JP5757302B2 - Carbon nanohorn composite - Google Patents

Description

  The present invention relates to a carbon nanohorn complex in which atoms or molecules of metal or oxide, or functional molecules are encapsulated in the internal space of carbon nanohorn (CNH).

  Conventionally, intensive studies have been conducted on characteristics and applications of nano-sized nanocarbon materials (carbon nanomaterials) such as carbon nanotubes and carbon nanohorns. Several methods have already been proposed for adsorbing various substances on the surface of carbon nanomaterials and for holding them inside.

  For example, Patent Document 1 discloses a method in which an adsorbed substance is adsorbed by a gas species on the surface and inside of an aggregate of carbon nanohorns provided with pores by oxidation treatment.

  Patent Document 2 discloses a method of encapsulating a dopant substance in a carbon nanotube by maintaining the single-walled carbon nanotube and the dopant substance at a temperature at which the dopant substance becomes a vapor under vacuum. .

  Patent Document 3 discloses a method in which a carbon nanotube is immersed in a solution in which a dopant substance is dissolved, and the dopant substance is included in the carbon nanotube.

  Further, Patent Document 4 discloses that an extraction substance having a high affinity for a carbon nanomaterial coexists with a carbon nanomaterial in a mixed solution in which a solvent having a lower affinity is added, so that the extraction substance is made of carbon. A method of adhering to the inner surface or the like of a nanomaterial is disclosed.

  By using the above-described method, it is possible to adsorb nanoparticles such as various metals and oxides inside carbon nanotubes and carbon nanohorns, and to provide new carbon nanomaterials that can be used for various applications. it can.

  It is also possible to change the surface state of carbon nanotubes or carbon nanohorns or improve conductivity by incorporating various dopant substances by the above method.

JP 2002-326032 A Japanese Patent Laid-Open No. 2002-97010 JP 2002-255520 A JP 2004-16909 A

  However, in the conventional method, the pores through which the inclusion substance can pass remain in the carbon nanotubes and carbon nanohorns even after the inclusion substance is taken in, and various substances pass through the holes to the inside of the carbon nanotubes and carbon nanohorns. Can go in and out. For this reason, substances such as metals and oxides contained in carbon nanotubes and carbon nanohorns react with other substances or elute. Thus, the carbon nanohorn composite produced by the conventional method has a problem that the encapsulated substance cannot be stably fixed.

  Therefore, in view of such circumstances, the present invention solves the problems of the prior art, can prevent corrosion and elution of the encapsulated metal and its oxide, etc. under acidic conditions and in an organic solvent. It is an object to provide a carbon nanohorn composite whose surface is not oxidized while maintaining its properties.

  The present invention is characterized by the following in order to solve the above problems.

That is, the first gist of the present invention, a carbon nanohorn, wherein a carbon nanohorn complex having carbon and entrapped substance that is encapsulated in nano-horn, the said encapsulated material comprises one or any of the metals and organic The hole formed in order to enclose the said inclusion substance in the said carbon nanohorn containing 2 or more types of mixtures or compounds is characterized by the above-mentioned .

The second gist of the present invention is that in the carbon nanohorn composite according to the first gist, the tip or wall surface of the carbon nanohorn encapsulating the inclusion substance is blocked by recombination of carbon atoms. Features.

Furthermore, a third aspect of the present invention, the carbon nanohorn complex according to the first or second aspect, the diameter of the carbon nano horn 2 - 5 nm, the diameter of the aggregates of the carbon nanohorn is set is 30 is -150 nm, and wherein the.

According to a fourth aspect of the present invention, in the carbon nanohorn composite according to any one of the first to third aspects, the hole formed in the carbon nanohorn to enclose the inclusion substance is the inclusion substance. substances that reaction or passed to the inside of the carbon nanohorn with the entrapped substance is occluded reduced to the lack magnitude or eluted from the carbon nanohorn, and wherein the.

  According to the present invention, even when the carbon nanohorn is encapsulated in a carbon nanohorn, a substance that reacts or dissolves in an organic solvent or the like that dissolves under an acidic condition such as a metal, the obtained carbon nanohorn composite is in an acidic condition. It can exist stably under and in organic solution. Further, even in an oxidizing atmosphere, the encapsulated metal or the like is stable without being oxidized. As described above, the carbon nanohorn composite according to the present invention is characterized by having a large resistance to oxidation, corrosion, dissolution and the like.

  And since it has such excellent features, the carbon nanohorn composite of the present invention can be used for conductive paints, various organic solvents and acidic solutions that require the surface not to be oxidized while maintaining conductivity. It is most suitable for applications such as battery electrode materials.

It is a graph which shows the relationship between the specific surface area estimated by BET method from the adsorption isotherm of nitrogen at 77K about the carbon nanohorn produced in each of Examples 1 and 2 and the oxidation treatment temperature. 4 is a TEM photograph of a Gd metal-encapsulating carbon nanohorn composite produced in Example 3. 4 is a TEM photograph of a Gd oxide-encapsulating carbon nanohorn composite having nanopores closed by heat treatment prepared in Example 4. FIG. It is a TEM photograph after washing the Gd oxide inclusion carbon nanohorn composite produced in Example 4 with nanopores closed by heat treatment with acid. Table showing the results of thermogravimetric analysis before and after dipping in a hydrochloric acid solution of a closed metal-encapsulated carbon nanohorn complex produced by the method of Example 1-4 and a non-closed metal-encapsulated carbon nanohorn complex It is.

  Hereinafter, embodiments of the present invention will be described in detail.

  The (substance-encapsulating) carbon nanohorn complex according to the present embodiment includes a carbon nanohorn and an inclusion substance incorporated therein, and the inclusion substance is shielded by the carbon nanohorn.

  More specifically, in the carbon nanohorn composite according to the present embodiment, the hole formed in the tip or wall surface of the carbon nanohorn is closed after the inclusion material is taken in, in order to take the inclusion material into the carbon nanohorn. ing.

  Hereinafter, a method for producing such a carbon nanohorn composite will be described.

  First, in order to form minute openings (holes or holes) in the carbon nanohorn, a weak oxidation treatment is performed on the carbon nanohorn (aggregates thereof). Subsequently, a dopant substance (inclusion substance) is taken into the carbon nanohorn in which the holes are formed. After that, the carbon nanohorn containing the substance is heat-treated in an inert atmosphere such as an inert gas or a vacuum, so that the opening formed in the oxidation treatment takes in the dopant by recombination of carbons. It is blocked by. In order to promote closing, an organic substance is added to the functional group of the opening by chemical bonding, or carbon clusters such as fullerene are adsorbed in the vicinity of the opening to supply carbon necessary for closing.

  In the above process, the carbon nanohorns used as starting materials are aggregates each having a diameter of 2 to 5 nm and aggregated in a spherical shape with the tip thereof outside. As the carbon nanohorn aggregate, one having a diameter of 30 to 150 nm can be used.

  In order to make fine holes in the carbon nanohorn, various oxidation methods can be used. For example, “Nanowindow-Induced Molecular Sieving Effect in a Single-Wall Carbon Nanohorn”, K. Murata, K. Hirahara, M. Yudasaka, S. Iijima, D. Kasuya, K. Kaneko, Journal of Physical Chemistry B, 2002, 106, 12668, `` Moleclar Potential Structure of Heat-Treated Single-Wall Carbon Nanohorn Assemblies '', K. Murata, K. Kaneko, WA Steele, F. Kokai, K. Takahashi, D. Kasuya, K .. Hirahara, M. Oxidation conditions described in Yudasaka, S. Iijima, Journal of Physical Chemistry B, 2001, 105, 10210 can be used. At this time, the size of the holes can be controlled by selectively adopting various oxidation conditions. For example, in oxidation by heat treatment in an oxygen atmosphere, by selecting an oxidation treatment temperature in the range of 300 to 420 ° C., holes having an arbitrary diameter in the range of 0.3 to 1 nm can be formed.

  The formation of the holes can also be performed by treatment with an acid or the like as disclosed in JP-A-2003-095624.

  In addition, an opening is easy to be formed in the defective part which exists in the surface of carbon nanohorn.

  The inclusion substance can be a substance that sublimates in a vacuum or an inert gas, or a substance that is dissolved in a solvent and exists in a solution. That is, the type is not particularly limited as long as it can be incorporated into the carbon nanohorn in either a gas phase or a liquid phase, and any one of organic, inorganic and metal, or two Mixtures and compounds of the above substances can be used.

  In addition, when the inclusion of the encapsulated substance into the carbon nanohorn is performed in the liquid phase, the incorporation condition of the substance to be incorporated can be changed by changing the condition of incorporation, for example, the type of solvent, pH, concentration, temperature, time, etc. in the solution. The size and quantity can be controlled.

  Moreover, when taking in the mixture of 2 or more types of substances, the composition ratio of the inclusion substance taken in by carbon nanohorn can be controlled by controlling the mixing ratio.

  As described above, after incorporating the encapsulated material into the carbon nanohorn, heat treatment is performed in a vacuum or in an inert gas atmosphere, so that the minute holes used to incorporate the material are on the surface made of carbon atoms. It is blocked. This is due to the recombination of carbon atoms in the vicinity of the hole, or the recombination of carbon atoms in the vicinity of the hole and impurity carbon atoms existing around it. When the minute hole formed in the carbon nanohorn is formed in the defect portion, the defect is repaired by this heat treatment (recombination).

  The temperature of the heat treatment performed to close the hole is optimally a temperature at which the surface functional group produced by the hole opening treatment is eliminated, for example, 800 to 1800 ° C.

  At this time, if heat treatment is performed under high pressure, light elements such as hydrogen can be taken into the carbon nanohorn by the above method, and the pressure is preferably 200 atm or more.

Since the degree of hole repair (ratio of closing) depends on the hole size when the carbon nanohorn is opened, it can be controlled by controlling the hole size as described above. In any case, the hole opened for taking in the encapsulated substance is reduced to a size that prevents a substance that reacts with the encapsulated substance from passing through or eluting the encapsulated substance. As a result, the inclusion substance is shielded from the outside by the carbon nanohorn, and can be stably present inside the carbon nanohorn.

  The material-encapsulated carbon nanohorn composite produced as described above has various electrical and magnetic properties greatly changed from those of the original carbon nanohorn due to the dopant material encapsulated while being shielded from the outside. . Alternatively, physical properties completely different from those of the original carbon nanohorn are given. And since the hole utilized for taking in dopant substance is closed, the said physical property can be maintained also in the environment where utilization was difficult until now. Therefore, the physical properties can be selected according to the purpose and function, and the creation of a new nanostructured material that is chemically or physically modified can be expected.

  The following examples illustrate the present invention in more detail. Of course, the invention is not limited by the following examples.

Example 1
(Carbon nanohorn opening control)
The carbon nanohorn was heat-treated in oxygen in the range of 350 to 550 ° C. for 10 minutes. At this time, the flow rate of oxygen was 200 ml / min. The oxygen partial pressure may be 1 atm or less.

  The sample subjected to the oxidation treatment was measured for an adsorption isotherm of nitrogen at 77K. The result was calculated as a specific surface area by the BET method. The result is shown as “SWNHox” in FIG.

  As can be seen from the graph of FIG. 1, the specific surface area of the carbon nanohorn that was oxidized at the above temperature was significantly higher than that of untreated carbon nanohorn (when the oxygen treatment temperature was 0 ° C.). From this, it can be seen that a hole is formed in the surface of the carbon nanohorn so that the inside can be used for adsorption of nitrogen. That is, the oxidation process is a hole opening process.

(Example 2)
(Closing control of carbon nanohorn)
In the same manner as in Example 1, the carbon nanohorns that were oxidized and opened in the temperature range of 350 to 550 ° C. were heat-treated in an argon atmosphere using an electric furnace. At that time, the electric furnace temperature was kept at 1200 ° C., and the heat treatment time was about 3 hours. The specific surface area of the carbon nanohorn produced in this manner was calculated by the BET method by nitrogen adsorption measurement at 77 K as in Example 1. The result is shown as “HT1200-SWNHox” in FIG.

  As shown in FIG. 1, the specific surface area of the carbon nanohorn having an oxidation treatment temperature up to about 500 ° C. is greatly reduced by the subsequent heat treatment in an inert gas atmosphere. That is, the hole formed by the oxidation treatment at a temperature lower than about 500 ° C. is almost completely closed by the subsequent heat treatment in the inert gas atmosphere. On the other hand, carbon nanohorns oxidized at a temperature higher than about 500 ° C. have a small decrease in specific surface area due to subsequent heat treatment in an inert gas atmosphere. That is, the hole formed by the oxidation treatment at a temperature higher than about 500 ° C. is not sufficiently blocked even by the subsequent heat treatment in the inert gas atmosphere. Thus, by controlling the temperature of the oxidation treatment, the rate at which the holes are closed by the subsequent heat treatment can be controlled.

  The heat treatment temperature for closing the holes is suitably in the range of 800 to 1800 ° C. as described above.

Example 3
(Introduction of metal complex into carbon nanohorn)
50 mg of gadolinium acetate and 50 mg of carbon nanohorn oxidized at 500 ° C. were mixed in 20 ml of ethanol solution and stirred at room temperature for about 24 hours. Then, it filtered using the filter. Subsequently, the substance (sample) remaining on the filter was vacuum-dried for 24 hours, and the solvent contained therein was evaporated and completely removed. A transmission electron microscope (TEM) image of the sample thus obtained is shown in FIG. In FIG. 2, it can be seen that the dark ellipse is gadolinium acetate and is encapsulated inside the carbon nanohorn.

Example 4
(Closing treatment of carbon nanohorn encapsulating metal complex)
The sample in which gadolinium acetate was incorporated into the carbon nanohorn produced as in Example 3 was heat-treated with an electric furnace in an argon atmosphere as in Example 2. At this time, the gadolinium acetate complex is an oxide. A TEM image of the obtained sample is shown in FIG.

  As can be seen from FIG. 3, the metal oxide is still taken into the carbon nanohorn, and many are gathered near the tip of the carbon nanohorn.

  Next, in order to confirm the resistance of the sample to acid, the sample was immersed in a 5M hydrochloric acid solution and stirred for 24 hours. Then, it filtered using the filter and the sample which remained on the filter was vacuum-dried for 24 hours. A TEM image of the sample is shown in FIG. As can be seen from FIG. 4, many metal compounds remain inside the carbon nanohorn.

  Further, by thermogravimetric analysis (TGA) of these samples, the amount of metal remaining in the carbon nanohorn without being eluted in hydrochloric acid was estimated. The result is shown in FIG. In addition, as a comparative example, a gadolinium oxide-encapsulating carbon nanohorn not subjected to pore closing treatment was prepared, and the result of obtaining the amount of metal remaining in the carbon nanohorn without being eluted in hydrochloric acid is also shown in FIG. In addition, the gadolinium oxide inclusion | inner_cover carbon nanohorn of the comparative example was obtained by producing the gadolinium acetate inclusion | inner_cover nanohorn by the method similar to Example 3, and heat-processing this at about 600 degreeC.

  From FIG. 5, it can be seen that the carbon nanohorn composite of the present invention in which the hole of the carbon nanohorn is closed and the inclusion substance is shielded from the outside allows the inclusion substance to exist stably in the carbon nanohorn.

Claims (4)

A carbon nanohorn complex having a carbon nanohorn, and a encapsulating material which is contained in the carbon nanohorn,
The inclusion substance includes one or a mixture of two or more of metals and organic substances , or a compound,
A carbon nanohorn composite comprising a hole formed to enclose the inclusion substance in the carbon nanohorn. 2. The carbon nanohorn complex according to claim 1, wherein a tip or a wall surface of the carbon nanohorn enclosing the inclusion substance is closed by recombination of carbon atoms. The carbon diameter of nano horn 2 - 5 nm, the carbon nanohorn aggregate was set diameter of 30-150Nm, carbon nanohorn complex according to claim 1 or 2, characterized in that. The hole formed to encapsulate the inclusion substance in the carbon nanohorn does not allow a substance that reacts with the inclusion substance to pass into the carbon nanohorn or to elute the inclusion substance from the carbon nanohorn. It is closed to shrink to the size,
The carbon nanohorn composite according to any one of claims 1 to 3, wherein the carbon nanohorn composite is provided.