JP6091928B2 - Cochineal pigment preparation - Google Patents
Cochineal pigment preparation Download PDFInfo
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- JP6091928B2 JP6091928B2 JP2013041549A JP2013041549A JP6091928B2 JP 6091928 B2 JP6091928 B2 JP 6091928B2 JP 2013041549 A JP2013041549 A JP 2013041549A JP 2013041549 A JP2013041549 A JP 2013041549A JP 6091928 B2 JP6091928 B2 JP 6091928B2
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- cochineal
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- 239000004106 carminic acid Substances 0.000 title claims description 67
- 235000012730 carminic acid Nutrition 0.000 title claims description 67
- 229940080423 cochineal Drugs 0.000 title claims description 66
- 238000002360 preparation method Methods 0.000 title claims description 50
- 239000000049 pigment Substances 0.000 title claims description 46
- 229940023462 paste product Drugs 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- 244000144972 livestock Species 0.000 claims description 9
- 238000013508 migration Methods 0.000 claims description 9
- 230000005012 migration Effects 0.000 claims description 9
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 8
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 8
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 8
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 description 15
- 238000004040 coloring Methods 0.000 description 12
- 235000013372 meat Nutrition 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 235000021317 phosphate Nutrition 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 7
- 235000019799 monosodium phosphate Nutrition 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 6
- 238000004804 winding Methods 0.000 description 6
- 241000257465 Echinoidea Species 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229960005069 calcium Drugs 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 4
- 235000019801 trisodium phosphate Nutrition 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 3
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 3
- 235000019798 tripotassium phosphate Nutrition 0.000 description 3
- 241000473391 Archosargus rhomboidalis Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000238413 Octopus Species 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 2
- 239000001527 calcium lactate Substances 0.000 description 2
- 229960002401 calcium lactate Drugs 0.000 description 2
- 235000011086 calcium lactate Nutrition 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000001394 sodium malate Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 229940078499 tricalcium phosphate Drugs 0.000 description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 description 2
- 241000238557 Decapoda Species 0.000 description 1
- 241000251511 Holothuroidea Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 241000485664 Protortonia cacti Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- -1 acidulants Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229940103272 aluminum potassium sulfate Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- DGQLVPJVXFOQEV-NGOCYOHBSA-N carminic acid Chemical compound OC1=C2C(=O)C=3C(C)=C(C(O)=O)C(O)=CC=3C(=O)C2=C(O)C(O)=C1[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O DGQLVPJVXFOQEV-NGOCYOHBSA-N 0.000 description 1
- 229940114118 carminic acid Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013622 meat product Nutrition 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Fish Paste Products (AREA)
- Meat, Egg Or Seafood Products (AREA)
Description
本発明は、コチニール色素製剤に関する。 The present invention relates to a cochineal pigment preparation.
コチニール色素は、耐熱性・耐光性に優れ、明るい赤色に着色できるため、かまぼこや魚肉ソーセージに代表される畜肉水産練り製品の着色に広く用いられている。畜肉水産練り製品の中でも、カマボコやなると巻きなどはコチニール色素により部分的に赤色に着色されることが多く、このような製品は、その製造途中または保存中に着色部分から非着色部分へ色素が移行し外観が劣化する現象（いわゆる色流れ、色移り、色にじみ等）が発生し易いという問題があった。 Cochineal pigments are excellent in heat resistance and light resistance and can be colored bright red, and are therefore widely used for coloring livestock and fishery products such as kamaboko and fish sausage. Among the meat and fishery products, the sea urchins are often colored partially red by the cochineal pigment, and the color of these products migrates from the colored part to the non-colored part during production or storage. However, there is a problem that the appearance is deteriorated (so-called color flow, color transfer, color blur, etc.).
この問題に対し、食用色素と、粉末状の難溶性カルシウム含有物質の混合物よりなる着色剤（特許文献１）、コチニール色素と、リン酸三ナトリウムおよび／またはリン酸三カリウムを含有した着色料製剤を用いて畜肉水産練り製品を着色することを特徴とする、畜肉水産練り製品の色流れおよび／または色移り防止方法（特許文献２）等が提案されている。 In order to solve this problem, a coloring agent comprising a food coloring material and a powdery mixture of a hardly soluble calcium-containing substance (Patent Document 1), a cochineal coloring material, trisodium phosphate and / or tripotassium phosphate A method for preventing color migration and / or color migration of a livestock and fishery product, characterized by coloring a livestock and fishery product using a rice bran has been proposed.
しかし、特許文献１に記載の着色剤は、色素の移行の抑制効果が弱く、実用上満足できるものではなかった。また、特許文献２に記載の方法は、リン酸三ナトリウム等を有効成分として畜肉水産練り製品の色流れ等を防止するものであるが、その効果をさらに高めるために着色料製剤中のリン酸三ナトリウム等の配合量を高めると、その使用の際に塩析等による色素成分の析出が生じ、均一な着色が困難になる場合がある。即ち、特許文献２に記載の方法では、畜肉水産練り製品の均一な着色と色素の移行の抑制との両立に難があった。 However, the colorant described in Patent Document 1 has a weak effect of suppressing the migration of the dye, and is not satisfactory in practical use. In addition, the method described in Patent Document 2 is intended to prevent color flow and the like of livestock and fishery products by using trisodium phosphate as an active ingredient. In order to further enhance the effect, triphosphate in a colorant preparation is used. When the blending amount of sodium or the like is increased, pigment components may precipitate due to salting out during use, and uniform coloring may be difficult. That is, in the method described in Patent Document 2, it is difficult to achieve both the uniform coloring of the meat and fishery paste product and the suppression of pigment migration.
本発明は、畜肉水産練り製品の均一な着色が可能であり、且つ畜肉水産練り製品を部分的に赤色に着色する場合の色素の移行が抑制可能なコチニール色素製剤を提供することを目的とする。 An object of the present invention is to provide a cochineal pigment preparation capable of uniformly coloring livestock and fishery paste products and capable of suppressing migration of pigment when the livestock and fishery paste products are partially colored red.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、特定のリン酸塩類を配合したコチニール色素製剤により、上記課題が解決されることを見出し、本発明を完成した。
即ち、本発明は、
（１）リン酸水素二ナトリウム、リン酸二水素ナトリウム、リン酸水素二カリウム及びリン酸二水素カリウムの群から選ばれる１種又は２種以上を含有することを特徴とするコチニール色素製剤、
（２）前記（１）に記載のコチニール色素製剤を用いて着色してなることを特徴とする畜肉水産練り製品、
からなっている。
As a result of intensive studies to solve the above problems, the present inventor has found that the above problems can be solved by a cochineal pigment preparation containing a specific phosphate, and has completed the present invention.
That is, the present invention
(1) Cochineal dye preparation characterized by containing one or more selected from the group consisting of disodium hydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate and potassium dihydrogen phosphate,
(2) A meat and fishery paste product characterized by being colored using the cochineal pigment preparation according to (1),
It is made up of.
本発明のコチニール色素製剤によれば、畜肉水産練り製品を均一に着色できる。
本発明のコチニール色素製剤を用いて部分的に着色した畜肉水産練り製品は、着色部分から非着色部分への色素の移行が抑制されている。
According to the cochineal pigment preparation of the present invention, it is possible to uniformly color livestock and fishery products.
The animal meat and fishery paste product partially colored using the cochineal pigment preparation of the present invention has suppressed migration of the pigment from the colored portion to the non-colored portion.
本発明のコチニール色素製剤は、少なくともコチニール色素と、リン酸水素二ナトリウム、リン酸二水素ナトリウム、リン酸水素二カリウム及びリン酸二水素カリウムの群から選ばれる１種又は２種以上（以下、「本発明に係るリン酸塩」ともいう）とを含有する。 The cochineal dye preparation of the present invention is at least one cochineal dye and one or more selected from the group of disodium hydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate and potassium dihydrogen phosphate (hereinafter, (Also referred to as “phosphate according to the present invention”).
本発明で用いられるコチニール色素は、アントラキノン系色素のカルミン酸を主成分とする赤色素であって、カイガラムシ科エンジムシ（Ｃｏｃｃｕｓ ｃａｃｔｉ Ｌ．）の乾燥体より、水及び／又はアルコールで抽出することにより得られる。コチニール色素の形態としては、コチニール色素を含有する水及び／又はアルコール溶液を自体公知の方法で粉末化したコチニール色素粉末であることが好ましい。コチニール色素粉末としては、例えばＣＡ−９０（商品名；クリスチャンハンセン社製）等が商業的に製造・販売されており、本発明ではこれらを用いることができる。 The cochineal pigment used in the present invention is a red pigment mainly composed of anthraquinone pigment carminic acid, and is extracted from a dried body of Coccus cacti L. with water and / or alcohol. can get. The form of the cochineal dye is preferably a cochineal dye powder obtained by pulverizing a water and / or alcohol solution containing a cochineal dye by a method known per se. As the cochineal pigment powder, for example, CA-90 (trade name; manufactured by Christian Hansen) and the like are commercially manufactured and sold, and these can be used in the present invention.
本発明で用いられるリン酸水素二ナトリウム、リン酸二水素ナトリウム、リン酸水素二カリウム及びリン酸二水素カリウムとしては、一般に市場で流通しているものであれば特に制限はない。本発明のコチニール色素製剤は、これらのリン酸塩のうち１種又は２種以上を含有するものであれば特に制限はないが、コチニール色素製剤の使用時にコチニール色素の水溶液を調製する場合（後述する）において、該水溶液の液性をｐＨ６．５〜７．５の中性付近に保つ必要があるときは、（１）リン酸水素二ナトリウム及びリン酸二水素ナトリウムの２種、（２）リン酸水素二ナトリウム及びリン酸二水素カリウムの２種、（３）リン酸水素二カリウム及びリン酸二水素ナトリウムの２種、又は（４）リン酸水素二カリウム及びリン酸二水素カリウムの２種を含有するコチニール色素製剤であることが好ましい。上記水溶液の液性を中性付近に保つことにより、カマボコ等を着色する場合に、それ特有の弾力ある食感を損なう虞が少ないため好ましい。 The disodium hydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate and potassium dihydrogen phosphate used in the present invention are not particularly limited as long as they are generally distributed in the market. The cochineal dye preparation of the present invention is not particularly limited as long as it contains one or more of these phosphates, but when an aqueous solution of a cochineal dye is prepared when the cochineal dye preparation is used (described later). When the liquidity of the aqueous solution needs to be kept near neutral pH 6.5 to 7.5, (1) two types of disodium hydrogen phosphate and sodium dihydrogen phosphate, (2) 2 types of disodium hydrogen phosphate and potassium dihydrogen phosphate, (3) 2 types of dipotassium hydrogen phosphate and sodium dihydrogen phosphate, or (4) 2 types of dipotassium hydrogen phosphate and potassium dihydrogen phosphate It is preferably a cochineal pigment preparation containing seeds. It is preferable to keep the liquidity of the aqueous solution near neutral, since there is little possibility of damaging the unique elastic texture when coloring oysters or the like.
本発明のコチニール色素製剤は、上述のコチニール色素及び本発明に係るリン酸塩の他に、本発明の効果を妨げない範囲において、従来コチニール色素製剤に使用されている硫酸アルミニウムカリウム（ミョウバン）、有機酸及びこれらの塩類、カルシウム塩類をはじめ、他の着色料、甘味料、酸味料、保存料、酸化防止剤、蛋白、アミノ酸及び糖類等通常色素製剤に使用されている成分を添加し、自体公知の方法により調製することができる。 In addition to the above-mentioned cochineal dye and the phosphate according to the present invention, the cochineal dye preparation of the present invention, in a range that does not interfere with the effects of the present invention, aluminum potassium sulfate (alum) conventionally used in cochineal dye preparations, In addition to organic acids and their salts, calcium salts, other colorants, sweeteners, acidulants, preservatives, antioxidants, proteins, amino acids, saccharides and other ingredients that are usually used in pigment preparations, add themselves It can be prepared by a known method.
具体的には、例えばデキストリン、乳糖、粉末水飴等を担体（賦形剤）とし、これをコチニール色素の溶液又は粉末に配合し、粉状、顆粒状、錠剤状又は丸剤状等に成形してなる乾燥（固形）状態の色素製剤として調製することができる。 Specifically, for example, dextrin, lactose, powdered syrup or the like is used as a carrier (excipient), and this is blended with a solution or powder of cochineal pigment, and formed into a powder, granule, tablet, pill, or the like. It can be prepared as a pigment preparation in a dry (solid) state.
本発明のコチニール色素製剤１００質量％中のコチニール色素及び本発明に係るリン酸塩の含有量に特に制限はないが、コチニール色素（色価１５００換算）が通常０．０５〜１０質量％、好ましくは０．１〜５質量％であり、本発明に係るリン酸塩が通常１〜５０質量％、好ましくは３〜４０質量％である。本発明に係るリン酸塩の含有量がこのような範囲であると、畜肉水産練り製品を均一に着色する効果と畜肉水産練り製品を部分的に赤色に着色する場合において色素の移行を抑制する効果がともに十分に発揮されるため好ましい。 The content of the cochineal dye and the phosphate according to the present invention in 100% by mass of the cochineal dye preparation of the present invention is not particularly limited, but the cochineal dye (color value 1500 conversion) is usually 0.05 to 10% by mass, preferably Is 0.1 to 5% by mass, and the phosphate according to the present invention is usually 1 to 50% by mass, preferably 3 to 40% by mass. When the phosphate content according to the present invention is within such a range, the effect of uniformly coloring the meat and fishery paste product and the effect of suppressing the migration of the pigment when the meat and fishery paste product is partially colored red. Both are preferable because they are sufficiently exhibited.
本発明のコチニール色素製剤により部分的に着色した畜肉水産練り製品は、着色部分から非着色部分への色素の移行（色流れ、色移り、色にじみ等）が抑制されるため、本発明のコチニール色素製剤は、部分的に赤色に着色してなるカマボコ（例えば、板付きカマボコ、カニ足又はエビの外観を模して製造されるカニ足様カマボコ又はエビ様カマボコ等）やなると巻き等の着色に好ましく使用できる。 The animal meat and fishery kneaded product partially colored with the cochineal pigment preparation of the present invention suppresses the migration (color flow, color transfer, color bleeding, etc.) of the pigment from the colored portion to the non-colored portion. The preparation is partially colored red, such as crab feet with a plate, crab foot-like crab feet or shrimp-like crab feet manufactured to mimic the appearance of shrimp, etc. It can be preferably used.
本発明のコチニール色素製剤の使用方法に特に制限はないが、畜肉水産練り製品を着色する場合には、あらかじめコチニール色素製剤に約１５〜９５℃の水を加えて撹拌・溶解し、コチニール色素の水溶液を調製した後に、該水溶液を畜肉水産練り製品に添加することが好ましい。添加方法としては、例えば、コチニール色素の水溶液を畜肉水産練り製品に噴霧又は塗布する、或いはコチニール色素の水溶液を畜肉水産練り製品の素材に練り込み調製する等、自体公知の方法を任意に採用することができる。また、コチニール色素製剤の添加量は、コチニール色素製剤の使用対象である畜肉水産練り製品の形態やコチニール色素製剤の色価等により異なり一様ではないが、例えば、畜肉水産練り製品１００質量％に対し、通常約０．０１〜５．０質量％、好ましくは約０．０２〜３．０質量％となるように添加することができる。 The method of using the cochineal pigment preparation of the present invention is not particularly limited. However, when coloring livestock fisheries paste products, water of about 15 to 95 ° C. is added to the cochineal pigment formulation in advance and stirred and dissolved to obtain an aqueous solution of cochineal pigment. After the preparation, it is preferable to add the aqueous solution to the meat product. As the addition method, for example, an aqueous solution of cochineal dye can be sprayed or applied to an animal meat and fishery paste product, or an aqueous solution of cochineal dye can be arbitrarily kneaded and prepared in an animal meat and fishery paste product. it can. Further, the amount of the cochineal pigment preparation added varies depending on the form of the animal meat and fishery paste product to be used for the cochineal pigment preparation and the color value of the cochineal pigment preparation and is not uniform, for example, for 100% by mass of the meat and fishery paste product, Usually, it can be added so that it may become about 0.01-5.0 mass%, Preferably it is about 0.02-3.0 mass%.
以下に本発明を実施例に基づいてより具体的に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described more specifically based on examples, but the present invention is not limited thereto.
［コチニール色素製剤の調製］
（１）原材料
１）コチニール色素粉末（商品名：ＣＡ−９０；クリスチャンハンセン社製；色価１５００）
２）リン酸水素二ナトリウム（商品名：リン酸水素二ナトリウム（無水）；太平化学産業社製）
３）リン酸二水素ナトリウム（商品名：リン酸二水素ナトリウム（無水）；太平化学産業社製）
４）リン酸水素二カリウム（商品名：リン酸水素二カリウム；太平化学産業社製）
５）リン酸二水素カリウム（商品名：リン酸二水素カリウム；太平化学産業社製）
６）リン酸三ナトリウム（商品名：リン酸三ナトリウム（無水）；太平化学産業社製）
７）リン酸三カリウム（商品名：リン酸三カリウム；太平化学産業社製）
８）リン酸三カルシウム（商品名：リン酸三カルシウム；太平化学産業社製）
９）炭酸カルシウム（商品名：コロカルソーＥＸ；白石カルシウム社製）
１０）貝殻焼成カルシウム（商品名：貝殻焼成カルシウム；カワイマテリアル社製）
１１）乳酸カルシウム（商品名：乳酸カルシウム；太平化学産業社製）
１２）硫酸アルミニウムカリウム（商品名：タイエースＫ−１５０；大明化学工業社製）
１３）リンゴ酸ナトリウム（商品名：ＤＬ−リンゴ酸ナトリウム；扶桑化学工業社製）
１４）デキストリン（商品名：サンデック＃３００；三和澱粉工業社製）
[Preparation of cochineal pigment preparation]
(1) Raw materials 1) Cochineal pigment powder (trade name: CA-90; manufactured by Christian Hansen; color value 1500)
2) Disodium hydrogen phosphate (trade name: disodium hydrogen phosphate (anhydrous); manufactured by Taihei Chemical Industry Co., Ltd.)
3) Sodium dihydrogen phosphate (trade name: sodium dihydrogen phosphate (anhydrous); manufactured by Taihei Chemical Industry Co., Ltd.)
4) Dipotassium hydrogen phosphate (trade name: Dipotassium hydrogen phosphate; manufactured by Taihei Chemical Industry Co., Ltd.)
5) Potassium dihydrogen phosphate (trade name: potassium dihydrogen phosphate; manufactured by Taihei Chemical Industrial Co., Ltd.)
6) Trisodium phosphate (trade name: trisodium phosphate (anhydrous); manufactured by Taihei Chemical Industry Co., Ltd.)
7) Tripotassium phosphate (trade name: Tripotassium phosphate; manufactured by Taihei Chemical Industry Co., Ltd.)
8) Tricalcium phosphate (trade name: Tricalcium phosphate; manufactured by Taihei Chemical Industrial Co., Ltd.)
9) Calcium carbonate (trade name: CoroCalso EX; manufactured by Shiroishi Calcium)
10) Calcined shell calcium (trade name: calcined shell calcium; manufactured by Kawai Materials)
11) Calcium lactate (trade name: calcium lactate; manufactured by Taihei Chemical Industrial Co., Ltd.)
12) Potassium aluminum sulfate (trade name: Taiace K-150; manufactured by Daimei Chemical Industry Co., Ltd.)
13) Sodium malate (trade name: DL-sodium malate; manufactured by Fuso Chemical Industries)
14) Dextrin (trade name: Sandeck # 300; manufactured by Sanwa Starch Co., Ltd.)
（２）製剤の配合
上記原材料を用いて調製したコチニール色素製剤１〜７の配合組成を表１に示した。この内、製剤１〜５は本発明に係る実施例であり、製剤６及び７はそれに対する比較例である。なお、これらのコチニール色素製剤は、製剤６を除き、リン酸塩の配合割合を同一に調整した。
(2) Formulation of formulation Table 1 shows the formulation composition of cochineal pigment formulations 1-7 prepared using the above raw materials. Among these, the preparations 1 to 5 are examples according to the present invention, and the preparations 6 and 7 are comparative examples. In these cochineal pigment preparations, except for the preparation 6, the blending ratio of phosphate was adjusted to be the same.
（３）コチニール色素製剤の調製方法
表１に示した原材料の配合割合に基づいて、全ての原材料を均一に混合し、粉状のコチニール色素製剤１〜７各１００ｇを調製した。
(3) Preparation Method of Cochineal Dye Formulation Based on the mixing ratio of the raw materials shown in Table 1, all the raw materials were mixed uniformly to prepare 100 g of powdery cochineal pigment preparations 1 to 7 each.
［試験例１］
［カマボコの着色試験］
（１）コチニール色素水溶液の調製
コチニール色素製剤１〜７各２０ｇに６０℃の水４０ｇを加え、同温度の温水浴中でマグネチックスターラーを用いて、２時間攪拌・溶解し、コチニール色素水溶液を得た。なお、得られたコチニール色素水溶液のうち、比較例のコチニール色素製剤７を用いたものは、コチニール色素が析出したため濃赤色の沈殿物が見られたが、その他のものでは、そのような沈殿物は見られなかった。
[Test Example 1]
[Kamaboko coloring test]
(1) Preparation of Cochineal Dye Aqueous Solution 40 g of water at 60 ° C. is added to 20 g of each of Cochineal Dye Formulations 1 to 7, and stirred and dissolved in a warm water bath at the same temperature for 2 hours to obtain a cochineal dye aqueous solution. Obtained. Of the obtained cochineal dye aqueous solutions, those using the cochineal dye preparation 7 of the comparative example showed a dark red precipitate because the cochineal dye was precipitated, but in other cases, such a precipitate was used. Was not seen.
（２）カマボコの調製
表２の配合割合に従い、解凍した冷凍魚肉すり身とその他の各原材料をサイレントカッターに入れ、らい潰・調味し、カマボコベースを得た。このカマボコベース１００質量部に対し、水１０質量部及び上記（１）のコチニール色素水溶液３．６質量部を各々加えてゴムベラで均一になるまで混合してカマボコベースを着色した。
続いて、着色したカマボコベースを耐熱性フィルム上に厚さ２ｍｍに塗布し、スチームオーブンにて９５℃で３０分間蒸煮した後、冷却し、着色カマボコを得た。
一方、上記と同様に調製したカマボコベースを着色せずに箱型のステンレス枠に充填して厚さ２０ｍｍに成形し、これをスチームオーブンにて９５℃で３０分間蒸煮した後冷却し、無着色カマボコを得た。
得られた無着色カマボコに、上記着色カマボコを載せ、ポリ袋に入れて真空パックした。これを４０℃の恒温槽に入れ、一昼夜静置後に取り出し、部分的に着色したカマボコ１〜７を得た。
(2) Preparation of Camaboko According to the blending ratio in Table 2, the thawed frozen fish paste and other raw materials were put into a silent cutter, crushed and seasoned, and a Camaboko base was obtained. 10 parts by weight of water and 3.6 parts by weight of the aqueous cochineal dye solution (1) above were added to 100 parts by weight of this sea bream base, and mixed with a rubber spatula until uniform, to color the sea bream base.
Subsequently, a colored kamaboko base was applied on a heat-resistant film to a thickness of 2 mm, steamed in a steam oven at 95 ° C. for 30 minutes, and then cooled to obtain a colored kamaboko.
On the other hand, Kamaboko base prepared in the same manner as above was filled in a box-shaped stainless steel frame without coloring and molded to a thickness of 20 mm. This was steamed in a steam oven at 95 ° C. for 30 minutes, cooled, and uncolored. I got a sea urchin.
The above-mentioned uncolored octopus was placed on the above colored octopus, placed in a plastic bag and vacuum-packed. This was put into a 40 degreeC thermostat, and it took out after leaving still for one day and night, and obtained partially colored sea cucumbers 1-7.
（３）評価方法及び結果
カマボコ１〜７について着色部分（着色カマボコの部分）を目視にて観察し、色むらを評価した。続いて、これらの着色部分を除去し、残った無着色カマボコの表面を目視にて観察し、色流れを評価した。結果を表３に示す。
(3) Evaluation method and result About the colored shells 1-7, the colored part (colored colored shell part) was observed visually, and the color unevenness was evaluated. Subsequently, these colored portions were removed, and the surface of the remaining uncolored sea urchin was visually observed to evaluate the color flow. The results are shown in Table 3.
表３の結果から、本発明のコチニール色素製剤１〜５の使用により、カマボコを色むらなく均一に着色することができると共に、カマボコを部分的に着色した際の色流れが抑制されることが明らかである。これに対し、比較例のコチニール色素製剤６及び７では色流れが確認された。特に、比較例のコチニール色素製剤７は、水溶液の調製時に生じた色素の沈殿物がかまぼこの蒸煮時に溶解して色むらとなり、その商品価値が著しく低下していた。 From the results in Table 3, the use of the cochineal pigment preparations 1 to 5 of the present invention can uniformly color the sea urchin without uneven color, and the color flow when the sea urchin is partially colored is suppressed. it is obvious. On the other hand, color flow was confirmed in the cochineal pigment preparations 6 and 7 of the comparative examples. In particular, in the cochineal pigment preparation 7 of the comparative example, the pigment precipitate generated during the preparation of the aqueous solution was dissolved when the kamaboko was cooked, resulting in uneven color, and the commercial value was significantly reduced.
［試験例２］
［なると巻きの着色試験］
（１）コチニール色素水溶液の調製
コチニール色素製剤１、６及び７各２０ｇに６０℃の水４０ｇを加え、同温度の温水浴中でマグネチックスターラーを用いて、２時間攪拌・溶解し、コチニール色素水溶液を得た。なお、得られたコチニール色素水溶液のうち、比較例のコチニール色素製剤７を用いたものは、コチニール色素が析出したため濃赤色の沈殿物が見られたが、その他のものには、そのような沈殿物は見られなかった。
[Test Example 2]
[Natural winding coloring test]
(1) Preparation of Cochineal Dye Aqueous Solution Cochineal Dye Formulations 1, 6 and 7 40 g of water at 60 ° C. is added to 20 g of each, and the mixture is stirred and dissolved in a warm water bath at the same temperature for 2 hours. An aqueous solution was obtained. In addition, among the obtained cochineal dye aqueous solutions, those using the cochineal dye preparation 7 of the comparative example showed a dark red precipitate because the cochineal dye was precipitated. Nothing was seen.
（２）なると巻きの調製
表４の配合割合に従い、解凍した冷凍魚肉すり身とその他の各原材料をサイレントカッターに入れ、らい潰・調味し、なると巻きベースを得た。次に、なると巻きベース１００質量部に対し、（１）のコチニール色素水溶液３．６質量部を各々加えてゴムベラで均一になるまで混合してなると巻きベースを着色した。
続いて、着色したなると巻きベースと、無着色のなると巻きベース（即ち、上記と同様に調製したなると巻きベースであって着色していないもの）とを巻き合わせ、スチームオーブンにて９５℃で１５分間蒸煮した後、冷却した。これをポリ袋に真空包装し、９０℃の温水中で２０分間加熱殺菌した後、冷却してなると巻き１〜３を得た。
(2) Preparation of the winding according to the blending ratio in Table 4 The frozen frozen fish meat and other raw materials were put into a silent cutter, crushed and seasoned, and then a winding base was obtained. Next, 3.6 parts by mass of the aqueous cochineal dye solution (1) was added to 100 parts by mass of the winding base and mixed until uniform with a rubber spatula to color the winding base.
Subsequently, the wound base is colored and the wound base is uncolored (that is, the wound base is not colored when prepared in the same manner as described above), and 15% at 95 ° C. in a steam oven. Steamed for a minute and then cooled. This was vacuum-packed in a plastic bag, heat-sterilized in 90 ° C. warm water for 20 minutes, and then cooled to obtain rolls 1 to 3.
（３）評価方法及び結果
なると巻き１〜３をカットし、その切断面に現れた渦巻き状の着色を目視にて観察し、色むら及び色にじみを評価した。結果を表５に示す。
(3) Evaluation method and result The windings 1 to 3 were cut, and the spiral coloration that appeared on the cut surface was observed with the naked eye to evaluate the color unevenness and the color blur. The results are shown in Table 5.
表５の結果から、本発明のコチニール色素製剤１の使用により、なると巻きの色むら及び色にじみが抑制されることが明らかである。これに対し、比較例のコチニール色素製剤６及び７を使用したものは、いずれかの評価項目において本発明のものに比べて劣っていた。特に、比較例のコチニール色素製剤７は、水溶液の調製時に生じた色素の沈殿物がなると巻の蒸煮時に溶解して色むらとなり、その商品価値が著しく低下していた。 From the results of Table 5, it is clear that the use of the cochineal pigment preparation 1 of the present invention suppresses uneven color unevenness and color bleeding. On the other hand, those using the cochineal pigment preparations 6 and 7 of the comparative example were inferior to those of the present invention in any of the evaluation items. In particular, when the cochineal pigment preparation 7 of the comparative example is a pigment precipitate generated during the preparation of the aqueous solution, it dissolves during the steaming of the roll and becomes uneven in color, and its commercial value is significantly reduced.
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