 days under the conditions of 20 ° C. and 85% RH, and the oxygen transmission rate was measured under the same conditions (Mocon "OX-TORAN MODEL 2/21") manufactured by the company was performed. As a result, the oxygen transmission rate (OTR) was 5.1 cc · 20 μm / m ² · day · atm. The results are shown in Table 2.

(3) Flexural resistance test The film having a thickness of 20 μm obtained in (1) was conditioned under conditions of 20 ° C./65% RH, and then bent using a gelboflex tester manufactured by Rigaku Corporation. The sex was measured. First, a 12 inch × 8 inch film was rolled and fastened with a ring to form a cylinder having a diameter of 3.5 inches. Grip both ends in accordance with ASTM F392, with initial gripping distance of 7 inches, gripping distance of 1 inch at maximum bending, and a twist of 440 degrees at the first 3.5 inches of stroke, followed by 2.5 inches of straight horizontal A reciprocating motion consisting of repetition of motion as a motion was performed at a speed of 40 times / minute. It was A when bending resistance was evaluated as follows. The results are shown in Table 2.
A: No pinholes generated after 50 reciprocations B: The number of reciprocating motions where the first pinhole is generated is 40 times or more and 50 times or less C: Reciprocating motion where the first pinhole is generated Less than 40 times

(4) Retort resistance test On the 20 μm resin composition film obtained in (1), an adhesive for dry lamination (two-pack type, urethane type) “A-520 / A-50” manufactured by Takeda Pharmaceutical Company Limited. ”And the solvent was evaporated at 80 ° C., and then a nylon film“ EMBLEM ONBC ”(biaxially stretched nylon film, double-sided corona-treated product, thickness 15 μm) manufactured by Unitika Ltd. was bonded. Next, after applying the dry laminating adhesive on the other side of the film obtained in (1) and evaporating the solvent at 80 ° C., polypropylene (hereinafter abbreviated as PP) manufactured by Mitsui Chemicals, Inc. ) Film “RXC-22” (unstretched PP film, single-sided corona-treated product, thickness 50 μm) was bonded. The PP film was bonded so that the corona-treated surface became an adhesive surface. Thereafter, the obtained film is aged at 40 ° C. for 5 days to obtain a multilayer film having a constitution of nylon 6 / adhesive layer / resin composition / adhesive layer / PP = 15 μm / 4 μm / 20 μm / 4 μm / 50 μm. It was.

The obtained multilayer film is sealed on all sides so that the PP layer is on the inside, and a 12 cm × 12 cm pouch containing 80 mL of distilled water is prepared. When the appearance was visually observed and evaluated as follows, it was A.
A: Overall high transparency and no unevenness B ... Local whitening is observed C ... Overall uneven whitening is observed

Example 2
A monolayer film was prepared and evaluated in the same manner as in Example 1 (1) except that 50 parts by weight of the modified EVOH composition pellets and 50 parts by weight of nylon 6 were used. The results are summarized in Table 2.

Example 3
In the same manner as in Example 1 (1), except that 80 parts by weight of modified EVOH composition pellets, 10 parts by weight of nylon 6 and 10 parts by weight of unmodified EVOH composition pellets obtained in Synthesis Example 2 were used. Single layer films were prepared and evaluated. The results are summarized in Table 2.

Example 4
In Example 3, a monolayer film was prepared and evaluated in the same manner except that 70 parts by weight of modified EVOH composition pellets, 10 parts by weight of nylon 6 and 20 parts by weight of unmodified EVOH composition pellets were used. The results are summarized in Table 2.

Example 5
In Example 1 (1), the modified EVOH composition pellet obtained in Synthesis Example 3 was used in place of the modified EVOH composition pellet obtained in Synthesis Example 1, and 80 parts by weight of modified EVOH composition pellets and nylon 6 were used. A single-layer film was prepared and evaluated in the same manner except that the amount was 20 parts by weight. The results are summarized in Table 2.

Example 6
In Example 5, a single layer film was produced and evaluated in the same manner except that the modified EVOH composition pellet obtained in Synthesis Example 4 was used instead of the modified EVOH composition pellet obtained in Synthesis Example 3. . The results are summarized in Table 2.

Example 7
In Example 3, the modified EVOH composition pellet obtained in Synthesis Example 5 was used in place of the modified EVOH composition pellet obtained in Synthesis Example 3, and 10 parts by weight of the modified EVOH composition pellet and 20 parts by weight of nylon 6 were used. A single layer film was prepared and evaluated in the same manner except that the weight was 70 parts by weight of the unmodified EVOH composition pellets. The results are summarized in Table 2.

Example 8
In Example 3, the modified EVOH composition pellet obtained in Synthesis Example 6 was used instead of the modified EVOH composition pellet obtained in Synthesis Example 3, and 40 parts by weight of the modified EVOH composition pellet and 20 parts by weight of nylon 6 were used. A single layer film was prepared and evaluated in the same manner except that the amount was 40 parts by weight of the unmodified EVOH composition pellets. The results are summarized in Table 2.

Example 9
In Example 7, a single layer film was prepared and evaluated in the same manner except that the modified EVOH composition pellets were 50 parts by weight and the unmodified EVOH composition pellets were 30 parts by weight. The results are summarized in Table 2.

Example 10
In Example 7, a monolayer film was produced and evaluated in the same manner except that the modified EVOH composition pellets were 30 parts by weight and the unmodified EVOH composition pellets were 50 parts by weight. The results are summarized in Table 2.

Comparative Example 1
In Example 1 (1), only the unmodified EVOH composition pellet obtained in Synthesis Example 2 was used, and a single layer film was formed in the same manner except that dry blending and melt kneading with nylon 6 were not performed. Fabricated and evaluated. The results are summarized in Table 2.

Comparative Example 2
A single layer film was prepared in the same manner as in Example 1 (1) except that the unmodified EVOH composition pellets obtained in Synthesis Example 2 were used instead of the modified EVOH composition pellets obtained in Synthesis Example 1. Were prepared and evaluated. The results are summarized in Table 2.

Comparative Example 3
In Example 5, a single layer film was prepared and evaluated in the same manner except that the unmodified EVOH composition pellet obtained in Synthesis Example 2 was used instead of the modified EVOH composition pellet obtained in Synthesis Example 1. did. The results are summarized in Table 2.

Comparative Example 4
In Example 2, a single layer film was prepared and evaluated in the same manner except that the unmodified EVOH composition pellet obtained in Synthesis Example 2 was used instead of the modified EVOH composition pellet obtained in Synthesis Example 1. did. The results are summarized in Table 2.

Comparative Example 5
A monolayer film was produced in the same manner as in Example 1 (1) except that only the modified EVOH composition pellets obtained in Synthesis Example 1 were used and dry blending and melt kneading with nylon 6 were not performed. And evaluated. The results are summarized in Table 2.

Comparative Example 6
A single layer film was prepared and evaluated in the same manner as in Example 1 (1) except that only nylon 6 pellets were used and dry blending and melt kneading with the modified EVOH composition pellets were not performed. The results are summarized in Table 2.

Claims (9)

It is represented by the following formula (I), and the content (mol%) of a, b and c with respect to all monomer units satisfies the following formulas (1) to (3) and is defined by the following formula (4). The modified ethylene-vinyl alcohol copolymer (A) having a saponification degree (DS) of 90 mol% or more and polyamide (B) are essential components, and the saponification is performed at an ethylene unit content of 20 to 60 mol%. A resin composition comprising an unmodified ethylene-vinyl alcohol copolymer (C) having a degree of 80 mol% or more as an optional component.

[In Formula (I), R ¹ , R ² , R ³ and R ⁴ each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and the alkyl group contains a hydroxyl group, an alkoxy group or a halogen atom. But you can. X, Y and Z each independently represent a hydrogen atom, a formyl group or an alkanoyl group having 2 to 10 carbon atoms. ]
18 ≦ a ≦ 55 (1)
0.01 ≦ c ≦ 20 (2)
[100− (a + c)] × 0.9 ≦ b ≦ [100− (a + c)] (3)
DS = [(total number of moles of hydrogen atoms among X, Y and Z) / (total number of moles of X, Y and Z)] × 100 (4)   The weight ratio [B / (A + C)] of the polyamide (B) to the total weight of the modified ethylene-vinyl alcohol copolymer (A) and the unmodified ethylene-vinyl alcohol copolymer (C) is 5/95 to 95/5. The weight ratio (C / A) of the unmodified ethylene-vinyl alcohol copolymer (C) to the modified ethylene-vinyl alcohol copolymer (A) is from 0/100 to 90/10. The resin composition described in 1. The resin composition according to claim 1 or 2, wherein R ¹ , R ² , R ³ and R ^{4 of the} modified ethylene-vinyl alcohol copolymer (A) are hydrogen atoms.   The resin composition according to any one of claims 1 to 3, wherein X, Y and Z of the modified ethylene-vinyl alcohol copolymer (A) are each independently a hydrogen atom or an acetyl group. 5. The resin composition according to claim 1, wherein the oxygen transmission rate at 20 ° C. and 65% RH is 100 cc · 20 μm / m ² · day · atm or less.   The barrier material which consists of a resin composition in any one of Claims 1-5   An extrusion-molded article having a layer made of the resin composition according to any one of claims 1 to 5.   The extrusion molded product according to claim 7, wherein a layer made of the resin composition and a layer made of another thermoplastic resin are laminated. A modified ethylene-vinyl ester copolymer represented by the following formula (IV) is obtained by radical polymerization of ethylene, a vinyl ester represented by the following formula (II), and an unsaturated monomer represented by the following formula (III). And then saponifying it to produce a modified ethylene-vinyl alcohol copolymer (A) and then mixing with the polyamide (B). A method for producing a resin composition.

Wherein (II), ^{R 5} represents a hydrogen atom or an alkyl group having 1 to 9 carbon atoms. ]

[In formula (III), R ¹ , R ² , R ³ and R ⁴ are the same as in formula (I). R ⁶ and R ⁷ each independently represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms. ]

[In formula (IV), R ¹ , R ² , R ³ , R ⁴ , R ⁵ , R ⁶ , R ⁷ , a, b and c are the same as in formulas (I) to (III). ]

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