JP5693061B2 - Exhaust gas treatment equipment - Google Patents

Description

  The present invention relates to an exhaust gas treatment apparatus that oxidizes mercury contained in exhaust gas discharged from a boiler or the like.

The exhaust gas generated when burning coal-fired exhaust gas or heavy oil may contain metal mercury (Hg ⁰ ) in addition to soot, sulfur oxide (SOx), and nitrogen oxide (NOx). In recent years, various devices have been devised for a method and apparatus for treating metallic mercury in combination with a denitration apparatus that reduces NOx and a wet desulfurization apparatus that uses an alkaline absorbent as an SOx absorbent.

As a method of treating metallic mercury in exhaust gas, in the flue, an ammonium (NH ₃ ) solution is sprayed on the upstream side of a high-temperature denitration device to reduce NOx, and an oxidizing aid such as a hydrochloric acid (HCl) solution is sprayed. Then, a system has been proposed in which mercury is oxidized (chlorinated) on a denitration catalyst to form water-soluble mercury chloride, and then mercury is removed by a wet desulfurization apparatus installed on the downstream side (for example, Patent Documents) 1).

  Further, as a method of supplying HCl, a hydrochloric acid (HCl) solution is vaporized using a hydrogen chloride (HCl) vaporizer to form hydrogen chloride (HCl) gas, adjusted to a mixed gas containing HCl of a predetermined concentration, and then mixed gas Is dispersed in the flue and sprayed uniformly in an exhaust gas containing mercury (see, for example, Patent Document 2).

As another method of supplying HCl, ammonium chloride (NH ₄ Cl) is added in powder form into the flue on the upstream side of the denitration device, and NH ₄ Cl is sublimated by the high-temperature ambient temperature of the exhaust gas, and HCl is added. There is a method in which ammonia (NH ₃ ) is vaporized, and the vaporized HCl gas and NH ₃ gas are mixed with the exhaust gas (see, for example, Patent Document 3).

In the method for treating metallic mercury in the exhaust gas as described above, when a hydrochloric acid solution is used, since hydrochloric acid is a dangerous substance, there is a problem that labor and cost such as transportation and handling are required. In addition, when an HCl vaporizer is used, steam or the like is required as a heat source, and there is a problem that costs such as equipment, operation, maintenance and the like such as an HCl vaporizer are required. Further, in the case of using NH ₄ Cl powder, since it is necessary to disperse the particle size finely, there is a problem that handling is difficult and the control of the spray amount is not easy.

Japanese Patent Laid-Open No. 10-230137 JP 2007-167743 A JP 2008-221087

Therefore, in recent years, in order to oxidize Hg ⁰ with a denitration catalyst, an ammonium chloride (NH ₄ Cl) solution is used as a liquid instead of supplying ammonium chloride (NH ₄ Cl) powder on the upstream side of the denitration device. The method of spraying with is being studied. Compared to the conventional method using a hydrochloric acid solution, the NH ₄ Cl solution is less dangerous and therefore easy to transport and handle. In addition, since the liquid is sprayed, no equipment such as a vaporizer is required, and the cost is low. Can be reduced.

  However, when ammonium chloride is sprayed in a liquid state, immediately after the spraying, the liquid droplets collide with the flue inner wall or the flue structure, and a thermal shock is generated due to instantaneous heat shrinkage. The wall may be damaged.

In view of the above problems, the present invention prevents mercury from colliding with a flue or the like when ammonium chloride (NH ₄ Cl) is sprayed in a liquid state, while reducing mercury and reducing nitrogen oxides. An object of the present invention is to provide an exhaust gas treatment apparatus capable of maintaining performance.

A first invention of the present invention that solves the above-mentioned problems is an exhaust gas treatment device that removes nitrogen oxides and mercury contained in exhaust gas from a boiler, and is vaporized in a flue downstream of the boiler. A reducing oxidation assistant supplying means for spraying liquid ammonium chloride that generates oxidizing gas and reducing gas in a liquid state with a spray nozzle; and reducing nitrogen oxide in the exhaust gas with the reducing gas; A reduction denitration means having a denitration catalyst that oxidizes mercury in the presence of the oxidizing gas, a wet desulfurization means for removing mercury oxidized in the reduction denitration means using an alkaline absorbent, and upstream of the spray nozzle provided on the side, it has a a mixer providing a disturbance in the gas flow of the exhaust gas, ammonium chloride supply pipe for supplying the ammonium chloride solution to the spray nozzle, the chloride ammonium A double pipe structure having an air supply pipe covering the periphery of the air supply pipe, cooling air is supplied from the air supply section to the spray nozzle through the air supply pipe, and is supplied to the spray nozzle. that said certain ammonium chloride solution to the exhaust gas treatment device according to claim Rukoto such cooled.

A second invention is the exhaust gas processing apparatus according to the first invention, wherein the nozzle hole of the spray nozzle is provided at a position separated from the wall surface of the flue by 0.5 m or more.

A third invention is the exhaust gas treatment apparatus according to the first or second invention, wherein the mixer has a lattice shape.

According to a fourth invention, in the first or second invention, the mixer is installed in a flue and arranged so as to form two opposing faces of a quadrangular pyramid having a vertex on the downstream side of the gas flow. Two opposing faces of a triangular pyramid, two opposite faces of a quadrangular pyramid that contact the vertex and the bottom face is located on the downstream side of the gas flow, opposite the two opposing faces on the upstream side and twisted 90 degrees. The lattice elements constituted by the triangular plates forming the planes are arranged in parallel to each other in a direction perpendicular to the fluid flow by changing the direction of adjacent lattice elements by 90 degrees in all lattice elements arranged in the fluid flow path. The bottom surfaces of the quadrangular pyramids are connected to form a lattice, and the ratio (L / B) of the width (B) perpendicular to the fluid flow of the lattice element to the length (L) parallel to the fluid flow of the lattice element is It exists in the range of 1.5-2.0, It exists in the waste gas processing apparatus characterized by the above-mentioned.

5th invention is 1st or 2nd invention. WHEREIN: The said mixer has a pair of 1st swirl flow induction board which has an opposing surface on the inlet_port | entrance side of the said waste gas, and an opposing surface on the exhaust_gas | exhaustion side of the said exhaust gas A pair of second swirl flow inducing plates, and a connecting portion connecting the first swirl flow inductive plate and the second swirl flow inducting plate; In the exhaust gas treatment apparatus, the swirl flow inducing members are connected so as to be different from the facing surface of the second swirl flow inducing plate.

A sixth invention is the fifth invention, wherein
An exhaust gas treatment apparatus, wherein a width L and a height D of the swirl flow inducing member are within the ranges of the following formulas (1) and (2).
MIN (B, H) / 10 ≦ L ≦ MIN (B, H) (1)
MIN (B, H) / 10 ≦ D ≦ 5 × MIN (B, H) (2)
However, B is the long side of the cross section of the flue at the installation position, H is the short side of the cross section of the flue, MIN (B, H) is the long side B of the cross section of the flue, the cross section of the flue This is the shorter side of the short sides H. When the long side B and the short side H of the cross section of the flue have the same length, either may be used.
A seventh invention is the exhaust gas treatment apparatus according to any one of the first to sixth inventions, wherein a protective wall is provided in the vicinity of the spray nozzle along the inner wall of the flue.

According to the present invention, when the reducing oxidation aid that generates oxidizing gas and reducing gas when vaporized in the flue downstream of the boiler is sprayed in liquid form from the spray nozzle, it is more effective than the spray nozzle. A mixer is provided on the upstream side, the gas flow is disturbed, and a velocity other than the axial flow is applied to the droplets sprayed from the spray nozzle, thereby improving the heat transfer rate and promoting evaporation.
By promoting the evaporation of the ammonia chloride droplets, collision with the inner wall of the flue and the flue internal structure will be prevented, and damage to the flue caused by corrosion of the flue may be prevented. it can.

FIG. 1 is a schematic diagram illustrating a configuration of an exhaust gas treatment apparatus according to Embodiment 1 of the present invention. FIG. 2 is a schematic view of the arrangement of the mixer and the spray nozzle. FIG. 3 is a schematic view of a grid mixer. FIG. 4 is a main part configuration diagram of the mixer according to the present invention. FIG. 5 is a front view according to the overall configuration of the mixer. 6 is a view taken along the line AA in FIG. FIG. 7 shows experimental data of the lattice element, mixing performance, and pressure loss characteristics of Example 2. FIG. 8 is a plan view illustrating an example of the mixer according to the third embodiment. FIG. 9 is a plan view of a swirl flow inducing member constituting the mixer. FIG. 10 is a front view of the swirling flow inducing member. FIG. 11 is a perspective view of the swirling flow inducing member. FIG. 12 is a diagram schematically showing the gas flow of exhaust gas when the mixer is installed in the flue. FIG. 13 is a partially enlarged view of FIG. FIG. 14 is a diagram illustrating the relationship between the pressure loss of the mixer and the dimensions of the mixer.

  Hereinafter, the present invention will be described in detail with reference to the drawings. Note that the present invention is not limited to the embodiments. In addition, constituent elements in the following embodiments include those that can be easily assumed by those skilled in the art or those that are substantially the same.

An exhaust gas treatment apparatus according to Embodiment 1 of the present invention will be described with reference to the drawings.
FIG. 1 is a schematic diagram illustrating a configuration of an exhaust gas treatment apparatus according to Embodiment 1 of the present invention. FIG. 2 is a schematic view of the arrangement of the mixer and the spray nozzle.
As shown in FIG. 1, an exhaust gas treatment apparatus 100 according to the present embodiment is an exhaust gas treatment apparatus that removes nitrogen oxides (NOx) and mercury (Hg) contained in exhaust gas 12 from a boiler 11. Ammonium chloride is sprayed in a liquid state by a plurality of spray nozzles 15 in a flue 13 downstream of 11 with an ammonium chloride (NH ₄ Cl) solution 14 containing ammonium chloride (NH ₄ Cl) as a liquid reducing oxidation aid. (NH ₄ Cl) solution supply means (reduction oxidation aid supply means) 16 and NOx in the exhaust gas 12 is reduced with ammonia (NH ₃ ) gas as a reducing gas, and hydrogen chloride (HCl) gas as an oxidizing gas A reduction denitration device (reduction denitration means) 18 having a denitration catalyst that oxidizes Hg in the presence of heat, a heat exchanger (air heater) 19 that exchanges heat with the denitrated exhaust gas 12, A dust collector 20 that removes soot and dust in the nitrified exhaust gas 12, a wet desulfurization device 22 that removes Hg oxidized in the reductive denitration device 18 by using a lime gypsum slurry 21 as an alkali absorbing liquid, and the spray nozzle 15 And a mixer 60 that is provided on the upstream side and that disturbs the gas flow of the exhaust gas 12.

In the exhaust gas treatment apparatus 100 according to the present embodiment, NH ₄ Cl is used as the reduction oxidation aid, but the present invention is not limited to this, and the reduction oxidation aid is oxidized when vaporized. Any gas that can generate a reactive gas and a reducing gas can be used.
Further, in the present invention, the reducing oxidation aid means an oxidation aid used for oxidizing and chlorinating mercury (Hg) in the presence of an oxidizing gas, and a reducing agent that reduces NOx with the reducing gas. As a function.
In this embodiment, HCl gas is used as the oxidizing gas, and NH ₃ gas is used as the reducing gas.

The flue gas 12 discharged from the boiler 11, solution _of NH ₄ Cl 14 is supplied from the solution _of NH ₄ Cl supply unit 16. The NH ₄ Cl solution supply means 16 compresses the NH ₄ Cl solution 14 into the flue 13 and an ammonium chloride (NH ₄ Cl) solution supply pipe 25 that supplies the NH ₄ Cl solution 14 in a liquid state into the flue 13. The air supply pipe 27 for supplying the air 26 to be sprayed into the flue 13, the ammonium chloride (NH ₄ Cl) solution supply pipe 25, and the tip of the air supply pipe 27 are attached to the NH ₄ Cl solution 14 and the air. And a spray nozzle 15 for injecting 26.

The NH ₄ Cl solution 14 is adjusted to a predetermined concentration in an ammonium chloride (NH ₄ Cl) solution tank 28. The flow rate of the NH ₄ Cl solution 14 supplied from the NH ₄ Cl solution supply pipe 25 is adjusted by a valve V1. The NH ₄ Cl solution 14 passes through the NH ₄ Cl solution supply pipe 25 from the NH ₄ Cl solution tank 28 and is sprayed into the flue 13 from the spray nozzle 15.

  In this embodiment, as shown in FIGS. 1 and 2, the mixer 60 is provided on the upstream side of the spray nozzle 15, the gas flow of the exhaust gas 12 is disturbed (for example, Karman vortex), and the velocity other than the axial flow is provided. Is applied to the spray droplets sprayed from the spray nozzle 15.

  The exhaust gas 12 is first stirred by the mixer 60. Thereafter, the stirred exhaust gas 12 becomes unsteady and is supplied to the spray zone of the flue 13.

Here, although the shape of the mixer 60 is not specifically limited, it demonstrates with reference to drawings as an example.
FIG. 3 is a schematic view of a grid mixer.
As shown in FIG. 3, the mixer 60A according to the present embodiment has cylinders 61 and 62 assembled in a lattice shape.
Further, by installing this grid-shaped mixer 60A, as shown in FIG. 2, turbulence is generated by vortices generated in the wake of the gas flow of the exhaust gas 12 of the mixer 60A composed of the cylinders 61 and 62. It becomes.

As a result of disturbing the gas flow with respect to the NH ₄ Cl solution 14 sprayed from the NH ₄ Cl solution supply means 16, a velocity other than the axial flow is given to the spray droplets, and the heat transfer coefficient is improved. Promotes evaporation.

In the gas flow in which only the axial flow component of the gas is present in the flue 13, it is considered that the sprayed droplets directly ride on the flow and the relative layer degree with the gas becomes small. That is, it becomes difficult for the droplets to evaporate.
On the other hand, by providing the mixer 60A and mixing the exhaust gas 12, the gas flow is disturbed and the velocity other than the axial flow is given to the droplets, thereby improving the heat transfer coefficient and promoting evaporation. Will be allowed to. In other words, since the gas collides with and interferes with the droplet from various directions, the droplet is easily evaporated.

Thus, by agitating the exhaust gas 12 in advance in the mixer 60A, it is possible to accelerate the evaporation and mixing of the HCl gas, NH ₃ gas into the flue gas 12, HCl gas in the flue gas 12, the concentration distribution of the NH ₃ gas uniformly can do.
By promoting the evaporation of the ammonia chloride droplets, collision with the duct wall and the internal structure is prevented, and damage to the flue caused by corrosion of the flue can be prevented.

  Further, by appropriately adjusting the installation distance between the mixer 60A and the spray nozzle 15, the strength of the turbulent field applied to the droplets can be adjusted to some extent.

Under general plant operating conditions, the mixer 60A is preferably provided 1 m or more upstream from the supply position for supplying the NH ₄ Cl solution 14.
Further, it is desirable that the mixer 60A is about 10 m from the supply position of the NH ₄ Cl solution 14 from the viewpoint of realistic equipment arrangement.

Generally, when the droplet diameter of the NH ₄ Cl solution 14 is about 40 μm, the time t until the droplet evaporates is about 0.032 s, and the time until the droplet of the NH ₄ Cl solution 14 evaporates. The moving distance L is supposed to be about 0.76 m in a direction parallel to the flow of the exhaust gas 12 from the spray nozzle 15.
When the droplet diameter of the NH ₄ Cl solution 14 is about 60 μm, the time t until the droplet evaporates is about 0.068 s, and the time until the droplet of the NH ₄ Cl solution 14 evaporates. The moving distance L is supposed to be about 1.6 m in a direction parallel to the flow of the exhaust gas 12 from the spray nozzle 15.
When the droplet diameter of the NH ₄ Cl solution 14 is about 80 μm, the time t until the droplet evaporates is about 0.119 s, and the time until the droplet of the NH ₄ Cl solution 14 evaporates. The moving distance L is supposed to be about 2.7 m from the spray nozzle 15 in the spray direction.

In addition, in order to protect the wall surface of the flue 13 around the position where the NH ₄ Cl solution 14 is ejected from thermal shock, the mixer 60 is installed upstream even when the wall surface of the flue is doubled with carbon steel or the like. This makes it possible to reduce the duplex area.

Further, in the NH ₄ Cl solution supply means 16 in the present embodiment, the spray nozzle 15 is arranged to supply the NH ₄ Cl solution 14 so as not to adhere to the inner wall of the flue 13 through which the exhaust gas 12 flows.
As an arrangement for supplying the NH ₄ Cl solution 14 so as not to adhere to the inner wall of the flue 13 through which the exhaust gas 12 flows, the spray nozzle 15 is placed in the flue 13 at a certain distance from the inner wall of the flue 13. It is preferable that the structure is arranged. The distance equal to or greater than a certain distance is a distance sufficient to vaporize the droplets of the NH ₄ Cl solution 14 to be sprayed before reaching the inner wall of the flue 13 from the spray nozzle 15.
Considering the actual flue size and actual processing conditions, the nozzle hole of the spray nozzle 15 is preferably provided at a position separated from the wall surface of the flue 13 by 0.5 m or more, for example.

The positions of the nozzle holes of the spray nozzle 15 that are separated from the wall surface of the flue 13 by 0.5 m or more are the gas flow rate of the exhaust gas 12 and the initial droplet velocity of the NH ₄ Cl solution 14 sprayed from the spray nozzle 15. This is because the droplet diameter, the injection angle of the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 with respect to the flue 13, the exhaust gas temperature of the exhaust gas 12, the droplet temperature of the NH ₄ Cl solution 14, etc. need to be considered. .

The spray nozzle 15 is a two-fluid nozzle that injects the NH ₄ Cl solution 14 and the compression air 26 simultaneously. The air 26 is supplied from the air supply unit 31 to the spray nozzle 15 via the air supply pipe 27 and is used as compression air when the NH ₄ Cl solution 14 is sprayed from the spray nozzle 15. Thereby, the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 can be sprayed as fine droplets into the flue 13 by the air 26.

Further, the flow rate of the air 26 supplied from the air supply pipe 27 is adjusted by the valve V2. The size of the droplets of the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 can be adjusted by the flow rate of the air 26 supplied from the air supply pipe 27.

Moreover, it is preferable that the flow rate of the air 26 injected from the spray nozzle 15 is, for example, an air / water ratio of 100 to 10,000 (volume ratio). This is because the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 is sprayed into the flue 13 as fine droplets.

The droplets of the NH ₄ Cl solution 14 sprayed into the flue 13 from the spray nozzle 15 evaporate due to the high-temperature atmosphere temperature of the exhaust gas 12 to generate fine NH ₄ Cl solid particles. As in 1), it decomposes into HCl and NH ₃ and sublimes. Therefore, by spraying the NH ₄ Cl solution 14 from the spray nozzle 15, HCl and NH ₃ are generated from the droplets of the sprayed NH ₄ Cl solution 14, and NH ₃ gas and HCl gas are supplied into the flue 13. can do.
NH ₄ Cl → NH ₃ + HCl (1)

Moreover, the temperature of the exhaust gas 12 in the flue 13 is 320 degreeC or more and 420 degrees C or less, for example, and is high temperature. The periphery of the NH ₄ Cl solution supply pipe 25 is a double pipe, and cooling air is supplied from the air supply unit 36 to the spray nozzle 15 via the air supply pipe 34 to cool the NH ₄ Cl solution 14. Yes. For this reason, the NH ₄ Cl solution 14 is maintained in a liquid state until immediately before being sprayed from the spray nozzle 15, and the NH ₄ Cl solution 14 is sprayed in droplets from the spray nozzle 15, so that the high temperature ambient temperature of the exhaust gas 12 The droplets of the sprayed NH ₄ Cl solution 14 can be vaporized.

The droplet diameter of the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 is preferably a fine droplet having an average of 1 nm or more and 100 μm or less. By generating fine droplets of 1 nm or more and 100 μm or less on average, NH ₄ Cl solid particles generated from the droplets of the sprayed NH ₄ Cl solution 14 can be converted into NH ₃ , HCl in the exhaust gas 12 with a short residence time. It can be decomposed and sublimated. Thereby, since it is not necessary to heat the NH ₄ Cl solution 14 in advance, it is possible to prevent the flue 13 and the spray nozzle 15 from being lowered and corroded.

The NH ₄ Cl solution 14 can be generated by dissolving ammonium chloride (NH ₄ Cl) powder in water. By adjusting the supply amounts of the NH ₄ Cl powder and water, the NH ₄ Cl solution 14 having a predetermined concentration can be adjusted. The NH ₄ Cl solution 14 may be generated by mixing an HCl solution and an NH ₃ solution at a predetermined concentration ratio.

  The temperature of the exhaust gas 12 in the flue 13 depends on the combustion conditions of the boiler 11, but is preferably 320 ° C. or higher and 420 ° C. or lower, more preferably 320 ° C. or higher and 380 ° C. or lower, and 350 ° C. or higher and 380 ° C. or lower. Further preferred. This is because the NOx denitration reaction and the Hg oxidation reaction can efficiently occur simultaneously on these denitration catalysts in these temperature zones.

Therefore, a solution _of NH ₄ Cl 14 in a liquid state from the spray nozzle 15 by supplying into lest flue 13 attached to the inner wall of the flue 13, a solution _of NH ₄ Cl 14 was decomposed by the high temperature ambient temperature of the flue gas 12 Since HCl gas and NH ₃ gas can be uniformly supplied into the flue 13 without unevenness in concentration, the concentration distribution of HCl gas and NH ₃ gas in the exhaust gas 12 can be made uniform.
Further, since the NH ₄ Cl solution 14 can be prevented from adhering to the wall surface of the flue 13 before being vaporized, it is possible to prevent the flue 13 from being damaged due to corrosion of the flue 13 or the like. Can do.

Further, HCl gas and NH ₃ gas generated from the droplets of the NH ₄ Cl solution 14 are accompanied by the exhaust gas 12 and sent to the reductive denitration device 18 as shown in FIG. Further, before the exhaust gas 12 passes through the reductive denitration device 18, the gas flow is made uniform by a rectifying plate (not shown) or the like. NH ₃ gas generated by the decomposition of NH ₄ Cl is used for NOx reduction denitration in the reduction denitration apparatus 18, and HCl gas is used for Hg oxidation to remove NOx and Hg from the exhaust gas 12.

That is, NH ₃ reductively denitrates NOx as in the following formula (2) on the denitration catalyst of the denitration catalyst layer packed in the reductive denitration device 18, and HCl oxidizes Hg into mercury as in the following formula (3). To do.
4NO + 4NH ₃ + O ₂ → 4N ₂ + 6H ₂ O (2)
Hg + 1 / 2O ₂ + 2HCl → HgCl ₂ + H ₂ O (3)

  In the reduction denitration device 18, the three denitration catalyst layers are preferably formed from a plurality of layers, and the number of denitration catalyst layers can be changed as appropriate according to the denitration performance.

  In addition, as shown in FIG. 1, after the exhaust gas 12 is reduced in NOx and Hg in the exhaust gas 12 in the reductive denitration device 18, it passes through the air heater 19 and the dust collector 20 to the wet desulfurization device 22. Be sent. A heat recovery unit may be provided between the air heater 19 and the dust collector 20.

  In the wet desulfurization apparatus 22, the exhaust gas 12 is fed from the bottom wall surface in the apparatus main body 41, and the lime gypsum slurry 21 used as an alkali absorbent is supplied into the apparatus main body 41 through the absorption liquid supply line 42. It is made to jet from 43 toward the tower top side. The exhaust gas 12 rising from the bottom side in the apparatus main body 41 and the lime gypsum slurry 21 jetted from the nozzle 43 are brought into gas-liquid contact to face each other, and HgCl and sulfur oxide (SOx) in the exhaust gas 12 are brought into contact with each other. Is absorbed in the lime gypsum slurry 21, separated and removed from the exhaust gas 12, and the exhaust gas 12 is purified. The exhaust gas 12 purified by the lime gypsum slurry 21 is discharged as a purified gas 44 from the tower top side, and is discharged from the chimney 45 to the outside of the system.

The lime gypsum slurry 21 used for the desulfurization of the exhaust gas 12 includes a lime slurry CaCO ₃ in which limestone powder is dissolved in water, a gypsum slurry CaSO _{4 in} which lime and SOx in the exhaust gas 12 are reacted and further oxidized, and water. Produced by mixing. As the lime gypsum slurry 21, for example, a pumped liquid stored in the tower bottom 55 of the apparatus main body 41 of the wet desulfurization apparatus 22 is used. In the apparatus main body 41, SOx in the exhaust gas 12 reacts with the lime gypsum slurry 21 as shown in the following formula (4).
CaCO ₃ + SO ₂ + 0.5H ₂ O → CaSO ₃ .0.5H ₂ O + CO ₂ (4)

On the other hand, the lime-gypsum slurry 21 that has absorbed SOx in the exhaust gas 12 is mixed with the water 46 supplied into the apparatus main body 41 and oxidized by the air 47 supplied to the tower bottom 55 of the apparatus main body 41. At this time, the lime-gypsum slurry 21 that has flowed down within the apparatus main body 41 reacts with water 46 and air 47 as shown in the following formula (5).
CaSO ₃ · 0.5H ₂ O + 0.5O ₂ + 1.5H ₂ O → CaSO ₄ · 2H ₂ O (5)

  The lime gypsum slurry 21 used for the desulfurization stored in the tower bottom 55 of the wet desulfurization apparatus 22 is oxidized and then extracted from the tower bottom 55 and fed to the dehydrator 48. It is discharged out of the system as a dehydrated cake (gypsum) 49 containing HgCl). As the dehydrator 48, for example, a belt filter or the like is used. Further, the dehydrated filtrate (dehydrated filtrate) is subjected to wastewater treatment such as removal of suspensions in the dehydrated filtrate, heavy metals, and pH adjustment of the dehydrated filtrate. A part of this drained filtrate is returned to the wet desulfurization device 22, and the other part of the dehydrated filtrate is treated as waste water.

  Moreover, although the lime gypsum slurry 21 is used as an alkali absorption liquid, another solution can be used as an alkali absorption liquid as long as it can absorb HgCl in the exhaust gas 12.

  The lime gypsum slurry 21 is not limited to the method of jetting from the nozzle 43 toward the tower top side, and may be caused to flow down from the nozzle 43 so as to face the exhaust gas 12, for example.

<Control of spray amount of NH ₄ Cl solution>
A flow meter 51 for measuring the flow rate of the exhaust gas 12 is provided on the upstream side of the spray nozzle 15. The flow rate of the exhaust gas 12 is measured by the flow meter 51. The flow rate value of the exhaust gas 12 measured by the flow meter 51 is sent to the control device 52, and the flow rate, angle, initial velocity, etc. of the NH ₄ Cl solution 14 injected from the spray nozzle 15 based on the flow rate value of the exhaust gas 12 are determined. Can be adjusted.

Further, a NOx concentration meter 53 is provided on the outlet side of the wet desulfurization apparatus 22. The value of the NOx concentration in the purified gas 44 measured by the NOx concentration meter 53 is transmitted to the control device 52. The control device 52 can confirm the NOx reduction ratio in the reductive denitration device 18 from the value of the NOx concentration in the purified gas 44 measured by the NOx concentration meter 53. Therefore, NH ₄ Cl concentration solution _of NH ₄ Cl 14 from the value of the NOx concentration in the purified gas 44 measured by the NOx concentration meter 53, by controlling the supply flow rate, NH ₄ Cl sprayed from the spray nozzle 15 The NH ₄ Cl concentration of the solution 14 can be made to satisfy a predetermined denitration performance.

The flue 13 is provided with mercury (Hg) concentration meters 54-1 and 54-2 for measuring the Hg content in the exhaust gas 12 discharged from the boiler 11. The Hg concentration meter 54-1 is provided in the flue 13 between the boiler 11 and the spray nozzle 15, and the Hg concentration meter 54-2 is provided between the reducing denitration device 18 and the heat exchanger 19. The value of the HCl concentration in the exhaust gas 12 measured by the Hg concentration meters 54-1 and 54-2 is transmitted to the control device 52. The control device 52 can confirm the content of Hg contained in the exhaust gas 12 from the value of the HCl concentration in the exhaust gas 12 measured by the Hg concentration meters 54-1 and 54-2. The NH sprayed from the spray nozzle 15 is controlled by controlling the NH ₄ Cl concentration and supply flow rate of the NH ₄ Cl solution 14 from the value of the Hg concentration in the exhaust gas 12 measured by the Hg concentration meters 54-1 and 54-2. The NH ₄ Cl concentration and supply flow rate of the ₄ Cl solution 14 can satisfy the predetermined denitration performance and maintain the Hg oxidation performance.

  The tower bottom 55 of the wet desulfurization apparatus 22 is provided with an oxidation-reduction potential measurement controller (ORP controller) 56 that measures the oxidation-reduction potential of the lime gypsum slurry 21. This ORP controller 56 measures the value of the oxidation-reduction potential of the lime gypsum slurry 21. Based on the measured oxidation-reduction potential, the supply amount of the air 47 supplied to the tower bottom 55 of the wet desulfurization apparatus 22 is adjusted. By adjusting the supply amount of the air 47 supplied to the tower bottom 55, the oxidized Hg collected in the lime gypsum slurry 21 stored in the tower bottom 55 of the wet desulfurization apparatus 22 is reduced. And can be prevented from being diffused from the chimney 45.

The oxidation-reduction potential of the lime gypsum slurry 21 in the wet desulfurization apparatus 22 is preferably in the range of 150 mV to 600 mV, for example, in order to prevent re-scattering of Hg from the lime gypsum slurry 21. This is because if the oxidation-reduction potential is within the above range, Hg collected as HgCl ₂ in the lime-gypsum slurry 21 is a stable region, and re-scattering into the atmosphere can be prevented.

In the exhaust gas treatment apparatus 100 according to the present embodiment, NH ₄ Cl is used as a reduction oxidation aid, but ammonium bromide (NH ₄ Br) other than NH ₄ Cl, ammonium iodide (NH ₄ I). ) Or the like may be used as a reduction oxidation aid, and a solution dissolved in water may be used.

As described above, according to the exhaust gas treatment apparatus 100 according to the present embodiment, the mixer 60 (60A) is provided on the upstream side of the NH ₄ Cl solution supply unit 16, so that the gas flow of the exhaust gas 12 is disturbed, By applying a speed other than the axial flow to the droplet sprayed from the spray nozzle 15, the heat transfer rate can be improved and evaporation can be promoted.
By promoting the evaporation of the ammonia chloride droplets, collision with the inner wall of the flue and the flue internal structure will be prevented, and damage to the flue caused by corrosion of the flue may be prevented. it can. Further, since the NH ₄ Cl solution 14 is supplied from the spray nozzle 15 so as not to adhere to the inner wall of the flue 13 through which the exhaust gas 12 flows, the droplets of the NH ₄ Cl solution 14 sprayed into the flue 13 are generated. HCl and NH ₃ produced by vaporization can be mixed with the exhaust gas 12. For this reason, HCl and NH ₃ can be supplied stably and uniformly into the flue 13 without concentration unevenness, so that the Hg oxidation performance in the reductive denitration device 18 can be improved and the NOx reduction performance can be improved. Can be improved. Further, since the NH ₄ Cl solution 14 can be prevented from adhering to the wall surface of the flue 13 before being vaporized, the flue 13 is prevented from being damaged due to corrosion of the flue 13 or the like. be able to.

The structure of the mixer of the exhaust gas treatment apparatus according to the second embodiment of the present invention is shown in FIGS. FIG. 4 is a block diagram showing the main part of the mixer according to the present invention. FIG. 5 is a front view according to the overall configuration of the mixer. 6 is a view taken along the line AA in FIG.
FIG. 7 shows experimental data of the lattice element, mixing performance, and pressure loss characteristics of Example 2, where (a) is a dimensional ratio diagram of (4-pyramid) lattice elements of a triangular plate, and (b) is mixed. It is a figure which shows the experimental data of performance (uniform effect parameter | index) and a pressure loss coefficient.
As shown in FIG. 4, the mixer 60 </ b> B according to the present embodiment shows the components of a rectifier having a triangular plate (quadrangular pyramid) lattice, and two triangular plates 63 on the upstream side are opposed to two quadrangular pyramids. A surface is formed, and on the downstream side, an apex is contacted with the upstream quadrangular pyramid, and two opposing faces of the quadrangular pyramid are formed by two triangular plates 64 shifted by 90 degrees, and the width of the lattice The length ratio (L / B) is in the range of 1.5 to 2.0 (see FIG. 7).

  FIG. 5 is an example of a mixer in which the lattice components of FIG. 4 are arranged side by side by changing the orientation of adjacent lattice components by 90 degrees, and the components are combined in this way. Thus, a mixer having an arbitrary cross-sectional area can be formed.

  In the case of a mixer combined with a triangular plate, the flow from the upstream side is bent obliquely in the direction of the opening of the quadrangular pyramid when passing through the inside of the rectifier, and the direction of the opening is different by 90 degrees. A swirl component in a direction perpendicular to the flow is given, and a vortex is generated on the downstream side of the diagonally arranged triangular plate. As a result, a large disturbance can be obtained.

  Such vortex generated by swirling the flow is strongly disturbed when the height of the quadrangular pyramid formed by the triangular plate in the flow direction is low, and the mixing effect is large. When the height is high, the vortex is weak and the mixing effect is small.

  However, since pressure loss is also proportional to the strength of the vortex that is generated, in order to obtain a large mixing effect with low pressure loss, the width (B) in the direction perpendicular to the flow of the grid component and the triangular plate grid In some cases, it is necessary to set the ratio (L / B) of the length (L) in the flow direction of the two quadrangular pyramids to be configured within a certain range.

Here, the flow velocity rectifying effect and the temperature and concentration mixing effect are defined as in Equation (6).
K = Lmax−Lmin / Gmax−Gmin (6)
Here, K: index of uniform effect of flow velocity / temperature / concentration Gmax: maximum value of flow velocity / temperature / concentration in flow path without rectifier Gmin: flow velocity / temperature / concentration in flow path without rectifier Minimum value Lmax: Maximum value of flow velocity / temperature / concentration in the flow channel after rectifier installation Lmin: Minimum flow velocity / temperature / concentration value in the flow channel after rectifier installation

  FIG. 7 shows the results obtained by experimentally determining the uniform effect index K with various changes in L / B for a triangular plate (4-pyramid) lattice. As shown in FIG. 7, when L / B of a triangular plate (quadrangular pyramid) lattice is 1.5 or less, the pressure loss coefficient CD is large, and when L / B is 2.0 or more, the mixing performance (an index of uniform effect). Since the reciprocal 1 / K) rapidly decreases, the range satisfying the low pressure loss and the high mixing performance is the range of L / B = 1.5 to 2.0. The pressure loss coefficient in this range is 1.1 for a triangular plate (quadrangular pyramid) lattice, which is an extremely small value compared to conventional perforated plates, etc., and both low pressure loss and high mixing performance are satisfied simultaneously. I understand that

Accordingly, the mixer 60B is provided upstream of the region in which the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 sprays, the gas flow is disturbed, and the liquid sprayed from the spray nozzle 15 at a speed other than the axial flow. By giving to the droplets, the heat transfer coefficient can be improved and evaporation can be promoted.
By promoting the evaporation of the ammonia chloride droplets, collision with the inner wall of the flue 13 and the internal structure of the flue 13 is prevented, and damage to the flue caused by corrosion of the flue and the like is prevented. Can be prevented.

The structure of the mixer of the exhaust gas treatment apparatus according to Embodiment 3 of the present invention is shown in FIGS. FIG. 8 is a plan view showing an example of a mixer according to the present embodiment, FIG. 9 is a plan view of a swirling flow inducing member constituting the mixer, and FIG. 10 is a front view of the swirling flow inducing member. FIG. 11 is a perspective view of the swirl flow inducing member.
In addition, about the code | symbol 73 shown in FIGS. 8-11, in order to clarify the difference with the member of the code | symbol 74, it has shown adding hatching.
As shown in FIG. 8, the mixer 60 </ b> C of the present embodiment is formed by a unit in which six swirl flow inducing members 72 that generate a swirl flow in the exhaust gas 12 are arranged so as to be orthogonal to the flow direction of the exhaust gas 12. Is. As shown in FIGS. 8 to 11, the swirling flow inducing member 72 has a pair of first swirling flow inducing plates 73 having a facing surface 73 a on the inlet side of the exhaust gas 12, and a facing surface 74 a on the exhaust side of the exhaust gas 12. And a pair of second swirl flow induction plates 74, and the first intermediate plate 75 in the flat plate-like intermediate member 75 serves as a connecting portion that connects the first swirl flow induction plate 73 and the second swirl flow induction plate 74. The opposing surface 73a of the second swirling flow induction plate 73 and the opposing surface 74a of the second swirling flow induction plate 74 are connected so as to be different. In the present embodiment, the facing surface 73a of the first swirling flow induction plate 73 and the facing surface 74a of the second swirling flow induction plate 74 are arranged so as to differ by about 90 °.

  The first swirl flow inducing plate 73 and the second swirl flow inducing plate 74 are each formed in a substantially triangular shape. In addition, since the first swirl flow induction plate 73 is provided on the inlet side of the exhaust gas 12 and the second swirl flow induction plate 74 is provided on the exhaust side of the exhaust gas 12, the swirl flow induction member 72 is viewed from the front. The first swirl flow induction plate 73 is positioned below the second swirl flow induction plate 74. The intermediate member 75 is a flat plate, and functions as a key for connecting the first swirl flow induction plate 73 and the second swirl flow induction plate 74. The first swirl flow induction plate 73 is provided with a lower support plate 76, and the second swirl flow induction plate 74 is provided with an upper support plate 77. The lower support plate 76 and the upper support plate 77 connect adjacent swirl flow inducing members 72 to each other.

  As shown in FIG. 11, when the exhaust gas 12 flows into the swirl flow inducing member 72, the exhaust gas 12 collides with the back surface side of the opposing surface 73 a of the first swirl flow inducing plate 73, and the gas flow is changed. It flows in the direction of the swirl flow induction plate 74. Thereafter, the exhaust gas 12 collides with the back side of the facing surface 74a of the second swirl flow induction plate 74, and the gas flow further changes. For this reason, the gas flow of the exhaust gas 12 is changed by the first swirl flow induction plate 73 and the second swirl flow induction plate 74, and bypasses the first swirl flow induction plate 73 and the second swirl flow induction plate 74. And flows while swirling from the inflow direction of the exhaust gas 12 of the swirling flow inducing member 72 toward the exhaust direction of the exhaust gas 12.

  In the present embodiment, the opposing surface 73a of the first swirling flow induction plate 73 and the opposing surface 74a of the second swirling flow induction plate 74 are arranged so as to be different from each other by about 90 °. The present invention is not limited to this. The orientation of the facing surface 73a of the first swirling flow induction plate 73 and the facing surface 74a of the second swirling flow induction plate 74 is such that the exhaust gas 12 flowing into the swirling flow inducing member 72 is converted into the exhaust gas 12 of the swirling flow inducing member 72. Any angle may be used as long as it can be swung from the inflow direction toward the discharge direction of the exhaust gas 12.

  Further, in this embodiment, the mixer 60C is a unit in which six swirl flow inducing members 72 are arranged so as to be orthogonal to the flow direction of the exhaust gas 12, as shown in FIG. The number of the swirl flow inducing members 72 to be installed is appropriately changed according to the area of the flue 13 or the like.

  Further, in this embodiment, the mixer 60C is configured as a single unit in which six swirl flow inducing members 72 are arranged in the flow direction of the exhaust gas 12, but the present invention is not limited to this. Instead, a plurality of units in which a plurality of swirl flow inducing members 72 are arranged in the flow direction of the exhaust gas 12 may be installed. Further, the mixer 60C of the present embodiment is provided with a unit in which a plurality of swirl flow inducing members 72 are arranged in a direction orthogonal to the flow direction of the exhaust gas 12, and a plurality of swirl flow inducing members 72 are arranged in the flow direction of the exhaust gas 12. A plurality of such units may be provided.

FIG. 12 is a diagram schematically showing the gas flow of the exhaust gas when the mixer is installed in the flue, and FIG. 13 is a partially enlarged view of FIG.
12 and 13, six swirl flow inducing members 72 are provided in the width direction of the flue 13 as shown in FIG. 8.
As shown in FIGS. 12 and 13, when the exhaust gas 12 passes through the swirling flow inducing member 72, the exhaust gas 12 collides with the first swirling flow inducing plate 73 and the second swirling flow inducing plate 74 to change the gas flow and swirl. However, the flue flows from the lower side to the upper side of the flue 13, and thus flows so as to bypass the first swirl flow induction plate 73 and the second swirl flow induction plate 74, so that the flue is swirling the exhaust gas 12. Therefore, when the NH ₄ Cl solution 14 is sprayed by the spray nozzle 15, the mixing of the exhaust gas 12 with the HCl gas and the NH ₃ gas can be promoted.

Further, since the mixer 60C is provided on the upstream side of the region where the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 is vaporized, evaporation of the droplets of the NH ₄ Cl solution 14 is promoted and vaporized. Since contact with the mixer 60C can be prevented before, damage to the flue 13 due to heat shock, corrosion of the flue 13 and accumulation of ash in the exhaust gas 12 can be prevented.

Therefore, the mixer 60C is provided on the upstream side of the region in which the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 is sprayed, the gas flow of the exhaust gas 12 is disturbed, and the speed other than the axial flow is increased from the spray nozzle 15. By giving to the sprayed droplets, the heat transfer coefficient can be improved and evaporation can be promoted.
By promoting the evaporation of the ammonia chloride droplets, collision with the inner wall of the flue and the flue internal structure will be prevented, and damage to the flue caused by corrosion of the flue may be prevented. it can.

Since the mixing of NH ₃ gas in the flue gas 12 in the flue 13 can be promoted, the variation in the concentration distribution of the NH ₃ gas in the exhaust gas 12 is suppressed, and the variation in the concentration distribution of the NH ₃ gas is about 5%, for example. And can be made substantially uniform. For this reason, the reduction efficiency of NOx by the denitration catalyst in the reduction denitration apparatus 18 can be improved.

Further, by providing the mixer 60 upstream of the region where the NH ₄ Cl solution 14 sprayed from the spray nozzle 15 vaporizes, the exhaust gas 12 in the flue 13 is mixed with HCl gas in addition to NH ₃ gas. Can be promoted. For this reason, the variation in the concentration distribution of the HCl gas in the exhaust gas 12 can be suppressed, and the variation in the concentration distribution of the HCl gas can be made substantially uniform, for example, within a range of about 5%. For this reason, in the reduction denitration apparatus 18, the oxidation performance of Hg in the denitration catalyst can be improved.

Moreover, as shown in FIGS. 8-11, it is preferable that the width | variety L and height D of the swirling flow induction member 72 are in the range of following formula (7), (8).
MIN (B, H) / 10 ≦ L ≦ MIN (B, H) (7)
MIN (B, H) / 10 ≦ D ≦ 5 × MIN (B, H) (8)
However, B is the long side of the cross section of the flue at the installation position, H is the short side of the cross section of the flue, MIN (B, H) is the long side B of the cross section of the flue, the cross section of the flue This is the shorter side of the short sides H. When the long side B and the short side H of the cross section of the flue have the same length, either may be used.

The reason why the swirl flow inducing member 72 is set within the range of the above formulas (7) and (8) is as follows, when the pressure loss condition of the mixer, the concentration of NH _{3 in} the exhaust gas 12 varies, This is because it needs to be determined in consideration of the workability, actual operating conditions, and maintainability.
FIG. 14 is a diagram illustrating the relationship between the pressure loss of the mixer and the dimensions of the mixer. As shown in FIG. 14, in order for the pressure loss of the mixer to be 25 mmAq or less, it is necessary to satisfy the following formula (9). Moreover, in order to make the concentration variation of the concentration of NH _{3 in} the exhaust gas 12 5% or less, it is necessary to satisfy the following formula (10).
MIN (B, H) × D / L ² ≧ 2 (9)
MIN (B, H) × D / L ² ≦ 5 (10)

That is, as the pressure loss condition, in order for the pressure loss of the mixer to be 25 mmAq or less, the above formula (9) needs to be satisfied. Moreover, in order to make the concentration variation of the concentration of NH _{3 in} the exhaust gas 12 5% or less as an effect of the mixer, it is necessary to satisfy the above formula (10).

Moreover, the mixer needs to satisfy | fill said Formula (7) and following formula (11) from a viewpoint of workability at the time of manufacture, a viewpoint of actual operation conditions, and a viewpoint of maintainability.
MIN (B, H) / 10 ≦ L ≦ MIN (B, H) (7)
MIN (B, H) / 10 ≦ D (11)

From the above formulas (9) and (10), D can be expressed as the following formula (12).
2L ² / MIN (B, H) ≦ D ≦ 5L ² / MIN (B, H) (12)

Substituting the above equation (7) into the above equation (12), D can be expressed as the following equation (13).
MIN (B, H) / 50 ≦ D ≦ 5 × MIN (B, H) (13)

Then, considering the above equation (11) in the above equation (13), D is expressed as the above equation (8).
MIN (B, H) / 10 ≦ D ≦ 5 × MIN (B, H) (8)

As described above, the width L and the height D of the swirling flow inducing member 72 are within the ranges of the above formulas (7) and (8), so that a plurality of swirling flow inducing members 72 are installed in the flue 13. Therefore, mixing of HCl and NH ₃ can be promoted with respect to the exhaust gas 12.

Further, the shapes of the first swirl flow induction plate 73 and the second swirl flow induction plate 74 are not limited to the triangular shape formed from the upper support plate 77 and the lower support plate 76 to the intermediate member 75, but the exhaust gas 12. Any shape that can generate a swirling flow and promote mixing of the exhaust gas 12 with HCl and NH ₃ may be used. For example, the shapes of the first swirl flow induction plate 73 and the second swirl flow induction plate 74 are curved, wave-shaped, etc. from one end side to the other end side of the second swirl flow induction plate 74 and the first swirl flow induction plate 73. Also good.

Therefore, according to the exhaust gas treatment apparatus 100 according to the present embodiment, by providing the mixer 60 (60A to 60C), the mixing of HCl and NH ₃ in the exhaust gas 12 can be promoted. It is possible to make uniform the distribution of the NH ₃ and HCl concentrations generated by vaporizing the sprayed NH ₄ Cl solution 14.
Thereby, in the reductive denitration device 18, the Hg oxidation performance and NOx reduction performance can be improved by the denitration catalyst, and the flue 13 is damaged by the heat shock, the flue 13 is corroded, and the ash is accumulated in the exhaust gas 11. Etc. can be prevented.

As described above, the exhaust gas treatment apparatus according to the present invention supplies to not adhere the solution _of NH ₄ Cl was sprayed flue to the inner wall of the flue, HCl gas, NH ₃ generated from the droplets of solution _of NH ₄ Cl Since the mixing of the gas and the exhaust gas can be promoted, it is suitable for use in an exhaust gas treatment apparatus that removes Hg and NOx in the exhaust gas.

100 exhaust gas treatment apparatus 11 boiler 12 flue gas 13 flue 14 ammonium chloride (NH ₄ Cl) solution 15,61 spray nozzle 16 ammonium chloride (NH ₄ Cl) solution supply means (reduction-oxidation auxiliary agent supply means)
18 Reduction denitration equipment (reduction denitration means)
19 Heat exchanger (air heater)
20 Dust Collector 21 Lime Gypsum Slurry 22 Wet Desulfurizer 25 Ammonium Chloride (NH ₄ Cl) Solution Supply Pipe 26, 33, 47 Air 27, 34 Air Supply Pipe 28 Ammonium Chloride (NH ₄ Cl) Solution Tank 41 Apparatus Main Body 42 Absorption Liquid feed line 43 Nozzle 44 Purified gas 45 Chimney 46 Water 48 Dehydrator 49 Gypsum 51 Flow meter 52 Control device 53 NOx concentration meter 54-1, 54-2 Mercury (Hg) concentration meter 55 Tower bottom 56 Redox potential measurement control Equipment (ORP controller)
60 (60A-60C) Mixer (mixing means)
72 swirl flow inducing member 73 first swirl flow inducing plate 74 second swirl flow inducing plate 75 intermediate member (connecting portion)
76 Lower support plate 77 Upper support plate V1-V3 Valve

Claims (7)

An exhaust gas treatment device for removing nitrogen oxides and mercury contained in exhaust gas from a boiler,
In the flue downstream of the boiler, reducing oxidation auxiliary agent supplying means for spraying liquid ammonium chloride that generates oxidizing gas and reducing gas when vaporized in a liquid state by a spray nozzle;
Reductive denitration means having a denitration catalyst for reducing nitrogen oxides in the exhaust gas with the reducing gas and oxidizing mercury in the presence of the oxidizing gas;
Wet desulfurization means for removing mercury oxidized in the reductive denitration means using an alkali absorbing solution;
Than said spray nozzle disposed on an upstream side, have a a mixer providing a disturbance in the gas flow of the exhaust gas,
The ammonium chloride supply pipe that supplies the ammonium chloride solution to the spray nozzle has a double pipe structure including an air supply pipe that covers the periphery of the ammonium chloride supply pipe, and the air supply section passes through the air supply pipe. the cooling air to the spray nozzle is fed, the exhaust gas processing device according to claim Rukoto such by cooling the ammonium chloride solution fed to the spray nozzle. Oite to claim 1,
An exhaust gas treatment apparatus, wherein a nozzle hole of the spray nozzle is provided at a position separated by 0.5 m or more from a wall surface of the flue. In claim 1 or 2 ,
The exhaust gas treatment apparatus, wherein the mixer has a lattice shape. In claim 1 or 2 ,
The mixer is
Two triangular plates installed in a flue and arranged to form two opposing faces of a quadrangular pyramid having a vertex on the downstream side of the gas flow, and the vertex and the vertex are in contact with each other, downstream of the gas flow A lattice element constituted by two opposing faces of a quadrangular pyramid having a bottom face on the side and a triangular plate forming the opposing two faces on the upstream side and the opposing two faces twisted at 90 degrees is provided as a fluid flow path. In all the lattice elements arranged in the inside, the direction of the adjacent lattice elements is changed by 90 degrees, and they are arranged in a direction perpendicular to the fluid flow, and the bottom surfaces of the quadrangular pyramids are connected to form a lattice, and the lattice elements The ratio (L / B) of the width (B) in the direction perpendicular to the fluid flow and the length (L) in the direction parallel to the fluid flow is in the range of 1.5 to 2.0. . In claim 1 or 2 ,
The mixer is
A pair of first swirl flow induction plates having opposing surfaces on the inlet side of the exhaust gas;
A pair of second swirl flow induction plates having opposing surfaces on the exhaust gas discharge side;
In the connecting portion connecting the first swirl flow induction plate and the second swirl flow induction plate, the opposing surface of the first swirl flow induction plate and the opposing surface of the second swirl flow induction plate are different from each other. An exhaust gas treatment apparatus that is a swirl flow induction member that is connected. In claim 5 ,
An exhaust gas treatment apparatus, wherein a width L and a height D of the swirl flow inducing member are within the ranges of the following formulas (1) and (2).
MIN (B, H) / 10 ≦ L ≦ MIN (B, H) (1)
MIN (B, H) / 10 ≦ D ≦ 5 × MIN (B, H) (2)
However, B is the long side of the cross section of the flue at the installation position, H is the short side of the cross section of the flue, MIN (B, H) is the long side B of the cross section of the flue, the cross section of the flue This is the shorter side of the short sides H. When the long side B and the short side H of the cross section of the flue have the same length, either may be used. In any one of Claims 1 thru | or 6 ,
An exhaust gas treatment apparatus, wherein a protective wall is provided in the vicinity of the spray nozzle along the inner wall of the flue.

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