JP6197320B2 - Liquid crystal display - Google Patents

Description

  The present invention relates to a liquid crystal display device having high luminance even when it is thin.

Conventionally, optical displays are widely used in televisions, computers, mobile phones, smartphones, and the like. A common liquid crystal display (LCD) is a typical example of such an optical display. The configuration of the liquid crystal display is a liquid crystal display in which a backlight, a backlight side polarizing plate, a liquid crystal cell, and a viewing side polarizing plate are laminated from the back side. Generally, a diffuser sheet, a lens sheet, a reflector, and the like are provided on the backlight side of the backlight side polarizing plate, and are devised to efficiently and uniformly irradiate the light from the light source on the viewer side.
However, since the backlight side polarizing plate transmits only a specific polarized light beam (linearly polarized light) and absorbs the other polarized light beam, there is a problem that only half of the light of the backlight is used.

  In order to solve this problem, there has been proposed a technique for improving the luminance by installing a polarizing reflection plate between the backlight side polarizing plate and the diffuse reflection sheet (reflection plate). The polarized light reflector has a function of transmitting only polarized light in a specific direction and reflecting polarized light components orthogonal thereto. By installing the polarizing reflector so that the transmission axis direction of the backlight-side polarizing plate coincides with the transmission axis direction of the polarizing reflector, the polarizing reflector transmits the backlight-side polarizing plate out of the light emitted from the backlight. Only the polarized light component that is not reflected, and the polarized light that is reflected by the polarized light reflection plate is reflected again by the diffuse reflection sheet (reflecting plate) to the viewing side, so that the polarized light is eliminated, and the polarized light component that passes through the polarized light reflection plate, That is, it is possible to generate a polarization component that passes through the backlight side polarizing plate, and to increase the total amount of light that passes through the backlight side polarizing plate.

  However, in recent years, thinning has progressed mainly in portable terminal devices such as smartphones and tablet computers, and these display devices have not been able to obtain a sufficient brightness enhancement effect.

Japanese National Patent Publication No. 9-506985 Special table 2002-502503 gazette

The present invention has been made against the background of such prior art problems. That is, an object of the present invention is a liquid crystal display device having high luminance even if it is a thin display device.

As a result of intensive studies, the present inventors have found that the above problems can be solved by the following means, and have reached the present invention.
That is, this invention consists of the following structures.

Item 1. In a liquid crystal display device having at least a reflecting plate, a backlight, a polarizing reflecting plate, a backlight side polarizing plate, a liquid crystal cell, and a viewing side polarizing plate, the retardation is 3000 to 300 between the reflecting layer of the reflecting plate and the polarizing reflecting plate. A liquid crystal display device provided with a high retardation film having a value of 150,000 nm.
Item 2. Item 2. The liquid crystal display device according to Item 1, wherein an angle formed between a transmission axis of a polarizer of the backlight side polarizing plate and an orientation main axis direction of the high retardation film is 45 ± 30 degrees or less.
Item 3.
Either a transmissive diffusion sheet or a lens sheet using a high retardation film having a retardation of 3000 to 150,000 nm as a base film is provided between the backlight or the light guide plate and the polarizing reflector. Item 3. A liquid crystal display device according to item 1 or 2.
Item 4.
Item 4. The liquid crystal display device according to any one of Items 1 to 3, wherein the reflector is a metal plate or a metal thin film laminate.

According to the present invention, the luminance of the liquid crystal display device is improved.

Conventional display configuration (edge light method) Conventional image display device configuration (direct type)

The liquid crystal display device of the present invention has at least a reflector, a backlight, a high retardation film, a polarizing reflector, a backlight side polarizing plate, a liquid crystal cell, and a viewing side polarizing plate. The liquid crystal display device is preferably arranged in the order of the reflector, the backlight, the polarizing reflector, the backlight side polarizing plate, the liquid crystal cell, and the viewing side polarizing plate from the back side.

(High retardation film)
The retardation of the high retardation film is preferably 3000 nm or more and 150,000 nm or less from the viewpoint of enhancing luminance without color unevenness. The lower limit of the retardation of the high retardation film is preferably 4500 nm or more, preferably 6000 nm or more, preferably 8000 nm or more, preferably 10,000 nm or more. On the other hand, the upper limit of the retardation of the high retardation film is not substantially obtained even if a film having a retardation higher than that is used, and the thickness of the oriented film depends on the retardation height. Therefore, it is set to 150,000 nm from the viewpoint that it may be contrary to the demand for thinning, but it can be set to a higher value.

  From the viewpoint that color unevenness is unlikely to occur even when viewed obliquely, the high retardation film has a ratio (Re / Rth) of the retardation (Re) to the thickness direction retardation (Rth) of preferably 0.2 or more. , Preferably 0.5 or more, preferably 0.6 or more. Thickness direction retardation means an average value of retardation obtained by multiplying two birefringences ΔNxz and ΔNyz by film thickness d when viewed from a cross section in the film thickness direction. As Re / Rth is larger, the birefringence action is more isotropic, and the luminance can be effectively increased without color unevenness. In this document, when simply described as “retardation”, it means in-plane retardation.

  The maximum value of Re / Rth is 2.0 (that is, a perfect uniaxial symmetry film), but the mechanical strength in the direction perpendicular to the orientation direction tends to decrease as the perfect uniaxial symmetry film is approached. is there. Therefore, the upper limit of Re / Rth of the high retardation film is preferably 1.2 or less, and preferably 1.0 or less.

  The retardation of the oriented film can be measured according to a known method. Specifically, it can be determined by measuring the refractive index and thickness in the biaxial direction. Moreover, it can also obtain | require using the commercially available automatic birefringence measuring apparatus (For example, KOBRA-21ADH: Oji Scientific Instruments Co., Ltd. make).

  The high retardation film can be produced by appropriately selecting a known method. For example, a high retardation film is a polyester resin, polycarbonate resin, polystyrene resin, syndiotactic polystyrene resin, polyether ether ketone resin, polyphenylene sulfide resin, cycloolefin resin, liquid crystalline polymer resin, and a liquid crystal compound added to a cellulose resin. It can manufacture using 1 or more types selected from the group which consists of resin. Therefore, the high retardation film is a polyester film, polycarbonate film, polystyrene film, syndiotactic polystyrene film, polyetheretherketone film, polyphenylene sulfide film, cycloolefin film, liquid crystalline film, and a liquid crystal compound added to a cellulose resin. It can be a film.

  Preferred raw material resins for the high retardation film are polycarbonate, polyester, and syndiotactic polystyrene. These resins are excellent in transparency and excellent in thermal and mechanical properties, and the retardation can be easily controlled by stretching. Polyesters typified by polyethylene terephthalate and polyethylene naphthalate are preferable because they have a large intrinsic birefringence, and relatively large retardation can be obtained even when the film thickness is thin. In particular, polyethylene naphthalate has a large intrinsic birefringence among polyesters, and therefore is suitable for a case where it is desired to make the retardation particularly high or a case where it is desired to reduce the film thickness while keeping the retardation high. A more specific method for producing a high retardation film will be described later using a polyester resin as a representative example.

  Below, the manufacturing method of a high retardation film is demonstrated to a polyester film as an example. The polyester film can be obtained by condensing an arbitrary dicarboxylic acid and a diol. Examples of the dicarboxylic acid include terephthalic acid, isophthalic acid, orthophthalic acid, 2,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid, and diphenylcarboxylic acid. Acid, diphenoxyethanedicarboxylic acid, diphenylsulfonecarboxylic acid, anthracenedicarboxylic acid, 1,3-cyclopentanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, hexahydroterephthalic acid, hexahydroisophthalate Acid, malonic acid, dimethylmalonic acid, succinic acid, 3,3-diethylsuccinic acid, glutaric acid, 2,2-dimethylglutaric acid, adipic acid, 2-methyladipic acid, trimethyladipic acid, pimelic acid, azelaic acid, Dimer , It may be mentioned sebacic acid, suberic acid, dodecamethylene dicarboxylic acid.

  Examples of the diol include ethylene glycol, propylene glycol, hexamethylene glycol, neopentyl glycol, 1,2-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, decamethylene glycol, 1,3-propanediol, 1,4 -Butanediol, 1,5-pentanediol, 1,6-hexadiol, 2,2-bis (4-hydroxyphenyl) propane, bis (4-hydroxyphenyl) sulfone and the like can be mentioned.

  Each of the dicarboxylic acid component and the diol component constituting the polyester film may be used alone or in combination of two or more. Specific polyester resins constituting the polyester film include, for example, polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, etc., preferably polyethylene terephthalate and polyethylene naphthalate, more preferably polyethylene terephthalate. is there. The polyester resin may contain other copolymer components, and from the viewpoint of mechanical strength, the proportion of the copolymer components is preferably 3 mol% or less, more preferably 2 mol% or less, still more preferably 1.5 mol% or less. is there. These resins are excellent in transparency and excellent in thermal and mechanical properties. Moreover, retardation of these resins can be easily controlled by stretching.

  The polyester film can be obtained according to a general production method. Specifically, the polyester resin is melted and the non-oriented polyester extruded and formed into a sheet shape is stretched in the longitudinal direction by utilizing the speed difference of the roll at a temperature equal to or higher than the glass transition temperature, and then in the transverse direction by a tenter. An oriented polyester film is mentioned by extending | stretching and heat-processing. The polyester film may be a uniaxially stretched film or a biaxially stretched film. Further, the high retardation film may be stretched in a direction substantially 45 degrees obliquely with respect to the MD direction.

  Manufacturing conditions for obtaining a polyester film can be appropriately set according to a known method. For example, the longitudinal stretching temperature and the transverse stretching temperature are usually 80 to 130 ° C, preferably 90 to 120 ° C. The longitudinal draw ratio is usually 1.0 to 3.5 times, preferably 1.0 to 3.0 times. The transverse draw ratio is usually 2.5 to 6.0 times, preferably 3.0 to 5.5 times.

  Controlling the retardation within a specific range can be performed by appropriately setting the stretching ratio, stretching temperature, and film thickness. For example, it becomes easier to obtain a higher retardation as the stretching ratio between the longitudinal stretching and the lateral stretching is higher, the stretching temperature is lower, and the film is thicker. On the contrary, it becomes easier to obtain a lower retardation as the stretching ratio between the longitudinal stretching and the lateral stretching is lower, the stretching temperature is higher, and the film thickness is thinner. Moreover, the higher the stretching temperature and the lower the total stretching ratio, the easier it is to obtain a film having a lower ratio of retardation to thickness direction (Re / Rth). Conversely, a film having a higher ratio of retardation to thickness direction retardation (Re / Rth) can be obtained as the stretching temperature is lower and the total stretching ratio is higher. Furthermore, the heat treatment temperature is usually preferably 140 to 240 ° C, and preferably 180 to 240 ° C.

  In order to suppress the fluctuation of the retardation in the polyester film, it is preferable that the thickness unevenness of the film is small. If the longitudinal stretching ratio is lowered to make a retardation difference, the value of the longitudinal thickness unevenness may be increased. Since there is a region where the value of the vertical thickness unevenness becomes very high in a specific range of the draw ratio, it is desirable to set the film forming conditions so as to exclude such a range.

The thickness unevenness of the polyester film is preferably 5.0% or less, more preferably 4.5% or less, still more preferably 4.0% or less, and 3.0% or less. Is particularly preferred. The thickness unevenness of the film can be measured by any means. For example, a tape-like sample (length: 3 m) continuous in the film flow direction is collected and 100 cm at a 1 cm pitch using a commercially available measuring instrument (for example, an electronic micrometer, Millitron 1240 manufactured by Seiko EM Co., Ltd.). The thickness of the point is measured, the maximum value (dmax), the minimum value (dmin), and the average value (d) of the thickness are obtained, and the thickness unevenness (%) can be calculated by the following formula.
Thickness unevenness (%) = ((dmax−dmin) / d) × 100

(Polarized reflector)
The polarization reflector has a function of transmitting only polarized light in a specific direction and reflecting polarized light components orthogonal to the passing polarized light. By installing the polarizing reflector so that the transmission axis direction of the backlight-side polarizing plate coincides with the transmission axis direction of the polarizing reflector, the polarizing reflector transmits the backlight-side polarizing plate out of the light emitted from the backlight. Only the polarized light component that is not reflected, and the polarized light that is reflected by the polarized light reflection plate is reflected again by the diffuse reflection sheet (reflecting plate) to the viewing side, so that the polarized light is eliminated, and the polarized light component that passes through the polarized light reflection plate, That is, it is possible to generate a polarization component that passes through the backlight side polarizing plate, and to increase the total amount of light that passes through the backlight side polarizing plate.

(Production method of polarizing reflector)
For example, a polarizing reflector having such a function uses a resin (resin A) that easily generates birefringence due to stretching and a resin (resin B) that does not easily generate birefringence. B, A, B, A, B,...) And orient in one direction (multi-layered type) or blend resin A and resin B to create a sea-island structure and orient in one direction (dispersion) Type). Further, a resin (resin C) having a positive birefringence in which the refractive index in the molecular orientation direction is larger than that in the orthogonal direction and a resin (resin D) having a negative birefringence in which the refractive index in the molecular orientation direction is smaller than that in the orthogonal direction. ) May be performed in a similar manner.
The multi-layered type polarizing reflector is, for example, by melting each resin and laminating 100 layers or more, preferably 200 layers using a feed block or the like, and extruding it on a cooling roll. It can be obtained by stretching and heat-setting in the longitudinal direction or the transverse direction 3 times or more, preferably 4 times or more.
The dispersion-type polarizing reflector is, for example, melt-mixed in an extruder and extruded onto a cooling roll, and the obtained unstretched sheet is stretched by 3 times or more, preferably 4 times or more in the longitudinal direction or the transverse direction. It can be obtained by heat fixing.
In the combination of the resin A and the resin B and the combination of the resin C and the resin D, the refractive indexes in the main alignment direction of the respective resins are almost the same, and the refractive indexes in the direction orthogonal to the main alignment direction are different. The refractive indexes in the main alignment directions of the respective resins are different so that the refractive indexes in the directions orthogonal to the main alignment directions are substantially the same. By doing so, it is possible to obtain a film that transmits polarized light in the direction in which the refractive indexes are substantially the same and reflects polarized light in the direction in which the refractive index is different.

(Polarized reflector resin)
Polyester such as polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polytrimethylene terephthalate (PTT), polybutylene terephthalate (PBT), polycyclohexanedimethylene terephthalate (PCT), etc. Resin, polyimide resin (PI), polyetherimide, atactic polystyrene (APS), syndiotactic polystyrene (SPS), polycarbonate (PC), polymethyl methacrylate (PMMA) and other acrylic resins, N-substituted maleimide copolymer resins, Cellulose derivatives such as cellulose acetate and cellulose propionate, polyolefins such as polypropylene (PP) and polymethylpentene, polytetrafluoroethylene, fluorinated ethylene-propylene copolymer, polyfluorination Fluorine resin such as nilidene, chlorine resin such as polyvinylidene chloride and polyvinyl chloride, polysulfone, polyethersulfone, polyacrylonitrile, polyamide, silicone resin, epoxy resin, polyvinyl acetate, polyether-amide, ionomer resin, elastomer, polyurethane, etc. There are various things.
Of these, polyester resins, polycarbonate resins, polyamide resins, polyphenylene ether resins, polysulfone resins, polyether sulfone resins, polyarylate resins and the like are typical positive birefringent resins. As mentioned. PMMA, N-substituted maleimide copolymer resins, and polystyrene resins are listed as typical negative birefringent resins.

  These resins may be copolymers. By making it a copolymer, the refractive index of the resin is matched, or by making it amorphous, it becomes difficult to be oriented and difficult to cause birefringence. Refraction can be made difficult to occur.

  Further, these resins may be blended and used. By blending, the refractive index of the resin can be adjusted, or by making it amorphous, it is difficult to be oriented to make birefringence difficult, or the photoelastic coefficient can be made low to make birefringence difficult to produce.

Suitable copolymers include, for example, polyester in the case of polyethylene naphthalate, terephthalic acid, isophthalic acid in the acid component, butanediol, neopentyl glycol, cyclohexanedimethanol, and diethylene glycol in the glycol component. 50 mol% (acid component and glycol component are each 100 mol%) copolymerized, polyethylene terephthalate, acid component naphthalene dicarboxylic acid, isophthalic acid, glycol component, butanediol, neopentyl glycol, Examples include those obtained by copolymerizing cyclohexane dimethanol and diethylene glycol in an amount of 10 to 50 mol% (the acid component and the glycol component are each 100 mol%).
Other examples include styrene copolymers such as styrene-butadiene copolymers, styrene-acrylonitrile copolymers, styrene-maleic anhydride copolymers, and styrene-N-substituted maleimide copolymers.

  Among these, particularly preferred combinations are PEN / copolymerized PEN, PEN / copolymerized PET, PET / copolymerized PEN, PET / copolymerized PET, PEN / styrene resin, PET / styrene resin, PEN / PCT, PET / PCT, PEN / styrene copolymer, and the like.

The surface of the polarizing reflector may be provided with unevenness or bead-coated to have a diffusion or condensing function.
The polarizing reflector may be directly attached to a polarizer used as a backlight side polarizing plate and used as a backlight side polarizer protective film. In this case, a method may be employed in which polyvinyl alcohol is laminated on the polarizing reflector before stretching and then uniaxially stretched, and further iodine is adsorbed on the polyvinyl alcohol layer.
The polarizing reflector is commercially available from 3M as DBEF, and can be used.

(reflector)
The reflecting plate not only reflects the light from the backlight source to the viewing side, but also has a function of reflecting the polarized light reflected by the polarizing reflecting plate to the viewing side again.

Reflector plate is a metal thin film laminate with white pigment added, white resin film containing fine bubbles, metal plate such as aluminum or stainless steel, aluminum foil laminated to the base material, or aluminum or silver deposited Is mentioned. As a suitable example of the base material of a metal thin film laminated board, transparent base materials, such as glass and resin, are mentioned. The reflection layer is a white layer when the reflection plate is white, and is a metal layer when the reflection plate is a metal thin film laminate.
Among these, a polyester film is one of suitable substrates. Alternatively, the reflectance may be increased by depositing metal on the white resin film.

  In order to make the display thinner and to obtain a high brightness improvement effect even if the display is thin, the reflection plate is preferably a metal plate or a metal thin film laminate. Even if it is such a metal plate or a metal thin film laminated plate, a high brightness improvement effect is acquired in this invention.

  The reflection surface of the metal plate or metal thin film laminate may be specular reflection, or may be provided with unevenness and diffusely reflected.

  Using a high retardation film as the base material of the reflector, placing the high retardation film on the viewing side and the metal thin film on the opposite side is also preferable for reducing the number of parts used and thinning the display device It is.

  It is also a preferred form that a metal thin film is provided on the surface opposite to the viewing side of the light guide plate, and the reflection plate and the light guide plate are integrated.

The thickness of the reflector is preferably 300 μm or less, more preferably 200 μm or less, further preferably 150 μm or less, particularly preferably 100 μm or less, and most preferably 50 μm or less. The lower limit is preferably 5 μm or more from the viewpoint of handleability.
In addition, if it is 150 micrometers or less, especially 100 micrometers or less, a sufficient reflective effect may not be acquired with a white resin film, and it is preferable to set it as a metal thin film laminated board.

(Backlight)
The light source used for the backlight preferably has a white light source having a continuous and broad emission spectrum from the viewpoint of suppressing color unevenness. The method and structure of the light source having a continuous and broad emission spectrum are not particularly limited, and may be, for example, an edge light method or a direct type.

In the direct type, it is preferable that the light source is provided on a transparent substrate when the reflecting plate is at the lower portion, or is provided on a ribbon-like or rod-like substrate in the case of an opaque substrate. The light source itself may be ribbon-shaped or rod-shaped. Alternatively, it may be provided on the reflecting plate, or a hole or a slit may be provided in the reflecting plate, and light from a light source installed at the lower portion of the reflecting plate may be emitted therefrom. Furthermore, in order to prevent the occurrence of uneven brightness, an umbrella may be provided on the viewing side of the light source so that the light from the light source is not directly emitted to the viewing side.
In the case of a planar light emitting body such as an organic electroluminescence light source, the light source may have a size of the entire back surface of the image display portion. In this case, the surface of the light emitter itself functions as a reflector.

“Continuous and broad emission spectrum” means an emission spectrum in which there is no wavelength region where the light intensity becomes zero in the wavelength region of at least 450 to 650 nm, preferably in the visible light region. The visible light region is, for example, a wavelength region of 400 to 760 nm, and may be 360 to 760 nm, 400 to 830 nm, or 360 to 830 nm.

As a white light source having a continuous and broad emission spectrum, for example, a white light emitting diode (white LED) can be exemplified. White LEDs include phosphor-type LEDs (that is, elements that emit white light by combining a light emitting diode that emits blue light or ultraviolet light using a compound semiconductor and a phosphor) and organic light emitting diodes (Organic light-emitting diodes). : OLED). A white light-emitting element that combines a blue light-emitting diode using a compound semiconductor with a yttrium, aluminum, and garnet-based yellow phosphor from the viewpoint of having a continuous and broad emission spectrum and excellent luminous efficiency. Light emitting diodes are preferred.

(Light guide plate)
In the case of an edge light type light source, light irradiated from the side is guided to the lower part of the liquid crystal display device and emitted to the viewing side.
The light guide plate has a base material in which a diffusing agent such as white pigment or resin beads is dispersed, a transparent base material provided with a diffusion layer on one or both sides, and a prism-like surface on the transparent base material. Various types such as those provided with a pattern are exemplified, but any type can be used in the present invention.
Examples of the resin used as the base material of the light guide plate include transparent resins such as acrylic resins, polycarbonate resins, styrene resins, cyclic and chain olefin resins, polyester resins, and polyamide resins.

  A light guide plate of a type in which a diffusing agent is dispersed in a substrate is obtained, for example, by adding a diffusing agent to the above resin, melt-kneading, extruding it onto a cooling roll, and stretching it uniaxially or biaxially as required.

  As a method of providing a diffusion layer on a transparent substrate, a method can be obtained by co-extrusion of a transparent resin and a resin to which a diffusing agent is added, or by coating a diffusing agent-containing coating on a transparent resin film or sheet. . For coating, there are a method of coating the entire surface, a method of coating with dots, stripes, a specific pattern, and the like.

  Examples of the diffusing agent include inorganic fine particles such as silica, calcium carbonate, barium sulfate, titanium oxide, and aluminum oxide, and organic fine particles such as silicone beads, PMMA beads, and styrene beads. Moreover, you may disperse | distribute during melt-kneading using a thermoplastic resin incompatible with a base material. The shape of the diffusing agent may be a spherical shape, a spherical shape, a scale shape, an indefinite shape, or the like, and is not particularly limited. The number average particle diameter of these diffusing agents is preferably 0.1 μm or more and 50 μm or less.

  Examples of the binder resin for the paint include polyester, urethane, acrylic, and the like, which are selected in consideration of the adhesiveness with the base material and the difference in refractive index between the base material and the diffusing agent.

  Examples of a method for providing a prism-like specific pattern on the surface of a transparent substrate include, for example, a method of embossing the substrate surface using a mold with a specific pattern, a mold with a specific pattern by applying a photosensitive resin such as acrylic For example, a method of curing with ultraviolet rays while contacting the substrate.

In order to reduce the number of parts and thin the liquid crystal display device, it is also a preferable form to use a high retardation film for the base material of the light guide plate.
Furthermore, as described above, it is also a preferable form that a metal such as aluminum is vapor-deposited on the side opposite to the viewing side of the light guide plate to give a function as a reflecting plate. In this case, considering the light guide plate as a reflection plate, the reflection layer is a metal layer.

(Transmission type diffusion sheet)
As a method for reducing the partial luminance unevenness of the display device, it is also preferable to provide a transmission type diffusion sheet between the backlight or the light guide plate and the polarizing reflection plate. The transmission type diffusion sheet may be either an anisotropic diffusion type having a high degree of diffusion in one direction or an isotropic diffusion type showing a similar degree of diffusion in the entire range in accordance with the backlight.

  Examples of the transmissive diffusion sheet include those having a concavo-convex surface on a transparent substrate, those obtained by dispersing a diffusing agent in a transparent resin, and those obtained by laminating a diffusing agent-containing layer on one or both sides of a transparent substrate. Both are preferably used.

  Transparent resins such as acrylic resins, polycarbonate resins, styrene resins, cyclic and chain olefin resins, polyester resins, polyamide resins, and triacetyl cellulose are used as the base material of the transmission type diffusion sheet. Resin. Among these, polyesters such as polyethylene terephthalate and polyethylene naphthalate are preferable examples, and these biaxially stretched films are most preferable as the base material.

  A transmission type diffusion sheet in which a diffusing agent is dispersed in a base material is obtained, for example, by adding a diffusing agent to the above resin, melt kneading, extruding it onto a cooling roll, and stretching it uniaxially or biaxially as required. It is done.

  As a method of providing a diffusion layer on a transparent substrate, a method can be obtained by co-extrusion of a transparent resin and a resin to which a diffusing agent is added, or by coating a diffusing agent-containing coating on a transparent resin film or sheet. .

  Examples of the diffusing agent include inorganic fine particles such as silica, calcium carbonate, barium sulfate, titanium oxide, and aluminum oxide, and organic fine particles such as silicone beads, PMMA beads, MS beads, and styrene beads. Moreover, you may disperse | distribute during melt-kneading using a thermoplastic resin incompatible with a base material. The shape of the diffusing agent may be a spherical shape, a spherical shape, a scale shape, an indefinite shape, or the like, and is not particularly limited. The number average particle diameter of these diffusing agents is preferably 0.1 μm or more and 50 μm or less.

  Examples of the binder resin for the paint include polyester, urethane, acrylic, and the like, which are selected in consideration of the adhesiveness with the base material and the difference in refractive index between the base material and the diffusing agent.

  Examples of the method of providing irregularities on the surface of the transparent substrate include, for example, a method of embossing the substrate surface using a mold having a specific pattern, a method of sandblasting the substrate surface, and an ultraviolet curable resin such as acrylic applied to the transparent substrate. And a method of curing with ultraviolet rays while contacting the mold. For polyester resins, surface matting by alkali treatment is also a preferable method.

  In order to reduce the number of parts and thin the liquid crystal display device, it is also a preferred form to use a high retardation film as a transparent substrate of the transmission type diffusion sheet.

  The thickness of the transmission type diffusion sheet is preferably 300 μm or less, more preferably 200 μm or less, further preferably 150 μm or less, particularly preferably 100 μm or less, and most preferably 50 μm or less. The lower limit is preferably 5 μm or more from the viewpoint of handleability.

  If necessary, a plurality of transmission type diffusion sheets can be used.

  The total light transmittance of the transmission type diffusion sheet is preferably 60% or more, more preferably 70% or more, and particularly preferably 80% or more.

(Lens sheet)
Although light from the backlight is directed in various directions, it is also preferable to provide a lens sheet in order to concentrate this light toward the viewer side and increase the luminance of the display device. As the lens sheet, depending on the shape of the lens processed on the surface, a single-axis condensing type that concentrates in only one direction, such as a cylindrical lens, a prism lens, or a lenticular lens, a quadrangular pyramid type, or a deformed shape with a long top in one direction. Two-axis condensing type that concentrates in two orthogonal directions such as a pyramid type, three-axis condensing type such as a three-sided pyramid and six-sided pyramid, an eight-sided pyramid and more multi-axis type, and a small hemisphere and an elliptical hemisphere A microlens type, a Fresnel lens type, etc. are mentioned, and all are used. The lens sheet may be lens-processed on both sides as well as on one side, and the lens shape may be different on both sides. A uniaxial condensing type lens may be processed so that the condensing axes are orthogonal on both surfaces.
Among these, the biaxial type, the triaxial type, the multiaxial type, and the microlens type have a high light collection effect, and are particularly preferable lens shapes.

  The resin used as the base material of the lens sheet includes acrylic resins, polycarbonate resins, styrene resins, cyclic and chain olefin resins, polyester resins, polyamide resins, triacetyl cellulose and other transparent resins. Can be mentioned. Among these, polyesters such as PET and PEN are preferable examples, and these biaxially stretched films are most preferable as the base material.

  The lens sheet includes a method of embossing the surface of a transparent substrate using a mold with a specific pattern, a method of applying an ultraviolet curable resin such as acrylic on a transparent substrate, and a method of UV curing while contacting the mold with a specific pattern. Can be mentioned.

  In order to reduce the number of parts and thin the liquid crystal display device, it is also a preferred form to use a high retardation film as the base material of the lens sheet.

  If necessary, a plurality of lens sheets can be used.

(Method of using a high retardation film as a base material for a transmissive diffusion sheet or a lens sheet)
In order to reduce the number of parts and reduce the thickness of the image display device, it is preferable to use a high retardation film as the transparent base material of the transmission type diffusion sheet or lens sheet.
In this case, in the case of a transmissive diffusion sheet, a method of applying a diffusion layer on a high retardation film substrate is applied, and in the case of a lens sheet, an ultraviolet curable resin is applied and UV cured while contacting with a specific pattern mold. The method of making it, etc. are mentioned.
In this case, it is preferable to provide an easy adhesion layer on the high retardation film. As a resin used for the easy adhesion layer, for example, when the high retardation film is polyethylene terephthalate or polyethylene naphthalate, a polyester resin, a polyurethane resin, a polyester polyurethane resin, a polycarbonate polyurethane resin, an acrylic resin, and the like are preferable examples. Can be mentioned. Examples of the crosslinking agent for the easy adhesion layer include melamine, an isocyanate compound, an oxazoline resin, and an epoxy resin.
In addition, even when it is a case where a high retardation film is used for a light-guide plate and a reflecting plate, it is preferable to provide an easily bonding layer.

(Backlight side polarizing plate and viewing side polarizing plate)
A polarizing plate (backlight side polarizing plate, viewing side polarizing plate) is provided on each of the backlight side and the viewing side of the liquid crystal cell. Each polarizing plate has a structure in which both sides of a film-like polarizer are sandwiched between two protective films (sometimes referred to as “polarizer protective film”). As the polarizer, any polarizer (or polarizing film) used in the technical field can be appropriately selected and used. Representative polarizers include those obtained by dyeing a dichroic material such as iodine on a polyvinyl alcohol (PVA) film or the like, but are not limited to this, and are known and will be developed in the future. A polarizer to be obtained can be appropriately selected and used.

  Commercially available products can be used as the PVA film. For example, “Kuraray Vinylon (manufactured by Kuraray Co., Ltd.)”, “Toselo Vinylon (manufactured by Toh Cello Co., Ltd.)”, “Nichigo Vinylon (Nippon Synthetic Chemical Co., Ltd.) The dichroic material includes iodine, a diazo compound, a polymethine dye, and the like.

  The polarizer can be obtained by any method. For example, a PVA film dyed with a dichroic material is uniaxially stretched in an aqueous boric acid solution, and washed and dried while maintaining the stretched state. Can be obtained. The stretching ratio of uniaxial stretching is usually about 4 to 8 times, but is not particularly limited. Other manufacturing conditions and the like can be appropriately set according to known methods.

  The protective film on the viewing side of the polarizer of the viewing side polarizing plate and the protective film on the backlight side of the polarizer of the backlight side polarizing plate are a high retardation film or an arbitrary film conventionally used as a polarizer protective film. However, it is not limited to these.

  The type of the protective film on the backlight side of the polarizer of the viewing side polarizing plate and the type of the protective film on the viewing side of the polarizer of the backlight side polarizing plate are arbitrary, and a film conventionally used as a protective film is appropriately selected and used. can do. From the viewpoint of handling and availability, for example, a triacetyl cellulose (TAC) film, an acrylic film, a cyclic olefin-based film (for example, a norbornene-based film), a polypropylene film, a polyolefin-based film (for example, TPX), etc. It is preferable to use one or more films selected from the group consisting of:

  In one embodiment, the backlight side protective film for the polarizer of the viewing side polarizing plate and the viewer side protective film for the polarizer of the backlight side polarizing plate are preferably optical compensation films having an optical compensation function. Such an optical compensation film can be appropriately selected according to each type of liquid crystal. For example, a liquid crystal compound (for example, a discotic liquid crystal compound and / or a birefringent compound) is dispersed in triacetyl cellulose. 1 selected from the group consisting of resin, cyclic olefin resin (for example, norbornene resin), propionyl acetate resin, polycarbonate film resin, acrylic resin, styrene acrylonitrile copolymer resin, lactone ring-containing resin, and imide group-containing polyolefin resin. What can be obtained from more than a seed can be mentioned.

  Since the optical compensation film is commercially available, they can be appropriately selected and used. For example, “Wideview-EA” and “Wideview-T” (made by Fujifilm) for TN system, “Wideview-B” (made by Fujifilm) for VA system, VA-TAC (Konica Minolta, Inc.) ), “ZEONOR FILM” (manufactured by ZEON CORPORATION), “ARTON” (manufactured by JSR), “X-plate” (manufactured by Nitto Denko), and “Z-TAC” (manufactured by FUJIFILM Corporation) for the IPS system ), “CIG” (manufactured by Nitto Denko Corporation), “P-TAC” (manufactured by Okura Kogyo Co., Ltd.), and the like.

  The polarizer protective film can be laminated on the polarizer directly or via an adhesive layer. From the viewpoint of improving adhesiveness, it is preferable to laminate via an adhesive. The adhesive is not particularly limited and any adhesive can be used. From the viewpoint of thinning the adhesive layer, an aqueous one (that is, an adhesive component dissolved in water or dispersed in water) is preferable. For example, when using a polyester film as a polarizer protective film, a polyvinyl alcohol resin, a urethane resin, or the like is used as a main component, and an isocyanate compound, an epoxy compound, or the like is blended as necessary in order to improve adhesiveness. The composition can be used as an adhesive. The thickness of the adhesive layer is preferably 10 μm or less, more preferably 5 μm or less, and even more preferably 3 μm or less.

  When a TAC film is used as the polarizer protective film, it can be bonded using a polyvinyl alcohol-based adhesive. When using a film with low moisture permeability such as an acrylic film, a cyclic olefin film, a polypropylene film, or TPX as the polarizer protective film, it is preferable to use a photocurable adhesive as the adhesive. Examples of the photocurable resin include a mixture of a photocurable epoxy resin and a photocationic polymerization initiator.

  The thickness of the polarizer protective film is arbitrary, and can be appropriately set, for example, in the range of 15 to 300 μm, preferably in the range of 30 to 200 μm.

  The polarizer protective film can contain various additives. For example, ultraviolet absorbers, inorganic particles, heat-resistant polymer particles, alkali metal compounds, alkaline earth metal compounds, phosphorus compounds, antistatic agents, light proofing agents, flame retardants, thermal stabilizers, antioxidants, anti-gelling agents And surfactants. Moreover, in order to show high transparency, it is also preferable that a film does not contain particle | grains substantially. “Substantially free of particles” means, for example, in the case of inorganic particles, when the inorganic element is quantified by fluorescent X-ray analysis, the content is 50 ppm or less, preferably 10 ppm or less, particularly preferably the detection limit or less. Means quantity.

  The polarizer protective film may have various functional layers. Examples of such a functional layer include a hard coat layer, an antiglare layer, an antireflection layer, a low reflection layer, a low reflection antiglare layer, an antireflection antiglare layer, an antistatic layer, a silicone layer, an adhesive layer, and an antifouling layer. One or more selected from the group consisting of a layer, a water repellent layer, a blue cut layer and the like can be used.

  When providing various functional layers, it is preferable to have an easy-adhesion layer on the surface of the polarizer protective film. At that time, from the viewpoint of suppressing interference due to reflected light, it is preferable to adjust the refractive index of the easy-adhesion layer so that it is close to the geometric mean of the refractive index of the functional layer and the refractive index of the alignment film. The refractive index of the easy-adhesion layer can be adjusted by a known method. For example, the refractive index of the easy-adhesion layer can be easily adjusted by adding titanium, zirconium, or other metal species to the binder resin.

(Liquid crystal cell)
As the liquid crystal cell, any liquid crystal cell that can be used in a liquid crystal display device can be appropriately selected and used, and the method and structure thereof are not particularly limited. For example, a liquid crystal cell such as a VA mode, an IPS mode, a TN mode, an STN mode, or a bend alignment (π type) can be appropriately selected and used. Therefore, the liquid crystal cell can be used by appropriately selecting a known liquid crystal material and a liquid crystal made of a liquid crystal material that can be developed in the future. In one embodiment, a preferred liquid crystal cell is a transmissive liquid crystal cell.

(Touch panel)
The liquid crystal display device may include a touch panel. The type and method of the touch panel are not particularly limited, and examples include a resistive touch panel and a capacitive touch panel. The touch panel usually has one or more transparent conductive films regardless of the method. The transparent conductive film has a structure in which a transparent conductive layer is laminated on a base film. As the base film, a film conventionally used as the base film, a high retardation film, or a rigid plate such as a glass plate can be used.

  Examples of films conventionally used as the base film include various resin films having transparency. For example, polyester resin, acetate resin, polyether sulfone resin, polycarbonate resin, polyamide resin, polyimide resin, polyolefin resin, (meth) acrylic resin, polyvinyl chloride resin, polyvinylidene chloride resin, polystyrene resin, polyvinyl alcohol resin, polyarylate A film obtained from one or more kinds of resins selected from the group consisting of resins and polyphenylene sulfide resins can be used. Among these, polyester resins, polycarbonate resins, and polyolefin resins are preferable, and polyester resins are preferable.

  Although the thickness of a base film is arbitrary, the range of 15-500 micrometers is preferable.

  The base film may be subjected to etching treatment or undercoating treatment such as sputtering, corona discharge, flame, ultraviolet irradiation, electron beam irradiation, chemical conversion, oxidation, etc. on the surface in advance. Thereby, adhesiveness with the transparent conductive layer etc. which are provided on a base film can be improved. Moreover, before providing a transparent conductive layer etc., you may remove and clean the surface of a base film by solvent washing | cleaning, ultrasonic washing | cleaning, etc. as needed.

The transparent conductive layer may be directly laminated on the base film, but can be laminated via an easy adhesion layer and / or various other layers. Examples of the other layer include a hard coat layer, an index matching (IM) layer, and a low refractive index layer. As a typical laminated structure of the transparent conductive film, the following 6 patterns can be exemplified, but the invention is not limited thereto.
(1) Base film / easy adhesion layer / transparent conductive layer (2) Base film / easy adhesion layer / hard coat layer / transparent conductive layer (3) Base film / easy adhesion layer / IM (index matching) layer / Transparent conductive layer (4) Base film / Easily adhesive layer / Hard coat layer / IM (Index matching) layer / Transparent conductive layer (5) Base film / Easily adhesive layer / Hard coat layer (High refractive index doubles as IM ) / Transparent conductive layer (6) Base film / Easily adhesive layer / Hard coat layer (high refractive index) / Low refractive index layer / Transparent conductive thin film

  Since the IM layer itself has a laminated structure of a high refractive index layer / low refractive index layer (the transparent conductive thin film side is a low refractive index layer), the ITO layer is used when the liquid crystal display screen is viewed. Can be difficult to see. As described in (6) above, the high refractive index layer of the IM layer and the hard coat layer can be integrated, which is preferable from the viewpoint of thickness reduction.

  The configurations (3) to (6) are particularly suitable for use in a capacitive touch panel. Moreover, the structure of said (2)-(6) is preferable from a viewpoint that an oligomer can prevent depositing on the surface of a base film, and providing a hard-coat layer also on the other one side of a base film. preferable.

  The transparent conductive layer on the base film is formed of a conductive metal oxide. The conductive metal oxide constituting the transparent conductive layer is not particularly limited, and is selected from the group consisting of indium, tin, zinc, gallium, antimony, titanium, silicon, zirconium, magnesium, aluminum, gold, silver, copper, palladium, and tungsten. A conductive metal oxide of at least one selected metal is used. The metal oxide may further contain a metal atom shown in the above group, if necessary. Preferred transparent conductive layers are, for example, a tin-doped indium oxide (ITO) layer and an antimony-doped tin oxide (ATO) layer, preferably an ITO layer. The transparent conductive layer may be Ag nanowire, Ag ink, a self-organized conductive film of Ag ink, a mesh electrode, CNT ink, or a conductive polymer.

The thickness of the transparent conductive layer is not particularly limited, but is preferably 10 nm or more, more preferably 15 to 40 nm, and even more preferably 20 to 30 nm. When the thickness of the transparent conductive layer is 15 nm or more, a good continuous film having a surface resistance of 1 × 10 ³ Ω / □ or less is easily obtained. Moreover, it can be set as a layer with higher transparency as the thickness of a transparent conductive layer is 40 nm or less.

  The transparent conductive layer can be formed according to a known procedure. For example, a vacuum deposition method, a sputtering method, and an ion plating method can be exemplified. The transparent conductive layer may be amorphous or crystalline. As a method for forming a crystalline transparent conductive layer, it is preferable to form an amorphous film once on a substrate and then heat and crystallize the amorphous film together with a flexible transparent substrate.

  The transparent conductive film may be patterned by removing a part of the surface of the transparent conductive layer. The transparent conductive film in which the transparent conductive layer is patterned has a pattern forming part in which the transparent conductive layer is formed on the base film and a pattern opening having no transparent conductive layer on the base film. Have. Examples of the shape of the pattern forming portion include a stripe shape, a square shape, and the like.

  The base film can contain various additives as long as the effects of the present invention are not hindered. For example, ultraviolet absorbers, inorganic particles, heat-resistant polymer particles, alkali metal compounds, alkaline earth metal compounds, phosphorus compounds, antistatic agents, light proofing agents, flame retardants, thermal stabilizers, antioxidants, anti-gelling agents And surfactants. Moreover, in order to show high transparency, it is also preferable that a film does not contain particle | grains substantially. “Substantially free of particles” means, for example, in the case of inorganic particles, when the inorganic element is quantified by fluorescent X-ray analysis, the content is 50 ppm or less, preferably 10 ppm or less, particularly preferably the detection limit or less. Means quantity.

(Installation of high retardation film)
(angle)
The angle formed by the transmission axis of the polarizer of the backlight-side polarizing plate (vibration direction of the transmitted light) and the alignment main axis direction of the high retardation film is preferably 45 from the viewpoint that the luminance can be effectively improved. It is ± 30 degrees or less, more preferably 45 ± 25 degrees or less, further preferably 45 ± 20 degrees or less, particularly preferably 45 ± 15 degrees or less, and most preferably 45 ± 10 degrees or less. . Here, the word “below” is applied only to the numerical value immediately after ±. That is, 45 ± 30 degrees or less means that an angle deviation within a range of ± 30 degrees around 45 degrees is allowed.

  The transmission axis direction of the polarizer of the backlight side polarizing plate (vibration direction of transmitted light) and the transmission axis of the polarization reflector (vibration direction of transmitted light) are preferably 0 ± 20 degrees or less, more preferably 0. It is ± 15 degrees or less, and particularly preferably 0 ± 10 degrees or less. Here, the word “below” is applied only to the numerical value immediately after ±. In other words, 0 ± 20 degrees or less means that an angle deviation within a range of ± 20 degrees around 0 degrees is allowed.

(Installation position)
The high retardation film can be placed at any position as long as it is between the polarizing reflector and the reflective layer of the reflector in accordance with the configuration of the liquid crystal display device. For example, between a polarized light reflector and a lens sheet, between a polarized light reflector and a transmissive diffusion sheet, between a polarized light reflector and a light guide plate, between a polarized light reflector and a reflector, and between a lens sheet and a transmissive diffuser. Between the sheet, between the lens sheet and the light guide plate, between the lens sheet and the reflective plate, between the transmissive diffusion sheet and the light guide plate, between the transmissive diffusion sheet and the reflective plate, and between the light guide plate and the reflective plate. And the like. When a plurality of lens sheets or a plurality of transmission type diffusion sheets are used, they may be installed between the lens sheets or between the transmission type diffusion sheets.

  In the above, an example in which a high retardation film is installed alone has been shown, but in order to reduce the number of parts of a liquid crystal display device and reduce the thickness, as described above, a lens sheet or a transmission type diffusion sheet is used. It is a preferable form to use a high retardation film as the base material of the base material, the light guide plate, and the reflection plate.

  The high retardation film may be installed at a plurality of locations. When a high retardation film is used at a plurality of locations, it is a preferred form to align the orientation main axes of the high retardation film in the same direction. In this case, the orientation axis of the high retardation film is preferably aligned within 30 degrees, more preferably within 20 degrees, further preferably within 15 degrees, and particularly preferably within 10 degrees.

The film used for the base material of the lens sheet or the transmissive diffusion sheet, the light guide plate, and the base material of the reflection plate is preferably a high retardation film as described above, but at least one high retardation film is used. In this case, the other film may be a non-oriented film (zero retardation film) or a commercially available general-purpose film. At this time, from the viewpoint of suppressing color unevenness, it is preferable that the high retardation film is disposed on the viewing side more than other films.

Further, from the viewpoint of suppressing color unevenness, the relationship between the orientation principal axis of the high retardation film and the orientation principal axis of the other film is preferably about 0 degrees or about 90 degrees. The term “substantially 0 degree” means that the angle may be shifted within a range of preferably ± 20 degrees or less, more preferably ± 15 degrees or less, particularly preferably ± 10 degrees or less, centering on 0 degrees. Further, “approximately 90 degrees” means that the angle may be shifted within a range of preferably ± 20 degrees or less, more preferably ± 15 degrees or less, and particularly preferably ± 10 degrees or less, centering on 90 degrees.

  EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to the examples.

(Retardation)
Retardation (Re) was measured as follows. That is, using two polarizing plates, the orientation principal axis direction of the film was obtained, and a 4 cm × 2 cm rectangle was cut out so that the orientation principal axis directions were orthogonal to each other, and used as a measurement sample. For this sample, the biaxial refractive index (Nx, Ny) perpendicular to each other and the refractive index (Nz) in the thickness direction were determined by an Abbe refractometer (NAR-4T, manufactured by Atago Co., Ltd.). The absolute value of the difference (| Nx−Ny |) was determined as the anisotropy (ΔNxy) of the refractive index. The thickness d (nm) of the film was measured using an electric micrometer (manufactured by Fine Reef, Millitron 1245D), and the unit was converted to nm. Retardation (Re) was determined from the product (ΔNxy × d) of refractive index anisotropy (ΔNxy) and film thickness d (nm). Further, Nx, Ny, Nz and film thickness d (nm) are obtained by the same method as the measurement of retardation, and the average value of (ΔNxz × d) and (ΔNyz × d) is calculated to obtain a thickness direction retardation ( Rth) was determined.

(Manufacture of high retardation film)

Production Example-PET (A)
When the temperature of the esterification reactor was raised to 200 ° C., 86.4 parts by mass of terephthalic acid and 64.6 parts by mass of ethylene glycol were charged and 0.017 parts by mass of antimony trioxide as a catalyst while stirring. 0.064 parts by mass of magnesium acetate tetrahydrate and 0.16 parts by mass of triethylamine were charged. Subsequently, the pressure was raised and the esterification reaction was performed under the conditions of a gauge pressure of 0.34 MPa and 240 ° C., and then the esterification reaction vessel was returned to normal pressure, and 0.014 parts by mass of phosphoric acid was added. Furthermore, it heated up to 260 degreeC over 15 minutes, and 0.012 mass part of trimethyl phosphate was added. Then, after 15 minutes, dispersion treatment was performed with a high-pressure disperser, and after 15 minutes, the obtained esterification reaction product was transferred to a polycondensation reaction can and subjected to polycondensation reaction at 280 ° C. under reduced pressure.

  After completion of the polycondensation reaction, it is filtered through a NASRON filter with a 95% cut diameter of 5 μm, extruded into a strand from a nozzle, and cooled and solidified using cooling water that has been filtered (pore diameter: 1 μm or less) in advance. And cut into pellets. The obtained polyethylene terephthalate resin (A) had an intrinsic viscosity of 0.62 dl / g and contained substantially no inert particles and internally precipitated particles. (Hereafter, abbreviated as PET (A).)

(High retardation film 1)
The PET (A) resin pellets were dried under reduced pressure (1 Torr) at 135 ° C. for 6 hours, then supplied to an extruder and dissolved at 285 ° C. This polymer is filtered with a filter material of stainless sintered body (nominal filtration accuracy 10 μm particles 95% cut), extruded into a sheet form from the die, and then applied to a casting drum having a surface temperature of 30 ° C. using an electrostatic application casting method. It was wound and solidified by cooling to make an unstretched film.

  The unstretched film was guided to a tenter stretching machine and guided to a hot air zone at a temperature of 125 ° C. while being gripped by a clip, and stretched 4.0 times in the width direction. Next, while maintaining the width stretched in the width direction, the film was treated at a temperature of 225 ° C. for 30 seconds, and further subjected to a relaxation treatment of 3% in the width direction to obtain a uniaxially oriented high retardation film 1 having a film thickness of about 100 μm. Obtained.

(High retardation film 2)
The unstretched film is heated to 105 ° C. using a heated roll group and an infrared heater, and then stretched 3.6 times in the running direction by a roll group having a difference in peripheral speed. A biaxially oriented high retardation film 2 having a film thickness of about 100 μm was obtained in the same manner as the oriented film 1 except that the film was stretched 1.0 times in the width direction.

(High retardation film 3)
A uniaxially oriented high retardation film 3 was obtained in the same manner as the oriented film 1, except that the thickness of the unstretched film was changed to about 80 μm.

(High retardation film 4)
By changing the thickness of the unstretched film, a uniaxially oriented high retardation film 4 was obtained in the same manner as the oriented film 1 except that the thickness of the film was about 50 μm.

(High retardation film 5)
The unstretched film is heated to 105 ° C. using a heated roll group and an infrared heater, and then stretched 2.0 times in the running direction by a roll group having a difference in peripheral speed, and then in the same manner as the oriented film 1. A biaxially oriented high retardation film 5 having a film thickness of about 50 μm was obtained in the same manner as the oriented film 1 except that the film was stretched 4.0 times in the width direction.

(High retardation film 6)
To a mixture of dimethyl 2,6-naphthalenedicarboxylate and ethylene glycol, manganese acetate tetrahydrate salt, antimony trioxide and trimethyl phosphoric acid are added as catalysts, and the ester exchange reaction is carried out while gradually raising the temperature. Then, the polycondensation reaction is continued at 290 ° C. under reduced pressure. After the polycondensation reaction is completed using the stirring torque as a guide, the cooled and solidified material in a strand state is cut into pellets, Polyethylene naphthalate was obtained by drying under reduced pressure.
Using an extruder, an unstretched sheet obtained by melting polyethylene naphthalate at about 300 ° C., melt-extruding from a slit, and cooling and solidifying it on a chill roll having a surface temperature of about 60 ° C. by an electrostatic application method is used. A heat treatment at 180 ° C. was performed continuously with TD stretching with a tenter having a stretching temperature of 5 times and a stretching temperature of 140 ° C. to obtain a high retardation film 6 having a thickness of about 50 μm.

High retardation film 7
Polycarbonate (manufactured by Aldrich) was dissolved in methylene chloride 4 times by weight to prepare a polymer solution. The polymer solution was developed into a smooth glass plate with a knife coater and allowed to stand at room temperature to dry the solvent. Thereafter, the polycarbonate sheet was peeled off from the glass plate and dried in a vacuum dryer at 90 ° C. for 24 hours. A sample was cut out in a dumbbell shape from the obtained polycarbonate sheet. The cut sheet sample was heated to about 160 ° C. using Tensilon (manufactured by Orientec) and stretched in the uniaxial direction. The uniaxially oriented high retardation film 7 having a retardation of 9087 nm was obtained by adjusting the stretching ratio and the stretching speed at that time.

(High retardation film 8)
A film made of syndiotactic polystyrene was prepared in accordance with JP-A-8-323877, and this was designated as a high retardation film 8.

(Low retardation film 9)
Using “A4300 (50 μm)” manufactured by Toyobo, this was designated as a low retardation film 9.

(Confirmation of brightness improvement effect by backlight device)
Reflector (aluminum plate with surface sandblasting), backlight source (phosphor-type white LED with continuous emission spectrum, light irradiation toward reflector), polarizing reflector (converted from commercially available liquid crystal display, 3M DBEF) and a polarizing plate (both surfaces of the PVA polarizer protected with TAC) were sequentially laminated to obtain an evaluation apparatus. The transmission axis of the polarizing reflector and the transmission axis of the polarizing plate were installed in parallel. Between the polarizing reflector and the backlight light source, the orientation main axis of the high retardation film 1 and the transmission axis of the polarizing plate were inserted in increments of 15 degrees from 0 degrees to 90 degrees, and the luminance was observed visually. In addition, the brightness improvement effect was the highest at 45 degrees. The results are shown in Table 1.
The evaluation was as follows. Evaluation is a thing compared with the case where the high retardation film 1 is not inserted.
○: Brightness was clearly improved.
Δ: A slight improvement in luminance was observed.
X: Almost no improvement in luminance was observed.

(Brightness improvement effect by liquid crystal display and confirmation of color unevenness 1)
Reflector (aluminum-deposited PET film (aluminum layer on the viewer side)), backlight and light guide plate (diverted from a side-edge type commercially available liquid crystal display using a phosphor-type white LED having a continuous spectrum), transmissive diffusion sheet (PET film with acrylic bead coating layer, diverted from a commercially available liquid crystal display), lens sheet (with PET film having a hemispherical lens made of many UV curable resins, diverted from a commercially available liquid crystal display), A liquid crystal panel (having a backlight-side polarizing plate, a liquid crystal cell, and a viewing-side polarizing plate) laminated with a polarizing reflector (converted from a commercially available liquid crystal display, DBEF manufactured by 3M) and further converted from a commercially available liquid crystal display. The evaluation device was laminated with high retardation between the lens sheet and the polarizing reflector. The film 1 to 9 is inserted so that the orientation axis of the high retardation film is 45 degrees with the transmission axis of the backlight side polarizing plate, the image display device displays white, and the brightness is improved and the color unevenness is visually observed. The orientation main axis of the transmissive diffusion sheet and the lens film substrate PET film was also set to be 45 degrees with the transmission axis of the backlight side polarizing plate.
The evaluation was as follows. The evaluation of luminance is compared with the case where each high retardation film was not inserted.
A: Brightness is clearly improved, and no color unevenness is observed even when viewed from the front or oblique direction.
○: The brightness was clearly improved, but slight color unevenness was observed when viewed from an oblique direction.
Δ: Some improvement in luminance was observed. Or the brightness was clearly improved, but color unevenness was observed from the front.
X: Almost no improvement in luminance was observed.
The results are shown in Table 2.
The insertion position of the high retardation film 1 was changed between the transmission type diffusion sheet and the light guide plate, and between the light guide plate and the reflection plate.

(Brightness improvement effect by liquid crystal display and confirmation of color unevenness 2)
An easy-adhesion coat in which polyester polyurethane is isocyanate-crosslinked is provided on the surface of the high retardation film 1, and a lens layer having a hemispherical microlens structure is provided thereon with an ultraviolet curable resin to prepare a high retardation base lens sheet.
In the above image evaluation apparatus (brightness enhancement effect by liquid crystal display device, confirmation of color unevenness 1), the lens sheet is replaced with the high retardation substrate lens sheet, and the high retardation film between the lens sheet and the polarizing reflector is not inserted. Observed. The orientation axis of the high retardation film was set to 45 degrees with the transmission axis of the light source side polarizing plate. Similar brightness enhancement effects were obtained, and no color unevenness was observed.

(Brightness improvement effect by liquid crystal display and confirmation of color unevenness 3)
An easy-adhesion coat obtained by cross-linking polyester polyurethane with isocyanate was provided on the surface of the high retardation film 1, and a diffusion coating layer containing acrylic beads was provided thereon to prepare a high retardation substrate transmission type diffusion sheet.
In the above image evaluation apparatus (brightness improvement effect by liquid crystal display device, confirmation of color unevenness 1), the transmissive diffusion sheet is replaced with the high retardation substrate transmissive diffusion sheet, and the high retardation film between the lens sheet and the polarizing reflector is Observed without insertion. The orientation axis of the high retardation film was set to 45 degrees with the transmission axis of the light source side polarizing plate. Similar brightness enhancement effects were obtained, and no color unevenness was observed.

(Brightness improvement effect by liquid crystal display and confirmation of color unevenness 4)
Aluminum was vapor-deposited on the surface of the high retardation film 3 to prepare a high retardation substrate reflector.
In the above image evaluation apparatus (brightness improvement effect by liquid crystal display device, confirmation of color unevenness 1), the reflection plate is replaced with the high retardation substrate reflection plate, and the high retardation film between the lens sheet and the polarizing reflection plate is not inserted. Observed. In addition, the high retardation film was installed so that it might become a visual recognition side, and the orientation main axis | shaft of the high retardation film was 45 degree | times with the transmission axis of the light source side polarizing plate. Similar brightness enhancement effects were obtained, and no color unevenness was observed.

Claims (4)

In a liquid crystal display device having at least a reflecting plate, a backlight, a polarizing reflecting plate, a backlight side polarizing plate, a liquid crystal cell, and a viewing side polarizing plate, the retardation is 5177 to between the reflecting layer of the reflecting plate and the polarizing reflecting plate. A liquid crystal display device provided with a high retardation film having a value of 150,000 nm.   2. The liquid crystal display device according to claim 1, wherein an angle formed between a transmission axis of the polarizer of the backlight side polarizing plate and an orientation main axis direction of the high retardation film is 45 ± 30 degrees or less.   Either a transmissive diffusion sheet or a lens sheet using a high retardation film having a retardation of 3000 to 150,000 nm as a base film is provided between the backlight or the light guide plate and the polarizing reflector. The liquid crystal display device according to claim 1 or 2. The liquid crystal display device according to claim 1, wherein the reflecting plate is a metal plate or a metal thin film laminated plate.