JP6209565B2 - Method for producing solid cosmetic soap that generates carbon dioxide - Google Patents
Method for producing solid cosmetic soap that generates carbon dioxide Download PDFInfo
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- JP6209565B2 JP6209565B2 JP2015148806A JP2015148806A JP6209565B2 JP 6209565 B2 JP6209565 B2 JP 6209565B2 JP 2015148806 A JP2015148806 A JP 2015148806A JP 2015148806 A JP2015148806 A JP 2015148806A JP 6209565 B2 JP6209565 B2 JP 6209565B2
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- 239000000344 soap Substances 0.000 title claims description 60
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims description 52
- 239000007787 solid Substances 0.000 title claims description 52
- 239000002537 cosmetic Substances 0.000 title claims description 49
- 239000001569 carbon dioxide Substances 0.000 title claims description 26
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 36
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 27
- 239000003094 microcapsule Substances 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 23
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- 150000007524 organic acids Chemical class 0.000 claims description 17
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 14
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 36
- 239000003795 chemical substances by application Substances 0.000 description 19
- 238000011156 evaluation Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000017531 blood circulation Effects 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000008149 soap solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FDEQQCOTLPPCAO-UHFFFAOYSA-N Cl.OC(O)=O Chemical compound Cl.OC(O)=O FDEQQCOTLPPCAO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229940061720 alpha hydroxy acid Drugs 0.000 description 1
- 150000001280 alpha hydroxy acids Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000008326 skin blood flow Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
- C11D9/12—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/18—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
Description
本発明は、従来一般に公知の固形化粧石鹸用素材に炭酸水素ナトリウムを含有せしめてアルカリ性の固形化粧石鹸用素材とし、該アルカリ性の固形化粧石鹸用素材に多孔質シリカにクエン酸等の有機酸を圧入して内包させて形成したマイクロカプセルを配合し、固形化粧石鹸の使用時に二酸化炭素を発生させることができる固形化粧石鹸の製造方法に関する。 In the present invention, an alkali solid cosmetic soap material is prepared by adding sodium hydrogen carbonate to a publicly known solid cosmetic soap material, and an organic acid such as citric acid is added to porous silica in the alkaline solid soap material. The present invention relates to a method for producing a solid cosmetic soap which can be blended with microcapsules formed by press-fitting and generate carbon dioxide when the solid cosmetic soap is used.
従来、炭酸水素ナトリウムを含有せしめて二酸化炭素を発生させる固形化粧石鹸を含む化粧品は、１剤と２剤（逆の場合もある）を用事混合して、１剤に含まれる炭酸水素ナトリウムを２剤に含まれる有機酸で反応させて二酸化炭素を発生させるものであった。そして、二酸化炭素を発生させずに化粧品として安定に保つために、１剤をアルカリ性にしておけば長時間安定であるが、二酸化炭素を発生させるためには、酸の２剤を添加して、系を酸性にする必要がある。一方、固形化粧石鹸は、その使用時に二酸化炭素を発生させることで、肌の血行促進、皮膚洗浄、消臭等の効能が期待できる。しかし、用事混合で１剤と２剤を混ぜる過程は時間がかかり不便なため、便利な１剤型式で使用時に二酸化炭素を発生させる固形化粧石鹸が待ち望まれていた。 Conventionally, cosmetics including solid cosmetic soap containing sodium hydrogen carbonate to generate carbon dioxide are mixed with 1 agent and 2 agents (there is the opposite case) and 2 sodium bicarbonates contained in 1 agent are mixed. It was made to react with the organic acid contained in the agent to generate carbon dioxide. And in order to keep it stable as cosmetics without generating carbon dioxide, it is stable for a long time if one agent is made alkaline, but in order to generate carbon dioxide, two agents of acid are added, The system needs to be acidic. On the other hand, solid cosmetic soap can be expected to have the effects of promoting blood circulation, skin washing, deodorization, etc. by generating carbon dioxide during use. However, since the process of mixing one agent and two agents in ergonomic mixing is time consuming and inconvenient, there has been a long-awaited solid cosmetic soap that generates carbon dioxide when used in a convenient one agent type.
特に、固形化粧石鹸は脂肪酸の強塩基性塩であって、強塩基性のため、相反する塩基性物質と酸性物質を共存させるのが極めて困難であり、更に加えて、石鹸使用中に酸性２剤を塗布することは、事実上使用法からもほぼ不可能であるので、１剤型式で使用時に二酸化炭素を発生させることができる固形化粧石鹸が望まれていた。 In particular, solid cosmetic soap is a strong basic salt of a fatty acid and it is very basic, so it is extremely difficult to coexist with a contradictory basic substance and an acidic substance. Since it is practically impossible to apply the agent, it has been desired to have a solid cosmetic soap that can generate carbon dioxide at the time of use in a single agent type.
そして、基礎化粧品の分野において、二酸化炭素を発生させるものとして、過去の特許文献を遡及検索すると、１剤を酸性の溶液にし、２剤を炭酸塩素を含有するアルカリ性溶液とし、両者を用事混合し二酸化炭素を発生させる「二剤式二酸化炭素発生組成物」が、下記各特許文献に開示されて公知である。 And in the field of basic cosmetics, when searching past patent documents for generating carbon dioxide, one agent becomes an acidic solution, two agents become an alkaline solution containing chlorine carbonate, and both are mixed. A “two-component carbon dioxide generating composition” that generates carbon dioxide is disclosed in the following patent documents and is publicly known.
前記特許文献に記載された「二酸化炭素発生組成物」は、１剤を酸性の溶液にし、２剤を炭酸塩を含有するアルカリ性溶液とし、両者を用事混合して二酸化炭素を発生させるものであるが、１剤と２剤を用事混合するのに手間と時間がかかり不便であるという課題があった。 The “carbon dioxide generating composition” described in the above-mentioned patent document is one in which one agent is an acidic solution, two agents are alkaline solutions containing carbonates, and both are mixed for generation to generate carbon dioxide. However, there is a problem that it takes time and effort to mix one agent and two agents, which is inconvenient.
本発明は、前記課題を解決すべくなされたものであって、従来一般に公知の固形化粧石鹸用素材に、炭酸水素ナトリウムを含有せしめてアルカリ性固形化粧石鹸用素材とし、該アルカリ性固形化粧石鹸用素材に多孔質シリカにクエン酸等の有機酸を圧入して内包させて形成したマイクロカプセルを配合することにより、従来のように、１剤と２剤を用事混合することなく、１剤式で系の安定性を保ちつつ、固型化粧石鹸の使用時のみ、二酸化炭素を発生させることができる固形化粧石鹸の製造方法を提供しようとするものである。 The present invention has been made in order to solve the above-mentioned problems, and is made into a material for an alkaline solid cosmetic soap by adding sodium hydrogen carbonate to a conventionally known solid cosmetic soap material, and the alkaline solid cosmetic soap material. By blending microcapsules formed by press-fitting organic acid such as citric acid into porous silica and encapsulating it, the conventional system can be used in a one-component system without mixing one agent and two agents as before. It is an object of the present invention to provide a method for producing a solid cosmetic soap capable of generating carbon dioxide only when using a solid cosmetic soap while maintaining the stability of the above.
本発明は、一般に既に公知の素材として使用されている固形化粧石鹸用素材（水を含む）８８．０〜９８．０重量％に、炭酸水素ナトリウム１．０〜７．０重量％を添加混入して製造されたアルカリ性固形化粧石鹸用素材に、更に多孔質シリカに有機酸を圧入して内包させて形成したマイクロカプセル１．０〜５．０重量％を配合して製造するという手段を採用することにより、上記課題を解決した。 In the present invention, 1.0 to 7.0% by weight of sodium hydrogen carbonate is added to 88.0 to 98.0% by weight of a solid soap soap material (including water) that is generally used as a known material. Adopted a means to manufacture by mixing 1.0 to 5.0% by weight of microcapsules formed by press-fitting organic acid into porous silica and encapsulating it into the alkaline solid soap material produced by By doing so, the above problems were solved.
前記本発明製造方法に基づき、一般に既に公知の素材として使用されている複数種の固形化粧石鹸用素材に、炭酸水素ナトリウムを含有せしめて製造したアルカリ性固形化粧石鹸用素材に、クエン酸等の有機酸を多孔質シリカに圧入して内包させて形成したマイクロカプセルを配合して製造した固形化粧石鹸の使用時に、湯水等により溶かした石鹸液を手で肌に塗布摩擦すると、その摩擦力により、前記マイクロカプセルが破壊され、該マイクロカプセルに内包されている有機酸が露出して、これらが炭酸水素ナトリウムを反応して二酸化炭素を発生させ、肌の血行促進、洗浄および消臭効果を実現することができるという優れた効果を奏することができる。 Based on the above-mentioned production method of the present invention, a plurality of types of solid cosmetic soap materials that are generally already used as publicly known materials, and an alkaline solid cosmetic soap material produced by adding sodium bicarbonate to organic materials such as citric acid. When using a solid cosmetic soap manufactured by blending microcapsules formed by pressing an acid into porous silica and encapsulating it, when a soap solution dissolved in hot water is applied to the skin by hand, the friction force The microcapsules are destroyed, the organic acids contained in the microcapsules are exposed, and these react with sodium hydrogen carbonate to generate carbon dioxide, realizing skin blood circulation promotion, cleaning and deodorizing effects. The outstanding effect that it can be performed can be produced.
本発明の実施例を詳細に説明する。本発明は、固形化粧石鹸を製造する際、一般に既に公知の素材として使用されている複数種の固形化粧石鹸用素材に、炭酸水素ナトリウムを添加混入して製造されたアルカリ性固形化粧石鹸用素材に、更に多孔質シリカに有機酸を圧入して内包させて形成したマイクロカプセルを配合して製造する固形化粧石鹸の製造方法であって、前記本発明によって製造された固形化粧石鹸を、湯水等により溶かした石鹸液を手で肌に塗布摩擦すると、その摩擦力により、前記マイクロカプセルが破壊され、該マイクロカプセルに内包されている有機酸を露出させて、該露出した有機酸が炭酸水素ナトリウムと反応して、石鹸の使用時に二酸化炭素を発生させることができる化粧用石鹸の製造方法である。 Examples of the present invention will be described in detail. The present invention provides an alkaline solid cosmetic soap material produced by adding sodium bicarbonate to a plurality of types of solid cosmetic soap materials that are generally used as publicly known materials when producing a solid cosmetic soap. Furthermore, a method for producing a solid cosmetic soap produced by blending microcapsules formed by press-fitting an organic acid into porous silica and encapsulating the same, wherein the solid cosmetic soap produced according to the present invention is prepared with hot water or the like. When the melted soap solution is applied and rubbed to the skin by hand, the microcapsule is broken by the frictional force, exposing the organic acid contained in the microcapsule, and the exposed organic acid is mixed with sodium bicarbonate. It is a method for producing a cosmetic soap that can react to generate carbon dioxide when the soap is used.
前記有機酸を圧入して内包させて形成するマイクロカプセルは、従来一般に広く知られている方法により製造することができるが、本発明においては、多孔質のシリカの粉末を使用する。また、前記多孔質のシリカに圧入して内包する有機酸は、α―ヒドロキシ酸であるクエン酸、グリコール酸、リンゴ酸および乳酸のいずれをも使用することができる。そして、前記有機酸を圧入して内包させるマイクロカプセルは、平均粒径０．５〜４５０μｍの多孔質シリカを担体として製造される。 The microcapsule formed by press-fitting and encapsulating the organic acid can be produced by a generally known method. In the present invention, porous silica powder is used. Moreover, as the organic acid that is press-fitted into the porous silica and encapsulated, any of citric acid, glycolic acid, malic acid, and lactic acid, which are α-hydroxy acids, can be used. The microcapsules that are encapsulated by press-fitting the organic acid are produced using porous silica having an average particle size of 0.5 to 450 μm as a carrier.
本発明は、従来一般に公知の素材として使用されている複数種の固形化粧石鹸用素材に、炭酸水素ナトリウムを含有せしめてアルカリ性固形化粧石鹸用素材とし、該アルカリ性固形化粧石鹸用素材に、クエン酸等の有機酸を多孔質シリカに圧入して内包させて形成したマイクロカプセルを配合して製造する固形化粧石鹸の製造方法であり、以下、図１に、本発明の素材を使用して製造された固形化粧石鹸と、他の素材を使用して製造された固形化粧石鹸の各素材の配合割合および製造された各化粧用石鹸の評価を比較して示す。なお、本実施例においては、前記有機酸として、クエン酸を使用するものとして説明する。 The present invention provides an alkaline solid cosmetic soap material by adding sodium hydrogen carbonate to a plurality of types of solid cosmetic soap materials that are conventionally used as publicly known materials, and the alkaline solid cosmetic soap material contains citric acid. 1 is a method for producing a solid cosmetic soap produced by blending microcapsules formed by press-fitting an organic acid such as, etc. into porous silica, and is manufactured using the material of the present invention in FIG. A comparison is made of the blending ratio of each raw material soap and other cosmetic soaps manufactured using other materials and the evaluation of each manufactured soap. In this example, it is assumed that citric acid is used as the organic acid.
図１は、本発明二酸化炭素を発生させる固形化粧石鹸の製造方法により製造された固形化粧石鹸と、他の方法により製造された固形化粧石鹸の各素材の配合割合（重量％）とその評価結果を示す図である。図１に示す「処方１」〜「処方８」が各素材の配合割合を変えて製造した固形化粧石鹸を示す。前記処方中の「石鹸素地」・「グリセリン」・「１・３ＢＧ」および「防腐剤」は、固形化粧石鹸用の素材として一般に既に公知の素材として使用されているので、その配合割合はいずれも同一である。図１中の「クエン酸多孔質シリカマイクロカプセル」は、前記「多孔質シリカにクエン酸を圧入して内包させて形成したマイクロカプセル」のことで、本発明製造方法における素材であるが、他の「クエン酸ゼラチンマイクロカプセル」は、前記本発明素材である「クエン酸多孔質シリカマイクロカプセル」と比較するために使用した。前記「クエン酸ゼラチンマイクロカプセル」は、本発明とは異なり、クエン酸を「ゼラチンマイクロカプセル」に内包したものである。更に、「炭素水素ナトリウム」はクエン酸等の酸と反応して二酸化炭素を発生させるものとして使用している。また更に、配合割合の表中の最下段の「水で１００」との記載は、前記各素材を配合した後、これらに水を加えて、全体の重量を「１００重量％」とするという意味である。なお、前記「クエン酸多孔質シリカマイクロカプセル」は、クエン酸３５重量％、多孔質シリカ６５重量％の配合比率として製造したものを使用した。
FIG. 1 shows the blending ratio (% by weight) of each material of the solid cosmetic soap produced by the method for producing solid cosmetic soap that generates carbon dioxide of the present invention, and the solid cosmetic soap produced by other methods, and the evaluation results thereof. FIG. “
前記各処方に従い各素材を配合して製造された固形化粧石鹸の「評価」の欄の上段には、「１．製剤の定着性（使用前に二酸化炭素を発生しない）」につき検証した結果が示されている。そして、「二酸化炭素」を発生しない、すなわち「固形化粧石鹸の完成直後、１日後、２日後、１週間後」の経時において、何も変化なし：◎」という評価を得たのは、「処方４」と「処方５」であった。また、「処方６」〜「処方８」および「処方２」も最高の評価ではないが、ある程度の評価が得られた。更に「評価」の欄には、「２、二酸化炭素の気泡の発生」を検証した結果が示されている。「気泡の確認」および「血行良し悪し」を検証した結果、「良好◎」の評価を得たのは、「処方２」・「処方３」・「処方５」・「処方６」および「処方７」であり、「処方８」は最高の評価ではないが、ある程度の評価が得られた。そして、前記２つの評価で、いずれも最高の評価を得たのは「処方５」の固形化粧石鹸であり、また多少優れた評価を得たのは、「処方２」および「処方６」〜「処方８」の固形化粧石鹸であった。
In the upper section of the “Evaluation” column of the solid cosmetic soap produced by blending each material according to each prescription, the result of verification regarding “1. Fixation of the preparation (carbon dioxide is not generated before use)” is shown. It is shown. In addition, “carbon dioxide” is not generated, that is, “no change in the lapse of time immediately after completion of the solid cosmetic soap, 1 day, 2 days, 1 week”: 4 ”and“
前記図１の評価の結果、一般に既に公知の素材として広く使用されている複数種の固形化粧石鹸用素材（水を含む）８８．０〜９８．０重量％に、炭酸水素ナトリウム１．０〜７．０重量％を添加混入して製造されたアルカリ性固形化粧石鹸用素材に、更に多孔質シリカに有機酸を圧入して内包させて形成したマイクロカプセル１．０〜５．０重量％を配合する配合割合が、特に好ましい配合割合であることを確認した。 As a result of the evaluation shown in FIG. 1, a plurality of types of solid soap soap materials (including water) that are generally widely used as publicly known materials are included in an amount of 88.0 to 98.0% by weight, sodium bicarbonate 1.0 to Blended with 1.0 to 5.0% by weight of microcapsules formed by adding an organic acid into porous silica and encapsulating it into a material for alkaline solid soap that was prepared by adding 7.0% by weight It was confirmed that the blending ratio to be performed was a particularly preferable blending ratio.
そして、図１の評価の結果、一般に既に公知の素材として使用されている複数種の固形化粧石鹸用素材（水を含む）９３．０重量％に、炭酸水素ナトリウム４．０重量％を添加混入して製造されたアルカリ性化粧品石鹸用素材に、更に多孔質シリカに有機酸を圧入して内包させて形成したマイクロカプセル３．０重量％を配合する場合割合が、最も好ましい配合割合であることを確認した。 As a result of the evaluation shown in FIG. 1, 4.0% by weight of sodium hydrogen carbonate is added to 93.0% by weight of a plurality of types of solid soap materials (including water) that are generally used as publicly known materials. In the case of blending 3.0% by weight of microcapsules formed by further encapsulating an organic acid into porous silica, the ratio is the most preferable blending ratio. confirmed.
以上のことから、一般に既に公知の素材として使用されている複数種の固形化粧石鹸用素材（水を含む）８８．０〜９８．０重量％に、炭酸水素ナトリウム１．０〜７．０重量％を添加混入して製造されたアルカリ性固形化粧石鹸用素材に、更に多孔質シリカに有機酸を圧入して内包させて形成したマイクロカプセル１．０〜５．０重量％を配合して製造した固形化粧石鹸が、固型化粧石鹸として使用しないときは二酸化炭素が発生せず安定で、使用時のみ二酸化炭素を発生させ、肌の血行促進、洗浄、消臭効果において優れていることが確認できた。 In view of the above, a plurality of kinds of solid cosmetic soap materials (including water) 88.0 to 98.0% by weight, which are generally used as publicly known materials, and 1.0 to 7.0% by weight of sodium bicarbonate. In addition, it is manufactured by blending 1.0 to 5.0% by weight of microcapsules formed by press-fitting an organic acid into porous silica and encapsulating it into a raw material for alkaline solid cosmetic soap produced by adding and mixing%. Solid soap does not generate carbon dioxide when it is not used as solid soap, is stable and generates carbon dioxide only during use, confirming excellent blood circulation promotion, cleaning, and deodorizing effects. It was.
Claims (1)
It is manufactured by adding 1.0 to 7.0% by weight of sodium bicarbonate to 88.0 to 98.0% by weight of solid cosmetic soap materials (including water) that are generally used as known materials. Carbon dioxide, characterized in that it is produced by blending 1.0 to 5.0% by weight of microcapsules formed by press-fitting an organic acid into porous silica and encapsulating it with a raw material for alkaline solid cosmetic soap. A method for producing the generated solid cosmetic soap.
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