JP6036313B2 - ORGANIC ELECTROLUMINESCENCE ELEMENT, DISPLAY DEVICE AND LIGHTING DEVICE HAVING THE SAME - Google Patents

Description

  The present invention relates to an organic electroluminescence element, a display device including the same, and a lighting device. More specifically, the present invention relates to an organic electroluminescence element having high light emission efficiency, a long lifetime, and excellent thermal stability and temporal stability, and a display device and an illumination device including the organic electroluminescence element.

  An organic electroluminescence element (hereinafter also referred to as an organic EL element) has a configuration in which a light emitting layer containing a light emitting compound is sandwiched between a cathode and an anode, and holes injected from the anode by applying an electric field. This is a light-emitting device that uses the emission of light (fluorescence / phosphorescence) when excitons are generated by recombining electrons and electrons injected from the cathode in the light-emitting layer. . The organic EL element is an all-solid-state element composed of an organic material film having a thickness of only a submicron between the electrodes, and can emit light at a voltage of several volts to several tens of volts. It is expected to be used for flat displays and lighting.

  As a development of an organic EL element for practical use, since Princeton University has reported an organic EL element using phosphorescence emission from an excited triplet (see, for example, Non-Patent Document 1), phosphorous is used at room temperature. Research on materials that exhibit light has become active (see, for example, Patent Document 1 and Non-Patent Document 2).

  Furthermore, organic EL elements that utilize phosphorescence emission can in principle achieve a luminous efficiency that is about four times that of elements that utilize previous fluorescence emission. Research and development of layer structure and electrodes are conducted all over the world. For example, many synthetic compounds have been studied focusing on heavy metal complexes such as iridium complexes (see Non-Patent Document 3, for example).

  As described above, the organic EL device using phosphorescence emission has a very high potential method, but is different from the organic EL device using fluorescence emission in that the method of controlling the position of the emission center, particularly the inside of the emission layer. In order to improve the efficiency and life of the device, it is an important technical problem how recombination can be performed to stabilize light emission.

  Therefore, a multi-layered device having a hole transport layer located on the anode side of the light emitting layer and an electron transport layer located on the cathode side of the light emitting layer adjacent to the light emitting layer is well known (for example, , See Patent Document 2). In addition, a mixed layer using a host compound and a phosphorescent compound as a dopant is often used for the light emitting layer.

On the other hand, from the viewpoint of materials, high carrier transportability and thermally and electrically stable materials are required. Especially when blue phosphorescence is used, the blue phosphorescent compound itself has high triplet excitation energy ( to have a T _1), the control of development and precise emission center of the applicable peripheral materials are strongly required.

  As a typical blue phosphorescent compound, bis [(4,6-difluorophenyl) -pyridinate-N, C2 ′] (picolinate) iridium complex (FIrpic) is known, and the main ligand phenylpyridine is known. Shortening of the wavelength has been realized by substituting fluorine in the resin and using picolinic acid as a secondary ligand. By combining this dopant with a carbazole derivative or triarylsilane as a host compound, a high-efficiency device can be constructed. However, since the light emission lifetime of the device is greatly deteriorated, the trade-off between light emission efficiency and light emission lifetime is improved. Was demanded.

  In recent years, Patent Document 3 discloses a metal complex having a specific ligand as a blue phosphorescent compound having a high potential. However, although the organic EL device described in Patent Document 3 is improved in terms of light emission efficiency and light emission lifetime, further higher light emission efficiency and longer life are required. There is a problem in the thermal stability of the metal complex that is a material, and when an organic layer is formed by vapor deposition using the metal complex, a decomposition product is generated, which may reduce the lifetime of the device.

  In addition, from the viewpoint of use for display and illumination, the organic EL element also needs to be stable over time. In the light emitting layer of an organic EL element, when light is emitted continuously for a long time due to thermal and electrical instability of a light emitting dopant, concentration quenching due to crystallization or aggregation, quenching due to interaction between excitons, etc. There is a concern that degradation of device performance such as an increase in driving voltage or a decrease in light emission luminance may occur due to decomposition of the metal complex itself in the light emitting layer or a change in the state of the film under high temperature and high humidity. Patent Document 3 does not describe at all such a viewpoint of stability over time, and it has been found that further improvement is necessary.

US Pat. No. 6,097,147 JP 2005-112765 A US Patent Application Publication No. 2011/0204333

M.M. A. Baldo et al. , Nature, 395, 151-154 (1998) M.M. A. Baldo et al. , Nature, 403, 17, 750-753 (2000) S. Lamansky et al. , J .; Am. Chem. Soc. 123, 4304 (2001)

  The present invention has been made in view of the above-described problems and circumstances, and a solution to the problem is to provide an organic electroluminescence device having high luminous efficiency, long life, and excellent thermal stability and temporal stability. is there. Moreover, it is providing the display apparatus and illuminating device using this organic electroluminescent element.

In order to solve the above problems, the present inventor includes an iridium complex having a specific structure represented by the following general formula (2) in the organic layer of the organic EL element in the process of examining the cause of the above problems. The inventors have found that the above problems can be solved and have reached the present invention.

  That is, the said subject which concerns on this invention is solved by the following means.

1. An organic electroluminescence device in which an organic layer including a light emitting layer is sandwiched between an anode and a cathode, and an iridium complex represented by the following general formula (2) (provided that at least one layer constituting the organic layer ) An organic electroluminescence device comprising the following compounds S15 and S25) .

(Ra, Ra ', Rb, Rb', Rc, Rd ', Rf and Rg are each independently a halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, aryl R ₄ represents an alkyl group , an aromatic hydrocarbon ring group, an aromatic heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, and may further have a substituent. the expressed. na is 0-4 .na '.nb is an integer of 0 to 3' representing the the .nc is 0-4 integer .nb is an integer of 0 to 3 representing an integer of 0 to 2 Nd ′ represents an integer of 0 to 2.

R _{1 to} R ₃ are each independently a hydrogen atom, halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, arylalkyl group, aromatic hydrocarbon ring group, aromatic Represents a heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, which may have a substituent. R ₁ and R ₃ do not both represent a hydrogen atom. Also, R ₁ and R ₂ are not connected to each other to form a ring.

X and Y each independently represent a single bond, CR ₅ R ₆ , NR ₇ , O, S or SiR ₈ R ₉ . R ₅ , R ₆ , R ₇ , R ₈ and R ₉ are each independently a hydrogen atom, alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon ring group, aromatic heterocyclic group or non-aromatic hydrocarbon. Represents a cyclic group or a non-aromatic heterocyclic group.

m and n represent 1 or 2. However, m + n is 3. )
2 . In the said General formula (2), Y represents a single bond, The organic electroluminescent element of 1st term | claim characterized by the above-mentioned.

3 . In the general formula (2), X represents an oxygen atom, The organic electroluminescent device according to the first or second item, wherein X represents an oxygen atom.

4 . The m represents 1, and the organic electroluminescence element according to any one of the first to third aspects.

5 . The organic electroluminescence element according to any one of Items 1 to 4, which emits white light.

6 . An illuminating device comprising the organic electroluminescent element according to any one of items 1 to 5 .

7 . A display device comprising the organic electroluminescence element according to any one of items 1 to 5 .

  By the above means of the present invention, it is possible to provide an organic electroluminescence device having high luminous efficiency, long life, and excellent thermal stability and temporal stability. In addition, a display device and a lighting device including the element can be provided.

  The expression mechanism or action mechanism of the effect of the present invention is not clear, but is presumed as follows.

In the organometallic complex having an imidazole mother nucleus, the relationship between the steric effect of the substituent and the stability of the organometallic complex was investigated. In general formula (2) , at least one of R ₁ and R ₃ is a hydrogen atom. By the steric effect of the substituent , the movement of the benzene ring substituted by R ₄ in the ground state and the excited state is reduced due to the steric effect of the substituent. It is presumed that this is because the binding moiety is protected, and as a result, the thermal stability and electrical stability of the iridium complex represented by the general formula (2) are enhanced.

Schematic diagram showing an example of a display device composed of organic EL elements Schematic diagram of the display unit Schematic diagram showing the pixel circuit Schematic diagram of passive matrix type full color display device Schematic of lighting device Cross section of the lighting device Schematic configuration diagram of organic EL full-color display device

The organic electroluminescent element of the present invention is an organic electroluminescent element in which an organic layer including a light emitting layer is sandwiched between an anode and a cathode, and at least one layer constituting the organic layer includes the general formula (2). It is characterized by containing an iridium genus complex represented by (except for the compounds S15 and S25) . This feature is a technical feature common to the inventions according to claims 1 to 7 .

Further, in the present invention, before following general formula (2), it is preferred that Y represents a single bond. Further, in the general formula (2), X preferably represents an oxygen atom. The m preferably represents 1.

  Furthermore, it is preferable that the organic EL element of the present invention emits white light.

  The organic EL element of the present invention can be suitably included in a display device and a lighting device.

  Hereinafter, the present invention, its components, and modes and modes for carrying out the present invention will be described in detail. In addition, in this application, "-" is used in the meaning which includes the numerical value described before and behind that as a lower limit and an upper limit.

<< Organic metal complex represented by the general formula (1) >>
The organic electroluminescence element used as a reference is an organic electroluminescence element in which an organic layer including a light emitting layer is sandwiched between an anode and a cathode, and at least one layer constituting the organic layer has the following general formula (1) The organometallic complex represented by these is contained . In the present invention, the organic layer refers to a layer containing an organic substance.

The organic metal complex contained in the organic EL element used as a reference as an organic EL element material will be described. The organometallic complex used as a reference is represented by the following general formula (1).

  In the general formula (1), ring A, ring B and ring C represent a 5-membered or 6-membered aromatic hydrocarbon ring or aromatic heterocycle.

  In the general formula (1), examples of the 5-membered or 6-membered aromatic hydrocarbon ring represented by the ring A, the ring B, and the ring C include a benzene ring.

  In the general formula (1), examples of the 5-membered or 6-membered aromatic heterocycle represented by the ring A, the ring B, and the ring C include a furan ring, a thiophene ring, an oxazole ring, a pyrrole ring, a pyridine ring, and a pyridazine. A ring, a pyrimidine ring, a pyrazine ring, a triazine ring, an oxadiazole ring, a triazole ring, an imidazole ring, a pyrazole ring, a thiazole ring, and the like.

  Preferably, ring A, ring B and ring C are all benzene rings.

In the general formula (1), Ra, Rb, Rc and R ₄ are each independently a halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, arylalkyl group, aromatic Represents an aromatic hydrocarbon ring group, an aromatic heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, and may further have a substituent. Of these, an alkyl group and an aromatic hydrocarbon ring group are preferable. More preferably, it is an alkyl group.

  na represents an integer of 0 to 2. nb represents an integer of 0 to 3. nc represents an integer of 0 to 4.

R _{1 to} R ₃ are each independently a hydrogen atom, halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, arylalkyl group, aromatic hydrocarbon ring group, aromatic Represents a heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, and may further have a substituent. Of these, an alkyl group and an aromatic hydrocarbon ring group are preferable. R ₁ and R ₃ do not both represent a hydrogen atom. That is, at least one of R ₁ and R ₃ represents the above substituent other than a hydrogen atom.

By at least one of R ₁ and R _{3 being} a substituent other than a hydrogen atom, the movement of ring A in the ground state and the excited state is reduced due to the steric effect of the substituent, and further, the bond is expected to be weak. The C—N bond portion to be protected is protected, and as a result, the metal complex represented by the general formula (1) contains the metal complex in the organic EL element in order to increase the thermal stability and the electrical stability. As a result, it is expected that the light emission efficiency and the light emission lifetime of the organic EL element are improved.

In addition, it is considered that at least one of R ₁ and R ₃ is a substituent other than a hydrogen atom, thereby suppressing intermolecular interaction between metal complexes via ring A and improving sublimation properties. In particular, when the vapor deposition method is used for a high molecular weight metal complex, it is considered that the good sublimation property suppresses the decomposition of the metal complex and enables uniform and rapid vapor deposition.

In the general formula (1), examples of the alkyl group represented by Ra, Rb, Rc and R _{1 to} R ₄ include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, sec- Examples thereof include a butyl group, a t-butyl group, a 1-ethyl-propyl group, a 2-methylhexyl group, a pentyl group, an adamantyl group, an n-decyl group, and an n-dodecyl group. Preferably, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, t-butyl group and the like can be mentioned.

In the general formula (1), the aromatic hydrocarbon ring group and the aromatic heterocyclic group represented by Ra, Rb, Rc and R _{1 to} R ₄ are derived from an aromatic hydrocarbon ring and an aromatic heterocyclic ring. And monovalent groups.

  Examples of the aromatic hydrocarbon ring include a benzene ring, biphenyl ring, biphenylene ring, naphthalene ring, azulene ring, anthracene ring, phenanthrene ring, pyrene ring, chrysene ring, naphthacene ring, triphenylene ring, o-terphenyl ring, m -Terphenyl ring, p-terphenyl ring, acenaphthene ring, coronene ring, fluorene ring, fluoranthrene ring, naphthacene ring, pentacene ring, perylene ring, pentaphen ring, picene ring, pyrene ring, pyranthrene ring, anthraanthrene ring Etc.

  As the aromatic heterocycle, for example, silole ring, furan ring, thiophene ring, oxazole ring, pyrrole ring, pyridine ring, pyridazine ring, pyrimidine ring, pyrazine ring, triazine ring, oxadiazole ring, triazole ring, imidazole ring, Pyrazole ring, thiazole ring, indole ring, benzimidazole ring, benzthiazole ring, benzoxazole ring, quinoxaline ring, quinazoline ring, phthalazine ring, thienothiophene ring, carbazole ring, azacarbazole ring (any of the carbon atoms constituting the carbazole ring) Or a ring in which any one or more of the carbon atoms constituting the dibenzosilole ring, dibenzofuran ring, dibenzothiophene ring, benzothiophene ring or dibenzofuran ring are replaced by a nitrogen atom. Ben Difuran ring, benzodithiophene ring, acridine ring, benzoquinoline ring, phenazine ring, phenanthridine ring, phenanthroline ring, cyclazine ring, kindlin ring, tepenidine ring, quinindrine ring, triphenodithiazine ring, triphenodioxazine ring, pheno dioxazine ring Nantrazine ring, anthrazine ring, perimidine ring, naphthofuran ring, naphthothiophene ring, naphthodifuran ring, naphthodithiophene ring, anthrafuran ring, anthradifuran ring, anthrathiophene ring, anthradithiophene ring, thianthrene ring, phenoxathiin ring , Dibenzocarbazole ring, indolocarbazole ring, dithienobenzene ring and the like.

In the general formula (1), examples of the non-aromatic hydrocarbon ring group represented by Ra, Rb, Rc, and R _{1 to} R ₄ include cycloalkane (eg, cyclopentane ring, cyclohexane ring, etc.), cycloalkane, and the like. And monovalent groups derived from the above.

In the general formula (1), examples of the non-aromatic heterocyclic group represented by Ra, Rb, Rc, and R _{1 to} R ₄ include an epoxy ring, an aziridine ring, a thiirane ring, an oxetane ring, an azetidine ring, and a thietane ring. , Tetrahydrofuran ring, dioxolane ring, pyrrolidine ring, pyrazolidine ring, imidazolidine ring, oxazolidine ring, tetrahydrothiophene ring, sulfolane ring, thiazolidine ring, ε-caprolactone ring, ε-caprolactam ring, piperidine ring, hexahydropyridazine ring, hexahydro Pyrimidine ring, piperazine ring, morpholine ring, tetrahydropyran ring, 1,3-dioxane ring, 1,4-dioxane ring, trioxane ring, tetrahydrothiopyran ring, thiomorpholine ring, thiomorpholine-1,1-dioxide ring, pyranose Ring, diazabicyclo [ And a monovalent group derived from a 2,2,2] -octane ring, a phenoxazine ring, a phenothiazine ring, an oxanthrene ring, a thioxanthene ring, and a phenoxathiin ring.

In the general formula (1), these aromatic hydrocarbon rings, aromatic heterocyclic rings, non-aromatic hydrocarbon rings and non-aromatic heterocyclic rings represented by Ra, Rb, Rc and R _{1 to} R ₄ are substituted. It may have a group.

Further, when a plurality of Ra, Rb or Rc are present, the substituents may be bonded to each other to form a ring, or Ra and R ₄ , or Rb and R ₃ may be bonded to each other to form a ring. good. However, R ₁ and R ₂ are not bonded to each other to form a ring.

In the general formula (1), X and Y each represent a single bond, CR ₅ R ₆ , NR ₇ , O, S, or SiR ₈ R ₉ , and X and Y do not both form a single bond. R ₅ , R ₆ , R ₇ , R ₈ and R ₉ are each independently a hydrogen atom, alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon ring group, aromatic heterocyclic group or non-aromatic hydrocarbon. Represents a cyclic group or a non-aromatic heterocyclic group, preferably an alkyl group or an aromatic hydrocarbon ring group.

In the general formula (1), an alkyl group represented by R ₅ , R ₆ , R ₇ , R ₈ and R ₉ , an aromatic hydrocarbon ring group, an aromatic heterocyclic group, a non-aromatic hydrocarbon ring group, non- Examples of the aromatic heterocyclic group include the alkyl groups, aromatic hydrocarbon ring groups, aromatic heterocyclic groups, non-aromatic hydrocarbon ring groups, non-aromatic groups represented by the aforementioned Ra, Rb, Rc, and R _{1 to} R _4. What was mentioned as an example of an aromatic heterocyclic group is mentioned. An alkyl group or an aromatic hydrocarbon ring group is preferable, and an alkyl group is preferably a methyl group, an ethyl group, an n-propyl group, an isopropyl group, or an n-butyl group, and is preferably an aromatic hydrocarbon ring group. Is a benzene ring group and may further have a substituent.

  In the general formula (1), Y is preferably a single bond, and X preferably represents an oxygen atom.

  In the general formula (1), L represents a monoanionic bidentate ligand coordinated to M. M represents an atomic number of 40 or more, and represents a transition metal atom of Group 8 to 10 in the periodic table, and M is preferably Ir, Pt or Os, and most preferably Ir.

  In General formula (1), m represents the integer of 1-3. n represents an integer of 0 to 2. However, m + n is 2 or 3.

  The structure of at least one ligand coordinated to M is preferably different from the structure of other ligands. More preferably, m = 1 and n = 2.

<< Organic metal complex represented by formula (2) >>
The organic metal complex represented by the above general formula (1) is iridium complex represented by the following general formula (2) in the present invention (excluding the compound S15 and S25) Ru der.

In the general formula (2), Ra, Rb, Rc and _R 1 ~ _{R 3} is Ra in formula (1), Rb, and Rc and _R 1 ~ _{R 3} synonymous. R ₄ represents an alkyl group.

  In the general formula (2), Ra ′, Rb ′, Rd ′, Rf and Rg are each independently a halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, aryl Represents an alkyl group, an aromatic hydrocarbon ring group, an aromatic heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, preferably an alkyl group or an aromatic hydrocarbon ring group, more preferably Is an alkyl group. Furthermore, you may have a substituent.

In the general formula (2), examples of the alkyl group represented by Ra, Ra ′, Rb, Rb ′, Rc, Rd ′, Rf, Rg and R _{1 to} R ₄ include a methyl group, an ethyl group, n- And a propyl group, an isopropyl group, an n-butyl group, a t-butyl group, a 1-ethyl-propyl group, a 2-methylhexyl group, a pentyl group, an adamantyl group, an n-decyl group, and an n-dodecyl group. Examples thereof include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, and an n-butyl group. More preferably, they are a methyl group, an ethyl group, and an isopropyl group.

In the general formula (2), the aromatic hydrocarbon ring group and the aromatic heterocyclic group represented by Ra, Ra ′, Rb, Rb ′, Rc, Rd ′, Rf, Rg, and R ₁ to R ₃ are as follows: And monovalent groups derived from an aromatic hydrocarbon ring and an aromatic heterocycle.

  Examples of the aromatic hydrocarbon ring include a benzene ring, biphenyl ring, biphenylene ring, naphthalene ring, azulene ring, anthracene ring, phenanthrene ring, pyrene ring, chrysene ring, naphthacene ring, triphenylene ring, o-terphenyl ring, m -Terphenyl ring, p-terphenyl ring, acenaphthene ring, coronene ring, fluorene ring, fluoranthrene ring, naphthacene ring, pentacene ring, perylene ring, pentaphen ring, picene ring, pyrene ring, pyranthrene ring anthraanthrene ring, etc. Is mentioned.

  As the aromatic heterocycle, for example, silole ring, furan ring, thiophene ring, oxazole ring, pyrrole ring, pyridine ring, pyridazine ring, pyrimidine ring, pyrazine ring, triazine ring, oxadiazole ring, triazole ring, imidazole ring, Pyrazole ring, thiazole ring, indole ring, benzimidazole ring, benzthiazole ring, benzoxazole ring, quinoxaline ring, quinazoline ring, phthalazine ring, thienothiophene ring, carbazole ring, azacarbazole ring (any of the carbon atoms constituting the carbazole ring) Or a ring in which any one or more of the carbon atoms constituting the dibenzosilole ring, dibenzofuran ring, dibenzothiophene ring, benzothiophene ring or dibenzofuran ring are replaced by a nitrogen atom. Ben Difuran ring, benzodithiophene ring, acridine ring, benzoquinoline ring, phenazine ring, phenanthridine ring, phenanthroline ring, cyclazine ring, kindlin ring, tepenidine ring, quinindrine ring, triphenodithiazine ring, triphenodioxazine ring, pheno dioxazine ring Nantrazine ring, anthrazine ring, perimidine ring, naphthofuran ring, naphthothiophene ring, naphthodifuran ring, naphthodithiophene ring, anthrafuran ring, anthradifuran ring, anthrathiophene ring, anthradithiophene ring, thianthrene ring, phenoxathiin ring , Dibenzocarbazole ring, indolocarbazole ring dithienobenzene ring and the like.

In the general formula (2), examples of the non-aromatic hydrocarbon ring group represented by Ra, Ra ′, Rb, Rb ′, Rc, Rd ′, Rf, Rg, and R ₁ to R ₃ include cycloalkane ( Examples thereof include a monovalent group derived from a cyclopentane ring, a cyclohexane ring, etc.) and a cycloalkane.

In the general formula (2), examples of the non-aromatic heterocyclic group represented by Ra, Ra ′, Rb, Rb ′, Rc, Rd ′, Rf, Rg and R ₁ to R ₃ include, for example, an epoxy ring, an aziridine Ring, thiirane ring, oxetane ring, azetidine ring, thietane ring, tetrahydrofuran ring, dioxolane ring, pyrrolidine ring, pyrazolidine ring, imidazolidine ring, oxazolidine ring, tetrahydrothiophene ring, sulfolane ring, thiazolidine ring, ε-caprolactone ring, ε- Caprolactam ring, piperidine ring, hexahydropyridazine ring, hexahydropyrimidine ring, piperazine ring, morpholine ring, tetrahydropyran ring, 1,3-dioxane ring, 1,4-dioxane ring, trioxane ring, tetrahydrothiopyran ring, thiomorpholine Ring, thiomorpholine-1,1-dioxy De ring, pyranose ring, a diazabicyclo [2,2,2] - octane ring, a phenoxazine ring, a phenothiazine ring, Okisantoren ring, thioxanthene ring, such as a monovalent group derived from phenoxathiin ring.

In the general formula (2), these rings represented by Ra, Ra ′, Rb, Rb ′, Rc, Rd ′, Rf, Rg, and R ₁ to R ₃ may have a substituent. Good.

Further, when there are a plurality of Ra, Ra ′, Rb, Rb ′, and Rc, the substituents may be bonded to each other to form a ring, and Rb and R ₃ , Ra and R ₄ , Ra ′ and Rf, Ra ′ and Rg may be bonded to each other to form a ring. However, R ₁ and R ₂ , or Rd ′ are not bonded to each other to form a ring.

  na represents an integer of 0 to 2. nb represents an integer of 0 to 3. nc represents an integer of 0 to 4. na 'represents the integer of 0-3. nb ′ represents an integer of 0 to 4. nd ′ represents an integer of 0 to 2.

In the general formula (2), X and Y each represent a single bond, CR ₅ R ₆ , NR ₇ , O, S, or SiR ₈ R ₉ , and X and Y do not both form a single bond. R ₅ , R ₆ , R ₇ , R ₈ and R ₉ are each independently a hydrogen atom, alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon ring group, aromatic heterocyclic group or non-aromatic hydrocarbon. Represents a cyclic group or a non-aromatic heterocyclic group, preferably an alkyl group or an aromatic hydrocarbon ring group.

  In the general formula (2), Y is preferably a single bond. X preferably represents an oxygen atom.

  In the general formula (2), m and n represent 1 or 2, and m + n is 3. Preferably, m = 1 and n = 2.

Hereinafter, the general formula being a reference (1), and specific examples of the organic metal complex represented by the general formula (2) according to the present invention, the present invention is not limited thereto.

≪Synthesis example≫
Although the synthesis example of the compound represented by General formula (1) is demonstrated below, this invention is not limited to this. Of the specific examples described above, the DP-1 synthesis method will be described below as an example.

  DP-1 can be synthesized according to the following scheme.

A 100 ml four-necked flask was charged with 1.65 g of intermediate A, 13 ml of 2-ethoxyethanol, and 3 ml of water, and set on an oil bath stirrer with a nitrogen blowing tube, a thermometer and a condenser. To this, 0.55 g of IrCl ₃ .3H ₂ O was added, and the reaction was terminated by boiling and refluxing at an internal temperature of 135 ° C. for 6 hours under a nitrogen stream.

  After completion of the reaction, the reaction mixture was cooled to room temperature, methanol was added, and the precipitated solid was collected by filtration. The obtained solid was thoroughly washed with methanol and dried to obtain 1.12 g (77.0%) of Intermediate B.

  Into a 50 ml four-necked flask, put 1.00 g of intermediate B, 0.86 g of intermediate C, 0.30 g of silver trifluoroacetate, 20 ml of phenyl acetate, and attach a nitrogen blowing tube, thermometer, and air cooling tube. Set on an oil bath stirrer. The reaction was terminated by heating and stirring for 8 hours at a nitrogen gas stream inner temperature of around 150 ° C.

  After completion of the reaction, the mixture was cooled to room temperature, methanol was added and dispersed, and the crystals were collected by filtration to obtain 1.06 g of crude crystals.

The crystals were purified by column chromatography (developing solvent, tetrahydrofuran / heptane), and the obtained crystals were suspended in a heated suspension in a mixed solvent of tetrahydrofuran and ethyl acetate, and filtered to obtain DP3 (0.93 g, 66.6%). Obtained. The structure of Compound DP-1 was confirmed by mass spectrum and ¹ H-NMR.

MASS spectrum (ESI): m / z = 1235 [M +]
¹ H-NMR (THF-d8, 400 MHz): δ 6.40-7.94 (28H, m), δ 2.64-3.48 (7H, m), δ 1.19-1.87, (42H, m )
The organic metal complex represented by the present invention engaging Ru one general formula (2) as the light emitting dopant is preferably used.

  Moreover, the well-known phosphorescence dopant and fluorescent dopant which are mentioned later can be used together as a light emission dopant.

<< Constitutional layer of organic EL element >>
The constituent layers of the organic EL element of the present invention will be described. In the organic EL device of the present invention, preferred specific examples of the layer structure of various organic layers sandwiched between the anode and the cathode are shown below, but the present invention is not limited thereto. In the present invention, the organic layer refers to a layer containing an organic substance.
(I) Anode / light emitting layer unit / electron transport layer / cathode (ii) Anode / hole transport layer / light emitting layer unit / electron transport layer / cathode (iii) Anode / hole transport layer / light emitting layer unit / hole blocking Layer / electron transport layer / cathode (iv) anode / hole transport layer / light emitting layer unit / electron transport layer / electron injection layer / cathode (v) anode / hole injection layer / hole transport layer / light emitting layer unit / electron Transport layer / electron injection layer / cathode (vi) anode / hole transport layer / light emitting layer unit / hole blocking layer / electron transport layer / electron injection layer / cathode (vii) anode / hole injection layer / hole transport layer / Light emitting layer unit / hole blocking layer / electron transport layer / electron injection layer / cathode As the blocking layer, an electron blocking layer can be used in addition to the hole blocking layer.

The light emitting layer unit (hereinafter simply referred to as the light emitting layer as appropriate) may be a single light emitting layer or a plurality of light emitting layers. Furthermore, the light emitting layer unit may have a non-light emitting intermediate layer between a plurality of light emitting layers, and may have a multi-photon unit configuration in which the intermediate layer is a charge generation layer. In this case, the charge generation layer includes ITO (indium tin oxide), IZO (indium zinc oxide), ZnO ₂ , TiN, ZrN, HfN, TiO _x , VO _x , CuI, InN, GaN, CuAlO _2. , CuGaO ₂ , SrCu ₂ O ₂ , LaB ₆ , RuO _{2 and} other conductive inorganic compound layers, Au / Bi ₂ O _{3 and} other bilayer films, SnO ₂ / Ag / SnO ₂ , ZnO / Ag / ZnO, Bi ₂ O ₃ / Au / Bi ₂ O ₃ , TiO ₂ / TiN / TiO ₂ , TiO ₂ / ZrN / TiO _{2 and} other multilayer films, C _{60 and} other fullerenes, conductive organic layer such as oligothiophene, metal Examples thereof include conductive organic compound layers such as phthalocyanines, metal-free phthalocyanines, metal porphyrins and metal-free porphyrins.

  The light emitting layer in the organic EL element of the present invention is preferably a white light emitting layer, and is preferably an illumination device or a display device using these. That is, the organic EL element preferably emits white light.

  Each layer which comprises the organic EL element of this invention is demonstrated below.

<Light emitting layer>
The light emitting layer is a layer that emits light by recombination of electrons and holes injected from the cathode or electron transport layer and the anode or hole transport layer, respectively, and the light emitting portion is in the layer of the light emitting layer. May be the interface between the light emitting layer and the adjacent layer.

  The total thickness of the light emitting layer is not particularly limited, but from the viewpoint of improving the stability of the emission color against the drive current and the uniformity of the film, preventing unnecessary application of high voltage during light emission. Preferably, it is adjusted to the range of 2 nm to 5 μm, more preferably adjusted to the range of 2 to 200 nm, and particularly preferably adjusted to the range of 5 to 100 nm.

  For the production of the light-emitting layer, a light-emitting dopant or a host compound, which will be described later, is used, for example, a vacuum deposition method, a wet method (also referred to as a wet process, for example, a spin coating method, a casting method, a die coating method, a blade coating method, Or the like, the ink jet method, the printing method, the spray coating method, the curtain coating method, the LB method (Langmuir Brodgett method, etc.). In addition, when using the organometallic complex which concerns on this invention as a material of a light emitting layer, it is preferable to form into a film by a wet process.

  The light emitting layer of the organic EL device of the present invention preferably contains a light emitting dopant (such as a phosphorescent light emitting dopant or a fluorescent light emitting dopant) and a host compound.

《Luminescent dopant》
A light-emitting dopant (also referred to as a light-emitting dopant) will be described. As the luminescent dopant, a fluorescent luminescent dopant (also referred to as a fluorescent dopant) or a phosphorescent dopant (also referred to as a phosphorescent dopant or a phosphorescent compound) can be used.

《Phosphorescent dopant》
A phosphorescent dopant (also referred to as a phosphorescent dopant) that can be used in the present invention will be described.

  The phosphorescent dopant that can be used in the present invention is a compound in which light emission from an excited triplet is observed. Specifically, it is a compound that emits phosphorescence at room temperature (25 ° C.), and is defined as a compound having a phosphorescence quantum yield of 0.01 or more at 25 ° C. 1 or more.

  The phosphorescence quantum yield can be measured by the method described in Spectroscopic II, page 398 (1992 edition, Maruzen) of Experimental Chemistry Course 4 of the 4th edition. Although the phosphorescence quantum yield in a solution can be measured using various solvents, the phosphorescence dopant that can be used in the present invention is the phosphorescence quantum yield (0.01 or more) in any solvent. It only has to be achieved.

  There are two types of light emission of the phosphorescent dopant in principle. One is the recombination of the carrier on the host compound to which the carrier is transported and the excited state of the luminescent host compound is generated, and this energy is used as the phosphorescent dopant. It is an energy transfer type in which light emission from a phosphorescent dopant is obtained by moving to. The other is a carrier trap type in which the phosphorescent dopant becomes a carrier trap, and carrier recombination occurs on the phosphorescent dopant, and light emission from the phosphorescent dopant compound is obtained. In any case, it is a condition that the excited state energy of the phosphorescent dopant is lower than the excited state energy of the host compound.

<< Fluorescent dopant (also called fluorescent compound) >>
Fluorescent dopants include coumarin dyes, pyran dyes, cyanine dyes, croconium dyes, squalium dyes, oxobenzanthracene dyes, fluorescein dyes, rhodamine dyes, pyrylium dyes, perylene dyes, stilbene dyes , Polythiophene dyes, rare earth complex phosphors, and the like, and compounds having a high fluorescence quantum yield such as laser dyes.

<< Combination with conventionally known dopants >>
In addition, the light-emitting dopant that can be used in the present invention may be used in combination of a plurality of types of compounds, a combination of phosphorescent dopants having different structures, or a combination of a phosphorescent dopant and a fluorescent dopant. .

Here, although the specific example of the conventionally well-known light emission dopant which may be used in combination with the organometallic complex represented by General formula ( 2) based on this invention as a light emission dopant is given, this invention is not limited to these. .

《Host compound》
In the present invention, a host compound (also referred to as a light-emitting host) is a phosphorescent light-emitting compound at a room temperature (25 ° C.) having a constituent mass ratio in the layer of 20% or more among the compounds contained in the light-emitting layer. Is defined as a compound having a phosphorescence quantum yield of less than 0.1. The phosphorescence quantum yield is preferably less than 0.01. Moreover, it is preferable that the mass ratio in the layer is 50% or more among the compounds contained in a light emitting layer.

  There is no restriction | limiting in particular as a host compound which can be used for this invention, The compound conventionally used with an organic EL element can be used. Typically, a carbazole derivative, a triarylamine derivative, an aromatic derivative, a nitrogen-containing heterocyclic compound, a thiophene derivative, a furan derivative, an oligoarylene compound or the like having a basic skeleton, or a carboline derivative or a diazacarbazole derivative (here And the diazacarbazole derivative represents one in which at least one carbon atom of the hydrocarbon ring constituting the carboline ring of the carboline derivative is substituted with a nitrogen atom.

  A known host compound that can be used in the present invention is preferably a compound that has a hole transporting ability or an electron transporting ability, prevents the emission of light from becoming longer, and has a high Tg (glass transition temperature).

  Moreover, in this invention, a conventionally well-known host compound may be used independently, and may be used in combination of multiple types. By using a plurality of types of host compounds, it is possible to adjust the movement of charges, and the organic EL element can be made highly efficient. Moreover, it becomes possible to mix different light emission by using multiple types of the metal complex of this invention used as the said phosphorescence dopant, and / or a conventionally well-known compound, and, thereby, arbitrary luminescent colors can be obtained.

  The host compound used in the present invention may be a low molecular compound, a high molecular compound having a repeating unit, or a low molecular compound (polymerizable host compound) having a polymerizable group such as a vinyl group or an epoxy group. Of course, one or a plurality of such compounds may be used.

  Specific examples of known host compounds include compounds described in the following documents.

  JP-A-2001-257076, 2002-308855, 2001-313179, 2002-319491, 2001-357777, 2002-334786, 2002-8860, 2002-334787, 2002-15871, 2002-334788, 2002-43056, 2002-334789, 2002-75645, 2002-338579, 2002-105445 gazette, 2002-343568 gazette, 2002-141173 gazette, 2002-352957 gazette, 2002-203683 gazette, 2002-363227 gazette, 2002-231453 gazette, No. 003-3165, No. 2002-234888, No. 2003-27048, No. 2002-255934, No. 2002-286061, No. 2002-280183, No. 2002-299060, No. 2002. -302516, 2002-305083, 2002-305084, 2002-308837, and the like.

  Hereinafter, although the specific example used as a host compound of the light emitting layer of the organic EL element of this invention is given, this invention is not limited to these.

  Furthermore, a compound represented by the following general formula (B) or general formula (E) is particularly preferable as the host compound of the light emitting layer of the organic EL device of the present invention.

  In the general formulas (B) and (E), Xa represents O or S, Xb, Xc, Xd and Xe each represents a hydrogen atom, a substituent or a group represented by the following general formula (C), Xb , Xc, Xd, and Xe represent a group represented by the following general formula (C), and at least one of the groups represented by the following general formula (C) represents Ar as a carbazolyl group.

General formula (C)
Ar- _(L 4) n- *
In general formula (C), L ₄ represents a divalent linking group derived from an aromatic hydrocarbon ring or an aromatic heterocyclic ring. n represents an integer of 0 to 3, and when n is 2 or more, the plurality of L ₄ may be the same or different. * Represents a linking site with the general formula (B) or (E). Ar represents a group represented by the following general formula (D).

In general formula (D), Xf represents N (R ″), O or S, E _{1 to} E ₈ represent C (R ″ ₁ ) or N, R ″ and R ″ ₁ are hydrogen atoms, substituents or it represents a linking site with L ₄ in formula (C). * Represents a linking site with L ₄ in the general formula (C).

  In the compound represented by the general formula (B), preferably, at least two of Xb, Xc, Xd and Xe are represented by the general formula (C), and more preferably Xc is represented by the general formula (C). And Ar in the general formula (C) represents a carbazolyl group which may have a substituent.

  Specific examples of the compound represented by the general formula (B) that are preferably used as the host compound of the light emitting layer of the organic EL device of the present invention are shown below, but the present invention is not limited thereto.

  Moreover, the compound represented by the following general formula (B ′) is also particularly preferably used as the host compound of the light emitting layer of the organic EL device of the present invention.

  In General Formula (B ′), Xa represents O or S, and Xb and Xc each represents a substituent or a group represented by General Formula (C).

  At least one of Xb and Xc represents a group represented by the general formula (C), and at least one of the groups represented by the general formula (C) represents Ar as a carbazolyl group.

In the compound represented by the general formula (B ′), preferably, Ar in the general formula (C) represents a carbazolyl group which may have a substituent, and more preferably, in the general formula (C). Ar may have a substituent, and represents a carbazolyl group linked to L ₄ in Formula (C) at the N position.

  The compound represented by the general formula (B ′) that is preferably used as the host compound of the light emitting layer of the organic EL device of the present invention is specifically the OC-9 mentioned as a specific example previously used as the host compound. , OC-11, OC-12, OC-14, OC-18, OC-29, OC-30, OC-31, and OC-32, but the present invention is not limited thereto.

《Electron transport layer》
The electron transport layer is made of a material having a function of transporting electrons, and in a broad sense, an electron injection layer and a hole blocking layer are also included in the electron transport layer. The electron transport layer can be provided with a single layer or a plurality of layers. The electron transport layer only needs to have a function of transmitting electrons injected from the cathode to the light emitting layer. As a constituent material of the electron transport layer, any conventionally known compound may be selected and used in combination. Is possible.

  Examples of conventionally known materials used for the electron transport layer (hereinafter referred to as electron transport materials) include polycyclic aromatic hydrocarbons such as nitro-substituted fluorene derivatives, diphenylquinone derivatives, thiopyran dioxide derivatives, naphthalene perylene, Ring tetracarboxylic anhydride, carbodiimide, fluorenylidenemethane derivative, anthraquinodimethane and anthrone derivative, oxadiazole derivative, carboline derivative, or at least carbon atoms of the hydrocarbon ring constituting the carboline ring of the carboline derivative Derivatives having a ring structure, one of which is substituted with a nitrogen atom, hexaazatriphenylene derivatives and the like.

  Furthermore, in the oxadiazole derivative, a thiadiazole derivative in which the oxygen atom of the oxadiazole ring is substituted with a sulfur atom, and a quinoxaline derivative having a quinoxaline ring known as an electron-withdrawing group can also be used as an electron transport material.

  It is also possible to use a polymer material in which these materials are introduced into a polymer chain or these materials are used as a polymer main chain.

  In addition, metal complexes of 8-quinolinol derivatives such as tris (8-quinolinol) aluminum (Alq), tris (5,7-dichloro-8-quinolinol) aluminum, tris (5,7-dibromo-8-quinolinol) aluminum Tris (2-methyl-8-quinolinol) aluminum, tris (5-methyl-8-quinolinol) aluminum, bis (8-quinolinol) zinc (Znq), and the like, and the central metals of these metal complexes are In, Mg, Metal complexes replaced with Cu, Ca, Sn, Ga, or Pb can also be used as the electron transport material.

  In addition, metal-free or metal phthalocyanine, or those having a terminal substituted with an alkyl group or a sulfonic acid group can be used as the electron transport material.

  In addition, inorganic semiconductors such as n-type-Si and n-type-SiC can also be used as the electron transport material.

  The electron transport layer is made of an electron transport material such as a vacuum deposition method, a wet method (also referred to as a wet process, such as a spin coating method, a casting method, a die coating method, a blade coating method, a roll coating method, an ink jet method, a printing method, or a spraying method. The film is preferably formed by thinning by a coating method, a curtain coating method, an LB method (such as Langmuir Brodgett method)).

  Although there is no restriction | limiting in particular about the layer thickness of an electron carrying layer, Usually, about 5-5000 nm, Preferably it is 5-200 nm. The electron transport layer may have a single layer structure composed of one or more of the above materials.

  Further, an n-type dopant such as a metal compound such as a metal complex or a metal halide may be doped.

  Hereinafter, although the specific example of the conventionally well-known compound (electron transport material) preferably used for formation of the electron carrying layer of the organic EL element of this invention is given, this invention is not limited to these.

"cathode"
On the other hand, as the cathode, a material having a low work function (4 eV or less) metal (referred to as an electron injecting metal), an alloy, an electrically conductive compound, and a mixture thereof as an electrode material is used. Specific examples of such electrode materials include sodium, sodium-potassium alloy, magnesium, lithium, magnesium / copper mixture, magnesium / silver mixture, magnesium / aluminum mixture, magnesium / indium mixture, aluminum / aluminum oxide (Al ₂ O ₃ ) Mixtures, indium, lithium / aluminum mixtures, rare earth metals and the like. Among these, from the point of durability against electron injection and oxidation, etc., a mixture of an electron injecting metal and a second metal which is a stable metal having a larger work function than this, for example, a magnesium / silver mixture, Magnesium / aluminum mixtures, magnesium / indium mixtures, aluminum / aluminum oxide (Al ₂ O ₃ ) mixtures, lithium / aluminum mixtures, aluminum and the like are preferred.

  The cathode can be produced by forming a thin film of these electrode materials by a method such as vapor deposition or sputtering. The sheet resistance as the cathode is preferably several hundred Ω / □ or less, and the layer thickness is usually selected in the range of 10 nm to 5 μm, preferably 50 to 200 nm.

  In order to transmit the emitted light, if either one of the anode or the cathode of the organic EL element is transparent or translucent, the emission luminance is advantageously improved.

  In addition, a transparent or translucent cathode can be produced by producing a conductive transparent material mentioned in the explanation of the anode described later on the cathode after producing the metal with a layer thickness of 1 to 20 nm. By applying this, an element in which both the anode and the cathode are transmissive can be manufactured.

<< Injection layer: hole injection layer (anode buffer layer), electron injection layer (cathode buffer layer) >>
The injection layer is a layer provided as necessary, and includes a hole injection layer and an electron injection layer. The injection layer may be present between the anode and the hole transport layer or between the cathode and the electron transport layer as shown in the above layer configuration. Alternatively, it may exist between the anode and the light emitting layer or between the cathode and the light emitting layer.

  An injection layer is a layer provided between an electrode and an organic layer in order to reduce drive voltage and improve light emission luminance. “Organic EL element and its forefront of industrialization (issued by NTT Corporation on November 30, 1998) 2), Chapter 2, “Electrode Materials” (pages 123 to 166), and includes a hole injection layer (anode buffer layer) and an electron injection layer (cathode buffer layer).

  The details of the anode buffer layer (hole injection layer) are described in JP-A-9-45479, JP-A-9-260062, JP-A-8-288069 and the like. As a specific example, copper phthalocyanine is used. Representative phthalocyanine buffer layer, hexaazatriphenylene derivative buffer layer, oxide buffer layer typified by vanadium oxide, amorphous carbon as described in JP-T-2003-519432 and JP-A-2006-135145 Examples thereof include a buffer layer, a polymer buffer layer using a conductive polymer such as polyaniline (emeraldine) and polythiophene, and an orthometalated complex layer represented by tris (2-phenylpyridine) iridium complex.

  The details of the cathode buffer layer (electron injection layer) are described in JP-A-6-325871, JP-A-9-17574, JP-A-10-74586, and the like. Specifically, strontium, aluminum, etc. Metal buffer layer typified by, alkali metal compound buffer layer typified by lithium fluoride and potassium fluoride, alkaline earth metal compound buffer layer typified by magnesium fluoride and cesium fluoride, typified by aluminum oxide Examples thereof include an oxide buffer layer. The buffer layer (injection layer) is preferably a very thin film, and the layer thickness is preferably in the range of 0.1 nm to 5 μm although it depends on the material.

<Blocking layer: hole blocking layer, electron blocking layer>
The blocking layer is provided as necessary in addition to the basic constituent layer of the organic compound thin film as described above. For example, it is described in JP-A Nos. 11-204258, 11-204359, and “Organic EL elements and their forefront of industrialization” (issued by NTT, Inc. on November 30, 1998). There is a hole blocking (hole blocking) layer.

  The hole blocking layer has a function of an electron transport layer in a broad sense, and is made of a hole blocking material that has a function of transporting electrons and has a remarkably small ability to transport holes. The probability of recombination of electrons and holes can be improved by blocking.

  Moreover, the structure of the electron carrying layer mentioned above can be used as a hole-blocking layer as needed.

  The hole blocking layer of the organic EL device of the present invention is preferably provided adjacent to the light emitting layer.

  The hole blocking layer includes a carbazole derivative, a carboline derivative, a diazacarbazole derivative (the diazacarbazole derivative is a nitrogen atom in which any one of carbon atoms constituting the carboline ring is cited as the host compound described above. It is preferable to contain (represented by).

  Further, in the present invention, when a plurality of light emitting layers having different emission colors are provided, the light emitting layer having the shortest wavelength of the light emission maximum wavelength (shortest wave layer) is closest to the anode among all the light emitting layers. preferable. In such a case, it is preferable to additionally provide a hole blocking layer between the shortest wave layer and the light emitting layer next to the anode next to the shortest wave layer. Further, it is preferable that 50% by mass or more of the compound contained in the hole blocking layer provided at this position has an ionization potential of 0.3 eV or more larger than the host compound of the shortest wave emitting layer.

  The ionization potential is defined by the energy required to emit electrons at the HOMO (highest occupied orbital) level of the compound to the vacuum level, and can be determined by, for example, the following method.

  (1) Using Gaussian 98 (Gaussian 98, Revision A.11.4, MJ Frisch, et al, Gaussian, Inc., Pittsburgh PA, 2002.), a molecular orbital calculation software manufactured by Gaussian, USA As a value (eV unit converted value) calculated by performing structure optimization using B3LYP / 6-31G *. This calculation value is effective because the correlation between the calculation value obtained by this method and the experimental value is high.

  (2) The ionization potential can also be obtained by a method of directly measuring by photoelectron spectroscopy. For example, a method known as ultraviolet photoelectron spectroscopy can be suitably used by using a low energy electron spectrometer “Model AC-1” manufactured by Riken Keiki Co., Ltd.

  On the other hand, the electron blocking layer has a function of a hole transport layer in a broad sense, and is made of a material that has a function of transporting holes and has an extremely small ability to transport electrons, and transports electrons while transporting holes. By blocking, the recombination probability of electrons and holes can be improved.

  Moreover, the structure of the positive hole transport layer mentioned later can be used as an electron blocking layer as needed. The layer thickness of the hole blocking layer and electron transport layer that can be used in the present invention is preferably 3 to 100 nm, and more preferably 5 to 30 nm.

《Hole transport layer》
The hole transport layer is made of a hole transport material having a function of transporting holes, and in a broad sense, a hole injection layer and an electron blocking layer are also included in the hole transport layer. The hole transport layer can be provided as a single layer or a plurality of layers.

  The hole transport material has any of hole injection or transport and electron barrier properties, and may be either organic or inorganic. For example, triazole derivatives, oxadiazole derivatives, imidazole derivatives, polyarylalkane derivatives, pyrazoline derivatives and pyrazolone derivatives, phenylenediamine derivatives, arylamine derivatives, amino-substituted chalcone derivatives, oxazole derivatives, styrylanthracene derivatives, fluorenone derivatives, hydrazone derivatives, Examples thereof include stilbene derivatives, silazane derivatives, aniline copolymers, and conductive polymer oligomers, particularly thiophene oligomers.

  Further, azatriphenylene derivatives such as those described in JP-T-2003-519432 and JP-A-2006-135145 can also be used as a hole transport material.

  The above-mentioned materials can be used as the hole transport material, but it is preferable to use a porphyrin compound, an aromatic tertiary amine compound and a styrylamine compound, particularly an aromatic tertiary amine compound.

  Representative examples of aromatic tertiary amine compounds and styrylamine compounds include N, N, N ', N'-tetraphenyl-4,4'-diaminophenyl; N, N'-diphenyl-N, N'- Bis (3-methylphenyl)-[1,1′-biphenyl] -4,4′-diamine (TPD); 2,2-bis (4-di-p-tolylaminophenyl) propane; 1,1-bis (4-di-p-tolylaminophenyl) cyclohexane; N, N, N ′, N′-tetra-p-tolyl-4,4′-diaminobiphenyl; 1,1-bis (4-di-p-tolyl) Aminophenyl) -4-phenylcyclohexane; bis (4-dimethylamino-2-methylphenyl) phenylmethane; bis (4-di-p-tolylaminophenyl) phenylmethane; N, N'-diphenyl-N, N ' − (4-methoxyphenyl) -4,4'-diaminobiphenyl; N, N, N ', N'-tetraphenyl-4,4'-diaminodiphenyl ether; 4,4'-bis (diphenylamino) quadriphenyl; N, N, N-tri (p-tolyl) amine; 4- (di-p-tolylamino) -4 '-[4- (di-p-tolylamino) styryl] stilbene; 4-N, N-diphenylamino- (2-diphenylvinyl) benzene; 3-methoxy-4'-N, N-diphenylaminostilbene; N-phenylcarbazole and also two condensations described in US Pat. No. 5,061,569 Having an aromatic ring in the molecule, for example, 4,4'-bis [N- (1-naphthyl) -N-phenylamino] biphenyl (NPD), JP-A-4-308688 4,4 ′, 4 ″ -tris [N- (3-methylphenyl) -N-phenylamino] triphenylamine (MTDATA) in which triphenylamine units described in the publication are linked in three starburst types Etc.

  Furthermore, a polymer material in which these materials are introduced into a polymer chain or these materials are used as a polymer main chain can also be used.

  In addition, inorganic compounds such as p-type-Si and p-type-SiC can also be used as the hole injection material and the hole transport material.

  JP-A-11-251067, J. Org. Huang et. al. A so-called p-type hole transport material as described in a book (Applied Physics Letters 80 (2002), p. 139) can also be used. In the present invention, these materials are preferably used because a light-emitting element with higher efficiency can be obtained.

  The hole transport layer can be formed by thinning the hole transport material by a known method such as a vacuum deposition method, a spin coating method, a casting method, a printing method including an ink jet method, or an LB method. it can.

  Although there is no restriction | limiting in particular about the layer thickness of a positive hole transport layer, Usually, 5 nm-about 5 micrometers, Preferably it is 5-200 nm. The hole transport layer may have a single layer structure composed of one or more of the above materials.

  Alternatively, a hole transport layer having a high p property doped with impurities can be used. Examples thereof include JP-A-4-297076, JP-A-2000-196140, 2001-102175, J. Pat. Appl. Phys. 95, 5773 (2004), and the like.

  In the present invention, it is preferable to use a hole transport layer having such a high p property because a device with lower power consumption can be produced.

"anode"
As the anode in the organic EL element, an electrode material made of a metal, an alloy, an electrically conductive compound, or a mixture thereof having a high work function (4 eV or more) is preferably used. Specific examples of such electrode materials include metals such as Au, and conductive transparent materials such as CuI, indium tin oxide (ITO), SnO ₂ , and ZnO.

Alternatively, an amorphous material such as IDIXO (In ₂ O ₃ —ZnO) capable of forming a transparent conductive film may be used. The anode may be formed by depositing a thin film of these electrode materials by vapor deposition or sputtering, and a pattern having a desired shape may be formed by photolithography, or when pattern accuracy is not so high (about 100 μm or more) A pattern may be formed through a mask having a desired shape at the time of vapor deposition or sputtering of the electrode material.

  Or when using the substance which can be apply | coated like an organic electroconductivity compound, wet film-forming methods, such as a printing system and a coating system, can also be used. When light emission is extracted from the anode, it is desirable that the transmittance be greater than 10%, and the sheet resistance as the anode is preferably several hundred Ω / □ or less. Further, although the layer thickness depends on the material, it is usually selected in the range of 10 to 1000 nm, preferably 10 to 200 nm.

《Support substrate》
The support substrate (hereinafter also referred to as a substrate) that can be used in the organic EL device of the present invention is not particularly limited in the type of glass, plastic, etc., and may be transparent or opaque. When extracting light from the support substrate side, the support substrate is preferably transparent. Examples of the transparent support substrate preferably used include glass, quartz, and a transparent resin film. A particularly preferable support substrate is a resin film capable of giving flexibility to the organic EL element.

  Examples of the resin film include polyesters such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyethylene, polypropylene, cellophane, cellulose diacetate, cellulose triacetate (TAC), cellulose acetate butyrate, cellulose acetate propionate ( CAP), cellulose esters such as cellulose acetate phthalate, cellulose nitrate or derivatives thereof, polyvinylidene chloride, polyvinyl alcohol, polyethylene vinyl alcohol, syndiotactic polystyrene, polycarbonate, norbornene resin, polymethylpentene, polyether ketone, polyimide , Polyethersulfone (PES), polyphenylene sulfide, polysulfones, Cycloolefin resins such as polyetherimide, polyetherketoneimide, polyamide, fluororesin, nylon, polymethylmethacrylate, acrylic or polyarylate, Arton (trade name, manufactured by JSR) or Appel (trade name, manufactured by Mitsui Chemicals) Can be mentioned.

An inorganic film, an organic film, or a hybrid film of both may be formed on the surface of the resin film, and the water vapor permeability (25 ± 0.5 ° C.) measured by a method according to JIS K 7129-1992. , Relative humidity (90 ± 2)% RH) is preferably a barrier film with 0.01 g / (m ² · 24 h) or less, and oxygen measured by a method in accordance with JIS K 7126-1987. A high barrier film having a permeability of 10 ⁻³ cm ³ / (m ² · 24 h · atm) or less and a water vapor permeability of 10 ⁻⁵ g / (m ² · 24 h) or less is preferable.

  As a material for forming the barrier film, any material may be used as long as it has a function of suppressing entry of elements that cause deterioration of elements such as moisture and oxygen. For example, silicon oxide, silicon dioxide, silicon nitride, or the like can be used. Further, in order to improve the brittleness of the film, it is more preferable to have a laminated structure of these inorganic layers and organic material layers. Although there is no restriction | limiting in particular about the lamination | stacking order of an inorganic layer and an organic layer, It is preferable to laminate | stack both alternately several times.

  The method for forming the barrier film is not particularly limited. For example, vacuum deposition, sputtering, reactive sputtering, molecular beam epitaxy, cluster ion beam, ion plating, plasma polymerization, atmospheric pressure plasma polymerization A plasma CVD method, a laser CVD method, a thermal CVD method, a coating method, or the like can be used, but an atmospheric pressure plasma polymerization method as described in JP-A-2004-68143 is particularly preferable.

  Examples of the opaque support substrate include metal plates such as aluminum and stainless steel, films, opaque resin substrates, and ceramic substrates.

  The external extraction quantum efficiency at room temperature of light emission of the organic EL device of the present invention is preferably 1% or more, and more preferably 5% or more.

  Here, external extraction quantum efficiency (%) = number of photons emitted to the outside of the organic EL element / number of electrons flowed to the organic EL element × 100.

  In addition, a hue improvement filter such as a color filter may be used in combination, or a color conversion filter that converts the emission color from the organic EL element into multiple colors using a phosphor. In the case of using a color conversion filter, the λmax of light emission of the organic EL element is preferably 480 nm or less.

<< Method for producing organic EL element >>
As an example of a method for producing an organic EL element, from anode / hole injection layer (anode buffer layer) / hole transport layer / light emitting layer / hole blocking layer / electron transport layer / electron injection layer (cathode buffer layer) / cathode A method for manufacturing the element will be described.

  First, a desired electrode material, for example, a thin film made of an anode material is formed on a suitable substrate so as to have a layer thickness of 1 μm or less, preferably 10 to 200 nm, and an anode is manufactured.

  Next, a thin film containing an organic compound such as a hole injection layer, a hole transport layer, a light emitting layer, a hole blocking layer, an electron transport layer, and an electron injection layer, which is a device material, is formed thereon.

  As a method for forming the thin film, for example, the thin film can be formed by a vacuum deposition method, a wet method (also referred to as a wet process), or the like.

  Wet methods include spin coating, casting, die coating, blade coating, roll coating, ink jet, printing, spray coating, curtain coating, and LB, but precise thin films can be formed. In view of high productivity, a method having high suitability for a roll-to-roll method such as a die coating method, a roll coating method, an ink jet method, or a spray coating method is preferable. Different film formation methods may be applied for each layer.

  Examples of the liquid medium for dissolving or dispersing the organic EL material that can be used in the present invention include ketones such as methyl ethyl ketone and cyclohexanone, fatty acid esters such as ethyl acetate, halogenated hydrocarbons such as dichlorobenzene, toluene, Aromatic hydrocarbon rings such as xylene, mesitylene and cyclohexylbenzene, aliphatic hydrocarbons such as cyclohexane, decalin and dodecane, and organic solvents such as DMF and DMSO can be used.

  Moreover, as a dispersion method, it can disperse | distribute by dispersion methods, such as an ultrasonic wave, high shear force dispersion | distribution, and media dispersion | distribution.

  After the formation of these layers, a thin film made of a cathode material is formed thereon so as to have a layer thickness of 1 μm or less, preferably in the range of 50 to 200 nm, and a desired organic EL device can be obtained by providing a cathode. .

  Alternatively, the cathode, electron injection layer, electron transport layer, hole blocking layer, light emitting layer, hole transport layer, hole injection layer, and anode can be formed in this order in the reverse order.

  The organic EL device of the present invention is preferably produced from the hole injection layer to the cathode consistently by a single evacuation, but it may be taken out halfway and subjected to different film forming methods. At that time, it is preferable to perform the work in a dry inert gas atmosphere.

<Sealing>
As a sealing means used for this invention, the method of adhere | attaching a sealing member, an electrode, and a support substrate with an adhesive agent can be mentioned, for example.

  As a sealing member, it should just be arrange | positioned so that the display area | region of an organic EL element may be covered, and concave plate shape or flat plate shape may be sufficient. Further, transparency and electrical insulation are not particularly limited.

  Specific examples include a glass plate, a polymer plate / film, and a metal plate / film. Examples of the glass plate include soda-lime glass, barium / strontium-containing glass, lead glass, aluminosilicate glass, borosilicate glass, barium borosilicate glass, and quartz.

  Examples of the polymer plate include those formed from polycarbonate, acrylic, polyethylene terephthalate, polyether sulfide, polysulfone and the like.

  Examples of the metal plate include those made of one or more metals or alloys selected from the group consisting of stainless steel, iron, copper, aluminum, magnesium, nickel, zinc, chromium, titanium, molybdenum, silicon, germanium, and tantalum.

  In the present invention, a polymer film and a metal film can be preferably used because the element can be thinned.

Further, the polymer film has an oxygen permeability measured by a method according to JIS K 7126-1987 of 1 × 10 ⁻³ cm ³ / (m ² · 24 h · atm) or less, and conforms to JIS K 7129-1992. The water vapor permeability (25 ± 0.5 ° C., relative humidity (90 ± 2)% RH) measured by the method is preferably 1 × 10 ⁻³ g / (m ² · 24 h) or less. .

  For processing the sealing member into a concave shape, sandblasting, chemical etching, or the like is used.

  Specific examples of the adhesive include photocuring and thermosetting adhesives having reactive vinyl groups such as acrylic acid oligomers and methacrylic acid oligomers, and moisture curing adhesives such as 2-cyanoacrylates. be able to. Moreover, heat | fever and chemical curing types (two-component mixing), such as an epoxy type, can be mentioned. Moreover, hot-melt type polyamide, polyester, and polyolefin can be mentioned. Moreover, a cationic curing type ultraviolet curing epoxy resin adhesive can be mentioned.

  In addition, since an organic EL element may deteriorate by heat processing, what can be adhesive-hardened from room temperature to 80 degreeC is preferable. A desiccant may be dispersed in the adhesive. Application | coating of the adhesive agent to a sealing part may use commercially available dispenser, and may print like screen printing.

  In addition, it is also preferable that the electrode and the organic layer are coated on the outside of the electrode facing the support substrate with the organic layer interposed therebetween, and an inorganic or organic layer is formed in contact with the support substrate to form a sealing film. . In this case, the material for forming the film may be any material that has a function of suppressing intrusion of elements that cause deterioration of elements such as moisture and oxygen. For example, silicon oxide, silicon dioxide, silicon nitride, or the like may be used. it can.

  Further, in order to improve the brittleness of the film, it is preferable to have a laminated structure of these inorganic layers and layers made of organic materials. The method for forming these films is not particularly limited. For example, vacuum deposition, sputtering, reactive sputtering, molecular beam epitaxy, cluster ion beam, ion plating, plasma polymerization, atmospheric pressure plasma A combination method, a plasma CVD method, a laser CVD method, a thermal CVD method, a coating method, or the like can be used.

  In the gap between the sealing member and the display area of the organic EL element, an inert gas such as nitrogen or argon, or an inert liquid such as fluorinated hydrocarbon or silicon oil can be injected in the gas phase and liquid phase. preferable. A vacuum is also possible. Moreover, a hygroscopic compound can also be enclosed inside.

  Examples of the hygroscopic compound include metal oxides (for example, sodium oxide, potassium oxide, calcium oxide, barium oxide, magnesium oxide, aluminum oxide) and sulfates (for example, sodium sulfate, calcium sulfate, magnesium sulfate, cobalt sulfate). Etc.), metal halides (eg calcium chloride, magnesium chloride, cesium fluoride, tantalum fluoride, cerium bromide, magnesium bromide, barium iodide, magnesium iodide etc.), perchloric acids (eg perchloric acid) Barium, magnesium perchlorate, and the like), and anhydrous salts are preferably used in sulfates, metal halides, and perchloric acids.

《Protective film, protective plate》
In order to increase the mechanical strength of the element, a protective film or a protective plate may be provided on the outer side of the sealing film on the side facing the support substrate with the organic layer interposed therebetween or on the sealing film. In particular, when the sealing is performed by the sealing film, the mechanical strength is not necessarily high, and thus it is preferable to provide such a protective film and a protective plate. As a material that can be used for this, the same glass plate, polymer plate / film, metal plate / film, etc. used for the sealing can be used, but the polymer film is light and thin. Is preferably used.

《Light extraction》
The organic EL element emits light inside a layer having a refractive index higher than that of air (refractive index is about 1.7 to 2.1) and can extract only about 15% to 20% of the light generated in the light emitting layer. It is generally said. This is because light incident on the interface (interface between the transparent substrate and air) at an angle θ greater than the critical angle causes total reflection and cannot be taken out of the device, or between the transparent electrode or light emitting layer and the transparent substrate. This is because the light is totally reflected between the light and the light is guided through the transparent electrode or the light emitting layer, and as a result, the light escapes in the direction of the element side surface.

  As a method for improving the light extraction efficiency, for example, a method of forming irregularities on the surface of the transparent substrate to prevent total reflection at the interface between the transparent substrate and the air (US Pat. No. 4,774,435), A method of improving efficiency by providing a light collecting property to a substrate (Japanese Patent Laid-Open No. 63-314795), a method of forming a reflective surface on a side surface of an element (Japanese Patent Laid-Open No. 1-220394), and light emission from a substrate A method of forming an antireflection film by introducing a flat layer having an intermediate refractive index between the bodies (Japanese Patent Laid-Open No. 62-172691), a flat having a lower refractive index between the substrate and the light emitter than the substrate A method of introducing a layer (Japanese Patent Laid-Open No. 2001-202827), a method of forming a diffraction grating between any one of a substrate, a transparent electrode layer and a light emitting layer (including between the substrate and the outside) (Japanese Patent Laid-Open No. 11-283951) Gazette).

  In the present invention, these methods can be used in combination with the organic EL device of the present invention. However, a method of introducing a flat layer having a lower refractive index than the substrate between the substrate and the light emitter, or a substrate, a transparent electrode A method of forming a diffraction grating between any of the layers and the light emitting layer (including between the substrate and the outside) can be suitably used.

  In the present invention, by combining these means, it is possible to obtain an element having higher luminance or durability.

  When a medium with a low refractive index is formed between the transparent electrode and the transparent substrate with a thickness longer than the wavelength of light, the light extracted from the transparent electrode has a higher extraction efficiency to the outside as the refractive index of the medium is lower. .

  Examples of the low refractive index layer include aerogel, porous silica, magnesium fluoride, and a fluorine-based polymer. Since the refractive index of the transparent substrate is generally about 1.5 to 1.7, the low refractive index layer preferably has a refractive index of about 1.5 or less. Further, it is preferably 1.35 or less.

  Further, the thickness of the low refractive index medium is preferably at least twice the wavelength in the medium. This is because the effect of the low-refractive index layer is reduced when the thickness of the low-refractive index medium is about the wavelength of light and the thickness of the electromagnetic wave exuded by evanescent enters the substrate.

  The method of introducing a diffraction grating into an interface or any medium that causes total reflection is characterized by a high effect of improving light extraction efficiency. This method uses the property that the diffraction grating can change the direction of light to a specific direction different from refraction by so-called Bragg diffraction such as first-order diffraction and second-order diffraction. Of these, light that cannot go out due to total reflection between layers, etc. is diffracted by introducing a diffraction grating into any layer or medium (inside a transparent substrate or transparent electrode). I want to take it out.

  The introduced diffraction grating desirably has a two-dimensional periodic refractive index. This is because light emitted from the light-emitting layer is randomly generated in all directions, so in a general one-dimensional diffraction grating having a periodic refractive index distribution only in a certain direction, only light traveling in a specific direction is diffracted. Therefore, the light extraction efficiency does not increase so much.

  However, by making the refractive index distribution a two-dimensional distribution, light traveling in all directions is diffracted, and light extraction efficiency is increased.

  As described above, the position where the diffraction grating is introduced may be in any one of the layers or in the medium (in the transparent substrate or the transparent electrode), but is preferably in the vicinity of the organic light emitting layer where light is generated.

  At this time, the period of the diffraction grating is preferably about 1/2 to 3 times the wavelength of light in the medium.

  The arrangement of the diffraction grating is preferably two-dimensionally repeated such as a square lattice, a triangular lattice, or a honeycomb lattice.

<Condenser sheet>
The organic EL element of the present invention can be processed on a light extraction side of a substrate, for example, by providing a microlens array-like structure, or combined with a so-called condensing sheet, for example in a specific direction, for example, with respect to the element light emitting surface. By condensing in the front direction, the luminance in a specific direction can be increased.

  As an example of the microlens array, quadrangular pyramids having a side of 30 μm and an apex angle of 90 degrees are arranged two-dimensionally on the light extraction side of the substrate. One side is preferably 10 μm to 100 μm. If it becomes smaller than this, the effect of diffraction will generate | occur | produce and color, and if too large, thickness will become thick and is not preferable.

  As the condensing sheet, for example, a sheet that is put into practical use in an LED backlight of a liquid crystal display device can be used. As such a sheet, for example, a brightness enhancement film (BEF) manufactured by Sumitomo 3M Limited can be used.

  As the shape of the prism sheet, for example, a triangular stripe having a vertex angle of 90 degrees and a pitch of 50 μm may be formed on the substrate, the vertex angle may be rounded, and the pitch may be changed randomly. Other shapes may be used.

  Moreover, in order to control the light emission angle from a light emitting element, you may use together a light diffusing plate and a film with a condensing sheet. For example, a diffusion film (light-up) manufactured by Kimoto Co., Ltd. can be used.

<Application>
The organic EL element of the present invention can be used as a display device, a display, and various light emission sources. For example, lighting devices (home lighting, interior lighting), clock and liquid crystal backlights, billboard advertisements, traffic lights, light sources of optical storage media, light sources of electrophotographic copying machines, light sources of optical communication processors, light Although the light source of a sensor etc. are mentioned, It is not limited to this, Especially, it can use effectively for the use as a backlight of a liquid crystal display device, and a light source for illumination.

  In the organic EL element of the present invention, patterning may be performed by a metal mask, an ink jet printing method, or the like as needed during film formation. In the case of patterning, only the electrode may be patterned, the electrode and the light emitting layer may be patterned, or the entire layer of the element may be patterned. In the fabrication of the element, a conventionally known method is used. Can do.

  The light emission color of the organic EL device of the present invention and the compound according to the present invention is shown in FIG. 4.16 on page 108 of “New Color Science Handbook” (edited by the Japan Color Society, University of Tokyo Press, 1985). It is determined by the color when the result measured with a total CS-1000 (manufactured by Konica Minolta Optics Co., Ltd.) is applied to the CIE chromaticity coordinates.

Further, when the organic EL element of the present invention is a white element, white means that the chromaticity in the CIE1931 color system at 1000 cd / m ² is x when the 2 ° viewing angle front luminance is measured by the above method. = 0.33 ± 0.07, y = 0.33 ± 0.1.

<Display device>
The display device of the present invention will be described. The display device of the present invention comprises the organic EL element of the present invention. Although the display device of the present invention may be single color or multicolor, the multicolor display device will be described here.

  In the case of a multicolor display device, a shadow mask is provided only at the time of forming a light emitting layer, and a film can be formed on one surface by vapor deposition, casting, spin coating, ink jet, printing, or the like.

  In the case of patterning only the light emitting layer, the method is not limited, but preferably the vapor deposition method, the ink jet method, the spin coating method, and the printing method.

  The configuration of the organic EL element provided in the display device is selected from the above-described configuration examples of the organic EL element as necessary.

  Moreover, the manufacturing method of an organic EL element is as having shown to the one aspect | mode of manufacture of the organic EL element of said invention.

  When a DC voltage is applied to the multicolor display device thus obtained, light emission can be observed when a voltage of about 2 V to 40 V is applied with the positive polarity of the anode and the negative polarity of the cathode. Further, even when a voltage is applied with the opposite polarity, no current flows and no light emission occurs. Further, when an AC voltage is applied, light is emitted only when the anode is in the + state and the cathode is in the-state. The alternating current waveform to be applied may be arbitrary.

  The multicolor display device can be used as a display device, a display, and various light emission sources. In display devices and displays, full-color display is possible by using three types of organic EL elements of blue, red, and green light emission.

  Examples of the display device and display include a television, a personal computer, a mobile device, an AV device, a character broadcast display, and an information display in an automobile. In particular, it may be used as a display device for reproducing still images and moving images, and the driving method when used as a display device for reproducing moving images may be either a simple matrix (passive matrix) method or an active matrix method.

  Light sources include home lighting, interior lighting, clock and liquid crystal backlights, billboard advertisements, traffic lights, light sources for optical storage media, light sources for electrophotographic copying machines, light sources for optical communication processors, light sources for optical sensors, etc. The present invention is not limited to these examples.

  Hereinafter, an example of a display device having the organic EL element of the present invention will be described with reference to the drawings.

  FIG. 1 is a schematic view showing an example of a display device composed of organic EL elements. It is a schematic diagram of a display such as a mobile phone that displays image information by light emission of an organic EL element.

  The display 1 includes a display unit A having a plurality of pixels, a control unit B that performs image scanning of the display unit A based on image information, and the like. The control unit B is electrically connected to the display unit A, and sends a scanning signal and an image data signal to each of a plurality of pixels based on image information from the outside, and the pixels for each scanning line respond to the image data signal by the scanning signal. The image information is sequentially emitted to scan the image and display the image information on the display unit A.

  FIG. 2 is a schematic diagram of the display unit A.

  The display unit A includes a wiring unit including a plurality of scanning lines 5 and data lines 6, a plurality of pixels 3 and the like on a substrate. The main members of the display unit A will be described below.

  FIG. 2 shows a case where the light emitted from the pixel 3 is extracted in the direction of the white arrow (downward). The scanning line 5 and the plurality of data lines 6 in the wiring portion are each made of a conductive material, and the scanning lines 5 and the data lines 6 are orthogonal to each other in a grid pattern and are connected to the pixels 3 at the orthogonal positions (details are illustrated). Not)

  When a scanning signal is applied from the scanning line 5, the pixel 3 receives an image data signal from the data line 6 and emits light according to the received image data. Full-color display is possible by appropriately arranging pixels in the red region, the green region, and the blue region on the same substrate.

  Next, the light emission process of the pixel will be described. FIG. 3 is a schematic diagram showing a pixel circuit.

  The pixel includes an organic EL element 10, a switching transistor 11, a driving transistor 12, a capacitor 13, and the like. A full color display can be performed by using red, green, and blue light emitting organic EL elements as the organic EL elements 10 in a plurality of pixels, and juxtaposing them on the same substrate.

  In FIG. 3, an image data signal is applied from the control unit B to the drain of the switching transistor 11 through the data line 6. When a scanning signal is applied from the control unit B to the gate of the switching transistor 11 via the scanning line 5, the driving of the switching transistor 11 is turned on, and the image data signal applied to the drain is supplied to the capacitor 13 and the driving transistor 12. Is transmitted to the gate.

  By transmitting the image data signal, the capacitor 13 is charged according to the potential of the image data signal, and the drive of the drive transistor 12 is turned on. The drive transistor 12 has a drain connected to the power supply line 7 and a source connected to the electrode of the organic EL element 10, and the power supply line 7 connects to the organic EL element 10 according to the potential of the image data signal applied to the gate. Current is supplied.

  When the scanning signal is moved to the next scanning line 5 by the sequential scanning of the control unit B, the driving of the switching transistor 11 is turned off. However, since the capacitor 13 holds the charged potential of the image data signal even if the driving of the switching transistor 11 is turned off, the driving of the driving transistor 12 is kept on and the next scanning signal is applied. Until then, the light emission of the organic EL element 10 continues. When the scanning signal is next applied by sequential scanning, the driving transistor 12 is driven according to the potential of the next image data signal synchronized with the scanning signal, and the organic EL element 10 emits light.

  That is, the light emission of the organic EL element 10 is performed by providing the switching transistor 11 and the drive transistor 12 which are active elements with respect to the organic EL element 10 of each of the plurality of pixels, and the light emission of the organic EL element 10 of each of the plurality of pixels 3. It is carried out. Such a light emitting method is called an active matrix method.

  Here, the light emission of the organic EL element 10 may be light emission of a plurality of gradations by a multi-value image data signal having a plurality of gradation potentials, or by turning on / off a predetermined light emission amount by a binary image data signal. Good. The potential of the capacitor 13 may be held continuously until the next scanning signal is applied, or may be discharged immediately before the next scanning signal is applied.

  In the present invention, not only the active matrix method described above, but also a passive matrix light emission drive in which the organic EL element emits light according to the data signal only when the scanning signal is scanned.

  FIG. 4 is a schematic diagram of a passive matrix display device. In FIG. 4, a plurality of scanning lines 5 and a plurality of image data lines 6 are provided in a lattice shape so as to face each other with the pixel 3 interposed therebetween.

  When the scanning signal of the scanning line 5 is applied by sequential scanning, the pixels 3 connected to the applied scanning line 5 emit light according to the image data signal.

  In the passive matrix system, the pixel 3 has no active element, and the manufacturing cost can be reduced.

《Lighting device》
The lighting device of the present invention will be described. The lighting device of the present invention comprises the organic EL element of the present invention.

  The organic EL element of the present invention may be used as an organic EL element having a resonator structure. The purpose of use of the organic EL element having such a resonator structure is as follows. The light source of a machine, the light source of an optical communication processing machine, the light source of a photosensor, etc. are mentioned, However, It is not limited to these. Moreover, you may use for the said use by making a laser oscillation.

  Further, the organic EL element of the present invention may be used as a kind of lamp for illumination or exposure light source, a projection device for projecting an image, or a display for directly viewing a still image or a moving image. It may be used as a device (display).

  The driving method when used as a display device for moving image reproduction may be either a simple matrix (passive matrix) method or an active matrix method. Alternatively, it is possible to produce a full-color display device by using two or more organic EL elements of the present invention having different emission colors.

  The organic EL material of the present invention can be applied to an organic EL element that emits substantially white light as a lighting device. A plurality of light emitting colors are simultaneously emitted by a plurality of light emitting materials to obtain white light emission by color mixing. The combination of a plurality of emission colors may include three emission maximum wavelengths of the three primary colors of red, green, and blue, or two of the complementary colors such as blue and yellow, blue green and orange, etc. The thing containing the light emission maximum wavelength may be used.

  In addition, a combination of light emitting materials for obtaining a plurality of emission colors is a combination of a plurality of phosphorescent or fluorescent materials, a light emitting material that emits fluorescence or phosphorescence, and light from the light emitting material as excitation light. Any of those combined with a dye material that emits light may be used, but in the white organic EL device according to the present invention, only a combination of a plurality of light-emitting dopants may be mixed.

  It is only necessary to provide a mask only when forming a light emitting layer, a hole transport layer, an electron transport layer, etc., and simply arrange them separately by coating with the mask. Since other layers are common, patterning of the mask or the like is not necessary. In addition, for example, an electrode film can be formed by a vapor deposition method, a cast method, a spin coating method, an ink jet method, a printing method, or the like, and productivity is also improved.

  According to this method, unlike a white organic EL device in which light emitting elements of a plurality of colors are arranged in parallel in an array, the elements themselves are luminescent white.

  There is no restriction | limiting in particular as a luminescent material used for a light emitting layer, For example, if it is a backlight in a liquid crystal display element, the metal complex which concerns on this invention so that it may suit the wavelength range corresponding to CF (color filter) characteristic, Any one of known luminescent materials may be selected and combined to whiten.

<< One Embodiment of Lighting Device of the Present Invention >>
One aspect of the lighting device of the present invention that includes the organic EL element of the present invention will be described.

  The non-light emitting surface of the organic EL device of the present invention is covered with a glass case, a 300 μm thick glass substrate is used as a sealing substrate, and an epoxy photocurable adhesive (LUX The track LC0629B) is applied, and this is overlaid on the cathode and brought into close contact with the transparent support substrate, irradiated with UV light from the glass substrate side, cured, sealed, and illuminated as shown in FIGS. A device can be formed.

  FIG. 5 shows a schematic diagram of a lighting device, and the organic EL element 101 of the present invention is covered with a glass cover 102 (in addition, the sealing operation with the glass cover is to bring the organic EL element 101 into contact with the atmosphere. And a glove box under a nitrogen atmosphere (in an atmosphere of high-purity nitrogen gas having a purity of 99.999% or more).

  FIG. 6 shows a cross-sectional view of the lighting device. In FIG. 6, 105 denotes a cathode, 106 denotes an organic EL layer, and 107 denotes a glass substrate with a transparent electrode. The glass cover 102 (see FIG. 5) is filled with nitrogen gas 108 and a water catching agent 109 is provided.

  EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto. In addition, although the display of "part" or "%" is used in an Example, unless otherwise indicated, "part by mass" or "mass%" is represented.

  The structures of the compounds used in the examples described below are shown below.

Example 1
<< Production of Organic EL Element 1-1 >>
After patterning on a substrate (NH Techno Glass, NA45) in which ITO (Indium Tin Oxide) 100 nm was formed as an anode on a 100 mm × 100 mm × 1.1 mm glass substrate, this ITO transparent The transparent support substrate provided with the electrodes was ultrasonically cleaned with isopropyl alcohol, dried with dry nitrogen gas, and subjected to UV ozone cleaning for 5 minutes.

  A solution obtained by diluting poly (3,4-ethylenedioxythiophene) -polystyrene sulfonate (PEDOT / PSS, manufactured by HC Starck Co., Ltd., CLEVIO P VP AI 4083) with pure water on this transparent support substrate to 70%. After forming a thin film by spin coating at 3000 rpm for 30 seconds, the film was dried at 200 ° C. for 1 hour to provide a first hole transport layer having a layer thickness of 20 nm.

  This transparent support substrate is fixed to a substrate holder of a commercially available vacuum deposition apparatus, while 200 mg of α-NPD is placed in a molybdenum resistance heating boat as a hole transport material, and OC- 200 mg of 30 was put, 200 mg of ET-8 as an electron transport material was put in another resistance heating boat made of molybdenum, and 100 mg of comparative compound A was put as a luminescent dopant in another resistance heating boat made of molybdenum, and attached to a vacuum deposition apparatus.

Next, the pressure in the vacuum chamber was reduced to 4 × 10 ⁻⁴ Pa, and the heating boat containing α-NPD was energized and heated, evaporated on the transparent support substrate at a deposition rate of 0.1 nm / second, and a layer thickness of 20 nm. The second hole transport layer was provided.

  Further, the second hole injection layer was heated by energizing the heating boat containing OC-30 as a host compound and comparative compound A as a luminescent dopant, respectively, at a deposition rate of 0.1 nm / second and 0.006 nm / second, respectively. A light-emitting layer having a layer thickness of 40 nm was provided by co-evaporation.

  Furthermore, the heating boat containing ET-8 was energized and heated, and deposited on the light emitting layer at a deposition rate of 0.1 nm / second to provide an electron transport layer having a layer thickness of 30 nm.

  In addition, the substrate temperature at the time of vapor deposition was room temperature.

  Subsequently, lithium fluoride was vapor-deposited to form a cathode buffer layer having a layer thickness of 0.5 nm, and aluminum was further vapor-deposited to form a cathode having a layer thickness of 110 nm. Thus, an organic EL element 1-1 was produced.

<< Production of Organic EL Elements 1-2 to 1-27 >>
In the production of the organic EL element 1-1, organic EL elements 1-2 to 1-27 were produced in the same manner except that the host compound and the light emitting dopant in the light emitting layer were changed to the compounds shown in Table 1.

<< Evaluation of Organic EL Elements 1-1 to 1-27 >>
When evaluating the obtained organic EL elements 1-1 to 1-27, the non-light-emitting surface of each organic EL element after production was covered with a glass case, and a glass substrate having a thickness of 300 μm was used as a sealing use substrate. An epoxy photo-curing adhesive (Luxtrac LC0629B, manufactured by Toagosei Co., Ltd.) is applied as a sealant around the periphery, and this is placed on the cathode so as to be in close contact with the transparent support substrate and irradiated with UV light from the glass substrate side. Then, it was cured and sealed, and a lighting device as shown in FIGS. 5 and 6 was produced and evaluated.

  The following evaluation was performed for each sample thus produced. The evaluation results are shown in Table 1.

  Subsequently, the following evaluation was performed.

(Luminescence efficiency)
The organic EL device is turned on under a constant current condition of 24 ° C. and ^2.5 mA / cm ² , and the light emission luminance (L) [cd / m ² ] immediately after the start of lighting is measured, whereby the external extraction quantum efficiency (η ) Was calculated as a measure of luminous efficiency.

  Here, the measurement of emission luminance was performed using a spectral radiance meter CS-1000 (manufactured by Konica Minolta Optics), and the external extraction quantum efficiency was expressed as a relative value where the organic EL element 1-1 was 100.

(Half life)
Each organic EL device driven with a constant current at a current giving an initial luminance 1000 cd / ^{m 2,} obtains the time to be 1/2 (500cd / ^{m 2)} of the initial luminance, which was used as a measure of the half-life. The half life was expressed as a relative value with the organic EL element 1-1 as 100.

(Stability over time)
After storing the organic EL element at 60 ° C. for 24 hours, each power efficiency before and after storage was determined, and each power efficiency ratio was determined according to the following formula, which was used as a measure of stability over time.

Stability over time (%) = (power efficiency after storage / power efficiency before storage) × 100
In addition, power efficiency measures the front luminance and luminance angle dependence of each organic EL element using a spectral radiance meter CS-1000 (manufactured by Konica Minolta Sensing Co., Ltd.), and obtains power efficiency at a front luminance of 1000 cd / m ² . It was.

(Sublimation)
For each of the organic EL elements 1-1 to 1-18, five elements having the same configuration were produced using the same vapor deposition boat (molybdenum resistance heating boat) (for example, organic EL elements 1-1, 1-1b, 1-1c, 1-1d and 1-1e).

  The half-life of each of the first fabricated element (for example, the organic EL element 1-1) and the fifth fabricated element (for example, the organic EL element 1-1e) is measured by the same method as described above. The decrease in half-life was determined according to the formula.

Reduction in half-life (%) = (half-life of fifth-fabricated device / half-life of first-fabricated device) × 100

As is clear from Table 1, the organic EL elements 1-3 and 1-8 to 1-27 of the present invention have higher luminous efficiency and longer length than the organic EL elements 1-1 and 1-2 of the comparative example. It can be seen that the characteristics as an element have been improved, such as a long lifetime and excellent stability over time. Furthermore, the organic EL elements 1-1 and 1-2 of the comparative example have a large decrease in half-life of the element manufactured for the fifth time, compared to the element manufactured for the first time. The organic EL elements 1-3 and 1-8 to 1-27 are used for the organic EL element of the present invention because the half-life of the first and fifth elements is suppressed. It can be seen that the light emitting dopant is excellent in sublimation.

(Example 2)
<< Production of organic EL element 2-1 >>
After patterning on a 100 mm × 100 mm × 1.1 mm glass substrate with a 100 nm ITO (indium tin oxide) film as an anode (AvanStrate, NA-45), this ITO transparent electrode is provided The transparent support substrate was ultrasonically cleaned with isopropyl alcohol, dried with dry nitrogen gas, and subjected to UV ozone cleaning for 5 minutes.

  On this transparent support substrate, using a solution obtained by diluting poly (3,4-ethylenedioxythiophene) -polystyrene sulfonate (PEDOT / PSS, manufactured by Bayer, Baytron P Al 4083) to 70% with pure water, 3000 rpm After forming a thin film by spin coating under the condition of 30 seconds, the film was dried at 200 ° C. for 1 hour to provide a first hole transport layer having a layer thickness of 30 nm.

  On the first hole transport layer, a hole transport material Poly (N, N′-bis (4-butylphenyl) -N, N′-bis (phenyl)) benzidine (manufactured by American Dye Source, ADS- A thin film was formed by spin coating using the chlorobenzene solution of No. 254). Heat drying at 150 ° C. for 1 hour to provide a second hole transport layer having a layer thickness of 40 nm.

  On this 2nd hole transport layer, using OC-11 as a host compound and the butyl acetate solution of the comparison compound A as a light emission dopant, a thin film is formed by a spin coat method, and it heat-drys at 120 degreeC for 1 hour, A light emitting layer having a layer thickness of 30 nm was provided.

On the light emitting layer, a 1-butanol solution of ET-11 as an electron transporting material was used, a thin film was formed by a spin coating method, and an electron transporting layer having a layer thickness of 20 nm was provided. This substrate was attached to a vacuum deposition apparatus, and the vacuum layer was depressurized to 4 × 10 ⁻⁴ Pa. Subsequently, lithium fluoride was vapor-deposited to form an electron injection layer having a layer thickness of 1.0 nm, and aluminum was further vapor-deposited to form a cathode having a layer thickness of 110 nm. Thus, an organic EL element 2-1 was produced.

<< Production of organic EL elements 2-2 to 2-18 >>
In the production of the organic EL element 2-1, organic EL elements 2-2 to 2-18 were produced in the same manner except that the host and the luminescent dopant in the light emitting layer were changed to the compounds shown in Table 2.

<< Evaluation of Organic EL Elements 2-1 to 2-18 >>
When evaluating the obtained organic EL elements 2-1 to 2-18, the organic EL elements were sealed in the same manner as the organic EL elements 1-1 to 1-27 of Example 1, and FIGS. A lighting device as shown in FIG.

  Each sample thus produced was evaluated for luminous efficiency, half-life and stability over time in the same manner as in Example 1. The evaluation results are shown in Table 2. In addition, the measurement result of the luminous efficiency in Table 2 and a half-life was represented by the relative value which sets the measured value of the organic EL element 2-1 to 100.

As is clear from Table 2, the organic EL elements 2-3 and 2-7 to 2-18 of the present invention have higher luminous efficiency and longer life than the organic EL elements 2-1 and 2-2 of the comparative example. Further, it can be seen that the characteristics as an element are improved, such as excellent stability over time.

Example 3
<< Production of Organic EL Element 3-1 >>
This ITO transparent electrode was provided after patterning on a substrate (NH Techno Glass, NA45) in which ITO (indium tin oxide) was deposited to a thickness of 100 nm on a glass substrate of 100 mm × 100 mm × 1.1 mm as an anode. The transparent support substrate was ultrasonically cleaned with isopropyl alcohol, dried with dry nitrogen gas, and subjected to UV ozone cleaning for 5 minutes.

  This transparent support substrate is fixed to a substrate holder of a commercially available vacuum deposition apparatus, while 200 mg of α-NPD is placed in a molybdenum resistance heating boat as a hole transport material, and OC- 200 mg of ET-11 as an electron transport material in another molybdenum resistance heating boat, 100 mg of Comparative Compound A as a luminescent dopant in another molybdenum resistance heating boat, and put in another molybdenum resistance heating boat 100 mg of D-10 was added as a luminescent dopant, and attached to a vacuum deposition apparatus.

Next, the pressure in the vacuum chamber was reduced to 4 × 10 ⁻⁴ Pa, and the heating boat containing α-NPD was energized and heated, evaporated on the transparent support substrate at a deposition rate of 0.1 nm / second, and a layer thickness of 20 nm. The hole transport layer was provided.

  Further, the heating boat containing OC-11 as a host compound and comparative compounds A and D-1 as luminescent dopants was energized and heated, and the deposition rates of OC-11, comparative compounds A and D-1 were 100: It adjusted so that it might be set to 5: 0.6, and it vapor-deposited on the said hole transport layer, and provided the light emitting layer with a layer thickness of 30 nm.

  Furthermore, it supplied with electricity to the said heating boat containing ET-11, it heated, and it vapor-deposited on the said light emitting layer with the vapor deposition rate of 0.1 nm / second, and provided the electron carrying layer with a layer thickness of 30 nm.

  In addition, the substrate temperature at the time of vapor deposition was room temperature.

  Subsequently, lithium fluoride was vapor-deposited to form a cathode buffer layer having a layer thickness of 0.5 nm, and aluminum was further vapor-deposited to form a cathode having a layer thickness of 110 nm, thereby producing an organic EL element 3-1. When the produced organic EL element 3-1 was energized, it was found that substantially white light was obtained and it could be used as a lighting device.

<< Production of organic EL elements 3-2 to 3-7 >>
In the production of the organic EL element 3-1, organic EL elements 3-2 to 3-7 were similarly produced except that the light emitting dopant in the light emitting layer was changed to the compounds shown in Table 3.

<< Evaluation of organic EL elements 3-1 to 3-7 >>
When evaluating the obtained organic EL elements 3-1 to 3-7, the organic EL elements were sealed in the same manner as the organic EL elements 1-1 to 1-18 of Example 1, and FIGS. A lighting device as shown in FIG.

  Each sample thus produced was evaluated for luminous efficiency, half-life and stability over time, and for thermal stability in the same manner as in Example 1. The evaluation results are shown in Table 3. In addition, the measurement results of luminous efficiency, half-life, and thermal stability in Table 3 were expressed as relative values with the measured value of the organic EL element 3-1 being 100. The thermal stability was evaluated by the following method.

(Thermal stability)
After storing the organic EL element at 60 ° C. for 24 hours, each power efficiency before and after storage was determined, and each power efficiency ratio was determined according to the following formula, which was used as a measure of stability over time.

Stability over time (%) = (power efficiency after storage / power efficiency before storage) × 100
(Measurement of chromaticity)
For each sample of the organic EL elements 3-1 to 3-7, when the luminescent color was measured using a spectral radiance meter CS-1000 (manufactured by Konica Minolta Optics, Inc.), the front luminance at a viewing angle of 2 degrees was measured. It was confirmed that the chromaticity in the CIE1931 color system at 1000 cd / m ² was in the region of x = 0.33 ± 0.07, y = 0.33 ± 0.1, and was white light.

As is clear from Table 3, the organic EL elements 3-3 and 3-5 to 3-7 of the present invention have higher luminous efficiency and longer life than the organic EL elements 3-1 to 3-2 of the comparative example. Further, it can be seen that the characteristics as an element are improved, such as excellent stability over time. Furthermore, it turns out that the light emission dopant used for the organic EL element of this invention is excellent in thermal stability.

Example 4
FIG. 7 shows a schematic configuration diagram of an organic EL full-color display device. After patterning at a pitch of 100 μm on a substrate (NA 45 manufactured by NH Techno Glass Co., Ltd.) with a 100 nm ITO transparent electrode 202 formed as an anode on a glass substrate 201 (see FIG. 7A), on this glass substrate 201 Then, a non-photosensitive polyimide partition wall 203 (width 20 μm, thickness 2.0 μm) was formed between the ITO transparent electrodes 202 by photolithography (see FIG. 7B).

  A hole injection layer composition having the following composition is ejected and injected on the ITO electrode 202 between the partition walls 203 using an inkjet head (manufactured by Epson: MJ800C), irradiated with ultraviolet light for 200 seconds, 60 ° C. A hole injection layer 204 having a layer thickness of 40 nm was provided by a drying process for 10 minutes (see FIG. 7C).

  A blue light-emitting layer composition, a green light-emitting layer composition, and a red light-emitting layer composition having the following compositions are similarly ejected and injected onto the hole injection layer 204 using an inkjet head, and dried at 60 ° C. for 10 minutes. The light emitting layers 205B, 205G, and 205R for each color were provided (see FIG. 7D).

(Hole injection layer composition)
Hole transport material 7 (Compound 7) 20 parts by mass Cyclohexylbenzene 50 parts by mass Isopropyl biphenyl 50 parts by mass (Blue light emitting layer composition)
Host material 2 0.70 parts by mass DP-11 0.04 parts by mass Cyclohexylbenzene 50 parts by mass Isopropyl biphenyl 50 parts by mass (green light emitting layer composition)
Host material 2 0.70 parts by mass D-1 0.04 parts by mass Cyclohexylbenzene 50 parts by mass Isopropyl biphenyl 50 parts by mass (red light emitting layer composition)
Host material 2 0.70 parts by mass D-10 0.04 parts by mass Cyclohexylbenzene 50 parts by mass Isopropyl biphenyl 50 parts by mass Next, an electron transport layer is deposited so as to cover each of the coloring layers 205B, 205G and 205R, and the layer thickness A 20 nm electron transport layer (not shown) is provided, lithium fluoride is further deposited to provide a cathode buffer layer (not shown) having a thickness of 0.6 nm, and Al is deposited to provide a cathode 206 having a layer thickness of 130 nm. An organic EL element was produced (see FIG. 7 (e)).

  It was found that the produced organic EL elements exhibited blue, green and red colors by applying a voltage to the electrodes, respectively, and could be used as a full color display device.

DESCRIPTION OF SYMBOLS 1 Display 3 Pixel 5 Scan line 6 Data line 7 Power supply line 10 Organic EL element 11 Switching transistor 12 Drive transistor 13 Capacitor 101 Organic EL element 102 Glass cover 105 Cathode 106 Organic EL layer 107 Glass substrate with a transparent electrode 108 Nitrogen gas 109 Water capture Agent 201 Glass substrate 202 ITO transparent electrode 203 Partition wall 204 Hole injection layer 205B, 205G, 205R Light emitting layer 206 Cathode A Display unit B Control unit

Claims (7)

An organic electroluminescence device in which an organic layer including a light emitting layer is sandwiched between an anode and a cathode, and an iridium complex represented by the following general formula (2) (provided that at least one layer constituting the organic layer ) An organic electroluminescence device comprising the following compounds S15 and S25) .

(Ra, Ra ', Rb, Rb', Rc, Rd ', Rf and Rg are each independently a halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, aryl R ₄ represents an alkyl group , an aromatic hydrocarbon ring group, an aromatic heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, and may further have a substituent. the expressed. na is .nb represents an integer of 0 to 2 representing the. nc is 0-4 integer representing an integer of 0 to 3. na 'is .nb represents an integer of 0 to 3' is 0-4 Nd ′ represents an integer of 0 to 2.
R _{1 to} R ₃ are each independently a hydrogen atom, halogen atom, cyano group, alkyl group, alkenyl group, alkynyl group, alkoxy group, amino group, silyl group, arylalkyl group, aromatic hydrocarbon ring group, aromatic Represents a heterocyclic group, a non-aromatic hydrocarbon ring group or a non-aromatic heterocyclic group, which may have a substituent. R ₁ and R ₃ do not both represent a hydrogen atom. Also, R ₁ and R ₂ are not connected to each other to form a ring.
X and Y each independently represent a single bond, CR ₅ R ₆ , NR ₇ , O, S or SiR ₈ R ₉ . R ₅ , R ₆ , R ₇ , R ₈ and R ₉ are each independently a hydrogen atom, alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon ring group, aromatic heterocyclic group or non-aromatic hydrocarbon. Represents a cyclic group or a non-aromatic heterocyclic group.
m and n represent 1 or 2. However, m + n is 3 . )

In Formula (2) The organic electroluminescent device according to claim 1, characterized in that Y represents a single bond. In the said General formula (2), X represents an oxygen atom, The organic electroluminescent element of Claim 1 or Claim 2 characterized by the above-mentioned. Wherein m is an organic electroluminescent device according to any one of claims 1 to 3, characterized in that represent 1. The organic electroluminescent device as claimed in any one of claims 1 to 4, characterized in that emits white light. An illuminating device comprising the organic electroluminescence element according to any one of claims 1 to 5 . A display device comprising the organic electroluminescence element according to any one of claims 1 to 5 .

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