JP5709710B2 - Infrared light reflection layer, infrared light reflection plate, laminated interlayer sheet for glass and laminated glass, and methods for producing them - Google Patents

Description

  The present invention relates to an infrared light reflection plate having a plurality of light reflection layers formed by fixing a cholesteric liquid crystal phase, and mainly relates to an infrared light reflection plate used for heat insulation of windows of buildings and vehicles. The present invention also provides an infrared light reflecting layer obtained by removing the substrate from the infrared light reflecting plate, the infrared light reflecting layer, or a laminated intermediate for infrared light reflecting laminated glass using the infrared light reflecting plate. The present invention relates to a film sheet, a laminated glass using the laminated interlayer film sheet for glass, and a method for producing them.

  In recent years, there has been a great need for industrial products related to energy conservation due to increased interest in the environment and energy, and as one of them, it is effective in reducing the heat load of window glass of houses and automobiles, that is, the heat load caused by sunlight There is a need for glass and film. In order to reduce the heat load due to sunlight, it is necessary to prevent the transmission of sunlight in either the visible light region or the infrared region of the sunlight spectrum.

  A multi-layer glass coated with a special metal film that cuts off heat radiation, called Low-E pair glass, is often used as eco-glass with high heat insulation and heat shielding properties. The special metal film can be manufactured by laminating a plurality of layers by, for example, a vacuum film forming method. Although these special metal film coatings produced by vacuum film formation have excellent reflection performance, the vacuum process has low productivity and high production cost. In addition, when a metal film is used, electromagnetic waves are simultaneously shielded. Therefore, when a mobile phone or the like is used, there are problems such as causing a radio wave interference or making the ETC unusable when used in an automobile.

  Actually, it is difficult to completely reflect light of a specific wavelength by using a light reflection film having a light reflection layer in which a cholesteric liquid crystal phase is fixed. It is common to use a special retardation plate such as a retardation plate (hereinafter also referred to as λ / 2 plate) having λ or a λ / 4 plate. For example, in Patent Documents 1 and 2, a light reflecting layer having an optical rotation in the same direction and having the same helical pitch and having a fixed cholesteric liquid crystal phase is provided with a phase difference of ½ wavelength. Attempts have been made to reflect right circularly polarized light and left circularly polarized light having a predetermined wavelength by forming them on both surfaces of the phase difference plate, respectively. Specifically, Patent Document 1 discloses a laminated optical film having a retardation film having a predetermined characteristic and a reflective circularly polarizing plate and having reflectivity with respect to infrared rays. As the retardation film, a cholesteric liquid crystal phase is disclosed. An example using is disclosed. Patent Document 2 discloses an infrared light reflective article including a visible light transmissive substrate and an infrared light reflective cholesteric liquid crystal layer.

  Usually, a retardation plate having a phase difference of ½ wavelength acts as a phase difference plate having a phase difference of ½ wavelength with respect to light incident from the normal direction to the layer surface. Strictly speaking, it does not function as a retardation plate having a half-wave phase difference.

  In addition, the cholesteric liquid crystal layer has a feature that the reflected wavelength band changes depending on the angle of incident light (when the incident angle becomes oblique, the reflection band shifts to the short wavelength side), so it is intended for infrared light reflection. Even in the cholesteric liquid crystal layer, it becomes visible light reflective in an oblique direction, and the reflected light may be reddish to yellowish. When such an infrared light reflective article having a cholesteric liquid crystal layer is used for a window glass of, for example, a house or an automobile, problems such as a reduction in visibility as a window glass and restrictions on appearance design occur.

As a method of improving the reflection of incident light from such an angle, Patent Document 3 describes that the transmittance of incident light differs depending on the incident angle of the incident light, and the shielded light is reflected without being absorbed. The condensing element has transmission characteristics for incident light in the visible region in the normal direction, has a reflection wavelength band in the infrared region, and reflects as the incident angle with respect to the normal direction increases. An optical element is described in which an infrared reflective layer whose wavelength band changes to the short wavelength side is disposed. According to Patent Document 3, such a configuration efficiently reflects obliquely transmitted light including a long wavelength range toward the light source without impairing transmission polarization characteristics of normal incident light that contributes to front luminance, and It is described that the reflected polarized light can be converted into light that can contribute to improvement of front luminance.
Further, in Patent Document 4, in the wavelength region of 800 nm to 1900 nm, by providing a cholesteric liquid crystal layer whose cholesteric regularity is adjusted so that a band reflecting 40% or more of incident light has 200 nm or more, a solar energy amount is provided. Describes a heat insulating member that can increase the reflectance of infrared rays in the wavelength region of about 900 to about 1300 nm, which is high, and can increase the light transmittance in the visible light region.

Japanese Patent No. 4109914 Special table 2009-514022 gazette JP 2004-309618 A JP 2010-256625 A

However, when reflection of incident light from an oblique direction was studied for a light reflection plate using a light reflection layer formed by fixing a cholesteric liquid crystal phase described in Patent Documents 3 and 4, the color change of reflected light in an oblique direction was examined. From the viewpoint of suppression, dissatisfaction still remains, and it has been found that the suppression of the color change of the reflected light in the oblique direction and the high heat shielding performance (solar reflectance) cannot be achieved at the same time.
As described above, the problem to be solved by the present invention is to provide an infrared light reflection layer and an infrared light reflection plate that can suppress the color of reflected light in an oblique direction and have high heat shielding properties. Furthermore, it is providing the manufacturing method of an infrared-light reflecting plate which can manufacture the infrared-light reflecting plate which satisfy | fills such a characteristic at low cost.

As a result of intensive studies by the present inventors to solve the above problems, it is possible to control the reflectance at the wavelength of 790 nm while increasing the wavelength of 1240 nm, the wavelength of 1040 nm, and the wavelength of 875 nm. It came to discover that it had a big influence on coexistence of suppression and thermal insulation performance. Controlling the reflectance at such a specific wavelength has not been studied in the past, and the light reflectors described in Patent Documents 3 and 4 actually do not satisfy the reflectance at such a specific wavelength. . Patent Document 3 describes that an infrared reflection layer having a reflection wavelength in the vicinity of a wavelength of 790 nm at the time of vertical incidence is preferable in order to cut a wavelength in an oblique 45 ° direction. Further, Patent Document 4 has an aspect having a cholesteric liquid crystal layer in which cholesteric regularity is adjusted so that a band reflecting 40% or more of incident light has a wavelength of 200 nm or more in a wavelength region of 750 to 2000 nm (or 800 to 2000 nm). It has only been disclosed, and nothing has been said about the method or mode for reducing the reflectance at 790 nm. In fact, Example 1 of Patent Document 4 reflects near infrared light by 40% or more in the band of 990 to 1226 nm, Example 2 in the band of 838 to 1250 nm, and Example 3 in the band of 944 to 1258 nm. Although the heat insulation film was described, there was no description about the reflectance of the wavelength of 790 nm.
Under these circumstances, as a result of further studies by the present inventor, the reflectance at a wavelength of 1240 nm, a wavelength of 1040 nm and a wavelength of 875 nm is set to a specific range or more, and the reflectance at a wavelength of 790 nm is controlled to a specific range or less. As a result, it was found that high heat shielding performance can be obtained while suppressing the color change of the reflected light in the oblique direction. Based on these findings, the present invention has been completed.

Means for solving the above problems are as follows.
[1] It has a light reflecting layer formed by fixing a cholesteric liquid crystal phase, has a reflectance of 40% or more at a wavelength of 1240 nm, a reflectance of 40% or more at a wavelength of 1040 nm, and a reflectance at a wavelength of 875 nm. Is an infrared light reflection layer characterized by having a reflectance of 40% or more, a reflectance at a wavelength of 790 nm of 10% or less, and reflecting infrared rays.
[2] The infrared light reflection layer according to [1] includes a light reflection layer X1, a light reflection layer X2, and a light reflection layer X3 each formed by fixing a cholesteric liquid crystal phase; The reflection center wavelength λ1 (nm) is in the range of 1190 to 1290 nm; the reflection center wavelength λ2 (nm) of the light reflection layer X2 is in the range of 1010 to 1070 nm; the reflection center wavelength λ3 (nm) of the light reflection layer X3 ) Is preferably in the range of 850 to 900 nm.
[3] The infrared light reflecting layer according to [1] or [2] is a liquid crystal composition in which at least one of the light reflecting layers is laminated on the surface of the lower light reflecting layer. A layer formed by fixing a cholesteric liquid crystal phase to a cholesteric liquid crystal phase is preferable.
[4] In the infrared light reflection layer according to any one of [1] to [3], the spiral direction of one of the light reflection layers is different from that of the other two light reflection layers. The direction is preferably different from the spiral direction.
[5] The infrared light reflecting layer according to any one of [1] to [4] is preferably a direction in which the spiral direction of the adjacent light reflecting layers is different among the light reflecting layers.
[6] An infrared light reflection plate comprising the substrate and the infrared light reflection layer according to any one of [1] to [5] disposed on at least one surface of the substrate. .
[7] In the infrared light reflector according to [6], the substrate is preferably a polymer film.
[8] In the infrared light reflecting plate according to [6] or [7], it is preferable that the substrate is a retardation plate having a phase difference of ½ wavelength.
[9] The infrared light reflecting layer according to any one of [1] to [5] or the infrared light reflecting plate according to any one of [6] to [8], and the infrared light A laminated interlayer film sheet for glass, comprising: an interlayer film sheet disposed on at least one outermost layer of the reflective layer or the infrared light reflector.
[10] The laminated interlayer film for glass according to [9] preferably has an interlayer sheet on the outermost layers of both the infrared light reflection layer and the infrared light reflection plate.
[11] A laminated glass comprising two sheets of glass and the laminated interlayer sheet for glass according to [9] or [10] disposed between the two sheets of glass.
[12] In the laminated glass according to [11], at least one of the two glasses is a heat ray absorbing glass, and the heat ray absorbing glass has a visible light transmittance of 80 to 90% with a standard A light source. It is preferable that the dominant wavelength measured using a standard A light source is in the range of 495 to 560 nm.
[13] First to obtain a first laminate by bonding a first intermediate film to one surface of the infrared light reflector according to any one of [6] to [8]. Including a step and a second step of bonding a second interlayer sheet on the surface of the first laminate opposite to the surface on which the first interlayer sheet is bonded. A method for producing a laminated interlayer film sheet for laminated glass.
[14] The method for producing a laminated interlayer sheet for glass according to [13] uses the infrared light reflecting plate in which a substrate is disposed only on one surface as the infrared light reflecting plate. The step of bonding the first interlayer film sheet to the surface of the infrared light reflector opposite to the surface on which the substrate is disposed, the infrared light reflector and the first Including the step of peeling the substrate contained in the infrared light reflector from the first laminate simultaneously with or after the step of laminating the intermediate film sheet, and the second step includes the second step. It is preferable to include the process of bonding an intermediate film sheet to the surface of the first laminate from which the substrate has been peeled off.
[15] A step of manufacturing a laminated body sandwiched between two glass plates by sandwiching the laminated interlayer film for glass according to [9] or [10] between two glass plates, and a laminate sandwiched between the glass plates The manufacturing method of a laminated glass including the process of crimping | bonding a body, heating.
[16] The infrared light reflecting layer according to any one of [1] to [5], the infrared light reflecting plate according to any one of [6] to [8], [9] or [ [10] A laminated interlayer film for glass according to [10], or a window member for buildings or vehicles using the laminated glass according to [11] or [12].

  ADVANTAGE OF THE INVENTION According to this invention, the tint change of the reflected light of an oblique direction can be suppressed, and the infrared-light reflection layer and infrared light reflecting plate with high heat-shielding property can be provided.

It is sectional drawing of an example of the infrared-light reflecting plate of this invention. It is sectional drawing of an example of the infrared-light reflecting plate of this invention. It is sectional drawing of an example of the infrared-light reflecting plate of this invention. It is sectional drawing of an example of the infrared-light reflecting plate of this invention. It is sectional drawing of an example of the infrared-light reflecting plate of this invention. It is the graph which showed intensity distribution of sunlight energy.

  Hereinafter, the present invention will be described in detail. The description of the constituent elements described below may be made based on typical embodiments of the present invention, but the present invention is not limited to such embodiments. In the present specification, a numerical range represented by using “to” means a range including numerical values described before and after “to” as a lower limit value and an upper limit value. In this specification, the laminate sandwiched between glass plates is a laminate of glass plate / intermediate film / infrared light reflecting layer (or infrared light reflecting plate) / intermediate film / glass plate in this order. It means that before being pressure-bonded with heating. Moreover, a laminated glass means what was crimped | bonded, heating the laminated body pinched | interposed into the said glass plate.

In the present specification, the refractive index anisotropy Δn of the layer formed by fixing the cholesteric liquid crystal phase is defined as follows.
In the present specification, the refractive index anisotropy Δn of a layer formed by fixing a cholesteric liquid crystal phase means Δn at a wavelength exhibiting selective reflection characteristics (specifically, near a wavelength of 1000 nm). Specifically, first, as a sample, a layer on which a cholesteric liquid crystal phase in which the helical axis is uniformly oriented with respect to the film surface is fixed is formed on a substrate (glass, film) subjected to orientation treatment or provided with an orientation film. To do. The selective reflection of the layer is measured, and the peak width Hw is obtained. Further, the spiral pitch p of the sample is separately measured. The helical pitch can be measured by observing a cross-section TEM. By substituting these values into the following equation, the refractive index anisotropy Δn of the sample can be obtained.
Δn = Hw / p

Further, in this specification, the “reflection center wavelength” refers to a wavelength indicating the maximum peak of the reflection spectrum measured from the front direction (substantially, the direction within 5 ° from the front).
Further, in the present specification, regarding “the reflection center wavelengths are substantially equal (to each other)” of each layer, it is a matter of course that an error generally allowed in the technical field to which the present invention belongs is considered. In general, even if there is a difference of about ± 30 nm with respect to the reflection center wavelength, it is considered to be substantially equal, preferably within ± 20 nm, and more preferably within ± 10 nm.

[Infrared light reflection layer, infrared light reflection plate]
The infrared light reflection layer of the present invention has a light reflection layer formed by fixing a cholesteric liquid crystal phase, and has a reflectance of 40% or more at a wavelength of 1240 nm and a reflectance of 40% or more at a wavelength of 1040 nm. The reflectance at a wavelength of 875 nm is 40% or more, the reflectance at a wavelength of 790 nm is 10% or less, and infrared rays are reflected. With such a configuration, the color of reflected light in an oblique direction can be suppressed, and an infrared light reflection layer having high heat shielding properties can be provided.

In the infrared light reflection layer of the present invention, the reflectance at a wavelength of 1240 nm is preferably 42% or more, more preferably 44% or more, and particularly preferably 45% or more.
The infrared light reflective layer of the present invention preferably has a reflectance at a wavelength of 1040 nm of 42% or more, more preferably 44% or more, and particularly preferably 45% or more.
In the infrared light reflection layer of the present invention, the reflectance at a wavelength of 875 nm is preferably 42% or more, more preferably 44% or more, and particularly preferably 45% or more.
The infrared light reflective layer of the present invention preferably has a reflectance at a wavelength of 790 nm of 8% or less, more preferably 7% or less, and particularly preferably 6% or less.

  Moreover, the infrared light reflection plate of the present invention includes a substrate and the infrared light reflection layer of the present invention disposed on at least one surface of the substrate.

The infrared light reflection plate of the present invention may be used by being integrated with another support member such as laminated glass. At that time, the substrate may be integrated with the other supporting member together with the light reflecting layer, or the light reflecting layer may be integrated with the supporting member by peeling the substrate. That is, the infrared light reflection plate of the present invention may or may not include a substrate. For example, the infrared light reflection plate includes a substrate sandwiched between two laminated glass interlayer films. Non-infrared light reflecting layers are also included in the present invention. In particular, the infrared light reflector of the present invention is not limited to the total film thickness, but from the viewpoint of vitrification, the total film thickness is preferably 160 μm or less, more preferably 110 μm or less, and 100 μm or less. It is particularly preferred. From the viewpoint of reducing the total film thickness, an infrared light reflection layer that does not include a substrate or an infrared light reflection plate in which the number of substrates is reduced by laminating light reflection layers on both sides of the substrate is also preferable. In particular, when the infrared light reflection plate of the present invention includes a phase difference plate having a ½ wavelength phase difference, a light reflection layer is laminated on both sides of the phase difference plate having a ½ wavelength phase difference, It is preferable to use an infrared light reflection plate from which the substrate used for laminating the reflective layer is peeled off.
Hereinafter, preferred embodiments of the present invention will be described. The points common to the infrared light reflecting plate of the present invention and the infrared light reflecting layer of the present invention will be described in the description of the infrared light reflecting plate of the present invention.

<Configuration of infrared light reflection layer and infrared light reflection plate>
The infrared light reflection layer of the present invention has a light reflection layer formed by fixing a cholesteric liquid crystal phase. There is no restriction | limiting in the lamination | stacking number of the light reflection layer formed by fixing the said cholesteric liquid crystal phase, For example, it can be set as 1-10 layers, 2-8 layers are preferable, 3-8 layers are especially preferable, 3-6 layers Is more particularly preferred.

The infrared light reflecting plate of the present invention may have a structure in which a light reflecting layer is laminated only on one surface of the substrate, or a structure in which light reflecting layers are laminated on both surfaces of the substrate. May be. Moreover, the aspect which has 2 or more sets of light reflection layers which show a substantially equal reflection center wavelength may be sufficient.
The infrared light reflection plate of the present invention is also preferably an embodiment in which two sets of infrared light reflection plates having a structure in which a light reflection layer is laminated only on one surface of a substrate are laminated on both surfaces of another substrate, In that case, it is preferable that the other substrate is a phase difference plate having a phase difference of ½ wavelength. Furthermore, in that case, it is more preferable that the substrate is peeled from the formed infrared light reflection plate to have a structure of a light reflection layer / a retardation plate / light reflection layer having a phase difference of ½ wavelength.

  In the infrared light reflecting layer of the present invention, a liquid crystal composition in which at least one of the light reflecting layers is laminated on the surface of the lower light reflecting layer is used as a cholesteric liquid crystal phase, and the cholesteric liquid crystal phase is used. A layer formed by fixing is preferable.

The infrared light reflection layer of the present invention has a light reflection layer X1, a light reflection layer X2, and a light reflection layer X3 each having a fixed cholesteric liquid crystal phase; the reflection center wavelength λ1 (nm) of the light reflection layer X1 ) Is in the range of 1190 to 1290 nm; the reflection center wavelength λ2 (nm) of the light reflection layer X2 is in the range of 1010 to 1070 nm; the reflection center wavelength λ3 (nm) of the light reflection layer X3 is 850 to 900 nm It is preferable to be in the range.
In this case, in the infrared light reflection layer of the present invention, the spiral direction of one of the light reflection layers may be different from the spiral direction of the other two light reflection layers.

  Hereinafter, preferred embodiments of the infrared light reflection layer and the infrared light reflection plate of the present invention will be described with reference to the drawings. However, the mode of the cholesteric liquid crystal layer of the infrared light reflector of the present invention is not limited to the mode shown in FIGS.

  The infrared light reflecting plate shown in FIG. 1 has a light reflecting layer X1 (hereinafter also referred to as light reflecting layer 14a) and a light reflecting layer X2 (hereinafter referred to as light reflecting layer 14a) formed by fixing a cholesteric liquid crystal phase on one surface of the substrate 12, respectively. , Also referred to as a light reflection layer Xa (hereinafter also referred to as a light reflection layer 18a. However, in the present invention, the stacking order of the light reflection layers 14a, 16a and 18a from the substrate 12 is particularly It is not limited, The infrared light reflection board of the lamination | stacking order other than the order described in FIG. 1 is also contained in this invention.

The infrared light reflection layer and the infrared light reflection plate of the present invention have a reflectance of 10% or less at a wavelength of 790 nm and are also characterized by reflecting infrared light.
In the infrared light reflection plate 10 shown in FIG. 1, the center wavelength λ ₁₄ of selective reflection by the light reflection layer 14a is in the range of 1190 to 1290 nm, and the center wavelength λ ₁₆ of selective reflection by the light reflection layer 16a is 1010-10. The center wavelength λ ₁₈ of selective reflection by the light reflecting layer 18a is in the range of 850 to 900 nm. Infrared reflection efficiency may be improved by using three light reflecting layers each having a selective reflection wavelength in the above range. As a result, the heat shielding property is further improved as compared with the infrared light reflector having the same configuration. As shown in FIG. 9, the spectral distribution of solar energy intensity shows a general tendency that the shorter the wavelength, the higher the energy, but the spectral distribution in the infrared wavelength region includes wavelengths of 950 to 1130 nm and wavelengths. There are two energy intensity peaks at 1130 to 1350 nm. As a result of intensive studies by the present inventors, a light reflection layer having a selective reflection center wavelength in the range of 1010 to 1070 nm (more preferably 1020 to 1060 nm) and a selective reflection center wavelength of 1190 to 1290 nm (more preferably By utilizing the light reflection layer in the range of 1200 to 1280 nm, light corresponding to the two peaks can be reflected more efficiently, and as a result, the heat shielding property can be further improved.
In addition, for the region of wavelength 950 nm or less, it is recognized that the heat shielding property is improved as the reflection wavelength band is closer to the short wavelength, but when the reflection wavelength band is in the visible light region, the reflected light is tinted. Is a problem. In the present invention, the reflection wavelength position on the short wave side is set to 790 nm or more in consideration of observation from an oblique direction (a normal observation condition is assumed to be inclined to about 60 ° from the normal direction) (details) Is controlled to have a reflectance of 10% or less at a wavelength of 790 nm), thereby suppressing the color of the reflected light.
In order to achieve both suppression of the color of the reflected light and improvement of the heat shielding property, the center wavelength λ ₁₈ of selective reflection of the light reflecting layer 18a is preferably in the range of 850 to 900 nm (more preferably 850 to 880 nm).

The helical pitch of the cholesteric liquid crystal phase exhibiting the reflection center wavelength is generally about 760 to 840 nm at the wavelength λ ₁₄ , about 650 to 690 nm at the wavelength λ ₁₆ , and about 550 to 580 nm at the wavelength λ ₁₈ .
The thickness of each light reflecting layer is about 1 μm to 8 μm (preferably about 3 to 7 μm). However, it is not limited to these ranges. A light reflecting layer having a desired helical pitch can be formed by adjusting the type and concentration of materials (mainly liquid crystal material and chiral agent) used for forming the layer. Moreover, the thickness of a layer can be made into a desired range by adjusting the application quantity.

In FIG. 2, sectional drawing of the infrared-light reflecting plate of the other embodiment of this invention is shown. 2 has a light reflection layer X1 (light reflection layer 14a), a light reflection layer X2 (light reflection layer 16b), and a light reflection layer X3 (light reflection layer) on one surface of the substrate 12. Layer 18a). Here, the light reflection layer 16b indicates that the reflection center wavelength is substantially equal to the light reflection layer 16a of the infrared light reflection plate 10 shown in FIG. 1, and the spiral direction of the cholesteric liquid crystal phase is opposite.
As a result of various studies by the present inventor, it is empirical data, but when the layers having different spiral directions of the cholesteric liquid crystal phase are combined, there is almost no difference in the reflection spectrum measured from the front direction. It has been found that the measurement results in a difference in the reflection spectrum, improving the heat shielding performance. For transmitted light from an oblique angle, the reflection wavelength of the light reflection layer is shifted to the short wave side while expanding the reflection band, so that the ratio of overlapping with the reflection wavelength band of the adjacent light reflection layer increases. Conceivable. When the spiral directions of the cholesteric liquid crystal phases of the adjacent light reflecting layers are the same, it is considered that the heat shielding efficiency is impaired due to the overlapping reflection wavelength bands. On the other hand, when the spiral directions of the cholesteric liquid crystal phases of the adjacent light reflecting layers are different, even if the reflection wavelength bands overlap, the reflected circularly polarized light components are different, which substantially impairs the heat shielding efficiency. There seems to be no.
In the present invention, the light reflecting layer having a different cholesteric liquid crystal phase spiral direction is not limited to the light reflecting layer X2, and may be either the light reflecting layer X1 or the light reflecting layer X3, and the stacking order thereof is also particularly limited. Is not to be done. The stacking order is preferably a configuration in which layers having different spiral directions of cholesteric liquid crystal phases are adjacent to each other (a configuration in which different spiral directions are alternated).

  In FIG. 3, sectional drawing of the infrared-light reflecting plate of the other embodiment of this invention is shown. Infrared light in which an adhesive 32 is pasted on the substrate 12 of the infrared light reflecting plate 10 shown in FIG. 1 and pasted on both surfaces of a wave plate (λ / 2 plate) 22 having a phase difference of ½ wavelength. It is a reflector. By sticking the same infrared light reflection plate 10 on both surfaces of the λ / 2 plate 22, right circularly polarized light and left circularly polarized light having a predetermined wavelength can be reflected, and the heat shielding performance can be greatly improved. . It is possible to produce an infrared light reflecting plate with high heat shielding performance only by preparing one kind of infrared light reflecting plate, which is a manufacturing method that is extremely advantageous with respect to the load on the manufacturing process and the manufacturing cost. .

  In FIG. 4, sectional drawing of the infrared-light reflecting plate of the other embodiment of this invention is shown. 1 is an infrared light reflecting plate in which an adhesive 32 is attached to the light reflecting layer 14a of the infrared light reflecting plate 10 shown in FIG. By exfoliating the substrate 12, the total film thickness as an infrared light reflector can be considerably reduced, and handling and processing suitability in subsequent processing steps (processing to a laminated interlayer sheet for glass and laminated glass). Will improve. The order of the light reflecting layers is reversed from that of the original infrared light reflecting plate 10, but it can be dealt with by preparing an infrared light reflecting plate having the original order reversed.

In FIG. 5, sectional drawing of the infrared-light reflecting plate of the other embodiment of this invention is shown. The λ / 2 plate 22 is used as a substrate, and light reflection layers 18a, 16a, and 14a are installed on both sides thereof.
Compared to FIG. 4, the adhesive 32 is not used, and the total film thickness as the infrared light reflection plate can be made thinner. However, since the λ / 2 plate 22 is used as a substrate, the light reflecting layer is manufactured by a method in which the light reflecting layer is sequentially laminated on both surfaces of the base material, which increases the manufacturing process load and manufacturing cost. Conceivable.

(Other aspects)
In addition, the infrared light reflector of the present invention may be used in combination with other infrared light reflectors for the purpose of broadening the reflection wavelength. Moreover, you may have the light reflection layer which reflects the light of a predetermined wavelength by principles other than the selective reflection characteristic of a cholesteric liquid crystal phase. Examples of the members that can be combined include the composite film described in JP-A-4-504555, each layer constituting the composite film, and the multilayer laminate described in JP-A-2008-545556.

  In addition, the infrared reflector of the present invention has, of course, selective reflection characteristics adapted to the respective wavelength regions with respect to infrared wavelength regions (for example, 1400 to 2500 nm) other than the above two peak spectra. Also good. For example, by further laminating a light reflecting layer formed by fixing a cholesteric liquid crystal phase, in particular, a light reflecting layer formed by fixing cholesteric liquid crystal phases opposite to each other in optical rotation (that is, right or left optical rotation), The selective reflection wavelength region can be broadened, and the heat shielding performance can be further improved.

<Material of each layer>
Next, preferable examples such as materials used for producing the infrared light reflection plate of the present invention will be described in detail.
1. Light Reflecting Layer Forming Material In the infrared light reflecting plate of the present invention, it is preferable to use a curable liquid crystal composition for forming each light reflecting layer. A preferred example of the liquid crystal composition contains at least a rod-like liquid crystal compound, an optically active compound (chiral agent), and a polymerization initiator. Two or more of each component may be included. For example, a polymerizable liquid crystal compound and a non-polymerizable liquid crystal compound can be used in combination. Also, a combination of a low-molecular liquid crystal compound and a high-molecular liquid crystal compound is possible. Furthermore, in order to improve alignment uniformity, coating suitability, and film strength, it contains at least one selected from various additives such as a horizontal alignment agent, a non-uniformity inhibitor, a repellency inhibitor, and a polymerizable monomer. May be. Further, in the liquid crystal composition, a polymerization inhibitor, an antioxidant, an ultraviolet absorber, a light stabilizer, a colorant, metal oxide fine particles, and the like are added in a range that does not deteriorate the optical performance, if necessary. Can be added.

(1) Liquid crystal compound The liquid crystal compound usable in the present invention may be a so-called rod-like liquid crystal compound or a discotic liquid crystal compound, and is not particularly limited. Among these, a rod-like liquid crystal compound is preferable.
Examples of the rod-like liquid crystal compound that can be used in the present invention are rod-like nematic liquid crystal compounds. Examples of the rod-like nematic liquid crystal compounds include azomethines, azoxys, cyanobiphenyls, cyanophenyl esters, benzoates, cyclohexanecarboxylic acid phenyl esters, cyanophenylcyclohexanes, cyano-substituted phenylpyrimidines, alkoxy-substituted Phenylpyrimidines, phenyldioxanes, tolanes and alkenylcyclohexylbenzonitriles are preferably used. Not only low-molecular liquid crystal compounds but also high-molecular liquid crystal compounds can be used.

The rod-like liquid crystal compound used in the present invention may be polymerizable or non-polymerizable. The rod-like liquid crystal compound having no polymerizable group is described in various documents (for example, Y. Goto et.al., Mol. Cryst. Liq. Cryst. 1995, Vol. 260, pp. 23-28). .
The polymerizable rod-like liquid crystal compound can be obtained by introducing a polymerizable group into the rod-like liquid crystal compound. Examples of the polymerizable group include an unsaturated polymerizable group, an epoxy group, and an aziridinyl group, preferably an unsaturated polymerizable group, and particularly preferably an ethylenically unsaturated polymerizable group. The polymerizable group can be introduced into the molecule of the rod-like liquid crystal compound by various methods. The number of polymerizable groups possessed by the polymerizable rod-like liquid crystal compound is preferably 1 to 6, and more preferably 1 to 3. Examples of the polymerizable rod-like liquid crystal compound are described in Makromol. Chem. 190, 2255 (1989), Advanced Materials 5, 107 (1993), US Pat. No. 4,683,327, US Pat. No. 5,622,648, US Pat. No. 5,770,107, International Publication WO95 / 22586. No. 95/24455, No. 97/00600, No. 98/23580, No. 98/52905, JP-A-1-272551, No. 6-16616, and No. 7-110469. 11-80081 and JP-A 2001-328773, and the like. Two or more kinds of polymerizable rod-like liquid crystal compounds may be used in combination. When two or more kinds of polymerizable rod-like liquid crystal compounds are used in combination, the alignment temperature can be lowered.

(2) Optically active compound (chiral agent)
The liquid crystal composition exhibits a cholesteric liquid crystal phase, and for that purpose, it preferably contains an optically active compound. However, when the rod-like liquid crystal compound is a molecule having an asymmetric carbon atom, the cholesteric liquid crystal phase may be stably formed without adding an optically active compound. The optically active compound is known in various known chiral agents (for example, liquid crystal device handbook, Chapter 3-4-3, TN, chiral agent for STN, 199 pages, edited by Japan Society for the Promotion of Science, 142nd Committee, 1989). ) Can be selected. The optically active compound generally contains an asymmetric carbon atom, but an axially asymmetric compound or a planar asymmetric compound that does not contain an asymmetric carbon atom can also be used as a chiral agent. Examples of the axial asymmetric compound or the planar asymmetric compound include binaphthyl, helicene, paracyclophane, and derivatives thereof. The optically active compound (chiral agent) may have a polymerizable group. When the optically active compound has a polymerizable group and the rod-like liquid crystal compound used in combination also has a polymerizable group, it is derived from the rod-like liquid crystal compound by a polymerization reaction of the polymerizable optically active compound and the polymerizable rod-like liquid crystal compound. A polymer having a repeating unit and a repeating unit derived from an optically active compound can be formed. In this embodiment, the polymerizable group possessed by the polymerizable optically active compound is preferably the same group as the polymerizable group possessed by the polymerizable rod-like liquid crystal compound. Accordingly, the polymerizable group of the optically active compound is also preferably an unsaturated polymerizable group, an epoxy group or an aziridinyl group, more preferably an unsaturated polymerizable group, and an ethylenically unsaturated polymerizable group. Is particularly preferred.
The optically active compound may be a liquid crystal compound.

  The optically active compound in the liquid crystal composition is preferably 1 to 30 mol% with respect to the liquid crystal compound used in combination. A smaller amount of the optically active compound is preferred because it often does not affect liquid crystallinity. Therefore, the optically active compound used as the chiral agent is preferably a compound having a strong twisting power so that a twisted orientation with a desired helical pitch can be achieved even with a small amount. Examples of such a chiral agent exhibiting a strong twisting force include the chiral agents described in JP-A No. 2003-287623, and can be preferably used in the present invention.

(3) Polymerization initiator The liquid crystal composition used for forming the light reflecting layer is preferably a polymerizable liquid crystal composition, and for that purpose, it preferably contains a polymerization initiator. In the present invention, since the curing reaction is advanced by irradiation with ultraviolet rays, the polymerization initiator to be used is preferably a photopolymerization initiator capable of starting the polymerization reaction by irradiation with ultraviolet rays. Examples of the photopolymerization initiator include α-carbonyl compounds (described in US Pat. Nos. 2,367,661 and 2,367,670), acyloin ether (described in US Pat. No. 2,448,828), α-hydrocarbon substituted aromatics. Group acyloin compounds (described in US Pat. No. 2,722,512), polynuclear quinone compounds (described in US Pat. Nos. 3,046,127 and 2,951,758), combinations of triarylimidazole dimers and p-aminophenyl ketone (US patents) No. 3549367), acridine and phenazine compounds (JP-A-60-105667, US Pat. No. 4,239,850), oxadiazole compounds (US Pat. No. 4,221,970), and the like. .

  The amount of the photopolymerization initiator used is preferably 0.1 to 20% by mass, more preferably 1 to 8% by mass, based on the liquid crystal composition (solid content in the case of a coating liquid).

(4) Alignment control agent An alignment control agent that contributes to stable or rapid cholesteric liquid crystal phase may be added to the liquid crystal composition. Examples of the orientation control agent include fluorine-containing (meth) acrylate polymers and compounds represented by the following general formulas (X1) to (X3). You may contain 2 or more types selected from these. These compounds can reduce the tilt angle of the molecules of the liquid crystal compound or can be substantially horizontally aligned at the air interface of the layer. In this specification, “horizontal alignment” means that the major axis of the liquid crystal molecule is parallel to the film surface, but it is not required to be strictly parallel. An orientation with an inclination angle of less than 20 degrees is meant. When the liquid crystal compound is horizontally aligned in the vicinity of the air interface, alignment defects are unlikely to occur, so that the transparency in the visible light region is increased and the reflectance in the infrared region is increased. On the other hand, when the molecules of the liquid crystal compound are aligned at a large tilt angle, the spiral axis of the cholesteric liquid crystal phase is shifted from the normal to the film surface, resulting in a decrease in reflectivity, a fingerprint pattern, an increase in haze and diffraction. It is not preferable because it is shown.
Examples of the fluorine-containing (meth) acrylate-based polymer that can be used as an orientation control agent are described in JP-A No. 2007-272185, [0018] to [0043].

  Hereinafter, the following general formulas (X1) to (X3) that can be used as the alignment control agent will be described in order.

In the formula, R ¹ , R ² and R ³ each independently represent a hydrogen atom or a substituent, and X ¹ , X ² and X ^{3 each} represent a single bond or a divalent linking group. The substituent represented by each of R ^{1 to} R ³ is preferably a substituted or unsubstituted alkyl group (more preferably an unsubstituted alkyl group or a fluorine-substituted alkyl group), an aryl group (particularly a fluorine-substituted alkyl). An aryl group having a group is preferred), a substituted or unsubstituted amino group, an alkoxy group, an alkylthio group, and a halogen atom. The divalent linking groups represented by X ¹ , X ² and X ³ are each an alkylene group, an alkenylene group, a divalent aromatic group, a divalent heterocyclic residue, —CO—, —NRa— (Ra Is a divalent linking group selected from the group consisting of an alkyl group having 1 to 5 carbon atoms or a hydrogen atom), —O—, —S—, —SO—, —SO ₂ — and combinations thereof. Is preferred. The divalent linking group is selected from the group consisting of an alkylene group, a phenylene group, —CO—, —NRa—, —O—, —S— and —SO ₂ —, or the group. It is more preferably a divalent linking group in which at least two groups are combined. The alkylene group preferably has 1 to 12 carbon atoms. The alkenylene group preferably has 2 to 12 carbon atoms. The number of carbon atoms of the divalent aromatic group is preferably 6-10.

In the formula, R represents a substituent, and m represents an integer of 0 to 5. When m represents an integer greater than or equal to 2, several R may be same or different. Preferred substituents for R are the same as those listed as preferred ranges for the substituents represented by R ¹ , R ² , and R ³ . m preferably represents an integer of 1 to 3, particularly preferably 2 or 3.

In the formula, R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁸ and R ⁹ each independently represent a hydrogen atom or a substituent. The substituents represented by R ⁴ , R ⁵ , R ⁶ , R ⁷ , R ⁸ and R ⁹ are each preferably a substituent represented by R ¹ , R ² and R ³ in the general formula (XI). It is the same as that mentioned as a thing.

Examples of the compounds represented by the formulas (X1) to (X3) that can be used as the alignment control agent in the present invention include compounds described in JP-A-2005-99248.
In the present invention, as the alignment control agent, one type of the compounds represented by the general formulas (X1) to (X3) may be used alone, or two or more types may be used in combination.

  The addition amount of the compound represented by any one of the general formulas (X1) to (X3) in the liquid crystal composition is preferably 0.01 to 10% by mass, and 0.01 to 5% by mass of the liquid crystal compound. % Is more preferable, and 0.02 to 1% by mass is particularly preferable.

2. Substrate The infrared light reflector of the present invention has a substrate. However, the infrared light reflection plate of the present invention may be used as an infrared light reflection layer of the present invention that does not include a substrate, depending on the use mode.
The substrate is self-supporting, and there is no limitation on the material and optical characteristics as long as it supports the light reflecting layer. Depending on the application, high transparency to ultraviolet light will be required.

  The substrate (substrate 12 in FIGS. 1 and 2, etc.) is, for example, a polymer film, and the optical properties thereof are not particularly limited. In the infrared light reflecting plate of the present invention, the substrate is preferably a polymer film. In the present invention, in particular, a member having variations in the in-plane retardation Re may be used as the substrate.

  Specifically, the optical characteristics of the substrate 12 are not particularly limited, and may be a phase difference plate showing a phase difference or an optically isotropic substrate. That is, the substrate 12 does not have to be a retardation plate such as a retardation plate having a phase difference of ½ wavelength whose optical characteristics are strictly adjusted. In the present invention, the in-plane retardation Re (1000) at a wavelength of 1000 nm of the substrate 12 may be made of a polymer film or the like having a variation of 20 nm or more. Furthermore, it may be made of a polymer film or the like having a variation of Re (1000) of 100 nm or more. The in-plane retardation of the substrate is not particularly limited. For example, a retardation plate having an in-plane retardation Re (1000) of a wavelength of 1000 nm of 800 to 13000 nm can be used.

  Examples of the polymer film having high transparency to visible light include polymer films for various optical films used as members of display devices such as liquid crystal display devices. Examples of the substrate include polyester films such as polyethylene terephthalate (PET), polybutylene terephthalate, and polyethylene naphthalate (PEN); polycarbonate (PC) films and polymethyl methacrylate films; polyolefin films such as polyethylene and polypropylene; polyimide films, An acetyl cellulose (TAC) film etc. are mentioned. Polyethylene terephthalate and triacetyl cellulose are preferred.

The substrate may be a special retardation plate such as a retardation plate having a half-wave retardation manufactured by managing a production process so as to satisfy predetermined optical characteristics, The predetermined retardation plate may be a polymer film that cannot be used. Among them, in the infrared reflecting plate of the present invention, it is preferable that the substrate is a retardation plate having a phase difference of ½ wavelength. In addition, it is preferable to suppress the number of laminated light reflecting layers by providing a retardation plate having a half-wave retardation from the viewpoint of increasing cost, manufacturing load, optical characteristics (haze), and coated surface. In addition, by using a phase difference plate having a phase difference of ½ wavelength, both right circularly polarized light and left circularly polarized light are reflected only by a light reflecting layer in which a cholesteric liquid crystal phase in one spiral direction is fixed. Cost and manufacturing load can be reduced.
There is no restriction | limiting in particular as a phase difference plate which has the said 1/2 wavelength phase difference, It can change suitably as needed and can use a preferable thing.

As the retardation plate having a half-wave retardation, for example, a retardation plate obtained by stretching a film made of a transparent resin can be used. A retardation plate described in JP-A-2002-40258 can also be used as a retardation plate having a half-wave retardation in the present invention. It can be used with reference to the invention.
The transparent resin is not particularly limited, but preferably has a thickness of about 0.1 mm and a total light transmittance of 80% or more. The transparent resin includes acetate resin such as triacetyl cellulose, polyester resin, polyethersulfone resin, polycarbonate resin, chain polyolefin resin, polymer resin having alicyclic structure, acrylic resin, polyvinyl alcohol. Resin, polyvinyl chloride resin, and the like. Among these, a polycarbonate resin or a polymer resin having an alicyclic structure is preferable. Specifically, the alicyclic structure-containing polymer resin includes (1) a norbornene polymer, (2) a monocyclic olefin polymer, (3) a cyclic conjugated diene polymer, and (4) vinyl fat. Examples thereof include cyclic hydrocarbon polymers and hydrogenated products thereof.

  If necessary, the resin may include an antioxidant, a heat stabilizer, a light stabilizer, an ultraviolet absorber, an antistatic agent, a dispersant, a chlorine scavenger, a flame retardant, a crystallization nucleating agent, an antiblocking agent, an antiblocking agent. Add known additives such as clouding agents, mold release agents, pigments, organic or inorganic fillers, neutralizing agents, lubricants, decomposition agents, metal deactivators, antifouling agents, antibacterial agents and thermoplastic elastomers be able to.

  In addition, as a phase difference plate having a half-wave phase difference, a liquid crystal compound applied, oriented, and fixed on a transparent resin, an inorganic crystal such as crystal or sapphire, and fine irregularities on a resin or glass substrate It is also possible to use a structural birefringent plate provided in the above.

Instead of the glass sandwiching the infrared light reflection layer, a glass substitute resin formed body or a combination of the glass substitute resin formed body and glass can be used. Examples of glass substitute resins include polycarbonate resins, acrylic resins, and methacrylic resins. It is also possible to use a glass substitute resin coated with a hard coat layer. Examples of hard coat layers include acrylic hard coat materials, silicone hard coat materials, melamine hard coat materials, and inorganic fine particles such as silica, titania, alumina, and zirconia dispersed in these hard coat materials. Things can be raised.
In the configuration containing the retardation plate having a retardation of λ / 2 wavelength according to the present invention, the liquid crystal film formed by fixing the cholesteric liquid crystal phase is preferably a laminate of three or more layers. In this configuration, a liquid crystal film in which a cholesteric liquid crystal phase is fixed / a phase difference plate having a phase difference of λ / 2 wavelength / a liquid crystal film in which a cholesteric liquid crystal phase is fixed is formed. It becomes the laminated body laminated | stacked.

3. Non-light reflecting layer The infrared light reflecting plate of the present invention may have a non-light reflecting layer containing an organic material and / or an inorganic material. An example of the non-light-reflective layer that can be used in the present invention includes an easy-adhesion layer for facilitating close contact with other members (for example, an interlayer film or the like). The easy-adhesion layer is preferably arranged as one or both outermost layers. For example, in the aspect in which the light reflecting layer is disposed on one surface of the substrate, the easy adhesion layer can be disposed on the uppermost light reflecting layer. And / or an easily bonding layer can also be arrange | positioned on the back surface (surface of the board | substrate of the side in which the light reflection layer is not arrange | positioned) of a board | substrate. The material used for forming the easy-adhesion layer is, depending on whether the easy-adhesion layer is formed adjacent to the light reflecting layer or the substrate, or depending on the material of other members to be bonded, etc. It is selected from various materials. Other examples of the non-light-reflective layer that can be used in the present invention include forming a light-reflective layer of a cholesteric liquid crystal phase, an undercoat layer that increases adhesion between the substrate, and a light-reflective layer. Included is an alignment layer that more precisely defines the alignment direction of the liquid crystal compound. The undercoat layer and the alignment layer are preferably disposed between the at least one light reflecting layer and the substrate. An alignment layer may be disposed between the light reflecting layers.

(Easily adhesive layer)
The infrared light reflection plate of the present invention may have an easy adhesion layer as one or both outermost layers. The easy-adhesion layer has a function of improving adhesiveness with an interlayer film for laminated glass, for example. More specifically, the easy-adhesion layer has a function of improving the adhesion between the cholesteric liquid crystal phase light reflection layer and / or substrate and the interlayer film for laminated glass. Examples of a material that can be used for forming the easy-adhesion layer include polyvinyl butyral (PVB) resin. The polyvinyl butyral resin is a kind of polyvinyl acetal produced by reacting polyvinyl alcohol (PVA) and butyraldehyde with an acid catalyst, and is a resin having a repeating unit having the following structure.

  The easy adhesion layer is preferably formed by coating. For example, you may form by the application | coating to the surface of the light reflection layer of a cholesteric liquid crystal phase, and / or the back surface (surface in which the light reflection layer is not formed) of a board | substrate. More specifically, one type of polyvinyl butyral resin is dissolved in an organic solvent to prepare a coating solution, and the coating solution is applied to the surface of the light reflecting layer of the cholesteric liquid crystal phase and / or the back surface of the substrate, If desired, it can be heated and dried to form an easy-adhesion layer. As a solvent used for preparing the coating solution, for example, methoxypropyl acetate (PGMEA), methyl ethyl ketone (MEK), isopropanol (IPA) and the like can be used. Various conventionally known methods can be used as the coating method. The preferred temperature of the drying temperature varies depending on the material used for the preparation of the coating solution, but generally it is preferably about 140 to 160 ° C. Although there is no restriction | limiting in particular also about drying time, Generally, it is about 5 to 10 minutes.

The easy-adhesion layer may be a layer made of an acrylic resin, a styrene / acrylic resin, a urethane resin, a polyester resin, or the like, so-called an undercoat layer. An easy adhesion layer made of these materials can also be formed by coating. Some commercially available polymer films are provided with an undercoat layer. Therefore, these commercially available products can be used as a substrate.
In addition, as for the thickness of an easily bonding layer, 0.1-2.0 micrometers is preferable.

(Undercoat layer)
The infrared light reflection plate of the present invention may have an undercoat layer between the light reflection layer of the cholesteric liquid crystal phase and the substrate. If the adhesion between the cholesteric liquid crystal phase light reflecting layer and the substrate is weak, peeling failure is likely to occur in the process of stacking and manufacturing the cholesteric liquid crystal phase light reflecting layer, or laminated glass as an infrared light reflecting plate. Cause a decrease in strength (impact resistance). Therefore, a layer that can improve the adhesion between the cholesteric liquid crystal layer and the substrate can be used as the undercoat layer. On the other hand, when the substrate or the substrate and the undercoat layer are peeled off and the member such as the intermediate film and the light reflecting layer are integrated, the substrate and the undercoat layer, or the undercoat layer and the light reflecting layer of the cholesteric liquid crystal phase The interface needs to be weak enough to be peelable. In view of making the laminated interlayer sheet in a subsequent process, it is preferable to peel at the interface between the undercoat layer and the substrate.
Examples of materials that can be used to form the undercoat layer include acrylate copolymer, polyvinylidene chloride, styrene butadiene rubber (SBR), aqueous polyester, and the like. Further, in an embodiment in which the surface of the undercoat layer is bonded to the intermediate film, it is preferable that the adhesion between the undercoat layer and the intermediate film is good. From this viewpoint, the undercoat layer also contains a polyvinyl butyral resin together with the material. It is preferable. Moreover, since it is necessary to adjust adhesive force moderately as above-mentioned for undercoat, dialdehydes, such as glutaraldehyde and 2, 3- dihydroxy- 1, 4- dioxane, or hardening agents, such as a boric acid, are used. It is preferable to use the film appropriately. The addition amount of the hardener is preferably 0.2 to 3.0% by mass of the dry mass of the undercoat layer.
The thickness of the undercoat layer is preferably 0.05 to 0.5 μm.

(Orientation layer)
The infrared light reflection plate of the present invention may have an alignment layer between the light reflection layer of the cholesteric liquid crystal phase and the substrate. The alignment layer has a function of more precisely defining the alignment direction of the liquid crystal compound in the cholesteric liquid crystal layer. The alignment layer can be provided by means such as a rubbing treatment of an organic compound (preferably a polymer), oblique vapor deposition of an inorganic compound, or formation of a layer having a microgroove. Furthermore, an alignment layer in which an alignment function is generated by application of an electric field, application of a magnetic field, or light irradiation is also known. The alignment layer is preferably formed on the surface of the polymer film by rubbing treatment.
Since the alignment layer needs to be adjacent to the light reflecting layer of the cholesteric liquid crystal phase, it is preferably provided between the light reflecting layer of the cholesteric liquid crystal phase and the substrate or the undercoat layer. However, the undercoat layer may have a function of an alignment layer. Moreover, you may have an orientation layer between the light reflection layers.

  The alignment layer preferably has a certain degree of adhesion to the adjacent light reflecting layer of the cholesteric liquid crystal phase, and the undercoat layer or the substrate. However, as an example of an embodiment of the present invention to be described later, an infrared light reflection plate is manufactured by laminating a substrate from a light reflection layer of a cholesteric liquid crystal phase and pasting it with a phase difference plate having a half wavelength retardation. In the case of producing a laminated interlayer film sheet, it is necessary to have a weakness that can be peeled off at any of the interfaces of the light reflecting layer / alignment layer / undercoat layer / substrate of the cholesteric liquid crystal phase. The interface to be peeled may be any interface, but it is preferable to peel at the interface between the alignment layer and the undercoat layer in consideration of making a laminated interlayer sheet in a subsequent step.

As a material used for the alignment layer, a polymer of an organic compound is preferable, and a polymer that can be crosslinked by itself or a polymer that is crosslinked by a crosslinking agent is often used. Of course, polymers having both functions are also used. Examples of the polymer include polymethyl methacrylate, acrylic acid / methacrylic acid copolymer, styrene / maleimide copolymer, polyvinyl alcohol and modified polyvinyl alcohol, and poly (N-methylol acrylamide). , Styrene / vinyl toluene copolymer, chlorosulfonated polyethylene, nitrocellulose, polyvinyl chloride, chlorinated polyolefin, polyester, polyimide, vinyl acetate / vinyl chloride copolymer, ethylene / vinyl acetate copolymer, carboxymethyl cellulose And polymers such as silica, gelatin, polyethylene, polypropylene and polycarbonate, and compounds such as silane coupling agents. Examples of preferred polymers are water-soluble polymers such as poly (N-methylacrylamide), carboxymethyl cellulose, gelatin, polyville alcohol, and modified polyvinyl alcohol, and gelatin, polyville alcohol, and modified polyvinyl alcohol. Are preferable, and in particular, polyvinyl alcohol and modified polyvinyl alcohol can be mentioned. Further, in the embodiment in which the surface of the alignment layer is bonded to the intermediate film, it is preferable that the adhesion between the alignment layer and the intermediate film is good. It is preferable.
The thickness of the alignment layer is preferably 0.1 to 2.0 μm.

4). Additives Further, the heat shielding effect of the infrared light reflecting layer and the infrared light reflecting plate of the present invention can be improved not only by the reflection property but also by the light absorption property of the material. The infrared light reflection layer and infrared light reflection plate of the present invention may contain an additive in an arbitrary layer.
For example, a color material exhibiting absorption characteristics in the near-infrared light region, preferably in the wavelength region range of about 780 to 940 nm is added to the substrate or at least one light reflection layer, or a layer containing the color material By separately arranging, light in the near infrared region can be absorbed and the heat shielding property can be further improved.

  Further, among the metal oxide fine particles, there are also materials having absorption characteristics and / or reflection characteristics in the infrared region, specifically, 1400 nm to 2500 nm. In the present invention, metal oxide fine particles exhibiting the properties can also be used, for example, by adding the metal oxide fine particles to a substrate or at least one light reflecting layer, or containing the metal oxide fine particles. By separately disposing the layer to be absorbed, light in the wavelength range of about 1400 to 2500 nm can be absorbed and / or reflected, and the heat shielding property can be further improved.

  As described above, the aspect in which the heat shielding property is improved by using the color material and / or the metal oxide fine particles is more suitable for the production than the band broadening by further laminating the light reflecting layer in which the cholesteric liquid crystal phase is fixed. It is preferable in terms of manufacturing cost.

  Further, each light reflecting layer formed by fixing a cholesteric liquid crystal phase has a tendency to be deteriorated by irradiation with ultraviolet light, and in particular, the present inventor shows that deterioration with respect to ultraviolet light having a wavelength of 380 nm or less is remarkable. It became clear by examination. Therefore, in the present invention, for example, a material that absorbs light in the wavelength range (ultraviolet absorber) is added to the substrate or at least one light reflecting layer, or a layer containing the material is separately disposed. Is preferable because deterioration can be remarkably suppressed.

In addition, since coloring materials, metal oxide fine particles, ultraviolet absorbers, and the like may affect the alignment of the liquid crystal, these materials are added to the substrate or other layers other than the light reflecting layer, or light reflecting. When the layer is integrated with another member, it is preferably added to the member. These materials may be added to the same layer, or may be added to different layers. The member (layer, substrate, etc.) to which each material is added will be determined so that the effect of the function of each material can be obtained more efficiently. In addition, in consideration of various properties of these materials (effect on haze, solubility, meltability, applicability, meltability), surface defects do not occur and transparency is not significantly reduced. The member to be added will be determined.
For example, it is preferable that the ultraviolet absorber is added to a member into which light enters earlier than the light reflecting layer. By adding an ultraviolet absorber to the member, it is possible to suppress the light reflecting layer from being deteriorated by ultraviolet rays.
Further, it is preferable that the coloring material and the metal oxide fine particles are added to a member into which light enters later, as compared with the light reflecting layer.

  Although not illustrated in the drawings, additives such as ultraviolet absorbers, coloring materials, metal oxide fine particles, etc., in the embodiment of the present invention, are optional layers of the infrared light reflection layer and infrared light reflection plate of the present invention. May be included. Among these, it is preferable that the additive is contained in the substrate or the non-light-reflective layer, and for example, it is preferably contained in any one of an easy-adhesion layer, an alignment layer, an undercoat layer, and a substrate. Which layer is added is selected according to the positional relationship between the light reflecting layer of the cholesteric liquid crystal phase and sunlight. The ultraviolet absorber is preferably contained in a layer closer to sunlight than the light reflecting layer of the cholesteric liquid crystal phase, and the coloring material and metal oxide fine particles are farther from sunlight than the light reflecting layer of the cholesteric liquid crystal phase. It is preferably contained in the side layer. Depending on the embodiment, the preferred layers for containing each of the ultraviolet absorber, the coloring material, and the metal oxide fine particles are replaced. Therefore, for each material, the composition, the solvent, the amount of use, etc. are adjusted as appropriate, It is necessary to take a method.

(UV absorber)
The infrared light reflection plate of the present invention preferably contains an ultraviolet absorber in at least one of the light reflection layer, the easy adhesion layer, the undercoat layer, the alignment layer, and the substrate. Depending on the type of the UV absorber, it may affect the alignment of the liquid crystal, so it is preferable to add it to members (layers, substrates, etc.) other than the light reflecting layer. The embodiment of the present invention may take various forms, but it is preferably added to a member into which light enters earlier than the light reflecting layer. For example, it is preferable to add to a layer disposed between the glass plate disposed on the outdoor side and the light reflecting layer of the cholesteric liquid crystal phase. Or it is also preferable to make it contain in the intermediate film adhere | attached on the glass plate arrange | positioned on the outdoor side, or the glass plate itself arrange | positioned on the outdoor side.
Examples of compounds that can be used as ultraviolet absorbers include ultraviolet absorbers such as benzotriazole-based, benzodithiol-based, coumarin-based, benzophenone-based, salicylic acid ester-based, and cyanoacrylate-based materials; titanium oxide, zinc oxide, and the like. Examples of particularly preferable ultraviolet absorbers include Tinuvin 326, 328, 479 (all manufactured by Ciba Japan). Moreover, the kind and compounding quantity of a ultraviolet absorber do not have a restriction | limiting in particular, According to the objective, it can select suitably. In particular, when the member containing the ultraviolet absorber has an effect of reducing the transmittance of ultraviolet rays having a wavelength of 380 nm or less to 0.1% or less, the deterioration of the light reflecting layer can be remarkably reduced, and yellowing due to ultraviolet rays is remarkably reduced. Since it can reduce, it is preferable. Therefore, it is preferable to determine the type and blending amount of the ultraviolet absorber so as to satisfy this characteristic.

(Color material)
The infrared light reflection plate of the present invention preferably contains a color material in at least one of the light reflection layer, the easy adhesion layer, the undercoat layer, the alignment layer, and the substrate. Depending on the type of the color material, it affects the alignment of the liquid crystal, so it is preferable to add it to a member (layer, substrate, etc.) other than the light reflecting layer. In addition, due to diffusion or absorption that occurs when light passes through a member containing a coloring material, the efficiency of infrared light reflection in the light reflection layer of the cholesteric liquid crystal phase may be reduced, and the heat shielding performance may be reduced. . Therefore, the embodiment of the present invention can take various forms, but it is preferably added to a member into which light enters later, compared with the light reflection layer. More specifically, it is preferable to contain in the layer arrange | positioned between the glass plate arrange | positioned indoors, and the light reflection layer of a cholesteric liquid crystal phase. Or it is also preferable to contain in the intermediate film adhere | attached on the glass plate arrange | positioned indoors, or the glass plate itself arrange | positioned indoors.

As the color material, both dyes and pigments can be used. In particular, it is preferable to use a material exhibiting absorber characteristics with respect to a wavelength region of 780 to 940 nm because the heat shielding property can be further improved. Moreover, the point which can reduce coloring is also preferable. As an absorbing material for a wavelength region of 780 to 940 nm, a cyan dye and a cyan pigment are preferable.
Examples of dyes used as cyan dyes include azomethine dyes such as indoaniline dyes and indophenol dyes; polymethine dyes such as cyanine dyes, oxonol dyes and merocyanine dyes; diphenylmethane dyes, triphenylmethane dyes and xanthene dyes Specific examples of carbonium dyes; phthalocyanine dyes; anthraquinone dyes; aryl or heteryl azo dyes having phenols, naphthols and anilines as coupling components, and indigo / thioindigo dyes. These dyes may exhibit cyan only after a part of the chromophore is dissociated, and the counter cation in that case may be an alkali metal or an inorganic cation such as ammonium, pyridinium, It may be an organic cation such as a quaternary ammonium salt, or may be a polymer cation having these in a partial structure. Also, black dyes such as polyazo dyes can be used.

  Examples of pigments used as cyan pigments include phthalocyanine pigments, anthraquinone-based indantron pigments (for example, CI Pigment Blue 60), and dyed lake pigment-based triarylcarbonium pigments. CI Pigment Blue 15: 1, 15: 2, 15: 3, 15: 4, 15: 6, copper phthalocyanine, monochloro or low chlorinated copper phthalocyanine, and arnium phthalocyanine described in European Patent No. 860475 CI Pigment Blue 15: 3, 15: 4, and aluminum phthalocyanine) are the most preferable, such as CI Pigment Blue 16, a metal-free phthalocyanine that is CI Pigment Blue 16, and phthalocyanine whose central metals are Zn, Ni, and Ti.

  As described above, when a color material that is a light-absorbing material is used, the transmittance spectrum in the visible light wavelength region is biased, and the transmitted light may be colored. Depending on the application, this characteristic can be actively used to select a color material so as to obtain a desired color. On the other hand, depending on the application (for example, a windshield of a car), coloring may not be preferable. When this inventor examined, it turned out that a color can be neutrally adjusted by using together the absorption material which has another absorption characteristic with the absorption material whose absorption maximum wavelength is 780-940 nm. For example, in order to adjust the color of the transmitted light of the infrared light reflector in a neutral direction, in addition to the cyan dye and / or cyan pigment, other color materials (yellow dye, yellow pigment, magenta dye, It is preferable to use a magenta pigment or the like. As these coloring materials, known materials described in various documents can be used. (The dye is described in JP-A-2005-105175 and the like, and the pigment is described in JP-A-2009-67956 and the like.)

(Metal oxide fine particles)
The infrared light reflection plate of the present invention is a metal oxide fine particle having absorption and / or reflection characteristics in the range of 1400 to 2500 nm in at least one of a light reflection layer, an easy adhesion layer, an undercoat layer, an alignment layer, and a substrate. It is preferable to contain. Depending on the type of the metal oxide fine particles, the liquid crystal orientation is affected, and therefore, it is preferably added to a member (layer, substrate, etc.) other than the light reflecting layer. In addition, due to diffusion or absorption that occurs when light passes through a member containing metal oxide fine particles, the efficiency of infrared light reflection in the light reflection layer of the cholesteric liquid crystal phase may be reduced, and the heat shielding performance may be reduced. is there. Therefore, the embodiment of the present invention can take various forms, but it is preferably added to a member into which light enters later, compared with the light reflection layer. More specifically, it is preferable to contain in the layer arrange | positioned between the glass plate arrange | positioned indoors, and the light reflection layer of a cholesteric liquid crystal phase. Or it is also preferable to contain in the intermediate film adhere | attached on the glass plate arrange | positioned indoors, or the glass plate itself arrange | positioned indoors.

Examples of usable metal oxide fine particles include at least one selected from Zn, Ge, Ti, Zr, Hf, Si, Sn, Mn, Ga, Mo, In, Sb, Ta, V, Y, and Nb. It is preferable to contain a metal oxide of a kind or a composite metal oxide formed by combining two or more of these metals.
As the metal oxide, _{e.g., ZnO, GeO 2, TiO 2} , ZrO 2, HfO 2, SiO 2, Sn 2 O 3, Mn 2 O 3, Ga 2 O 3, Mo 2 O 3, In 2 O 3, _{sb 2 O 3, Ta 2 O} 5, V 2 O 5, Y 2 O 3, etc. Nb ₂ O ₅ and the like.
Examples of the composite metal oxide include a composite oxide of titanium and zirconium, a composite oxide of titanium, zirconia and hafnium, a composite oxide of titanium and barium, a composite oxide of titanium and silicon, and a composite of titanium, zirconium and silicon. Examples thereof include oxides, composite oxides of titanium and tin, and composite oxides of titanium, zirconia, and tin.

  The method for producing metal oxide fine particles is not particularly limited, and any known method can be used. For example, desired oxide fine particles can be obtained by using a metal salt or metal alkoxide as a raw material and hydrolyzing in a reaction system containing water.

  In addition to the method of hydrolyzing in water, the inorganic fine particles may be produced in an organic solvent or an organic solvent in which a thermoplastic resin is dissolved. Examples of the solvent used in these methods include acetone, 2-butanone, dichloromethane, chloroform, toluene, ethyl acetate, cyclohexanone, anisole and the like. These may be used alone or as a mixture of two or more.

<Infrared light reflector manufacturing method>
Each light reflection layer in the infrared light reflection plate of the present invention can be formed by various methods. An example is a method of forming by coating, which will be described later. More specifically, a curable liquid crystal composition capable of forming a cholesteric liquid crystal phase is applied to the surface of a substrate, an alignment layer, a light reflection layer, or the like. After the composition is made into a cholesteric liquid crystal phase, it can be formed by curing by advancing a curing reaction (for example, a polymerization reaction or a crosslinking reaction).
The infrared light reflector of the present invention is preferably produced by a coating method. An example of a manufacturing method is
(1) Applying a curable liquid crystal composition to the surface of a substrate or the like to make a cholesteric liquid crystal phase;
(2) irradiating the curable liquid crystal composition with ultraviolet rays to advance a curing reaction, fixing a cholesteric liquid crystal phase, and forming a light reflection layer;
Is a production method comprising at least
By repeating the steps (1) and (2) three times on one surface of the substrate, an infrared light reflector having the same configuration as that shown in FIG. 1 can be produced.
Note that the direction of rotation of the cholesteric liquid crystal phase can be adjusted by the type of liquid crystal used or the type of chiral agent added, and the helical pitch (that is, the central reflection wavelength) can be arbitrarily adjusted by the concentration of these materials. In addition, it is known that the wavelength of a specific region reflected by the light reflecting layer can be shifted by various factors of the manufacturing method. In addition to the concentration of addition of a chiral agent or the like, when fixing a cholesteric liquid crystal phase It can be shifted depending on conditions such as temperature, illuminance, and irradiation time.

  In the step (1), first, the curable liquid crystal composition is applied to the surface of the substrate or the lower light reflection layer. The curable liquid crystal composition is preferably prepared as a coating solution in which a material is dissolved and / or dispersed in a solvent. The coating liquid can be applied by various methods such as a wire bar coating method, an extrusion coating method, a direct gravure coating method, a reverse gravure coating method, and a die coating method. Alternatively, a liquid crystal composition can be discharged from a nozzle using an ink jet apparatus to form a coating film.

  Next, the curable liquid crystal composition applied to the surface to form a coating film is brought into a cholesteric liquid crystal phase. In the aspect in which the curable liquid crystal composition is prepared as a coating solution containing a solvent, the coating film may be dried and the solvent may be removed to obtain a cholesteric liquid crystal phase. Moreover, in order to set it as the transition temperature to a cholesteric liquid crystal phase, you may heat the said coating film if desired. For example, the cholesteric liquid crystal phase can be stably formed by heating to the temperature of the isotropic phase and then cooling to the cholesteric liquid crystal phase transition temperature. The liquid crystal phase transition temperature of the curable liquid crystal composition is preferably in the range of 10 to 250 ° C., more preferably in the range of 10 to 150 ° C. from the viewpoint of production suitability and the like. When the temperature is lower than 10 ° C., a cooling step or the like may be required to lower the temperature to a temperature range exhibiting a liquid crystal phase. When the temperature exceeds 200 ° C., a high temperature is required to make the isotropic liquid state higher than the temperature range once exhibiting the liquid crystal phase, which is disadvantageous from waste of thermal energy, deformation of the substrate, and alteration.

Next, in the step (2), the coating film in the cholesteric liquid crystal phase is irradiated with ultraviolet rays to advance the curing reaction. For ultraviolet irradiation, a light source such as an ultraviolet lamp is used. In this step, by irradiating ultraviolet rays, the curing reaction of the liquid crystal composition proceeds, the cholesteric liquid crystal phase is fixed, and a light reflecting layer is formed.
No particular limitation is imposed on the amount of irradiation energy of ultraviolet rays, in ^{general, 100mJ / cm 2 ~800mJ / cm} 2 is preferably about. Moreover, there is no restriction | limiting in particular about the time which irradiates an ultraviolet-ray to the said coating film, but it will be determined from the viewpoint of both sufficient intensity | strength and productivity of a cured film.

  In order to accelerate the curing reaction, ultraviolet irradiation may be performed under heating conditions. Moreover, it is preferable to maintain the temperature at the time of ultraviolet irradiation in the temperature range which exhibits a cholesteric liquid crystal phase so that a cholesteric liquid crystal phase may not be disturbed. Also, since the oxygen concentration in the atmosphere is related to the degree of polymerization, if the desired degree of polymerization is not reached in the air and the film strength is insufficient, the oxygen concentration in the atmosphere is reduced by a method such as nitrogen substitution. It is preferable. A preferable oxygen concentration is preferably 10% or less, more preferably 7% or less, and most preferably 3% or less. The reaction rate of the curing reaction (for example, polymerization reaction) that proceeds by irradiation with ultraviolet rays is 70% or more from the viewpoint of maintaining the mechanical strength of the layer and suppressing unreacted substances from flowing out of the layer. Preferably, it is 80% or more, more preferably 90% or more. In order to improve the reaction rate, a method of increasing the irradiation amount of ultraviolet rays to be irradiated and polymerization under a nitrogen atmosphere or heating conditions are effective. In addition, after polymerization, a method of further promoting the reaction by a thermal polymerization reaction by maintaining the polymer at a temperature higher than the polymerization temperature, or a method of irradiating ultraviolet rays again (however, irradiation is performed under conditions satisfying the conditions of the present invention). Can also be used. The reaction rate can be measured by comparing the absorption intensity of the infrared vibration spectrum of a reactive group (for example, a polymerizable group) before and after the reaction proceeds.

In the above process, the cholesteric liquid crystal phase is fixed and the light reflecting layer is formed. Here, the state in which the liquid crystal phase is “fixed” is the most typical and preferred mode in which the orientation of the liquid crystal compound in the cholesteric liquid crystal phase is maintained. However, it is not limited to this, and specifically, it is usually 0 ° C. to 50 ° C., and under severer conditions, in the temperature range of −30 ° C. to 70 ° C., the layer has no fluidity, and is oriented by an external field or an external force. It shall mean a state in which the fixed orientation form can be kept stable without causing a change in form. In the present invention, the alignment state of the cholesteric liquid crystal phase is fixed by a curing reaction that proceeds by ultraviolet irradiation.
In the present invention, it is sufficient that the optical properties of the cholesteric liquid crystal phase are maintained in the layer, and the liquid crystal composition in the light reflection layer does not need to exhibit liquid crystal properties. For example, the liquid crystal composition may have a high molecular weight due to a curing reaction and may no longer have liquid crystallinity.

[Laminated interlayer sheet for glass]
The laminated interlayer sheet for glass of the present invention comprises the infrared light reflecting layer of the present invention or the infrared light reflecting plate of the present invention, and the outermost layer of at least one of the infrared light reflecting layer or the infrared light reflecting plate. And an interlayer film disposed on the substrate.

(Characteristics of laminated interlayer sheet for glass)
An interlayer film can be bonded to one and / or both surfaces of the infrared light reflecting layer or the infrared light reflecting plate of the present invention. The laminated interlayer sheet for glass of the present invention preferably has an interlayer sheet on the outermost layers of both the infrared light reflecting layer and the infrared light reflecting plate. By laminating the interlayer film, it can be easily incorporated into laminated glass as a laminated interlayer film for laminated glass. When pasting the interlayer film, it may be pasted while leaving the substrate, or may be pasted after peeling off the substrate, but considering that it will be incorporated into the laminated glass in a later step In consideration of thickness, flexibility, and compression resistance, it is preferable that the substrate is peeled and then bonded to the interlayer sheet.
As the intermediate film, a general intermediate film used for producing laminated glass can be used. Specific examples include a sheet prepared from a composition containing a polyvinyl butyral resin or an ethylene / vinyl acetate copolymer as a main raw material.
The thickness of the interlayer film is generally about 380 to 760 μm.

[Method for producing laminated interlayer sheet for glass]
The infrared light reflecting plate of the present invention can be made into a laminated interlayer film for laminated glass sandwiched between interlayer films by bonding both surfaces with an interlayer film.
The method for producing a laminated interlayer film sheet for glass of the present invention,
(1) The 1st process of bonding the 1st interlayer film sheet on one surface of an infrared light reflector, and obtaining the 1st layered product, and
(2) The 2nd process of pasting up the 2nd interlayer film sheet on the surface on the opposite side of the surface where the 1st interlayer film sheet of the 1st layered product is bonded,
Is a production method comprising at least The first and second steps may be performed sequentially or simultaneously. Moreover, after implementing one process, you may once store and convey and implement the other process.

Although a well-known bonding method can be used for bonding with an interlayer film sheet, it is preferable to use a laminating process. In order to prevent the infrared light reflection plate and the interlayer film from being peeled off after processing, it is preferable that the lamination process be performed under some heating and pressurization conditions.
In order to perform lamination stably, the film surface temperature on the side to which the interlayer film sheet adheres is preferably 50 to 130 ° C, and more preferably 70 to 100 ° C.
It is preferable to apply pressure during lamination. Pressurization condition is preferably less than 2.0 kg / cm ^2, more preferably in the range of 0.5~1.8kg / cm ^2, in the range of 0.5~1.5kg / cm ² More preferably it is.

Moreover, in this invention, you may peel a board | substrate (or laminated body containing at least a board | substrate) from an infrared-light reflecting plate simultaneously with a lamination, immediately after that, or just before that. That is, the laminated interlayer sheet obtained after lamination may not have a substrate. For example, an example of a method for producing a laminated interlayer sheet for laminated glass according to the present invention uses the infrared light reflecting plate in which a substrate is disposed only on one surface as the infrared light reflecting plate, In the step, simultaneously with or after the step of bonding the first intermediate film to the surface opposite to the surface on which the substrate of the infrared light reflector is disposed, the infrared light reflector The process of peeling the board | substrate contained from the said 1st laminated body, The process of bonding the said 2nd intermediate film sheet to the surface which peeled the said board | substrate of the said 1st laminated body in the said 2nd process. Is a method for producing a laminated interlayer film sheet for glass.
By this method, a laminated interlayer film sheet for glass that does not include a substrate can be produced. By using the laminated interlayer film sheet for glass, an infrared reflective laminated glass that does not include a substrate can be easily produced. be able to. In order to peel the substrate stably without breakage or the like, the temperature of the substrate when peeling the substrate from the light reflecting layer of the cholesteric liquid crystal phase is preferably 40 ° C. or higher, and preferably 40 to 60 ° C. More preferred.

[Laminated glass]
The laminated glass of the present invention is characterized by comprising two glasses and the laminated interlayer film for glass of the present invention contained between the two glasses.

(Configuration of laminated glass)
The laminated interlayer sheet for laminated glass of the present invention can be made into a laminated glass by being sandwiched between two glass plates. A general glass plate can be used as the glass plate. In order to improve the heat shielding performance in combination with the infrared light reflector using the cholesteric liquid crystal phase of the present invention, heat ray absorbing glass having absorption in the visible light region can be used. By adjusting the absorption in the visible light region, it is possible to adjust the visibility (transmittance) and the heat shielding performance as glass. As described in Japanese Patent No. 2544035, Japanese Patent No. 2617223, and the like, the heat ray absorbing glass contains a metal oxide such as iron, tin, nickel, cobalt, selenium, etc. The color as the transmitted light can be adjusted. For example, when used as a windshield for automobiles, the absorption in the visible light region is suppressed so as to satisfy “visible light transmittance (standard light source A) 70% or more” defined by JIS-R-3211 as a laminated glass, It is preferable to improve the heat shielding performance while adjusting the transmitted light color. The heat ray absorbing glass preferably has a visible light transmittance (standard light source A) in the range of 80 to 95% and a main wavelength measured using a standard A light source in the range of 495 to 560 nm.
There is no restriction | limiting in particular about the thickness of a glass plate, A preferable range changes according to a use. For example, in the use of windshields (window shields) for transportation vehicles, it is generally preferable to use a glass plate having a thickness of 2.0 to 2.3 mm. Moreover, in the use of the heat-insulating window material for buildings such as houses and buildings, it is generally preferable to use a glass plate having a thickness of about 40 to 300 μm. However, it is not limited to this range.

The laminated body sandwiched between the glass plates is a glass plate / intermediate film / substrate / light reflection layer formed by fixing a cholesteric liquid crystal / a retardation plate having a phase difference of 1/2 wavelength / light formed by fixing a cholesteric liquid crystal. A structure in which the reflective layer / substrate / intermediate film / glass plate are laminated in this order may be employed.
Furthermore, a glass plate / intermediate film / cholesteric liquid crystal is obtained by removing a substrate (such as a PET film used for film formation other than a retardation plate having a half-wave retardation) from an infrared light reflection plate. A structure in which a light reflection layer fixed / a phase difference plate having a phase difference of ½ wavelength / a light reflection layer formed by fixing a cholesteric liquid crystal / an intermediate film / a glass plate may be laminated in this order.
At this time, the spiral direction of the liquid crystal phase formed by fixing the cholesteric liquid crystals on both surfaces of the retardation plate having a phase difference of ½ wavelength is preferably the same direction when the reflection center wavelength is the same.

[Production method of laminated glass]
The laminated interlayer sheet for laminated glass of the present invention can be made into a laminated glass by being sandwiched between two glass plates.
The method for producing a laminated glass of the present invention comprises a step of producing a laminated body sandwiched between two glass plates by sandwiching a laminated interlayer film sheet for laminated glass and a laminated body sandwiched between the glass plates. It includes a step of pressure bonding while heating.
As a detailed manufacturing method, a known laminated glass manufacturing method can be appropriately used.
In general, after sandwiching the laminated interlayer sheet for laminated glass between two glass plates, heat treatment and pressure treatment (such as ironing with a rubber roller) are repeated several times, and finally using an autoclave or the like. A method of performing heat treatment under a pressurized condition is employed.

The manufacturing method of this invention includes the process of crimping | bonding the laminated body clamped by the said glass plate, heating.
In the production method of the present invention, it is preferable that the laminate sandwiched between the glass plates in which the two intermediate films are not in contact with each other is pressure-bonded while being heated.
The lamination of the laminate sandwiched between the glass plates and the glass plate is performed by, for example, pre-pressing in a vacuum bag or the like under reduced pressure at a temperature of 80 to 120 ° C. for 30 to 60 minutes, and then in an autoclave. Lamination can be performed at a temperature of 120 to 150 ° C. under a pressure of 0 to 1.5 MPa to obtain a laminated glass in which a laminate is sandwiched between two glasses. Moreover, you may bond together using an adhesive material etc.
At this time, it is preferable that the time of thermocompression bonding at a temperature of 120 to 150 ° C. under a pressure of 1.0 to 1.5 MPa is 20 to 90 minutes.
After the thermocompression bonding, there is no particular limitation on the method of cooling, and the laminated glass body may be obtained by cooling while releasing the pressure as appropriate. In the present invention, it is preferable to lower the temperature while maintaining the pressure after completion of the thermocompression bonding from the viewpoint of further improving the wrinkles and cracks of the obtained laminated glass body. Here, when the temperature is lowered while maintaining the pressure, the pressure inside the apparatus at the time of thermocompression bonding (preferably 130 ° C.) is such that the pressure inside the apparatus at 40 ° C. becomes 75% to 100% at the time of thermocompression bonding. It means to cool down. The method of lowering the temperature while maintaining the pressure is not particularly limited as long as the pressure when the temperature is lowered to 40 ° C. is within the above range, but the pressure inside the pressure device naturally decreases as the temperature decreases. In addition, a mode in which the temperature is lowered without leaking pressure from the inside of the apparatus or a mode in which the temperature is lowered while further pressurizing from the outside so that the internal pressure of the apparatus does not decrease as the temperature decreases is preferable. In the case where the temperature is lowered while maintaining the pressure, it is preferable to cool to 120 ° C. to 150 ° C. and then cool to 40 ° C. over 1 to 5 hours.
In the present invention, it is preferable to include a step of releasing the pressure after the temperature is lowered while the pressure is maintained. Specifically, it is preferable to lower the temperature by releasing the pressure after the temperature in the autoclave becomes 40 ° C. or lower after the temperature is lowered while the pressure is maintained.
As mentioned above, the manufacturing method of the laminated glass body of this invention laminates | stacks said 1st glass, said 1st intermediate film, the said infrared reflective layer, said 2nd intermediate film, and said 2nd glass in this order. Preferably, the method includes a step, a step of thermocompression bonding at a temperature of 120 to 150 ° C. under a pressure of 1.0 to 1.5 MPa, a step of lowering the temperature while maintaining the pressure, and a step of releasing the pressure. .

  The range in which the infrared light reflection layer (or infrared light reflection plate) and the intermediate film are subjected to thermocompression bonding may be a range over the entire area of the glass plate, or may be only the peripheral portion of the glass plate. The thermocompression bonding can further suppress the generation of wrinkles.

[Window materials]
The infrared light reflector of the present invention exhibits selective reflection characteristics having reflection peaks at 850 to 900 nm, 1010 to 1070 nm, and 1190 to 1290 nm corresponding to the peak of solar energy. The reflection plate having such characteristics is attached to a building such as a house, an office building, or a window of a vehicle such as an automobile as a member for heat insulation of solar radiation. Or the infrared-light reflecting plate of this invention can be used for the use as a member for heat insulation of solar radiation itself (for example, glass for heat insulation, a film for heat insulation).

Other important performances as an infrared light reflector are visible light transmittance and haze. By adjusting the selection of materials and manufacturing conditions, etc., an infrared light reflecting plate exhibiting preferable visible light transmittance and haze can be provided according to the application. For example, in an aspect used for an application with high visible light transmittance, an infrared light reflecting plate having a visible light transmittance of 90% or more and an infrared reflectance satisfying the above reaction can be obtained.
The infrared light reflection layer of the present invention, the infrared light reflection plate of the present invention, the laminated interlayer sheet for glass of the present invention, and the laminated glass of the present invention may be used as a window member for buildings or vehicles. preferable.

  Hereinafter, the features of the present invention will be described more specifically with reference to examples and comparative examples (note that comparative examples are not known techniques). The materials, amounts used, ratios, processing details, processing procedures, and the like shown in the following examples can be changed as appropriate without departing from the spirit of the present invention. Accordingly, the scope of the present invention should not be construed as being limited by the specific examples shown below.

<Preparation of coating liquid (liquid crystal composition)>
Coating solutions (R1) and (L1) having the compositions shown in the following table were prepared.

  Also, coating solutions (R2) to (R5) were prepared in the same manner except that the formulation amount of the chiral agent LC-756 of the coating solution (R1) was changed to the amount shown in the table below.

  Also, coating solutions (L2) to (L3) were prepared in the same manner except that the amount of the chiral agent (compound 2) in the coating solution (L1) was changed to the amount shown in the table below.

<Manufacture 1 of an infrared light reflector>
[Example 1]
Using the prepared coating liquids (R1), (R2), and (R3), an infrared light reflection plate was produced by the following procedure. As the substrate, a PET film (no undercoat layer, thickness: 75 μm) manufactured by FUJIFILM Corporation was used.
(1) Each coating solution was applied on a PET film at room temperature using a wire bar so that the thickness of the dried film was 6 μm.
(2) After drying at room temperature for 30 seconds to remove the solvent, the mixture was heated in an atmosphere of 125 ° C. for 2 minutes, and then made a cholesteric liquid crystal phase at 95 ° C. Next, UV irradiation was performed for 6 to 12 seconds at an output of 60% with an electrodeless lamp “D bulb” (90 mW / cm ² ) manufactured by Fusion UV Systems Co., Ltd., and the cholesteric liquid crystal phase was fixed. ) Was produced.
(3) After cooling to room temperature, the steps (1) and (2) are repeated, and the infrared light reflection of Example 1 having the structure shown in FIG. 1 having a light-reflecting layer of a cholesteric liquid crystal phase laminated in three layers A plate was made.
The coating liquid was applied in the order of (R3), (R2), and (R1).

[Example 2]
The infrared light reflector of Example 2 having the configuration shown in FIG. 1 was prepared in the same procedure as in Example 1 except that (R3) was changed to (R4) among the coating solutions to be applied.

[Comparative Example 1]
The infrared light reflector of Comparative Example 1 having the configuration shown in FIG. 1 was prepared in the same procedure as in Example 1 except that (R3) was changed to (R5) in the coating solution to be applied.

<Evaluation 1 of Infrared Light Reflector 1>
[Reflectance measurement and thermal insulation performance evaluation 1]
About each produced infrared light reflecting plate, a 5 degree regular reflection spectrum was measured with the spectrophotometer "V-670" by JASCO Corporation, the reflectance of 790 nm, the reflectance of 875 nm, the reflectance of 1040 nm The heat shielding performance (transmittance) for the solar radiation spectrum in the wavelength range of 300 to 2500 nm was calculated by measuring the reflectance of 1240 nm and the front transmission spectrum. The heat shielding performance was determined based on the following criteria (the solar radiation transmittance is preferably low).
◎: Solar spectrum transmittance 70% or less ○: Solar spectrum transmittance 70% or more, 80% or less Δ: Solar spectrum transmittance 80% or more, 85% or less ×: Solar spectrum transmittance 85% or less Shown in the table below.

[Slant reflection light color evaluation 1]
About each produced infrared light reflector, after measuring a 60 degree regular reflection spectrum with the spectrophotometer "V-670" by JASCO Corporation, and calculating the hue with respect to D65 standard light source, xy chromaticity diagram The degree of variation Δxy from the above standard white point (x = 0.127, y = 0.3290) was calculated. The effect of suppressing the oblique reflected light color was determined based on the following criteria.
：: Δxy 0.03 or less ○: Greater than Δxy 0.03, 0.04 or less Δ: Greater than Δxy 0.04, 0.045 or less ×: Greater than Δxy 0.045 The results are shown in the table below.

As shown in the above table, the infrared light reflection plate of Example 1 in which the reflection center wavelength of the light reflection layer whose reflection wavelength band is on the short wavelength side is 850 nm or more exhibits high heat shielding performance, and the color of obliquely reflected light Taste change was suppressed. In Example 2 in which the center wavelength of the light reflection layer on the short wavelength side was set to 860 nm, although the heat shielding performance was slightly inferior, the color change of the oblique reflected light was further suppressed.
Comparative Example 1 in which the center wavelength of the light reflection layer on the short wavelength side is 840 nm and the reflectance at the wavelength of 790 nm exceeds the upper limit of the range defined in the present invention is compared with Examples 1 and 2. Although the heat shielding performance was slightly high, the color change of the oblique reflected light was greatly inferior.

<Manufacture of infrared light reflector 2>
[Example 3]
An infrared light reflector of Example 3 was prepared in the same procedure as Example 1 except that the order of the coating liquids to be applied was changed to the order of (R2), (R3), and (R1).

[Example 4]
An infrared light reflector of Example 4 was prepared in the same procedure as in Example 1 except that the order of the coating liquids to be applied was changed to the order of (R1), (R2), and (R3).

<Evaluation 2 of infrared light reflector>
[Reflectance measurement and thermal insulation performance evaluation 1]
About each produced infrared light reflection board, the reflectance of 790 nm, the reflectance of 875 nm, the reflectance of 1040 nm, the reflectance measurement of 1240 nm, and the thermal-insulation performance evaluation 1 were performed similarly to the above. The results are shown in the table below.

[Heat insulation performance evaluation 2]
About each produced infrared light reflector, 60 degree regular reflection spectrum and 60 degree transmission spectrum were measured with the spectrophotometer "V-670" by JASCO Corporation, and 60 degrees diagonal of the wavelength range of 300-2500 nm. The heat shielding performance (transmittance) for the solar radiation spectrum was calculated. The heat shielding performance was determined based on the following criteria (the solar radiation transmittance is preferably low).
◎: Solar spectrum transmittance 70% or less ○: Solar spectrum transmittance 70% or more, 80% or less Δ: Solar spectrum transmittance 80% or more, 85% or less ×: Solar spectrum transmittance 85% or less Shown in the table below.

[Slant reflection light color evaluation 1]
About each produced infrared light reflecting plate, the diagonal reflected light color evaluation 1 was performed similarly to the above. The results are shown in the table below.

  As shown in the above table, even if the order of the infrared light reflecting layers is changed, the reflectance and heat shielding performance in the front direction hardly change. However, there was a difference in the heat shielding performance at an angle of 60 ° and the light color change of the oblique reflection. By installing an infrared light reflection layer with a shorter reflection wavelength on the surface side, the heat shielding performance at 60 ° obliquely improves, while the color change of obliquely reflected light tends to be somewhat worse. Indicated.

<Manufacture of infrared light reflector 3>
[Example 5]
The infrared light reflector of Example 5 was produced in the same procedure as in Example 1 except that (R1) was changed to (L1) among the coating liquids to be applied.

[Example 6]
The infrared light reflector of Example 6 having the configuration shown in FIG. 2 was prepared in the same procedure as in Example 1 except that (R2) was changed to (L2) in the coating solution to be applied.

[Example 7]
The infrared light reflector of Example 7 was prepared in the same procedure as in Example 1 except that (R3) was changed to (L3) among the coating liquids to be applied.

<Evaluation of infrared light reflector 3>
[Reflectance measurement and thermal insulation performance evaluation 1]
About each produced infrared light reflection board, the reflectance of 790 nm, the reflectance of 875 nm, the reflectance of 1040 nm, the reflectance measurement of 1240 nm, and the thermal-insulation performance evaluation 1 were performed similarly to the above. The results are shown in the table below.

[Heat insulation performance evaluation 2]
About each produced infrared light reflecting plate, the heat-shielding performance evaluation 2 was performed similarly to the above. The results are shown in the table below.

[Slant reflection light color evaluation 1]
About each produced infrared light reflecting plate, the diagonal reflected light color evaluation 1 was performed similarly to the above. The results are shown in the table below.

As shown in the above table, Examples 5 to 7 including the light reflection layer in which the spiral direction of the cholesteric liquid crystal layer is different from each other show almost the same performance as that of Example 1 in terms of reflectance and heat shielding performance in the front direction. It was. However, there was a slight difference in the heat shielding performance at an oblique angle of 60 ° and the oblique reflected light color. By combining layers having different spiral directions of the cholesteric liquid crystal layer, the heat shielding performance at an angle of 60 ° was improved. Further, although the color of the oblique reflected light is slightly deteriorated, the degree is slight.

<Manufacture of infrared light reflector 4>
[Example 8]
(Production of half-wave retardation plate (λ / 2 plate))
A broadband λ / 2 plate (thickness: 73 μm) was produced with reference to Example 4 of JP-A-2002-40258.

(Preparation of infrared light reflector including λ / 2 plate)
A highly transparent adhesive transfer tape (baseless adhesive (adhesive material), thickness: 25 μm) manufactured by Sumitomo 3M Co., Ltd. is attached to the PET film side of the infrared light reflector produced in Example 1, and the adhesive is used. An attached infrared light reflector was prepared. The prepared infrared light reflecting plate with adhesive was attached to both surfaces so as to sandwich the broadband λ / 2 plate prepared above, and an infrared light reflecting plate of Example 8 having the configuration shown in FIG. 3 was produced. The total thickness of the infrared light reflector of Example 8 was 309 μm.

[Example 9]
A highly transparent adhesive transfer tape (baseless adhesive, thickness: 25 μm) manufactured by Sumitomo 3M Co., Ltd. is attached to the infrared light reflecting layer side of the infrared light reflecting plate produced in Example 1, with an adhesive. An infrared light reflector was produced. The prepared infrared light reflecting plate with adhesive is attached to both surfaces so as to sandwich the broadband λ / 2 plate prepared above, and then the PET film is peeled off from the infrared light reflecting plate, and the configuration shown in FIG. The infrared light reflector of Example 9 was prepared. The total thickness of the infrared light reflector of Example 9 was 159 μm.

[Example 10]
A highly transparent adhesive transfer tape (baseless adhesive, thickness: 25 μm) manufactured by Sumitomo 3M Co., Ltd. is attached to the infrared light reflecting layer side of the infrared light reflecting plate produced in Example 4, with an adhesive. An infrared light reflector was produced. The prepared infrared light reflecting plate with adhesive is attached to both surfaces so as to sandwich the broadband λ / 2 plate prepared above, and then the PET film is peeled off from the infrared light reflecting plate, and the configuration shown in FIG. The infrared light reflector of Example 10 (however, the positions of 14a and 18a are interchanged) was produced. The total thickness of the infrared light reflector of Example 10 was 159 μm.

[Comparative Example 2]
A highly transparent adhesive transfer tape (baseless adhesive, thickness: 25 μm) manufactured by Sumitomo 3M Co., Ltd. is attached to the infrared light reflecting layer side of the infrared light reflecting plate produced in Comparative Example 1, with an adhesive. An infrared light reflector was produced. The prepared infrared light reflecting plate with adhesive is stuck on both sides so as to sandwich the phase difference plate having the half-wave phase difference produced above, and then the PET film is peeled off from the infrared light reflecting plate. And the infrared-light reflecting plate of the comparative example 2 of the structure as described in FIG. 4 was produced. The total thickness of the infrared light reflector of Comparative Example 2 was 159 μm.

[Example 11]
Using the coating solutions (R1), (R2), and (R3) and following the procedure of Example 1, using the broadband λ / 2 plate produced in Example 8 as a substrate, the order of (R3), (R2), and (R1) The coating was performed. Coating was performed on both sides of the broadband λ / 2 plate, and an infrared light reflection plate of Example 11 having the configuration shown in FIG. 5 was produced. The total thickness of the infrared light reflector of Example 11 was 109 μm.

<Evaluation of infrared light reflector 4>
[Reflectance measurement and thermal insulation performance evaluation 1]
About each produced infrared light reflection board, the reflectance of 790 nm, the reflectance of 875 nm, the reflectance of 1040 nm, the reflectance measurement of 1240 nm, and the thermal-insulation performance evaluation 1 were performed similarly to the above. Among them, the results of reflectance measurement at 790 nm and thermal insulation performance evaluation 1 are shown in the table below.

[Heat insulation performance evaluation 2]
About each produced infrared light reflecting plate, the heat-shielding performance evaluation 2 was performed similarly to the above. The results are shown in the table below.

[Slant reflection light color evaluation 1]
About each produced infrared light reflecting plate, the diagonal reflected light color evaluation 1 was performed similarly to the above. The results are shown in the table below.

[Haze]
About the produced infrared light reflecting plate, haze was measured with Nippon Denshoku Industries Co., Ltd. haze meter "NDH2000". The haze was determined based on the following criteria (the haze is preferably lower).
◎: Haze 0.5% or less ○: Haze greater than 0.5%, 0.8% or less △: Haze greater than 0.8%, 1.0% or less ×: Haze greater than 1.0% Shown in the table below.

  Moreover, the reflectance of 875 nm of the infrared light reflector of Example 8 was 88.1%, the reflectance of 1040 nm was 85.3%, and the reflectance of 1240 nm was 86.3%. In the infrared light reflector of Example 9, the reflectance at 875 nm was 88.2%, the reflectance at 1040 nm was 85.1%, and the reflectance at 1240 nm was 88.7%. The reflectance of 875 nm of the infrared light reflector of Example 10 was 87.7%, the reflectance of 1040 nm was 85.7%, and the reflectance of 1240 nm was 88.3%. In the infrared light reflector of Example 11, the reflectance at 875 nm was 88.3%, the reflectance at 1040 nm was 85.9%, and the reflectance at 1240 nm was 86.5%.

As shown in the above table, an infrared light reflector produced by sandwiching a λ / 2 plate between two infrared light reflectors has greatly improved thermal insulation performance. Although the color of obliquely reflected light has deteriorated, it can be seen that the heat shielding performance at 60 ° obliquely has been greatly improved, and the heat shielding performance is improved as an infrared light reflector. Further, in Examples 9 and 10 prepared by peeling off the PET film, the haze was suppressed to be lower and the heat shielding performance was slightly improved as compared with Example 8 prepared by pasting together the PET film.
Further, in Example 11 in which the light reflection layer was directly installed using the λ / 2 plate as a substrate, the haze was suppressed to be lower.

<Manufacture of infrared light reflector 5>
[Example 12]
An infrared light reflector of Example 12A was produced in the same procedure as Example 1 except that the order of the coating liquids to be applied was changed to the order of (L1), (R2), and (R3). Next, an infrared light reflector of Example 12 was produced in the same procedure as Example 10 except that the infrared light reflector of Example 4 was changed to the infrared light reflector of Example 12A produced. . The total thickness of the infrared light reflector of Example 12 was 159 μm.

[Example 13]
An infrared light reflector of Example 13A was produced in the same procedure as Example 1 except that the order of the coating liquids to be applied was changed to the order of (R1), (L2), and (R3). Subsequently, the infrared light reflector of Example 13 was produced in the same procedure as in Example 10 except that the infrared light reflector of Example 4 was changed to the infrared light reflector of Example 13A thus produced. . The total thickness of the infrared light reflector of Example 13 was 159 μm.

[Example 14]
An infrared light reflector of Example 14A was produced in the same procedure as Example 1 except that the order of the coating liquids to be applied was changed to the order of (R1), (R2), and (L3). Subsequently, the infrared light reflector of Example 14 was produced in the same procedure as Example 10 except that the infrared light reflector of Example 4 was changed to the infrared light reflector of Example 14A produced. . The total thickness of the infrared light reflector of Example 14 was 159 μm.

<Evaluation 5 of Infrared Light Reflector>
[Reflectance measurement and thermal insulation performance evaluation 1]
About each produced infrared light reflection board, the reflectance of 790 nm, the reflectance of 875 nm, the reflectance of 1040 nm, the reflectance measurement of 1240 nm, and the thermal-insulation performance evaluation 1 were performed similarly to the above. Among them, the results of reflectance measurement at 790 nm and thermal insulation performance evaluation 1 are shown in the table below.

[Heat insulation performance evaluation 2]
About each produced infrared light reflecting plate, the heat-shielding performance evaluation 2 was performed similarly to the above. The results are shown in the table below.

[Slant reflection light color evaluation 1]
About each produced infrared light reflecting plate, the diagonal reflected light color evaluation 1 was performed similarly to the above. The results are shown in the table below.

[Haze]
About each produced infrared-light reflecting plate, haze measurement was performed similarly to the above. The results are shown in the table below.

  Moreover, the reflectance of 875 nm of the infrared light reflector of Example 12 was 89.5%, the reflectance of 1040 nm was 88.0%, and the reflectance of 1240 nm was 86.8%. In the infrared light reflector of Example 13, the reflectance at 875 nm was 87.6%, the reflectance at 1040 nm was 88.3%, and the reflectance at 1240 nm was 89.4%. The infrared light reflecting plate of Example 14 had a reflectance of 875 nm of 89.3%, a reflectance of 1040 nm was 85.4%, and a reflectance of 1240 nm was 85.2%.

  As shown in the above table, Examples 12 to 14 including the light reflecting layer in which the spiral direction of the cholesteric liquid crystal layer is different are substantially the same as those in Example 10 in terms of the reflectance and heat shielding performance in the front direction. However, the heat shielding performance at an angle of 60 ° was improved. Moreover, the deterioration of the color of oblique reflected light was also suppressed. In particular, in Example 13, in which the spiral directions of the cholesteric liquid crystal layers are alternated, the red light is substantially red (considering that the direction of transmitted circularly polarized light is reversed) by sandwiching the λ / 2 plate. The spiral directions of all six layers of the external light reflecting layer were alternated, and the degree of improvement in heat shielding performance was large, and the oblique reflected light color was further suppressed.

<Production of infrared light reflector, laminated interlayer sheet for laminated glass, laminated glass>
[Example 15]
(Preparation of coating solution for easy adhesion layer)
A coating solution for an easy-adhesion layer having the composition shown below was prepared.
Polyvinyl butyral resin B1776 (Changchun Co., Ltd. (Taiwan)) 10 parts by mass Methoxypropyl acetate (PGMEA) 100 parts by mass

(Production of infrared light reflector)
Apply the coating liquid for easy adhesion layer prepared above on the surface (both sides) of the infrared light reflector prepared in Example 8 using a wire bar so that the film thickness after drying becomes 1.0 μm. did. Then, it heated at 150 degreeC for 10 minute (s), dried and solidified, the easily bonding layer was formed, and the infrared-light reflecting plate of Example 15 was produced.

(Production of laminated interlayer film for glass and laminated glass)
Next, it is sandwiched between the infrared light reflector produced above and a polyvinyl butyral interlayer film for laminated glass (thickness: 380 μm) and laminated using a laminator (manufactured by Taisei Laminator) (heating temperature: 80 ° C., added temperature). (Pressure: 1.5 kg / cm ² , Conveying speed: 0.1 m / min), a laminated interlayer film sheet for glass of Example 15 was produced.
Next, the laminated interlayer film for glass of Example 15 prepared above was sandwiched between two clear glasses (thickness: 2 mm), placed in a rubber bag, and decompressed with a vacuum pump. Thereafter, the temperature was raised to 90 ° C. under reduced pressure, held for 30 minutes, and then returned to normal temperature and pressure. Thereafter, it was kept in an autoclave for 20 minutes under conditions of a pressure of 1.3 MPa and a temperature of 130 ° C. This was returned to normal temperature and normal pressure, and the laminated glass of Example 15 with an infrared-light reflective function was produced.

[Example 16]
A laminated glass of Example 16 with an infrared light reflecting function was produced in the same procedure as in Example 15 except that the infrared light reflecting plate of Example 8 was changed to the infrared light reflecting plate of Example 10. .

[Example 17]
A laminated glass of Example 17 with an infrared light reflecting function was produced in the same procedure as in Example 15 except that the infrared light reflecting plate of Example 8 was changed to the infrared light reflecting plate of Example 11. .

[Example 18]
Of the two clear glasses, the example is the same except that the clear glass on the PET film substrate side of the infrared light reflector is changed to heat ray absorbing glass (visible light transmittance 85% with standard A light source, main wavelength 550 nm). The laminated glass of Example 18 with an infrared light reflection function was produced in the same procedure as in Example 15.

<Evaluation of laminated glass>
[Visible light transmittance]
Measure the front transmission spectrum on the cholesteric liquid crystal phase reflection layer side of each of the produced laminated glasses with infrared light reflection function in accordance with JIS-R3211, using a spectrophotometer "V-670" manufactured by JASCO Corporation. The visible light transmittance with respect to the standard light source A was calculated. Visible light transmittance was determined based on the following criteria.
○: Visible light transmittance of 70% or more ×: Visible light transmittance of less than 70% The results are shown in the table below.

[Heat insulation performance evaluation 3]
About each produced laminated glass with an infrared light reflection function, the spectrophotometer "V-670" by JASCO Corporation measured the 5 degree regular reflection spectrum and front transmission spectrum by the side of a cholesteric liquid crystal phase reflection layer. The heat shielding performance (transmittance) for the solar radiation spectrum in the wavelength range of 300 to 2500 nm was calculated. The heat shielding performance was determined based on the following criteria (the solar radiation transmittance is preferably low).
◎: Solar spectrum transmittance 50% or less ○: Solar spectrum transmittance 50% or more, 60% or less Δ: Solar spectrum transmittance 60% or more, 70% or less ×: Solar spectrum transmittance 70% or less Shown in the table below.

[Slant reflection light color evaluation 2]
About each produced laminated glass with an infrared light reflection function, the 60 degree specular reflection spectrum by the side of a cholesteric-liquid-crystal phase reflection layer is measured with JASCO Corporation spectrophotometer "V-670", and with respect to D65 standard light source After calculating the tint, the degree of variation Δxy from the standard white point (x = 0.3127, y = 0.3290) on the xy chromaticity diagram was calculated. The effect of suppressing the oblique reflected light color was determined based on the following criteria.
：: Δxy 0.04 or less ○: Greater than Δxy 0.04, 0.05 or less Δ: Greater than Δxy 0.05, 0.06 or less ×: Greater than Δxy 0.06 The results are shown in the table below.

As shown in the above table, in Examples 15 to 18, by making a laminated glass, higher heat shielding performance and oblique reflection compared to the film forms of Examples 8, 10 and 11 before being sandwiched in the laminated glass. The light tint suppression effect was shown.
In particular, Example 18 in which laminated glass was formed using heat-absorbing glass having absorption in the visible light region showed very high heat shielding performance.
In Example 15, since the total thickness of the infrared light reflector was 300 μm or more (about 311 μm), the handleability in the laminated glass production process was poor and there was a work load. On the other hand, in Examples 16 and 18, the total thickness of the infrared light reflector was about 160 μm, the handleability was good, and the work load in the laminated glass production process was small. Furthermore, in Example 17, the total thickness of the infrared light reflecting plate was about 110 μm, the handleability was further improved, and the work load in the laminated glass production process was considerably reduced.

From the above results, it was shown that according to the examples of the present invention, it is possible to obtain an infrared light reflector that has excellent heat shielding performance and suppresses the color of reflected light in an oblique direction.
Moreover, when using laminated glass, it was also shown that the heat shielding performance is further improved by using heat ray absorbing glass having absorption in the visible light region.

12 Substrate 14a Light reflecting layer (light reflecting layer X1)
16a and 16b Light reflection layer (light reflection layer X2)
18a Light reflection layer (light reflection layer X3)
Retardation plate (λ / 2 plate) having a phase difference of 22 1/2 wavelengths
32 Adhesive

Claims (16)

Having a light reflection layer formed by fixing a cholesteric liquid crystal phase;
The cholesteric liquid crystal phase light reflecting layer formed of a fixed reflectance at a wavelength of 1240nm of 40% or more, the reflectance at a wavelength of 1040nm is on 40% or more, the reflectance at a wavelength of 875nm 40% or more, wavelength The reflectance at 790 nm is 10% or less, and
An infrared light reflecting layer that reflects infrared rays.   A light reflection layer X1, a light reflection layer X2, and a light reflection layer X3 each having a fixed cholesteric liquid crystal phase; the reflection center wavelength λ1 (nm) of the light reflection layer X1 is in the range of 1190 to 1290 nm; The reflection center wavelength λ2 (nm) of the light reflection layer X2 is in the range of 1010 to 1070 nm; the reflection center wavelength λ3 (nm) of the light reflection layer X3 is in the range of 850 to 900 nm. The infrared light reflection layer according to 1.   At least one of the light reflecting layers is a layer formed by fixing a cholesteric liquid crystal phase using a liquid crystal composition laminated on the surface of the lower light reflecting layer as a cholesteric liquid crystal phase. The infrared light reflective layer according to claim 1, wherein the infrared light reflective layer is provided.   4. The spiral direction of one of the light reflective layers is different from the spiral direction of the other two light reflective layers. 5. Infrared light reflection layer.   The infrared light reflection layer according to any one of claims 1 to 4, wherein in the light reflection layer, the spiral directions of adjacent light reflection layers are different from each other.   An infrared light reflecting plate comprising the substrate and the infrared light reflecting layer according to claim 1 disposed on at least one surface of the substrate.   The infrared light reflector according to claim 6, wherein the substrate is a polymer film.   The infrared light reflector according to claim 6 or 7, wherein the substrate is a retardation plate having a phase difference of ½ wavelength. The infrared light reflection layer according to any one of claims 1 to 5 or the infrared light reflection plate according to any one of claims 6 to 8,
A laminated interlayer sheet for glass, comprising: an interlayer film disposed on at least one outermost layer of the infrared light reflecting layer or the infrared light reflecting plate.   The laminated interlayer sheet for glass according to claim 9, further comprising an interlayer sheet on outermost layers of both the infrared light reflecting layer and the infrared light reflecting plate.   A laminated glass comprising two glasses and the laminated interlayer film sheet for glass according to claim 9 or 10 disposed between the two glasses. Of the two glasses, at least one is heat-absorbing glass,
The heat ray absorbing glass has a visible light transmittance of 80 to 90% in a standard A light source, and a main wavelength measured using the standard A light source is in a range of 495 to 560 nm. Item 11. The laminated glass according to Item 11. The 1st process of bonding the 1st interlayer film sheet on one surface of the infrared light reflector according to any one of claims 6 to 8, and obtaining the 1st layered product, and
It includes a second step of bonding a second interlayer film on the surface opposite to the surface on which the first interlayer sheet of the first laminate is bonded. A method for producing a laminated interlayer sheet for laminated glass. Using an infrared light reflector in which a substrate is disposed only on one surface as the infrared light reflector,
The first step is a step of bonding the first intermediate film sheet to a surface opposite to the surface on which the substrate of the infrared light reflection plate is disposed; and the infrared light reflection plate; Including the step of peeling the substrate contained in the infrared light reflector from the first laminate simultaneously with or after the step of laminating the first intermediate film sheet,
The said 2nd process includes the process of bonding the said 2nd intermediate film sheet to the surface which peeled the said board | substrate of the said 1st laminated body, The lamination | stacking intermediate | middle for glass of Claim 13 characterized by the above-mentioned. Manufacturing method of membrane sheet. A step of producing a laminated body sandwiched between two glass plates by sandwiching the laminated interlayer film sheet for glass according to claim 9 or 10 between the glass plates;
The manufacturing method of a laminated glass including the process of crimping | bonding the laminated body pinched | interposed between the said glass plates, heating.   The infrared light reflecting layer according to any one of claims 1 to 5, the infrared light reflecting plate according to any one of claims 6 to 8, and the laminated intermediate for glass according to claim 9 or 10. The member for windows for buildings or vehicles using the membrane sheet or the laminated glass of Claim 11 or 12.