JP5857091B2 - Stereoscopic image display device - Google Patents

Description

  The present invention relates to an optical film having an optically anisotropic layer on one surface of a transparent support and a hard coat layer on the other surface, a polarizing plate having the optical film, and an image display device. In particular, an optical film suitably used as a surface film for a liquid crystal display device, a polarizing plate including the optical film as a protective film, the hard coat layer on the viewing side, and the optical anisotropic layer on the polarizing film side Thus, the present invention relates to a liquid crystal display device having the optical film disposed on the surface.

Liquid crystal display devices (LCDs) are widely used because they are thin, lightweight, and have low power consumption. The liquid crystal display device includes a liquid crystal cell and a polarizing plate. The polarizing plate is usually composed of a protective film and a polarizing film, and is obtained by dyeing a polarizing film made of a polyvinyl alcohol film with iodine, stretching, and laminating both surfaces with a protective film. In a transmissive liquid crystal display device, this polarizing plate is generally attached to both sides of a liquid crystal cell, and one or more optical compensation films (retardation films) are arranged inside two liquid crystal plates (liquid crystal cell side). Has been. An optical compensation film may be used as the protective film. As an optical compensation film, for example, a film having an optically anisotropic layer in which a discotic liquid crystalline compound is fixed in an aligned state on a base film is widely used.
In recent years, in order to increase the functionality of liquid crystal display devices, development of stereoscopic image display devices using transmissive liquid crystal display devices has been underway. For example, Patent Document 1 discloses a phase difference film (λ) having a front retardation of λ / 4 in which the polarization axis of linearly polarized light emitted from a liquid crystal cell has an optical axis of + 45 ° in the vertical direction as a stereoscopic image display method. / 4 plate) is disposed outside the polarizing plate, and a time-division two-eye stereoscopic transmission type liquid crystal display device is described.

Examples of the retardation film having a front retardation of λ / 4 include those using a stretched film and those having an optically anisotropic layer formed of a curable liquid crystalline compound on a transparent substrate film.
Among these, since a stretched film is generally produced by stretching in the length direction or the width direction, the slow axis is parallel or orthogonal to the length direction.
In the production of the polarizing plate, when the retardation film and the polarizer are bonded, it is preferable in terms of production efficiency that the retardation film and the polarizer are bonded by roll-to-roll.
On the other hand, in a liquid crystal display device, a stretched film of polyvinyl alcohol is generally used as a polarizing film, and the absorption axis of polarized light is parallel to the length direction.
Therefore, in order to bond a retardation film having a slow axis in the 45 ° direction with respect to the polarization axis and a polarizer by roll-to-roll, a roll film of a retardation film having a slow axis in the 45 ° direction. Therefore, the stretched film is not suitable for bonding by roll-to-roll.
In contrast, a retardation film having an optically anisotropic layer formed of a curable liquid crystalline compound can freely change the direction of the slow axis by controlling the orientation direction of the liquid crystalline compound by a method such as rubbing. Therefore, it is suitable for roll-to-roll bonding.

In Patent Document 2, a roll film-like λ / 4 plate having a slow axis in the 45 ° direction in which a polymerizable rod-like liquid crystal compound is oriented is prepared using a triacetyl cellulose film as a base film, and the roll-to- It has been shown that an elliptically polarizing plate can be made by laminating with a polarizer with a roll. The elliptically polarizing plate thus prepared has a configuration of optically anisotropic layer / alignment film / base film / polarizer / protective film, the liquid crystal cell is on the optically anisotropic side, and the protective film is displayed. Located on the viewing side of the device.
Although not described in Patent Document 2, it is considered that a hard coat film is usually used as a protective film for the purpose of imparting a scratch-resistant function to the protective film disposed on the surface side of the display device.
On the other hand, when the elliptically polarizing plate having the structure described in Patent Document 2 is used as the λ / 4 plate in the time-division binocular stereoscopic transmission liquid crystal display device disclosed in Patent Document 1, the optically anisotropic layer is a display device. Therefore, it is considered that a hard coat film is preferably used on the outermost surface for imparting scratch resistance. When a hard coat film (usually provided with a hard coat layer on a transparent support) is provided on the surface of the optical anisotropic layer, the hard coat layer / transparent support / adhesive layer / optical anisotropic layer / Alignment film / base film / polarizer / protective film, resulting in a problem that the surface member (polarizing plate) becomes thick.

JP 2010-243705 A JP 2007-155970 A

To summarize the above, it is necessary to develop an optical film that can provide retardation and surface scratch resistance and can provide a polarizing plate that satisfies the demand for thinning.
Furthermore, the present inventors have started the development of a surface film suitable for a time-division binocular stereoscopic transmission type liquid crystal display device using an optically anisotropic layer based on conventional knowledge. I found two new problems that did not exist.
The first problem is a time-division binocular stereoscopic transmission type liquid crystal equipped with a λ / 4 layer prepared from a polymerizable rod-like liquid crystalline compound using a triacetyl cellulose film described in Patent Document 2 as a base film. Although the display device is excellent in front display performance, there is a problem in that when viewed from an oblique direction, crosstalk is observed and image quality is degraded. The present inventors have found that this problem can be solved by controlling Re and Rth of the optical film and making the Nz factor (Rth / Re + 0.5) close to 0.5. The configuration of the optical film of the present invention (optically anisotropic layer / alignment film / transparent support / hard coat layer) can make Nz close to 0.5, but like a comparative sample 139 described later, In a configuration in which a hard coat film is simply formed on a λ / 4 plate (base film / alignment film / optically anisotropic layer / adhesive layer / transparent support / hard coat layer), Nz is greater than 1 and oblique direction It was found that crosstalk was not resolved when viewed from the above.
The second problem is that interference unevenness due to a difference in refractive index between the transparent substrate film and the optically anisotropic layer occurs, and the display quality of a liquid crystal display device on which the same is mounted is deteriorated. In particular, in the configuration of “hard coat layer / transparent support / adhesive layer / optically anisotropic layer / alignment film / substrate film / polarizer / protective film”, a substrate film adjacent to the optically anisotropic layer, It was found that interference unevenness due to reflected light generated at the interface of the pressure-sensitive adhesive layer becomes remarkable.

  The present invention relates to a composite film having functions of a surface protective film and a retardation film, and has high productivity, high surface hardness, no interference unevenness, excellent image quality of a mounted image display device, and a polarizing plate It is providing the optical film suitable for thickness reduction. The present invention also relates to a polarizing plate and a liquid crystal display device equipped with such an optical film.

As a result of intensive studies, the inventors have made the hard coat layer and the optically anisotropic layer common, have the optically anisotropic layer on one side of the transparent support, and the hard coat on the other side. In the optical film having a layer, it was found that these problems can be solved by controlling the in-plane retardation and the retardation in the thickness direction of the optical film, and the present invention has been completed.
In particular, those having optical anisotropy formed from a composition containing a discotic liquid crystalline compound using a support composed of cellulose acylate were particularly excellent in oblique image quality.

The above-described problem of the present invention can be achieved by the following configuration.
<1>
From the viewing side, a stereoscopic image display device having an optical film, a polarizing film, and a liquid crystal cell in this order,
The optical film is
An optical film having an optically anisotropic layer on one surface of a transparent support and a hard coat layer on the other surface,
The optical film has an alignment film between the transparent support and the optically anisotropic layer,
In-plane retardation at 550 nm of the optical film is 80 to 200 nm, retardation in the thickness direction at a wavelength of 550 nm is −70 to 70 nm,
Nz (= Rth (550) / Re (550) +0.5) calculated from the in-plane retardation Re (550) at a wavelength of 550 nm of the optical film and the retardation Rth (550) in the thickness direction is −0. 50 to 1.50,
A liquid crystal display device in which the optical film is disposed such that the hard coat layer is on the viewing side and the optical anisotropic layer is on the polarizing film side.
<2>
The liquid crystal display device according to <1>, wherein Nz (= Rth (550) / Re (550) +0.5) of the optical film is −0.10 to 1.10.
< 3 >
The liquid crystal display device according to <1> or <2> , wherein the optically anisotropic layer of the optical film is formed from a composition containing a liquid crystalline compound.
< 4 >
The liquid crystal display device according to < 3 >, wherein the liquid crystal compound is a discotic liquid crystal compound.
< 5 >
In any one of <1> to < 4 >, the surface unevenness shape of the surface on which the hard coat layer of the optical film is laminated has an arithmetic average roughness Ra based on JIS B0601 of 0 to 0.08 μm. The liquid crystal display device described.
< 6 >
The liquid crystal display device according to any one of <1> to < 5 >, wherein a surface haze of the optical film is less than 1.0%.
< 7 >
The liquid crystal display device according to any one of <1> to < 6 >, wherein an internal haze of the optical film is 1 to 10%.
< 8 >
The liquid crystal display device according to any one of <1> to < 7 >, wherein a transmittance of 380 nm of the transparent support of the optical film is 10% or less.
< 9 >
The hard coat layer of the optical film contains a binder and translucent particles, the average particle diameter of the translucent particles is 1 to 12 μm, and the absolute value of the refractive index difference between the binder and the translucent particles is 0. The liquid crystal display device according to any one of <1> to < 8 >, which is 0.01 or more and less than 0.05.
< 10 >
The liquid crystal display according to any one of <1> to < 9 >, wherein a low refractive index layer having a refractive index lower than that of the transparent support is provided on the opposite side of the hard coat layer of the optical film from the transparent support. apparatus.
The present invention relates to the above <1> to < 10 >, but other matters (for example, items described in the following 1 to 16) are also described for reference.

1.
An optical film having an optically anisotropic layer on one surface of a transparent support and a hard coat layer on the other surface,
An optical film having an in-plane retardation at 550 nm of 80 to 200 nm, and a retardation in the thickness direction at a wavelength of 550 nm of −70 to 70 nm.
2.
2. The optical film as described in 1 above, having an alignment film between the transparent support and the optically anisotropic layer.
3.
3. The optical film as described in 1 or 2 above, wherein the transparent support has a retardation in the thickness direction at a wavelength of 550 nm of 20 to 100 nm.
4).
4. The optical film as described in any one of 1 to 3 above, wherein the optically anisotropic layer is formed from a composition containing a liquid crystalline compound.
5.
5. The optical film as described in 4 above, wherein the liquid crystalline compound is a discotic liquid crystalline compound.
6).
The optical surface according to any one of 1 to 5 above, wherein the surface irregularity shape of the surface on which the hard coat layer of the optical film is laminated has an arithmetic average roughness Ra based on JIS B0601 of 0 to 0.08 μm. the film.
7).
The optical film according to any one of 1 to 6 above, wherein the surface haze of the optical film is 1% or less.
8).
The optical film according to any one of 1 to 7 above, wherein an internal haze of the optical film is 1 to 10%.
9.
The optical film according to any one of 1 to 8 above, wherein the transparent support has a transmittance of 380 nm of 10% or less.
10.
The hard coat layer contains a binder and translucent particles, the translucent particles have an average particle diameter of 1 to 12 μm, and the absolute value of the difference in refractive index between the binder and the translucent particles is 0.01 or more. 10. The optical film as described in any one of 1 to 9 above, which is less than 0.05.
11.
11. The optical film as described in any one of 1 to 10 above, wherein a low refractive index layer having a refractive index lower than that of the transparent support is provided on the opposite side of the hard coat layer from the transparent support.
12
The optical film according to any one of 1 to 11 in the form of a long roll, wherein a slow axis of front retardation is 5 to 85 ° clockwise or counterclockwise with respect to the length direction.
13.
13. The optical film as described in any one of 1 to 12 above, which is a surface film for a liquid crystal display device.
14
A polarizing plate having at least one protective film and a polarizing film, wherein the at least one protective film is the optical film described in any one of 1 to 13 above, and the optical anisotropic layer of the optical film The polarizing plate with which the surface of the side and the said polarizing film were bonded.
15.
14. An image display device comprising at least one of the optical film described in any one of 1 to 13 or the polarizing plate described in 14 above.
16.
It is a liquid crystal display which has the optical film of any one of said 1-13, a polarizing film, and a liquid crystal cell in this order from the visual recognition side, Comprising: The said optical film has a hard-coat layer in the visual recognition side. A liquid crystal display device arranged so that the optically anisotropic layer is on the polarizing film side.

According to the present invention, the productivity is high, the surface hardness is high, there is no interference unevenness, the image quality of the mounted image display device (excellent optical compensation, no crosstalk, etc.) is excellent. An optical film suitable for reducing the thickness of the mounted image display device can be provided.
The optical film of the present invention is suitable for a stereoscopic image display device based on a transmissive liquid crystal display device.

  Hereinafter, although the form for implementing this invention is demonstrated in detail, this invention is not limited to these. In the present specification, when a numerical value represents a physical property value, a characteristic value, etc., the description “(numerical value 1) to (numerical value 2)” means “(numerical value 1) or more and (numerical value 2) or less”. .

  The optical film of the present invention is an optical film having an optically anisotropic layer on one surface of a transparent support and a hard coat layer on the other surface, wherein the optical film is in-plane at a wavelength of 550 nm. The retardation (Re (550)) is 80 to 200 nm, and the retardation in the thickness direction (Rth (550)) is -70 to 70 nm.

  Hereinafter, the materials used for the optical film, the polarizing plate and the image display device of the present invention, and the production methods thereof will be described in detail.

[Transparent support]
[Material of transparent support]
As a material for forming the transparent support of the present invention, a polymer excellent in optical performance transparency, mechanical strength, thermal stability, moisture shielding property, isotropy and the like is preferable. The term “transparent” as used in the present invention indicates that the visible light transmittance is 60% or more, preferably 80% or more, and particularly preferably 90% or more. Examples include polycarbonate polymers, polyester polymers such as polyethylene terephthalate and polyethylene naphthalate, acrylic polymers such as polymethyl methacrylate, and styrene polymers such as polystyrene and acrylonitrile / styrene copolymer (AS resin). Polyolefins such as polyethylene and polypropylene, polyolefin polymers such as ethylene / propylene copolymers, vinyl chloride polymers, amide polymers such as nylon and aromatic polyamide, imide polymers, sulfone polymers, polyethersulfone polymers , Polyether ether ketone polymers, polyphenylene sulfide polymers, vinylidene chloride polymers, vinyl alcohol polymers, vinyl butyral polymers, arylate polymers, polyoxymethylene polymers, epoxy polymers, or polymers mixed with the above polymers Take an example. The polymer film of the present invention can also be formed as a cured layer of an ultraviolet-curable or thermosetting resin such as acrylic, urethane, acrylic urethane, epoxy, or silicone.

  Further, as a material for forming the transparent support of the present invention, a thermoplastic norbornene resin can be preferably used. Examples of the thermoplastic norbornene-based resin include ZEONEX, ZEONOR manufactured by Nippon Zeon Co., Ltd., and ARTON manufactured by JSR Corporation.

  Further, as a material for forming the transparent support of the present invention, a cellulose polymer (particularly preferably, cellulose acylate) represented by triacetyl cellulose, which has been conventionally used as a transparent protective film of a polarizing plate, is preferable. Can be used. Hereinafter, cellulose acylate will be mainly described in detail as an example of the transparent support of the present invention, but it is obvious that the technical matters can be applied to other polymer films as well.

[Substitution degree of cellulose acylate]
Next, the cellulose acylate of the present invention produced from the above-mentioned cellulose will be described. Cellulose acylate is obtained by acylating a hydroxyl group of cellulose, and the substituent can be any acetyl group having 2 carbon atoms in the acyl group to those having 22 carbon atoms. In the cellulose acylate of the present invention, the degree of substitution of cellulose with a hydroxyl group is not particularly limited, but the degree of binding of acetic acid and / or a fatty acid having 3 to 22 carbon atoms substituted with a hydroxyl group of cellulose is measured and substituted by calculation. You can get a degree. As a measuring method, it can carry out according to ASTM D-817-91.

  In the cellulose acylate, the substitution degree of the hydroxyl group of cellulose is not particularly limited, but the acyl substitution degree of the cellulose hydroxyl group is preferably 2.50 to 3.00. Furthermore, the substitution degree is preferably 2.75 to 3.00, and more preferably 2.85 to 3.00.

  Among the acetic acid and / or the fatty acid having 3 to 22 carbon atoms substituted for the hydroxyl group of cellulose, the acyl group having 2 to 22 carbon atoms may be an aliphatic group or an aromatic group, and is not particularly limited. It may be a mixture of more than one type. Examples of the cellulose ester acylated by these include alkylcarbonyl ester, alkenylcarbonyl ester, aromatic carbonyl ester, aromatic alkylcarbonyl ester and the like of cellulose, and each may further have a substituted group. Preferred acyl groups include acetyl group, propionyl group, butanoyl group, heptanoyl group, hexanoyl group, octanoyl group, decanoyl group, dodecanoyl group, tridecanoyl group, tetradecanoyl group, hexadecanoyl group, octadecanoyl group, iso -Butanoyl group, t-butanoyl group, cyclohexanecarbonyl group, oleoyl group, benzoyl group, naphthylcarbonyl group, cinnamoyl group and the like can be mentioned. Among these, acetyl group, propionyl group, butanoyl group, dodecanoyl group, octadecanoyl group, t-butanoyl group, oleoyl group, benzoyl group, naphthylcarbonyl group, cinnamoyl group and the like are preferable, and acetyl group, propionyl group, butanoyl group are preferable. Groups are more preferred.

[Degree of polymerization of cellulose acylate]
The degree of polymerization of cellulose acylate preferably used in the present invention is 180 to 700 in terms of viscosity average polymerization degree, and in cellulose acetate, 180 to 550 is more preferable, 180 to 400 is more preferable, and 180 to 350 is particularly preferable. .

[Additive for transparent support]
Various additives (for example, optical anisotropy adjusting agent, wavelength dispersion adjusting agent, fine particles, plasticizer, ultraviolet ray preventing agent, deterioration preventing agent, release agent, etc.) are added to the transparent support in the present invention. These will be described below. In addition, when the transparent support is a cellulose acylate film, the addition time may be any in the dope preparation process (preparation process of cellulose acylate solution), but an additive is added and prepared at the end of the dope preparation process. You may perform a process.

[Ultraviolet absorber]
The transparent support of the optical film of the present invention preferably contains an ultraviolet absorber (UV absorber). By containing the ultraviolet absorber, ultraviolet absorptivity can be imparted. By including an ultraviolet absorber in the transparent support, the support is yellowed (for example, observed as a decrease in transmittance at a wavelength of 400 nm) or one of the supports when exposed to ultraviolet rays contained in external light. It is possible to prevent retardation change (for example, observed as Re change) of the optically anisotropic layer laminated on the surface. Specific examples of the UV absorber include compounds described in JP-A-2006-199855, [0059] to [0135].
The transmittance at 380 nm of the transparent support is preferably 50% or less, more preferably 20% or less, still more preferably 10% or less, and particularly preferably 5% or less.

[Matting agent fine particles]
It is preferable to add fine particles as a matting agent to the transparent support in the present invention. Examples of the fine particles include silicon dioxide, titanium dioxide, aluminum oxide, zirconium oxide, calcium carbonate, talc, clay, calcined kaolin, calcined calcium silicate, hydrated calcium silicate, aluminum silicate, magnesium silicate, and calcium phosphate. . Fine particles containing silicon are preferable in terms of low turbidity, and silicon dioxide is particularly preferable. The silicon dioxide fine particles preferably have a primary average particle size of 20 nm or less and an apparent specific gravity of 70 g / liter or more. Those having an average primary particle size as small as 5 to 16 nm are more preferred because they can reduce the haze of the film. The apparent specific gravity is preferably 90 to 200 g / liter, and more preferably 100 to 200 g / liter. A larger apparent specific gravity is preferable because a high-concentration dispersion can be produced, and haze and aggregates are improved.

  These fine particles usually form secondary particles having an average particle diameter of 0.1 to 3.0 μm, and these fine particles are present as aggregates of primary particles in the film, and 0.1 to 0.1 μm on the film surface. A convex part of 3.0 μm is formed. The secondary average particle size is preferably from 0.2 to 1.5 μm, more preferably from 0.4 to 1.2 μm, and most preferably from 0.6 to 1.1 μm. The primary and secondary particle sizes were determined by observing the particles in the film with a scanning electron microscope and determining the diameter of a circle circumscribing the particles as the particle size. Also, 200 particles are observed at different locations, and the average value is taken as the average particle diameter. Moreover, the uneven | corrugated state of the film surface can be measured by techniques, such as AFM.

  As the fine particles of silicon dioxide, for example, commercially available products such as Aerosil R972, R972V, R974, R812, 200, 200V, 300, R202, OX50, TT600 (above Nippon Aerosil Co., Ltd.) can be used. Zirconium oxide fine particles are commercially available, for example, under the trade names Aerosil R976 and R811 (manufactured by Nippon Aerosil Co., Ltd.) and can be used.

  Among these, Aerosil 200V and Aerosil R972V are fine particles of silicon dioxide having a primary average particle diameter of 20 nm or less and an apparent specific gravity of 70 g / liter or more, and the coefficient of friction is maintained while keeping the turbidity of the optical film low. It is particularly preferable because it has a great effect of reducing the effect.

[Compound that reduces optical anisotropy]
Specific examples of the compound for reducing the optical anisotropy of the transparent support include, for example, compounds described in JP-A 2006-199855, [0035] to [0058], but are not limited to these compounds.

[Plasticizer, degradation inhibitor, release agent]
In addition to compounds that reduce optical anisotropy, UV absorbers, and matting agents, as described above, various additives (for example, plasticizers, deterioration inhibitors, release agents, infrared absorbers) depending on the application. , Etc.), which may be solid or oily. Details of these materials are described in detail on pages 16 to 22 in the Japan Institute of Invention Disclosure Technical Bulletin (Public Technical Number 2001-1745, published on March 15, 2001, Japan Institute of Invention).

[Knurling]
Even if the transparent support in the present invention is wide and thin, it has a knurling part at the film end of the transparent support in order to suppress the generation of black bands and film deformation when handled in a roll state. Is preferred. A knurling part is what gives unevenness to the edge part of the width direction of a transparent long support body, and makes the edge part bulky, and it is preferred to provide in both ends. As a method of providing unevenness as a knurling portion, it can be formed by pressing a heated embossing roll on the film. Fine embossing is formed on the embossing roll. By pressing this embossing roll, unevenness can be formed on the film and the end can be made bulky. The height of the knurling part which concerns on this invention says the height from a film surface to an embossing convex part. The knurling can be provided on both the front and back surfaces of the transparent support, or three or more on one side. The height of the knurling part is preferably 1 μm or more higher than the film thickness of the entire optical functional layer including the optically anisotropic layer and the hard coat layer, and the width of one knurling part is in the range of 5 mm to 30 mm. Preferably there is. In the case where knurling portions are provided on both the front and back surfaces of the film, the sum of the heights of the knurling portions may be increased by at least 1 μm. By controlling the thickness to 1 μm or more, the effect of suppressing the generation of black bands and film deformation appears. The height of the knurling part is preferably higher in the range of 2 μm to 10 μm than the film thickness of the entire optical functional layer. By setting it within this range, it is possible to prevent the occurrence of a black band and the deformation of the film, and no adverse effects such as winding deviation and deformation of the support due to the swelling of the knurling portion occur.

[Optically anisotropic layer]
The optical anisotropic layer which the optical film of the present invention has will be described. The optically anisotropic layer refers to a layer that generates a phase difference by forming the layer on the transparent support.
The optically anisotropic layer in the present invention can be selected from materials and production conditions in accordance with various uses, and a λ / 4 film using a polymerizable liquid crystalline compound is one preferred embodiment.

First, a method for measuring optical characteristics will be described. In this specification, Re (λ) and Rth (λ) represent in-plane retardation and retardation in the thickness direction at the wavelength λ, respectively. Re (λ) is measured with KOBRA 21ADH or WR (manufactured by Oji Scientific Instruments Co., Ltd.) by making light having a wavelength of λ nm incident in the normal direction of the film. In selecting the measurement wavelength λnm, the wavelength selection filter can be exchanged manually, or the measurement value can be converted by a program or the like. When the film to be measured is represented by a uniaxial or biaxial refractive index ellipsoid, Rth (λ) is calculated by the following method. This measuring method is also partially used for measuring the average tilt angle on the alignment film side of the discotic liquid crystal molecules in the optically anisotropic layer, which will be described later, and the average tilt angle on the opposite side.
Rth (λ) is the film surface when Re (λ) is used and the in-plane slow axis (determined by KOBRA 21ADH or WR) is the tilt axis (rotation axis) (if there is no slow axis) Measurement is performed at a total of 6 points by injecting light of wavelength λ nm from each inclined direction in steps of 10 degrees from the normal direction to 50 ° on one side with respect to the film normal direction (with any rotation direction as the rotation axis). Then, KOBRA 21ADH or WR is calculated based on the measured retardation value, the assumed value of the average refractive index, and the input film thickness value. In the above case, in the case of a film having a direction in which the retardation value is zero at a certain tilt angle with the in-plane slow axis from the normal direction as the rotation axis, retardation at a tilt angle larger than the tilt angle. The value is calculated by KOBRA 21ADH or WR after changing its sign to negative. The retardation value is measured from two inclined directions with the slow axis as the tilt axis (rotation axis) (if there is no slow axis, the arbitrary direction in the film plane is the rotation axis). Rth can also be calculated from the following formula (A) and formula (III) based on the value, the assumed value of the average refractive index, and the input film thickness value (d).

Formula (A):

  Note that Re (θ) represents a retardation value in a direction inclined by an angle θ from the normal direction. In the formula (A), nx represents the refractive index in the slow axis direction in the plane, ny represents the refractive index in the direction orthogonal to nx in the plane, and nz is the direction orthogonal to nx and ny. Represents the refractive index.

  Rth = ((nx + ny) / 2−nz) × d (formula (III))

  When the film to be measured is a film that cannot be expressed by a uniaxial or biaxial refractive index ellipsoid, that is, a film without a so-called optical axis, Rth (λ) is calculated by the following method. Rth (λ) is from −50 ° to the normal direction of the film, with Re (λ) being the in-plane slow axis (determined by KOBRA 21ADH or WR) as the tilt axis (rotary axis). Measured at 11 points by making light of wavelength λ nm incident in 10 ° steps up to + 50 °, and based on the measured retardation value, average refractive index assumption value and input film thickness value. KOBRA 21ADH or WR is calculated. In the above measurement, as the assumed value of the average refractive index, values in the polymer handbook (John Wiley & Sons, Inc.) and catalogs of various optical films can be used. If the average refractive index is not known, it can be measured with an Abbe refractometer. The average refractive index values of main optical films are exemplified below: cellulose acylate (1.48), cycloolefin polymer (1.52), polycarbonate (1.59), polymethyl methacrylate (1.49), Polystyrene (1.59). The KOBRA 21ADH or WR calculates nx, ny, and nz by inputting the assumed value of the average refractive index and the film thickness. Nz = (nx−nz) / (nx−ny) is further calculated from the calculated nx, ny, and nz.

[Retardation of optically anisotropic layer]
The front retardation Re (550) at a wavelength of 550 nm of the optically anisotropic layer in the present invention is preferably from 80 to 200 nm, more preferably from 90 to 180 nm, still more preferably from 100 to 170 nm.
The front retardation Re (550) at a wavelength of 550 nm of the optical film of the present invention is 80 to 200 nm, more preferably 100 to 170 nm, and still more preferably 110 to 160 nm.
By suppressing the front retardation Re (550) at a wavelength of 550 nm within the above range, for example, front crosstalk and luminance reduction when mounted on a transmission liquid crystal display device for time-division binocular stereoscopic viewing are suppressed. Can do. The effect is particularly remarkable when the viewer looks at his / her face.
The retardation Rth (550) in the thickness direction at a wavelength of 550 nm of the optical film is −70 to 70 nm, preferably −60 to 60 nm, more preferably −50 to 50 nm, and particularly preferably −20 to 20 nm.
By controlling Rth (550) within the above range, it is possible to suppress crosstalk in an oblique direction and a decrease in luminance when mounted on a time-division binocular stereoscopic transmission type liquid crystal display device.
Nz (= Rth (550) / Re (550) +0.5) calculated from Re (550) and Rth (550) at the wavelength of 550 nm is preferably −0.50 to 1.50, and −0. 10 to 1.10 are more preferable, 0.1 to 0.9 are more preferable, and 0.3 to 0.7 are particularly preferable.

[Optically anisotropic layer containing liquid crystalline compound]
The optically anisotropic layer in the present invention is preferably formed using a liquid crystalline compound. The type of liquid crystal compound used is not particularly limited. For example, after forming a low molecular weight liquid crystalline compound in a nematic orientation in a liquid crystal state, an optically anisotropic layer obtained by fixing by photocrosslinking or thermal crosslinking, or after forming a polymer liquid crystalline compound in a nematic orientation in a liquid crystal state, An optically anisotropic layer obtained by fixing the orientation by cooling can also be used. In the present invention, even when a liquid crystalline compound is used for the optically anisotropic layer, the optically anisotropic layer is a layer formed by fixing the liquid crystalline compound by polymerization or the like. After that, it is no longer necessary to show liquid crystallinity. The polymerizable liquid crystal compound may be a polyfunctional polymerizable liquid crystal or a monofunctional polymerizable liquid crystal compound.
The liquid crystalline compound may be a discotic liquid crystalline compound (also referred to as a discotic liquid crystalline compound) or a rod-shaped liquid crystalline compound. In order to obtain the retardation Rth (550)), a discotic liquid crystalline compound is more preferable.

In the optically anisotropic layer, it is preferable that the molecules of the liquid crystalline compound are fixed in any alignment state of vertical alignment, horizontal alignment, hybrid alignment, and tilt alignment. In order to produce a retardation plate whose viewing angle dependency is symmetric, the disc surface of the discotic liquid crystalline compound is substantially perpendicular to the film surface (surface direction of the optically anisotropic layer) Or it is preferable that the long axis of a rod-shaped liquid crystalline compound is substantially horizontal with respect to a film surface (optically anisotropic layer surface). The term “substantially perpendicular to the discotic liquid crystalline compound” means that the average value of the angle formed by the film surface (optically anisotropic layer surface) and the disc surface of the discotic liquid crystalline compound is in the range of 70 ° to 90 °. Means. 80 ° to 90 ° is more preferable, and 85 ° to 90 ° is still more preferable. That the rod-like liquid crystalline compound is substantially horizontal means that the angle formed by the film surface (optically anisotropic layer surface) and the director of the rod-like liquid crystalline compound is in the range of 0 ° to 20 °. 0 ° to 10 ° is more preferable, and 0 ° to 5 ° is still more preferable.
In the case of producing an optical compensation film in which the viewing angle dependency is asymmetric by hybrid alignment of liquid crystal compound molecules, the average tilt angle of the director of the liquid crystal compound is preferably 5 to 85 °, and 10 to 80 More preferably, the angle is more preferably 15 to 75 °.

  In the optical film of the present invention, the optically anisotropic layer may be composed of only one layer or a laminate of two or more optically anisotropic layers.

  The optically anisotropic layer comprises a coating liquid containing a liquid crystalline compound such as a rod-like liquid crystalline compound or a discotic liquid crystalline compound, and, if desired, a polymerization initiator, an alignment control agent and other additives described later. It can be formed by coating on top. It is preferable to form an alignment film on a support and apply the coating solution on the surface of the alignment film.

[Discotic liquid crystalline compounds]
In the present invention, it is preferable to use a discotic liquid crystalline compound for forming the optically anisotropic layer of the optical film. Discotic liquid crystalline compounds are disclosed in various documents (C. Destrade et al., Mol. Crysr. Liq. Cryst., Vol. 71, page 111 (1981); edited by The Chemical Society of Japan, Quarterly Chemical Review, No. 22, Liquid Crystal Chemistry, Chapter 5, Chapter 10 Section 2 (1994); B. Kohne et al., Angew. Chem. Soc. Chem. Comm., Page 1794 (1985); J. Zhang et al., J Am.Chem.Soc., Vol.116, page 2655 (1994)). The polymerization of discotic liquid crystalline compounds is described in JP-A-8-27284.

  Specific examples of the discotic liquid crystalline compound that can be preferably used in the present invention include compounds described in JP-A-2009-97002 [0038] to [0069]. Further, examples of the discotic liquid crystalline compound having a small wavelength dispersion, which is a triphenylene compound, include compounds described in paragraphs [0062] to [0067] of JP-A No. 2007-108732.

When the optically anisotropic layer is formed using the discotic liquid crystalline compound as described above, the average angle formed by the film surface (optically anisotropic layer surface) and the disc surface of the discotic liquid crystalline compound is 70 °. It is preferably within the range of ˜90 °, more preferably 80 ° to 90 °, and still more preferably 85 ° to 90 °.
The optimum retardation required for the transparent support varies depending on the material forming the optically anisotropic layer. When the optically anisotropic layer contains a discotic liquid crystalline compound and the discotic liquid crystalline compound is oriented at the above angle, the retardation Rth (550) in the thickness direction at a wavelength of 550 nm of the transparent support is 20 -100 nm is preferable, 30-90 nm is more preferable, and 40-80 nm is especially preferable. By controlling Rth (550) of the transparent support within the above range, Rth (550) of the optical film can be controlled within the above preferred range.
The in-plane retardation Re (550) at a wavelength of 550 nm of the transparent support is preferably 0 to 10 nm, more preferably 0 to 8 nm, and particularly preferably 0 to 6 nm.
When a cellulose acylate film is used as the transparent support, the above preferred thickness direction retardation and in-plane retardation can be easily obtained. An embodiment in which a cellulose acylate film is used as the transparent support and a discotic liquid crystalline compound is used in the optically anisotropic layer is particularly preferable for obtaining the preferable optical characteristics as the optical film described above.

[Bar-shaped liquid crystalline compound]
In the present invention, a rod-like liquid crystalline compound may be used for the optically anisotropic layer. Examples of rod-like liquid crystalline compounds include azomethines, azoxys, cyanobiphenyls, cyanophenyl esters, benzoic acid esters, cyclohexanecarboxylic acid phenyl esters, cyanophenylcyclohexanes, cyano-substituted phenylpyrimidines, alkoxy-substituted phenylpyrimidines. , Phenyldioxanes, tolanes and alkenylcyclohexylbenzonitriles are preferably used. Not only the above low-molecular liquid crystalline compounds but also high-molecular liquid crystalline compounds can be used. It is more preferable to fix the alignment of the rod-like liquid crystal compound by polymerization. As the liquid crystalline compound, those having a partial structure capable of causing polymerization or crosslinking reaction by actinic rays, electron beams, heat, or the like are suitably used. The number of the partial structures is preferably 1 to 6, more preferably 1 to 3. As the polymerizable rod-like liquid crystalline compound, Makromol. Chem. 190, 2255 (1989), Advanced Materials 5, 107 (1993), US Pat. No. 4,683,327, US Pat. No. 5,622,648, US Pat. No. 5,770,107, International Publication WO95 / 22586. No. 95/24455, No. 97/00600, No. 98/23580, No. 98/52905, JP-A-1-272551, No. 6-16616, and No. 7-110469. 11-80081 and JP-A-2001-328773, etc. can be used.

As described above, the optimum retardation required for the transparent support varies depending on the material forming the optically anisotropic layer. When the optically anisotropic layer contains a rod-like liquid crystalline compound and the rod-like liquid crystalline compound is oriented at the above angle, the retardation Rth (550) in the thickness direction at a wavelength of 550 nm of the transparent support is -120 to 20 nm is preferable, −100 to 10 nm is more preferable, and −80 to −50 nm is particularly preferable. By controlling Rth (550) of the transparent support within the above range, Rth (550) of the optical film can be controlled within the above preferred range.
The in-plane retardation Re (550) at a wavelength of 550 nm of the transparent support is preferably 0 to 10 nm, more preferably 0 to 8 nm, and particularly preferably 0 to 6 nm.

[Vertical alignment accelerator]
In order to uniformly align the molecules of the liquid crystalline compound when forming the optically anisotropic layer, an alignment controller capable of controlling the alignment of the liquid crystalline compound vertically on the alignment film interface side and the air interface side is provided. It is preferable to use it. For this purpose, an optically anisotropic composition using a composition containing, together with a liquid crystalline compound, an alignment film having a function of vertically aligning the liquid crystalline compound by an excluded volume effect, electrostatic effect or surface energy effect. It is preferable to form a conductive layer. In addition, regarding the orientation control on the air interface side, a compound that is unevenly distributed at the air interface at the time of orientation of the liquid crystalline compound, and that acts to vertically align the liquid crystalline compound by its excluded volume effect, electrostatic effect, or surface energy effect It is preferable to form an optically anisotropic layer using a composition contained together with a liquid crystal compound. As such a compound (alignment film interface side vertical alignment agent) that promotes the vertical alignment of the molecules of the liquid crystal compound on the alignment film interface side, a pyridinium derivative is preferably used. As a compound (air interface side vertical alignment agent) that promotes the vertical alignment of the molecules of the liquid crystal compound on the air interface side, a fluoro aliphatic group that promotes the uneven distribution of the compound on the air interface side, One or more hydrophilic groups selected from the group consisting of a carboxyl group (—COOH), a sulfo group (—SO ₃ H), a phosphonoxy group {—OP (═O) (OH) ₂ }, and salts thereof A compound is preferably used. Further, by blending these compounds, for example, when a liquid crystalline composition is prepared as a coating solution, the coating property of the coating solution is improved, and the occurrence of unevenness and repellency is suppressed. The vertical alignment agent will be described in detail below.

[Alignment film interface side vertical alignment agent]
As the alignment film interface-side vertical alignment agent usable in the present invention, a pyridinium derivative (pyridinium salt) is preferably used. Specific examples of the compound include [0058] to [0058] in JP-A-2006-113500. 0061] can be mentioned.

  The preferred range of the content of the pyridinium derivative in the composition for forming an optically anisotropic layer varies depending on the application, but the composition (liquid crystalline composition excluding the solvent when prepared as a coating solution) In the inside, it is preferable that it is 0.005-8 mass%, and it is more preferable that it is 0.01-5 mass%.

[Air interface side vertical alignment agent]
As the air interface side vertical alignment agent, the following fluorine-based polymer (including formula (II) as a partial structure) or a fluorine-containing compound represented by general formula (III) is preferably used.

  First, the fluorine-based polymer (including formula (II) as a partial structure) will be described. As the air interface side vertical alignment agent, the fluoropolymer is preferably a copolymer containing a repeating unit derived from a fluoroaliphatic group-containing monomer and a repeating unit represented by the following formula (II).

In the formula, R ¹ , R ² and R ³ each independently represent a hydrogen atom or a substituent; L is a divalent linking group selected from the following linking group group or 2 selected from the following linking group group. Represents a divalent linking group formed by combining two or more, (linking group group)
Single bond, —O—, —CO—, —NR ⁴ — (R ⁴ represents a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group), —S—, —SO ₂ —, —P (═O) (OR ⁵ ) — (R ⁵ represents an alkyl group, an aryl group, or an aralkyl group), an alkylene group, and an arylene group;
Q represents a carboxyl group (—COOH) or a salt thereof, a sulfo group (—SO ₃ H) or a salt thereof, or phosphonoxy {—OP (═O) (OH) ₂ } or a salt thereof.

The fluoropolymer usable in the present invention includes a fluoroaliphatic group, a carboxyl group (—COOH), a sulfo group (—SO ₃ H), a phosphonoxy group {—OP (═O) (OH) ₂ }, and their It contains one or more hydrophilic groups selected from the group consisting of salts. The types of polymers are described in “Revised Chemistry of Polymer Synthesis” (Takayuki Otsu, published by Kagaku Dojin Co., 1968), pages 1-4, for example, polyolefins, polyesters, polyamides, polyimides. , Polyurethanes, polycarbonates, polysulfones, polycarbonates, polyethers, polyacetals, polyketones, polyphenylene oxides, polyphenylene sulfides, polyarylates, PTFEs, polyvinylidene fluorides, cellulose derivatives, etc. It is done. The fluoropolymer is preferably a polyolefin.

  The fluorine-based polymer is a polymer having a fluoroaliphatic group in the side chain. The fluoroaliphatic group preferably has 1 to 12 carbon atoms, and more preferably 6 to 10 carbon atoms. The aliphatic group may be linear or cyclic, and when it is linear, it may be linear or branched. Of these, a linear fluoroaliphatic group having 6 to 10 carbon atoms is preferable. The degree of substitution with fluorine atoms is not particularly limited, but 50% or more of hydrogen atoms in the aliphatic group are preferably substituted with fluorine atoms, and more preferably 60% or more are substituted. The fluoroaliphatic group is contained in a side chain bonded to the polymer main chain via an ester bond, an amide bond, an imide bond, a urethane bond, a urea bond, an ether bond, a thioether bond, an aromatic ring, or the like.

  Specific examples of the fluoroaliphatic group-containing copolymer preferably used in the present invention as a fluorine-based polymer include the compounds described in paragraphs [0110] to [0114] of JP-A-2006-113500. Is not limited by these specific examples.

  The fluoropolymer used in the present invention preferably has a mass average molecular weight of 1,000,000 or less, more preferably 500,000 or less, 100,000 or less, and more preferably 10,000 or more. preferable. By setting it within this range, it is effective for controlling the alignment of the liquid crystal compound while satisfying the solubility. The mass average molecular weight can be measured as a value in terms of polystyrene (PS) using gel permeation chromatography (GPC).

  The preferred range of the content of the fluoropolymer in the composition varies depending on the application, but when used for forming the optically anisotropic layer, the composition (a composition excluding the solvent in the case of a coating solution) Among these, 0.005 to 8% by mass is preferable, 0.01 to 5% by mass is more preferable, and 0.05 to 3% by mass is even more preferable. If the addition amount of the fluorine-based polymer is less than 0.005% by mass, the effect is insufficient, and if it exceeds 8% by mass, the coating film cannot be sufficiently dried, or the performance as an optical film (for example, letter Adversely affects the uniformity of the foundation.

A fluorine-containing compound represented by the following formula (III).
(III) (R ⁰ ) _m -L ^0- (W) _n
In the formula, R ⁰ represents an alkyl group, an alkyl group having a CF ₃ group at the terminal, or an alkyl group having a CF ₂ H group at the terminal, and m represents an integer of 1 or more. A plurality of R ⁰ may be the same or different, but at least one represents an alkyl group having a CF ₃ group or a CF ₂ H group at the terminal. L ⁰ represents a (m + n) -valent linking group, W represents a carboxyl group (—COOH) or a salt thereof, a sulfo group (—SO ₃ H) or a salt thereof, or phosphonoxy {—OP (═O) (OH) ₂ } Or a salt thereof, and n represents an integer of 1 or more.

  Specific examples of the fluorine-containing compound represented by the formula (III) that can be used in the present invention include compounds described in paragraphs [0136] to [0140] of JP-A-2006-113500. Is not limited by these specific examples.

  The preferred range of the content of the fluorine-containing compound in the composition varies depending on the use, but when used for forming the optically anisotropic layer, the composition (a composition excluding the solvent in the case of a coating solution) Among these, 0.005 to 8% by mass is preferable, 0.01 to 5% by mass is more preferable, and 0.05 to 3% by mass is even more preferable.

[Polymerization initiator]
The aligned (preferably vertically aligned) liquid crystal compound is fixed while maintaining the alignment state. The immobilization is preferably performed by a polymerization reaction of the polymerizable group (P) introduced into the liquid crystal compound. The polymerization reaction includes a thermal polymerization reaction using a thermal polymerization initiator and a photopolymerization reaction using a photopolymerization initiator. A photopolymerization reaction is preferred. Examples of the photopolymerization initiator include α-carbonyl compounds (described in US Pat. Nos. 2,367,661 and 2,367,670), acyloin ether (described in US Pat. No. 2,448,828), α-hydrocarbon substituted aromatic acyloin. Compound (described in US Pat. No. 2,722,512), polynuclear quinone compound (described in US Pat. Nos. 3,046,127 and 2,951,758), a combination of triarylimidazole dimer and p-aminophenyl ketone (US Pat. No. 3,549,367) Description), acridine and phenazine compounds (JP-A-60-105667, U.S. Pat. No. 4,239,850) and oxadiazole compounds (U.S. Pat. No. 4,212,970).

The amount of the photopolymerization initiator used is preferably 0.01 to 20% by mass, more preferably 0.5 to 5% by mass, based on the solid content of the coating solution. It is preferable to use ultraviolet rays for light irradiation for polymerization of liquid crystalline molecules. The irradiation energy ^is preferably ^{20mJ / cm 2 ~50J / cm 2} , further preferably 100 to 800 mJ / cm ^2. In order to accelerate the photopolymerization reaction, light irradiation may be performed under heating conditions or at a low oxygen concentration of 0.1% or less. The thickness of optical anisotropy containing the liquid crystalline compound is preferably 0.1 to 10 μm, more preferably 0.5 to 5 μm, and most preferably 1 to 5 μm.

[Other additives for optically anisotropic layer]
Along with the liquid crystal compound, a plasticizer, a surfactant, a polymerizable monomer, and the like can be used in combination to improve the uniformity of the coating film, the strength of the film, the orientation of the liquid crystal compound, and the like. These materials are preferably compatible with the liquid crystal compound and do not inhibit the alignment.

  Examples of the polymerizable monomer include radically polymerizable or cationically polymerizable compounds. Preferably, it is a polyfunctional radically polymerizable monomer and is preferably copolymerizable with the polymerizable group-containing liquid crystalline compound. Examples thereof include those described in paragraph numbers [0018] to [0020] in JP-A No. 2002-296423. The amount of the compound added is generally in the range of 1 to 50% by mass and preferably in the range of 5 to 30% by mass with respect to the liquid crystal molecules.

  Examples of the surfactant include conventionally known compounds, and fluorine compounds are particularly preferable. Specifically, for example, compounds described in paragraphs [0028] to [0056] in JP-A No. 2001-330725, and paragraphs [0069] to [0126] in Japanese Patent Application No. 2003-295212 are described. The compound of this is mentioned.

The polymer used together with the liquid crystal compound is preferably capable of thickening the coating solution. A cellulose ester can be mentioned as an example of a polymer. Preferable examples of the cellulose ester include those described in paragraph [0178] of JP-A No. 2000-155216. The addition amount of the polymer is preferably in the range of 0.1 to 10% by mass, and in the range of 0.1 to 8% by mass with respect to the liquid crystal molecules so as not to inhibit the alignment of the liquid crystal compound. It is more preferable.
The discotic nematic liquid crystal phase-solid phase transition temperature of the liquid crystal compound is preferably 70 to 300 ° C, more preferably 70 to 170 ° C.

  The surface of the optically anisotropic layer containing the liquid crystalline compound of the present invention is preferably smooth so that the liquid crystalline compound is aligned without defects. The range of the arithmetic average roughness Ra (JIS B 0601: 1998) of the roughness curve is preferably 0 to 0.05 μm, more preferably 0.01 to 0.04 μm. On such a smooth surface, there is a tendency that the fluorine-containing compound for aligning the liquid crystalline compound tends to be transferred due to contact with the hard coat layer side surface facing in a roll state. However, the present invention can be solved by setting the shape and surface free energy of the opposing hard coat layer side surface within a specific range.

[Coating solvent]
As a solvent used for preparing the coating solution, an organic solvent is preferably used. Examples of organic solvents include amides (eg, N, N-dimethylformamide), sulfoxides (eg, dimethyl sulfoxide), heterocyclic compounds (eg, pyridine), hydrocarbons (eg, benzene, hexane), alkyl halides (eg, , Chloroform, dichloromethane), esters (eg, methyl acetate, ethyl acetate, butyl acetate), ketones (eg, acetone, methyl ethyl ketone), ethers (eg, tetrahydrofuran, 1,2-dimethoxyethane). Alkyl halides and ketones are preferred. Two or more organic solvents may be used in combination.

[Coating method]
The coating liquid can be applied by a known method (eg, wire bar coating method, extrusion coating method, direct gravure coating method, reverse gravure coating method, die coating method).

[Alignment film]
In the present invention, it is preferable to align the molecules of the liquid crystal compound by applying the composition to the surface of the alignment film. The optical film of the present invention preferably has an alignment film between the transparent support and the optically anisotropic layer. Since the alignment film has a function of defining the alignment direction of the liquid crystalline compound, it is preferably used for realizing a preferred embodiment of the present invention. However, if the alignment state is fixed after aligning the liquid crystalline compound, the alignment film plays the role, and thus is not necessarily an essential component of the present invention. That is, it is also possible to produce the optical substrate for an optical film of the present invention by transferring only the optical anisotropic layer on the alignment film in which the alignment state is fixed onto another transparent support.
The alignment film is an organic compound (eg, ω-tricosanoic acid) formed by rubbing treatment of an organic compound (preferably polymer), oblique deposition of an inorganic compound, formation of a layer having a microgroove, or Langmuir-Blodgett method (LB film). , Dioctadecylmethylammonium chloride, methyl stearylate). Furthermore, an alignment film in which an alignment function is generated by application of an electric field, application of a magnetic field, or light irradiation is also known.
The alignment film is preferably formed by polymer rubbing treatment.

  Examples of the polymer include methacrylate copolymer, styrene copolymer, polyolefin, polyvinyl alcohol, modified polyvinyl alcohol, poly (N-methylol) described in paragraph No. [0022] of JP-A-8-338913. Acrylamide), polyester, polyimide, vinyl acetate copolymer, carboxymethylcellulose, polycarbonate and the like. Silane coupling agents can be used as the polymer. Water-soluble polymers (eg, poly (N-methylolacrylamide), carboxymethylcellulose, gelatin, polyvinyl alcohol, modified polyvinyl alcohol) are preferred, gelatin, polyvinyl alcohol and modified polyvinyl alcohol are more preferred, and polyvinyl alcohol and modified polyvinyl alcohol are most preferred. .

  The saponification degree of polyvinyl alcohol is preferably 70 to 100%, and more preferably 80 to 100%. The polymerization degree of polyvinyl alcohol is preferably 100 to 5000.

In the alignment film, a side chain having a crosslinkable functional group (eg, a double bond) is bonded to the main chain, or a crosslinkable functional group having a function of aligning liquid crystal molecules is introduced into the side chain. Is preferred. As the polymer used for the alignment film, either a polymer that can be crosslinked by itself or a polymer that is crosslinked by a crosslinking agent can be used, and a plurality of combinations thereof can be used.
When a side chain having a crosslinkable functional group is bonded to the main chain of the alignment film polymer or a crosslinkable functional group is introduced into a side chain having a function of aligning liquid crystal molecules, the alignment film polymer and the optically anisotropic film The polyfunctional monomer contained in the conductive layer can be copolymerized. As a result, not only between the polyfunctional monomer and the polyfunctional monomer, but also between the alignment film polymer and the alignment film polymer and between the polyfunctional monomer and the alignment film polymer is firmly bonded by a covalent bond. Therefore, the strength of the optical compensation sheet can be remarkably improved by introducing the crosslinkable functional group into the alignment film polymer.
The crosslinkable functional group of the alignment film polymer preferably contains a polymerizable group in the same manner as the polyfunctional monomer. Specific examples include those described in paragraphs [0080] to [0100] in JP-A-2000-155216.

  Apart from the crosslinkable functional group, the alignment film polymer can also be crosslinked using a crosslinking agent. Examples of the crosslinking agent include aldehydes, N-methylol compounds, dioxane derivatives, compounds that act by activating carboxyl groups, active vinyl compounds, active halogen compounds, isoxazole and dialdehyde starch. Two or more kinds of crosslinking agents may be used in combination. Specific examples include compounds described in paragraphs [0023] to [0024] in JP-A-2002-62426. Aldehydes having high reaction activity, particularly glutaraldehyde are preferred.

  0.1-20 mass% is preferable with respect to a polymer, and, as for the addition amount of a crosslinking agent, 0.5-15 mass% is still more preferable. The amount of the unreacted crosslinking agent remaining in the alignment film is preferably 1.0% by mass or less, and more preferably 0.5% by mass or less. By adjusting in this way, even if the alignment film is used for a long time in a liquid crystal display device or left in a high temperature and high humidity atmosphere for a long time, sufficient durability without reticulation can be obtained.

  The alignment film is basically formed by applying a solution containing the polymer, the cross-linking agent, and the additive, which is an alignment film forming material, onto a transparent support, followed by heat drying (cross-linking) and rubbing treatment. be able to. As described above, the crosslinking reaction may be performed at an arbitrary time after coating on the transparent support. When a water-soluble polymer such as polyvinyl alcohol is used as the alignment film forming material, the coating solution is preferably a mixed solvent of an organic solvent (eg, methanol) having a defoaming action and water. The ratio of water: methanol is preferably 0: 100 to 99: 1, and more preferably 0: 100 to 91: 9. Thereby, generation | occurrence | production of a bubble is suppressed and the defect of the layer surface of an orientation film and also an optically anisotropic layer reduces remarkably.

  The coating method used for forming the alignment film is preferably a spin coating method, a dip coating method, a curtain coating method, an extrusion coating method, a rod coating method or a roll coating method. A rod coating method is particularly preferable. Moreover, 0.1-10 micrometers is preferable, as for the film thickness after drying, 0.2-5.0 micrometers is more preferable, 0.3-3.0 micrometers is still more preferable, 0.4-2.0 micrometers is especially preferable. Heating and drying can be performed at 20 ° C to 110 ° C. In order to form sufficient cross-linking, 60 ° C to 100 ° C is preferable, and 80 ° C to 100 ° C is particularly preferable. The drying time can be 1 minute to 36 hours, preferably 1 minute to 30 minutes. The pH is also preferably set to an optimum value for the cross-linking agent to be used, and when glutaraldehyde is used, pH 4.5 to 5.5 is preferable.

  The alignment film is preferably provided on the transparent support. The alignment film can be obtained by rubbing the surface after crosslinking the polymer layer as described above.

  For the rubbing treatment, a treatment method widely adopted as a liquid crystal alignment treatment process of LCD can be applied. That is, a method of obtaining the orientation by rubbing the surface of the orientation film in a certain direction using paper, gauze, felt, rubber, nylon, polyester fiber or the like can be used. In general, it is carried out by rubbing several times using a cloth in which fibers having a uniform length and thickness are flocked on average.

  The said composition is apply | coated to the rubbing process surface of alignment film, and the molecule | numerator of a liquid crystalline compound is aligned. Thereafter, if necessary, the alignment film polymer and the polyfunctional monomer contained in the optically anisotropic layer are reacted, or the alignment film polymer is crosslinked using a crosslinking agent, thereby the optically anisotropic layer. Can be formed.

[Hard coat layer]
The hard coat layer in the optical film of the present invention will be described.
In the present invention, the hard coat layer refers to a layer in which the pencil hardness of the transparent support is increased by forming the layer. Practically, the pencil hardness (JIS K5400) after laminating the hard coat layer is preferably H or higher, more preferably 2H or higher, and most preferably 3H or higher.
The thickness of the hard coat layer is preferably 0.4 to 35 μm, more preferably 1 to 30 μm, and most preferably 1.5 to 20 μm.
In the present invention, the hard coat layer may be a single layer or a plurality of layers. When there are a plurality of hard coat layers, it is preferable that the total film thickness of all the hard coat layers is in the upper range.
From the viewpoint of blackening, the optical film of the present invention has an internal haze of 1% or more in order to make interference unevenness inconspicuous, and the surface on the side where the hard coat layer is formed is substantially smooth. preferable.
More specifically, it is preferable to satisfy the conditions regarding the following internal haze, surface haze, and Ra.

The internal haze of the hard coat layer is preferably 1 to 20%, more preferably 1 to 15%, and still more preferably 1 to 10% from the viewpoint of uneven interference and blackening. By controlling the internal haze within the above range, interference unevenness due to the optically anisotropic layer is hardly noticeable, and the darkening feeling can be made in a good range.
Further, the internal haze of the optical film of the present invention is preferably 1 to 20%, more preferably 1 to 15%, and still more preferably 1 to 10%.

The surface haze of the hard coat layer lamination surface is preferably less than 1.0%, more preferably 0.6% or less, and 0.4% or less from the viewpoint of interference unevenness and blackening. Is more preferable.
The surface haze of the optical film of the present invention is preferably less than 1.0%, more preferably 0.6% or less, and further preferably 0.4% or less.

  The laminated surface of the hard coat layer (surface opposite to the transparent support) is substantially smooth. In the present invention, the arithmetic mean roughness Ra (JIS B 0601: 1998) of the roughness curve of the laminated surface of the hard coat layer is preferably 0.08 μm or less, more preferably 0.07 μm or less, and 0.06 μm or less. Is more preferable, and 0.05 μm or less is particularly preferable.

[Hard coat layer forming material]
In the present invention, the hard coat layer comprises a compound containing an unsaturated double bond, a light-transmitting particle, a polymerization initiator, and a fluorine-containing or silicone-based compound, if necessary, a composition on a support. It can be formed by coating, drying, and curing directly or through another layer. Each component will be described below.

[Compound having an unsaturated double bond]
The composition for forming a hard coat layer of the present invention can contain a compound having an unsaturated double bond. The compound having an unsaturated double bond can function as a binder, and is preferably a polyfunctional monomer having two or more polymerizable unsaturated groups. The polyfunctional monomer having two or more polymerizable unsaturated groups can function as a curing agent, and can improve the strength and scratch resistance of the coating film. The number of polymerizable unsaturated groups is more preferably 3 or more. These monomers can be used in combination of a monofunctional or bifunctional monomer and a trifunctional or higher monomer.

Examples of the compound having an unsaturated double bond include compounds having a polymerizable functional group such as a (meth) acryloyl group, a vinyl group, a styryl group, and an allyl group. Among them, a (meth) acryloyl group and —C (O ) OCH = CH ₂ is preferred. Particularly preferably, a compound containing three or more (meth) acryloyl groups in one molecule described below can be used.

  Specific examples of the compound having a polymerizable unsaturated bond include (meth) acrylic acid diesters of alkylene glycol, (meth) acrylic acid diesters of polyoxyalkylene glycol, and (meth) acrylic acid diesters of polyhydric alcohol. , (Meth) acrylic acid diesters of ethylene oxide or propylene oxide adducts, epoxy (meth) acrylates, urethane (meth) acrylates, polyester (meth) acrylates, and the like.

  Among these, esters of polyhydric alcohol and (meth) acrylic acid are preferable. For example, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, neopentyl glycol (meth) acrylate, ethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate , Pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, trimethylolpropane tri (meth) acrylate, EO modified trimethylolpropane tri (meth) acrylate, PO modified trimethylolpropane tri (meth) acrylate, EO modified Tri (meth) acrylate phosphate, trimethylolethane tri (meth) acrylate, ditrimethylolpropane tetra (meth) acrylate, dipentaerythritol tetra (meth) acrylate Rate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, pentaerythritol hexa (meth) acrylate, 1,2,3-chlorohexane tetramethacrylate, polyurethane polyacrylate, polyester polyacrylate, caprolactone modified tris And (acryloxyethyl) isocyanurate.

  Commercially available polyfunctional acrylate compounds having a (meth) acryloyl group can be used, such as NK ester A-TMMT manufactured by Shin-Nakamura Chemical Co., Ltd., KAYARAD DPHA manufactured by Nippon Kayaku Co., Ltd. Can be mentioned. The polyfunctional monomer is described in paragraphs [0114] to [0122] of JP-A-2009-98658, and the same applies to the present invention.

  The compound having an unsaturated double bond is preferably a compound having a hydrogen-bonding substituent from the viewpoint of adhesion to the support, low curl, and fluorine-containing or silicone-based compound fixation described later. . The hydrogen-bonding substituent refers to a substituent in which an atom having a large electronegativity such as nitrogen, oxygen, sulfur, or halogen and a hydrogen bond are covalently bonded. Specifically, OH—, SH—, — NH-, CHO-, CHN- and the like can be mentioned, and urethane (meth) acrylates and (meth) acrylates having a hydroxyl group are preferable. Commercially available polyfunctional acrylates having a (meth) acryloyl group can also be used. Shin Nakamura Chemical Co., Ltd. NK Oligo U4HA, NK Ester A-TMM-3, Nippon Kayaku Co., Ltd. KAYARAD PET-30 etc. can be mentioned.

  The content of the compound having an unsaturated double bond in the composition for forming a hard coat layer of the present invention provides a sufficient polymerization rate and imparts hardness and the like, so that the total solid in the composition for forming a hard coat layer 60-99 mass% is preferable with respect to a minute, 70-99 mass% is more preferable, and 80-99 mass% is especially preferable.

[Translucent particles]
The optical film of the present invention needs to have an internal haze of 1% or more, and the internal haze is imparted by incorporating light-scattering fine particles having a refractive index difference with the hard coat layer binder in the hard coat layer. It is preferable.
As described above, the hard coat layer of the present invention may be a single layer or a plurality of layers. However, when the hard coat layer contains light scattering fine particles to impart internal haze, the hard coat layer contains light scattering fine particles. The surface of the coat layer may develop unnecessary irregularities. As described above, in the present invention, it is preferable that the surface of the hard coat layer lamination side is substantially flat. In this case, the hard coat layer has a two-layer structure, and only the hard coat layer on the side close to the support is light scattering. It is also a preferred embodiment to contain fine particles.

  Translucent particles that can be used in the hard coat layer include polymethyl methacrylate particles (refractive index 1.49), crosslinked poly (acryl-styrene) copolymer particles (refractive index 1.54), melamine resin particles ( Refractive index 1.57), polycarbonate particles (refractive index 1.57), polystyrene particles (refractive index 1.60), cross-linked polystyrene particles (refractive index 1.61), polyvinyl chloride particles (refractive index 1.60), Examples include benzoguanamine-melamine formaldehyde particles (refractive index 1.68), silica particles (refractive index 1.46), alumina particles (refractive index 1.63), zirconia particles, titania particles, or particles having hollow or pores. It is done.

  Of these, crosslinked poly ((meth) acrylate) particles and crosslinked poly (acryl-styrene) particles are preferably used, and the refractive index of the binder is adjusted according to the refractive index of each light-transmitting particle selected from these particles. By adjusting, surface irregularities, surface haze, internal haze, and total haze suitable for the hard coat layer of the optical film of the present invention can be achieved.

The refractive index of the binder (translucent resin) is preferably 1.45 to 1.70, more preferably 1.48 to 1.65.
Further, the difference in refractive index between the translucent particles and the binder of the hard coat layer (“refractive index of the translucent particles” − “refractive index of the hard coat layer excluding the translucent particles”) is an absolute value. As for it, Preferably it is less than 0.05, More preferably, it is 0.001-0.030, More preferably, it is 0.001-0.020. When the difference in refractive index between the light-transmitting particles and the binder in the hard coat layer is less than 0.05, the light refraction angle by the light-transmitting particles decreases, the scattered light does not spread to a wide angle, and the optical anisotropy There is no adverse effect such as depolarization of the transmitted light of the layer, which is preferable.

In order to realize the difference in refractive index between the particles and the binder, the refractive index of the light-transmitting particles may be adjusted, or the refractive index of the binder may be adjusted.
As a preferable first embodiment, a binder having a tri- or higher functional (meth) acrylate monomer as a main component (a refractive index after curing is 1.50 to 1.53) and an acrylic content of 50 to 100 mass percent is used. It is preferable to use a combination of translucent particles made of poly (meth) acrylate / styrene polymer. By adjusting the composition ratio of the acrylic component having a low refractive index and the styrene component having a high refractive index, it is easy to make the difference in refractive index between the translucent particles and the binder less than 0.05. The ratio of the acrylic component to the styrene component is preferably 50/50 to 100/0, more preferably 60/40 to 100/0, and most preferably 65/35 to 90/10 in terms of mass ratio. The refractive index of the light-transmitting particles comprising the crosslinked poly (meth) acrylate / styrene polymer is preferably 1.49 to 1.55, more preferably 1.50 to 1.54, and most preferably 1. 51 to 1.53.
As a preferred second embodiment, a binder composed of a monomer and inorganic fine particles is obtained by using inorganic fine particles having an average particle size of 1 to 100 nm in combination with a binder mainly composed of a tri- or higher functional (meth) acrylate monomer. The refractive index difference is adjusted to adjust the refractive index difference from the existing light-transmitting particles. The inorganic particles include oxides of at least one metal selected from silicon, zirconium, titanium, aluminum, indium, zinc, tin, and antimony. Specific examples include SiO ₂ , ZrO ₂ , TiO ₂ , and Al ₂ O. ₃ , In ₂ O ₃ , ZnO, SnO ₂ , Sb ₂ O ₃ , ITO and the like. _Preferably, such _{SiO 2, ZrO 2, Al 2} O 3 and the like. These inorganic particles can be used by mixing in the range of 1 to 90% by mass with respect to the total amount of monomers, and preferably 5 to 65% by mass.
Here, the refractive index of the hard coat layer excluding the translucent particles can be quantitatively evaluated by directly measuring with an Abbe refractometer or by measuring a spectral reflection spectrum or a spectral ellipsometry. The refractive index of the translucent particles is measured by measuring the turbidity by dispersing an equal amount of the translucent particles in the solvent in which the refractive index is changed by changing the mixing ratio of two types of solvents having different refractive indexes. It is measured by measuring the refractive index of the solvent when the turbidity is minimized with an Abbe refractometer.

  The average particle diameter of the translucent particles is preferably 1.0 to 12 μm, more preferably 3.0 to 12 μm, still more preferably 4.0 to 10.0 μm, and most preferably 4.5 to 8 μm. By setting the refractive index difference and the particle size within the above ranges, the light scattering angle distribution does not spread to a wide angle, and it is difficult to cause blurring of characters on the display and a decrease in contrast. It is not necessary to increase the thickness of the layer to be added, and 12 μm or less is preferable because it is difficult to cause problems such as curling and cost increase. Furthermore, it is preferable that the amount falls within the above range from the viewpoint that the coating amount during coating can be suppressed, drying is quick, and surface defects such as drying unevenness are unlikely to occur.

  The measuring method of the average particle diameter of the translucent particles can be any measuring method as long as it is a measuring method for measuring the average particle diameter of the particles, but preferably a transmission electron microscope (magnification of 500,000 to 2,000,000 times) The particles are observed by observing 100 particles, and the average value can be obtained as the average particle diameter.

  The shape of the translucent particles is not particularly limited, but in addition to the spherical particles, translucent particles having different shapes such as irregularly shaped particles (for example, non-spherical particles) may be used in combination. In particular, when the minor axes of non-spherical particles are aligned in the normal direction of the hard coat layer, particles having a smaller particle diameter than the true spherical particles can be used.

  The translucent particles are preferably blended so as to be contained in an amount of 0.1 to 40% by mass in the total solid content of the hard coat layer. More preferably, it is 1-30 mass%, More preferably, it is 1-20 mass%. The internal haze can be controlled within a preferable range by adjusting the blending ratio of the translucent particles within the above range.

Moreover, the application amount of translucent particles is preferably 10 to 2500 mg / m ² , more preferably 30 to 2000 mg / m ² , and still more preferably 100 to 1500 mg / m ² .

<Translucent particle preparation, classification method>
Examples of the method for producing the translucent particles include a suspension polymerization method, an emulsion polymerization method, a soap-free emulsion polymerization method, a dispersion polymerization method, a seed polymerization method, and the like, and any method may be used. These production methods are described in, for example, “Experimental Methods for Polymer Synthesis” (Takayuki Otsu and Masaaki Kinoshita, Chemical Dojinsha), pages 130 and 146 to 147, “Synthetic Polymers”, Vol. 246-290, 3rd volume, p. 1 to 108, etc., and Japanese Patent Nos. 2543503, 3508304, 2746275, 3521560, 3580320, and Japanese Patent Laid-Open No. 10-1561. Reference can be made to methods described in JP-A No. 7-2908, JP-A No. 5-297506, JP-A No. 2002-145919, and the like.

The particle size distribution of the translucent particles is preferably monodisperse particles in terms of haze value and diffusibility control, and uniformity of the coated surface. The CV value representing the uniformity of the particle diameter is preferably 15% or less, more preferably 13% or less, and still more preferably 10% or less. Further, when a particle having a particle size of 20% or more than the average particle size is defined as a coarse particle, the proportion of the coarse particle is preferably 1% or less of the total number of particles, more preferably 0.1% or less. Yes, more preferably 0.01% or less. Particles having such a particle size distribution are also effective means of classification after preparation or synthesis reaction, and particles having a desired distribution can be obtained by increasing the number of classifications or increasing the degree of classification. .
It is preferable to use a method such as an air classification method, a centrifugal classification method, a sedimentation classification method, a filtration classification method, or an electrostatic classification method for classification.

[Photopolymerization initiator]
Next, the photopolymerization initiator that can be contained in the composition for forming a hard coat layer will be described.
As photopolymerization initiators, acetophenones, benzoins, benzophenones, phosphine oxides, ketals, anthraquinones, thioxanthones, azo compounds, peroxides, 2,3-dialkyldione compounds, disulfide compounds, Examples include fluoroamine compounds, aromatic sulfoniums, lophine dimers, onium salts, borate salts, active esters, active halogens, inorganic complexes, and coumarins. Specific examples, preferred embodiments, commercially available products, and the like of the photopolymerization initiator are described in paragraphs [0133] to [0151] of JP-A-2009-098658, and can be suitably used in the present invention as well. it can.

  “Latest UV Curing Technology” {Technical Information Association, Inc.} (1991), p. 159, and “UV Curing System” written by Kiyomi Kato (published by the General Technology Center in 1989), p. Various examples are also described in 65-148 and are useful in the present invention.

  Commercially available photocleavable photoradical polymerization initiators include “Irgacure 651”, “Irgacure 184”, “Irgacure 819”, “Irgacure 907”, “Irgacure 1870” (CGI) manufactured by Ciba Specialty Chemicals Co., Ltd. -403 / Irg184 = 7/3 mixing initiator), "Irgacure 500", "Irgacure 369", "Irgacure 1173", "Irgacure 2959", "Irgacure 4265", "Irgacure 4263", "Irgacure 127", "OXE01 “Kaya Cure DETX-S”, “Kaya Cure BP-100”, “Kaya Cure BDK”, “Kaya Cure CTX”, “Kaya Cure BMS”, “Kaya Cure 2-EAQ”, “Kaya Cure ABQ” manufactured by Nippon Kayaku Co., Ltd. ”,“ Kayaki Ar CPTX, Kaya Cure EPD, Kaya Cure ITX, Kaya Cure QTX, Kaya Cure BTC, Kaya Cure MCA, etc .; “Esacure (KIP100F, KB1, EB3, BP, X33, KTO46, KT37) manufactured by Sartomer , KIP150, TZT) ", etc., and combinations thereof are preferred examples.

  The content of the photopolymerization initiator in the composition for forming a hard coat layer of the present invention is large enough to polymerize the polymerizable compound contained in the composition for forming a hard coat layer, and the starting point does not increase too much. For the reason that it is set to a sufficiently small amount, 0.5 to 8% by mass is preferable and 1 to 5% by mass is more preferable with respect to the total solid content in the composition for forming a hard coat layer.

[solvent]
The composition for forming a hard coat layer of the present invention can contain a solvent. Various solvents can be used as the solvent in consideration of the solubility of the monomer, the dispersibility of the light-transmitting particles, the drying property at the time of coating, and the like. Examples of such organic solvents include dibutyl ether, dimethoxyethane, diethoxyethane, propylene oxide, 1,4-dioxane, 1,3-dioxolane, 1,3,5-trioxane, tetrahydrofuran, anisole, phenetole, dimethyl carbonate, carbonic acid. Methyl ethyl, diethyl carbonate, acetone, methyl ethyl ketone (MEK), diethyl ketone, dipropyl ketone, diisobutyl ketone, cyclopentanone, cyclohexanone, methylcyclohexanone, ethyl formate, propyl formate, pentyl formate, methyl acetate, ethyl acetate, propyl acetate, Methyl propionate, ethyl propionate, γ-ptyrolactone, methyl 2-methoxyacetate, methyl 2-ethoxyacetate, ethyl 2-ethoxyacetate, ethyl 2-ethoxypropionate, 2-metho Siethanol, 2-propoxyethanol, 2-butoxyethanol, 1,2-diacetoxyacetone, acetylacetone, diacetone alcohol, methyl acetoacetate, methyl acetoacetate and other methyl alcohol, ethyl alcohol, isopropyl alcohol, n-butyl alcohol, cyclohexyl Alcohol, isobutyl acetate, methyl isobutyl ketone (MIBK), 2-octanone, 2-pentanone, 2-hexanone, ethylene glycol ethyl ether, ethylene glycol isopropyl ether, ethylene glycol butyl ether, propylene glycol methyl ether, ethyl carbitol, butyl carbitol , Hexane, heptane, octane, cyclohexane, methylcyclohexane, ethylcyclohexane, benzene, tolu Examples thereof include ene and xylene, and these can be used alone or in combination of two or more.

  It is preferable to use a solvent so that the solid content of the composition for forming a hard coat layer of the present invention is in the range of 20 to 80% by mass, more preferably 30 to 75% by mass, and still more preferably 40 to 40% by mass. 70% by mass.

[Layer structure of optical film]
The optical film of the present invention has a hard coat layer on one side of the transparent support and an optically anisotropic layer on the other side, but additionally a necessary functional layer alone depending on the purpose. Alternatively, a plurality of layers may be provided. For example, an antireflection layer (a layer having a refractive index adjusted, such as a low refractive index layer, a medium refractive index layer, or a high refractive index layer), an antistatic layer, an ultraviolet absorption layer, or the like can be provided. The hard coat layer may have antistatic properties and ultraviolet absorption properties.

The example of the more concrete layer structure of the optical film of this invention is shown below.
Optical anisotropic layer / alignment film / transparent support / hard coat layer Optical anisotropic layer / alignment film / transparent support / hard coat layer / overcoat layer Optical anisotropic layer / alignment film / transparent support / hard Coat layer / low refractive index layer optical anisotropic layer / alignment film / transparent support / hard coat layer / high refractive index layer / low refractive index layer optical anisotropic layer / alignment film / transparent support / hard coat layer / Medium refractive index layer / high refractive index layer / low refractive index layer Optically anisotropic layer / alignment film / transparent support / hard coat layer / medium refractive index layer / high refractive index layer / low refractive index layer / antifouling layer Among the configurations, a low refractive index layer is preferably provided on the outermost layer on the hard coat layer side. Providing a low refractive index layer further improves the feeling of blackening.

[Material for low refractive index layer]
The material for the low refractive index layer will be described below.

[Inorganic fine particles]
From the viewpoint of lowering the refractive index and improving the scratch resistance, it is preferable to use inorganic fine particles in the low refractive index layer. The inorganic fine particles are not particularly limited as long as the average particle size is 5 to 120 nm, but inorganic low refractive index particles are preferable from the viewpoint of lowering the refractive index.

  Examples of the inorganic fine particles include magnesium fluoride and silica fine particles because of their low refractive index. In particular, silica fine particles are preferable in terms of refractive index, dispersion stability, and cost. The size (primary particle size) of these inorganic particles is preferably 5 to 120 nm, more preferably 10 to 100 nm, 20 to 100 nm, and most preferably 30 to 90 nm.

  If the particle size of the inorganic fine particles is too small, the effect of improving the scratch resistance is reduced. If the particle size is too large, fine irregularities are formed on the surface of the low refractive index layer, and the appearance such as black tightening and the integrated reflectance are deteriorated. Further, when hollow silica fine particles described later are used, if the particle size is too small, the ratio of the pores is reduced and a sufficient decrease in the refractive index cannot be expected. The inorganic fine particles may be either crystalline or amorphous, and may be monodispersed particles or aggregated particles as long as a predetermined particle size is satisfied. The shape is most preferably a spherical diameter, but may be indefinite.

The coating amount of the inorganic fine particles is ^{preferably 1mg / m 2 ~100mg / m 2} , more preferably ^{5mg / m 2 ~80mg / m 2} , more preferably from ^{10mg / m 2 ~60mg / m 2} . If the amount is too small, a sufficiently low refractive index cannot be expected or the effect of improving the scratch resistance is reduced. If the amount is too large, fine irregularities are formed on the surface of the low refractive index layer, and the appearance and integration such as black tightening Reflectivity deteriorates.

(Porous or hollow fine particles)
In order to reduce the refractive index, it is preferable to use fine particles having a porous or hollow structure. It is particularly preferable to use hollow structure silica particles. The porosity of these particles is preferably 10 to 80%, more preferably 20 to 60%, and most preferably 30 to 60%. It is preferable that the void ratio of the hollow fine particles be in the above range from the viewpoint of lowering the refractive index and maintaining the durability of the particles.

  When the porous or hollow particles are silica, the refractive index of the fine particles is preferably 1.10 to 1.40, more preferably 1.15 to 1.35, and most preferably 1.15 to 1.30. is there. The refractive index here represents the refractive index of the entire particle, and does not represent the refractive index of only the outer shell silica forming the silica particles.

  Further, two or more kinds of hollow silica having different particle average particle sizes can be used in combination. Here, the average particle diameter of the hollow silica can be determined from an electron micrograph.

The specific surface area of the hollow silica in the present invention is preferably from 20 to 300 m ² / g, more preferably 30~120m ² / g, most preferably 40~90m ² / g. The surface area can be determined by the BET method using nitrogen.

  In the present invention, silica particles having no pores can be used in combination with hollow silica. The preferred particle size of silica without voids is 30 nm to 150 nm, more preferably 35 nm to 100 nm, and most preferably 40 nm to 80 nm.

[Inorganic fine particle surface treatment method]
Further, in the present invention, inorganic fine particles can be used after being surface-treated with a silane coupling agent or the like by a conventional method.
In particular, in order to improve dispersibility in the binder for forming a low refractive index layer, the surface of the inorganic fine particles is preferably treated with a hydrolyzate of an organosilane compound and / or a partial condensate thereof. In this case, it is more preferable to use either an acid catalyst or a metal chelate compound or both.
The method for treating the surface of the inorganic fine particles is described in paragraphs [0046] to [0076] of JP-A-2008-242314, and the organosilane compound, the siloxane compound, and the solvent for the surface treatment described in the document. Surface treatment catalysts, metal chelate compounds, and the like can also be suitably used in the present invention.

For the low refractive index layer, (b2) a fluorine-containing or non-fluorine-containing monomer having a polymerizable unsaturated group can be used. As the non-fluorinated monomer, it is preferable to use a compound having an unsaturated double bond described as being usable in the hard coat layer. As the fluorine-containing monomer, a fluorine-containing polyfunctional monomer (d) represented by the following general formula (1), containing 35% by mass or more of fluorine and having a calculated value of all cross-linking molecular weights smaller than 500 is used. Is preferred.
General formula (1): Rf2 {-(L) mY} n
(In General Formula (1), Rf2 represents an n-valent group containing at least a carbon atom and a fluorine atom, n represents an integer of 3 or more, L represents a single bond or a divalent linking group, and m represents 0. Or represents 1. Y represents a polymerizable unsaturated group.)
Rf2 may contain at least one of an oxygen atom and a hydrogen atom. Rf2 is linear (straight or branched) or cyclic.

Y is preferably a group containing two carbon atoms forming an unsaturated bond, more preferably a radical polymerizable group, a (meth) acryloyl group, an allyl group, an α-fluoroacryloyl group, and Those selected from —C (O) OCH═CH ₂ are particularly preferred. Among these, from the viewpoint of polymerizability, (meth) acryloyl group, allyl group, α-fluoroacryloyl group, and C (O) OCH═CH ₂ having radical polymerizability are more preferable.

L represents a divalent linking group, specifically, an alkylene group having 1 to 10 carbon atoms, an arylene group having 6 to 10 carbon atoms, -O-, -S-, -N (R)-, 1 to carbon atoms. A group obtained by combining 10 alkylene group and —O—, —S— or N (R) —, a combination of an arylene group having 6 to 10 carbon atoms and —O—, —S— or N (R) —. Represents the resulting group. R represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms. When L represents an alkylene group or an arylene group, the alkylene group and the arylene group represented by L are preferably substituted with a halogen atom, and preferably substituted with a fluorine atom.
Specific examples of the compound represented by the general formula (1) are described in paragraphs [0121] to [0163] of JP 2010-152111 A.

(Method of applying hard coat layer)
The hard coat layer according to the optical film of the present invention can be formed by the following method.
First, a composition for forming a hard coat layer is prepared. Next, the composition is applied onto a transparent support by dip coating, air knife coating, curtain coating, roller coating, wire bar coating, gravure coating, die coating, or the like, and heated and dried. A micro gravure coating method, a wire bar coating method, and a die coating method (see US Pat. No. 2,681,294 and JP-A-2006-122889) are more preferable, and a die coating method is particularly preferable.
The optical film of the present invention is an optical film in which an optically anisotropic layer containing a liquid crystalline compound is applied to one side of a transparent support and a hard coat layer is applied to another side. The order to do is not specifically limited.

  After the hard coat layer is coated on the transparent support, it is conveyed by a web to a heated zone to dry the solvent. In this case, the temperature of the drying zone is preferably 25 ° C. to 140 ° C., the first half of the drying zone is relatively low temperature, and the second half is preferably relatively high temperature. However, it is preferably below the temperature at which components other than the solvent contained in the coating composition of each layer start to volatilize. For example, some of the commercially available photo radical generators used in combination with ultraviolet curable resins volatilize around several tens of percent within a few minutes in warm air at 120 ° C. Some acrylate monomers and the like undergo volatilization in warm air at 100 ° C. In such a case, as described above, the temperature is preferably equal to or lower than the temperature at which components other than the solvent contained in the hard coat layer coating composition start to volatilize.

Moreover, the drying wind after apply | coating the coating composition of a hard-coat layer on a base film has a wind speed of the coating-film surface of 0.1-2 m while the solid content concentration of the said coating composition is 1-50%. / Second is preferable in order to prevent unevenness in drying.
In addition, after the coating composition of the hard coat layer is coated on the base film, the temperature difference between the transport roll and the base film contacting the surface opposite to the coating surface of the base film in the drying zone is 0 ° C. When the temperature is within -20 ° C, drying unevenness due to heat transfer unevenness on the transport roll can be prevented, which is preferable.

After the solvent drying zone, the web is passed through a zone where the hard coat layer is cured by irradiation with ionizing radiation, and the coating film is cured. For example, if the coating film is ultraviolet-curable, preferably to cure the coating by an irradiation amount of 10mJ ^/ cm ² ~1000mJ ^/ cm 2 by an ultraviolet lamp. At that time, the irradiation distribution in the width direction of the web is preferably 50 to 100%, more preferably 80 to 100%, including both ends with respect to the central maximum irradiation. Further, when it is necessary to purge nitrogen gas or the like to lower the oxygen concentration in order to promote surface hardening, the oxygen concentration is preferably 0.01% to 5%, and the distribution in the width direction is 2% or less in terms of oxygen concentration. Is preferred. In the case of ultraviolet irradiation, ultraviolet rays emitted from light such as an ultrahigh pressure mercury lamp, a high pressure mercury lamp, a low pressure mercury lamp, a carbon arc, a xenon arc, a metal halide lamp, etc. can be used. Moreover, in order to accelerate | stimulate hardening reaction, temperature can also be raised at the time of hardening, 25-100 degreeC is preferable, More preferably, it is 30-80 degreeC, Most preferably, it is 40-70 degreeC.

  In this way, the hard coat layer of the present invention can be applied, dried and cured. Further, other functional layers can be provided as necessary. When other functional layers are laminated in addition to the hard coat layer, a plurality of layers may be applied simultaneously or sequentially. The manufacturing method of these layers can be performed according to the manufacturing method of a hard-coat layer.

[Polarizer]
The polarizing plate of the present invention is a polarizing plate having a polarizing film and two protective films for protecting both surfaces of the polarizing film, and at least one of the protective films is preferably the optical film of the present invention.
The polarizing plate of the present invention is a polarizing plate having at least one protective film and a polarizing film, wherein the at least one protective film is the optical film of the present invention, and the optical anisotropic layer side of the optical film. And a polarizing plate in which the polarizing film is bonded. Here, it is preferable that the optically anisotropic layer and the polarizing film are bonded directly or via an adhesive layer or an adhesive layer. For example, other members such as a transparent support are not interposed therebetween. It is preferable. By not interposing other members, it is possible to contribute to the thinning of the polarizing plate, and interference unevenness hardly occurs, which is preferable.
Examples of the polarizing film include an iodine polarizing film, a dye polarizing film using a dichroic dye, and a polyene polarizing film. The iodine-based polarizing film and the dye-based polarizing film can be generally produced using a polyvinyl alcohol film.

It is preferable that the optical anisotropic layer side of the optical film is bonded to the polarizing film via an adhesive or other base material, and the protective film is also provided on the other side of the polarizing film, more preferably the optical film. The optically anisotropic layer is directly bonded to the polarizing film through an adhesive. In order to improve the adhesion between the optically anisotropic layer and the polarizing film, the surface of the optically anisotropic layer is subjected to surface treatment (eg, glow discharge treatment, corona discharge treatment, plasma treatment, ultraviolet (UV) treatment, flame (Treatment, saponification treatment, solvent washing) is preferably carried out. Further, an adhesive layer (undercoat layer) may be provided on the optically anisotropic layer.
Moreover, you may have an adhesive layer in the surface on the opposite side to the polarizing film of the other protective film which comprises a polarizing plate.

By using the optical film of the present invention as a protective film for a polarizing plate, a polarizing plate excellent in physical strength, antifouling property and durability can be produced in addition to the optical performance expected for a λ / 4 film.
The optical film of the present invention is suitably used as a surface film for liquid crystal display devices.

  Moreover, the polarizing plate of the present invention can also have an optical compensation function. In that case, it is preferable to use the optical film of the present invention as a protective film on one surface of the polarizing film and the optical compensation film as a protective film on the other surface.

[Image display device]
The optical film and polarizing plate of the present invention are suitably used for image display devices such as liquid crystal display devices (LCD), plasma display panels (PDP), electroluminescence displays (ELD), and cathode ray tube display devices (CRT). In particular, it is preferably used for a liquid crystal display device and is suitable for a stereoscopic image display device (3D display device). Among them, it is particularly preferable to use for a time-division binocular stereoscopic transmission type liquid crystal display device.

In general, a liquid crystal display device has a liquid crystal cell and two polarizing plates arranged on both sides thereof, and the liquid crystal cell carries a liquid crystal between two electrode substrates.
A preferred embodiment of the liquid crystal display device of the present invention is a liquid crystal display device having the optical film, the polarizing film, and the liquid crystal cell in this order from the viewing side, wherein the optical film has a hard coat layer. In the liquid crystal display device, the optically anisotropic layer is disposed on the viewing side so that the optically anisotropic layer is on the polarizing film side.
The liquid crystal cell is preferably in TN mode, VA mode, OCB mode, IPS mode or ECB mode.

  The features of the present invention will be described more specifically with reference to examples and comparative examples. The materials, amounts used, ratios, processing details, processing procedures, and the like shown in the following examples can be changed as appropriate without departing from the spirit of the present invention. Therefore, the scope of the present invention should not be construed as being limited by the specific examples shown below. Unless otherwise specified, “part” and “%” are based on mass.

<Preparation of transparent support (cellulose acetate film T1)>
The following composition was put into a mixing tank, stirred while heating to dissolve each component, and a cellulose acetate solution (dope A) having a solid content concentration of 22% by mass was prepared.
[Composition of Cellulose Acetate Solution (Dope A)]
Cellulose acetate with an acetyl substitution degree of 2.86 100 parts by weight Triphenyl phosphate (plasticizer) 7.8 parts by weight Biphenyl diphenyl phosphate (plasticizer) 3.9 parts by weight Ultraviolet absorber (manufactured by Tinuvin 328 Ciba Japan) 0.9 Part by weight Ultraviolet absorber (manufactured by Tinuvin 326 Ciba Japan) 0.2 part by weight Methylene chloride (first solvent) 336 parts by weight Methanol (second solvent) 29 parts by weight 1-butanol (third solvent) 11 parts by weight

  A dope B containing a matting agent was prepared by adding 0.02 parts by mass of silica particles (AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) having an average particle diameter of 16 nm to 100 parts by mass of cellulose acetate. The dope B was adjusted so that the solid content concentration was 19% by mass with the same solvent composition as the dope A.

  The dope A was mainstream, and the dope B with matting agent was the lowermost layer and the uppermost layer, and was cast using a band stretching machine. After the film surface temperature on the band reaches 40 ° C., the film is dried with warm air of 70 ° C. for 1 minute, and the film is peeled off from the band and dried with 140 ° C. drying air for 10 minutes. % Cellulose acetate film T1 was produced. The flow rate was adjusted so that the lowermost layer and the uppermost layer containing the matting agent each had a thickness of 3 μm, and the mainstream had a thickness of 74 μm.

The obtained long cellulose acetate film T1 had a width of 2300 mm and a thickness of 80 μm. The in-plane retardation (Re) at a wavelength of 550 nm was 3 nm, and the retardation in the thickness direction (Rth) was 45 nm. The transmittance at 380 nm was 3.8%, and the average transmittance at 450 to 650 nm was 92%.
The measurement of retardation was performed by the method described in this specification.
The transmittance was measured with a spectrophotometer.

<Preparation of transparent support (cellulose acetate film T2)>
The following composition was put into a mixing tank and stirred while heating to dissolve each component to prepare a cellulose acetate solution (dope C) having a solid content concentration of 22% by mass.
[Composition of cellulose acetate solution (Dope C)]
Cellulose acetate with an acetyl substitution degree of 2.86 100 parts by weight Triphenyl phosphate (plasticizer) 7.8 parts by weight Biphenyl diphenyl phosphate (plasticizer) 3.9 parts by weight Ultraviolet absorber (Tinuvin 328 manufactured by Ciba Japan) 0.45 Part by mass Ultraviolet absorber (manufactured by Tinuvin 326 Ciba Japan) 0.10 parts by mass Methylene chloride (first solvent) 336 parts by mass Methanol (second solvent) 29 parts by mass 1-butanol (third solvent) 11 parts by mass

  A dope D containing a matting agent was prepared by adding 0.02 parts by mass of silica particles (AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) having an average particle diameter of 16 nm to 100 parts by mass of cellulose acetate. The dope D was adjusted so that the solid content concentration was 19% by mass with the same solvent composition as the dope C.

  The dope C was mainstream, the matting agent-containing dope D was the lowermost layer and the uppermost layer, and cast using a band stretching machine. After the film surface temperature on the band reaches 40 ° C., the film is dried with warm air of 70 ° C. for 1 minute, the film is peeled off from the band and dried with 140 ° C. drying air for 10 minutes, and the residual solvent amount is 0.3 mass. % Cellulose acetate film T2 was produced. The flow rate was adjusted so that the lowermost layer and the uppermost layer containing the matting agent each had a thickness of 3 μm, and the mainstream had a thickness of 74 μm.

  The obtained long cellulose acetate film T2 had a width of 2300 mm and a thickness of 80 μm. The in-plane retardation (Re) at a wavelength of 550 nm was 3 nm, and the retardation in the thickness direction (Rth) was 45 nm. The transmittance at 380 nm was 19.5%, and the average transmittance at 450 to 650 nm was 92%.

<Preparation of transparent support (cellulose acetate film T3)>
The following composition was put into a mixing tank and stirred while heating to dissolve each component to prepare a cellulose acetate solution (dope E) having a solid content concentration of 22% by mass.
[Composition of cellulose acetate solution (Dope E)]
Cellulose acetate with an acetyl substitution degree of 2.86 100 parts by weight Triphenyl phosphate (plasticizer) 7.8 parts by weight Biphenyl diphenyl phosphate (plasticizer) 3.9 parts by weight UV absorber (Tinubin 328 manufactured by Ciba Japan) 0.20 Part by mass Ultraviolet absorber (manufactured by Tinuvin 326 Ciba Japan) 0.05 part by mass Methylene chloride (first solvent) 336 parts by mass Methanol (second solvent) 29 parts by mass 1-butanol (third solvent)

  A dope F containing a matting agent was prepared by adding 0.02 parts by mass of silica particles (AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) having an average particle diameter of 16 nm to 100 parts by mass of cellulose acetate. The solid composition concentration was adjusted to 19% by mass with the same solvent composition as dope E.

  The dope E was used as the main stream, and the dope F containing the matting agent was formed in the lowermost layer and the uppermost layer, and was cast using a band stretching machine. After the film surface temperature on the band reaches 40 ° C., the film is dried with warm air of 70 ° C. for 1 minute, the film is peeled off from the band and dried with 140 ° C. drying air for 10 minutes, and the residual solvent amount is 0.3 mass. % Cellulose acetate film T3 was produced. The flow rate was adjusted so that the lowermost layer and the uppermost layer containing the matting agent each had a thickness of 3 μm, and the mainstream had a thickness of 74 μm.

  The obtained long cellulose acetate film T3 had a width of 2300 mm and a thickness of 80 μm. The in-plane retardation (Re) at a wavelength of 550 nm was 3 nm, and the retardation in the thickness direction (Rth) was 45 nm. The transmittance at 380 nm was 49.0%, and the average transmittance at 450 to 650 nm was 92%.

<Preparation of transparent support (cellulose acetate film T4)>
The following composition was put into a mixing tank and stirred while heating to dissolve each component to prepare a cellulose acetate solution (dope G) having a solid content concentration of 22% by mass.
[Composition of cellulose acetate solution (Dope G)]
Cellulose acetate with an acetyl substitution degree of 2.86 100 parts by weight Triphenyl phosphate (plasticizer) 7.8 parts by weight Biphenyl diphenyl phosphate (plasticizer) 3.9 parts by weight Ultraviolet absorber (Tinubin 328 manufactured by Ciba Japan) 0.18 Part by mass UV absorber (manufactured by Tinuvin 326 Ciba Japan) 0.04 parts by mass Methylene chloride (first solvent) 336 parts by mass Methanol (second solvent) 29 parts by mass 1-butanol (third solvent) 11 parts by mass

  A dope H containing a matting agent was prepared by adding 0.02 parts by mass of silica particles (AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) having an average particle diameter of 16 nm to 100 parts by mass of cellulose acetate. The solid composition concentration was adjusted to 19% by mass with the same solvent composition as the dope G.

  The dope G was mainstream, the dope H containing the matting agent was the lowermost layer and the uppermost layer, and cast using a band stretching machine. After the film surface temperature on the band reaches 40 ° C., the film is dried with warm air of 70 ° C. for 1 minute, the film is peeled off from the band and dried with 140 ° C. drying air for 10 minutes, and the residual solvent amount is 0.3 mass. % Cellulose acetate film T4 was produced. The flow rate was adjusted so that the lowermost layer and the uppermost layer containing the matting agent each had a thickness of 3 μm, and the mainstream had a thickness of 74 μm.

  The obtained long cellulose acetate film T4 had a width of 2300 mm and a thickness of 80 μm. The in-plane retardation (Re) at a wavelength of 550 nm was 3 nm, and the retardation in the thickness direction (Rth) was 45 nm. The transmittance at 380 nm was 52.0%, and the average transmittance at 450 to 650 nm was 92%.

<Preparation of transparent support (cellulose acetate film T5)>
The following composition was put into a mixing tank, stirred while heating to dissolve each component, and a cellulose acetate solution (dope I) having a solid content concentration of 22% by mass was prepared.
[Composition of cellulose acetate solution (Dope I)]
Cellulose acetate having an acetyl substitution degree of 2.86 100 parts by weight Triphenyl phosphate (plasticizer) 7.8 parts by weight Biphenyl diphenyl phosphate (plasticizer) 3.9 parts by weight Methylene chloride (first solvent) 336 parts by weight Methanol (second Solvent) 29 parts by mass 1-butanol (third solvent) 11 parts by mass

  A dope J containing a matting agent was prepared by adding 0.02 parts by mass of silica particles (AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) having an average particle diameter of 16 nm to 100 parts by mass of cellulose acetate. It adjusted so that solid content concentration might be 19 mass% by the same solvent composition as dope I.

  The dope I was mainstream, the dope J with matting agent was the lowermost layer and the uppermost layer, and was cast using a band stretching machine. After the film surface temperature on the band reaches 40 ° C., the film is dried with warm air of 70 ° C. for 1 minute, the film is peeled off from the band and dried with 140 ° C. drying air for 10 minutes, and the residual solvent amount is 0.3 mass. % Cellulose acetate film T5 was produced. The flow rate was adjusted so that the lowermost layer and the uppermost layer containing the matting agent each had a thickness of 3 μm, and the mainstream had a thickness of 74 μm.

  The obtained long cellulose acetate film T5 had a width of 2300 mm and a thickness of 80 μm. The in-plane retardation (Re) at a wavelength of 550 nm was 3 nm, and the retardation in the thickness direction (Rth) was 45 nm. The transmittance at 380 nm was 90%, and the average transmittance at 450 to 650 nm was 92%.

<Preparation of transparent support (cellulose acetate film T6)>
The dope I was mainstream, the dope J with matting agent was the lowermost layer and the uppermost layer, and was cast using a band stretching machine. After the film surface temperature on the band reaches 40 ° C., the film is dried with warm air of 70 ° C. for 1 minute, the film is peeled off from the band and dried with 140 ° C. drying air for 10 minutes, and the residual solvent amount is 0.3 mass. % Cellulose acetate film T6 was produced. The flow rate was adjusted so that the lowermost layer and the uppermost layer containing the matting agent each had a thickness of 3 μm, and the main flow had a thickness of 34 μm.

  The obtained long cellulose acetate film T6 had a width of 2300 mm and a thickness of 40 μm. The in-plane retardation (Re) at a wavelength of 550 nm was 3 nm, and the retardation in the thickness direction (Rth) was 20 nm. The transmittance at 380 nm was 90%, and the average transmittance at 450 to 650 nm was 92%.

<Preparation of transparent support (cellulose acetate film T7)>
(Preparation of cellulose acetate solution K)
The following composition was put into a mixing tank and stirred to dissolve each component to prepare a cellulose acetate solution K.
[Composition of cellulose acetate solution K]
Cellulose acetate with an acetyl substitution degree of 2.94 100 parts by weight Methylene chloride (first solvent) 402 parts by weight Methanol (second solvent) 60 parts by weight

(Preparation of matting agent solution)
20 parts by mass of silica particles having an average particle diameter of 16 nm (AEROSIL R972, manufactured by Nippon Aerosil Co., Ltd.) and 80 parts by mass of methanol were mixed well for 30 minutes to obtain a silica particle dispersion. This dispersion was put into a disperser together with the following composition, and further stirred for 30 minutes or more to dissolve each component to prepare a matting agent solution.
[Matting agent solution composition]
Silica particle dispersion with an average particle size of 16 nm 10.0 parts by weight Methylene chloride (first solvent) 76.3 parts by weight Methanol (second solvent) 3.4 parts by weight Cellulose acetate solution K 10.3 parts by weight

(Preparation of additive solution)
The following composition was put into a mixing tank and stirred while heating to dissolve each component to prepare an additive solution.
[Additive solution composition]
The following optical anisotropy reducing agent 49.3 parts by mass The following wavelength dispersion adjusting agent 4.9 parts by mass Methylene chloride (first solvent) 58.4 parts by mass Methanol (second solvent) 8.7 parts by mass Cellulose acetate Solution K 12.8 parts by mass

(Production of cellulose acetate film)
94.6 parts by mass of the cellulose acetate solution K, 1.3 parts by mass of the matting agent solution, and 4.1 parts by mass of the additive solution were mixed after filtration, and cast using a band casting machine. The mass ratio of the compound for reducing optical anisotropy and the wavelength dispersion adjusting agent to cellulose acetate in the above composition was 12% by mass and 1.2% by mass, respectively. The film was peeled from the band with a residual solvent amount of 30% by mass and dried at 140 ° C. for 40 minutes to produce a long cellulose acetate film T7 having a width of 2300 mm and a thickness of 80 μm. The in-plane retardation (Re) of the obtained film was 1 nm (the slow axis was a direction perpendicular to the longitudinal direction of the film), and the retardation (Rth) in the thickness direction was −1 nm. The transmittance at 380 nm was 90%, and the average transmittance at 450 to 650 nm was 92%.

<Creation of optical substrate F1>
<< Formation of optically anisotropic layer containing liquid crystalline compound >>
(Alkaline saponification treatment)
The cellulose acetate film T1 is passed through a dielectric heating roll having a temperature of 60 ° C., and the film surface temperature is raised to 40 ° C., and then an alkaline solution having the following composition is applied to the band surface of the film using a bar coater The coating was carried out for 10 seconds under a steam far-infrared heater manufactured by Noritake Co., Ltd., which was applied at an amount of 14 ml / m ² and heated to 110 ° C. Subsequently, 3 ml / m ^{2 of} pure water was applied using the same bar coater. Next, washing with a fountain coater and draining with an air knife were repeated three times, and then transported to a drying zone at 70 ° C. for 10 seconds and dried to prepare an alkali saponified cellulose acetate film.

[Alkaline solution composition]
Potassium hydroxide 4.7 parts by weight Water 15.8 parts by weight Isopropanol 63.7 parts by weight Surfactant SF-1: C ₁₄ H ₂₉ O (CH ₂ CH ₂ O) ₂₀ H
1.0 part by mass Propylene glycol 14.8 parts by mass

(Formation of alignment film)
An alignment film coating solution having the following composition was continuously applied to the long cellulose acetate film saponified as described above with a wire bar. Drying was performed with warm air of 60 ° C. for 60 seconds, and further with warm air of 100 ° C. for 120 seconds. The thickness of the alignment film was 0.7 μm.
[Composition of alignment film coating solution]
Modified polyvinyl alcohol 10 parts by weight Water 371 parts by weight Methanol 119 parts by weight Glutaraldehyde 0.5 parts by weight Photopolymerization initiator (Irgacure 2959, manufactured by Ciba Specialty Chemicals Co., Ltd.) 0.3 parts by weight

(Formation of optically anisotropic layer containing discotic liquid crystalline compound)
The alignment film thus prepared was continuously rubbed. At this time, the longitudinal direction of the long film and the conveyance direction were parallel, and the rotation axis of the rubbing roller was set to a direction of 45 ° counterclockwise with respect to the film longitudinal direction.

A coating solution containing a discotic liquid crystalline compound having the following composition was continuously applied to the prepared alignment film with a # 3.6 wire bar. The conveyance speed (V) of the film was 36 m / min. In order to dry the solvent of the coating solution and to mature the alignment of the discotic liquid crystal compound, the coating liquid was heated with warm air at 120 ° C. for 90 seconds. Subsequently, UV irradiation was performed at 80 ° C. to fix the orientation of the liquid crystalline compound and form an optically anisotropic layer having a thickness of 1.6 μm, thereby obtaining an optical substrate F1.
The produced optical substrate F1 had an Re at 550 nm of 125 nm. The slow axis was 45 ° clockwise with respect to the length direction of the support. The average inclination angle of the disc surface of the discotic liquid crystalline molecules with respect to the film surface was 90 °, and it was confirmed that the discotic liquid crystal was aligned perpendicular to the film surface. The arithmetic average roughness Ra (JIS B 0601: 1998) of the optically anisotropic side surface was in the range of 0.01 to 0.04 μm and had high smoothness.

[Composition of optically anisotropic layer coating solution]
91 parts by weight of the following discotic liquid crystalline compound 5 parts by weight of the following acrylate monomer Photopolymerization initiator (Irgacure 907, manufactured by Ciba Specialty Chemicals)
3 parts by mass Sensitizer (Kayacure DETX, manufactured by Nippon Kayaku Co., Ltd.) 1 part by mass The following pyridinium salt 0.5 part by mass The following fluoropolymer (FP1) 0.2 part by mass The following fluoropolymer (FP3) ) 0.1 parts by mass Methyl ethyl ketone 189 parts by mass

Acrylate monomer:
Ethylene oxide modified trimethylolpropane triacrylate (V # 360, manufactured by Osaka Organic Chemical Co., Ltd.)

<Creation of optical base materials F2 to F5>
Optical substrates F2 to F5 were produced in the same manner as the optical substrate F1 except that the cellulose acetate film was changed to T2 to T5 with respect to the optical substrate F1. The optical substrates F2 to F5 thus produced all had a Re at 550 nm of 125 nm. The arithmetic average roughness Ra (JIS B 0601: 1998) of the optically anisotropic side surface was in the range of 0.01 to 0.04 μm and had high smoothness.

<Creation of optical substrate F6>
An optical substrate F6 was produced in the same manner as the optical substrate F1 except that the cellulose acetate film was changed to T6 with respect to the optical substrate F1. The manufactured optical substrate F6 had Re at 550 nm of 125 nm. Arithmetic mean roughness Ra of optically anisotropic surface (JIS)
B 0601: 1998) was in the range of 0.01 to 0.04 μm and had high smoothness.

<Creation of optical substrate F7>
An optical substrate F7 was produced in the same manner as the optical substrate F1 except that the cellulose acetate film was changed to T7 with respect to the optical substrate F1. The produced optical substrate F7 had Re at 550 nm of 125 nm. Arithmetic mean roughness Ra of optically anisotropic surface (JIS)
B 0601: 1998) was in the range of 0.01 to 0.04 μm and had high smoothness.

<Creation of optical base materials F8 to F15>
The optical base materials F8 to F15 are manufactured in the same manner as the manufacturing method of the optical base material F1 except that the thickness of the optical anisotropic layer is changed so that the Re value becomes the value shown in Table 1 with respect to the optical base material F1. Produced. The arithmetic average roughness Ra (JIS B 0601: 1998) on the optically anisotropic side surface was all in the range of 0.01 to 0.04 μm and had high smoothness.

<Creation of optical substrate F16>
The rubbing treatment was continuously performed on the alignment film of the substrate (the one in which the alignment film was formed) before forming the optically anisotropic layer used in the optical substrate F1. At this time, the longitudinal direction of the long film and the conveyance direction were parallel, and the rotation axis of the rubbing roller was set to a direction of 45 ° counterclockwise with respect to the film longitudinal direction.
Using the first optical anisotropy coating liquid (including a rod-like liquid crystalline compound) described in [0117] of JP-A-2004-272202 on the alignment film, the coating amount is adjusted so that Re at 550 nm is 125 nm. After adjusting and ultraviolet curing, an optically anisotropic layer was formed to obtain an optical substrate F16.

  The manufactured optical substrate F16 had Re at 550 nm of 125 nm. The slow axis was 45 ° clockwise relative to the longitudinal direction of the support. The average inclination angle of the rod-like liquid crystalline molecules with respect to the film surface was 0 °, and it was confirmed that the rod-like liquid crystalline compound was aligned horizontally with respect to the film surface. The arithmetic average roughness Ra (JIS B 0601: 1998) of the optically anisotropic side surface was in the range of 0.01 to 0.04 μm and had high smoothness.

<Creation of optical substrate F17>
An optical base material F17 was obtained in the same manner as the manufacturing method of the optical base material F16 except that the cellulose acylate film was changed to T7 with respect to the optical base material F16.
The slow axis was 45 ° clockwise relative to the longitudinal direction of the support. The average inclination angle of the rod-like liquid crystal molecules with respect to the film surface was 0 °, and it was confirmed that the rod-like liquid crystal was aligned horizontally with respect to the film surface. Re at 550 nm was 125 nm. The arithmetic average roughness Ra (JIS B 0601: 1998) of the optically anisotropic side surface was in the range of 0.01 to 0.04 μm and had high smoothness.

<Creation of optical substrate F18>
The optical base material F18 was obtained in the same manner as the manufacturing method of the optical base material F16 except that the rotation axis of the rubbing roller was changed to the 45 ° direction clockwise with respect to the optical base material F16.

  The produced optical substrate F18 had Re at 550 nm of 125 nm. The slow axis was 45 ° counterclockwise with respect to the longitudinal direction of the support. The average inclination angle of the rod-like liquid crystal molecules with respect to the film surface was 0 °, and it was confirmed that the rod-like liquid crystal was aligned horizontally with respect to the film surface. The arithmetic average roughness Ra (JIS B 0601: 1998) of the optically anisotropic side surface was in the range of 0.01 to 0.04 μm and had high smoothness.

[Lamination of hard coat layer]
A coating solution for forming each layer shown below was prepared.
(Preparation of hard coat layer coating solution HC-1)
PET-30 (100%) 53.7g
Biscote 360 (100%) 32.2g
Irgacure 127 (100%) 3.2 g
8 μm crosslinked acrylic particles (30% dispersion) 33.6 g
CAB polymer (20% solution) 7.0 g
SP-13 (5% solution) 2.3 g
MIBK 36.8g
MEK 26.1g

(Preparation of hard coat layer coating solution HC-10)
PET-30 (100%) 60.0g
Viscoat 360 (100%) 36.0 g
Irgacure 127 (100%) 3.2 g
CAB polymer (20% solution) 7.0 g
SP-13 (5% solution) 2.3 g
MIBK 60.0g
MEK 26.0g

  The hard coat layer coating solution was filtered through a polypropylene filter having a pore size of 30 μm to prepare a coating solution. The refractive index of the matrix after curing in the coating solution was 1.525.

The materials used are shown below.
・ 8μm crosslinked acrylic particles Refractive index 1.495 (30% MIBK dispersion)
PET-30: A mixture of pentaerythritol triacrylate and pentaerythritol tetraacrylate [manufactured by Nippon Kayaku Co., Ltd.]
-Biscoat 360: ethylene oxide-modified trimethylolpropane triacrylate [manufactured by Osaka Organic Chemical Co., Ltd.]
CAB polymer: Cellulose acetate butyrate (20% solution) [MIBK solution of 53.1 / 1 manufactured by Eastman Chemical Co., Ltd.]
・ Irgacure 127: Polymerization initiator [Ciba Specialty Chemicals Co., Ltd.]
Leveling agent (SP-13): 5% MEK solution of the following fluoropolymer

(Preparation of coating solution Ln-1 for low refractive index layer)
Each component was mixed as follows and dissolved in a 90/10 mixture (mass ratio) of MEK / MMPG-Ac to prepare a low refractive index layer coating solution having a solid content of 5% by mass.

(Composition of Ln-1)
The following perfluoroolefin copolymer (P-1) 15 parts by mass DPHA 7 parts by mass RMS-033 5 parts by mass The following fluorine-containing monomer (M-1) 20 parts by mass Hollow silica particles (as solid content) 50 parts by mass Irgacure 127 3 parts by mass

  The compounds used are shown below.

DPHA: Mixture of dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate, manufactured by Nippon Kayaku Co., Ltd. RMS-033: Silicone polyfunctional acrylate (manufactured by Gelest, Mwt = 28000)
Irgacure 127: Photopolymerization initiator, manufactured by Ciba Specialty Chemicals Co., Ltd. Hollow silica: Hollow silica particle dispersion (average particle size 45 nm, refractive index 1.25, surface with silane coupling agent having acryloyl group) Surface treatment, MEK dispersion concentration 20%)
MEK: methyl ethyl ketone MMPG-Ac: propylene glycol monomethyl ether acetate

  The coating solution for the low refractive index layer was filtered through a polypropylene filter having a pore size of 1 μm to prepare a coating solution. The refractive index after curing of the low refractive index layer obtained by coating and curing the coating liquid Ln-1 for low refractive index layer was 1.36.

[Preparation of optical film sample]
(Preparation of optical film sample 107)
The hard base layer coating liquid HC-1 is used on the surface of the support on the side where the optical base material F1 produced above is unwound from the roll form and the optically anisotropic layer is not coated. In the die coating method using the slot die described in Example 1 of US Pat. No. 122889, the coating speed was 30 m / min, the coating was dried at 60 ° C. for 150 seconds, and further 160 W with an oxygen concentration of about 0.1% under a nitrogen purge. Using an air-cooled metal halide lamp (manufactured by Eye Graphics Co., Ltd.), the coating layer was cured and wound by irradiating with ultraviolet rays having an illuminance of 400 mW / cm ² and an irradiation amount of 100 mJ / cm ² . The coating amount was adjusted so that the thickness of the hard coat layer was 10 μm.
Further, the hard coat film prepared above was unwound from the roll form and the hard coat layer coating liquid HC-10 was used on the side where the hard coat layer was coated. Example 1 of JP-A-2006-122889 The die-coating method using the slot die described above was applied at a conveyance speed of 30 m / min, dried at 60 ° C. for 150 seconds, and further air-cooled metal halide lamp with an oxygen concentration of about 0.1% and 160 W / cm under a nitrogen purge. (Igraphics Co., Ltd.) was used to irradiate ultraviolet rays with an illuminance of 400 mW / cm ² and an irradiation amount of 100 mJ / cm ² to cure and wind up the coating layer. After adjusting the coating amount so that the thickness of the hard coat layer by the hard coat layer coating solution HC-10 is 4 μm (the total thickness of the hard coat is 14 μm), the low refractive index layer is formed on the hard coat layer. The coating liquid Ln-1 was applied to prepare an optical film sample 107. The low refractive index layer was dried at 60 ° C. for 60 seconds, and the ultraviolet curing condition was 240 W / cm air-cooled metal halide lamp (eye graphics) while purging with nitrogen so that the atmosphere had an oxygen concentration of 0.1% by volume or less. The irradiance was 600 mW / cm ² and the irradiation amount was 300 mJ / cm ² . The low refractive index layer had a refractive index of 1.36 and a film thickness of 95 nm.

(Preparation of optical film samples 101-106, 108-112)
The optical film samples 101 to 106 were the same as the optical film sample 107 except that the amount of particles in the hard coat coating solution was adjusted so that the internal haze was a value shown in Table 2 with respect to the optical film sample 107 produced above. 108-112.
In addition, adjustment of the particle amount in the coating liquid is performed by keeping the solid content concentration of the hard coat coating liquid HC-1 constant, while keeping the addition ratio of PET-30 and biscoat 360 constant, and by adding 8 μm crosslinked acrylic particles (solid It was done by replacing with min).

(Preparation of optical film sample 113)
An optical film sample 113 was produced in the same manner as the optical film sample 107 except that the hard coat layer coating solution HC-1 was changed to the hard coat layer coating solution HC-10 for the optical film sample 107 produced above.

(Preparation of optical film samples 114 to 117)
For the optical film sample 107 produced above, the hard coat layer coating solution HC-1 is changed to the hard coat layer coating solution used in the optical film sample 105, and is formed from the hard coat layer coating solution HC-10. Optical film samples 114 to 117 were prepared in the same manner as the optical film sample 107 except that the surface Hz was adjusted to the value shown in Table 2 by adjusting the film thickness of the hard coat layer.

(Preparation of optical film samples 118-120)
The irradiation amount after applying a coating solution for hard coat layer HC-10 to an optical film sample 102,104,107 prepared above was changed from 100 mJ / cm ² to 300 mJ / cm ^2, laminating a low refractive index layer Optical film samples 118 to 120 were prepared in the same manner as the optical film samples 102, 104, and 107 except that the points were not changed.

(Preparation of optical film sample 121)
An optical film sample 121 was prepared by stacking neither the hard coat layer nor the low refractive index layer on the optical film sample 107 produced above, that is, the optical substrate F1.

(Production of optical film sample 122)
An optical film sample 122 was produced in the same manner as the optical film sample 105 except that the optical substrate F1 was changed to the cellulose acetate film T1 with respect to the optical film sample 105 produced above. In this configuration, the optically anisotropic layer was not laminated.

(Preparation of optical film samples 123-138)
Optical film samples 123 to 138 were prepared in the same manner as the optical film sample 105 except that the optical base material F1 was changed to the optical base materials F2 to F17 with respect to the optical film sample 105 manufactured above.

(Preparation of optical film sample 139)
The optical film sample 138 and the optical film sample 122 produced above were bonded with an adhesive to produce an optical film sample 139. The bonding surface is a surface where the optically anisotropic layer of the optical film sample 138 and the hard coat layer of the optical film sample 122 are not laminated.

Various characteristics of the optical film or the transparent support were measured by the following methods.
(Measurement of characteristics of optical film or transparent support)
(1) Surface shape of optical film Ra (arithmetic mean roughness of roughness curve) of the surface on the hard coat layer side where the optically anisotropic layer of the optical film is not formed is measured according to JIS B 0601: 1998 did.

(2) Haze (Hz)
The total haze (H), internal haze (Hi), and surface haze (Hs) of the obtained optical film were measured by the following measurements.
1. The haze value (H) of the film obtained according to JIS-K7136 is measured. This value is the total haze.
2. Add a few drops of silicone oil to the front and back surfaces of the hard coat layer side of the resulting film, and sandwich it from the front and back using two 1 mm thick glass plates (micro slide glass product number S9111, made by MATSUNAMI). Two glass plates and the obtained film were optically adhered, and the haze was measured with the surface haze removed, and the haze was measured by sandwiching only silicone oil between two separately measured glass plates. The value obtained by subtracting was calculated as the internal haze (Hi) of the film.
3. The value obtained by subtracting the internal haze (Hi) calculated in 2 above from the total haze (H) measured in 1 above was calculated as the surface haze (Hs) of the film.

(3) Average reflectance (integral sphere reflectance)
The back side of the optical film, that is, the surface on which the hard coat layer is not coated, is roughened with sandpaper and then treated with black ink to eliminate the back side reflection, and the front side is then a spectrophotometer (Japan) Spectral reflectance was measured in a wavelength region of 380 to 780 nm using a spectrophotometer. The arithmetic average value of the integrating sphere reflectance of 450 to 650 nm was used for the result.

(4) Pencil hardness Pencil hardness evaluation described in JIS K 5400 was performed as an index of scratch resistance. After conditioning the optical film for 2 hours at a temperature of 25 ° C. and a humidity of 60% RH,
Using a 2H-5H test pencil specified in S6006, the scratch test was repeated five times with a pencil at a load of 4.9 N, and left for 24 hours at a temperature of 25 ° C. and a humidity of 60% RH. Evaluation was made according to the following criteria, and the highest hardness that gave OK was taken as the evaluation value.
If the pencil hardness is less than 2H, there is a problem level.
OK: 2 or less scratches in 5 evaluations NG: 3 or more scratches in 5 evaluations

(5) Transmittance at 380 nm After leaving the transparent support at 25 ° C. and 60% RH for 2 hours or more, the transmittance was measured at a transmittance of 380 nm using a spectrophotometer “U-3210” {Hitachi, Ltd.). It was measured.

[Production of Polarizing Plate and Image Display Device]
In order to evaluate the produced optical film with an image display device, the following polarizing plate processing was performed and the evaluation with an image display device was performed.
The surface of the optically anisotropic layer of the optical film produced above was washed with MEK. The film surface after washing was subjected to alkali saponification treatment. It was immersed in a 1.5 N aqueous sodium hydroxide solution at 55 ° C. for 2 minutes, washed in a water bath at room temperature, and neutralized with 0.1 N sulfuric acid at 30 ° C. Again, it was washed in a water bath at room temperature and further dried with hot air at 100 ° C.
Subsequently, a roll-shaped polyvinyl alcohol film having a thickness of 80 μm was continuously stretched 5 times in an iodine aqueous solution and dried to obtain a polarizing film having a thickness of 20 μm. Each film subjected to the alkali saponification treatment using a 3% aqueous solution of polyvinyl alcohol (Kuraray PVA-117H) as an adhesive, and the same alkali saponification-treated retardation film for VA (Re / Rth = 550 nm at 550 nm, manufactured by Fuji Film Co., Ltd.) / 125) is prepared, and the saponified surface is bonded to the polarizing film side so that the polarizing film is sandwiched therebetween, and the optical film and the retardation film for VA serve as a polarizing film protective film. Plates 101-139 were prepared. At this time, the angle formed by the slow axis of the optical film and the absorption axis of the polarizer was set to 45 degrees.

(Implementation)
TV: The polarizing plate on the viewing side of UN46C7000 (3D-TV) manufactured by SAMSUNG was peeled off, and the VA retardation film of the prepared polarizing plate and the LC cell were bonded via an adhesive to produce a stereoscopic display device. . In all display devices including the display device to which the polarizing plate 139 was bonded, the direction of the slow axis of the optically anisotropic layer of the optical film was the same.
LC shutter glasses: The polarizing plate on the side opposite to the eyes (panel side) of SSG-2100AB (LC shutter glasses) manufactured by SAMSUNG is peeled off, and the optical anisotropic layer side of the optical film sample 113 prepared above is removed with an adhesive. LC shutter glasses were produced. Here, the slow axis of the optical film bonded to the glasses was set to be orthogonal to the slow axis of the optical film included in the polarizing plate bonded to the TV.

(Evaluation of display device)
In a room with a fluorescent lamp, under the environment where the illuminance on the panel surface was about 200 lux, the above-prepared LC shutter glasses were put on and a 3D image was viewed.
The evaluation of the image was carried out by sensory evaluation of the three-dimensional effect when viewed from the front of the 3D image and the crosstalk when viewed from the front and diagonally according to the following criteria.

[Three-dimensional effect]
Observed from the front, ◯ indicates that the stereoscopic effect is seen, and x indicates that the stereoscopic effect is not observed.
[Crosstalk]
The crosstalk (double image) when viewed from the front and an oblique 45 ° direction was observed, and the following four-level evaluation was performed.
◎: Crosstalk is not visible at all ○: If you look closely, there is crosstalk, but I do not care.
Δ: Crosstalk is slightly visible. (This is the acceptable level.)
X: Crosstalk is clearly visible. (Problem level)

  Tables 1 and 2 show the evaluation results for the above items.

<Light resistance evaluation>
After irradiating light for 100 hours under the condition of 300-400 nm UV intensity of 150 W / m ² in a black panel temperature of 60 ° C. and a relative humidity of 50% with Super Xenon Weather Meter SX75 manufactured by Suga Test Instruments Co., Ltd. The film coloration and front retardation (Re) were measured. Irradiation light contained ultraviolet light and visible light of 300 nm or more.

(3) Blackening feeling A sensory evaluation was performed on the feeling of blackening on a liquid crystal display device in which a polarizing plate having a film attached to the surface on the viewing side was disposed.
The display devices created above were arranged in parallel and compared at the same time, and the blackness when the power was turned off from the front in the bright room was compared for each film and evaluated according to the following criteria. It was expressed by the standard that the stronger the blackness, the stronger the tightness of the screen.

A: Strong blackness and the screen looks very strong.
○: Black color is strong and the screen appears to be strong.
Δ: Black but gray, and the screen is not tight. (This is the acceptable level.)
X: Strong gray color, tightness on screen (problem level)

(Evaluation of interference spots)
Interference spots were evaluated in four stages by the following method.
Evaluation of interference spots: A sample was illuminated with a three-wavelength fluorescent lamp (National Paroch fluorescent lamp FL20SS · EX-D / 18) from 50 cm before the display device, and the interference spots were observed and evaluated according to the following criteria.
◎: Interference unevenness is not visible at all ○: Interference unevenness is hardly visible ○ △: Interference unevenness appears to be weak.
Δ: Interference unevenness appears to be weak overall (tolerable level so far)
X: Interference unevenness appears strong overall (problem level)

From the results shown in Tables 1 and 2, the following is clear.
1. It has an optically anisotropic layer on one surface of the support, a hard coat layer on the other surface, an in-plane retardation of the optical film at 550 nm of 80 to 200 nm, and a thickness at a wavelength of 550 nm. Those having a directional retardation of -70 to 70 nm are suitable for a three-dimensional display device, have a high surface hardness, good blackening under a bright room, and no interference unevenness.
2. What stuck the hard coat film with the adhesive on the optical film which has an optically anisotropic layer is thick, and interference nonuniformity is very conspicuous. (For sample No. 139, sample No. 138, etc.)
3. The optically anisotropic layer of the present invention can be formed from a discotic liquid crystalline compound or a rod-shaped liquid crystalline compound.
4). The disc-shaped liquid crystal compound in which the optically anisotropic layer was formed had excellent visibility because no crosstalk was observed in the oblique direction compared to the rod-shaped liquid crystal compound in which the optically anisotropic layer was formed. (For sample Nos. 137 and 138, sample No. 105, etc.)
5. When Ra of the hard coat layer is 0 to 0.08 μm and 1 to 20% of internal haze is introduced, interference unevenness is less noticeable and blackening can be maintained well.
6). When a low refractive index layer is laminated on the hard coat layer, the reflectance can be reduced, interference unevenness is not noticeable, and blackening can be further improved. (107 etc. for sample No. 120)
7). By using an ultraviolet-absorbing transparent support having a transmittance of 380 nm or less at a wavelength of 380 nm, the change in front retardation after the light resistance test can be significantly suppressed. (Comparison between sample No. 105 and 123-126)

Claims (10)

From the viewing side, a stereoscopic image display device having an optical film, a polarizing film, and a liquid crystal cell in this order,
The optical film is
An optical film having an optically anisotropic layer on one surface of a transparent support and a hard coat layer on the other surface,
The optical film has an alignment film between the transparent support and the optically anisotropic layer,
In-plane retardation at 550 nm of the optical film is 80 to 200 nm, retardation in the thickness direction at a wavelength of 550 nm is −70 to 70 nm,
Nz (= Rth (550) / Re (550) +0.5) calculated from the in-plane retardation Re (550) at a wavelength of 550 nm of the optical film and the retardation Rth (550) in the thickness direction is −0. 50 to 1.50,
A liquid crystal display device in which the optical film is disposed such that the hard coat layer is on the viewing side and the optical anisotropic layer is on the polarizing film side.   2. The liquid crystal display device according to claim 1, wherein Nz (= Rth (550) / Re (550) +0.5) of the optical film is −0.10 to 1.10. The liquid crystal display device according to claim 1 or 2 optically anisotropic layer and is formed from a composition containing a liquid crystalline compound of the optical film. The liquid crystal display device according to claim 3 , wherein the liquid crystal compound is a discotic liquid crystal compound. The surface unevenness shape of the surface of the optical film on which the hard coat layer is laminated has an arithmetic average roughness Ra based on JIS B0601 of 0 to 0.08 μm, according to any one of claims 1 to 4 . Liquid crystal display device. The surface haze of the optical film is less than 1.0%, the liquid crystal display device according to any one of claims 1-5. The internal haze of the optical film is 1-10%, the liquid crystal display device according to any one of claims 1-6. The 380nm of transmittance of the transparent support of the optical film is 10% or less, the liquid crystal display device according to any one of claims 1-7. The hard coat layer of the optical film contains a binder and translucent particles, the average particle diameter of the translucent particles is 1 to 12 μm, and the absolute value of the refractive index difference between the binder and the translucent particles is 0. .01 or less than 0.05, the liquid crystal display device according to any one of claims 1-8. The opposite side to the transparent support of the hard coat layer of the optical film, a liquid crystal display device according to any one of claims 1 to 9, having a transparent support lower low refractive index layer having a refractive index than body.