JP5766471B2 - Radioactive waste decontamination method - Google Patents

Description

  The present invention relates to a method for decontaminating radioactive materials such as piping, equipment, and structural members installed in a radiation handling facility such as a nuclear power plant, and removing an oxide film formed on the inner surface of a reactor primary system piping or equipment. It is about the method.

  In a radiation handling facility such as a nuclear power plant, an oxide film containing a radioactive substance is attached to or generated on the inner surface of a structural part such as a pipe that comes into contact with a fluid containing a radioactive substance in accordance with the operation of the facility. If the operation period of the facility becomes longer, the radiation dose around pipes and equipment increases, and there is a risk that the dose of workers will be increased during periodic inspections, maintenance work, or waste demolition work. In order to reduce the exposure of workers, radioactive materials adhering to pipes and equipment must be removed (hereinafter referred to as decontamination).

  A typical reactor to be decontaminated is a reactor primary cooling system (hereinafter also referred to as a primary system). A scale called a clad containing a radioactive substance is attached to the primary cooling system. This cladding serves as a radiation source for workers to receive radiation exposure around the reactor primary cooling system piping and equipment. It is necessary to remove the cladding in order to reduce the radiation exposure and improve the working environment. This removal of the cladding is mainly performed by a chemical decontamination method.

  Patent Document 1 proposes a chemical cleaning agent having a high detergency, capable of decontaminating a radioactive cladding, and having a low corrosiveness to a metal material. This is a chemical detergent comprising a composition containing malonic acid and hydrazine as active ingredients.

Japanese Patent Laid-Open No. Sho 62-127483

  The chemical cleaning agent described in Patent Document 1 has a problem that new equipment and equipment are required because it is necessary to immerse the object to be decontaminated in the chemical solution. In addition, since the object to be decontaminated has to be immersed in a solution at 80 ° C. to 100 ° C., there is a problem that it takes time to manage the chemical solution during work, and it becomes a long continuous work and increases human burden. It was.

  In addition, conventional chemical decontamination methods have problems in that if the object to be decontaminated is large, a new decontamination treatment facility is installed, the size is increased, a large amount of chemical solution is required, and the cost of waste liquid treatment after work increases. It was.

  In addition, pipes and equipment after decontamination are put in drums and discarded, but the amount of radiation per drum can is fixed. If the decontamination rate is low, the amount of radiation is high, so the number of drums to be discarded There was a problem that would increase.

  The present invention has been made in view of the above, and the amount of chemical solution used is small, the processing temperature is low, and the radioactivity capable of improving the decontamination rate of an oxide film containing a radioactive substance even in a short time. The purpose is to provide a waste decontamination method.

In order to solve the above-described problems and achieve the object, the radioactive waste decontamination method of the present invention is formed on the inner surface of the decontamination target to be discarded after replacing the members constituting the primary system of the nuclear power plant. a radioactive waste decontamination method for removing an oxide film that is, a first measurement step of measuring the radiation dose of the decontamination object, said decontaminated by dissolving the oxide film on the decontamination object a drug solution holding step of holding to remain a predetermined time on the inner surface of the chemical solution to the decontamination object for the chemical removal step of removing a chemical solution wherein is held after a lapse of the predetermined time, the decontamination after decontamination possess a second measurement step of measuring the radiation dose of the object, wherein the chemical solution, features and nitric hydrofluoric acid, and at least one of oxalic acid and citric acid, a gelling agent, to include a solvent And
Further, the radioactive waste decontamination method of the present invention is a radioactive waste decontamination method for removing an oxide film formed on the inner surface of an object to be decontaminated after replacing a member constituting a primary system of a nuclear power plant. A first measurement step of measuring a radiation dose of the decontamination target, and a chemical solution for decontamination by dissolving the oxide film of the decontamination target on the inner surface of the decontamination target A chemical solution holding step for holding the liquid so as to stay for a predetermined time, a chemical solution removing step for removing the held chemical solution after the lapse of the predetermined time, and a second measurement step for measuring a radiation dose of the decontamination target after decontamination. And the chemical solution contains nitric hydrofluoric acid, at least one of permanganic acid and potassium permanganate, a gelling agent, and a solvent.

  According to this configuration, since the chemical solution is gelled to form a gel, it is possible to apply the chemical solution to the surface of the oxide film to be decontaminated and keep the chemical solution on the oxide film surface for a long time. By holding the chemical solution on the surface of the oxide film for a long time, it is possible to secure a sufficient time for the chemical solution to dissolve the surface of the oxide film and subsequently to infiltrate the chemical solution into the base metal. Thereby, the decontamination rate of a radioactive substance can be improved. Further, since the chemical solution can be sufficiently kept in contact with the surface of the oxide film, the decontamination treatment can be performed in a shorter time than conventional.

  In the radioactive waste decontamination method of the present invention, the radiation dose is reduced to ½ or less by comparing the radiation dose obtained in the chemical solution preparation step for preparing the chemical solution and the first measurement step and the second measurement step. It is preferable to have a determination step for determining whether or not a decontamination target from which the chemical solution has been removed, and a waste liquid treatment step for treating the chemical solution removed in the chemical removal step.

  According to this configuration, since the chemical solution is gelled to form a gel, it is possible to apply the chemical solution to the surface of the oxide film to be decontaminated and keep the chemical solution on the oxide film surface for a long time. As a result, by holding the chemical solution on the surface of the oxide film for a long time, it is possible to secure sufficient time for the chemical solution to dissolve the surface of the oxide film, and then to penetrate the chemical solution into the base metal. The decontamination rate can be improved. In addition, the amount of waste liquid treated and the amount of waste can be greatly reduced.

In the radioactive waste decontamination method of the present invention, the gelling agent contains at least one of phosphoric acid crosslinked starch and a cellulose derivative, and the solvent contains at least one of pure water and pure water containing micro-nano bubbles. but good Masui.

  According to this configuration, since the chemical solution is gelled to form a gel, it is possible to apply the chemical solution to the surface of the oxide film to be decontaminated and keep the chemical solution on the oxide film surface for a long time. Thereby, the decontamination rate of a radioactive substance can be improved.

  The chemicals for the radioactive waste decontamination method according to the present invention include nitric hydrofluoric acid, nitric hydrofluoric acid and oxalic acid, nitric hydrofluoric acid and permanganic acid, nitric hydrofluoric acid and potassium permanganate, nitric acid. Including one or more of hydrofluoric acid and citric acid, the gelling agent includes one or more of phosphoric acid crosslinked starch and cellulose derivative, depending on the type of chemical and the type of decontamination target, It is preferable that the solvent contains one or both of pure water and pure water containing micro-nano bubbles.

  According to this configuration, by holding the chemical solution on the oxide film surface for a long time, the chemical solution dissolves the oxide film surface, and then it is possible to ensure sufficient time for the chemical solution to penetrate the base metal, The decontamination rate of radioactive substances can be improved.

Wastewater treatment of the waste liquid treatment process radioactive waste decontamination method of the present invention uses a medicament containing at least neutralizing agent, neutralizing agent, it is better good comprising at least hand of calcium hydroxide and calcium carbonate Yes.

  According to this configuration, the amount of waste liquid treated and the amount of waste can be greatly reduced.

  The chemical solution holding step of the radioactive waste decontamination method of the present invention has an application step of applying the chemical solution to the inner surface of the object to be decontaminated, and the application step is preferably performed by a remotely operable coating apparatus.

  According to this structure, since a chemical | medical solution is a gel form, it can apply | coat to the inner surface of a decontamination target object using a brush, a spatula, etc. as a simple method. Thereby, since chemical | medical solution can be apply | coated using a brush, a spatula, etc. by remote operation, such as a robot hand, even if the radiation dose is high, decontamination work can be performed, preventing exposure.

  The predetermined time of the radioactive waste decontamination method of the present invention is preferably 16 hours or less.

  According to this configuration, the chemical solution can be sufficiently kept in contact with the surface of the oxide film, so that the decontamination process can be performed in a shorter time than before.

  According to the radioactive waste decontamination method of the present invention, it is possible to improve the decontamination rate of an oxide film containing a radioactive substance even when the amount of chemical solution used is small, the processing temperature is low, and the time is short.

FIG. 1 is a schematic configuration diagram schematically showing a nuclear power plant to which a radioactive waste decontamination method according to an embodiment of the present invention is applied. FIG. 2 is a flowchart showing the procedure of the radioactive waste decontamination method according to the present embodiment. FIG. 3 is a view showing a state in which the gelled chemical solution of this example is applied to the inner surface of the pipe. FIG. 4 is a view of the pipe to which the chemical solution of this embodiment is applied as seen from the direction of the arrow X in FIG. FIG. 5 is a view showing a patch in which a chemical solution is held on the base material of this example. FIG. 6 is a diagram illustrating a state in which a sticking agent is pasted on the pipe inner surface of the decontamination target of this example. FIG. 7 is a diagram for explaining a conventional decontamination method.

  Below, the Example of the radioactive waste decontamination method which concerns on this invention is described in detail based on drawing. In addition, this invention is not limited by this Example. In addition, constituent elements in the following embodiments include those that can be easily replaced by those skilled in the art or those that are substantially the same.

  In the following embodiments, a method for decontaminating primary waste pipes and equipment installed in a nuclear power plant will be described as an example, but the present invention is not limited to this.

  FIG. 1 is a schematic configuration diagram schematically showing a nuclear power plant to which a radioactive waste decontamination method according to an embodiment of the present invention is applied.

  The nuclear power plant nuclear reactor to which the present embodiment is applied uses light water as a reactor coolant and a neutron moderator, and produces high-temperature and high-pressure water that does not boil over the entire primary system 3, and this high-temperature and high-pressure water is used as a steam generator. This is a pressurized water reactor (PWR) that generates steam by sending and exchanging heat with a secondary coolant, and sends the steam to a turbine generator to generate electricity. The present embodiment is not limited to this PWR, and can be applied to an improved pressurized water reactor (APWR) or a boiling water reactor (BWR) which is an improvement of the PWR. . It can also be applied to radiation handling facilities.

  A nuclear power plant using the nuclear reactor 2 includes a nuclear reactor cooling system 3 including the nuclear reactor 2 (hereinafter also referred to as a primary system) and a turbine system 4 (hereinafter referred to as a secondary system) that exchanges heat with the nuclear reactor cooling system 3. The reactor cooling system 3 is circulated through the reactor coolant (primary cooling water), and the turbine system 4 is circulated through the secondary coolant (secondary cooling water). Yes.

  The nuclear reactor cooling system (primary system) 3 includes a nuclear reactor 2 and a steam generator 6 connected to the nuclear reactor 2 via a cold leg 5a and a hot leg 5b. In addition, a pressurizer 7 is interposed in the hot leg 5b, and a reactor coolant pump 8 is interposed in the cold leg 5a. The reactor 2, the cold leg 5 a, the hot leg 5 b, the steam generator 6, the pressurizer 7, and the reactor coolant pump 8 are accommodated in the reactor containment vessel 1.

  As described above, the nuclear reactor 2 is a pressurized water nuclear reactor, and the inside thereof is filled with a nuclear reactor coolant (primary cooling water). In the nuclear reactor 2, a large number of fuel assemblies 15 are accommodated, and a large number of control rods 16 for controlling nuclear fuel fission in the fuel rods of the fuel assemblies 15 can be inserted into the fuel assemblies 15. Is provided.

  When the nuclear fuel in the fuel rod of the fuel assembly 15 is fissioned while controlling the fission reaction by the control rod 16, thermal energy is generated by this fission. The generated thermal energy heats the reactor coolant, and the heated reactor coolant is sent to the steam generator 6 via the hot leg 5b. On the other hand, the reactor coolant sent from each steam generator 6 through the cold leg 5 a flows into the reactor 2 and cools the inside of the reactor 2.

  The pressurizer 7 interposed in the hot leg 5b suppresses boiling of the reactor coolant by pressurizing the reactor coolant that has become high temperature. In addition, the steam generator 6 evaporates the secondary coolant by causing the reactor coolant (primary coolant), which has become high temperature and pressure, to exchange heat with the secondary coolant (secondary coolant), thereby generating steam. The reactor coolant generated and cooled to high temperature and pressure is cooled. The reactor coolant pump 8 circulates the reactor coolant in the reactor cooling system 3, and sends the reactor coolant from the steam generator 6 to the reactor 2 via the cold leg 5 a, and also the reactor coolant. From the nuclear reactor 2 to the steam generator 6 through the hot leg 5b.

  The reactor coolant circulates between the reactor 2 and the steam generator 6. The reactor coolant is light water used as a coolant and a neutron moderator.

  The turbine system (secondary system) 4 includes a turbine 22 connected to each steam generator 6 via a steam pipe 21, a condenser 23 connected to the turbine 22, a condenser 23, and each steam generator. And a water supply pump 24 interposed in a water supply pipe 26 that connects to the water supply pipe 26. A generator 25 is connected to the turbine 22.

  Here, a series of operations in the turbine system 4 of the nuclear power plant will be described. When steam flows from the steam generator 6 into the turbine 22 via the steam pipe 21, the turbine 22 rotates. When the turbine 22 rotates, the generator 25 connected to the turbine 22 generates power. Thereafter, the steam discharged from the turbine 22 flows into the condenser 23. The condenser 23 has a cooling pipe 27 disposed therein, and one of the cooling pipes 27 is connected to a water intake pipe 28 for supplying cooling water (for example, seawater). A drain pipe 29 for draining the cooling water is connected to. The condenser 23 cools the steam flowing in from the turbine 22 by the cooling pipe 27, thereby returning the steam to a liquid. The secondary coolant that has become liquid is sent to the steam generator 6 through the water supply pipe 26 by the water supply pump 24. The secondary coolant sent to the steam generator 6 becomes steam again by exchanging heat with the reactor coolant in the steam generator 6.

  In the nuclear power plant as described above, nuclear reactor equipment and various pipes are made of steel materials such as stainless steel and carbon steel. The reactor equipment and the inner surface of the pipe are corroded by contact with high temperature water (primary cooling water), and an oxide film is formed. Radioactivity in the reactor water is taken into the reactor equipment exposed to high-temperature water (primary cooling water) and the oxide film formed on the wetted part of the inner surface of the pipe, which is the source of radiation. When such reactor equipment and piping are replaced by maintenance work or the like, they are discarded as waste equipment or waste piping in drums. By applying the radioactive waste decontamination method of this embodiment to the decontamination before discarding the above-mentioned disposal equipment and disposal pipes, decontamination can be done in a short time and the amount of waste liquid is small, so the waste liquid processing cost is reduced. It becomes possible.

  Next, the radioactive waste decontamination method according to the present embodiment will be described with reference to FIG. FIG. 2 is a flowchart showing the procedure of the radioactive waste decontamination method according to the present embodiment. Hereinafter, a series of procedures of the radioactive waste decontamination method of the present embodiment will be schematically described, and then a detailed description of each step will be described later.

  As shown in FIG. 2, the radioactive waste decontamination method of the present embodiment uses a chemical solution 43 for decontamination by dissolving the oxide film formed on the inner surface 42 of the decontamination target 41 such as piping or equipment. The chemical solution preparation step (step S1) to be prepared, the first measurement step (step S2) for measuring the radiation dose of the decontamination target 41 before decontamination, and the oxide film of the decontamination target 41 are dissolved. In order to perform decontamination, the chemical liquid 43 prepared in the chemical liquid preparation process is applied to the inner surface 42 of the decontamination object 41, and the chemical liquid 43 applied in the application process is included in the decontamination object 41. A chemical solution holding step (step S4) for holding the surface 42 so as to stay for a predetermined time, and holding after a predetermined time has passed in order to obtain the effect of the chemical solution 43 applied to the inner surface 42 of the decontamination target 41 for decontamination. Chemical removal to remove the chemical 43 In step (S5), a second measurement step (step S6) for measuring the radiation dose to examine how much the radiation dose of the decontamination target 41 after decontamination has been reduced, and radiation in the second measurement step As a result of measuring the amount, a determination step (step S7) for determining whether the radiation dose is reduced to ½ or less compared to the radiation dose before decontamination, and the radiation dose to ½ or less in the determination step When it has been reduced (step S7, YES), the cleaning process (step S8) for cleaning the decontamination target 41 after the chemical liquid 43 is removed in the chemical liquid removal process, and the chemical liquid 43 removed in the chemical liquid removal process as waste liquid treatment And a waste liquid treatment process (step S9). If the radiation dose is not reduced to ½ or less in the determination process (step S7, NO), the process returns to step S3, and again from the application process of applying the chemical solution 43 to the inner surface 42 of the decontamination target 41. repeat. In order to obtain a high decontamination rate from the beginning, steps S3 to S5 may be repeated a plurality of times. The process surrounded by the broken line indicated by reference numeral 30 is an operation in the field room, but the other processes of step S1 and step S9 do not need to be performed in the field room. And so on. Detailed description of each of the above steps will be described later.

  Here, a conventional decontamination method will be described with reference to FIG. Conventionally, the decontamination object 58 is completely immersed in the decontamination tank 50 filled with the chemical solution 43, and the chemical solution 43 is heated to about 80 ° C. to 100 ° C. by the heater 57 to perform decontamination while maintaining the temperature. . The decontamination rate in the conventional decontamination method using such an apparatus was about 1%. Further, when the chemical solution 43 in the decontamination tank 50 is reduced, it is supplied from the chemical supply tanks 55 and 56. Therefore, a lot of chemicals 43 exceeding the volume of the decontamination tank 50 are required. When processing the chemical solution 43 in the decontamination tank 50, the chemical solution 43 is sent to the UV tower 51, and UV irradiation 52 is performed to reduce and decompose the components of the chemical solution 43. The chemical solution 43 component that could not be decomposed by the UV tower 51 was processed by sending the chemical solution 43 to the ion exchange resin tower 53 and adsorbing it to the ion exchange resin 54. When the decontamination object 58 is large, the decontamination tank 50 must be enlarged. In addition, a large amount of the chemical solution 43 is required, and the cost of waste liquid treatment increases. Conventionally, the series of decontamination processes described above have been performed continuously for several days, which takes time and increases the burden on workers.

  Compared with such a conventional decontamination method, the radioactive waste decontamination method of this embodiment does not require the decontamination tank 50 for immersing the decontamination object 41 in the chemical solution 43, and therefore uses a large amount of the chemical solution 43. There is nothing. Since the amount of the chemical solution 43 to be used is small, the amount of waste liquid after decontamination is small and the waste liquid treatment does not take time and money. In the present embodiment, the chemical solution 43 is gelled and formed into a gel, so that the chemical solution 43 can be kept on the oxide film surface for a long time by applying the chemical solution 43 to the surface of the oxide film to be decontaminated. is there. By holding the chemical solution 43 on the surface of the oxide film, it is possible to ensure sufficient time for the chemical solution 43 to dissolve the surface of the oxide film and subsequently to penetrate the chemical solution 43 into the base metal. Thereby, the decontamination rate of a radioactive substance can be improved to 50% or more. Further, since the decontamination work can be performed indoors, it can be performed at room temperature (room temperature).

  Next, each step of the radioactive waste decontamination method according to the present embodiment will be described in detail.

  The chemical solution preparation step (step S1) is a step of preparing a chemical solution 43 for decontamination by dissolving the oxide film formed on the inner surface 42 of the decontamination target 41. The chemical solution 43 prepared in the present embodiment can be obtained by mixing a chemical, a solvent for dissolving the chemical, and a gelling agent for gelling the chemical solution 43. The mixing ratio of the solvent and the gelling agent is preferably, for example, about solvent: gelling agent = 10: 1 (mass ratio). The gelling agent includes at least one of phosphoric acid crosslinked starch and cellulose derivative depending on the type of chemical and the type of decontamination object, and the solvent is pure water or pure water containing micro-nano bubbles. Including one or both. For example, when the acidity of the chemical is strong, the gelling agent is more preferably Rasnonwell (trade name: Cellulose derivative, manufactured by Keisho Co., Ltd.) rather than phosphoric acid crosslinked starch. For example, when the surface shape of the chemical solution 43 applied to the decontamination object is simple, the amount of the solvent to be mixed may be reduced to form a slightly hard gel, but the surface shape of the chemical solution 43 application surface of the decontamination object is complicated or small When there is, it is preferable that the amount of the solvent to be mixed is increased to form a slightly soft gel. Thus, according to the kind of chemical | medical agent used or the kind of decontamination object, the kind of gelling agent, the mixing ratio with a solvent, etc. can be selected suitably. In this embodiment, the chemical solution 43 is gelled and then applied to the surface of the oxide film to be decontaminated, so that the chemical solution 43 can remain on the oxide film surface for a long time. In this embodiment, the gel state means that when the chemical solution 43 is applied to the inner surface 42 such as a pipe, the state where it does not flow while being attached to the applied portion can be maintained. Specifically, the viscosity and fluidity of the chemical solution 43 can be applied to the object to be decontaminated with a brush or the like, and it does not hang down even if it is applied to the lateral surface or ceiling surface of the object to be decontaminated. Means. In the present embodiment, for example, it is assumed that the state in which the chemical solution 43 is held at the applied site can be maintained for at least 72 hours, preferably 24 hours, and more preferably 16 hours. In this sense, in this embodiment, a cream or a highly viscous liquid is included in the gel.

  In the chemical solution preparation step (step S1), the chemical is a chemical for dissolving an oxide film containing a radioactive substance formed on the piping constituting the primary system 3 of the nuclear power plant and the inner surface 42 of the equipment. As the chemical, one or more of nitric acid, sulfuric acid, and hydrofluoric acid may be used. Any one of nitric hydrofluoric acid, nitric hydrofluoric acid and oxalic acid, nitric hydrofluoric acid and permanganic acid, nitric hydrofluoric acid and potassium permanganate, nitric hydrofluoric acid and citric acid, depending on the type of oxide film to be removed It is preferable to include two or more. For example, when the main component in the oxide film is an iron-based oxide or nickel-based oxide, it contains one or more of nitric hydrofluoric acid, nitric hydrofluoric acid and oxalic acid, nitric hydrofluoric acid and citric acid. Can be mentioned. Moreover, when the main component in an oxide film is a chromium type oxide, what contains any one or more of nitric hydrofluoric acid and permanganic acid, nitric hydrofluoric acid, and potassium permanganate is mentioned. In addition, said permanganic acid and potassium permanganate are shown as an example of an oxidizing agent, and if it is a chemical | medical agent (oxidizing agent) which has equivalent oxidizing power, it can use it conveniently. Further, the above oxalic acid and citric acid are shown as examples of the reducing agent, and any chemical (reducing agent) having an equivalent reducing power can be suitably used. Depending on the type of oxide film, it is preferable to use a combination of a chemical that dissolves the surface oxide and a chemical that dissolves the metal material itself as the base material. Concentrations of chemicals used in this example include nitric acid and hydrofluoric acid in the range of 0.5% by mass to 20% by mass, preferably 1% by mass to 15% by mass, and more preferably 1% by mass to 10% by mass. It is. Further, oxalic acid, citric acid, permanganic acid, and potassium permanganate are 0.005% by mass to 0.5% by mass, preferably 0.01% by mass to 0.3% by mass, and more preferably 0.01%. The mass is 0.1% by mass or more.

  As a density | concentration of the nitric-hydrofluoric acid used by a present Example, 1 mass% or more and 10 mass% or less, Preferably they are 3 mass% or more and 7 mass% or less, More preferably, 5 mass% is preferable. Examples of the gelling agent include phosphoric acid crosslinked starch and cellulose derivatives. Moreover, Rasnonwell (trade name: manufactured by Keisho Co., Ltd.) and the like can be given as examples containing an acid and a gelling agent. A known gelling agent can be appropriately selected as long as it retains the gel state for 72 hours, preferably 24 hours, more preferably about 16 hours with respect to the above-mentioned acid chemicals. Examples of the solvent include pure water and pure water containing micro / nano bubbles. In particular, when the oxidizing power is required to dissolve the film according to the type of the oxide film, pure water containing micro-nano bubbles is preferably used.

  Since the method of measuring the radiation dose in the first measurement step (step S2) and the second measurement step (step S6) can be performed by, for example, a GM tube survey meter, detailed description thereof is omitted. The decontamination rate determined in the determination step (step S7) is the radiation amount of the decontamination target 41 before the decontamination measured in the first measurement step (step S2) and the second measurement step (step S6). ) And the radiation dose of the decontamination target 41 after decontamination measured in (1). The decontamination rate by the radioactive waste decontamination method of this example is 30% or more, preferably 50% or more, more preferably 90% or more.

  FIG. 3 is a view showing a state in which the gelled chemical solution of this example is applied to the inner surface of the pipe. FIG. 4 is a view of the pipe to which the chemical solution is applied as seen from the direction of the arrow X in FIG. In the coating process (step S3) and the chemical solution holding process (step S4), the oxide film is applied for a predetermined time to allow the chemical solution 43 to permeate into the decontamination target, for example, the oxide film formed on the inner surface 42 of the primary system 3 pipe. It is necessary to keep the chemical solution 43 on the surface. In this example, in order to keep the chemical solution 43 on the surface of the oxide film in the chemical solution holding step (step S4), the chemical solution 43 was gelled using a gelling agent to form a gel. As shown in FIGS. 3 and 4, in the chemical solution holding step (step S4), the chemical solution 43 can be kept on the surface of the oxide film for a long time only by applying the gelled chemical solution 43 to the surface of the oxide film to be decontaminated. it can. The coating amount of the chemical solution 43 is preferably 0.5 mm to 5 mm, more preferably 1 mm to 3 mm, and still more preferably 1 mm. A sufficient decontamination effect can be obtained by maintaining the chemical solution 43 on the surface of the oxide film for 72 hours, preferably 24 hours, more preferably 16 hours at the above coating thickness.

  In the application step (step S3), as a method for applying the chemical solution 43 for holding the chemical solution 43, for example, a simple method may be applied to the inner surface 42 of the pipe to be decontaminated using a brush or a spatula. Can be mentioned. In addition, if the radiation dose is high, there is a risk of exposure during work. For example, by using a brush or spatula by remote control with a robot hand or the like, it is applied to the inner surface 42 of the pipe to be decontaminated to prevent exposure. Decontamination work can be performed. Thus, the present embodiment can be applied without exposure by a simple coating device such as a robot hand and a brush.

  FIG. 5 is a view showing a patch in which a chemical solution is held on a base material. FIG. 6 is a diagram showing a state in which a sticking agent is stuck on the inner surface of a pipe of a decontamination target. In the application step (step S3) and the chemical solution holding step (step S4), as another method of holding the chemical solution 43, for example, a non-woven fabric having a predetermined area as shown in FIG. An adhesive 45 holding the chemical solution 43 is prepared by coating on the substrate 44. And as shown in FIG. 6, the chemical | medical solution 43 can be kept on the oxide film surface for a long time by affixing the adhesive 45 on the oxide film surface of decontamination object so that a poultice may be affixed on an affected part. When the adhesive 45 is used, when removing the chemical solution 43, the chemical solution 43 can be removed simply by removing the adhesive 45, as if removing the compress. In FIG. 6, in order to make the adhesive 45 easy to understand, a gap is provided between the adhesive 45 and the adhesive 45. However, in actual construction, the adhesive 45 is preferably attached without a gap.

  By holding the chemical solution 43 on the surface of the oxide film as described above, it is possible to secure a sufficient time for the chemical solution 43 to dissolve the surface of the oxide film and subsequently to penetrate the chemical solution 43 into the base metal. Thereby, the decontamination rate of a radioactive substance can be improved. In this embodiment, the time for keeping the chemical solution 43 on the surface of the oxide film is 72 hours or less, preferably 24 hours or less, more preferably 16 hours or less for shortening the decontamination work time. In this embodiment, it is possible to perform the decontamination process by a simple method by applying the gel-like strongly acidic chemical solution 43 to the decontamination target portion. Moreover, since the above decontamination treatment can be performed indoors, a decontamination effect can be obtained at room temperature (room temperature). The application of the gel-like chemical solution 43 is not limited to one time, and can be repeatedly applied during the decontamination work. Further, it is possible to improve the decontamination rate by repeating the operation of removing the chemical solution 43 applied once during the decontamination operation and then applying the chemical solution 43 again a plurality of times.

  The chemical solution removing step (step S5) is a step of removing the chemical solution 43 held on the surface of the oxide film after a predetermined time has elapsed since the chemical solution 43 was applied. In this embodiment, since the chemical solution 43 applied to the surface of the oxide film is in the form of a gel, it can be removed by a simple method such as a spatula-like scrubber. Moreover, when the adhesive 45 is used, the chemical | medical solution 43 can be removed by peeling the adhesive 45 currently affixed on the inner surface 42 of piping. In addition, as long as it can remove the gel-like chemical | medical solution 43, not only a scrubber etc. but a tool can be selected and used suitably. In addition, if the radiation dose is high, there is a risk of exposure during work. For example, by using a scrubber or the like by remote operation with a robot hand or the like, the applied chemical solution 43 is removed to prevent exposure and perform decontamination work. be able to. As described above, this embodiment can be applied without exposure by a simple removing device such as a robot hand and a scrubber. As another removal method, after the passage of a predetermined time, the pipe to which the chemical solution 43 is applied is cooled to freeze the gel-like chemical solution 43. Thereafter, the applied chemical solution 43 can be easily removed by splitting the frozen chemical solution 43 by applying an impact with, for example, a hammer and removing the fragments. This method is effective for the decontamination target 41 that has a complicated shape and is difficult to wipe off with a spatula-like scrubber or the like.

  The cleaning process (step S8) is a process of removing the chemical liquid 43 that could not be removed in the chemical liquid removal process (step S5). In the present embodiment, since the chemical solution 43 is in the form of a gel, it is not necessary to use a cleaning agent or a solvent even if it cannot be removed with a spatula-like scrubber or the like. For example, it can be removed simply by wiping with a waste cloth. As a result, no cleaning agent or the like is used, so there is no need to perform waste liquid treatment. Moreover, it is only necessary to discard the used waste, and the amount of waste liquid and waste used for decontamination can be greatly reduced.

  The waste liquid treatment process (step S9) is a process for treating the gel-like chemical liquid 43 peeled off in the chemical liquid removal process (step S5). In the treatment of the waste liquid, the removed chemical solution 43 is dissolved in a solvent such as pure water, and then mixed with a neutralizing agent such as calcium hydroxide or calcium carbonate to form a compound produced as calcium fluoride. Can be treated as waste. Oxalic acid, citric acid, and the like can be decomposed into carbon dioxide and water by using an oxidizing agent or a catalyst. Since the chemical solution 43 of the present embodiment is in a gel form, the application amount is about 1 mm and the usage amount is small, so the waste liquid treatment amount and the waste amount can be greatly reduced. According to the present embodiment, the amount of waste related to waste liquid treatment can be reduced to 1/100 or less as compared with the prior art. In addition, the chemical | medical agent used for a neutralizer is not restricted above, What is necessary is just a chemical | medical agent which produces | generates a compound with respect to the component of the chemical | medical solution 43, The neutralization processing method can also be selected suitably. Furthermore, since the waste liquid treatment process of this embodiment does not require treatment of a large amount of the chemical solution 43 as in the conventional decontamination method shown in FIG. 7, the UV tower 51 and the ion exchange resin tower 53 for waste liquid treatment, etc. The large-scale processing apparatus can be reduced.

(Effect of this embodiment)
The radioactive waste decontamination method of this example is that the chemical solution is gelled to form a gel, so that the chemical solution is applied to the surface of the oxide film to be decontaminated and the chemical solution is kept on the oxide film surface for a long time. Became possible. By holding the chemical solution on the surface of the oxide film for a long time, it is possible to secure a sufficient time for the chemical solution to dissolve the surface of the oxide film and subsequently to infiltrate the chemical solution into the base metal. Thereby, the decontamination rate of a radioactive substance can be improved. Further, since the chemical solution can be sufficiently kept in contact with the surface of the oxide film, the decontamination treatment can be performed in a shorter time than conventional.

  Since the chemical solution of this example is in the form of a gel, it can be applied to the inner surface of the object to be decontaminated using a brush or spatula as a simple method. Further, the applied chemical solution can be removed using a scriber or the like. For this reason, the chemical solution can be applied by using a brush or spatula, etc. by remote control using a robot hand, etc., and the chemical solution can be removed using a scrubber, etc., so that decontamination work can be performed while preventing exposure even when the radiation dose is high. Can do. Thus, the present embodiment can be applied without exposure with a simple application device such as a robot hand and a brush, and a simple removal device such as a robot hand and a scrubber.

  The radioactive waste decontamination method of the present embodiment does not require a decontamination tank that immerses the decontamination object in the chemical solution, so the amount of the waste liquid and the amount of waste after decontamination is small because the chemical solution to be used is small. Processing takes less time and money. Further, since it is not necessary to process a large amount of chemical solution as in the prior art, it is possible to reduce a large-scale processing apparatus such as a UV tower or an ion exchange resin tower for waste liquid treatment.

1 Reactor containment vessel 2 Reactor 3 Reactor cooling system (primary system)
4 Turbine system (secondary system)
41 Decontamination object (pipe)
42 Inner surface 43 Chemical solution 44 Base material 45 Adhesive 50 Decontamination tank 51 UV tower 52 UV
53 Ion exchange resin tower 54 Ion exchange resin 55, 56 Chemical supply tank 57 Heater 58 Decontamination target

Claims (7)

A radioactive waste decontamination method that removes an oxide film formed on the inner surface of an object to be decontaminated after replacing a member constituting a primary system of a nuclear power plant,
A first measurement step of measuring a radiation dose of the decontamination object;
A chemical solution holding step for holding a chemical solution for dissolving the oxide film of the decontamination object on the inner surface of the decontamination object for a predetermined time; and
A chemical removal step for removing the held chemical after the predetermined time has elapsed;
A second measurement step of measuring the radiation dose of the decontamination object after decontamination, was closed,
The method for decontaminating radioactive waste , wherein the chemical solution contains nitric hydrofluoric acid, at least one of oxalic acid and citric acid, a gelling agent, and a solvent . A radioactive waste decontamination method that removes an oxide film formed on the inner surface of an object to be decontaminated after replacing a member constituting a primary system of a nuclear power plant,
A first measurement step of measuring a radiation dose of the decontamination object;
A chemical solution holding step for holding a chemical solution for dissolving the oxide film of the decontamination object on the inner surface of the decontamination object for a predetermined time; and
A chemical removal step for removing the held chemical after the predetermined time has elapsed;
A second measurement step of measuring a radiation dose of the decontamination target after decontamination,
The radioactive liquid decontamination method , wherein the chemical solution includes nitric hydrofluoric acid, at least one of permanganic acid and potassium permanganate, a gelling agent, and a solvent . A chemical preparation step for preparing the chemical,
A determination step of comparing the radiation dose acquired in the first measurement step and the second measurement step to determine whether the radiation dose is reduced to ½ or less;
A cleaning step of cleaning the decontamination object from which the chemical solution has been removed;
A waste liquid treatment step for waste liquid treatment of the chemical liquid removed in the chemical liquid removal step;
The radioactive waste decontamination method according to claim 1 or 2 , characterized by comprising: Claims prior Symbol gelling agent comprises at least one-phosphate crosslinked starch do and cellulose derivatives, said solvent, which comprises a pure water and containing micro-nano bubbles at least hand of pure water The radioactive waste decontamination method according to any one of 1 to 3. Wastewater treatment of the wastewater treatment process uses an agent comprising at least neutralizing agent, said neutralizing agent is radioactive claim 3, characterized in that it comprises at least hand of calcium hydroxide and calcium carbonate Waste decontamination method.   The said chemical | medical solution holding | maintenance process has an application | coating process which apply | coats the said chemical | medical solution to the inner surface of the said decontamination object, The said application | coating process is performed with the application | coating apparatus which can be operated remotely. The radioactive waste decontamination method according to any one of the above items.   The radioactive waste decontamination method according to claim 1, wherein the predetermined time is 16 hours or less.

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