JP5738722B2 - Plant water treatment device, control method for electric desalination device, and steam turbine plant - Google Patents

Description

  The present invention relates to a plant water treatment apparatus, a control method for an electric desalination apparatus, and a steam turbine plant, which are related to water quality improvement by high-temperature electric desalination in a condensate water supply system of a steam turbine plant.

  In general, a pressurized water nuclear power plant (hereinafter referred to as “PWR”) is divided into a primary cooling system and a secondary cooling system via a steam generator, and high-temperature high-pressure water generated in a nuclear reactor in the primary cooling system. Heat is exchanged with a steam generator to generate steam on the secondary cooling system side.

  In the secondary cooling system of the PWR, steam generated by a steam generator is sent to a steam turbine, and the steam turbine is driven to generate power.

  On the other hand, in a thermal power plant, coal or oil is burned in a boiler, water is heated to generate steam, and a steam turbine is driven by this steam to generate power.

  In any steam turbine plant, steam expanded by driving the steam turbine is introduced into a condenser, where it is cooled and condensed to become condensed water.

  This condensate is subjected to demineralization treatment for removing ions by an ion exchange resin or the like in a condensate demineralizer as necessary, and then heated by a feed water heater and supplied as feed water to a steam generator or a boiler.

  In PWR, water supplied to the steam generator is injected with a chemical from the viewpoint of suppressing corrosion of structural materials such as piping and equipment in the secondary cooling system. That is, ammonia or an amine compound is used as a pH adjuster, and hydrazine is used as an oxygen scavenger.

  On the other hand, in the steam generator, impurities such as ions and corrosion products brought in by the water supply are concentrated, which causes corrosion of the heat transfer tube in the steam generator and a decrease in heat transfer performance. For this reason, operation which discharges a part of water in a steam generator (blowdown) is performed.

  Blow-down water from the steam generator is guided and purified by existing water purification equipment such as a condensate demineralizer. The pH adjuster, which is a drug contained in the blowdown water, is removed by a desalting process of the condensate demineralizer, and then a new drug is injected separately. Removing the pH adjuster with the condensate demineralizer and injecting a new drug separately increases the ion removal load on the condensate demineralizer and increases the cost of drug injection.

  Bypassing the condensate demineralizer (condensate demineralization tower) as a method to reduce blowdown water ion removal in the condensate demineralizer and reduce the cost of injected chemicals from the steam generator blowdown water Means are disclosed in Patent Document 1.

  Patent Document 2 discloses a technology for recycling ammonia removed by a low-temperature electric regenerative desalination apparatus. In this recycling technology, cations that are concentrated simultaneously with the removed ammonia are separated and purified. It requires technology and has the disadvantage of increasing costs.

  On the other hand, in the high temperature desalination system described in patent documents 3-6, the means to carry out the electrical desalination of blowdown water in high temperature high pressure is provided.

  Since ammonia hardly becomes an ion at a high temperature, it is hardly removed in an electrodesalting system using electrophoresis. On the other hand, the ions such as cobalt, sodium, and iron to be removed can be removed because of the nature of the ions.

  For this reason, if a high temperature desalting system is used, only the impurity ions can be selectively removed from the blow-down water, and a desalting technique for leaving ammonia that is injected and adjusted to a higher concentration than the impurity ions by chemical injection is provided. Is possible.

  Thereby, the ion removal load in the condensate demineralizer can be reduced, and the cost of ammonia injection can be reduced.

JP 2000-171585 A JP 11-47560 A JP 2009-268999 A JP 2008-178826 A JP 2009-216495 A

Reactor Water Chemistry Handbook, p. 158-163, Corona, 2000

  In the high-temperature desalination system described in Patent Documents 3 to 6, the blow-down water is electrically desalted at high temperature and high pressure. By passing hot water between the electrodes and applying a voltage to the electrodes, the positive ions move in the direction of the negative electrode and the negative ions move in the direction of the positive electrode.

  Utilizing this principle of electrophoresis, making all materials heat resistant, and making the container pressure resistant, it is intended to operate at a temperature of about 300 ° C and a pressure of about 10 MPa, which are the conditions of blowdown water. It is.

  Impurities in the secondary cooling system of PWR are strongly required to have a chloride ion concentration of 100 ppb or less and a sodium concentration of 70 ppb or less in order to suppress corrosion in the steam generator.

In order to maintain this water quality, blow-down of 1 to 3% of the feed water is aimed at, and in a typical steam turbine plant, the feed water flow rate is 5200 t / h, so high temperature water of 52 to 156 t / h is treated. There is a need to. (See Non-Patent Document 1)
In the electrodeionization, a voltage of about 50 to 300 V is applied between the electrodes in order to process the above flow rate. Although it is considered to take measures against insulation in the device, the occurrence of a certain amount of leakage current is unavoidable, and the amount increases in proportion to the applied voltage.

  This power is essentially unnecessary energy, and there is a problem in that electricity is wasted at a power plant for producing electricity and the overall power generation efficiency is lowered.

  Moreover, if the reference value of the reactor water concentration is exceeded, the steam turbine plant must be stopped, and the high-temperature desalination system is required to be able to cope with a stable and sudden change in water quality.

  Therefore, the present invention has been made in consideration of the above-described circumstances, and water treatment of a steam turbine plant that requires chemical injection into the system water is performed, such as impurity ion desalting and purification load, chemical consumption such as ammonia, and heat loss. The objective is to be able to follow the changes in water quality and perform stably.

To achieve the above object, the present onset Ming, a condensate demineralizer for removing ions of condensate water on the downstream side of the condenser of the steam turbine plant, the downstream side of the condensate demineralizer, steam In a plant water treatment system comprising: a chemical injection device for injecting a pH adjusting agent to adjust pH of feed water supplied to a generation device; and an electric desalination device for purifying blowdown water from the steam generation device. The electric demineralizer separates ions from the blowdown water, generates purified water after reduced ion separation and concentrated concentrated water of ions, and the electric demineralizer. A direct current power source for ensuring a potential difference in the main body, a purified water transfer pump for transferring the purified water to a water supply system to the steam generator, a voltage of the direct current power source and a flow rate of the purified water transfer pump are controlled. Outlet for detecting a gas demineralizer controller, an inlet water quality measuring unit for detecting the conductivity of the blowdown water of the electrodeionization apparatus body inlet, the conductivity of the purified water of the electrodeionization body outlet A water quality measuring unit, wherein the electric desalinator control unit calculates a difference between the conductivity of blowdown water at the inlet of the electric desalter body and the conductivity of purified water at the outlet of the electric desalter body. in response to the increase of the value obtained by dividing the conductivity of the inlet, the increase command value for the voltage applied to the electrodeionization body to the DC power source and a flow rate command value of the to purified water transfer pump, characterized And

The present onset Ming is a control method of electrodeionization apparatus in the plant water treatment system of the steam turbine plant to perform feedwater pH adjustment to be supplied to the steam generator blowdown water electrodeionization body inlet The step of detecting the conductivity of the purified deionizer body outlet, the step of detecting the conductivity of the purified water at the outlet of the electric desalter body, the conductivity of the blowdown water at the inlet of the electric desalter body, and the outlet of the electric desalter body of the inlet of the difference between the conductivity of the purified water with an increase in the value obtained by dividing the conductivity, the command value of voltage applied to the electrodeionization body to the DC power supply to the purified water transfer pump And increasing the flow rate command value.

Furthermore, the onset Ming, a steam generator, a steam turbine driven by steam generated in the steam generator, a condenser for generating the condensate by condensing the steam discharged from the steam turbine, the A pump that feeds condensate to the steam generator, an electric desalination device that purifies blowdown water from the steam generator, and is supplied to the steam generator downstream of the condensate demineralizer. A steam turbine plant comprising a chemical injection device for injecting a pH adjusting agent for pH adjustment of feed water, wherein the electric desalting device separates ions from the blowdown water, and reduces ion separation. An electric desalter body that generates purified water and concentrated water having an ionic content, a direct current power source for ensuring a potential difference in the electric desalter body, and the purified water to the steam generator And purified water transfer pump for transferring the water supply system, the voltage and the electrical deionization apparatus control unit for controlling the flow rate of purified water transfer pump, the conductivity of the blowdown water of the electrodeionization body inlet of the DC power supply And an outlet water quality measuring unit for detecting the conductivity of the purified water at the outlet of the electric desalter body, and the electric desalinator control unit is provided with the electric desalter body. In accordance with an increase in the value obtained by dividing the difference between the conductivity of the blow-down water at the inlet and the conductivity of the purified water at the outlet of the electric desalter body by the conductivity of the inlet, the electric desalination to the DC power source command value of voltage applied to the vessel main body and increasing the flow rate command value of the to purified water transfer pump, characterized in that.

  According to the present invention, water treatment in a steam turbine plant that requires injection of chemicals into the system water is less likely to cause impurity ion desalting and purification, chemical consumption such as ammonia, and heat loss, and is stable following changes in water quality. Can be implemented.

It is a block diagram which shows the structure of 1st Embodiment of the steam turbine plant provided with the plant water treatment apparatus which concerns on this invention. It is a conceptual diagram which shows the structure of the electric desalinator main body in 1st Embodiment of the plant water treatment apparatus which concerns on this invention. It is a block diagram which shows the structure of the inlet_port | entrance and exit water quality measurement part in 1st Embodiment of the plant water treatment apparatus which concerns on this invention. It is a graph which shows the voltage dependence of the desalination rate in the electric desalinator main body for description of 1st Embodiment of the plant water treatment apparatus which concerns on this invention. It is a block diagram which shows the structure of the electrical desalination apparatus control part in 1st Embodiment of the plant water treatment apparatus which concerns on this invention. It is a figure which shows the outline of dissociation of the temperature of blowdown water at the time of starting and a stop of the steam turbine plant of 1st Embodiment of the plant water treatment apparatus which concerns on this invention, and ammonia. It is a block diagram which shows the structure of 2nd Embodiment of the steam turbine plant provided with the plant water treatment apparatus which concerns on this invention. It is a block diagram which shows the structure of 3rd Embodiment of the plant water treatment apparatus which concerns on this invention.

  Hereinafter, an embodiment of a plant water treatment system according to the present invention will be described with reference to the drawings. Here, the same or similar parts are denoted by common reference numerals, and redundant description is omitted.

[First embodiment]
FIG. 1 is a block diagram showing a configuration of a first embodiment of a steam turbine plant provided with a plant water treatment apparatus according to the present invention.

  The steam generator 1 is, for example, a boiler of a thermal power plant or a steam generator of a PWR, and generates steam. The steam generated in the steam generator 1 is sent to a steam turbine 2 having a high-pressure turbine 2a and a low-pressure turbine 2b, and heat energy is converted into mechanical energy by the high-pressure turbine 2a and the low-pressure turbine 2b. Energy is converted into electrical energy and electricity is generated.

  The condenser 4 is a seawater-cooled heat exchanger, and the steam that has worked in the steam turbine 2 is cooled and condensed by seawater in the condenser 4 to become condensed water. Condensate discharged from the condenser 4 is sent to the water supply system 20 via the condensate system 10 by the condensate pump 11.

  The condensate system 10 includes a condensate demineralizer 12, a low-pressure feed water heater 13, and a deaerator 14. The condensate demineralizer 12 removes ionic components in the condensate. The deaerator 14 is a direct contact heat exchanger, and reduces the amount of dissolved oxygen in the condensate by mixing the condensate and the heating steam.

  Condensate that exits the deaerator 14 passes through the heat exchanger 153, is pressurized by the feed water pump 21, and is sent to the steam generator 1 through the high-pressure feed water heater 22. In addition, ammonia or an amine compound is injected into the water supply system 20 as a pH adjuster of the water supply, and hydrazine is injected as an oxygen scavenger by the chemical solution injection device 23.

  From the steam generator 1, 1 to 3% of the feed water flow rate is discharged to the electric desalting apparatus 100 as blowdown water 201.

  The electrical desalting apparatus 100 is installed at the electrical desalter body 130, the DC power supply 151, the purified water transfer pump 152, the heat exchanger 153 installed in the water supply system 20, and the inlet and outlet of the electrical desalter body 130. It has an inlet water quality measurement unit 160, an outlet water quality measurement unit 170, and an electric desalination apparatus control unit 140.

  After the water quality is monitored by the inlet water quality measurement unit 160, the blow-down water 201 enters the electric demineralizer main body 130 to be purified, and purified water 202 and concentrated water 203 are generated. The purified water 202 is re-measured by the outlet water quality measurement unit 170, then fed by the purified water transfer pump 152, and returned to the water supply system 20 immediately before the steam generator 1. The concentrated water 203 is discharged out of the system via the heat exchanger 153.

  DC power having a voltage based on the control of the electric desalting apparatus control unit 140 is supplied between the electrodes installed in the electric desalter body 130 by the DC power supply 151.

  FIG. 2 is a conceptual diagram showing the configuration of the electric desalter body in this embodiment.

  The electric desalter body 130 has a housing 131, a pair of electrodes 132 and a pair of diaphragms 133 housed therein. The casing 131 receives the blow-down water 201 and concentrates the ionic component therein, and then generates this concentrated water 203 and purified water 202 from which the ionic component has been removed.

  The inside of the housing 131 is divided into three spaces by a pair of diaphragms 133 that are spaced apart from each other and arranged in parallel with each other. Among these, the central space sandwiched between the diaphragms 133 is a desalting portion 135, and a space outside the diaphragm 133 is provided with a pair of electrodes 132 extending along the side surface of the housing 131. This electrode 132 is supplied with DC power of a predetermined voltage by an external DC power supply 151.

  In the desalting unit 135, purified water 202 is generated. In the two concentrating parts 136, concentrated water 203 is generated. That is, the ionic component of the blowdown water 201 that has flowed into the desalting unit 135 is transferred to the concentration unit 136 via the diaphragm 133, so that the blowdown water 201 is separated into the purified water 202 and the concentrated water 203. The

  The diaphragm 133 is exemplified as a flat parallel arrangement, but may be concentric cylinders (cylindrical, elliptical, rectangular, etc.).

  The electric desalting apparatus control unit 140 uses the inlet water quality signal 160a that is the measurement result of the inlet water quality measurement unit 160 and the outlet water quality signal 170a that is the result of the outlet water quality measurement unit 170 to determine the voltage value of the DC power to be supplied. The applied voltage command value 140a is output to the DC power supply 151. Further, the flow rate command value 140b determined in the same manner is output to the purified water transfer pump 152.

  When the inlet water quality signal 160a shifts to the side where the water quality of the blow-down water 201 is lowered, the electric desalting apparatus control unit 140 increases the applied voltage command signal to the DC power supply 151. When the water quality is improved, the electric desalting apparatus control unit 140 reduces the applied voltage command signal to the DC power supply 151 with emphasis on efficiency.

  In the experiment of the electric desalter body 130, the voltage / current when the temperature was 280 ° C., the flow rate was 500 cc / min, and the sodium ion 10 ppb was purified 90% was 45 V, 10.5 mA.

  However, the theoretical current that flows when sodium ions move the distance between the diaphragms is about 0.01 mA, and most of them are leakage currents. Therefore, most of the applied power is leakage current, and the lower the voltage / current applied from Ohm's law, the smaller the lost power.

  Therefore, the power loss can be minimized by setting the minimum voltage / current that can achieve the target water quality of the purified water 202 from the signals of the inlet water quality measurement unit 160 and the outlet water quality measurement unit 170.

  FIG. 3 is a block diagram showing the configuration of the inlet and outlet water quality measuring units in the plant water treatment apparatus according to this embodiment.

  The first conductivity meter 162, the first pH meter 163, and the first dissolved oxygen meter are used as devices for measuring the quality of the test water cooled to about room temperature by the inlet water quality measuring unit cooler 161 of the inlet water quality measuring unit 160. 164, a first dissolved hydrogen meter 165 is arranged.

  In addition, the second conductivity meter 172, the second pH meter 173, and the second dissolved water are used as devices for measuring the quality of the test water cooled to about room temperature by the outlet water quality measuring unit cooler 171 of the outlet water quality measuring unit 170. An oxygen meter 174 and a second dissolved hydrogen meter 175 are arranged.

  The conductivity is a value that directly reflects the ion concentration, and corresponds to 0.1 μS / cm at 1 ppb. However, as described above, since ammonia easily changes to ions at high temperature and room temperature and easily ionizes at low temperature, pH is used as an index for separating the concentrations of ammonia and other ions.

  The conductivity obtained by subtracting the ammonia concentration calculated by pH is the conductivity contributed by the impurities to be removed. The dissolved oxygen concentration and dissolved hydrogen concentration are indicators of how much iron, nickel, etc. will be ionized, and if necessary, the values may be incorporated into the control.

  FIG. 4 is a graph showing the voltage dependence of the desalination rate in the electric desalter body of the plant water treatment apparatus according to the present embodiment, the temperature simulating the blowdown water 201 of the steam generator 1 of the PWR, This is a test result when the impurity concentration is about 10 ppb under pressure.

  In this experiment, the distance between the electrodes is about 5 mm to 10 mm, which is very small compared to a normal actual steam turbine plant. The horizontal axis represents the voltage applied between the electrodes, and the vertical axis represents the desalination rate calculated from the result of ion concentration measurement at the entrance and exit. By applying a voltage, the desalination rate is increased except for ammonia, and a high desalting rate can be achieved by applying a high voltage.

  For example, if the blowdown water 201 is 1% of the water supply flow rate and the conductivity of the water supply is 0.1 μS / cm, the blowdown water 201 needs to process impurities equivalent to 10 μS / cm. In the case where the efficiency of the sodium electric demineralizer main body 130 is 60 V, for example, 76%, the purified water 202 returns to the water supply system 20 again at 2.4 μS / cm.

  When this is mixed, it becomes 0.13 μS / cm. If it is carried out at 30V, the efficiency drops to 45%, down to 0.22 μS / cm. If the target value of water quality is 0.13 μS / cm or less, an efficiency of 77% is required, and 61 V is required if linearity is assumed.

  However, if the target is 0.15 μS / cm, 67% is the target, and 51V is sufficient. If the resistance is the same between 51V and 61V, the power consumption is 1.43 times different.

  Even if heat loss is minimized as high temperature electric desalination, heat loss is generated by using a high temperature desalting apparatus. Therefore, when the inlet conductivity is small, the heat loss can be reduced by reducing the pump flow rate. If the efficiency target is reduced from 76% to 67%, the flow rate should be 0.88 times, and the heat loss will also be 0.88 times.

  Thus, the heat loss can be greatly reduced by slightly reducing the target value of efficiency.

  FIG. 5 is a block diagram showing the configuration of the electrical desalting apparatus control unit in the present embodiment. The electric desalting apparatus control unit 140 includes a subtraction unit 141, a division unit 142, and a gain 143.

  The subtracting unit 141 receives the conductivity signals from the first conductivity meter 162 and the second conductivity meter 172 as input, and from the conductivity signal of the first conductivity meter 162, the second conductivity meter 172. The value obtained by subtracting the conductivity signal is output.

  The division unit 142 divides the value of the conductivity difference from the subtraction unit 141 by the value of the conductivity signal of the first conductivity meter 162 and outputs the quotient. The gain 143 multiplies the output of the division unit 142 by a predetermined value and outputs an applied voltage command value to the DC power supply 151 and a flow rate command value to the purified water transfer pump 152 side as a control signal.

  In addition, about the efficiency of the electric desalinator main body 130, the value confirmed by experiment is used as an initial value. Furthermore, more accurate control can be performed by feedback from the result of water quality measurement at the entrance / exit. The efficiency generally uses the removal rate, which corresponds to the difference in the conductivity at the outlet inlet divided by the inlet conductivity.

  FIG. 6 is a diagram showing an outline of blowdown water temperature and ammonia dissociation when the steam turbine plant according to this embodiment is started and stopped.

  At the beginning of the start of the steam turbine plant, the temperature of the feed water is low, and the temperature of the feed water increases as the start-up process proceeds. For this reason, the temperature of the blowdown water 201 from the steam generator 1 is also low at the beginning of the start of the steam turbine plant, and the temperature gradually increases.

  The ratio of ammonia to ions is about four times higher at 25 ° C than at 250 ° C. For this reason, the rate of dissociation of ammonia is large at the beginning of the plant startup, and when the electric desalination apparatus 100 is moved from the beginning of the startup of the steam turbine plant, the electric desalter body 130 removes ammonia.

  Therefore, as shown in FIG. 6, when the steam turbine plant is started, the electric desalter body 130 is kept in a standby state until the temperature exceeds 250 ° C., and water passage is gradually started after the temperature becomes high. Further, when the steam turbine plant is stopped, an operation method is adopted in which the electric desalter body 130 is operated up to 250 ° C., and the electric desalter body 130 is shifted to a standby state after the temperature becomes 250 ° C. or lower.

  With the plant water treatment system configured as described above, the voltage applied to the electric desalter body 130 is reduced as much as possible, and when the water quality deteriorates, the applied voltage is increased to suppress the electrical load. it can. In particular, by controlling the voltage applied to the electric demineralizer main body 130 using pH as an index, the concentration of ammonia and other ions can be controlled as a whole in a rational manner. Further, since ammonia water is not decomposed and ionized in the normal operation state of the steam turbine plant, it is recirculated together with the purified water, so that it is possible to maintain a state in which chemicals such as ammonia are consumed and heat loss is small. Furthermore, it is possible to avoid wasteful removal of ammonia by operating an electric desalination device especially when starting and stopping a steam turbine plant, and to carry out stable and rational water treatment following changes in water quality. it can.

  As a result, stable water treatment can be performed following the change in water quality.

[Second Embodiment]
FIG. 7: is a block diagram which shows the structure of 2nd Embodiment of the steam turbine plant provided with the plant water treatment apparatus which concerns on this invention.

  Even if a high-temperature electric desalination system is introduced, the condensate desalination apparatus 12 cannot be eliminated to prevent seawater leakage. Therefore, when the water quality is deteriorated and the conductivity is increased to affect the operation of the steam turbine plant, the condensate demineralizer 12 is used during the operation.

  For this reason, when both the inlet water quality measurement unit 160 and the outlet water quality measurement unit 170 exceed the set value, the electric demineralizer control unit 140 converts the condensate downstream of the condenser 4 into the condensate demineralizer 12. A command to pass water is issued. Specifically, a command signal is issued to open the condensate demineralizer inlet valve 12a and close the condensate demineralizer bypass valve 12b.

  Accordingly, it is possible to ensure the necessary water quality in response to an increase in the concentration of impurities brought into the steam generator 1, and to ensure a stable water treatment function following the change in the water quality.

[Third embodiment]
FIG. 8 is a block diagram showing the configuration of the third embodiment of the plant water treatment apparatus according to the present invention.

  For example, there are water quality standards for secondary cooling water in pressurized water reactors. If the water quality standard is deviated, water supply to the steam generator 1 cannot be performed, so that the normal operation state cannot be maintained, and the reactor needs to be stopped. Therefore, it is necessary to detect failure and malfunction of the high temperature desalination system at an early stage.

  For this reason, when an abnormality occurs in the high temperature desalination system, an alarm is issued to the control panel 145 in the central control room, the voltage application to the electric desalter body 130 is stopped for further safety, and the purified water is transferred. The pump 152 is stopped and the electric desalination apparatus 100 is isolated from the water supply system.

  In order to detect an abnormality, monitoring of the relationship between voltage and current is possible in addition to mechanical monitoring such as vibration of the purified water transfer pump 152. In the high-temperature desalination system, about several tens of mA per cell is planned at about 45V, so if this current is more than twice or less than half, there is a high possibility of equipment failure. Is determined.

(effect)
In the present embodiment, particularly when there is an abnormality in the electric desalination apparatus 100, a situation such as an unplanned shutdown of the steam turbine plant due to an abnormality in water quality is avoided, and a stable and rational operation is achieved. Can be realized.

[Other Embodiments]
As mentioned above, although several embodiment of this invention was described, these embodiment is shown as an example and is not intending limiting the range of invention.

  Moreover, you may combine the characteristic of each embodiment. For example, the operation of the condensate demineralizer, which is a feature of the second embodiment, may be combined with the first embodiment. In the first and second embodiments, an alarm on the control panel, which is a feature of the third embodiment, may be added.

  Furthermore, these embodiments can be implemented in various other forms, and various omissions, replacements, and changes can be made without departing from the scope of the invention. These embodiments and their modifications are included in the scope and gist of the invention, and are also included in the invention described in the claims and the equivalents thereof.

1 ... Steam generator (steam generator)
DESCRIPTION OF SYMBOLS 2 ... Steam turbine 2a ... High pressure turbine 2b ... Low pressure turbine 3 ... Generator 4 ... Condenser 10 ... Condensate system 11 ... Condensate pump 12 ... Condensate Demineralizer 12a ... Condensate demineralization tower inlet valve 12b ... Condensate demineralization tower bypass valve 13 ... Low-pressure feed water heater 14 ... Deaerator 20 ... Feed water system 21 ... Water supply pump 22 ・ ・ ・ High pressure feed water heater 23 ・ ・ ・ Chemical liquid injection device 100 ・ ・ ・ Electrical desalination device 130 ・ ・ ・ Electrical desalter body 131 ・ ・ ・ Case 132 ・ ・ ・ Electrode 133 ・ ・ ・ Diphragm 135 ・ ・ ・ Desalination unit 136 ・ ・ ・ Concentration unit 140 ・ ・ ・ Electrical desalination apparatus control unit 140 a ・ ・ ・ Applied voltage command value 140 b ・ ・ ・ Flow rate command value 141 ・ ・ ・ Subtraction unit 142 ・ ・ ・ Division unit 143: Gain 145: Control panel 15・ ・ ・ DC power supply 152 ・ ・ ・ Purified water transfer pump 153 ・ ・ ・ Heat exchanger 160 ・ ・ ・ Inlet water quality measurement unit 160a ・ ・ ・ Inlet water quality signal 161 ・ ・ ・ Inlet water quality measurement unit cooler 162 ・ ・ ・ No. 1 conductivity meter 163... First pH meter 164... First dissolved oxygen meter 165... First dissolved hydrogen meter 170... Outlet water quality measuring unit 170 a.・ ・ ・ Exit water quality measuring unit cooler 172 ・ ・ ・ Second conductivity meter 173 ・ ・ ・ Second pH meter 174 ・ ・ ・ Second dissolved oxygen meter 175 ・ ・ ・ Second dissolved hydrogen meter 201 ..Blowdown water 202 ... Purified water 203 ... Concentrated water

Claims (8)

A condensate demineralizer that removes ions in the condensate downstream of the condenser of the steam turbine plant;
On the downstream side of the condensate demineralizer, a chemical injection device for injecting a pH adjusting agent for adjusting the pH of the feed water supplied to the steam generator;
An electrical desalination device for purifying blowdown water from the steam generator;
In a plant water treatment system comprising:
The electric desalination apparatus is:
An electric demineralizer main body that separates ions from the blowdown water, and generates purified water after ion separation reduction and concentrated water concentrated with ions;
A DC power source for securing a potential difference in the electric desalter body;
A purified water transfer pump for transferring the purified water to a water supply system to the steam generator;
An electric desalination device controller that controls the voltage of the DC power supply and the flow rate of the purified water transfer pump;
An inlet water quality measurement unit for detecting conductivity of the blowdown water at the electric desalter body inlet;
An outlet water quality measurement unit for detecting conductivity of the purified water at the electric desalter body outlet;
With
The electric desalination apparatus control unit is a value obtained by dividing the difference between the electrical conductivity of the blow-down water at the electrical desalter body inlet and the conductivity of the purified water at the electrical desalter body outlet by the electrical conductivity of the inlet. according to an increase of, increasing the flow rate command value of the command value of voltage applied to the electrodeionization body to the DC power supply to the purified water transfer pump,
A plant water treatment system characterized by that. The electric demineralizer controller controls the condensate when the electrical conductivity of the blow-down water at the electric desalter main body inlet and the conductivity of the purified water at the electric desalter main body outlet exceed predetermined values. The plant water treatment system according to claim 1, wherein a signal for opening a condensate demineralizer inlet valve and a command for closing a condensate demineralizer bypass valve are output to the desalting apparatus . In the starting process of the steam turbine plant, the electric demineralizer control unit initially stops power supply from the DC power source to the electric demineralizer, and the temperature of the blow-down water at the inlet of the electric demineralizer main body 3. The plant water treatment system according to claim 1 , wherein a command signal is output to the DC power supply so as to supply electric power when the value rises and reaches a predetermined value . The electric demineralizer control unit stops the power supply when the temperature of the blow-down water at the electric demineralizer main body inlet decreases and reaches a predetermined value in the process of stopping the steam turbine plant. The plant water treatment system according to any one of claims 1 to 3 , wherein a command signal is output to the DC power supply. Further comprising means for measuring the voltage applied to the electric desalter body,
When the measured voltage applied to the electric demineralizer body exceeds a predetermined value, the electric desalination device controller stops power supply from the DC power supply and stops the purified water transfer pump. and the electrodeionization apparatus so as to isolate from the feed water system, plant water treatment system according to any one of claims 1 to 4, characterized in that issues a command signal. The electric desalter body is
A housing,
A pair of diaphragms that are spaced apart from each other, each partitioning a space in the housing;
A pair of electrodes disposed outside the diaphragm;
And a desalinating section surrounded by the pair of diaphragms and the casing, and two concentrating sections surrounded by the respective diaphragms and the casing are formed in the casing. Being
The plant water treatment system according to any one of claims 1 to 5 characterized by things .   A control method for an electrical desalination apparatus in a plant water treatment system of a steam turbine plant that adjusts the pH of feed water supplied to a steam generator,
  Detecting the conductivity of the blow-down water at the electric desalter body inlet;
  Detecting the conductivity of purified water at the outlet of the electric desalter body;
  In accordance with an increase in the value obtained by dividing the difference between the conductivity of the blow-down water at the inlet of the electric desalter main body and the conductivity of the purified water at the outlet of the electric desalter main body by the conductivity of the inlet, the DC power supply Increasing the command value of the applied voltage to the electric demineralizer main body and the flow rate command value to the purified water transfer pump;
  A method for controlling an electrical desalting apparatus, comprising:   A steam generator;
  A steam turbine driven by steam generated by the steam generator;
  A condenser for condensing steam discharged from the steam turbine to generate condensate;
  A pump for feeding the condensate to the steam generator;
  An electrical desalination device for purifying blowdown water from the steam generator;
  On the downstream side of the condensate demineralizer, a drug injector for injecting a pH adjuster for adjusting the pH of the feed water supplied to the steam generator;
  A steam turbine plant comprising:
  The electric desalination apparatus is:
  An electric demineralizer main body that separates ions from the blowdown water, and generates purified water after ion separation reduction and concentrated water concentrated with ions;
  A DC power source for securing a potential difference in the electric desalter body;
  A purified water transfer pump for transferring the purified water to a water supply system to the steam generator;
  An electric desalination device controller that controls the voltage of the DC power supply and the flow rate of the purified water transfer pump;
  An inlet water quality measurement unit for detecting conductivity of the blowdown water at the electric desalter body inlet;
  An outlet water quality measurement unit for detecting conductivity of the purified water at the electric desalter body outlet;
  With
  The electric desalination apparatus control unit is a value obtained by dividing the difference between the electrical conductivity of the blow-down water at the electrical desalter body inlet and the conductivity of the purified water at the electrical desalter body outlet by the electrical conductivity of the inlet. In response to the increase in the increase in the command value of the voltage applied to the electric demineralizer body to the DC power supply and the flow rate command value to the purified water transfer pump,
  A steam turbine plant characterized by that.

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