JP5757233B2 - Band with water-absorbing resin that keeps the cool feeling - Google Patents

Description

The present invention relates to a band containing a water absorbent resin and a method of using the same. More specifically, the present invention relates to a band using a fabric having a large moisture (%) on the surface of the fabric when wet as the fabric of the outermost layer of the band containing the water-absorbent resin, and a method of using the same.

There is a method to cool the human body by keeping the head and neck cold by using a water-containing towel when the human body heats up due to a hot summer or a cold. The water-containing towel removes heat using the latent heat of vaporization of water, and recently, a neck cooler has been sold as a means for keeping the neck cool. As this neck cooler, a water absorbent resin powder is used. When water is absorbed, the water absorbent resin in the neck swells into a gel, and the water in the gel gradually evaporates through the breathable fabric. The temperature of the cooler itself decreases and the neck can be kept cool. When the blood in the neck carotid artery is kept cool, the appropriately cooled blood can go around the body and lower the temperature of the body. As such, a cooling neck band is sewn in the longitudinal direction so as to bisect it in the width direction, and a water-absorbing resin is put therein to cool the neck (for example, Patent Document 1) or a water-soluble component There is a band containing a water-absorbent resin used by containing a water-absorbent resin with a small content (for example, Patent Document 2).

Registered Utility No. 3019831 Japanese Patent No. 4204904

However, when these water-containing bands are wound, for example, around the neck, a cold sensation is initially felt, but the cool sensation decreases with time. In this case, if you remove it once and leave it for a while, the temperature of the band will drop, and if you use it again, the feeling of cooling will return. There is a need for a neck cooler that can maintain a cool feeling without removing the band.
An object of the present invention is to provide a band containing a water-absorbent resin and a method of using the same, which can maintain the cooling sensation of the water-containing band for a longer time than before.

As a result of earnest research, the present inventors have achieved that the outermost layer fabric of the water-absorbent resin-containing band can be achieved by using a fabric having a large amount of water absorption (%) on the fabric surface when wet. The headline has led to the present invention.
That is, the present invention provides a water-absorbent resin, the band consisting of bag-shaped breathable fabric take this, Ri Na outermost portion enveloping at least a water-absorbent resin is formed by the fabric (A), the fabric (A ) Is a layer formed of ultrafine fibers or ultrafine fibers, and has a water permeability of 0.1 cm ³ / cm ² · s or more and 30 cm ³ / cm ² · s or less by the Frazier method. It is a band with a functional resin.

Furthermore, the present invention is characterized in that a breathable fabric different from the fabric (A) is interposed between the fabric (A) and the water absorbent resin .
Furthermore, the present invention is characterized in that the fabric (A) is a fabric formed of microfibers or nanofibers.
In the present invention, the band containing the water-absorbing resin is a human body cold band or cold bandana.

According to the present invention, the surface of the surface of the fabric (A) measured by the following moisture measurement method in a band composed of a water-absorbent resin and a bag-shaped fabric for containing the water-absorbent resin (hereinafter sometimes simply referred to as a band or a cold insulation band) Since the outermost layer of at least the portion that wraps the water-absorbent resin is formed by the fabric (A) having a moisture content of 0.3% or more than the moisture of the surface of the cotton fabric fabric measured at the same time, the cotton fabric is used as the outermost layer. The cool feeling is improved as compared with the conventional band, and the cool feeling can be maintained for a long time.
The cold feeling is the consciousness of feeling cold, and the cold temperature has a great influence, but not the cold temperature itself. The more moisture on the surface of the outermost fabric that forms the band, the greater the transpiration of the water, the lower the temperature of the band itself, and the greater the feeling of cooling, whereby the feeling of cooling lasts longer. Conceivable. In addition, the more moisture on the surface of the fabric, the more the skin that comes into contact with the band gets wet, and the more the moisture in the skin evaporates, the lower the skin temperature. Although both of these phenomena occur simultaneously on the skin surface, the latter seems to have a significant effect on the cold feeling. However, no particular attention is paid to the moisture on the surface of the outermost fabric in this field.

Further, according to the present invention, when the moisture of the fabric (A) is 21.0% or more, the moisture on the surface of the water-absorbing resin-containing band is the moisture on the surface of the cold insulation band formed of a conventional cotton fabric. Therefore, the feeling of cooling is greater than that of a conventional cold band, and the feeling of cooling can be maintained for a long time.

Further, according to the present invention, when the fabric (A) is formed of microfibers or nanofibers, the moisture on the surface of the water-absorbing resin-containing band is absorbed on the surface of the cold-insulated band formed of a conventional cotton fabric. Since it is larger than moisture, it has a greater cooling sensation than a conventional cold band, and the cooling sensation can be maintained for a long time. As will be described later, microfibers and nanofibers are ultrafine fibers or ultrafine fibers, have much higher water absorption than cotton fabrics, and the surface moisture of the cold insulation band is very large. The cool feeling is greater than that of a conventional cold insulation band formed of cotton fabric, and the cool feeling can be maintained for a long time.

In addition, since the fabric (A) is used after being in contact with the skin after the water-absorbing resin-containing band is contained, the moisture on the surface of the fabric in contact with the skin is greater than the moisture of the conventional cotton fabric. The feeling of cooling is large and the feeling of cooling can be maintained for a long time.

In the present invention, since the band containing the water-absorbent resin is a human body cold band or a cold bandana, the cold feeling is increased as compared with the conventional cold band or cold bandana, and the cold feeling is sustained.

It is a graph which shows the change of the temperature of a cold insulation band when the fabric (A) in this invention and the comparative cotton fabric are wound around a cold insulation band, and the cold insulation experiment was conducted.

Hereinafter, embodiments of the present invention will be described. Note that the present invention is not limited to the following embodiments. Various modifications can be made to the following embodiments within the same and equivalent scope as the present invention.

The fabric (A) used in the present invention is a breathable fabric that forms the outermost layer of a band containing a water-absorbent resin, and the moisture on the surface measured by the following measurement method is formed by the cotton fabric and hydrated. The fabric is 0.3% more than the moisture on the surface measured simultaneously with the band containing the water absorbent resin. The cold feeling of the cold insulation bands currently on the market is the one with the outermost layer made of cotton fabric. The more the fabric with a larger difference from the moisture on the surface of the cotton fabric, the better the feeling of cooling. If so, it is difficult to feel the difference in cold feeling. If the difference is 0.3% or more according to the numerical values of the examples described later, it is considered that a difference in cool feeling can be felt. Therefore, in the present invention, the fabric (A) has a moisture content of 0.3% or more.
Moisture measurement method: Cloth (A) was hydrated, picked up to 100%, closely attached onto a swollen water-absorbent resin-containing band, and allowed to stand at 25 ± 5 ° C. for 30 minutes in the room (fabric ( The moisture on the surface of A) is measured with a moisture meter.

Specifically, the cold insulation band is dipped in water at 15 to 20 ° C. for 2 to 3 minutes to sufficiently swell and absorb water, and then placed on a non-water-absorbing substrate. The fabric (A) containing water and picked up at a pickup rate of 100% is placed in close contact with the fabric, and allowed to stand at room temperature for 30 minutes, and then the moisture on the surface of the fabric (A) is measured with a moisture meter. Measure 10 times and use the average value as the measured value. Sufficient water absorption and swelling means a state where the cold insulation band is rounded or gently swells and water is found on the surface.
In this measurement method, the moisture on the surface of the fabric (A) must be measured in a state in which the moisture on the surface has reached a certain steady state due to transpiration of water to the outside and the movement of water from the inside to the surface. The method of the present invention is a measurement method in which factors such as air permeability and water absorption of the fabric (A) are combined. The reason for setting the measurement time after 30 minutes is that the moisture on the surface of the fabric is considered to be in a steady state.

At the same time, the surface moisture of the cotton fabric used in the conventional cold band is measured in the same manner. At the same time, it means that the measurement conditions are made the same as much as possible. If the test conditions change, for example, if the temperature of the water that contains water changes, the water content changes, and the measured value is affected.
A commercially available moisture measuring device can be measured as the moisture measuring device. For example, "moisture Chiekka" (model: SK-940A, manufactured by Hakaru Sato instrument Manufacturing Co., Ltd.) and the like.

It is believed that the moisture on the fabric surface is due to the balance between the evaporation of moisture from the fabric surface and the migration of moisture from the hydrogel to the surface. The amount of moisture when the fabric surface is wet varies depending on the material of the fibers forming the fabric, the cross-sectional shape of the fibers, the entanglement state of the fibers, and is also affected by the processing of the fabric surface. Seems to be less affected.
The fabric (A) of the cold insulation band is selected including the moisture content when wet, air permeability, strength, touch, skin safety, cost, and the like. The material is formed of fibers having high hydrophilicity, and the greater the official moisture content, the greater the moisture on the fabric surface when wet. As for the structure of the fibers, the more moisture there is in each fiber with irregularities and holes, the greater the amount of moisture. In addition, the greater the entanglement between the fibers, the greater the space where moisture enters and the greater the amount of moisture. In addition, the moisture content on the surface can be increased by water absorption processing.

Specific examples of the breathable fabric (A) used in the present invention include, but are not limited to, fabrics made of fibers such as superabsorbent fibers, hemp, rayon, microfibers, and nanofibers. Among these, fabrics made of microfibers and nanofibers that are less likely to swell even when water is absorbed and have a large surface water absorption are preferable. According to the measurement method of the present invention, the moisture (%) on the surface of the cotton fabric used for the conventional cold band is at most about 20%. Therefore, it is preferable that the water | moisture content of the surface of a fabric (A) is 21.0% or more.

The microfiber is a chemically composed fiber such as ultrafine nylon or polyester of 8 micrometers or less, for example, a split microfiber of 0.01 to 50 denier, more preferably 0.01 to 0.99 denier. , Unsplit microfibers, or combinations thereof. Moreover, the microfiber which consists of polyester and polyamide whose ratio of weight% is 50 / 50-90 / 10; the microfiber of 100% polyester; and the microfiber of 100% polyamide (nylon). Since the fabric made of microfibers bundles ultrafine fibers, it has a lot of spaces between the fibers and has high water absorption due to capillary action. Further, microfibers spun by extruding fibers and then tearing to form wrinkles and grooves are preferable because they further promote capillary action, and moisture is drawn into the void space. Fabrics formed from microfibers can have, for example, 90,000 to 180,000 microfibers per square inch, and thus have a large surface area to contact moisture-containing surfaces. Similarly, a large number of fibers will proportionally increase the amount of capillary action and the amount of void space into which moisture is drawn.

The nanofiber is an ultrafine fiber having an average fiber diameter smaller than that of the microfiber, and is preferably 1 to 800 nm, more preferably 10 to 700 nm. Examples of the resin constituting the nanofiber include polylactic acid, polyamide, polyurethane, polyacrylonitrile, polystyrene, polyimide, polyethylene, polypropylene, polyester, polyvinyl alcohol, polyethylene glycol, polyoxyethylene, polyvinyl pyrrolidone, polyvinyl acetate, starch, Examples thereof include carboxymethyl cellulose. The fiber may be a fiber made of a single resin or a composite fiber made of two or more kinds of resins. Examples of the shape of the composite fiber include side-by-side composite fiber, core-sheath fiber, and composite hollow fiber. In addition, the single yarn cross-sectional shape of the fiber includes a circle, a triangle, a flat shape, a multi-leaf, a porous shape, and the like, and may be appropriately selected from these according to the application. Further, the thickness of the fabric (A) composed of nanofibers is preferably 1 μm or more. When the thickness is less than 1 μm, handling properties and workability may be deteriorated. Preferably it is 10-100 micrometers. Nanofibers have the same or better water absorption performance as microfibers.

The fabric (A) is formed with at least the outermost layer that wraps the water-absorbent resin. Since the fabric (A) is preferably used in contact with the human skin, at least the outermost layer where the water-absorbing resin exists is formed. The outermost layer means that the skin can be contacted in consideration of other fabrics between the water-absorbent resin and the outermost layer.

In addition to the fabric (A), a breathable fabric usually used for a cold band can be used together with the fabric (A). The breathable fabric is not particularly limited in form and material as long as it has flexibility and water permeability and has a wet strength that does not break when it contains a hydrogel.

Examples of the material of the breathable fabric include natural fibers such as cotton, wool, silk, cellulose, and pulp, synthetic resins or fibers such as polyester, nylon, acrylic, polyethylene, polypropylene, polyurethane, polystyrene, and poval, and modified products thereof. Semi-synthetic fibers such as acetate and mixed materials thereof can be applied. Preferred are natural fibers having water absorption, and mixed materials of these and other fibers.
Examples of the form include cloth such as knitted fabric, woven fabric, and non-woven fabric.

The breathability of the breathable fabric and the breathable fabric (A) is preferably 0.1 cm ³ / cm ² · s or more, more preferably 0.3 cm ³ / cm ² · s or more. More preferably. Further, it is preferably 30 cm ³ / cm ² · s or less, and more preferably 20 cm ³ / cm ² · s or less. When it is 0.1 cm ³ / cm ² · s or more, the vaporization rate at which the moisture of the water-containing gel of the cold insulation band is gradually vaporized through the cloth increases rapidly, and the cooling feeling increases, and the cooling feeling can be maintained for a long time. When it is 0.3 cm ³ / cm ² · s or more, the vaporization rate of vaporization is further accelerated and the cooling feeling is improved. If it is 30 cm ³ / cm ² · s or less, the water-absorbent resin powder before water absorption does not spill outside, the water vaporization rate of the water-absorbent resin after water absorption is not too fast, and the cold insulation duration is not shortened.

The water-absorbing resin that forms the water-containing gel in the band in the present invention is not particularly limited, whether natural or synthetic, but is inexpensive and has excellent water absorption characteristics such as safety, durability, water absorption magnification and water absorption speed, And what does not worry about corruption is preferable.
Examples of such materials include synthetic water-absorbing resins and are not particularly limited as long as they absorb water and swell. For example, crosslinked polyacrylic acid partially neutralized product, starch-acrylic acid graft Neutralized polymer, hydrolyzate of starch-acrylonitrile graft polymer, saponified vinyl acetate-acrylic ester copolymer, cross-linked isobutylene-maleic anhydride copolymer, acrylonitrile copolymer or acrylamide copolymer Hydrolyzate or cross-linked product thereof, acrylate-acrylamide copolymer cross-linked product, polyvinyl alcohol cross-linked product, modified polyethylene oxide cross-linked product, acrylamide-2-methylpropane sulfonate copolymer cross-linked product, (meth) acryloylalkane Cross-linked sulfonate copolymer, cross-linked carboxymethyl Cellulose salts, and the like crosslinked polymer of a cationic monomer. Among these, a crosslinked polyacrylic acid partial neutralized product and a neutralized product of starch-acrylic acid graft polymer are preferable because they have particularly good water absorption swelling characteristics, water retention, safety, and economic efficiency.

These water-absorbing resins may be used alone or in combination of two or more. The water-absorbent resin may be granulated in a predetermined shape, and may be in various shapes such as irregularly crushed, spherical, scaly, fibrous, rod-like, massive, powdery, In order to improve water absorption performance, it is more preferable that it is powdery.

Although there is no limitation in particular about the average particle diameter of particle | grains, Preferably it is 30-850 micrometers, More preferably, it is 60-400 micrometers. If it is larger than 30 μm, the water-absorbent resin powder hardly leaks from the breathable substrate, and if it is smaller than 850 μm, the water absorption speed when producing the hydrogel is good. The particle size distribution is not particularly limited, but is preferably a particle size distribution such that particles in the range of 30 to 850 μm are 95% by mass or more. Here, the average particle diameter means the mass average particle diameter, the mass average particle diameter is plotted on the logarithmic probability paper of the particle size distribution of the cross-linked polymer on the horizontal axis is the particle diameter, the vertical axis is the content based on the mass, It is measured by a method for determining the particle size that occupies 50% of the total. For example, a normal sieving method can be applied.

The water absorption capacity of the water absorbent resin is preferably 100 to 1000 times by weight. The water absorption ratio can be measured by the following method.
<Measurement method of water absorption capacity of water absorbent resin>
A sample of water-absorbent resin (sample amount: Xg) was placed in a nylon net bag (250 mesh), and the bag was immersed in excess water. After 60 minutes of immersion, the whole bag was pulled up in the air, allowed to stand and drained for 15 minutes, and then the mass (Yg) was measured to determine the water absorption capacity from the following formula. [The same operation as described above was performed using only a mesh bag, and the mass (Zg) of this amount was subtracted as a blank. ]
Water absorption magnification = (Y−Z) / X

The water absorption rate of the water absorbent resin is preferably 5 to 200 seconds, more preferably 5 to 100 seconds. When the water absorption speed is 5 seconds or more, the water-absorbing resin is less likely to be blocked due to the humidity in the air, and it is easy to use because there is no “mamako” before use. When the water absorption rate is 200 seconds or less, the water absorption rate when water is contained is sufficiently high, and the water evaporation rate is also high, so that the cooling rate is also fast and preferable.

The water absorption rate of the water absorbent resin can be measured by the following method.
<Measurement method of water absorption rate of water-absorbing resin>
50 mL of tap water is put into a 100 mL glass beaker, and stirred at 600 rpm using a magnetic stirrer (diameter (center portion: 8 mm, both ends: 7 mm), length: 30 mm fluororesin coated). The sample 2.00 test sample is put into the vortex at once, and the time (seconds) from when the vortex disappears until the liquid level becomes horizontal is measured to obtain the water absorption speed.

The water-absorbing resin preferably has a low molecular weight water-soluble component, for example, a low molecular weight molecule such as an acrylic acid oligomer. These water-soluble components give a slimy feeling when the hydrogel is touched by hand, and are not good in touch. If the water-soluble component in the water-absorbent resin is 10% or less, the feeling of slime is small, and if it is 5% or less, it feels even less. The water-soluble component can be measured by a method such as a gravimetric method or an electrodrop method described in JP-A-2005-445.
Since the water-soluble component is not water and is difficult to evaporate, it tends to come out and remain on the surface of the fabric when a cold band is used. Therefore, although the moisture content on the surface of the fabric may increase, such a state gives a slimy feeling to the skin and is not suitable for the cold band of the present invention.

The water-absorbing resin-containing band is a band in which the water-absorbing resin is put in a bag made of a cloth, and the bag is formed by forming the outermost layer of at least a portion including the water-absorbing resin with the cloth (A). The portion not containing the water-absorbing resin may or may not be formed of the fabric (A). Further, the entire portion including the water-absorbing resin may be formed of the fabric (A), but if the bag is flat, only one side is covered with the fabric (A), and the opposite surface is conventionally used. It may be covered with a breathable fabric such as a cotton fabric. Preferably, more than half of the portion of the bag having the water-absorbing resin is covered with the fabric (A), and more preferably, the entire surface of one portion of the bag having the water-absorbing resin is covered. Particularly preferably, the entire surface of both portions where the water-absorbing resin is present is covered.
There is no particular limitation on the joining means for forming the band containing the water-absorbent resin into a bag shape. For example, sewing, heat sealing, adhesive, and heat fusion tape are interposed between the cloths and fusion is performed by heat. There are ways to do this. Sewing and heat sealing are preferred.

The size of the cold insulation band is determined by the part to be worn, the child, and the adult, but is preferably 1 cm to 15 cm in width and 15 cm to 150 cm in length, more preferably 2 cm to 10 cm in width and 20 cm to 90 cm in length. There is no particular limitation, and there are strips and triangles. A triangular thing like an isosceles triangle with a long bottom part in a band shape is particularly called a bandana. Also, as a part of scarf, it is fashionable and favored by young people.

Further, the bag portion of the fabric is divided into one section or two sections or more, preferably stitched or heat sealed between the upper and lower sides so as to be divided into one section or 2 to 5 sections. It is preferable that the water-absorbent resin is uniformly filled in the space per unit area. This is because the water absorbent resin can be prevented from being biased to one side in the bag. In addition, in order to prevent the unevenness of the water absorbent resin, a sheet in which the water absorbent resin is applied to a base material such as a nonwoven fabric instead of the water absorbent resin or the water absorbent resin is sandwiched between the base materials such as the nonwoven fabric is placed in the bag portion. May be put in.
Around the band, the end of the water-absorbent resin may be sewn with bending to prevent it from falling off, or hem may be attached if necessary. In order to prevent powder from falling from the seam, it is preferable to use a thin needle and a thin thread. If necessary, the stitches can be crushed later by resin processing or the like.

The band with the water absorbent resin can be produced by a known method. For example, the form which provides the bag part of 1 section or 2 sections or more as mentioned above, and encloses the water-absorbent resin formed in powder form water absorbent resin or a sheet form, or a thin plate shape in each bag part is mentioned. . The amount of the water-absorbing resin can also be added in a known amount.

The more moisture on the surface of the outermost fabric that forms the band, the greater the transpiration of the water, the lower the temperature of the band itself, and the greater the feeling of cooling, whereby the feeling of cooling lasts longer. Conceivable. In addition, the more moisture on the surface of the fabric, the more the skin that comes into contact with the band gets wet, and the more the moisture in the skin evaporates, the lower the skin temperature. Both of these phenomena occur simultaneously on the skin surface.

In order to improve and maintain the cooling sensation, the present inventors thought that the above two functions would increase if the moisture content on the surface of the fabric was increased. In particular, it is considered that the skin is likely to feel cold when moisture directly contacting the skin evaporates. That is, since the cold insulation band and the skin are slightly in close contact with each other as the person moves, the above phenomenon increases and the effect is improved.
The most cool fabric in the current commercial band is a cotton fabric, but if a fabric having a higher moisture content on the surface of the fabric than the cotton fabric is used for the portion of the band that comes into contact with the skin, it will wet the skin much. Therefore, it is considered that the above effects can be achieved.

If both sides of the cold insulation band of the present invention are formed of the fabric (A), there is no problem. However, if one side or a part thereof is formed of the fabric (A), the cold insulation band is hydrated. If the fabric (A) is used in contact with the skin, the feeling of cooling can be felt stronger than the conventional band using the cotton fabric as the outermost layer, and the feeling of cooling can be maintained for a long time.

The band containing the water-absorbent resin of the present invention can be suitably used as a cold-retaining band or a cold-retaining bandana for clothing that is water-containing and wound around a human head, neck, arm or the like to keep it cool. When using it as a cool band for clothing or as a cool bandana, a band containing a water-absorbing resin is used for 1 to 15 minutes.
Use after soaking in water at 1-25 ° C. Preferably it is 3-20 degreeC. In addition, when not containing moisture, if the surface of the fabric (A) has a high moisture content, if used as a sweat removing band, it absorbs sweat faster than a sweat removing band having a conventional cotton fabric as the outermost layer, It can also be used as a sweat band.

EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, it is not limited to this.
(Test Example 1)
“Icool” (neck cooler: manufactured by IJE, the outermost layer is a cotton fabric) was immersed in tap water at 20 ° C. for 5 minutes to swell water. On top of that, the following fabric is hydrated, the pickup rate is reduced to 100%, the hydrated and swollen “I-Cool” is kept in close contact, and after left for 20 minutes, 30 minutes, 1 hour, the moisture on the surface of the fabric is “Moisture checker” (model: SK-940A, manufactured by Sato Light Equipment Co., Ltd.) was measured ten times with a moisture meter, and the average value is shown in Table 1.

From the above results, those having larger water absorption (%) than cotton fabric are microfiber (hereinafter referred to as MF) fabric and hemp fabric, and the water content after 30 minutes is 0.3% or more than the cotton fabric measured simultaneously. large. The moisture on the surface of the ester / cotton fabric was the lowest.
The amount of water absorption (%) on the surfaces of the cotton fabrics A and B is almost the same as the water content (%) on the surface of “Ikuru”. It is considered that all outermost fabrics including “Ikuru” itself are cotton fabrics. Further, when only the cotton fabrics A and B are viewed, it seems that the surface moisture (%) and the basis weight are not related.

Next, with respect to the fabric after 30 minutes, 10 people (A to J) touched with the back of the hand, and numbers were assigned in the order of coldness. As a result, it became as shown in Table 2. The smaller the value, the colder it is.

From Tables 1 and 2, the cooler the better the surface moisture (%). Since the temperature of the cold insulation band is the same, the cooling sensation is not related to the temperature in this evaluation. The MF fabric and the hemp fabric have a cooler feeling than the cotton fabric. That is, it can be said that a fabric with a large moisture (%) on the surface of the fabric is likely to feel a cool feeling.

(Test Example 2)
The following experiment was conducted in the shade in the outdoors. MF fabric A and cotton fabric A listed in Table 1 were hydrated and picked up to 100%, and the part with the water-absorbing resin of “Ikuru” (above) fully swollen with water was wound once on the entire surface, It was allowed to stand on a plate warmed to 36 ° C. (this temperature is close to human body temperature). A temperature sensor was inserted between the plate and the outermost fabric, and the temperature for 1 hour was measured every 10 minutes. In addition, the temperature, the temperature of the plate, and the moisture (%) on the surface of the fabric that had been banded were measured. The results are shown in Table 3 and FIG. FIG. 1 is a graph in which the numerical values in Table 1 are plotted.

The observation time was 1 hour, during which the temperature rose from 34.0 ° C. to 35.5 ° C. and dropped to 34.0 ° C. Accordingly, the temperature of the lower plate also increased from 36.0 ° C. to 36.5 ° C. and decreased to 36.0 ° C. As for the temperature between the fabric of the cold insulation band and the lower plate, there was a clear difference between the two fabrics. That is, in the case of cotton fabric, the temperature increased from 29.7 ° C. to 30.3 ° C. and decreased to 29.7 ° C. In the case of MF fabric, the temperature dropped from 29.9 ° C. to 28.9 ° C. In the case of cotton fabric, the surface moisture (%) was changed from 19.7 to 19.0, but finally decreased to 16.7%. In the case of MF fabric, it was stable between 20.7 and 20.4.

From this, the temperature of the first band of both was the same, but after 30 minutes, a 1 ° C. opening occurred. In the case of cotton fabric, the temperature of the band increased as the temperature increased, but in the case of MF fabric, the temperature hardly increased. Since the amount of moisture on the surface of the cotton fabric was small, the rise in temperature could not be covered by evaporation, but in the case of MF fabric, the moisture on the surface was so large that the moisture for temperature rise could be covered by evaporation. Conceivable. In the case of the MF woven fabric, the amount of water on the surface does not change during that time, so it is considered that the moisture has moved from the internal hydrogel and the surface moisture has been replenished. Since the temperature of the lower plate is always about 36 ° C., it is considered that human skin (other than movement) can be assumed.

From the above, it can be considered that if the moisture content on the surface of the outermost layer of the band is large, the temperature of the band hardly rises even if the temperature rises, and this is one reason for maintaining the cool feeling. In the above test, since the band is left still, only the temperature change of the band itself can be known. However, when the band is worn on the human body, the phenomenon between the skin and the band due to the movement of the person is unknown, so it is necessary to test what actually happens on the human body, and the following tests were performed.

First, the cold insulation band was created as follows.
Example 1
As a water absorbent resin, a crosslinked sodium polyacrylate having an average particle size of 200 μm, a water absorption of 100 g / g, and a water-soluble component content of 1.5% was prepared. Separately, three types of fabrics of size 5 × 80 cm (MF fabric A, cotton fabric A, ester / cotton (65/35) fabric of Table 1 above: air permeability ²⁰ , 16, 14 cm ³ / cm ² · sec,) Two sheets were prepared for each. Then, two sheets were overlapped, and two sections of bags were vertically provided and sewn in a portion where the central length of the band was 35 cm. Each of the divided spaces was filled with 1.0 g of the above water-absorbing resin from the unstitched side, and three sides of the water-absorbing resin-containing band were manufactured by stitching the sides. A band made of MF fabric A is the band of the present invention.

Below, using cotton woven fabric A, MF woven fabric A, ester / cotton (65/35) woven fabric, the cold insulation band created above was immersed in water at 20 ° C. for 3 minutes, and the room temperature was 23 to 28 ° C. I asked 10 people to wear them on their necks and looked at the order of cold sensitivity and the duration of the cold feeling. The results are shown in Table 4. In Table 4, time represents the number of people, but the cold sensitivity was given 1, 2, and 3 in order of coldness, and the total score of 10 people was described. The smaller the value, the greater the cool feeling.

From this result, the cold-insulated band made of MF fabric A had the best cooling sensation. Moreover, the more moisture (%) on the surface of Table 1, the greater the cold sensitivity and the longer the time for feeling the cool feeling. In addition to the temperature drop of the cold insulation band itself, there is a lot of moisture that wets the skin surface, so it seems that the effect including the temperature drop due to evaporation of the moisture was also affected.
Therefore, the cold insulation band of the present invention has a higher moisture sensitivity (%) on the surface of the outermost layer than the conventionally used cotton fabric of the cold insulation band, so that the cold sensitivity is large and the cold feeling can be sustained for a long time. It is.

Claims (4)

A water-absorbent resin, the band consisting of bag-shaped breathable fabric take this, Ri Na outermost portion enveloping at least a water-absorbent resin is formed by the fabric (A), the fabric (A) is microfine fibers or A band with a water-absorbent resin , which is a single layer formed of ultrafine fibers and has a permeability of 0.1 cm ³ / cm ² · s or more and 30 cm ³ / cm ² · s or less by the Frazier method .   The band with a water absorbent resin according to claim 1, wherein a breathable fabric different from the fabric (A) is interposed between the fabric (A) and the water absorbent resin. The band with a water-absorbent resin according to claim 1 or 2, wherein the fabric (A) is a fabric formed of microfibers or nanofibers. The band with a water-absorbent resin according to any one of claims 1 to 3, wherein the band is a human cold band or a cold bandana.

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