JP6103096B2 - Exhaust drain valve for fuel cell - Google Patents

Description

  The present invention relates to an exhaust / drain valve that is used in a fuel cell and discharges generated water and impure gas from the anode electrode side to the outside air.

  A fuel cell has a structure in which an anode and a cathode are arranged with an electrolyte membrane such as a solid polymer membrane interposed therebetween, a fuel gas containing hydrogen contacts the anode, and an oxidizing gas containing a gas such as air contacts the anode. By doing so, an electrochemical reaction occurs in both electrodes, and an electromotive force is generated. In such a fuel cell system that obtains electric power by a fuel cell, it is important from the viewpoint of energy saving to eliminate wasteful consumption of hydrogen as a fuel. For this reason, by effectively circulating the off-gas of the fuel gas used in the fuel cell to the fuel cell, the hydrogen remaining in the off-gas is effectively used.

  On the other hand, in the fuel cell, water is generated by a reaction between hydrogen ions that have permeated the electrolyte membrane from the anode side and oxygen in the oxidizing gas due to a chemical reaction at the cathode. Most of the water produced by the reaction is contained in the oxidizing gas off-gas and released into the atmosphere, but a part of the produced water moves to the anode through the electrolyte membrane. The generated water that has moved to the anode side is included in the off-gas of the fuel gas and discharged from the fuel cell. However, since the off-gas is circulated back to the fuel cell as the fuel gas, water remains in the fuel gas circulation system. Will do. The retention of water in the circulation system hinders the supply of hydrogen to the anode, leading to a decrease in the power generation performance of the fuel cell.

  Patent Document 1 describes an exhaust drain valve provided in a valve drain device installed in a reaction gas supply / discharge passage of a fuel cell. This exhaust / drain valve has a seal rubber that opens and closes the discharge port by being held and slid by the valve holder, and a seat portion that contacts the seal rubber around the discharge port, and the seal rubber is separated from the seat portion. In this document, drainage and exhaust are performed, and a coating agent having water repellency is applied to the surface of the seal rubber on the sheet side to prevent freezing due to moisture adhering to the surface of the seal rubber.

JP 2008-116042 A

  However, the conventional exhaust / drain valve is often made of metal (SUS) as the material of the body, because of its reliability against hydrogen permeation. Recently, in order to further reduce the weight, a resin body is often used. However, in the exhaust drain valve disclosed in Patent Document 1, the upstream primary flow path (primary flow path) has a resin molding. There is a possibility that leakage due to voids and welds, which are the above problems, or leakage due to cracks caused by external force may occur.

  The present invention has been made in view of the problems of the background art described above, and an object to be solved is to provide an exhaust / drain valve for a fuel cell that can suppress the occurrence of leakage in the exhaust / drain valve.

The structural feature of the invention according to claim 1 that solves the above problem is that, in the exhaust drain valve for a fuel cell, the fuel gas that is communicated with the fuel gas discharge port of the fuel cell and discharged from the fuel gas discharge port An exhaust / drain valve for blocking or allowing water to flow out to a diluting device for diluting the fuel gas, the exhaust / drain valve being provided in a valve casing and communicating with the fuel gas discharge port. A first gas-liquid circulation part in which a primary flow passage through which fuel gas discharged from the outlet and produced water circulates is formed; provided in the valve casing; formed around the first gas-liquid circulation part; A second gas-liquid circulation part formed so as to surround the first gas-liquid circulation part, and a first gas-liquid circulation part provided in a secondary gas passage communicating with the dilution device side; Mounting member to which the circulation part and the exhaust / drain valve are attached A first seal member provided with a first seal member that seals between the second seal member and a second seal member provided in the second gas-liquid circulation part and sealing between the second gas-liquid circulation part and the mounting member A second seal portion provided with a valve seat, an annular valve seat interposed between the primary flow passage and the secondary flow passage, and advancing and retreating with respect to the valve seat to contact the valve seat. A valve body in which a detachable valve portion is formed, a valve shaft fixed to the valve body, a closed position where the valve portion abuts on the valve seat, and a separation position where the valve portion is separated from the valve seat A valve body operating device for moving the valve body between the valve body and the valve shaft by a predetermined biasing force in a direction in which the valve portion is pressed against the valve seat. Is moved to the closed position, the valve portion is brought into contact with the valve seat, and the pressure applied to the primary flow passage is predetermined. When more than the valve opening pressure is that provided with an elastic member for separating the valve portion from the valve seat.

  The structural feature of the invention according to claim 2 is that, in claim 1, the valve casing is made of resin.

3. The step according to claim 1 , further comprising a support wall that fixes the first gas-liquid circulation part and the second gas-liquid circulation part to each other, wherein the first seal part is provided with the first seal member. with part is circumferentially provided, wherein a first fitting portion cylindrical to fit into the first fitting hole formed in the mounting member, the second sealing portion, said second sealing member is provided A cylindrical second fitting portion that is provided with a stepped portion and is coaxially formed with a larger diameter than the first fitting portion and fitted in a second fitting hole formed in the mounting member. The first seal member is provided on an outer periphery of the first fitting portion and seals between an outer peripheral surface of the first fitting portion and an inner peripheral surface of the first fitting hole of the mounting member. It is a first shaft seal member, and the second seal member is provided on the outer periphery of the second fitting portion, and the outer peripheral surface of the second fitting portion and the front It is that it is the second shaft sealing member for sealing between the inner circumferential surface of the second fitting hole formed in the mounting member.

  According to a fourth aspect of the present invention, in the first or second aspect, the tip of the first gas-liquid circulation portion of the primary flow passage communicates with the fuel gas discharge port of the fuel cell. An introduction opening is provided, and a discharge opening that communicates with the diluting device is provided at the tip of the second gas-liquid circulation portion disposed around the primary flow passage, and the first seal member and At least one of the second seal members is a face seal member that seals between the end face of the introduction opening and the attachment member or between the end face of the discharge opening and the attachment member.

  According to a fifth aspect of the present invention, in any one of the first to fourth aspects, the attachment member is provided between the fuel gas discharge port of the fuel cell and the exhaust drain valve. It is a housing of the gas-liquid separator provided.

  According to the first aspect of the present invention, fuel gas and moisture flow through the primary flow passage communicating with the fuel gas discharge port of the fuel cell. Even if a crack or the like occurs in the first gas-liquid circulation wall and the fuel gas leaks out, the primary gas-flow passage is surrounded by the secondary flow passage. The fuel gas leaking from the fuel flows out into the secondary flow passage. Since this secondary flow passage is sealed between the mounting member by the second seal member, the fuel gas can be prevented from being directly released to the outside air.

  According to the invention which concerns on Claim 2, since the 1st gas-liquid circulation part and 2nd gas-liquid circulation part which comprise a valve casing are resin-made, the weight reduction of the whole valve can be achieved. On the other hand, voids and welds are produced as problems in production during resin molding, and leakage and cracks resulting from these problems become a problem. In the present invention, the primary flow path is surrounded by the secondary flow path. Since the fuel gas leaking from the 1 gas-liquid circulation part flows out to the secondary flow passage, it is possible to prevent the fuel gas from being directly released to the outside air.

  According to the third aspect of the present invention, the first shaft seal member provided on the outer periphery of the first fitting portion is used to assemble the outer peripheral surface of the first fitting portion and the inner peripheral surface of the first fitting hole of the mounting member. It can be sealed while being attached, and the second shaft seal member provided on the outer periphery of the second fitting portion is assembled between the outer peripheral surface of the second fitting portion and the inner peripheral surface of the second fitting hole of the mounting member. Can be sealed while. Also, by setting the first fitting portion and the second fitting portion to be coaxial, one of the shaft of the first fitting portion and the shaft of the second fitting portion is connected to the first fitting hole and the second fitting hole. Since the other of the shaft of the first fitting portion and the shaft of the second fitting portion matches the other of the first fitting hole and the second fitting hole, the first fitting portion and the second fitting portion are aligned with each other. The fitting portion can be easily and simultaneously assembled to the mounting member.

  According to the fourth aspect of the present invention, one of the introduction opening portion of the first seal portion and the discharge opening portion of the second seal portion is sealed by the face seal member, so that the first seal portion and the second seal portion are coaxial. Even when the accuracy is rough, it can be surely sealed by pressing the end face of the introduction opening or the discharge opening from the axial direction.

  According to the invention which concerns on Claim 5, the produced water mixed with fuel gas is isolate | separated by a gas-liquid separator, and it is used as storage water, A part of fuel gas with which this storage water and density | concentration became low is taken from an exhaust drainage valve. Drain to the dilution device side. Thus, since the exhaust / drain valve is attached to the casing of the gas-liquid separator, the number of parts can be reduced and the cost can be reduced without providing a dedicated attachment device.

The figure which shows the outline | summary of the fuel cell system which uses the exhaust drain valve in 1st Embodiment of this invention. It is sectional drawing which shows an exhaust_drain_valve. III-III sectional drawing in FIG. The perspective view which has a cross section in a part which shows the state which attached the exhaust drain valve to the gas-liquid separator. The figure which shows that an exhaust_gas | exhaustion drain valve is a closed state. The figure which shows that an exhaust_gas | exhaustion drain valve is an open state. The figure which shows the exhaust drain valve in 2nd Embodiment.

A first embodiment in which an exhaust / drain valve of an embodiment of the present invention is used in a fuel cell system will be described below with reference to the drawings.
As shown in FIG. 1, the fuel cell system 1 includes an oxygen system 2, a fuel system 5, a cell stack (fuel cell) 6, a power system 7, a cooling system 8, and a control device 9.

  The battery stack 6 is not limited to this, but is formed by stacking a plurality of solid polymer type single cells. The plurality of single cells are electrically connected in series, and each single cell includes an electrolyte membrane and an anode electrode and a cathode electrode (both not shown) sandwiching the electrolyte membrane. In addition, an anode channel 61 for supplying hydrogen gas to the anode electrode is formed in the single cell anode separator (not shown), and the cathode separator (not shown) has a cathode electrode. On the other hand, a cathode channel 62 for supplying air is formed.

  The oxygen system 2 includes an oxygen system supply pipe 21 a, and the oxygen system supply pipe 21 a is connected to one end of the cathode channel 62 in the battery stack 6. On the oxygen supply pipe 21 a, the air filter 22, the compressor 23 that takes in air (oxidized gas) in the atmosphere (compressed gas) and sends it out in order toward the battery stack 6, and the heat of the air pumped from the compressor 23. A three-way valve 3 is formed that shuts off or allows the supply of air to the intercooler 24 and the battery stack 6.

  One end of an oxygen-based discharge pipe 21b is connected to the other end of the cathode channel 62, and an air pressure regulating valve 4 that is a two-port fluid control valve is provided on the oxygen-based discharge pipe 21b. Note that the air pressure regulating valve 4 can be replaced with a shut-off valve and a back pressure regulating valve provided upstream thereof. The above-described three-way valve 3 is a three-port fluid control valve, and one end of the bypass pipe 21c is connected to the other end of the bypass pipe 21c from the air pressure regulating valve 4 of the oxygen-based discharge pipe 21b. Is also connected to a downstream portion (side to which the battery stack 6 is not connected).

  On the other hand, in the fuel system 5, a hydrogen tank 52 is connected to one end of a fuel system supply pipe 51a, and a pressure regulating valve 53 is formed on the fuel system supply pipe 51a. The other end of the fuel system supply pipe 51 a is connected to one end of the anode flow path 61 in the battery stack 6. A fuel system discharge pipe 51b is connected to the other end (fuel gas discharge port 63) of the anode flow path 61, and a gas-liquid separator is arranged on the fuel system discharge pipe 51b in order from the side close to the battery stack 6. 54, an exhaust drain valve 55 and a dilution device 56 are formed. The other end of the oxygen-based exhaust pipe 21b described above is connected to the exhaust gas diluter 56.

  The gas-liquid separator 54 is connected to a portion between the pressure regulating valve 53 and the connection portion of the anode flow path 61 on the fuel system supply pipe 51a via the fuel system circulation path 51c. A circulation pump 57 is provided on the fuel system circulation path 51 c to circulate hydrogen gas from the gas-liquid separator 54 toward the anode flow path 61.

  The gas-liquid separator 54 is connected to a portion between the pressure regulating valve 53 on the fuel system supply pipe 51a and the connection portion of the anode flow path 61 via the fuel system circulation path 51c. A circulation pump 57 is provided on the fuel system circulation path 51 c, and hydrogen gas obtained by separating generated water from hydrogen off-gas (used hydrogen gas) by the gas-liquid separator 54 is supplied to the anode flow path 61 by the circulation pump 57. Sent to. Thereby, a part of the used hydrogen gas is circulated and reused.

The power system 7 includes an electric motor 71 for running the vehicle. The electric motor 71 is connected to the positive electrode and the negative electrode of the battery stack 6 and is driven by the power generation of the battery stack 6.
The cooling system 8 includes a water cooling pump 81 and circulates cooling water in the battery stack 6 to cool the battery stack 6.
The control device (controller) 9 is electrically connected to the compressor 23, the three-way valve 3, the air pressure regulating valve 4, the exhaust / drain valve 55, the pressure regulating valve 53, the circulation pump 57 and the cooling pump 81. The control device 9 controls the operation of each of these components based on the necessary power generation amount of the battery stack 6 calculated according to the running state of the vehicle.

With the configuration described above, when the vehicle starts operation, the control device 9 operates the compressor 23 to supply air to the cathode flow path 62, and operates the pressure regulating valve 53 and the circulation pump 57 to supply hydrogen gas to the anode flow path 61. And the battery stack 6 generates power.
In the oxygen system 2, the air containing oxygen sucked through the air filter 22 is compressed by the compressor 23 and then cooled by the intercooler 24. The three-way valve 3 displaces the position of the valve member in accordance with the amount of power generated by the battery stack 6, and diverts the air supplied from the intercooler 24 and releases it to the bypass pipe 21c. Is controlling.

Further, the air pressure regulating valve 4 controls the pressure in the battery stack 6 by adjusting the opening degree thereof and adjusting the discharge amount of the air remaining in the battery stack 6.
From the gas-liquid separator 54, water generated by power generation and a part of the remaining hydrogen gas are discharged through the exhaust / drain valve 55. The hydrogen gas discharged from the exhaust / drain valve 55 is diluted by the air supplied from the oxygen-based discharge pipe 21b in the dilution device 56, and then released to the outside together with water.

  Here, the exhaust drain valve 55 for the fuel cell will be described in detail. As shown in FIG. 2, the exhaust drain valve 55 includes a valve casing 82, a valve mechanism 83, and a valve body actuating device 84 for driving the valve mechanism 83. I have.

  The valve casing 82 has a body portion 85 and a cover portion 86. The body portion 85 is made of, for example, a polyphenylene sulfide resin reinforced with glass fiber, and is fixed to the casing 54a of the gas-liquid separator 54 as an attachment member with, for example, a bolt, and the flange portion 87 A tubular first gas-liquid circulation part 88 projecting in a direction perpendicular to the vertical direction, and a tubular second gas-liquid circulation projecting from the flange part 87 and disposed around the first gas-liquid circulation part 88 Part 89. A second gas-liquid circulation part 89 projects from the flange part 87, and a step is provided from the second gas-liquid circulation part 89 toward the front end to form the outer periphery of the first gas-liquid circulation part 88. The first gas-liquid circulation part 88 is formed with a primary flow passage 88a that further communicates with the gas-liquid separator 54 that communicates with the fuel gas discharge port 63 of the battery stack 6, and the second gas-liquid circulation part 89 has a diluting device. A secondary flow passage 89 a communicating with 56 is formed. A cylindrical first fitting portion (first seal portion) 88b is formed on the distal end side of the first gas-liquid circulation portion 88, and a step portion provided around the base end portion of the first fitting portion 88b A first shaft seal member (O-ring) 90 is provided so as to surround the outer periphery of the base end portion of the first fitting portion 88b. A cylindrical second fitting portion (second seal portion) 89b is formed on the distal end side of the second gas-liquid circulation portion 89, and the step portion provided around the base end portion of the second fitting portion has a second portion. A biaxial seal member (O-ring) 91 is provided so as to surround the outer periphery of the base end portion of the second fitting portion 89b. As shown in FIG. 3, the first gas-liquid circulation part 88 and the second gas-liquid circulation part 89 are fixed to each other by a support wall 80 extending in the direction in which the first gas-liquid circulation part 88 protrudes. ing.

  In the present embodiment, as shown in FIG. 4, when the exhaust / drain valve 55 is attached to the gas / liquid separator 54 as an attachment member, the first fitting portion 88 b of the exhaust / drain valve 55 is provided with the gas / liquid separator 54. Is fitted into a first fitting hole 92 provided in the casing 54a. The first fitting hole 92 is provided at the bottom of the gas-liquid separator 54, and the generated water that has become liquid in the gas-liquid separator 54 (in the fuel system discharge pipe 51b upstream of the gas-liquid separator 54, The generated water is a mixture of steam and mist, and water vapor is condensed in the gas-liquid separator 54, and the mist generated water aggregates to form a liquid aggregate.) It is designed to accumulate in the part. The second fitting portion 89b of the exhaust / drain valve 55 is also fitted into the second fitting hole 93 provided in the casing 54a of the gas-liquid separator 54 simultaneously with the fitting of the first fitting portion 88b. A step portion is provided around the inner peripheral wall of the first fitting hole 92, and when the first fitting portion 88 b is fitted, the first shaft seal member 90 is connected to the inner peripheral surface of the first fitting hole 92. And the outer peripheral surface of the first fitting portion 88b are axially sealed and pressed in the axial direction by the stepped portion of the first fitting hole 92 and the stepped portion of the first fitting portion 88b. The space between the gas-liquid separator 54 is sealed. In this embodiment, the central axis of the primary flow path 88a is attached substantially horizontally. Similarly, a stepped portion is provided around the inner peripheral wall of the second fitting hole 93, and when the second fitting portion 89 b is fitted, the second shaft seal member 91 is connected to the second fitting hole 93. The inner peripheral surface and the outer peripheral surface of the second fitting portion 89b are axially sealed, and are held and pressed in the axial direction by the step portion of the second fitting hole 93 and the step portion of the second fitting portion 89b. The path 89a and the casing 54a are configured to be sealed. The gas from the secondary flow passage 89 a in FIG. 4 is discharged from the passage 100 formed in the wall of the second fitting hole 93. The passage 100 communicates with a fuel system discharge pipe 51 b downstream of the exhaust drain valve 55.

  On the proximal end side of the first gas-liquid circulation portion 88, a valve storage portion 94 formed by opening one end surface side (upper side in FIG. 2) at the center portion of the flange portion 87 is formed. A primary flow passage 88a is opened at the center of the secondary flow passage, and a secondary flow passage 89a is opened around the opening of the primary flow passage 88a. The opening edge of the primary flow passage 88a projects toward the valve storage portion 94 so as to taper inwardly toward a small diameter, and an annular valve seat 95 is formed on the opening edge. A fixed groove 96 for fixing a peripheral end portion of a diaphragm portion of a valve body, which will be described later, is provided on the peripheral end surface of the valve storage portion 94.

  On the peripheral end side of the flange portion 87, an attachment hole 87a for attaching to the gas-liquid separator 54 and an assembly hole 87b for assembling a support plate described later are provided. Metal female screw members are embedded around the mounting hole 87a and the assembly hole 87b, respectively.

  The cover portion 86 is made of, for example, a nylon resin, and has a cylindrical cylindrical portion 86a. A connector support portion 86b that constitutes a connector is formed at the tip of the cylindrical portion 86a with respect to the longitudinal direction of the cover portion 86. Projected at a right angle. The connector support portion 86a is provided with a terminal 86c connected to a solenoid, which will be described later, and a locking claw 86d that is detachably locked to a socket (not shown). A guide groove 86e into which a support band described later is inserted in a direction perpendicular to the mounting direction of the connector support portion is formed at the front end portion of the cover member.

The valve mechanism 83 mainly includes a valve body 97, a plunger 98 as a valve shaft, and the above-described valve seat 95.
The valve body 97 is made of, for example, rubber, and includes a valve portion 97a that contacts and separates from the valve seat 95, a diaphragm portion 97b that is integrally formed around the valve portion 97a, and a locking portion that is formed on the back side of the valve portion 97a. 97c and is stored in the valve storage portion 94.
The peripheral edge of the diaphragm portion 97b is fitted and fixed in the above-described fixing groove 96, and the valve housing portion 94 allows the opening side of the primary flow passage 88a and the opening side of the secondary flow passage 89a to be outside air by the valve portion 97a and the diaphragm portion 97b. Against airtight condition.

  The plunger 98 is, for example, a magnetic material made of ferritic stainless steel, and is formed in a columnar shape. A hooked claw 98 a that the locking portion 97 c of the valve body 97 is locked is formed at the end on the valve body 97 side. Has been. At the end of the plunger 98 opposite to the valve body 97, a bottomed spring accommodating hole 98b is formed along the axial direction of the plunger 98 to accommodate a spring member to be described later. The plunger 98 plays a role as a mover of the valve body actuating device 84.

The valve body actuating device 84 includes the above-described plunger 98, a sleeve 99 for guiding the plunger, a core member 106, a solenoid 101, a yoke member, and the like.
The sleeve 99 is made of, for example, austenitic stainless steel, which is a non-magnetic material, and extends in a radial direction perpendicular to the axial direction of the guide portion 99a at the bottomed cylindrical guide portion 99a and the opening end of the guide portion 99a. Mounting flange portion 99b. The attachment flange portion 99b is provided so as to be in close contact with the periphery of the valve storage portion 94 via the diaphragm portion 97b of the valve body 97. A plunger 98 to which a valve body 97 is fixed is slidably provided on the guide part 99 a, and the valve part 97 a of the valve body 97 comes into contact with and separates from the valve seat 95. Further, the distal end portion of the spring member 102 compressed and accommodated in the spring accommodation hole 98b abuts on the bottom portion of the sleeve 99, and the base end portion of the spring member 102 abuts on the bottom portion of the spring accommodation hole 98b. The plunger 98 and the valve body 97 are urged toward the valve seat 95.

  The sleeve 99 is fixed to the body portion 85 with a bolt, for example, via the support plate 103. The support plate 103 is made of, for example, magnetic stainless steel that is a magnetic material, and includes a support hole 103a (see FIG. 4) that supports a support band 104 described later, an assembly hole 103b that attaches the support plate 103 to the body portion 85, and a sleeve. A through hole 103c through which 99 guide portions 99a pass is provided.

  The solenoid 101 is wound around a bobbin 105, and an operating hole 105a is provided in the bobbin 105. The positive and negative pole ends of the solenoid 101 are connected to a power supply (not shown), and a predetermined current is applied according to a command from the control device 9. The solenoid 101 and the bobbin 105 are disposed on the inner peripheral wall portion of the cover portion 86 by integral molding. The guide hole 99a of the sleeve 99 is inserted into the operation hole 105a of the bobbin 105 from one end (valve element 97) side, and the cylindrical core member 106 is inserted from the other end side of the operation hole 105a of the bobbin 105.

  The core member 106 is made of, for example, ferritic stainless steel, which is a magnetic material, and the inserted distal end portion comes into contact with the bottom portion of the sleeve 99 (the upper end portion of the guide portion 99a in FIG. 2). A locking flange 106 a is provided on the base end side (the upper end side in FIG. 2) of the core member 106, and is locked to one end edge (opposite side of the valve body) of the operation hole 105 a of the bobbin 105. The base end portion of the core member 106 is supported and fixed by a support band 104 that is bent into a U-shape.

  The support band 104 is made of, for example, magnetic stainless steel, which is a magnetic material, and a fitting hole 104a into which the base end portion of the core member 106 is fitted is formed in a central portion where both sides are bent at a right angle. Engaging claws 104b that engage with the support holes 103a of the support plate 103 are formed at two tip portions that are bent at right angles and extend from the central portion of the support band 104a (see FIG. 4). The width direction of the support band 104 is fitted into the guide groove 86e of the cover portion 86, the base end portion of the core member 106 is fitted into the insertion hole 104a, and the engagement claw 104b is inserted into the support hole of the support plate 103. The cover portion 86 and the core member 106 are assembled and fixed to the body portion 85 by engaging with 103a. Note that the support plate 103 and the support band 104 have a role as a yoke for preventing magnetic field lines from leaking.

  Next, when the exhaust / drain valve 55 configured as described above is assembled to the gas-liquid separator 54, the first drain hole 55 of the exhaust / drain valve 55 is inserted into the first fitting hole 92 of the gas-liquid separator 54 as shown in FIG. While the 1 fitting part 88b is made to oppose, it fits in the 2nd fitting hole 93 of the gas-liquid separator 54 corresponding to the 2nd fitting part 89b of the exhaust drainage valve 55. FIG. Since the 1st fitting part 88b and the 2nd fitting part 89b are formed coaxially, each fitting can be performed simultaneously and easily. After fitting the first fitting portion 88b and the second fitting portion 89b of the exhaust / drain valve 55 into the corresponding first fitting hole 92 and second fitting hole 93 of the corresponding gas-liquid separator 54, the exhaust / drain valve The flange portion 85 of 55 is fixed by a bolt or the like to an unillustrated female screw hole provided in the housing 54a of the gas-liquid separator 54 through the mounting hole 87a.

Next, the operation of the exhaust / drain valve 55 configured as described above will be described with reference to the drawings.
As shown in FIGS. 2 and 5, the plunger 98 and the valve body 97 are biased toward the valve seat 95 by the spring member 102, and the valve portion 97 a of the valve body 97 is in contact with the valve seat 95. . The valve housing portion 94 where the primary flow passage 88a and the secondary flow passage 89a open is in a state where the flow is blocked by the valve portion 97a. The primary flow path 88a stores, for example, high-concentration hydrogen gas and generated water of 300 kPa, and the secondary flow path 89a is hydrogen gas and generated water, for example, 20 kPa. The pressure in the primary flow passage 88a is higher than that in the secondary flow passage 89a. In this case, even if a crack or the like enters the wall of the first gas-liquid circulation portion 88 and hydrogen gas leaks out, the leaked hydrogen gas leaks into the secondary flow passage 89a, so that the hydrogen gas directly Leakage to the outside air can be suppressed.

  The stored water stored in the gas-liquid separator 54 can be calculated according to the fuel cell operating state (power generation output and power generation time). When the amount of stored water reaches a predetermined amount (predetermined amount of water), the control device 9 applies a current from the power source to the solenoid 101 to generate a magnetic force in a direction in which the plunger 98 is attracted to the core member 106. As a result, as shown in FIG. 6, the plunger 98 moves in the sleeve 99 while resisting the biasing force of the spring member 102 and is attracted to the core member 106 side. Then, the valve body 97 is separated from the valve seat 95, the primary flow passage 88a and the secondary flow passage 89a communicate with each other, and hydrogen gas in the primary flow passage 89a flows out to the secondary flow passage 89a. Due to the pressure of the fuel off-gas (hydrogen gas or the like) in the gas-liquid separator 54, the stored water also flows out into the secondary flow passage 89a and is discharged.

  According to the exhaust drain valve for a fuel cell configured as described above, fuel gas and moisture flow through the primary flow passage 88a communicating with the fuel gas discharge port 63 of the battery stack 6. Even if a crack or the like occurs in the first gas-liquid flow wall 88 and the fuel gas leaks, the primary gas flow wall 88a is surrounded by the secondary flow channel 89a. The fuel gas leaking from the cracks 88 will flow out to the secondary flow passage 89a. The secondary flow passage 89a is cut off from the outside air by the second gas-liquid circulation portion 89 and is sealed from the gas-liquid separator 54 by the second seal member 91, so that the fuel gas can be directly received. Release to the outside air can be prevented.

  Moreover, since the 1st gas-liquid circulation part 88 and the 2nd gas-liquid circulation part 89 which comprise the valve casing 82 are resin, the weight reduction of the whole valve can be achieved. On the other hand, voids and welds are produced as problems in manufacturing during resin molding, and leakage and cracks resulting from these problems become a problem. In the present invention, the primary flow passage 88a is surrounded by the secondary flow passage 89a. Since the fuel gas leaking from the first gas-liquid circulation portion 88 flows out into the secondary flow passage 89, the fuel gas can be prevented from being directly released to the outside air.

  Further, the first shaft seal member 90 provided on the outer periphery of the first fitting portion 88b seals between the outer peripheral surface of the first fitting portion 88b and the inner peripheral surface of the first fitting hole 92 of the gas-liquid separator 54. The outer peripheral surface of the second fitting portion 89b and the inner peripheral surface of the second fitting hole 93 of the gas-liquid separator 54 by the second shaft seal member 91 provided on the outer periphery of the second fitting portion 89b. The gap can be sealed. Also, by setting the first fitting portion 88b and the second fitting portion 89b to be coaxial, one of the shaft of the first fitting portion 88b and the shaft of the second fitting portion 89b is connected to the first fitting hole 92 and When matched with one of the second fitting holes 93, the other of the shaft of the first fitting portion 88b and the shaft of the second fitting portion 89b matches the other of the first fitting hole 92 and the second fitting hole 93. Therefore, the first fitting portion 88b and the second fitting portion 89b can be assembled to the gas-liquid separator 54 simultaneously and easily. Since the exhaust / drain valve is attached to the casing 54a of the gas-liquid separator 54 in this way, the number of parts can be reduced and cost can be reduced without providing a dedicated attachment device.

  In the present embodiment, the valve casing is made of resin, but is not limited to this, and may be made of aluminum, for example. Moreover, although the body part of the valve casing is made of polyphenylene sulfide resin reinforced with glass fiber, it is not limited to this, and a known resin material such as polyether ether ketone (PEEK) can be used.

  In the present embodiment, the attachment member is a gas-liquid separator. However, the present invention is not limited to this, and any component / device may be provided in the pipe between the fuel gas outlet of the fuel cell and the dilution device.

  In addition, the valve body actuating device is an electromagnetic solenoid, but is not limited thereto, and may be a linear motor, an actuator using air pressure or hydraulic pressure, for example.

  A second embodiment in which the gas exhaust / drain valve of the embodiment of the present invention is used in a fuel cell system will be described below with reference to FIG. In the exhaust drain valve 155 for the fuel cell according to the present embodiment, an introduction opening 157 communicating with the fuel gas discharge port 63 is provided at the tip of the first gas-liquid circulation part 88, and the tip of the second gas-liquid circulation part 89. Is provided with a discharge opening 159 communicating with the diluting device 56 side. A face seal member 161 is provided between the end face of the discharge opening 159 and the step provided in the second fitting hole 89b. Since these points are different from the first embodiment and the other configurations are the same, the same reference numerals are given and the description is omitted.

  According to the exhaust drainage valve 155 configured as described above, when the exhaust wastewater valve 155 is assembled to the gas-liquid separator 54, the first fitting portion (first seal portion) 88b of the exhaust drainage valve 155 and the second fitting are provided. Even when the coaxial accuracy with the joint portion (second seal portion) 89b is low, the second fitting portion is provided by the face seal member 161 provided on the end face of the discharge opening 159 at the tip of the second gas-liquid circulation portion 89. Since the space between 89b and the second fitting hole 93 is pressed and sealed in the axial direction of the second fitting portion, the sealing can be ensured.

  In the present embodiment, the face seal member 161 provided on the end face of the discharge opening 159 of the second gas-liquid circulation part 29 provides a gap between the second fitting part 89b and the second fitting hole 93. However, the present invention is not limited to this. For example, the first fitting is performed by a face seal member provided on the end face of the introduction opening at the tip of the first gas-liquid circulation part. It may be sealed by pressing between the joint portion and the first fitting hole in the axial direction of the first fitting portion.

  Thus, the specific configuration described in the above-described embodiment is merely an example of the present invention, and the present invention is not limited to such a specific configuration. Various embodiments can be adopted without departing from the scope.

DESCRIPTION OF SYMBOLS 6 ... Fuel cell (battery stack), 54 ... Mounting member (gas-liquid separator), 54a ... Case, 55 ... Exhaust drain valve, 56 ... Dilution device, 63 ... Fuel gas discharge port, 82 ... Valve casing, 88 ... 1st gas-liquid circulation part, 88a ... primary flow path, 88b ... 1st fitting part, 89 ... 2nd gas-liquid circulation part, 89a ... secondary flow path, 89b ... 2nd fitting part, 90 ... 1st Seal member (first shaft seal member), 91 ... second seal member (second shaft seal member), 92 ... first fitting hole, 93 ... second fitting hole, 95 valve seat, 97 ... valve body, 97a DESCRIPTION OF SYMBOLS ... Valve part, 98 ... Valve shaft (plunger), 99 ... Valve body operating device (sleeve), 101 ... Valve body operating device (solenoid), 106 ... Valve body operating device (bobbin), 106 ... Valve body operating device (core) Member), 155 ... exhaust drain valve, 157 ... introduction opening, 159 ... discharge opening, 161 ... face seal Wood.

Claims (5)

An exhaust drain valve that communicates with a fuel gas discharge port of the fuel cell and blocks or allows the fuel gas and generated water discharged from the fuel gas discharge port to flow out to a diluting device that dilutes the fuel gas;
The exhaust drain valve is
A first gas-liquid circulation part provided in a valve casing, in which a primary flow passage is formed which communicates with the fuel gas discharge port and through which the fuel gas discharged from the fuel gas discharge port and generated water flow;
The second gas is provided in the valve casing, is formed around the first gas-liquid circulation part, and is formed so that a secondary flow passage communicating with the dilution device side surrounds the first gas-liquid circulation part. A liquid distribution department;
A first seal part provided in the first gas-liquid circulation part and provided with a first seal member for sealing between the first gas-liquid circulation part and an attachment member to which the exhaust drainage valve is attached;
A second seal part provided in the second gas-liquid circulation part and provided with a second seal member for sealing between the second gas-liquid circulation part and the mounting member;
A valve seat interposed between the primary flow passage and the secondary flow passage and formed in an annular shape;
A valve body in which a valve portion that moves forward and backward with respect to the valve seat and that can contact and separate from the valve seat is formed;
A valve shaft fixed to the valve body;
A valve body actuating device for moving the valve body between a closed position where the valve portion abuts on the valve seat and a spaced position where the valve portion is separated from the valve seat;
When the valve shaft is urged with a predetermined urging force in a direction in which the valve portion is pressed against the valve seat, and the valve body actuating device moves the valve portion to the closed position, the valve portion is An elastic member that contacts the valve seat and separates the valve portion from the valve seat when the pressure applied to the primary flow passage exceeds a predetermined valve opening pressure;
Exhaust drain valve for fuel cell with   2. The exhaust drain valve for a fuel cell according to claim 1, wherein the valve casing is made of resin. In claim 1 or 2,
A support wall for fixing the first gas-liquid circulation part and the second gas-liquid circulation part to each other;
The first seal portion is a cylindrical first fitting portion that is provided with a stepped portion on which the first seal member is provided and is fitted in a first fitting hole formed in the mounting member. ,
The second seal portion has a stepped portion on which the second seal member is provided and is coaxially formed with a larger diameter than the first fitting portion, and is formed on the mounting member. It is a cylindrical second fitting portion that fits into the fitting hole,
The first seal member is provided on an outer periphery of the first fitting portion, and seals between an outer peripheral surface of the first fitting portion and an inner peripheral surface of the first fitting hole of the mounting member. A shaft seal member,
The second seal member is provided on an outer periphery of the second fitting portion and seals between an outer peripheral surface of the second fitting portion and an inner peripheral surface of a second fitting hole formed in the attachment member. An exhaust drain valve for a fuel cell which is a second shaft seal member. In Claim 1 or 2, an introduction opening part connected to the fuel gas discharge port of the fuel cell is provided in a tip part of the first gas-liquid circulation part of the primary flow passage,
A discharge opening communicating with the diluting device is provided at the tip of the second gas-liquid circulation portion disposed around the primary flow passage.
At least one of the first seal member and the second seal member is a surface seal member that seals between the end surface of the introduction opening and the mounting member or between the end surface of the discharge opening and the mounting member. An exhaust drain valve for a fuel cell.   5. The fuel cell according to claim 1, wherein the mounting member is a casing of a gas-liquid separator provided between a fuel gas discharge port of the fuel cell and the exhaust drain valve. Exhaust drain valve.

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