JP6165269B2 - Gunpowder to accelerate mortar shells - Google Patents

Description

  The present invention relates to explosives as propellant or igniting explosives for accelerating shells for mortar systems, the explosives being based on nitrocellulose and a nitramine based crystalline energy carrier of 1-30% by weight, and inorganic It contains a flame retardant, where the explosive is present in particulate form, the particles optionally having an inert plasticizer on the surface of the particles. The present invention further relates to a method for producing such explosives.

Prior Art In recent years, great fluctuations have occurred in the field of large caliber artillery. Until the end of the Cold War, large-diameter tanks and heavy weapons systems were the foundation of land support units. These systems have been optimized to defend their territories, but their weight has limited their mobility. In particular, such weapons systems cannot be airlifted, making rapid deployment to territory extremely difficult.

  However, with the outbreak of the Gulf War (first Iraq War) in the early 1990s, the strategy that had been used until then reached a major turning point. The large caliber artillery had to be transported to a far-off operating point in a short time. For this reason, rediscovery about the mortar system was conspicuous in the Gulf War. Because of its relatively light weight, such a large caliber artillery can be air transported as a large number of parts without problems and can operate quickly in times of conflict. In addition, the development of high-performance electronics (eg satellite navigation or route guidance) has significantly improved accuracy.

  Recent examples show that this trend of military force movement is supported almost all over the world. Thanks to the high interest in mortar systems, demand is increasing and performance improvements are also desired. The new mortar shell with route guidance by electronic equipment and accurate point detonation performance is heavier than the conventional standard shell. Therefore, there has been a demand for improved propellant performance that compensates for the effect on range due to its relatively heavy weight, or even further extends range.

  In addition, over the last 20 years, military conflicts have mainly occurred in areas with hot climates (eg Iraq or Afghanistan). The propellant that has been used so far contains nitroglycerin, which has been popular in order to obtain high performance potential, and has not been assumed to have a high heat load. Important internal ballistic data (eg, muzzle initial velocity and peak gas pressure) has been confirmed to change with months of use and storage in hot weather areas. The lower the muzzle initial speed, the shorter the range and the lower the accuracy. On the other hand, the gas pressure increases by up to 50%, which increases the safety risk when firing a shell. In addition, due to the intense thermal effects of the climate, the chemical stability of the propellant is reduced, in particular by the immediate consumption of the stabilizer. Therefore, in general, conventional nitroglycerin-containing explosives may spontaneously shift to autocatalysis when stored in a hot storage room or in an ammunition box under direct sunlight, injuring surrounding personnel by explosion, This is a safety risk that the structure can be destroyed.

  Nitrochemie has already been aware of the signs of the trend and has begun developing a new generation of high-performance explosives free of nitroglycerin. The gunpowder showed no change in ballistic or chemical stability when used for long periods in hot climates. This means that there is no safety risk even if the explosives according to the invention are used and stored in hot climate areas. These new generations of gunpowder are first for high-performance applications in medium caliber artillery, such as wing-stabilized bombs with shells for APs (APFSDS T), or ABMs for non-fire guns (Airburst-Munition) Developed specially. Such a weapon system usually has a relatively long barrel, and the peak gas pressure is usually relatively high at 3000 to 5000 bar at the time of bullet injection.

  In contrast, the mortar system has a clearly short barrel and a low peak gas pressure that occurs when the shell is fired. That is, 1000 bar at maximum load, and lower if the load is lower. This means that the gunpowder must be fully reacted even at gas pressures below 100 bar. This criterion could not be achieved by conventional high performance formulations without nitroglycerin. Thus, there was a need for new opportunities for proper propulsion techniques that have a special ratio configured for mortar systems with low peak gas pressure and short barrels. Such new propellants are also required to have excellent chemical and ballistic stability, where the propellant must also have the property of reacting with high performance and efficiency in a mortar system. I must.

DESCRIPTION OF THE INVENTION An object of the present invention is to obtain a gunpowder belonging to the technical field mentioned at the beginning, which is a propellant or a gunpowder for accelerating a mortar system shell, It has excellent chemical stability and ballistic stability and is capable of reacting with high performance and high efficiency.

  This problem has been solved by the features specified in claim 1. According to the present invention, there is provided an explosive as a propellant or an explosive for accelerating a mortar for a mortar system, which is based on nitrocellulose. This explosive contains 1-30% by weight of a nitramine-based crystalline energy carrier and 0.1-10% by weight of an inorganic flame retardant. This gunpowder exists in the form of particles. These particles can have an inert plasticizer on the particle surface. This additive is present in the range of 1% by weight or less, ie in the range of 0-1% by weight.

  These particles preferably have 0.01 to 1% by weight of an inert plasticizer on the particle surface.

  Surprisingly, the use of a relatively small amount of inert plasticizer on the surface of the explosive can reduce the pressure dependence when the temperature rises. It is known that the propellant for medium caliber can certainly adjust the pressure transition flatly by using a large amount of inert plasticizer. In this case, if it is less than 2% by mass, almost no effect is obtained. However, this relevance turned out not to apply to propellant for mortars. In the case of the propellant for the mortar system according to the present invention, the flat pressure transition can be adjusted even if the amount of the inert additive is relatively small. When the concentration increases, the pressure transition gradually becomes steep, and when the concentration is clearly over 1% by mass, the pressure increases remarkably with increasing temperature. In the preferable range of 1% by mass or less of the inactive plasticizer, the increase in the muzzle initial velocity becomes relatively small as the temperature rises, so that the propellant is generally characterized by a substantially neutral temperature characteristic. Some applications also do not require any inert plasticizer.

  The explosive according to the present invention has a flat energy transition and a high energy conversion rate, thereby improving the internal ballistic performance.

  A mortar system is generally understood as a system with a relatively short barrel and firing at a relatively steep angle. Mortars range from 37 mm caliber (light mortar) to 240 mm caliber (super heavy mortar). The most important here is a heavy mortar with a caliber of 60-120 mm. Of particular interest to the present invention are propellants for mortars with calibers of 60 mm, 81 mm and 120 mm and / or mortar systems with calibers of 60 mm, 81 mm and 120 mm.

  The explosives according to the invention can also be used as igniting explosives for mortars. The igniting explosive is contained in the shaft of the mortar shell and is needed to enhance the initial firing impact of the pyrotechnic and to transmit this impact to the propellant in the increment (horse-shoe-type charge). The composition of the ignition powder is the same as that of the propellant. However, they differ in particle size and particle shape.

  Both propellant and igniting explosives are extrudable bulk explosives that can be produced by the solvent process and contain nitrocellulose as the main component. Nitrocellulose has been a very important starting material for the production of single, double and triple base propellants for over a hundred years. This is obtained by nitrification of cellulose (cotton linter, pulp), is available in a large amount at a low cost, and various physicochemical properties are widely obtained. Nitrocellulose can vary, for example, nitrogen content, molecular weight, or viscosity, and can be processed into various types of homogeneous propellant based on these differences. The energy ratio of nitrocellulose is adjusted by the nitrogen content. In a single base formulation, nitrocellulose is the sole energy carrier. This means that the energy density of nitrocellulose is relatively high compared to other synthetic binding polymers.

  The explosive according to the invention is based on nitrocellulose. This preferably has an average nitrogen content of 12.6 to 13.25%. Further important components contained within the particle matrix are crystalline energy carriers and inorganic anti-inflammatory agents.

  Crystalline energy carriers improve the energy content of the explosive and are used at concentrations ranging from 1 to 30% by weight. With such a ratio based on nitrocellulose, the average distance between the crystals of the crystalline energy carrier is sufficiently large, so that the crystals hardly contact each other. As a result, the influence of the mechanical stimulus of the external shock wave is not further transmitted from the crystal of the explosive material to the adjacent crystal. Therefore, the shock wave which acts primarily is propagated through the entire amount of the explosive without being doubled. On the other hand, when the mass ratio of the crystalline energy carrier is relatively large, it is considered that the crystals are adjacent to each other at random, thereby greatly increasing the killing ability of the explosive.

  The inorganic flame retardant is used at a concentration in the range of 0.1 to 10% by mass. By adding an inorganic flame retardant, the reaction of unburned gases (eg, hydrogen or carbon monoxide) is suppressed in the muzzle region, so these gases do not ignite at all or hardly. This reduces the muzzle flame, which reduces the flame blinding effect on the shooter, while making it more difficult to locate the shooter.

Preferred among the nitramine-based crystalline energy carriers are at least one compound from the group comprising hexogen (RDX) and octogen (HMX). Both compounds of the general formula R—N—NO ₂ (where R represents a group) have a relatively small group R, which has a lower proportion of the total molecular weight than the nitramine structural unit. . This gives these two compounds a relatively high energy content.

  RDX is preferably used as a crystalline energy carrier. This is advantageous during manufacture and safer than HMX. HMX is more expensive than RDX but has no particular advantage. Other nitramine compounds (for example, NIGU) have inferior performance compared to RDX. For stabilization, known agents (eg Akardit II) can also be used.

  Particularly preferably, the crystalline nitramine compound has a defined average particle size. Therefore, for example, it is preferable to use RDX having an average particle diameter of 4 to 8 micrometers, particularly 6 micrometers. Due to the uniform particle size of the crystalline energy carrier, it is possible to produce an explosive having relatively constant chemical and ballistic properties.

Instead of the nitramine compound, for example, nitrate esters of the general formula R—O—NO ₂ are also conceivable. However, nitrate esters are less chemically stable than nitramine compounds. In addition, at least one of the following compounds can be used as the crystalline nitramine compound: hexanitroisol titanium (CL-20, CAS No. 14913-74-7), nitroguanidine (NIGU, NQ, CAS) No. 70-25-7), N-methylnitramine (tetril, N-methyl-N, 2,4,6-tetranitrobenzoamine, CAS No. 479-45-8), and nitrotriazolone (NTO CAS No. 932-64-9), and triaminotrinitrobenzene (TATB, CAS No. 3058-38-6). All of these energy compounds can be used alone or in combination with each other.

  Particularly preferably, the proportion of the crystalline energy carrier is 5 to 25% by weight. Explosives containing a crystalline energy carrier in a proportion of 10 to 20% by weight are particularly preferred. When the mass proportion is less than 25% by mass, especially at most 20% by mass, the crystals of the energy carrier are separated from each other, and therefore the explosive killing ability is at a very low level. By using an inert plasticizer, the killing ability of the explosive can be somewhat weakened even when the mass ratio of the crystalline nitramine compound is relatively high. This makes it easy to use a crystalline nitramine compound in a high proportion.

  In addition to its properties as a crystalline energy carrier, RDX also has a certain stabilizing action, this action already appears from about 1% by weight and hardly improves even when its proportion is increased.

  An inorganic flame retardant is at least one compound from the group of alkali metal salts (eg, potassium nitrate and potassium sulfate). In addition to reducing muzzle flames, these compounds also promote combustion, thereby reducing residue formation, which further improves energy conversion.

  In a special embodiment, the inorganic flame retardant is present in a proportion of 0.1 to 5% by weight.

Inert plasticizers that may be present on the surface of the explosive particles are in particular camphor, dialkyl phthalate (preferably di- (C ₈ -C ₁₂ ) phthalate, or di- (C ₈ -C ₁₂ ) phthalate hydrogen. Compound) and dialkyldiphenylurea (preferably dimethyldiphenylurea, commonly known as Centralit II). Inert plasticizers can also be applied in combination of multiple compounds.

  Of the compounds that can optionally be applied to the surface of the explosive particles, camphor is particularly preferred.

  Furthermore, the surface of the explosive particles is preferably treated with graphite and ethanol.

  Extruded explosive particles are preferably surface treated with ethanol and graphite. Optionally, the surface can be treated with an inert plasticizer. The inert plasticizer penetrates the area close to the surface of the explosive particle and stays there. That is, the inert plasticizer is localized and not distributed within the particle matrix. The inert plasticizer has a penetration depth of a few hundred micrometers, for example a maximum of 400 micrometers, preferably 100-300 micrometers. This means that at least 95% by weight of the inert plasticizer is contained to this depth.

  The applied graphite preferably remains on the surface of the explosive particles.

  The properties of the explosive particles are positively influenced by surface treatment (ie, application of ethanol and graphite) and optionally by applying an inert plasticizer to the surface of the extruded explosive particles. Thus, temperature insensitive behavior and apparent density (ie, how much explosive is present in a given container volume) are improved, especially by surface treatment with ethanol and graphite. The pressure level (ie, the ratio of peak gas pressure to muzzle velocity) is particularly improved by adding an inert plasticizer to the surface of the extruded explosive particles, which can degrade the temperature coefficient. is there. At the same time, the particle matrix does not contain inert compounds as essential components, and can thereby have a large amount of energy compounds. A great effect can be obtained by surface treatment combining these substances.

  Particularly preferably in the case of a mortar gunpowder, an inert plasticizer is present on the particle surface in an amount of 0.1% by weight or less, ie 0 to 0.1% by weight, in particular 0.01 to 0.1% by weight. With just this amount of inert plasticizer, there is relatively little change in muzzle speed and pressure rise when moving to high temperatures. If there are clearly more inert plasticizers, the possibility of obtaining temperature-insensitive behavior is reduced.

  The particles preferably have a cylindrical shape with a longitudinal channel in the axial direction for propulsion. The number of channels is arbitrary and often one particle has one channel, seven or nineteen channels. Such ammunition explosives (also referred to as perforated explosives) can therefore be deposited or flowed and industrially filled into a cartridge case.

  The value of the ratio of length (L) to diameter (D) of the cylindrical particles is usually L / D = 0.25-5. The length of the cylindrical shape is, for example, in the range of 0.3 to 10 mm, and the diameter is in the range of 0.3 to 10 mm.

  When the present invention is implemented as a porous explosive, a shape having a small pitch circle, and hence a relatively large wall thickness is preferable. This means that, when the vertical channels are observed in the cross section, the central part is thickly arranged, and generally occupies a relatively small pitch circle. For example, preferably, six axial channels in a seven-holed gunpowder with a total diameter of about 3.6 mm form a pitch circle with a diameter of about 2.1 mm.

  In a particularly preferred embodiment, each of the vertical channels of propellant has a pore diameter of 0.1 to 0.5 mm.

  When the explosive according to the present invention is used as an ignition explosive, its particle size is usually smaller than when it is used for propellant. Such explosives more often have a cylindrical shape with a longitudinal channel in the center. Such explosives have, for example, an outer diameter of 1.3 to 1.7 mm, a length of 1.5 to 2.0 mm, an average wall thickness of 0.6 to 0.8 mm, and a hole diameter of about 0.10 mm. is there.

  Alternatively, the explosive material can be present in the form of a strip or directly extruded into a specific shape suitable for a gun. This form of gunpowder is particularly suitable for large caliber ammunition. Such a shape usually corresponds to a shape whose width is much smaller than the length (eg at least 5 times or at least 10 times) and whose thickness is much smaller than the width (eg at least 5 times or at least 10 times). is there. When the thickness is 1 to 2 mm, the width is usually 10 mm or more and the length is 100 to 150 mm, for example.

  A so-called “molded body”, ie a hollow cylindrical shape for ammunition, is also conceivable, in which case there is no shell and / or is replaced by a “molded body” arranged behind the ignition point.

  The particle matrix can optionally contain further additives known per se. In order to improve the stability, for example, sodium bicarbonate (CAS No.144-55-8), calcium carbonate (CAS No.471-34-1), magnesium oxide (CAS No.1309-48-4), Akardit Il (CAS No.724-18-5), Centrailt I (CAS No.90-93-7), Centraiit II (CAS No.611-92-7), 2-nitrodiphenylamine (CAS No.836-30) -6) and diphenylamine (CAS No.122-39-4) can be added. Additives such as lime, manganese oxide, magnesium oxide (CAS No.1303-48-4), molybdenum trioxide (CAS No.1313-27-5), magnesium silicate (CAS No .: 14807-96-6) , Calcium carbonate (CAS No.471-34-1), titanium dioxide (CAS No.13463-67-7), tungsten trioxide (CAS No.1314-35-8) are useful for protecting the barrel and Compounds such as acid esters, citrate esters, or adipic acid esters are common plasticizers.

  Furthermore, the particle compact (the particles themselves to be further processed) can further contain other known additives in the matrix, for example to improve ignitability and to adjust the flammability.

  A feature of the method for producing an explosive according to the present invention is to produce a solvent-containing explosive paste based on nitrocellulose, 1-30% by weight of a crystalline energy carrier based on nitramine and an inorganic flame retardant. is there. Subsequently, a particle compact is produced from the solvent-containing explosive paste by extrusion molding. The solvent is removed from the particle compact, and the particle compact is optionally surface treated with an inert plasticizer. Finally, the optionally shaped particle compact is dried.

  The explosive according to the present invention (the explosive binder is mainly composed of nitrocellulose and further contains a nitramine-based crystalline energy carrier and an inorganic flame retardant) can be produced with existing production equipment. Solid formulation ingredients such as solvent-containing mixtures can be added. The resulting solvent wet kneaded paste can be kneaded with a kneader and then extruded into a desired shape with a press. The extruded strand can be pre-dried and cut to the desired particle length. Subsequently, the solvent can be removed from the particles. These particles can optionally be surface treated with an inert plasticizer and / or finished.

  Preferably, the particle compact is surface-treated with ethanol and graphite, that is, graphitized. This graphitization can be carried out as a separate process step. However, it is also possible to apply graphite and ethanol to the particle compact together with an inert plasticizer.

  Particularly preferably, the solvent is removed from the particle compact by a wet method.

  The particle compact obtained by extrusion contains an inorganic flame retardant in the particle matrix. Therefore, it is desirable that this particle compact is not subjected to a water bath method in order to remove the solvent from the particle matrix. Otherwise, the water-soluble inorganic flame retardant will flow down from the particle matrix.

Therefore, the solvent used in the manufacturing process is removed by a wet method. At this time, an air stream (saturated with water vapor) at a temperature of 20 to 70 ° C. is allowed to flow through the particle compact wetted with the solvent for 10 to 60 hours at a flow rate of several hundred m ³ per hour. Thus, while the proportion of solvent is reduced to less than 1%, the water-soluble anti-inflammatory agent is not removed from the particle matrix and remains in the particle matrix.

  It is preferable to finish after drying the surface-treated particles. This finish is understood in particular as careful drying and sieving of the surface-treated particles.

  Further advantageous embodiments and combinations of features of the method can be obtained from the following detailed description and the entire claims.

Method of Implementation of the Invention During the production of particle compacts, various additives are added to the nitrocellulose-based explosive paste. That is, these additives are uniformly distributed in the matrix. The total amount of these additives (excluding the crystalline nitramine compound) is 0 to 10% by mass, preferably 2 to 7% by mass, based on nitrocellulose. In the case of normal RDX, the total amount of the crystalline nitramine compound is 0 to 30% by mass, preferably 0 to 20% by mass, based on the amount of nitrocellulose. The crystalline nitramine compound optionally has to be subjected to a pretreatment in order to improve the binding to the matrix, after which this compound is added to the explosive paste.

  After the explosive paste is kneaded with a solvent, the particle compact is extruded using a mold. Subsequently, water and solvent are removed, preferably by wet air drying. The particle compact is subjected to a surface treatment, for example optionally applying an inert plasticizer, and preferably further additives (eg graphite) in the presence of ethanol (impregnation + coating).

Example 1 propellant 1 (FM4651 / 21)
To produce 520 kg of explosives with 7 holes, nitrocellulose (RDX 20% by mass, Akardit II 1.2% by mass, potassium nitrate 3.2% by mass, and nitrogen content 13.20% by mass (total of 100%) %) Is processed for 70 minutes after addition of diethyl ether and ethanol to obtain a kneaded paste wetted with solvent. Subsequently, the explosive paste is pressed into a 5.2 mm strand with 7 holes (ie, extrusion) using a mold. The extruded strand is pre-dried with air for a short time, cut to the desired length, and the particle compact thus obtained is spread evenly on a fine sieve. Thereafter, an air stream saturated with water is passed through the particle compact for 30 hours at a temperature of 200 m ³ / h, 30 ° C., and subsequently for 30 hours at a temperature of 400 m ³ / h, 65 ° C. (wetting) Air drying). Next, 60 kg of the particle compact heated to 60 ° C., 0.05 mass% of graphite and 1.2 liters of ethanol are added in a copper polishing drum heated to 55 ° C., and then rotated constantly for 1 hour. Finally, the explosive is spread on the steel plate and dried at 60 ° C. for 24 hours.

  The physical properties of the generated propellant 1 (referred to as FM4651 / 21) are as follows: outer diameter 3.63 mm, length 3.61 mm, average wall thickness 0.76 mm, pore diameter 0.20 mm, heat content 1 g Per 4251 J, bulk density 1048 g / l. Chemical stability: explosion temperature 172 ° C., heat flux calorimetry according to STANAG 4582, 44 J / g, or 30.4 μW (standard heat generation is less than 114 μW based on STANAG 4582).

Example 2 ... propellant 2 (FM4650 / 22)
The explosive paste from Example 1 is pressed (ie extruded) into 4.8 mm strands with 7 holes using a mold. The extruded strand is pre-dried with air for a short time, cut to the desired length, and the particle compact thus obtained is dried with wet air (as in Example 1). Subsequently, 60 kg of the particle compact is preheated to 60 ° C. and transferred to a copper polishing drum heated to 55 ° C. A 1% by mass camphor solution in graphite 0.05% and ethanol 1.2 kg is added to this particle compact, and the mixture is always rotated for 1 hour. Finally, the explosive is spread on the steel plate and dried at 60 ° C. for 24 hours.

  The physical properties of the generated propellant 2 (referred to as FM4650 / 22) are as follows: outer diameter 3.42 mm, length 3.45 mm, average wall thickness 0.71 mm, pore diameter 0.19 mm, heat content 1 g Per 4152 J, bulk density 1002 g / l. Chemical stability: Explosion temperature 172 ° C, heat flux calorimetry according to STANAG 4582 47J / g, or 30.9μW (standard heat generation is less than 114μW based on STANAG 4582).

表２

Comparison of propellant 1 and 2 Comparison of pressure rise due to change in amount of camphor when gunpowder temperature is high System: Cannon equivalent to US military standard 120mm mortar M120, especially in terms of gun length and muzzle shape A 120mm barrel with internal ballistics. The fire mass of the inert mortar used was 15.5 kg. The speed was measured with a Doppler radar, and the peak gas pressure was measured in the area of the muzzle with a piezoelectric element. The results of the temperature firing of the two propellant explosives (one without camphor coating and one with camphor coating 1% by weight) were performed at gunpowder temperatures of 21 ° C. and 63 ° C. and are summarized in Tables 1 and 2 below.
Table 1

Table 2

  From the results of Tables 1 and 2, the pressure rise when the pressure is shifted from 21 ° C. to 63 ° C. has 1% by mass of camphor when the camphor is 0% by mass of propellant 1 (FM 4651/21). Clearly lower than propellant 2 (FM 4650/22). This finding is unexpected and goes against conventional experience in the medium caliber field (previously, increasing the amount of camphor was thought to reduce the pressure increase).

Example 3 ... propellant 3 (FM4714)
The explosive paste from Example 1 is extruded into 5.1 mm strands with 7 holes using a mold. The extruded strand is pre-dried with air for a short time, cut to the desired length, and the particle compact thus obtained is dried with wet air (as in Example 1). Subsequently, 120 kg of the particle compact is preheated to 60 ° C. and transferred to a copper polishing drum heated to 55 ° C. A 0.1% by mass camphor solution in 0.05% graphite and 2.4 kg of ethanol is added to this particle compact, and it is always rotated for 1 hour. Finally, the explosive is spread on the steel plate and dried at 60 ° C. for 24 hours.

  The physical properties of the generated propellant 3 (referred to as FM 4714) are as follows: outer diameter 3.58 mm, length 3.59 mm, average wall thickness 0.75 mm, pore diameter 0.20 mm, heat content 4g / g , Bulk density 1026 g / l. Chemical stability: explosion temperature = 172 ° C. Heat flux calorimetry according to STANAG 4582 50 J / g, or 32.6 μW (standard heat generation is less than 114 μW based on STANAG 4582).

表４

Comparison between propellant 3 and spherical powder Comparison of pressure increase at high gunpowder temperature and internal gunball ballistic performance with comparative gunpowder containing nitroglycerin (spherical powder GD from St. Marks) System: Especially A 120mm gun barrel that has the same internal ballistics as the US military standard 120mm mortar M120 in terms of gun length and muzzle shape. The fire mass of the inert mortar used was 15.1 kg. The speed was measured with a Doppler radar, and the peak gas pressure was measured in the area of the muzzle with a piezoelectric element. The results of the two gunpowder temperature shootings were performed at gunpowder temperatures of 21 ° C. and 63 ° C. and are summarized in Tables 3 and 4 below.
Table 3

Table 4

  As can be seen from the results shown in Tables 3 and 4, in the case of the comparative explosive containing nitroglycerin, the pressure rise at the time of shifting to 63 ° C. is higher than that of propellant 3 (FM4714) having 0.1% by mass of camphor. Is also obviously high. In addition, the speed of the comparative gunpowder at 21 ° C. is about 25 m / sec lower despite the 28 g loading, which significantly reduces the range.

  The explosive tests described in Example 3 generally indicate high performance explosives with low temperature dependence. Furthermore, the variability during each measurement is much less than other explosives, which means that the explosives are homogeneous and thus have a constant performance.

Example 4 ... ignition powder (FM 4483/21)
The explosive paste from Example 1 is pressed (ie extruded) into 2.1 mm strands with one hole using a mold. The extruded strand is pre-dried with air for a short time, cut to the desired length, and the particle compact thus obtained is dried with wet air (as in Example 1). Subsequently, 20 kg of the particle compact is preheated to 60 ° C. and transferred to a copper polishing drum heated to 55 ° C. To this particle compact, 0.3% by mass of graphite and 0.3 kg of ethanol are added, and then rotated constantly for 1 hour. Finally, the explosive is spread on the steel plate and dried at 60 ° C. for 24 hours.

  The physical properties of the generated explosive 1 (referred to as FM4483 / 21) are as follows: outer diameter 1.47 mm, length 1.75 mm, average wall thickness 0.69 mm, pore diameter 0.10 mm, heat content 1 g 4393J per unit, bulk density 1001 g / l. Chemical stability: explosion temperature 172 ° C. It is 46J / g or 30.2μW in heat flux calorimetry according to STANAG 4582 (the standard heat generation amount is less than 114μW according to STANAG 4582).

Example 5 ... ignition powder 2 (FM4483 / 22)
The explosive paste from Example 1 is pressed (ie extruded) into 2.1 mm strands with one hole using a mold. The extruded strand is pre-dried with air for a short time, cut to the desired length, and the particle compact thus obtained is dried with wet air (as in Example 1). Subsequently, 20 kg of the composition particles are preheated to 60 ° C. and transferred to a copper polishing drum heated to 55 ° C. To this particle compact, 0.3% by mass of graphite, 0.5% by mass of camphor, and 0.15 kg of ethanol are added and then rotated constantly for 1 hour. Finally, the explosive is spread on the steel plate and dried at 60 ° C. for 24 hours.

  The physical properties of the generated explosive 2 (referred to as FM4483 / 22) are as follows: outer diameter 1.47 mm, length 1.75 mm, average wall thickness 0.69 mm, pore diameter 0.10 mm, heat content 1 g 4343J per unit, bulk density 995g / l. Chemical stability: explosion temperature 172 ° C. STANAG 4582 compliant heat flux calorimetry of 52 J / g or 32.4 μW (Standard by STANAG 4582, maximum heat generation is less than 114 μW).

表６

表７

Comparison of ignition powder 1 and 2 with spherical powder Comparison of pressure rise at high temperature by changing camphor amount of ignition powder 1 and 2 and comparison with introduced M48 spherical powder System: 120mm barrel with internal ballistics characteristics similar to US standard 120mm mortar M120 in terms of length and muzzle shape. The fire mass of the inert mortar used was 14.0 kg. The speed was measured with a Doppler radar, and the peak gas pressure was measured in the area of the muzzle with a piezoelectric element. This test is performed with 4 loads, ie 4 standard increments of M234. The results of temperature firing of two types of propellant (camphor coating 0 mass% (FM 4483/21) and camphor coating 0.5 mass% (FM 4483/22)) are compared with the introduced M48 spherical powder And performed in standard M1020 shells at gunpowder temperatures of 21 ° C. and 63 ° C., and are summarized in Tables 5, 6, and 7 below.
Table 5

Table 6

Table 7

  The presence of 0.5% by mass of camphor in the ignition powder 2 according to the present invention reduces the peak gas pressure at 21 ° C. This can be advantageous for certain applications. However, the ignition powder 2 having 0.5% by mass of camphor has a larger pressure rise than the ignition powder without the camphor, and is optimal in accordance with the application in order to best satisfy the application of a predetermined system requirement. It is necessary to accurately measure the amount of camphor. Furthermore, it can be seen that the maximum gas pressure occurs at 21 ° C. for the introduced M48 spherical powder. The pressure increase from 21 ° C. to 63 ° C. is about 2300 psi for the introduced M48 spherical explosive, which is clearly higher compared to the explosives 1 and 2 according to the present invention.

  In summary, the nitrocellulose-containing explosive according to the present invention containing a nitramine-based crystalline energy carrier and an inorganic flame retardant and having a small amount of inert plasticizer on the surface is a propellant or an ignition explosive. As a result, it can be confirmed that it is suitable for accelerating the munition of the mortar system. At this time, the temperature dependence is low, so it can be used without being influenced by climatic conditions.

Claims (11)

Explosive as propellant or igniting explosive for accelerating shell for mortar system, the explosive being based on nitrocellulose and 1-30% by mass of crystalline energy carrier based on nitramine, and inorganic flame retardant contains, wherein the explosive that Mashimasu exist in the form of particles, in the powder,
The explosive according to claim 1 , wherein 0.1 to 10% by mass of the inorganic flame retardant is present, and the particles have 0.01 to 1% by mass of an inert plasticizer on the surface thereof . Crystalline energy carrier of the nits Ramin base, characterized in that at least one compound from the group comprising Hekisogen (RDX) and Okutogen (HMX), explosive of claim 1. The explosive according to claim 1 or 2 , wherein the crystalline energy carrier is present in an amount of 5 to 25% by mass. The explosive according to any one of claims 1 to 3 , wherein the inorganic anti-inflammatory agent is at least one compound from the group comprising potassium nitrate and potassium sulfate. The explosive according to any one of claims 1 to 4 , wherein the inorganic flame retardant is present in an amount of 0.1 to 5% by mass. The explosive according to any one of claims 1 to 5 , characterized in that the inert plasticizer is at least one compound from the group comprising camphor, dialkyl phthalate, and dialkyl diphenyl urea. The explosive according to any one of claims 1 to 6 , wherein the inactive plasticizer is present in an amount of 0.01 to 0.1% by mass. The explosive according to any one of claims 1 to 7 , wherein the particles have a cylindrical shape and have a longitudinal channel in an axial direction. In the manufacturing method of the explosive as a propellant or an ignition explosive as described in any one of Claim 1-8 , the following processes a) -e):
a) producing a solvent-containing explosive paste based on nitrocellulose, a nitramine based crystalline energy carrier 1-30% by weight, and an inorganic flame retardant;
b) Extruding the solvent-containing explosive paste to produce a particle compact,
c) removing the solvent from the particle compact,
d) a step of surface treatment by an inert plasticizer of the particle moldings 0.01 wt%, and e) drying the grain compact treated front surface,
The manufacturing method described above, characterized by comprising: The method according to claim 9 , wherein the solvent is removed from the particle compact by a wet air method. The method according to claim 9 or 10 , wherein finishing is performed after the surface-treated particle compact is dried.