JP5954362B2 - Packaging materials for electrochemical cells - Google Patents

Description

  The present invention relates to a packaging material for an electrochemical cell having an identification mark that can be recognized from the outside and difficult to counterfeit.

  In recent years, as shown in Patent Document 1, for example, a lithium ion battery, a lithium polymer battery, a fuel cell, or a liquid capacitor including a dielectric such as a liquid, a solid ceramic, an organic substance, a solid capacitor, a double layer capacitor, etc. In the electrochemical cell, a packaging material for an electrochemical cell composed of a multilayer film is used as an exterior body.

  FIG. 3 is a cross-sectional view showing a layer structure of a conventional electrochemical cell packaging material. As shown in FIG. 3, the conventional electrochemical cell packaging material 110 includes at least a base material layer 111, a metal foil layer 112, The base material layer 111 and the metal foil layer 112 are bonded via an adhesive layer 113, and the heat adhesive resin layer 115 and the metal foil layer 112 are formed of an acid-modified polyolefin layer 114. Is glued through.

  4A is an exploded perspective view of a lithium ion battery using a conventional embossed type exterior body, and FIG. 4B is a perspective view of a lithium ion battery using a conventional embossed type exterior body. It is. As shown in FIGS. 4A and 4B, in the cold press molding process, the lithium ion battery 121 is formed by cold pressing the electrochemical cell packaging material 110 shown in FIG. The lithium ion battery main body 122 is accommodated inside the tray 120a having a recess, the opening of the tray 120a is closed with the sheet 120b, and in the sealing step, the heat adhesive resin layers 115 of the tray 120a and the sheet 120b are overlapped with each other, It is produced by heat sealing the periphery.

  In the final step of battery production, the lithium ion battery 121 manufactured in this way is attached with a label on which the product information is written on the surface of the exterior body 120, or directly on the surface of the exterior body 120 by inkjet instead of the label. Product information etc. are printed.

  However, when a counterfeit lithium ion battery or electrochemical cell packaging material that is different from the authorized manufacturer is marked with the same identification mark as the authorized manufacturer, it is difficult to distinguish between the authorized and counterfeit products. It was.

JP 2007-273398 A

  Conventionally, in order to solve this problem, a method of discriminating between a regular product and a counterfeit product using a hologram label as an identification mark has been proposed. However, the hologram label increases the cost of the product, and the hologram label may be forged.

  In view of the above problems, an object of the present invention is to provide a packaging material for an electrochemical cell having an identification mark that can be recognized from the outside and difficult to counterfeit.

  To achieve the above object, the present invention provides a packaging material for an electrochemical cell, a positive electrode comprising a positive electrode active material and a positive electrode current collector, a negative electrode comprising a negative electrode active material and a negative electrode current collector, and a positive electrode and a negative electrode An electrochemical cell main body containing an electrolyte filled in between, and the electrochemical cell main body sealing the electrochemical cell main body by heat-sealing the peripheral edge, at least a base material layer, an adhesive It is a multilayer film having a structure in which an agent layer, a metal foil layer, and a heat-adhesive resin layer are laminated in this order, a base material layer has a stretched polyester film and a stretched nylon film, and a stretched polyester film and a stretched nylon film An identification mark is included between the two.

  According to this configuration, the identification mark is protected by the stretched polyester film, and the printed layer cannot be forged or processed from the outside of the packaging material for electrochemical cells. Moreover, by forming the identification mark between the stretched polyester film and the stretched nylon film, the adhesive strength between the stretched nylon film layer and the metal foil layer does not decrease. For this reason, when carrying out the press molding etc. of the packaging material for electrochemical cells, it can prevent that a base material layer and a metal foil layer peel, and a float and a wrinkle generate | occur | produce. In addition, by forming the stretched polyester film as the outermost layer, the stretched polyester film protects the stretched nylon film even when the electrolyte or solvent adheres to the surface of the electrochemical cell packaging material. Can prevent scratches and whitening.

  According to a second configuration of the present invention, in the packaging material for an electrochemical cell of the first configuration, the identification mark is configured by a printed layer provided on the stretched nylon film side surface of the stretched polyester film. To

  According to this configuration, an identification mark can be easily formed between the stretched polyester film and the stretched nylon film by printing the identification mark on the surface of the stretched polyester film and bonding the stretched polyester film and the stretched nylon film. Can do. In addition, a complicated design can be formed on the surface of the stretched polyester film by printing, and an identification mark that is difficult to forge can be formed.

  According to a third configuration of the present invention, in the electrochemical cell packaging material according to the first configuration, the identification mark is configured by a colored adhesive layer interposed between the stretched polyester film and the stretched nylon film. It is characterized by that.

  According to this configuration, a colored layer can be formed between the stretched polyester film and the stretched nylon film, and the packaging material for electrochemical cells can be identified by the colored color. For this reason, even if a label that becomes a counterfeit identification mark is attached to the packaging material for electrochemical cells or printed, the authenticity of the product is determined by the color difference that can be recognized from the appearance of the packaging material for electrochemical cells. Can be easily determined.

  According to a fourth configuration of the present invention, in the electrochemical cell packaging material according to the first configuration, the stretched polyester film has a mat varnish layer formed on a surface opposite to the surface facing the stretched nylon film. And

  According to this configuration, the matte varnish layer can be formed on the surface of the stretched polyester film, so that the matte effect can be exhibited on the surface of the base material layer. Thereby, a design can be formed in the whole base material layer together with the identification mark formed on the other surface of the stretched polyester film. Moreover, the mat | matte varnish layer increases the slipperiness of the base material layer surface, and can reduce molding defects in the embossing molding process. At this time, the slipperiness can be adjusted by adjusting the addition amount of the lubricant added to the mat varnish, and the matte effect can be adjusted by adjusting the particle size and the addition amount of the mat material.

  According to a fifth configuration of the present invention, in the electrochemical cell packaging material of the first configuration, the stretched polyester film is subjected to a mat treatment on a surface opposite to the surface facing the stretched nylon film, and the surface is It is processed to a predetermined surface roughness.

  According to this configuration, the matte treatment can be performed on the surface of the base material layer by processing the surface of the stretched polyester film to a predetermined surface roughness and performing a mat treatment. Thereby, a design can be formed in the whole base material layer together with the identification mark formed on the other surface of the stretched polyester film. Further, the matte film that has been subjected to a matte treatment by processing the surface is less likely to have a delustering effect because the surface of the base material layer is worn or pressed during press molding. Moreover, even when the solvent of an electrochemical cell adheres, a matting effect is hard to fall.

  According to a sixth aspect of the present invention, in the electrochemical cell packaging material according to the first aspect, the identification mark is partially formed in a plan view of the stretched polyester film.

  According to this configuration, it is possible to form a complicated identification mark that is difficult to forge.

These are sectional drawings which show the layer structure of the packaging material for electrochemical cells of this invention. These are sectional drawings which show the layer structure of the modification of the packaging material for electrochemical cells of this invention. These are sectional drawings which show the layer structure of the conventional packaging material for electrochemical cells. These are the exploded perspective views of the lithium ion battery using the conventional embossed type exterior body. These are perspective views of the lithium ion battery using the conventional embossed type exterior body.

  The present invention is an electrochemical cell packaging material that has an identification mark that is recognizable from the outside and difficult to counterfeit, and that does not delaminate due to heat applied in the sealing process after molding, and does not generate floats or wrinkles. This will be described in more detail below with reference to the drawings. Note that description of portions common to those in FIGS. 3 to 4 in the conventional example is omitted.

  FIG. 1 is a cross-sectional view showing the layer structure of an electrochemical cell packaging material of the present invention. As shown in FIG. 1, the electrochemical cell packaging material 10 of the present invention has a base material layer 11 and an innermost layer as an outermost layer. The heat-adhesive resin layer 15 and the metal foil layer 12 are disposed therebetween, and the heat-adhesive resin layer 15 and the metal foil layer 12 are bonded via the acid-modified polyolefin layer 14. Moreover, the base material layer 11 and the metal foil layer 12 are bonded via an adhesive layer 13. At this time, the chemical conversion treatment layer 12a is provided on the surface of the metal foil layer 12 on the acid-modified polyolefin layer 14 side. The base material layer 11 includes a mat varnish layer 11a, a stretched polyester film 11b, a printing layer 11c, an adhesive layer 11d, and a stretched nylon film 11e. In addition, the packaging material 10 for electrochemical cells of this invention shall also include the case where a different layer is interposed between each layer while including each said layer in the technical scope of this invention.

  Here, the printing layer 11c and the mat varnish layer 11a are formed by printing and applying an ink material or a mat varnish material on both sides of the stretched polyester film 11b. With this configuration, when the packaging material 10 for an electrochemical cell is viewed from the base material layer 11 side, the printed layer 11c is visually decorated with the matte varnish layer 11a. Moreover, the mat | matte varnish layer 11a increases the slipperiness of the base material layer 11 surface, and can reduce the molding defect in an embossing molding process. In addition, by adjusting the addition amount of the lubricant contained in the mat varnish material, the slipperiness of the surface of the base material layer 11 can be adjusted, and the particle size and the addition amount of the mat agent contained in the mat varnish material are adjusted. Thereby, the mat feeling (matte effect) of the mat varnish layer 11a can be adjusted.

  Moreover, since the printing layer 11c is formed on the surface of the stretched polyester film 11b on the stretched nylon film 11e side, the printing layer 11c is protected from the outside by the stretched polyester film 11b, and the printing layer 11c from the outside of the packaging material 10 for electrochemical cells. Cannot be counterfeited or rewritten. Further, even if the surface of the electrochemical cell packaging material 10 is worn, the printed layer 11c is not worn. Moreover, since the printing layer 11c is formed between the stretched polyester film 11b and the stretched nylon film 11e, the adhesive strength between the stretched nylon film 11e and the metal foil layer 12 does not decrease. For this reason, when press-molding the packaging material 10 for electrochemical cells, it can prevent that the base material layer 11 and the metal foil layer 12 peel, and a float and a wrinkle generate | occur | produce. In addition, by forming the stretched polyester film 11b as the outermost layer, the stretched polyester film 11b protects the stretched nylon film 11e even when an electrolytic solution or a solvent adheres to the surface of the packaging material 10 for electrochemical cells. Scratches and whitening of the cell packaging material 10 can be prevented.

  Further, in the plan view of the stretched polyester film 11b, if the printing layer 11 is formed as a whole, the entire packaging material 10 for electrochemical cells is colored, and if the printing layer 11 is partially formed, it is difficult to forge the printing layer 11. A unique identification mark or design can be attached. The printing layer 11c can be formed using an ink material by a conventionally known printing method such as gravure printing, silk screen printing, or offset printing.

  Here, by using a stretched polyester film in which the surface of the stretched polyester film 11b has a predetermined surface roughness in advance, the surface of the base material layer 11 can be decorated in a matte tone without forming the mat varnish layer 11a. . At this time, compared to the mat varnish layer 11a, the mat feeling (matte effect) is less likely to decrease due to wear or pressing during press molding. Moreover, even when the solvent of an electrochemical cell adheres, a mat | matte feeling (matte effect) is hard to fall.

  Next, each layer which comprises the packaging material 10 for electrochemical cells which concerns on this invention shown in FIG. 1 is demonstrated concretely.

  The mat varnish layer 11a is made of, for example, an inorganic material such as a cellulose, a polyamide, a vinyl chloride, a modified polyolefin, a rubber, an acrylic or a urethane, or an alkyd synthetic resin, a silica or a kaolin. A mat varnish to which an appropriate amount of a matting agent is added can be used. Alternatively, a mat varnish obtained by adding an appropriate amount of a matting agent and a wax of an inorganic material such as silica or kaolin to the olefin-based or alkyd-based synthetic resin can be used. The method for forming the mat varnish layer is not particularly limited. For example, an offset printing method, a gravure printing method, a flexographic printing method, a silk screen printing method, a roll coating method, a reverse coating method, or the like is appropriately used. be able to.

  As the stretched polyester film 11b, a polyester resin having a spreadability that can withstand press working can be used. Specific polyester resins include polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polybutylene naphthalate, and copolyester. And polycarbonate.

  The ink material used for the printing layer 11c can be composed of a binder, a colorant such as a pigment or a dye, and various additives that are appropriately added thereto, as in general inks. As the colorant, chromatic color pigments or inorganic color pigments can be used. Examples of chromatic color pigments include azo pigments, phthalocyanine pigments, and condensed polycyclic pigments. As soluble pigments such as Looting Red and Carmine 6C, insoluble azo pigments such as monoazo yellow, disazo yellow, pyrazolone orange, red and permanent red, copper phthalocyanine pigments as phthalocyanine pigments, blue and green as metal-free phthalocyanine pigments Examples of pigments and condensed polycyclic pigments include dioxazine violet and quinacridone violet. Examples of inorganic coloring pigments include titanium oxide and carbon black.

  For the adhesive layer 11d, an adhesive or a polyolefin resin can be used. Specific examples of the adhesive include a polyvinyl acetate adhesive, a homopolymer such as ethyl butyl acrylate, 2-ethylhexyl ester, and the like. Polyacrylic acid ester adhesives, such as copolymers with methyl methacrylate, acrylonitrile, styrene, etc., cyanoacrylate adhesives, copolymers of ethylene and monomers such as vinyl acetate, ethyl acrylate, acrylic acid, methacrylic acid, etc. Ethylene copolymer adhesives made of polymers, cellulose adhesives, polyester adhesives, polyamide adhesives, polyimide adhesives, amino resin adhesives made of urea resin or melamine resin, phenol resin adhesives Agent, epoxy adhesive, polyurethane adhesive, reactive type (meta Acrylic adhesives, chloroprene rubber, nitrile rubber, styrene - butadiene made of rubber or the like rubber adhesive, a silicone-based adhesive, an alkali metal silicate, inorganic adhesive or the like made of a low-melting glass. In addition, the polyolefin resin can be adhered between the stretched polyester film 11b and the stretched nylon film 11e in a molten state, and both films can be bonded. Specific examples of the polyolefin resin include thermal adhesive properties such as polyethylene and polypropylene. Resin.

  Examples of the stretched nylon film 11e include polyamide resins, that is, nylon 6, nylon 6, 6, a copolymer of nylon 6 and nylon 6, 6, nylon 6, 10, polymetaxylylene adipamide (MXD6), and the like. .

  The adhesive layer 13 is a layer that adheres the stretched nylon film 11e and the metal foil layer 13 by a dry laminating method, and the same adhesive as the above-described adhesive layer 11d can be used.

  Next, the metal foil layer 12 will be described. The metal foil layer 12 is a layer for preventing water vapor from entering the inside of the lithium ion battery from the outside, and the pinhole and processing suitability (pouching, cold press formability) of the metal foil layer alone are stabilized. For example, a film having a thickness of 15 μm or more, such as aluminum or nickel, or a film in which an inorganic compound such as silicon oxide or alumina is vapor-deposited is used. The metal foil to be configured is preferably aluminum having a thickness of 20 to 100 μm.

  Moreover, in order to improve the occurrence of pinholes and to make the outer body type of the lithium ion battery an embossed type, there is no occurrence of cracks or the like in cold press molding. It is desirable that the material has an iron content of 0.3 to 9.0% by weight, preferably 0.7 to 2.0% by weight.

  As a result, compared with aluminum that does not contain iron, aluminum has good spreadability, the occurrence of pinholes caused by bending as an exterior body is reduced, and the side wall is easily formed when cold-pressing the packaging material. be able to. When the iron content is less than 0.3% by weight, effects such as prevention of pinholes and improvement of cold press formability are not recognized, and the iron content of aluminum is 9.0% by weight. In the case of exceeding, the flexibility as aluminum is inhibited, and the bag-making property as a packaging material is deteriorated.

  In addition, aluminum produced by cold rolling changes its flexibility, waist strength and hardness under annealing (so-called annealing treatment) conditions, but the aluminum used in the present invention is harder than the non-annealed hard-treated product. Aluminum which tends to be soft with some or complete annealing is preferred.

  That is, the annealing conditions may be appropriately selected in accordance with processability (pouching, cold press molding). For example, in order to prevent wrinkles and pinholes during cold press molding, soft aluminum annealed according to the degree of molding can be used.

  Moreover, by performing a chemical conversion treatment on the front and back surfaces of the aluminum that is the metal foil layer 12 to form the chemical conversion treatment layer 12a, the adhesive strength with the adhesive can be improved.

  Next, the chemical conversion treatment layer 12a will be described. As shown in FIG. 1, the chemical conversion treatment layer 12 a is formed on at least the surface of the metal foil layer 12 on the thermal adhesive resin layer 15 side. The chemical conversion treatment layer 12 a stably adheres the acid-modified polyolefin layer 14 and the metal foil layer 12, and can prevent delamination of the metal foil layer 12 and the heat-adhesive resin layer 15. Further, the chemical conversion treatment layer 12 a also has a function of preventing the corrosion of the metal foil layer 12.

  Specifically, delamination between the metal foil layer 12 and the heat-adhesive resin layer 15 during embossing by forming an acid-resistant film such as phosphate, chromate, fluoride, triazine thiol compound, etc. And hydrogen fluoride produced by the reaction between the electrolyte and water in the lithium ion battery prevents the aluminum surface from being dissolved and corroded, especially the aluminum oxide present on the aluminum surface from being dissolved and corroded. Surface adhesion can be improved.

  The chemical conversion treatment layer 12a is made of metal by chromium-based chemical conversion treatment such as chromate chromate treatment, phosphoric acid chromate treatment, and coating-type chromate treatment, or non-chromium (coating-type) chemical conversion treatment such as zirconium, titanium, and zinc phosphate. Although it is formed on the surface of the foil layer 12, it is firmly bonded to the fluororesin, the point that it can be continuously processed and the water washing step is unnecessary, and the processing cost can be reduced. It is most preferable to treat with a treatment solution containing a coating type chemical conversion treatment, particularly an aminated phenol polymer, a trivalent chromium compound, and a phosphorus compound.

  Next, the thermal adhesive resin layer 15 will be described. The innermost heat-adhesive resin layer 15 is sandwiched and thermally bonded with the metal terminals of the lithium battery main body 122 protruding outward. At this time, the type of propylene constituting the thermal adhesive resin layer 15 differs depending on whether or not a metal terminal sealing adhesive film having metal adhesiveness is interposed between the thermal adhesive resin layer 15 and the metal terminal. When an adhesive film for sealing metal terminals is interposed, a film made of a propylene-based resin alone or a mixture may be used. When an adhesive film for sealing metal terminals is not interposed, graft modification with unsaturated carboxylic acid is performed. It is necessary to use a film made of the acid-modified olefin resin.

  Polypropylene is suitably used as the heat-adhesive resin layer 15, but a single layer or a multilayer of linear low density polyethylene or medium density polyethylene, or a single resin composed of a blend resin of linear low density polyethylene and medium density polyethylene. Films consisting of layers or multilayers can also be used. Polypropylene can be classified into random propylene, homopropylene, block propylene and the like.

  Each of the above types of polypropylene, ie, random polypropylene, homopolypropylene, and block polypropylene, includes a low crystalline ethylene-butene copolymer, a low crystalline propylene-butene copolymer, and a three-component copolymer of ethylene, butene, and propylene. An antiblocking agent (AB agent) such as a polymer terpolymer, silica, zeolite, or acrylic resin beads, a fatty acid amide slip agent, or the like may be added.

  Further, the heat-adhesive resin layer 15 according to the present invention may be multilayered by combining the above-mentioned types of polypropylene layers as appropriate.

  Next, the acid-modified polyolefin layer 14 will be described. The acid-modified polyolefin layer 14 is a layer provided for bonding the metal foil layer 12 and the heat-adhesive resin layer 15. The acid-modified polyolefin layer 14 needs to be appropriately selected depending on the resin type used for the heat-adhesive resin layer 15. Modified polyolefin resins can be used, such as polyolefin resins graft-modified with unsaturated carboxylic acids, copolymers of ethylene or propylene and acrylic acid, or methacrylic acid, or metal-crosslinked polyolefin resins. 5% or more of a butene component, an ethylene-propylene-butene copolymer, an amorphous ethylene-propylene copolymer, a propylene-α-olefin copolymer, etc. may be added.

  Moreover, the acid-modified polyolefin layer 14 can provide the packaging material 10 for electrochemical cells excellent in content resistance and adhesive strength by using acid-modified polypropylene.

When using acid-modified polypropylene,
(1) A homotype having a bigat softening point of 115 ° C or higher and a melting point of 150 ° C or higher,
(2) A copolymer of ethylene-propylene having a bigat softening point of 105 ° C or higher and a melting point of 130 ° C or higher (random copolymer type)
(3) A simple substance or a blended product obtained by acid-modified polymerization using an unsaturated carboxylic acid having a melting point of 110 ° C. or higher can be used.

  Next, a modification of the above embodiment will be described. FIG. 2 is a cross-sectional view showing a modified example of the packaging material for electrochemical cells. The same parts as those in the above embodiment are denoted by the same reference numerals and description thereof is omitted. As shown in FIG. 2, the identification mark may be formed using a colored adhesive layer 11d containing a coloring pigment such as titanium oxide in the adhesive layer 11d instead of the printed layer 11c. According to this configuration, the adhesive layer 11d is colored white by titanium oxide, and the electrochemical cell packaging material 10 is identified as white when viewed from the permeable base material layer 11 side. For this reason, even if the label used as the forgery identification mark is stuck on the surface of the base material layer 11 of the packaging material 10 for electrochemical cells, or printing is given, it recognizes from the external appearance of the packaging material 10 for electrochemical cells. The authenticity of the product can be easily determined by the difference in colors that can be made.

  The adhesive layer 11d is preferably composed of an adhesive to which a color pigment such as titanium oxide is added in a solid content of 5 wt% to 30 wt%, preferably 10 wt% to 25 wt%. In addition, when the addition amount of a coloring agent is less than 5 weight%, the color to be colored becomes light and difficult to identify. Moreover, when the addition amount of a coloring agent exceeds 30 weight%, adhesive strength becomes weak and is not preferable. Moreover, the shade of the color to be colored can be expressed by adjusting the addition amount of the colorant. Thereby, the packaging material 10 for electrochemical cells can also be identified by the color shading. The adhesives listed above can be used as specific examples of the adhesive layer 11d. Further, an embodiment in which a polyolefin resin such as polyethylene blended with a color pigment is extruded in a molten state and the stretched polyester film 11b and the stretched nylon film 11e are laminated is also included in the technical scope of the present invention.

  As the colored pigment, a chromatic colored pigment or an inorganic colored pigment can be used.Examples of the chromatic colored pigment include an azo pigment, a phthalocyanine pigment, and a condensed polycyclic pigment. Azo-based pigments are soluble pigments such as Watching Red and Carmine 6C, insoluble azo pigments such as monoazo yellow, disazo yellow, pyrazolone orange, red, and permanent red, phthalocyanine-based pigments are copper phthalocyanine pigments, and metal-free phthalocyanine pigments are blue Examples of green pigments and condensed polycyclic pigments include dioxazine violet and quinacridone violet. Examples of inorganic coloring pigments include titanium oxide and carbon black.

In addition to the color pigment such as titanium oxide, the adhesive layer 11d can be colored with a pearl pigment or a fluorescent pigment. As the pearl pigment, pearl powder or powder of the inner part of the shell was used classically, but now the outer side of the fine flakes (flakes) is coated with a metal oxide or a mixture of metal oxides Is used. Examples of fine flakes include mica, talc, kaolin, bismuth oxychloride, glass flakes, SiO ₂ flakes, and synthetic ceramic flakes. Examples of metal oxides that coat the outside of these fine flakes Are TiO ₂ , Fe ₂ O ₃ , SnO ₂ , Cr ₂ O ₃ , and ZnO. Among these combinations, mica, glass flakes, or SiO ₂ flakes coated with TiO ₂ and / or Fe ₂ O ₃ are preferable. In addition, the fluorescent pigment is a phosphor, that is, a substance that emits luminescence in a broad sense, and includes both inorganic fluorescent pigments and organic fluorescent pigments. Inorganic fluorescent pigments include oxidation of Ca, Ba, Mg, Zn, Cd, and the like. Mainly composed of crystals such as oxides, sulfides, silicates, phosphates and tungstates, and metal elements such as Mn, Zn, Ag, Cu, Sb and Pb or rare earth elements such as lanthanoids as activators A pigment obtained by adding and baking can be used. Preferred phosphors include ZnO: Zn, Br ₅ (PO ₄ ) ₃ Cl: Eu, Zn ₂ GeO ₄ : Mn, Y ₂ O ₃ : Eu, Y (P, V) O ₄ : Eu, Y ₂ O ₂ Si: Eu, Zn ₂ GeO ₄ : Mn, etc. can be exemplified, and examples of organic fluorescent pigments include diaminostilbene disulfonic acid derivatives, imidazole derivatives, coumarin derivatives, triazoles, carbazoles, pyridines, naphthalic acid, imidazolone derivatives, fluorescein, eosin, etc. A compound having a benzene ring such as a dye or anthracene can be used.

  The present invention is not limited to the above-described embodiments, and various modifications are possible. Embodiments obtained by appropriately combining technical means disclosed in different embodiments are also included in the present invention. Included in the technical scope. For example, the matting varnish layer 11a, the printing layer 11c, and the colored adhesive layer 11d can be combined to form an identification mark. The matting varnish layer 11a is not provided, and the identification mark is formed only by the printing layer 11c or the colored adhesive layer 11d. Can also be formed.

  In the present embodiment, the acid-modified polyolefin layer 14 is provided between the metal foil layer 12 and the heat-adhesive resin layer 15, but the embodiment in which the acid-modified polyolefin layer 14 is not provided is also within the technical scope of the present invention. included. Specifically, an adhesive layer other than an acid-modified polyolefin resin is interposed between the metal foil layer 12 and the heat-adhesive resin layer 15, and an acid-modified polyolefin resin is used for the heat-adhesive resin layer 15. And those obtained by heat laminating the laminated metal foil layer 12 and the heat-adhesive resin layer 15 and the like.

10, 110 Electrochemical cell packaging material 11, 111 Base material layer 11a Matte varnish layer 11b Stretched polyester film 11c Print layer 11d Adhesive layer 11e Stretched nylon film 12, 112 Metal foil layer 12a, 112a Chemical conversion treatment layer 13,113 Adhesive layer 14, 114 Acid-modified polyolefin layer 15, 115 Thermal adhesive resin layer
120 exterior body
120a tray
120b sheet
121 Lithium-ion battery
122 Lithium-ion battery body

Claims (3)

Containing an electrochemical cell body comprising a positive electrode comprising a positive electrode active material and a positive electrode current collector, a negative electrode comprising a negative electrode active material and a negative electrode current collector, and an electrolyte filled between the positive electrode and the negative electrode;
A packaging material for an electrochemical cell that seals the electrochemical cell body by heat-sealing a peripheral edge,
At least a multilayer film having a structure in which a base material layer, an adhesive layer, a metal foil layer, and a heat-adhesive resin layer are laminated in this order,
The base material layer has a stretched polyester film and a stretched nylon film,
An identification mark is included between the stretched polyester film and the stretched nylon film,
The identification mark is composed of an adhesive layer made of an adhesive to which a colored pigment interposed between the stretched polyester film and the stretched nylon film is added in a solid content of 5 wt% to 30 wt%,
The adhesive is polyvinyl acetate adhesive, polyacrylate adhesive, cyanoacrylate adhesive, ethylene copolymer adhesive, cellulose adhesive, polyester adhesive, polyamide adhesive, polyimide adhesive Agent, amino resin adhesive, phenol resin adhesive, epoxy adhesive, polyurethane adhesive, reactive (meth) acrylic adhesive, silicone adhesive, inorganic adhesive,
The stretched polyester film is arranged on the outer surface side from the stretched nylon film,
The stretched polyester film is a packaging material for electrochemical cells, wherein a mat varnish layer is formed on a surface opposite to the surface facing the stretched nylon film. The mat varnish layer is formed on a surface opposite to the surface facing the stretched nylon film of the stretched polyester film, the surface of which is processed to have a predetermined surface roughness and subjected to mat processing. The packaging material for electrochemical cells according to claim 1. Containing an electrochemical cell body comprising a positive electrode comprising a positive electrode active material and a positive electrode current collector, a negative electrode comprising a negative electrode active material and a negative electrode current collector, and an electrolyte filled between the positive electrode and the negative electrode;
A packaging material for an electrochemical cell that seals the electrochemical cell body by heat-sealing a peripheral edge,
At least a multilayer film having a structure in which a base material layer, an adhesive layer, a metal foil layer, and a heat-adhesive resin layer are laminated in this order,
The base material layer has a stretched polyester film and a stretched nylon film,
An identification mark is included between the stretched polyester film and the stretched nylon film,
The identification mark is composed of an adhesive layer made of an adhesive to which a colored pigment interposed between the stretched polyester film and the stretched nylon film is added in a solid content of 5 wt% to 30 wt%,
The adhesive is polyvinyl acetate adhesive, polyacrylate adhesive, cyanoacrylate adhesive, ethylene copolymer adhesive, cellulose adhesive, polyester adhesive, polyamide adhesive, polyimide adhesive Agent, amino resin adhesive, phenol resin adhesive, epoxy adhesive, polyurethane adhesive, reactive (meth) acrylic adhesive, silicone adhesive, inorganic adhesive,
The stretched polyester film is arranged on the outer surface side from the stretched nylon film,
A packaging material for an electrochemical cell, wherein the stretched polyester film is matted on a surface opposite to the surface facing the stretched nylon film, and the surface is processed to a predetermined surface roughness.

Images