JP6182002B2 - Manufacturing method of vacuum double container - Google Patents

Manufacturing method of vacuum double container Download PDF

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JP6182002B2
JP6182002B2 JP2013145116A JP2013145116A JP6182002B2 JP 6182002 B2 JP6182002 B2 JP 6182002B2 JP 2013145116 A JP2013145116 A JP 2013145116A JP 2013145116 A JP2013145116 A JP 2013145116A JP 6182002 B2 JP6182002 B2 JP 6182002B2
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container
inner container
temperature
vacuum double
sealing
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田中 達也
達也 田中
奥平 有三
有三 奥平
小林 徹
徹 小林
森 俊彦
俊彦 森
光司 内海
光司 内海
正史 武居
正史 武居
外村 卓也
卓也 外村
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Doshisha
Tiger Corp
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Tiger Corp
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Description

本発明は、真空二重容器の製造方法に関する。
The present invention relates to the production how the vacuum double container.

従来より、携帯用魔法瓶やスープマグ等と称される真空二重容器に暖かいスープやコーヒーを入れて職場、学校、行楽地等まで持って行き、昼食時等に飲食する人が多数存在する。
また、駅中や、駅周辺には、スープやコーヒーなどを客が持参した真空二重容器に入れて持ち帰ることができる店舗が増えてきており、通勤の途中、通学の途中、行楽地へ向かう途中等にこれらの店舗に立ち寄って購入したスープやコーヒーなどを持参した魔法瓶に入れて職場、学校、行楽地等に向かう人もいる。
Conventionally, there are many people who put warm soup or coffee in a vacuum double container called a portable thermos or soup mug and take it to the workplace, school, resort, etc. and eat and drink at lunch time.
In addition, there are an increasing number of stores in and around the station where you can take soups and coffee in vacuum double containers brought by customers and take them home. Some people stop by these stores and go to workplaces, schools, resorts, etc. in a thermos bottle with soup or coffee they bought.

昨今の携帯用魔法瓶等の真空二重容器においては、例えば、室温で、95±1℃の熱水を入れた場合の保温効力が6時間で80℃前後と、長時間高い温度に保たれるという高性能のものも市販されている。したがって、朝の通勤前や通勤途中に95℃前後に加温したスープやコーヒーなどを魔法瓶に入れて職場、学校、行楽地等に持って行けば、昼食時には80℃以上のスープやコーヒーを飲食することができる。   In recent vacuum double containers such as portable thermos bottles, for example, the temperature retention effect when hot water of 95 ± 1 ° C. is added at room temperature is maintained at a high temperature for a long time of around 80 ° C. in 6 hours. High performance products are also commercially available. Therefore, if you put soup or coffee heated to around 95 ° C in the thermos before commuting in the morning or during commuting, take it to the workplace, school, resort, etc., and eat and drink soup and coffee at 80 ° C or higher at lunch time. can do.

しかし、スープやコーヒーなどは、飲んだり食したりするのに適した最適飲食温度域があり、特に、コーヒーでは70℃前後が最適飲食温度であるといわれている。
そのため、上記のような店舗では、すぐに飲食する場合も考慮して、通常、95℃よりかなり低い最適飲食温度域の上限附近の温度にして飲食物を販売しているため、真空二重容器に入れた直後に真空二重容器の内容器に温度が奪われて温度が下がり、3,4時間後の例えば、昼食時に飲もうとした場合には、70℃の飲み頃よりも低い温度になってしまうおそれがある。一方、上記のように95℃程度の高温のコーヒーを入れたのでは、出勤直後に飲もうとした場合、熱すぎて飲めないという問題が発生する。
However, soup, coffee, and the like have an optimum eating and drinking temperature range suitable for drinking and eating, and in particular, about 70 ° C. is said to be the optimum eating and drinking temperature for coffee.
Therefore, considering the case of eating and drinking immediately in stores such as the above, food and drinks are usually sold at a temperature close to the upper limit of the optimum eating and drinking temperature range that is considerably lower than 95 ° C. Immediately after being put in, the temperature of the inner container of the vacuum double container is deprived and the temperature falls, and after 3 or 4 hours, for example, when trying to drink at lunch, the temperature is lower than when drinking at 70 ° C. There is a risk of becoming. On the other hand, if coffee with a high temperature of about 95 ° C. is added as described above, there is a problem that if it is attempted to drink immediately after going to work, it is too hot to drink.

そこで、内容器の底に電熱コイルを加熱手段として備え、蓄電池から電熱コイルに給電して電熱コイルを発熱させて内容器を加熱できるようにした携帯用魔法瓶(特許文献1)、ガラス製の内容器と外容器とからなり、両容器間を真空構造とするとともに、内容器の外壁面に電磁誘導発熱層を設け、IH調理器等の電磁誘導装置によって電磁誘導発熱層に渦電流を発生させて電磁誘導発熱層を発熱させて内容器を加熱できるようにした電磁調理器具(特許文献2)、弱磁性体で形成した外容器と、強磁性体で形成した内容器とからなり、IH調理器等によって内容器を構成する強磁性体に渦電流を発生させて発熱させて内容器を加熱するようにした真空二重容器(特許文献3)等が提案されている。
すなわち、上記のような構造の真空二重容器は、電熱コイルに通電して電熱コイルを発熱させる、あるいは、電磁誘導によって内容器自体を加熱することによって内容物を容器から取り出すことなく温め直すことができる。
Therefore, a portable thermos equipped with an electric heating coil as a heating means at the bottom of the inner container, and heated from the storage battery to heat the electric heating coil by heating the inner container (Patent Document 1), glass contents And a vacuum structure between the two containers, an electromagnetic induction heating layer is provided on the outer wall surface of the inner container, and an eddy current is generated in the electromagnetic induction heating layer by an electromagnetic induction device such as an IH cooker. It consists of an electromagnetic cooker (Patent Document 2) that heats the electromagnetic induction heat generating layer to heat the inner container, an outer container formed of a weak magnetic material, and an inner container formed of a ferromagnetic material. There has been proposed a vacuum double container (Patent Document 3) or the like in which an eddy current is generated in a ferromagnetic body constituting the inner container by a vessel or the like to generate heat and heat the inner container.
That is, in the vacuum double container having the above structure, the electric heating coil is energized to heat the electric heating coil, or the inner container itself is heated by electromagnetic induction without taking out the contents from the container. Can do.

実開平6−21549号公報Japanese Utility Model Publication No. 6-21549 実公平1−25506号公報Japanese Utility Model No. 1-25506 実開平6−52719号公報Japanese Utility Model Publication No. 6-52719

しかしながら、上記特許文献1〜3のような真空二重容器には、それぞれ以下のような問題がある。
すなわち、特許文献1の携帯用魔法瓶においては、蓄電池などを搭載した場合、魔法瓶自体が大型化するとともに、重量も重くなり、持ち運びに不便になるという問題があるとともに、電熱コイルに給電するケーブルを内容器側から外容器を貫通して外側に出さなければならず、内容器と外容器との間の真空度を確保するための工夫が必要で製造が難しいという問題がある。
一方、特許文献2の電磁調理器用調理器具は、内容器および外容器がガラスで形成されているため、携帯用魔法瓶のように持ち運ぶ場合、破損しやすい、また、電磁誘導層と内容器のガラスとの熱収縮差によって内容器が破損するおそれがある。
他方、特許文献3の真空二重容器は、内容器が強磁性体で形成され、外容器が弱磁性体で形成されているが、強磁性体と弱磁性体とを接合することは技術的に難しく、量産に適さないという問題がある。
However, the vacuum double containers as described in Patent Documents 1 to 3 have the following problems.
That is, in the portable thermos of Patent Document 1, when a storage battery or the like is mounted, the thermos itself becomes large and heavy, and there is a problem that it is inconvenient to carry. There is a problem that it is difficult to manufacture because it is necessary to penetrate the outer container from the inner container side and take it out to the outside, and to devise a device for ensuring a vacuum between the inner container and the outer container.
On the other hand, in the cooking device for an electromagnetic cooker of Patent Document 2, since the inner container and the outer container are formed of glass, they are easily damaged when carried like a portable thermos, and the electromagnetic induction layer and the glass of the inner container The inner container may be damaged due to the difference in thermal shrinkage.
On the other hand, in the vacuum double container of Patent Document 3, the inner container is made of a ferromagnetic material and the outer container is made of a weak magnetic material, but it is technical to join the ferromagnetic material and the weak magnetic material. However, it is difficult and is not suitable for mass production.

本発明は、上記事情に鑑みて、容器内に内容物を容れた状態で、内容物を容易に加熱できるとともに、製造が容易で強度的に優れた真空二重容器の製造方法を提供することを目的としている。
The present invention is, in view of the above circumstances, in a state in which was placed the contents in the container, together with the contents can be easily heated, a manufacturing how the vacuum double container production is easy strength superior The purpose is to do.

上記目的を達成するために、本発明にかかる真空二重容器の製造方法は、内容器となる内容器構成部材と、封止口を備える外容器構成部材とを容器入り口側部分で一体化した封止口を有する二重容器本体を、真空加熱炉中に入れ、ロウ材を溶融し、ロウ材で直接前記封止口を封止する、あるいは、封止板の周囲をロウ材で封止口の周囲を封止する封止工程を実施する前に、予め前記ロウ材の溶融温度以下の焼成温度を有する金属ペーストを前記内容器構成部材の外壁面に塗布しておき、前記真空加熱炉内を前記ロウ材溶融温度以上にして封止工程を実施すると同時に前記金属ペーストを焼成して電磁誘導発熱層を形成する真空二重容器の製造方法であって、前記内容器構成部材が、非磁性の金属材料からなり、前記外容器構成部材が、前記内容器構成部材の金属材料と易溶接性の非磁性の金属材料からなるとともに、前記金属ペーストが、粒径の大きい金属粒子を含む金属ペーストと、粒径の小さい金属粒子を含む金属ペーストとを混合して焼成温度をロウ材の溶融温度以下に調整した混合金属ペーストであることを特徴としている。
In order to achieve the above-mentioned object, the method for manufacturing a vacuum double container according to the present invention integrates an inner container constituent member serving as an inner container and an outer container constituent member having a sealing opening at a container inlet side portion. Put double container body with sealing port in vacuum heating furnace, melt brazing material and seal the sealing port directly with brazing material, or seal the periphery of sealing plate with brazing material Before carrying out the sealing step for sealing the periphery of the mouth, a metal paste having a firing temperature not higher than the melting temperature of the brazing material is applied in advance to the outer wall surface of the inner container constituent member, and the vacuum heating furnace A manufacturing method of a vacuum double container in which the inside of the brazing material is heated to the melting temperature or higher and the metal paste is fired to form an electromagnetic induction heat generating layer at the same time. The outer container component is made of a magnetic metal material and the inner container The metal paste is made of a non-magnetic metal material that is easily weldable and a metal component, and the metal paste is a mixture of a metal paste containing metal particles having a large particle size and a metal paste containing metal particles having a small particle size. The mixed metal paste is characterized in that the firing temperature is adjusted to be equal to or lower than the melting temperature of the brazing material .

本発明において、非磁性の金属材料としては、非磁性であり、内容器を構成する金属材料と、外容器を構成する金属材料とが易溶接性であれば、特に限定されないが、内容器と外容器とを同種の金属材料で形成することが好ましく、例えば、非磁性のオーステナイト系ステンレス鋼を用いることができる。
上記オーステナイト系ステンレス鋼としては、SUS301、SUS302、SUS303、SUS304、SUS305、SUS316等が挙げられ、中でもSUS304が好ましい。
なお、本発明において、易溶接性とは、ほぼ同種の金属材料同士を溶接する一般的な溶接手法で溶接することができることを意味する。
In the present invention, the nonmagnetic metal material is not particularly limited as long as it is nonmagnetic and the metal material constituting the inner container and the metal material constituting the outer container are easily weldable. The outer container is preferably formed of the same kind of metal material, and for example, nonmagnetic austenitic stainless steel can be used.
Examples of the austenitic stainless steel include SUS301, SUS302, SUS303, SUS304, SUS305, SUS316, etc. Among them, SUS304 is preferable.
In addition, in this invention, easy weldability means that it can weld by the general welding method which welds substantially the same kind of metal materials.

また、電磁誘導発熱層は、特に限定されないが、例えば、電磁誘導により渦電流が発生する金属粒子からなる金属ペーストを内容器となる内容器形成体の外壁面に塗布し焼成して得る方法、電磁誘導によって渦電流が発生し発熱可能な金属材料を溶射する方法、電磁誘導によって渦電流が発生し発熱可能な金属材料からなる筒状体を内容器となる内容器形成体の底に嵌合一体化する方法等によって得ることができる。   The electromagnetic induction heating layer is not particularly limited.For example, a method of applying and baking a metal paste made of metal particles that generate eddy currents by electromagnetic induction on the outer wall surface of the inner container forming body serving as the inner container, A method of spraying a metal material that can generate heat by generating eddy current by electromagnetic induction. It can be obtained by a method of integration.

上記のように、電磁誘導発熱層として金属ペーストの焼成体を用いる場合、金属ペーストは、まず、内容器となる内容器構成部材の外壁面の所望位置に塗布されるが、塗布方法としては、特に限定されないが、例えば、ディッピング、インクジェット印刷、スクリーン印刷、ロールコート、スプレーコート、スピンコート、アプリケーター法、バーコータ法、凸版印刷、凹版印刷、刷毛塗布等が挙げられる。または、離型性を有するポリエチレンテレフタレート(PET)などの基材に金属ペーストを前記塗布方法により塗布したのち、内容器構成部材の外壁面に貼り合せ転写することで形成しても良い。
上記電磁誘導発熱層は、少なくとも電磁誘導加熱装置で誘導加熱できれば、内容器の外壁面の全周面に設けられていても、内容器の底面部等の一部に設けられていて構わない。
As described above, when a fired body of metal paste is used as the electromagnetic induction heat generating layer, the metal paste is first applied to a desired position on the outer wall surface of the inner container constituting member serving as the inner container. Although not particularly limited, for example, dipping, ink jet printing, screen printing, roll coating, spray coating, spin coating, applicator method, bar coater method, letterpress printing, intaglio printing, brush application and the like can be mentioned. Alternatively, it may be formed by applying a metal paste to a base material such as polyethylene terephthalate (PET) having releasability by the application method and then transferring the paste onto the outer wall surface of the inner container constituting member.
The electromagnetic induction heat generating layer may be provided on the entire peripheral surface of the outer wall surface of the inner container or a part of the bottom surface of the inner container as long as induction heating can be performed by at least an electromagnetic induction heating device.

なお、電磁誘導発熱層と外容器との隙間は、真空二重容器の断熱効果を阻害しない限り、電磁誘導加熱装置と電磁誘導発熱層との距離を近づけるために、できるだけ小さくすることが好ましい。
また、電磁誘導発熱層は、IH調理器等の電磁誘導加熱装置からの磁力線によって渦電流が効率よく発生するように、電磁誘導加熱装置に対面する面は、平坦で平滑になっていることが好ましい。
Note that the gap between the electromagnetic induction heating layer and the outer container is preferably as small as possible in order to reduce the distance between the electromagnetic induction heating device and the electromagnetic induction heating layer as long as the heat insulating effect of the vacuum double container is not hindered.
The surface facing the electromagnetic induction heating device may be flat and smooth so that the eddy current is efficiently generated by the magnetic lines of force from the electromagnetic induction heating device such as an IH cooker. preferable.

本発明において、粒径の小さい金属粒子としては、粒径が100nm以下のものが好ましい。
In the present invention, the metal particles having a small particle diameter are preferably those having a particle diameter of 100 nm or less.

なお、上記金属ペーストを構成する金属粒子としては、金粒子、銀粒子、パラジウム粒子、銅粒子、ニッケル粒子等やこれらの混合粒子が挙げられ、銀粒子が好適である。
銀粒子を含む銀ペーストとしては、市販のものを用いることができ、たとえば、100nm以下のナノオーダーの銀粒子を含む銀ペーストとしては、特開2012-52225号公報(出願人バンドー化学株式会社)に記載の方法で得られるものが使用でき、市販のものとしては、バンドー化学株式会社製の、SW1000、SW2000、SW3000、SW4000、SR4000、SR5000が使用できる。
Examples of the metal particles constituting the metal paste include gold particles, silver particles, palladium particles, copper particles, nickel particles, and mixed particles thereof, and silver particles are preferable.
As a silver paste containing silver particles, commercially available ones can be used. For example, as a silver paste containing nano-order silver particles of 100 nm or less, JP 2012-52225 A (Applicant Bando Chemical Co., Ltd.) Those obtained by the method described in 1) can be used, and commercially available SW1000, SW2000, SW3000, SW4000, SR4000, SR5000 manufactured by Bando Chemical Co., Ltd. can be used.

電磁誘導加熱装置としては、市販のIH調理器や、本発明の真空二重容器の電磁誘導加熱層を最も効率よく誘導加熱することができるように最適な構造とした電磁誘導加熱装置を製作するようにしても構わない。
ロウ材としては、特に限定されず、例えば、封止口を封止板とロウ材とを用いて封止する場合、銀ロウが挙げられ、固形ロウ材を直接封止材として用いる場合には、軟化点が200〜600℃の低温溶融ガラスが挙げられる。
低温溶融ガラスとしては、B23-PbO系、B23-ZnO系、PbO-B23-ZnO-SiO2系、PbO-B23-Al23-SiO2系、PbO-B23-SiO2系、PbO-B23-BaO-SiO2系のものなどが挙げられる。
As an electromagnetic induction heating device, a commercially available IH cooker or an electromagnetic induction heating device having an optimum structure so that the electromagnetic induction heating layer of the vacuum double container of the present invention can be induction heated most efficiently is manufactured. It doesn't matter if you do.
The brazing material is not particularly limited. For example, when the sealing port is sealed using a sealing plate and a brazing material, silver brazing is used, and when the solid brazing material is used directly as the sealing material. And low-temperature molten glass having a softening point of 200 to 600 ° C.
Examples of the low temperature molten glass include B 2 O 3 —PbO, B 2 O 3 —ZnO, PbO—B 2 O 3 —ZnO—SiO 2 , and PbO—B 2 O 3 —Al 2 O 3 —SiO 2. PbO—B 2 O 3 —SiO 2 type, PbO—B 2 O 3 —BaO—SiO 2 type, and the like.

状飲食物は、本発明の真空二重容器の内容器の外壁面に設けられた電磁誘導発熱層を電磁誘導加熱装置によって発熱させて内容器を真空二重容器に入れられる液状飲食物の最適飲食温度域の下限温度以上の設定加熱温度に予め加熱した状態で前記最適飲食温度域にある前記液状飲食物を真空二重容器内に注ぎ込んだのち、前記発熱体を非発熱状態にして前記液状飲食物を真空二重容器内で保温することができる
Liquid-like food, the electromagnetic induction heating layer by heating by the electromagnetic induction heating unit internal container liquid food product to be placed in a vacuum double container provided on the outer wall surface of the inner container of the vacuum double container of the present invention After pouring the liquid food or drink in the optimum food temperature range into a vacuum double container in a state heated in advance to a set heating temperature equal to or higher than the lower limit temperature of the optimum food temperature range, the heating element is set to a non-heated state. Liquid food and drink can be kept warm in a vacuum double container.

また、上記設定加熱温度は、真空二重容器に入れられる液状飲食物の最適飲食温度によって適宜決定される。なお、設定加熱温度の上限は特に限定されないが、あまり高すぎると飲食物を入れる際に危険が伴う。   Moreover, the said setting heating temperature is suitably determined by the optimal food-drinking temperature of the liquid foodstuffs put into a vacuum double container. The upper limit of the set heating temperature is not particularly limited, but if it is too high, there is a danger in putting food and drink.

また、液状飲食物としては、特に限定されないが、例えば、スープ、コーヒー、おかゆなどが挙げられる。   Moreover, it is although it does not specifically limit as liquid food / beverage, For example, soup, coffee, porridge, etc. are mentioned.

本発明の真空二重容器の製造方法は、内容器となる内容器構成部材と、封止口を備える外容器構成部材とを容器入り口側部分で一体化した封止口を有する二重容器本体を、真空加熱炉中に入れ、ロウ材を溶融し、ロウ材で直接前記封止口を封止する、あるいは、封止板の周囲をロウ材で封止口の周囲を封止する封止工程を実施する前に、予め前記ロウ材の溶融温度以下の焼成温度を有する金属ペーストを前記内容器構成部材の外壁面に塗布しておき、前記真空加熱炉内を前記ロウ材溶融温度以上にして封止工程を実施すると同時に前記金属ペーストを焼成して電磁誘導発熱層を形成する真空二重容器の製造方法であって、前記内容器構成部材が、非磁性の金属材料からなり、前記外容器構成部材が、前記内容器構成部材の金属材料と易溶接性の非磁性の金属材料からなるとともに、前記金属ペーストが、粒径の大きい金属粒子を含む金属ペーストと、粒径の小さい金属粒子を含む金属ペーストとを混合して焼成温度をロウ材の溶融温度以下に調整した混合金属ペーストであるので、高価な小さな粒子を含む金属ペーストの使用量を低減できるとともに、混合量によって電磁誘導発熱体層の電気抵抗等もコントロールできる。
The manufacturing method of the vacuum double container of the present invention includes a double container main body having a sealing port in which an inner container constituent member serving as an inner container and an outer container constituent member having a sealing opening are integrated at a container inlet side portion. In a vacuum heating furnace, melt the brazing material, and seal the sealing port directly with the brazing material, or seal the periphery of the sealing port with the brazing material Before carrying out the process, a metal paste having a firing temperature equal to or lower than the melting temperature of the brazing material is applied to the outer wall surface of the inner container component in advance, and the inside of the vacuum heating furnace is set to the melting temperature of the brazing material or higher. A method for manufacturing a vacuum double container in which the metal paste is fired to form an electromagnetic induction heat generating layer at the same time as the sealing step is performed, wherein the inner container component is made of a non-magnetic metal material, The container constituent member is easily weldable with the metal material of the inner container constituent member. The metal paste is made of a non-magnetic metal material, and the metal paste is mixed with a metal paste containing metal particles having a large particle size and a metal paste containing metal particles having a small particle size, and the firing temperature is equal to or lower than the melting temperature of the brazing material. Therefore, the amount of the metal paste containing expensive small particles can be reduced, and the electric resistance of the electromagnetic induction heating element layer can be controlled by the amount of mixing.

本発明の真空二重容器の1つの実施の形態を模式的にあらわす断面図である。It is sectional drawing which typically represents one embodiment of the vacuum double container of this invention. 図1の真空二重容器の製造方法を説明する図であって、その内容器への銀ペースト塗布工程を模式的にあらわす断面図である。It is a figure explaining the manufacturing method of the vacuum double container of FIG. 1, Comprising: It is sectional drawing which represents typically the silver paste application | coating process to the inner container. 図2の工程の後工程を模式的にあらわす断面図である。FIG. 3 is a cross-sectional view schematically showing a subsequent process of the process in FIG. 2. 図3の工程の後工程を模式的にあらわす断面図である。FIG. 4 is a cross-sectional view schematically showing a subsequent process of the process in FIG. 3. 図4の工程の後工程を模式的にあらわす断面図である。FIG. 5 is a cross-sectional view schematically showing a subsequent process of the process in FIG. 4. 図1の真空二重容器を用いた本発明の保温方法の1つの実施の形態を説明する図である。It is a figure explaining one embodiment of the heat retention method of this invention using the vacuum double container of FIG.

以下に、本発明を、その実施の形態をあらわす図面を参照しつつ詳しく説明する。
図1は、本発明の保温方法に用いられる真空二重容器の1つの実施の形態をあらわしている。
Hereinafter, the present invention will be described in detail with reference to the drawings showing embodiments thereof.
FIG. 1 shows one embodiment of a vacuum double container used in the heat insulation method of the present invention.

図1に示すように、この真空二重容器1は、内容器2と、外容器3とを備え、内容器2の外側底面部および側面部の下方に電磁誘導発熱体層4が設けられ、外容器3と内容器2との間が真空になっている。
内容器2および外容器3は、例えば、非磁性ステンレス鋼であるSUS304で形成されている。
電磁誘導発熱体層4は、後述するように、混合銀ペースト40を焼成して形成されている。
なお、混合銀ペースト40の塗布面積および塗布厚みは、家庭用IH調理器で電磁誘導発熱体層4を誘導加熱したときに、内容器2の温度が真空二重容器1に注がれる液状飲食物の最適飲食温度の上限温度までしか上がらないように設定することが望ましく、塗布厚みとしては0.1〜100μmが好ましく、より好ましくは0.5〜50μmである。0.1μm未満では十分な発熱効果が得られず、100μmを超えるとコスト高となり好ましくない。
As shown in FIG. 1, this vacuum double container 1 includes an inner container 2 and an outer container 3, and an electromagnetic induction heating element layer 4 is provided below the outer bottom surface and side surfaces of the inner container 2, A vacuum is formed between the outer container 3 and the inner container 2.
The inner container 2 and the outer container 3 are made of, for example, SUS304 that is nonmagnetic stainless steel.
The electromagnetic induction heating element layer 4 is formed by firing a mixed silver paste 40 as will be described later.
In addition, the application area and application thickness of the mixed silver paste 40 are liquid food and drink in which the temperature of the inner container 2 is poured into the vacuum double container 1 when the electromagnetic induction heating element layer 4 is induction-heated with a household IH cooker. It is desirable to set so that it only rises to the upper limit temperature of the optimum food and drink temperature of the thing, and as application | coating thickness, 0.1-100 micrometers is preferable, More preferably, it is 0.5-50 micrometers. If it is less than 0.1 μm, a sufficient heat generation effect cannot be obtained, and if it exceeds 100 μm, the cost increases, which is not preferable.

次に、この真空二重容器1の製造方法を図2〜図5を用いて工程順に説明する。
(1)図2に示すように、ミクロンオーダーの大きな銀粒子が分散された焼成温度が900℃前後の大径銀ペーストと、100nm以下の小さな銀粒子が分散された焼成温度が200℃前後の小径銀ペーストとを混合し、後述する封止板32の真空ロウ付け温度(例えば,500℃)以下の焼成温度に調整された混合銀ペースト40を、非磁性ステンレス鋼板をプレス成形して得られた内容器2となる底が平坦な内容器構成部材としての有底筒状部材21の底全面および底近傍の外側面に塗布する。
なお、混合銀ペースト40の塗布面積および塗布厚みは、家庭用IH調理器で電磁誘導発熱体層4を誘導加熱したときに、内容器2の十分な温度まで加熱できれば特に限定されないが、同一の液状飲食物のみに繰り返し用いられる場合には、内容器2の温度が真空二重容器1に注がれる液状飲食物の最適飲食温度の上限温度までしか上がらないような塗布面積および塗布厚みに設定することもできる。
(2)図3に示すように、底に封止口となる孔31aが穿設された非磁性ステンレス鋼板をプレス成形して得られた外容器構成体としての孔明き筒状部材31を有底筒状部材21に外嵌し、有底筒状部材21と孔明き筒状部材31の容器の入口側端縁同士を溶接一体化して二重容器本体11を得る。
(3)図4に示すように、封止板32を、ロウ材33を介して孔31aを塞ぐように二重容器本体11の底上に載置されたようにセットする。
(4)上記のように、封止板32がセットされた二重容器本体11を、図5に示すように、真空加熱炉5中にセットし、通常の携帯用魔法瓶の製造方法と同様に、孔31aから二重容器本体11の中空部11aの空気を排気して真空にしながらロウ材33を溶融して封止板32を二重容器本体11にロウ付けして、二重容器本体11の孔31aが封止板32で封止された図1に示す真空二重容器1を得る。
すなわち、混合銀ペースト40がロウ付け温度より低い焼成温度であるので、上記ロウ付けと同時に混合銀ペースト40が焼成されて銀の焼結体からなる電磁誘導発熱体層4が形成される。
Next, the manufacturing method of this vacuum double container 1 is demonstrated in order of a process using FIGS.
(1) As shown in FIG. 2, a large-diameter silver paste having a baking temperature around 900 ° C. in which large silver particles of micron order are dispersed and a baking temperature in which small silver particles of 100 nm or less are dispersed are around 200 ° C. It is obtained by mixing a small-diameter silver paste and press-molding a non-magnetic stainless steel plate with a mixed silver paste 40 adjusted to a firing temperature not higher than the vacuum brazing temperature (for example, 500 ° C.) of the sealing plate 32 described later. Further, it is applied to the entire bottom surface of the bottomed cylindrical member 21 as the inner container constituting member having a flat bottom which becomes the inner container 2 and the outer surface near the bottom.
The application area and application thickness of the mixed silver paste 40 are not particularly limited as long as the electromagnetic induction heating element layer 4 can be heated to a sufficient temperature of the inner container 2 when the electromagnetic induction heating element layer 4 is induction-heated with a household IH cooker. When it is used repeatedly only for liquid foods and drinks, the coating area and the coating thickness are set such that the temperature of the inner container 2 rises only to the upper limit temperature of the optimum food and drink temperature for the liquid foods and drinks poured into the vacuum double container 1 You can also
(2) As shown in FIG. 3, there is a perforated cylindrical member 31 as an outer container structure obtained by press-molding a non-magnetic stainless steel plate having a hole 31a serving as a sealing port at the bottom. The double-cylinder main body 11 is obtained by externally fitting to the bottom cylindrical member 21 and welding and integrating the bottom-side cylindrical member 21 and the perforated cylindrical member 31 at the inlet side edges of the container.
(3) As shown in FIG. 4, the sealing plate 32 is set so as to be placed on the bottom of the double container body 11 so as to close the hole 31 a via the brazing material 33.
(4) As described above, the double container body 11 on which the sealing plate 32 is set is set in a vacuum heating furnace 5 as shown in FIG. The brazing material 33 is melted while exhausting the air in the hollow portion 11a of the double container body 11 from the hole 31a and evacuating it, and the sealing plate 32 is brazed to the double container body 11 so that the double container body 11 The vacuum double container 1 shown in FIG. 1 in which the holes 31a are sealed with the sealing plate 32 is obtained.
That is, since the mixed silver paste 40 has a firing temperature lower than the brazing temperature, the mixed silver paste 40 is fired simultaneously with the brazing to form the electromagnetic induction heating element layer 4 made of a silver sintered body.

この真空二重容器1は、上記のように、内容器2および外容器3が同じ種類の非磁性ステンレス鋼板で形成されているので、溶接部の溶接を容易に行える。
また、内容器2および外容器3がステンレス鋼であるので、耐衝撃性にも優れている。勿論、内容器2の外壁面に電磁誘導発熱層4が設けられているので、IH調理器等の電磁誘導加熱装置を用いて内容器2を加熱することができる。
したがって、真空二重容器1内の飲食物を他の容器に移し替えることなく、IH調理器等の電磁誘導加熱装置を用いて温め直すことができるとともに、以下に説明するような液状飲食物の保温方法に好適に用いることができる。
In the vacuum double container 1, as described above, the inner container 2 and the outer container 3 are formed of the same kind of non-magnetic stainless steel plate, so that the welded portion can be easily welded.
Moreover, since the inner container 2 and the outer container 3 are stainless steel, they are excellent in impact resistance. Of course, since the electromagnetic induction heat generating layer 4 is provided on the outer wall surface of the inner container 2, the inner container 2 can be heated using an electromagnetic induction heating device such as an IH cooker.
Therefore, the food and drink in the vacuum double container 1 can be reheated by using an electromagnetic induction heating device such as an IH cooker without transferring the food and drink to another container, and the liquid food and drink as described below can be used. It can be suitably used for a heat retention method.

すなわち、この保温方法は、まず、図6に示すように、空の真空二重容器1を、底が家庭のIH調理器6に受けられるように載置し、IH調理器6をオンにして電磁誘導発熱体層4を発熱させて内容器2をコーヒーやスープなどの最適飲食温度の上限温度まで加熱する。なお、内容器2の温度がコーヒーやスープなどの最適飲食温度の上限温度になったか否かの判定は、例えば、使用する真空二重容器1とIH調理器6と組み合わせで、経験的に求めた時間に設定する方法や、赤外線温度計を用いて内容器内部の温度を測定して行う方法で行うことができる。
つぎに、加熱が完了したら、誘導加熱をやめ、調理したあるいは抽出した最適飲食温度になった液状飲食物を内容器2が加熱された真空二重容器1に注ぎ入れたのち、図示していない従来の携帯用魔法瓶の注ぎ口付きの内蓋をしたのち、外蓋をして液状飲食物を保温状態にする。
そして、所望のときに、真空二重容器1内の液状飲食物を外蓋に注ぎ込む、あるいは、カップ等の別の容器に入れて飲食する。
That is, in this warming method, first, as shown in FIG. 6, the empty vacuum double container 1 is placed so that the bottom can be received by the home IH cooker 6, and the IH cooker 6 is turned on. The electromagnetic induction heating element layer 4 is heated to heat the inner container 2 to the upper limit temperature of the optimum eating and drinking temperature such as coffee or soup. The determination as to whether or not the temperature of the inner container 2 has reached the upper limit temperature of the optimum eating and drinking temperature such as coffee and soup is empirically based on the combination of the vacuum double container 1 to be used and the IH cooker 6, for example. It can be performed by a method of setting the obtained time or a method of measuring the temperature inside the inner container using an infrared thermometer.
Next, when the heating is completed, the induction heating is stopped and the cooked or extracted liquid food or drink at the optimum food temperature is poured into the vacuum double container 1 where the inner container 2 is heated, and is not shown in the figure. After the inner lid with a spout of a conventional portable thermos, the outer lid is put on and the liquid food is kept warm.
Then, when desired, the liquid food or drink in the vacuum double container 1 is poured into the outer lid, or is put in another container such as a cup to eat or drink.

この保温方法によれば、液状飲食物を真空二重容器1内に注ぎ込む際に、内容器2が予め液状飲食物の最適飲食温度の上限温度まで加熱されているので、最適飲食温度になった液状飲食物は、真空二重容器1に熱を奪われることがなく、最適飲食温度が保たれる。
そして、この状態で保温されるので、内容器が加熱されていない従来の真空二重容器に液状飲食物を入れた場合に比べ、長時間最適飲食温度に保持される。
According to this heat retention method, when the liquid food or drink is poured into the vacuum double container 1, the inner container 2 is heated up to the upper limit temperature of the optimum food and drink temperature of the liquid food and drink, so that the optimum food and drink temperature is reached. The liquid food is not deprived of heat by the vacuum double container 1, and the optimum food temperature is maintained.
And since it heat-retains in this state, compared with the case where liquid food / drink is put into the conventional vacuum double container with which the inner container is not heated, it is hold | maintained at the optimal food-drinking temperature for a long time.

しかも、注ぎ込む液状飲食物も最適飲食温度であるので、真空二重容器1に入れた直後に飲食する場合も最もおいしい状態で飲食できる。
また、混合銀ペースト40の焼成温度がロウ付け温度より低く、ロウ付けと同時に焼成できるので、焼成工程を別途設ける場合に比べ、製造工程が簡略化できる。
さらに、大きな銀粒子を含む銀ペーストと、小さな銀粒子を含む銀ペーストを混合して用いるようにしたので、高価な小さな銀粒子を含む銀ペーストの使用量を低減できるとともに、混合量によって電磁誘導発熱体層の電気抵抗等もコントロールできる。
Moreover, since the liquid food to be poured is also at the optimum food and drink temperature, it can be eaten and consumed in the most delicious state even when eating and drinking immediately after being put in the vacuum double container 1.
Moreover, since the firing temperature of the mixed silver paste 40 is lower than the brazing temperature and can be fired at the same time as the brazing, the manufacturing process can be simplified compared to the case where a firing process is separately provided.
Furthermore, since the silver paste containing large silver particles and the silver paste containing small silver particles are mixed and used, it is possible to reduce the amount of silver paste containing expensive small silver particles and to reduce electromagnetic induction depending on the mixing amount. The electrical resistance of the heating element layer can also be controlled.

なお、上記保温方法は、図示していないが、店舗に多数の真空二重容器1を並列してセットでき、各真空二重容器1の電磁誘導発熱体層4を同時に誘導加熱できる電磁誘導加熱装置を設置し、多数の真空二重容器1の内容器2を予め加熱しておき、テイクアウトの客が来店した場合、客のオーダーに応じた最適飲食温度に加熱された液状飲食物を加熱された真空二重容器1に入れて販売する温かいコーヒーやスープ等をテイクアウトできる店舗等の新しい販売システムとしても応用できる。
すなわち、客は、上記のようにして保温状態にされた真空二重容器1を受け取り、職場にもっていく、あるいは家に持ち帰るなどして、所望のときに上記と同様にして飲食できる。
In addition, although the said heat retention method is not shown in figure, the electromagnetic induction heating which can set many vacuum double containers 1 in parallel in a store, and can induction-heat the electromagnetic induction heating body layer 4 of each vacuum double container 1 simultaneously. When the apparatus is installed and the inner container 2 of a large number of vacuum double containers 1 is heated in advance and a takeout customer comes to the store, the liquid food heated to the optimum food and drink temperature according to the customer's order is heated. It can also be applied as a new sales system such as a store that can take out hot coffee or soup that is sold in a vacuum double container 1.
That is, the customer can receive the vacuum double container 1 kept in the above-described heat state and take it to the workplace or take it home to eat and drink in the same manner as described above.

なお、上記販売システムにおいては、液状飲食物の販売に際し、液状飲食物の代金とともに、真空二重容器1、内蓋および外蓋の保証金を客から貰い、客が返却すれば保証金を返却する、あるいは、再度購入する場合、前の真空二重容器1、内蓋および外蓋を返却すれば、液状飲食物を予め上記のようにして内容器2を加熱した別の真空二重容器1に入れて客が液状飲食物の代金のみを支払うようにすることが考えられる。   In the above sales system, when selling liquid food and drink, along with the price of liquid food and drink, the deposit of the vacuum double container 1, inner lid and outer lid is received from the customer, and if the customer returns, the deposit is returned. Alternatively, when purchasing again, if the previous vacuum double container 1, the inner lid and the outer lid are returned, the liquid food and drink is put in another vacuum double container 1 in which the inner container 2 is heated in advance as described above. It may be possible for customers to pay only for liquid food and drink.

本発明は、上記の実施の形態に限定されない。たとえば、上記の実施の形態では、混合銀ペースト40の塗布面積および塗布厚みを制御することによって家庭用のIH調理器6を用いて加熱したとき、電磁誘導発熱体層4が液状飲食物の最適飲食温度の上限温度までしか上がらないようになっていたが、電磁誘導加熱装置に温度センサやタイマーを設けるなどして、電磁誘導加熱装置で加熱設定温度を制御できるようにしても構わない。
上記の実施の形態では、真空二重容器から蓋を取り除き、真空二重容器内の液状飲食物をカップに移して飲食するようにしていたが、例えば、蓋につけたノズル上の飲み口から直飲みできるようにしても構わないし、容器から蓋を取り外し、容器から直飲みできるようにしても構わない。
The present invention is not limited to the above embodiment. For example, in the above embodiment, the electromagnetic induction heating element layer 4 is optimal for liquid food and drink when heated using a home IH cooker 6 by controlling the application area and application thickness of the mixed silver paste 40. Although the temperature only reaches the upper limit of the eating and drinking temperature, the heating setting temperature may be controlled by the electromagnetic induction heating device by providing a temperature sensor or a timer in the electromagnetic induction heating device.
In the embodiment described above, the lid is removed from the vacuum double container, and the liquid food and drink in the vacuum double container is transferred to the cup for eating and drinking, but for example, directly from the mouth on the nozzle attached to the lid. It may be possible to drink, or the lid may be removed from the container so that it can be directly taken from the container.

また、上記の実施の形態では、本発明の真空二重容器を本発明の保温方法に用いるようにしていたが、本発明の真空二重容器は、熱していないペットボトルのお茶等を直接真空二重容器に容れた状態でIH調理器等で電磁誘導発熱体層を誘導加熱してお茶を温めるような方法に用いるようにしても構わない。   In the above embodiment, the vacuum double container of the present invention is used for the heat insulation method of the present invention. However, the vacuum double container of the present invention directly vacuums tea from tea bottles that are not heated. You may make it use for the method of induction-heating an electromagnetic induction heating body layer with an IH cooker etc. in the state enclosed in the double container, and warming tea.

1 真空二重容器
11 二重容器本体
2 内容器
21 有底筒状部材(内容器構成部材)
3 外容器
31 孔明き筒状部材(外容器構成部材)
31a 真空吸引用の孔
32 封止板
33 ロウ材
4 電磁誘導発熱体層
40 混合銀ペースト
5 真空加熱炉
6 IH調理器
DESCRIPTION OF SYMBOLS 1 Vacuum double container 11 Double container main body 2 Inner container 21 Bottomed cylindrical member (inner container component)
3 Outer container 31 Perforated cylindrical member (outer container component)
31a Vacuum suction hole 32 Sealing plate 33 Brazing material 4 Electromagnetic induction heating element layer 40 Mixed silver paste 5 Vacuum heating furnace 6 IH cooker

Claims (1)

内容器となる内容器構成部材と、封止口を備える外容器構成部材とを容器入り口側部分で一体化した封止口を有する二重容器本体を、真空加熱炉中に入れ、ロウ材を溶融し、ロウ材で直接前記封止口を封止する、あるいは、封止板の周囲をロウ材で封止口の周囲を封止する封止工程を実施する前に、予め前記ロウ材の溶融温度以下の焼成温度を有する金属ペーストを前記内容器構成部材の外壁面に塗布しておき、前記真空加熱炉内を前記ロウ材溶融温度以上にして封止工程を実施すると同時に前記金属ペーストを焼成して電磁誘導発熱層を形成する真空二重容器の製造方法であって、A double container body having a sealing port in which an inner container constituent member serving as an inner container and an outer container constituent member having a sealing port are integrated at a container inlet side portion is placed in a vacuum heating furnace, and a brazing material is used. Before the sealing step of melting and sealing the sealing port directly with the brazing material or sealing the periphery of the sealing plate with the brazing material, A metal paste having a firing temperature equal to or lower than the melting temperature is applied to the outer wall surface of the inner container constituent member, and the sealing process is performed at the same time as the brazing material melting temperature is set at the vacuum heating furnace or higher. A method of manufacturing a vacuum double container that is baked to form an electromagnetic induction heating layer,
前記内容器構成部材が、非磁性の金属材料からなり、The inner container component is made of a nonmagnetic metal material,
前記外容器構成部材が、前記内容器構成部材の金属材料と易溶接性の非磁性の金属材料からなるとともに、The outer container component is made of a metal material of the inner container component and an easily weldable non-magnetic metal material,
前記金属ペーストが、粒径の大きい金属粒子を含む金属ペーストと、粒径の小さい金属粒子を含む金属ペーストとを混合して焼成温度をロウ材の溶融温度以下に調整した混合金属ペーストであることを特徴とする真空二重容器の製造方法。The metal paste is a mixed metal paste in which a metal paste containing metal particles having a large particle size and a metal paste containing metal particles having a small particle size are mixed to adjust the firing temperature to be equal to or lower than the melting temperature of the brazing material. A manufacturing method of a vacuum double container characterized by the above.
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