JP6061627B2 - Fly larvae control agent and fly larvae control method using the same - Google Patents

Description

The present invention relates to a fly eye larva control agent, particularly a fly eye larva control agent for treatment in a small water system of a general household, such as drainage of a drain outlet or a flowerpot, and a fly eye larva control method using the same. .

Pest control methods include source control and adult control for eggs and larvae of pests. The former is an attempt to eliminate pests in total, mainly by municipalities and contractors, and it can be said that it is an efficient method if it is made as planned, but in reality this method completely eradicates eggs and larvae. Is impossible, and the current situation is to leave the pests that are generated to the latter.
For example, juvenile hormones are used for combating larvae such as septic tanks, but their effects are generally very slow, and they are not easy to use for personal control in ordinary households. Thus, until now, pest control agents for pest eggs and larvae have been unfamiliar in general households.

By the way, countermeasures against pests that occur in small water systems of general households, such as butterflies that occur under drain outlets and unit baths, mosquitoes that originate from the drainage of flower pots, and the like, are required. In the past, it was common to control adult worms using transpiration agents or sprays, but this is not always effective. On the other hand, as described above, prevention agents for home use There was not.
However, the present inventors conducted various tests on the premise that the prevention agent is effective when controlling the insect pests generated in the small water systems of general households, particularly fly larvae. It is necessary to obtain a knockdown effect in a shorter time than when treating a septic tank, and it is also important to keep the source itself clean so that adults sporadically enter the house and propagate. I found out. In addition, after that, the use of the bleaching component was recognized to be extremely useful and the present invention was completed, but the technical idea of applying the bleaching component to immediate pest control rather than microorganisms is completely new. .

For example, Japanese Patent Application Laid-Open No. 9-30912 (Patent Document 1) describes that soil nematodes and the like can be controlled by irrigating ozone-dissolved water and / or hydrogen peroxide water into the soil. Also, Japanese Patent No. 2811512 is rich in oxygen, such as a hydrogen peroxide solution, with a hole at a predetermined height of a standing tree, with respect to the one where the worm has propagated on the trunk of the standing tree, etc. Disclosed are pest control methods for trees that control harmful microorganisms by injecting the solution into the trunk, but these are all intended to improve the environment over a long period of time, and are intended to be effective immediately The technical idea is different from fly larvae control.

Japanese Patent Laid-Open No. 9-30912 Japanese Patent No. 2811512

The present invention eliminates the source of fly larvae based on the excellent knockdown effect that is manifested in a short time of treatment when treating small water systems such as drains of general households and drainage of flower pots. An object of the present invention is to provide a fly larva control agent that can clean the source itself and prevent the occurrence of fly larvae, and a fly larva control method using the same.

The present invention has been found that the following constitution has an excellent effect for achieving the above-mentioned object.
(1) Oxygen-based bleaching component (excluding peroxycarboxylic acid) containing 0.1-30 w / v% hydrogen peroxide (0.1-30 w / w% in the case of solid preparation) as hydrogen peroxide relative to the total amount of the preparation, or A surfactant is added as a knockdown active ingredient, and as an insecticidal ingredient, one or more selected from etofenprox, silafluophene, dinotefuran, imidacloprid, clothianidin and acetamiprid are blended. Flyfly larvae control agent.
(2) The fly larva control according to (1), wherein the oxygen bleaching component is at least one selected from hydrogen peroxide adducts, hydrogen peroxide water, or oxygen bleach that is hydrogen persulfate. Agent.
(3) The fly larva control agent according to (2), wherein the hydrogen peroxide adduct is at least one selected from percarbonate, perborate, and urea peroxide.
(4) The fly eye larva control agent according to any one of (1) to (3), wherein the surfactant is an anionic surfactant and / or an amphoteric surfactant.
(5) before SL (1) to (4) Diptera larvae disinfection method of the aqueous treating the Diptera larvicides according to any one of the.

The fly eye larvae control agent of the present invention is a source of fly eye larvae based on an excellent knockdown effect that is manifested in a short time of treatment when treating small water systems such as drainage of general household drains and flower pots. It is extremely practical because it can be controlled and the source itself can be cleaned to prevent the occurrence of fly larvae. And the fly eye larvae extermination method using this also has an effective extermination effect against the fly insect pests.

The fly order larva control agent of the present invention is characterized by using a bleaching component as an active ingredient. Examples of bleaching components include percarbonates (sodium percarbonate, potassium percarbonate, etc.), hydrogen peroxide adducts such as perborate and urea peroxide, hydrogen peroxide, or hydrogen persulfate (potassium hydrogen persulfate). Salt) and other oxygen-based bleaches using active oxygen, and chlorine-based bleaches such as hypochlorite and chloroisocyanurate. Among these, the percarbonate represented by the former sodium percarbonate and the hydrogen peroxide solution are excellent bleaching components because they are excellent in the knockdown effect against fly-eye larvae and can exert a good extermination effect by stopping the action. is there. In addition, about a hydrogen sulfate, since it has the lethal effect which was excellent with the knockdown effect, the higher extermination effect can be achieved.
On the other hand, the latter hypochlorite has a high lethal effect but has a poor knockdown effect. Therefore, the former oxygen bleaching agent is suitable for application scenes that require a high knockdown effect as in the present invention. I can say that. In addition, about the chlorine type bleaching agent, although it has strong alkalinity and it has to consider the influence which it has on the stability of the insecticidal component mentioned later, it is fully applicable in the scene where a lethal effect is regarded as important.
The blending amount of the bleaching component is 0.1 to 30 w / v% as hydrogen peroxide with respect to the total amount of the fly eye larva control agent (0.1 to 30 w / w in the case of a solid agent). %) Is appropriate. If it is less than 0.1 w / v%, the desired extermination effect cannot be obtained. On the other hand, adding 30 w / v% or more is not realistic in view of the hydrogen peroxide content of the hydrogen peroxide adduct.

In the present invention, it is preferable to contain a surfactant as an active ingredient in addition to the bleaching ingredient. Surfactants are considered to have the effect of improving the permeability of bleaching components to insects, such as polyoxyethylene higher alkyl ethers (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether, etc.), polyoxyethylene Ethylene alkyl phenyl ethers, polyoxyethylene styryl phenyl ethers, polyoxyethylene higher fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sorbitan fatty acid esters, polyoxyethylene glycerin fatty acid esters, polyoxyethylene hydrogenated castor oil, Nonionic surfactants such as coconut oil fatty acid diethanolamide, polyoxyethylene polyoxypropylene alkyl ether, linear benzene sulfonate, alpha olefin sulfonate, laur Anionic surfactants such as sulfuric acid sulfate, lauryl sulfate ester triethanolamine, polyoxyethylene lauryl sulfate ester salt, lauryldimethylaminoacetic acid betaine, laurylamine oxide, stearylamine oxide, laurylamidopropyldimethylamine oxide, myristyl Examples include amphoteric surfactants such as dimethyl betaine and coconut oil fatty acid amidopropyl betaine. In particular, anionic surfactants and / or amphoteric surfactants are preferred. In particular, amphoteric surfactants are preferred in that they can impart foaming properties in addition to the action of enhancing the extermination effect. In addition, for the purpose of solubilizing the insecticidal component described later, a nonionic surfactant may be used in combination with the anionic surfactant and / or amphoteric surfactant as appropriate.
A suitable blending amount of the surfactant is about 0.05 to 10 times the bleaching component.

The fly eye larvae control agent of the present invention can further contain an insecticidal component and provide an insecticidal effect together with a knockdown effect by the bleaching component to ensure the extermination effect. Since this fly larvae control agent is mainly used in aqueous systems, it is required to have low fish toxicity as an insecticidal component. And neonicotinoid compounds such as clothianidin, acetamiprid, thiamethoxam, nitenpyram and thiacloprid.
One kind of these compounds may be used, or two or more kinds of compounds may be used in combination. In the present invention, etofenprox, which is excellent in rapid insecticidal effect, is easy to use.
The content of the insecticidal component is suitably about 0.01 to 5.0 w / v% per fly fly larvae (0.01 to 5.0 w / w% in the case of a solid preparation). If it is less than 0.01 w / v%, the desired effect cannot be obtained. On the other hand, if it exceeds 5.0 w / v%, the effectiveness of the bleaching component is affected.

Examples of the form of the fly eye larva control agent include liquid agents, emulsions, aqueous solvents, microemulsions and aerosols used in the form of sprays, and solid agents such as powders, granules and baits.
Solvents used for preparing spray-type fly larvae control agents include, in addition to water, hydrocarbon solvents such as n-paraffin and isoparaffin, ethanol, isopropanol (IPA) and n-propanol (nPA). Lower alcohols having 1 to 3 carbon atoms, propylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, dipropylene glycol, diethylene glycol monobutyl ether and other glycols having 3 to 6 carbon atoms, glycol ethers, and ketones A solvent, ester solvent, etc. may be used as appropriate. In the case of aerosol form, put aerosol solution into aerosol container and pressurize with dimethyl ether as propellant, liquefied petroleum gas (LPG), compressed gas (nitrogen gas, carbon dioxide, nitrous oxide, compressed air, etc.) Can be made.

For the preparation of solid agents such as powders, granules and tablets, various mineral powders such as silicic acid, kaolin and talc, various vegetable powders such as wood flour and wheat flour, and dispersion are used for the purpose of increasing and shaping. Agents, gelling agents such as polyvinyl alcohol, alginic acid, and carrageenan are appropriately used. The base material does not affect the bleaching component, and the prepared solid agent is required to have an appropriate water decomposability when treated in an aqueous system.

In the present invention, in addition to the components described above, a pyrethroid synergist, a foaming agent, a dispersant, a binder, a stabilizer, a pH adjuster, You may mix | blend an odorant, a coloring agent, etc. suitably.

Examples of the pyrethroid synergist include piperonyl butoxide and N- (2-ethylhexyl) -bicyclo [2,2,1] hept-5-ene-2,3-dicarboximide. Moreover, citric acid, sodium hydrogencarbonate, etc. can be illustrated as a foaming agent.

A container filled with a spray-form fly-eye larva control agent may be appropriately selected in the shape of a valve, a nozzle, a nozzle, a spray port, and the like according to its use, purpose of use, usage scene, and the like. For example, if a trigger spray type with a wide-angle nozzle is used, a wide range can be processed with a single operation, which is convenient. The amount to be applied may be determined as appropriate. For example, when used in an aqueous system such as a drain or a septic tank, about 10 to 100 mL / m ² is appropriate.
On the other hand, in the case of solid preparations such as granules and tablets, it is used by spraying or placing in the above-mentioned aqueous system with about 5 to 50 g / m ² as a guide, and hydrolyzes to exhibit the fly eye larvae controlling effect.

The fly larvae control agent of the present invention thus obtained is sprayed or dispersed and placed under a drain outlet, a unit bath, a small water system such as a septic tank or a flower pot, etc. Effective against mosquitoes such as Drosophila and Drosophila and house flies, mosquitoes and chikaeka, and has a practical knockdown effect against larvae of butterflies that require a particularly high knockdown effect, Since the larvae whose behavior has stopped are washed away from the inhabited water system, high extinction treatment is realized. In addition, it is extremely practical because the source itself is cleaned by the action of the bleaching component and the generation of adults is prevented over a long period of time. In addition, the fly larva repellent of the present invention further containing an insecticidal component is imparted with an insecticidal effect as well as a knockdown effect, and the repellent effect is more reliably achieved.

Next, the fly larva control agent of the present invention will be described in more detail based on specific examples. Typical examples of commercially available surfactants are described below. Among them, the surfactants used in the examples are represented by abbreviated symbols.
(Non-ionic)
Nonionic E-202S: POE (2) oleyl ether Nonionic S-207: POE (7) stearyl ether Nonionic S-220: POE (20) stearyl ether [N-1]
-Unilube 50MT-2200B: polyoxyethylene polyoxypropylene decyl tetradecyl ether (m24n13) [N-2]
Nonionic O-4: Polyethylene glycol monooleate [N-3]
Nonionic LP-20R: sorbitan monolaurate [N-4]
-Stahome F: coconut oil fatty acid diethanolamide (1: 2 type) [N-5]
Solpol SM-100PD: a mixture containing polyoxyethylene styryl phenyl ether formaldehyde polycondensate and polyoxyethylene styryl phenyl ether [N-6]
(Anionic)
・ Persoft SF-T: Lauryl sulfate triethanolamine [A-1]
・ Persoft EP: Polyoxyethylene lauryl sulfate sodium salt [A-2]
Monogen Y-500: lauryl sulfate sodium salt [A-3]
Sun base: α-sulfo fatty acid methyl ester sodium salt [A-4]
Newlex R: linear benzenesulfonic acid sodium salt [A-5]
Lipolane PB-800: alpha olefin sulfonic acid sodium salt [A-6]
-Lipolane LJ-441: Alpha olefin sulfonate-Sinoline SPE-1250: POE (2) sodium lauryl ether sulfate-Syntrex EH-R: 2-ethylhexyl sulfate sodium salt (amphoteric)
Nissan Anon BL-SF: lauryldimethylaminoacetic acid betaine [B-1]
Aromox DM12D-W (c): Lauryldimethylamine oxide [B-2]
-Aromox DMC-W: Coconut alkyl dimethylamine oxide [B-3]
Aromox DM 10D-W: Decyldimethylamine oxide MITAINE L: Lauryl dimethyl betaine Ricavion A-200: Myristyl dimethyl betaine Enadicol L-30B: Amidopropyl betaine laurate C-30B: Palm oil fatty acid amidopropyl betaine MIRATAIN CBS: palm oil fatty acid amidopropylhydroxysultain

Sodium percarbonate 20 w / w% (5.6 w / w% as hydrogen peroxide), amphoteric surfactant [B-1] 1.0 w / w%, dinotefuran 0.1 w / w%, and lactose An excipient containing hydroxypropylcellulose (remainder) was mixed and molded into 10 g tablets per one to prepare the fly larvae control agent of the present invention.
Three tablets obtained were put into a household drain and 4 hours later, approximately 10 L of water was poured. As a result, there was evidence of extermination of larvae such as butterflies, and the unpleasant odor of the drainage port disappeared due to the action of the bleaching component. This treatment can prevent the occurrence of butterflies and the like over one month, and is extremely practical.

30% hydrogen peroxide solution 17w / v% (5.1w / v% as hydrogen peroxide), amphoteric surfactant [B-2] 5.0w / v%, etofenprox 0.04w / v V%, 0.08 w / v% of a nonionic surfactant [N-6] and water (remainder) were mixed to prepare a liquid type fly larvae control agent of the present invention.
50 mL of the obtained liquid agent was treated in the same manner as in Example 1 at a household drain outlet. This agent had good foaming and was able to achieve more effective control and prevention of larvae such as butterflies, and also helped clean the drain.

According to Example 2, various fly larvae control agents shown in Table 1 were prepared, and the following insecticidal efficacy test was performed.
[Insecticidal efficacy test 1]
20 mL of a reagent solution having a predetermined concentration was placed in a plastic container having a diameter of 10 cm and a height of 4.4 cm, and the 4th instar larvae were immersed therein. After 2 hours of immersion, knockdown insects were counted to calculate the knockdown rate, and transferred to an untreated container (20 mL of water) to observe the lethality after 24 hours.

As a result of the test, the fly larva control agent of the present invention containing a bleaching component is extremely effective for controlling larvae of butterflies and prevention of occurrence by preferably adding a surfactant, and more preferably also an insecticidal component. there were. From the comparison of the test results of Examples 8 to 10, the addition of the nonionic surfactant contributes to the solubilization of the insecticidal component and is particularly useful for reliably achieving the lethal effect. Admitted.
On the other hand, as shown in the comparative example, a satisfactory extermination effect could not be obtained with only the insecticidal component or the surfactant.

According to Example 2, various fly larvae control agents shown in Table 2 were prepared, and the following insecticidal efficacy test was performed.
[Insecticidal efficacy test 2]
In a plastic container having a diameter of 12 cm and a height of 10.5 cm, 200 mL of an aqueous reagent reagent solution having a predetermined concentration was placed, and Culex mosquito 8-day-old larvae were immersed therein. After 2 hours of immersion, knockdown insects were counted and the knockdown rate was calculated. Moreover, it moved to the clean cup containing water 2 hours after immersion, and knockdown insects and lethal insects were counted 24 hours later, and lethality was calculated.

that's all

As a result of the test, the pest control agent of the present invention containing a bleaching component showed an excellent knockdown effect against Culex larvae, preferably by adding a surfactant. Moreover, Example 17 which mix | blended the insecticidal component became 100%, and it was recognized that it is more effective by extermination of the squid larva.
On the other hand, as shown in the comparative example, a satisfactory extermination effect could not be obtained with only the insecticidal component or the surfactant.

The fly eye larvae control agent of the present invention should be used not only for small water systems in general households, such as drainage outlets for butterflies etc. Is possible.

Claims (5)

Oxygen-based bleaching component (excluding peroxycarboxylic acid) containing 0.1-30 w / v% hydrogen peroxide (0.1-30 w / w% in the case of solid preparation) as the total amount of the preparation,
Or what added a surfactant to this as a knockdown active ingredient ,
Furthermore , a fly-eye larvae control agent comprising one or more selected from etofenprox, silafluophene, dinotefuran, imidacloprid, clothianidin and acetamiprid as an insecticidal component . 2. The fly eye according to claim 1, wherein the oxygen bleaching component is at least one selected from an oxygen bleaching agent that is a hydrogen peroxide adduct, a hydrogen peroxide solution, or a hydrogen persulfate. Larva control agent. 3. The fly eye larva control agent according to claim 2, wherein the hydrogen peroxide adduct is at least one selected from percarbonate, perborate, and urea peroxide. The fly larvae control agent according to any one of claims 1 to 3, wherein the surfactant is an anionic surfactant and / or an amphoteric surfactant. 5. A method for controlling fly larvae, comprising subjecting the fly larva control agent according to any one of claims 1 to 4 to an aqueous treatment.