JP5616564B1 - Lead-acid battery, lead-acid battery package, and lead-acid battery transport method - Google Patents

Lead-acid battery, lead-acid battery package, and lead-acid battery transport method Download PDF

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JP5616564B1
JP5616564B1 JP2014531800A JP2014531800A JP5616564B1 JP 5616564 B1 JP5616564 B1 JP 5616564B1 JP 2014531800 A JP2014531800 A JP 2014531800A JP 2014531800 A JP2014531800 A JP 2014531800A JP 5616564 B1 JP5616564 B1 JP 5616564B1
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tube
lead
exhaust port
electrode plate
acid battery
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JPWO2014162653A1 (en
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晃平 佐野
晃平 佐野
恒典 吉村
恒典 吉村
圭 石牧
圭 石牧
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Panasonic Corp
Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/121Valve regulated lead acid batteries [VRLA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/102Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/112Monobloc comprising multiple compartments
    • H01M50/114Monobloc comprising multiple compartments specially adapted for lead-acid cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/317Re-sealable arrangements
    • H01M50/325Re-sealable arrangements comprising deformable valve members, e.g. elastic or flexible valve members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/35Gas exhaust passages comprising elongated, tortuous or labyrinth-shaped exhaust passages
    • H01M50/358External gas exhaust passages located on the battery cover or case
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Gas Exhaust Devices For Batteries (AREA)
  • Secondary Cells (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

本発明の鉛蓄電池は、正極板と負極板とをセパレータを介して対峙させた複数の極板群と、中仕切板によって複数のセル室に区切られ、各前記セル室に前記複数の極板群のそれぞれと電解液とを収容し、上方が開口している直方体形状の電槽と、前記電槽の開口部を塞ぐ蓋とを備え、前記蓋は、前記複数のセル室のそれぞれの直上に対応する複数の弁と、前記複数の弁の上方を覆う上蓋と、前記複数の弁を連通させつつ一端が排気口となっている連通経路とを有しており、一方の端が前記排気口に接続されているとともに、前記排気口の直下にある前記電槽の側面に対峙して渦巻状に捲回されたチューブをさらに備えている。The lead storage battery of the present invention is divided into a plurality of cell chambers by a plurality of electrode plate groups in which a positive electrode plate and a negative electrode plate are opposed to each other via a separator, and a partition plate, and each of the cell chambers includes the plurality of electrode plates. A rectangular parallelepiped battery case that accommodates each of the groups and the electrolyte, and has an open top; and a lid that closes the opening of the battery case, the lid being directly above each of the plurality of cell chambers A plurality of valves corresponding to the above, a top cover that covers the top of the plurality of valves, and a communication path having one end serving as an exhaust port while allowing the plurality of valves to communicate with each other. A tube connected to the mouth and wound in a spiral shape so as to face the side surface of the battery case immediately below the exhaust port is further provided.

Description

本発明は、鉛蓄電池、鉛蓄電池の梱包体及び鉛蓄電池の搬送方法に関する。   The present invention relates to a lead-acid battery, a lead-acid battery package, and a lead-acid battery transport method.

自動車用などの鉛蓄電池のうち、電解液の補水などのメンテナンスを不要とするものについては、例えば特許文献1のように、電池の内部で発生したガスを一括で排気する構造を有している。具体的には図5(a)および(b)に示すように、直方体形状の電槽1の開口部を塞ぐ蓋2は、正極板と負極板とをセパレータを介して対峙させた複数の極板群と電解液とを収容する複数のセル室のそれぞれの直上に対応する複数の弁2aと、これら複数の弁2aを連通させつつ一端が排気口2bとなっている連通経路とを有している。そして車に鉛蓄電池を載せる際に排気口2bを排気管5と接続することで、電池の内部で発生したガスを一括で排気するようになっている。なお図5では、隣り合う弁2aを連通孔2cで連通させつつ上蓋2dによって弁2aの直上を一括で塞ぐことで、連通経路を形成している。   Among lead storage batteries for automobiles and the like, those that do not require maintenance such as replenishment of electrolyte solution have a structure that exhausts the gas generated inside the battery as in Patent Document 1, for example. . Specifically, as shown in FIGS. 5A and 5B, the lid 2 that closes the opening of the rectangular parallelepiped battery case 1 has a plurality of electrodes in which a positive electrode plate and a negative electrode plate are opposed to each other with a separator interposed therebetween. A plurality of valves 2a corresponding directly above each of the plurality of cell chambers containing the plate group and the electrolyte solution, and a communication path having one end serving as an exhaust port 2b while communicating the plurality of valves 2a ing. When the lead storage battery is placed on the vehicle, the exhaust port 2b is connected to the exhaust pipe 5 so that the gas generated inside the battery is exhausted collectively. In FIG. 5, the communication path is formed by closing the valve 2 a immediately above by the upper lid 2 d while communicating adjacent valves 2 a through the communication hole 2 c.

このような鉛蓄電池は電解液が電槽1の内部で流動できる構造なので、梱包して輸送あるいは荷積みする際にはいわゆる天地無用となるように留意されている。ところが輸送あるいは荷積みの際に、大きな搖動や作業者の無作為によって、天地無用が順守されない場合がある。そうすると排気口2bから電解液が溢れ出ることになり、この溢れ出た電解液に作業者が気付かないと、作業者が電解液である硫酸に触れてしまって傷ついてしまうことになる。   Since such a lead storage battery has a structure in which the electrolytic solution can flow inside the battery case 1, attention is paid to avoid the so-called top-and-bottom use when packing and transporting or loading. However, when transporting or loading, there is a case where the use of the top and bottom is not observed due to large peristalsis and the randomness of workers. If it does so, electrolyte solution will overflow from the exhaust port 2b, and if an operator does not notice this overflowed electrolyte solution, an operator will touch the sulfuric acid which is electrolyte solution, and will be damaged.

このような不具合を避けるために、特許文献2は、排気口2bに相当する箇所の近傍に、通気性はあるが水分は通さないフィルタを設けることを提案している。   In order to avoid such a problem, Patent Document 2 proposes to provide a filter that has air permeability but does not allow moisture to pass in the vicinity of a portion corresponding to the exhaust port 2b.

特開2001−266845号公報JP 2001-266845 A 米国特許第6110617号明細書US Pat. No. 6,110,617

しかしながら特許文献2の構成において、長時間に亘り天地無用が順守されなかった場合(例えば長時間の倒立など)、フィルタが電解液によって目詰まりすることになる。そうすると、電池の内部で発生したガスを一括で排気できなくなり、電槽の変形などの新たな課題を引き起こすことになる。   However, in the configuration of Patent Document 2, when the use of upside down is not observed for a long time (for example, a long-time inversion or the like), the filter is clogged with the electrolytic solution. If it does so, it will become impossible to exhaust the gas generated inside a battery collectively, and new problems, such as a deformation | transformation of a battery case, will be caused.

本発明はこの課題を解決するためのものであって、内部で発生したガスを一括で排気する構造を有し、長時間に亘り天地無用としなかった場合でも、電解液を溢れさせたり電槽を変形させたりする不具合を回避できる、安全性の高い鉛蓄電池を提供することを目的とする。   The present invention is for solving this problem, and has a structure for exhausting the gas generated inside, and even if it is not used for a long time without being used upside down, the electrolytic solution overflows or the battery case An object of the present invention is to provide a lead-acid battery with high safety that can avoid a problem of deforming the battery.

前述した課題を解決するために、本発明の鉛蓄電池は、正極板と負極板とをセパレータを介して対峙させた複数の極板群と、中仕切板によって複数のセル室に区切られ、各前記セル室に前記複数の極板群のそれぞれと電解液とを収容し、上方が開口している直方体形状の電槽と、前記電槽の開口部を塞ぐ蓋とを備え、前記蓋は、前記複数のセル室のそれぞれの直上に対応する複数の弁と、前記複数の弁の上方を覆う上蓋と、前記複数の弁を連通させつつ一端が排気口となっている連通経路とを有しており、一方の端が前記排気口に接続されているとともに、前記排気口の直下にある前記電槽の側面に対峙して渦巻状に捲回されたチューブをさらに備えている。   In order to solve the above-described problem, the lead storage battery of the present invention is divided into a plurality of cell chambers by a plurality of electrode plate groups in which a positive electrode plate and a negative electrode plate are opposed to each other via a separator, and a partition plate, Each of the plurality of electrode plate groups and the electrolytic solution is accommodated in the cell chamber, and includes a rectangular parallelepiped battery case having an open top, and a lid that closes the opening of the battery case, A plurality of valves corresponding directly above each of the plurality of cell chambers, an upper lid covering the top of the plurality of valves, and a communication path having one end serving as an exhaust port while communicating the plurality of valves. And a tube that is connected to the exhaust port and wound in a spiral while facing the side surface of the battery case directly below the exhaust port.

前記チューブを、前記排気口の直下を起点として360°を超えて捲回させてもよい。   The tube may be wound over 360 ° starting from directly below the exhaust port.

排気口の直下を起点としてチューブを450°を超えて捲回させてもよい。   The tube may be wound over 450 ° starting from directly under the exhaust port.

前記チューブは、前記電解液を視認できる材質からなるようにしてもよい。   The tube may be made of a material that allows the electrolyte solution to be visually recognized.

排気口の直下にある電槽の側面にチューブを当接させたことを特徴としてもよい。   A tube may be brought into contact with the side surface of the battery case directly under the exhaust port.

排気口の直下にある電槽の側面に隣接する他の側面にチューブの先端を対峙させたことを特徴としてもよい。   The tip of the tube may be opposed to the other side surface adjacent to the side surface of the battery case directly under the exhaust port.

チューブの他方の端を樹脂製のフィルタで塞いだことを特徴としてもよい。   The other end of the tube may be blocked with a resin filter.

前記フィルタは、通気性を有し液体の水は不透過である材質からなることを特徴としてもよい。   The filter may be made of a material that is air permeable and impermeable to liquid water.

本発明の梱包体は、上記の鉛蓄電池を箱に収容した構成を有している。   The package of this invention has the structure which accommodated said lead acid battery in the box.

本発明の鉛蓄電池の搬送方法は、正極板と負極板とをセパレータを介して対峙させた複数の極板群と、中仕切板によって複数のセル室に区切られるとともに各前記セル室に前記複数の極板群のそれぞれと電解液とを収容して上方が開口している直方体形状の電槽と、前記電槽の開口部を塞ぐ蓋とを備え、前記蓋は、前記複数のセル室のそれぞれの直上に対応する複数の弁と、前記複数の弁の上方を覆う上蓋と、前記複数の弁を連通させつつ一端が排気口となっている連通経路とを有している鉛蓄電池を、前記排気口の直下にある前記電槽の側面に対峙して渦巻状に捲回されたチューブの一方の端を前記排気口に接続した状態で搬送する。   The transport method of the lead storage battery of the present invention is divided into a plurality of cell chambers by a plurality of electrode plate groups in which a positive electrode plate and a negative electrode plate are opposed to each other via a separator, and a partition plate, and the plurality of cell chambers are divided into the plurality of cell chambers. Each of the electrode plate group and an electrolyte solution, and a rectangular parallelepiped battery case having an open top, and a lid that closes the opening of the battery case, the lid comprising the plurality of cell chambers A lead-acid battery having a plurality of valves corresponding to each of the above, an upper lid that covers the top of the plurality of valves, and a communication path having one end serving as an exhaust port while communicating the plurality of valves, It conveys in the state which connected one end of the tube wound in the shape of a spiral facing the side surface of the said battery case directly under the said exhaust port to the said exhaust port.

本発明を用いれば、内部で発生したガスを一括で排気する構造を有する鉛蓄電池を長時間に亘り天地無用としなかった場合でも、電解液を溢れさせたり電槽を変形させたりする不具合を回避できる。   By using the present invention, even when a lead storage battery having a structure for exhausting gas generated inside is not used for a long time, it avoids problems such as overflowing electrolyte or deforming the battery case. it can.

(a)実施形態の一例を部分的に示す図、(b)一部を拡大した図(A) The figure which shows an example of an embodiment partially, (b) The figure which expanded a part 実施形態の一例を部分的に示す図The figure which shows an example of embodiment partially 実施形態の一例を部分的に示す図The figure which shows an example of embodiment partially 実施形態の一例を部分的に示す図The figure which shows an example of embodiment partially (a)鉛蓄電池の一例を示す部分図、(b)同左(A) Partial view showing an example of a lead storage battery, (b) Same as the left 実施形態の一例を部分的に示す図The figure which shows an example of embodiment partially

以下、本発明の実施の形態を、図を用いて説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(実施形態1)
図1は本発明の鉛蓄電池の一例を部分的に示す図である。鉛蓄電池は、正極板と負極板とをセパレータを介して対峙させた複数の極板群(図示せず)と、これら複数の極板群と電解液とを収容するために中仕切板で複数のセル室に区切られて、上方が開口している直方体形状の電槽1と、この電槽1の開口部を塞ぐ蓋2とからなる。そして蓋2は、電槽1の複数のセル室のそれぞれの直上に対応する複数の弁2aと、これら複数の弁2aを連通させつつ一端が排気口2bとなっている連通経路とを有している。なお図1では図5と同様、隣り合う弁2a同士を連通孔2cで連通させつつ上蓋2dで弁2aの直上を一括で塞ぐことで、連通経路を形成している。また複数の極板を直列あるいは並列に接続した上で、正極性および負極性の端子3をそれぞれ、蓋2から突出させている。
(Embodiment 1)
FIG. 1 is a diagram partially showing an example of the lead storage battery of the present invention. The lead storage battery includes a plurality of electrode plates (not shown) in which a positive electrode plate and a negative electrode plate are opposed to each other with a separator interposed therebetween, and a plurality of partition plates in order to accommodate the electrode plates and the electrolyte solution. The battery case 1 has a rectangular parallelepiped shape that is divided into cell chambers and is open at the top, and a lid 2 that closes the opening of the battery case 1. The lid 2 has a plurality of valves 2a corresponding to the respective cell chambers of the battery case 1 and a communication path having one end serving as an exhaust port 2b while communicating the plurality of valves 2a. ing. In FIG. 1, similarly to FIG. 5, the communication path is formed by closing the valves 2 a together with the upper lid 2 d while connecting the adjacent valves 2 a through the communication holes 2 c. In addition, a plurality of electrode plates are connected in series or in parallel, and positive and negative terminals 3 are respectively projected from the lid 2.

そして実施形態1では、渦巻状に捲回されたチューブ4の一方の端が、排気口2bに接続されつつ、チューブ4の捲回された部分は排気口2bの直下にある電槽の側面1aに対峙している。そしてこの状態で、図6に示すように鉛蓄電池とチューブ4とが、箱6に収容されて鉛蓄電池の梱包体となっている。   In the first embodiment, one end of the spirally wound tube 4 is connected to the exhaust port 2b, and the wound part of the tube 4 is directly below the exhaust port 2b. Confronted. And in this state, as shown in FIG. 6, the lead acid battery and the tube 4 are accommodated in the box 6, and become the package of a lead acid battery.

本実施形態の鉛蓄電池は、工場にて製造された後、図6に示すように箱6に収容されて梱包体となって倉庫に搬送され、あるいは販売業者のもとへ搬送される。あるいは箱6に入れないで鉛蓄電池そのものが搬送される場合もある。卸売業者から小売業者へ、あるいは小売業者から需要者へも同様に梱包体又は鉛蓄電池そのもののみの状態で搬送を行う。このように搬送を行えば、電解液が鉛蓄電池から外部に漏れ出ることなく搬送が行えて作業者にとって安全である。   After the lead storage battery of this embodiment is manufactured in a factory, as shown in FIG. 6, it is accommodated in the box 6 and is transported to a warehouse as a package, or is transported to a dealer. Alternatively, the lead storage battery itself may be transported without being placed in the box 6. Similarly, the product is transported from the wholesaler to the retailer or from the retailer to the consumer in the state of the package or the lead storage battery itself. If transported in this way, the electrolyte can be transported without leaking from the lead-acid battery to the outside, which is safe for the operator.

図2は、本実施形態に係る鉛蓄電池の、電槽1の側面1aにおける側面図である。本実施形態の鉛蓄電池は排気口2bの直下を起点として、チューブ4を360°を超えて捲回させた形態を有している。このような形態にすれば、チューブ4において360°を超えた部分Aがあることで、電槽1の側面1bを下面として載置した状態で鉛蓄電池を搖動させても、連通経路に溢れ出た電解液は渦巻状に捲回されたチューブ4の途中で止まる。すなわち、電解液はチューブ4内においてAを超えてチューブ出口(チューブ4の他方の端)まで達することはないので、電解液がチューブ4から溢れでることがなくなる。そのため、作業者が電解液に直に触れてしまうことを防ぐことができて、安全に作業することができる。   FIG. 2 is a side view of the lead storage battery according to the present embodiment on the side surface 1 a of the battery case 1. The lead storage battery of the present embodiment has a configuration in which the tube 4 is wound over 360 ° starting from directly below the exhaust port 2b. In such a form, the tube 4 has a portion A exceeding 360 °, so that even if the lead storage battery is swung while the side surface 1b of the battery case 1 is placed on the bottom surface, it overflows into the communication path. The electrolytic solution stops in the middle of the tube 4 wound in a spiral shape. That is, since the electrolyte does not exceed A in the tube 4 and reaches the tube outlet (the other end of the tube 4), the electrolyte does not overflow from the tube 4. Therefore, it can prevent that an operator touches electrolyte solution directly, and can work safely.

なおチューブ4の素材としては、ポリエチレン系合成樹脂、ポリプロピレン系合成樹脂、ポリアミド系合成樹脂、またはゴムなどを用いることができる。さらにチューブ4の先端に樹脂製のフィルタ4a(好ましくは通気性があり、かつ液体としての水は通さない材質からなるフィルタ)で塞げば、万一の激しい搖動があった場合でも、チューブ4の中に溜まった電解液が漏れることを防ぎつつ、電槽の変形を抑制できるようになる。このような効果を発揮できる樹脂製のフィルタ4aとしては、撥水性を有する多孔体(ポリテトラフルオロエチレンなどの多孔体)を用いることができる。   As a material of the tube 4, a polyethylene synthetic resin, a polypropylene synthetic resin, a polyamide synthetic resin, rubber, or the like can be used. Further, if the tube 4 is closed with a resin filter 4a (preferably a filter made of a material that is breathable and does not allow liquid water to pass through), the tube 4 can be It is possible to suppress the deformation of the battery case while preventing the electrolytic solution accumulated therein from leaking. As the resin filter 4a capable of exhibiting such an effect, a water-repellent porous body (a porous body such as polytetrafluoroethylene) can be used.

(実施形態2)
図3は本発明の鉛蓄電池の一例を部分的に示す図である。本実施形態の鉛蓄電池は排気口2bの直下を起点として、チューブ4を450°を超えて捲回させた形態を有している。このような形態にすれば、チューブ4おいて450°を超えた部分Bがあることで、蓋2の天面を下面として載置した状態(倒立状態)で搖動させても、電解液はチューブ4内においてBを超えてチューブ出口まで達することはないので、電解液がチューブ4から溢れ出ることがなくなる。
(Embodiment 2)
FIG. 3 is a diagram partially showing an example of the lead storage battery of the present invention. The lead storage battery of the present embodiment has a configuration in which the tube 4 is wound over 450 ° starting from directly under the exhaust port 2b. In such a form, since there is a portion B exceeding 450 ° in the tube 4, even if the tube 2 is swung with the top surface of the lid 2 placed on the bottom surface (inverted state), the electrolyte solution is in the tube. 4, the electrolyte does not overflow from the tube 4 because it does not exceed B and reach the tube outlet.

(実施形態3)
図4は本発明の鉛蓄電池の一例を部分的に示す図である。本実施形態の鉛蓄電池は電槽の側面のうち、排気口2bの直下にある側面1aに隣接する他の側面1bにチューブ4の先端を対峙させた形態を有している。つまり、チューブ4が側面1aに対峙して捲回され、チューブ4の出口となる端が別の側面1bの方へ曲げられている状態である。このような形態にすれば、チューブ4において側面1bに対峙している先端部分Cがあることで、電槽1の側面1aを下面として載置されても、電解液がチューブ4から溢れでることがなくなる。
(Embodiment 3)
FIG. 4 is a diagram partially showing an example of the lead storage battery of the present invention. The lead storage battery of this embodiment has the form which made the front-end | tip of the tube 4 oppose the other side surface 1b adjacent to the side surface 1a directly under the exhaust port 2b among the side surfaces of a battery case. That is, the tube 4 is wound around the side surface 1a, and the end serving as the outlet of the tube 4 is bent toward another side surface 1b. In such a form, the electrolyte solution overflows from the tube 4 even when the tube 4 is placed with the side surface 1a of the battery case 1 as the bottom surface because of the tip portion C facing the side surface 1b. Disappears.

以上の実施形態1から3の全てを組み合わせた形態とすれば、鉛蓄電池及び梱包体をどのような状態で載置しても、電解液がチューブ4から溢れ出ることを抑えることができるようになる。   If all the above Embodiments 1 to 3 are combined, the electrolyte solution can be prevented from overflowing from the tube 4 regardless of the state in which the lead storage battery and the package are placed. Become.

なお鉛蓄電池を車載するのは、専門知識を持った作業者であることが多い。この作業者に排気口2bからチューブ4内へ電解液の漏れがあったか否かを判断させるには、チューブ4の材質は電解液を視認できるものとするのが望ましい。このような形態にすれば、車載を行う作業者が電解液の漏れに気づくことができるので、チューブ4を取り外す際に作業者が溢れ出た電解液に触れることによって傷ついてしまうことが防げる上に、弁2aを開閉できる構造であれば、溢れ出た電解液の総量を目分量で把握し、その分だけ鉛蓄電池に新たな電解液を補うことも可能になる。具体的には、チューブ4の素材を透明または淡い色調の半透明の材質とすることで、電解液が視認できるようになる。   In many cases, the lead-acid battery is mounted on the vehicle by an operator having specialized knowledge. In order for this operator to determine whether or not the electrolyte solution has leaked from the exhaust port 2b into the tube 4, it is desirable that the material of the tube 4 is such that the electrolyte solution can be visually recognized. With such a configuration, an on-board operator can notice the leakage of the electrolytic solution, so that it is possible to prevent the worker from being damaged by touching the overflowing electrolytic solution when removing the tube 4. In addition, if the valve 2a can be opened and closed, it is possible to grasp the total amount of the overflowing electrolyte solution with a nominal amount and supplement the lead storage battery with a new electrolyte solution accordingly. Specifically, the electrolyte solution can be visually recognized by making the material of the tube 4 transparent or a semi-transparent material with a light color tone.

また捲回したチューブ4を排気口2bの直下にある電槽1の側面1aに単に対峙させる(例えばぶら下げる)だけでなく、このチューブ4を側面1aに当接させることにより、鉛蓄電池とチューブ4とが密着して梱包性が高まる(箱に入れやすくなる)上に、梱包体を輸送する際にチューブ4が箱の内面にも密着するので、箱の内部で鉛蓄電池が過剰に搖動しなくなって、電解液がさらに溢れ出にくくなる。チューブ4を側面1aに当接させるには、チューブ4を粘着テープや粘着剤等を用いて側面1aに固定をすればよい。   In addition, the wound tube 4 is not simply opposed (for example, hung) to the side surface 1a of the battery case 1 immediately below the exhaust port 2b, but the lead-acid battery and the tube 4 are brought into contact with the side surface 1a. And the packing performance is improved (it is easy to put in the box), and when the package is transported, the tube 4 also adheres to the inner surface of the box, so that the lead-acid battery does not excessively move inside the box. As a result, the electrolyte is more difficult to overflow. In order to bring the tube 4 into contact with the side surface 1a, the tube 4 may be fixed to the side surface 1a using an adhesive tape, an adhesive, or the like.

本発明を用いた鉛蓄電池は、少々乱暴に輸送あるいは荷積みを行っても電解液が漏れにくく、安全性が高い。したがって工業上、極めて有用である。   The lead-acid battery using the present invention has high safety because the electrolyte does not easily leak even if it is transported or loaded a little roughly. Therefore, it is very useful industrially.

1 電槽
1a、1b 側面
2 蓋
2a 弁
2b 排気口
2c 連通孔
2d 上蓋
3 端子
4 チューブ
4a フィルタ
5 排気管
6 箱
DESCRIPTION OF SYMBOLS 1 Battery case 1a, 1b Side surface 2 Lid 2a Valve 2b Exhaust port 2c Communication hole 2d Upper lid 3 Terminal 4 Tube 4a Filter 5 Exhaust pipe 6 Box

Claims (9)

正極板と負極板とをセパレータを介して対峙させた複数の極板群と、
中仕切板によって複数のセル室に区切られ、各前記セル室に前記複数の極板群のそれぞれと電解液とを収容し、上方が開口している直方体形状の電槽と、
前記電槽の開口部を塞ぐ蓋と
を備え、
前記蓋は、前記複数のセル室のそれぞれの直上に対応する複数の弁と、前記複数の弁の上方を覆う上蓋と、前記複数の弁を連通させつつ一端が排気口となっている連通経路とを有しており、
一方の端が前記排気口に接続されているとともに、前記排気口の直下にある前記電槽の側面に対峙して渦巻状に捲回されたチューブをさらに備え
前記チューブは、前記電解液を視認できる材質からなることを特徴とする、鉛蓄電池。
A plurality of electrode plate groups in which a positive electrode plate and a negative electrode plate are opposed to each other via a separator;
A battery case having a rectangular parallelepiped shape that is divided into a plurality of cell chambers by an intermediate partition plate, accommodates each of the plurality of electrode plate groups and the electrolytic solution in each of the cell chambers, and has an open top.
A lid for closing the opening of the battery case;
The lid includes a plurality of valves corresponding directly above the plurality of cell chambers, an upper lid covering the top of the plurality of valves, and a communication path having one end serving as an exhaust port while communicating the plurality of valves. And
One end is connected to the exhaust port, and further includes a tube wound in a spiral shape facing the side surface of the battery case directly below the exhaust port ,
The lead-acid battery according to claim 1 , wherein the tube is made of a material that allows the electrolyte solution to be visually recognized .
前記チューブを、前記排気口の直下を起点として360°を超えて捲回させたことを特徴とする、請求項1に記載の鉛蓄電池。   The lead acid battery according to claim 1, wherein the tube is wound over 360 ° starting from directly under the exhaust port. 前記チューブを、前記排気口の直下を起点として450°を超えて捲回させたことを特徴とする、請求項2に記載の鉛蓄電池。   The lead acid battery according to claim 2, wherein the tube is wound over 450 ° starting from directly under the exhaust port. 前記チューブを、前記排気口の直下にある前記電槽の側面に当接させたことを特徴とする、請求項1に記載の鉛蓄電池。   The lead acid battery according to claim 1, wherein the tube is brought into contact with a side surface of the battery case directly under the exhaust port. 前記チューブの先端を、前記排気口の直下にある前記電槽の側面に隣接する他の側面に対峙させたことを特徴とする、請求項1に記載の鉛蓄電池。   The lead acid battery according to claim 1, wherein the tip of the tube is opposed to another side surface adjacent to the side surface of the battery case directly below the exhaust port. 前記チューブの他方の端を、樹脂製のフィルタで塞いだことを特徴とする、請求項1に記載の鉛蓄電池。   The lead acid battery according to claim 1, wherein the other end of the tube is closed with a resin filter. 前記フィルタは、通気性を有し液体の水は不透過である材質からなることを特徴とする、請求項に記載の鉛蓄電池。 The lead storage battery according to claim 6 , wherein the filter is made of a material that is air permeable and impermeable to liquid water. 請求項1からのいずれか一つに記載の鉛蓄電池を箱に収容した、鉛蓄電池の梱包体。 The package of a lead storage battery which accommodated the lead storage battery as described in any one of Claim 1 to 7 in the box. 正極板と負極板とをセパレータを介して対峙させた複数の極板群と、中仕切板によって複数のセル室に区切られるとともに各前記セル室に前記複数の極板群のそれぞれと電解液とを収容して上方が開口している直方体形状の電槽と、前記電槽の開口部を塞ぐ蓋とを備え、前記蓋は、前記複数のセル室のそれぞれの直上に対応する複数の弁と、前記複数の弁の上方を覆う上蓋と、前記複数の弁を連通させつつ一端が排気口となっている連通経路とを有している鉛蓄電池を、前記排気口の直下にある前記電槽の側面に対峙して渦巻状に捲回され且つ前記電解液を視認できる材質からなるチューブの一方の端を前記排気口に接続した状態で搬送する、鉛蓄電池の搬送方法。 A plurality of electrode plate groups in which a positive electrode plate and a negative electrode plate are opposed to each other via a separator, and divided into a plurality of cell chambers by an intermediate partition plate, and each of the plurality of electrode plate groups and an electrolyte solution in each cell chamber And a lid that closes the opening of the battery case, and the lid includes a plurality of valves corresponding to each of the plurality of cell chambers. A lead-acid battery having an upper lid that covers the upper side of the plurality of valves and a communication path having one end serving as an exhaust port while allowing the plurality of valves to communicate with each other; and the battery case directly below the exhaust port A method for transporting a lead-acid battery, comprising transporting the tube with one end of a tube made of a material wound in a spiral shape facing the side surface of the tube and connected to the exhaust port.
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