JP5570889B2 - Ballast water treatment equipment - Google Patents

Ballast water treatment equipment Download PDF

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JP5570889B2
JP5570889B2 JP2010147047A JP2010147047A JP5570889B2 JP 5570889 B2 JP5570889 B2 JP 5570889B2 JP 2010147047 A JP2010147047 A JP 2010147047A JP 2010147047 A JP2010147047 A JP 2010147047A JP 5570889 B2 JP5570889 B2 JP 5570889B2
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water
electrolyzed water
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ballast water
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吉宏 稲本
浩之 梅沢
達哉 廣田
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Sanyo Electric Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63JAUXILIARIES ON VESSELS
    • B63J4/00Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for
    • B63J4/002Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for for treating ballast water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/70Treatment of water, waste water, or sewage by reduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/008Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/29Chlorine compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/40Liquid flow rate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/18Removal of treatment agents after treatment
    • C02F2303/185The treatment agent being halogen or a halogenated compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Description

本発明は、タンカー等の船舶で使用される海水の取水及びバラスト水の排水を行うと共にバラスト水が排水されることによる環境への悪影響を防止できるようにしたバラスト水処理装置に関する。   The present invention relates to a ballast water treatment apparatus that can take in seawater and ballast water used in a ship such as a tanker, and prevent adverse effects on the environment due to the drainage of ballast water.

タンカー等の船舶においては、荷揚港で積荷の原油等を降ろした後、再度積荷港に向けて航行する際、航行中の船舶のバランスを取るため、所定のタンク(バラスト水タンク)内にバラスト水と呼ばれる海水を貯留している。このタンク内のバラスト水は、通常、荷揚港で積荷を降ろす際に海水を汲み上げ貯留されると共に、積荷港で積荷を積む際に排水される。   For ships such as tankers, when unloading crude oil, etc. at the unloading port and sailing again to the loading port, the ballast is placed in a specified tank (ballast water tank) in order to balance the ship in operation. It stores seawater called water. The ballast water in the tank is usually pumped up and stored when unloading at the unloading port and drained when loading at the loading port.

そして、荷揚港で取水するバラスト水には海水中の有毒微細藻類、プランクトン、コレラ菌や大腸菌などの細菌などの微小な生物(以下、「有害生物」という。)が混入することがあり、積荷港でバラスト水をそのまま放出すると、有害生物が積荷港付近の海域を汚染することになる。これらの有害生物のうち、特に微小な生物は、環境条件によって積荷港付近の海域で増殖し、その海域に本来生息する生物を死滅させるなどの大きな被害をもたらすことがある。   Ballast water taken at the port of unloading may contain toxic microalgae in the seawater, plankton, microbes such as bacteria such as cholera and Escherichia coli (hereinafter referred to as “pests”). If ballast water is discharged as it is at the port, pests will contaminate the sea area near the loading port. Among these pests, especially minute ones can grow in the sea area near the port of loading depending on the environmental conditions and cause great damage such as killing the creatures that originally live in the sea area.

このようなバラスト水による積荷港での水質汚染を防止するために、種々のバラスト水処理装置が提案されているが、例えば海水を電気分解して生成した次亜塩素酸を含む電解水をバラスト水タンクに注入することにより荷揚港で取水したバラスト水中の有害生物を積荷港で排水するまでに不活性化又は死滅させるようにし、バラスト水の排水によって積荷港の海域の環境を破壊しないようにしたバラスト水処理装置がある(例えば、特許文献1参照)。   Various ballast water treatment devices have been proposed in order to prevent water pollution at the loading port due to such ballast water. For example, electrolytic water containing hypochlorous acid generated by electrolyzing seawater is ballasted. By injecting into the water tank, pests in the ballast water taken at the port of discharge will be inactivated or killed before draining at the port of loading, so that the environment of the sea area of the port of loading will not be destroyed by draining the ballast water. There is a ballast water treatment apparatus (see, for example, Patent Document 1).

このバラスト水処理装置では、海水を利用して次亜塩素酸を含む電解水を生成し、バラスト水中の有害生物を不活性化又は死滅させるようにしているので、電解水生成装置を組み込むだけで良く、設備費の低減化やランニングコストの削減が図れる反面、電解水を含むバラスト水が排水されることによって積荷港の海域に生息する生物を死滅させないようにするために、バラスト水の排水前にバラスト水中の残留塩素濃度が実質的にゼロになるまでバラスト水を放置しておかなければならず、積荷港でのバラスト水の排水に時間を要する問題があった。   In this ballast water treatment device, electrolyzed water containing hypochlorous acid is generated using seawater, and pests in the ballast water are inactivated or killed. Although the equipment cost can be reduced and the running cost can be reduced, the ballast water before the ballast water is drained in order not to kill the organisms that live in the sea area of the loading port by draining the ballast water including electrolyzed water. In addition, the ballast water must be left until the residual chlorine concentration in the ballast water becomes substantially zero, and there is a problem that it takes time to drain the ballast water at the loading port.

また、電解水生成装置で使用する海水の濾過精度が低いことから、電解水生成装置の電極表面に海水中の有機物やミネラルが付着して電解水の生成能力が低下したり、電解水生成のための消費電力が大きくなる問題があった。   In addition, since the filtration accuracy of seawater used in the electrolyzed water generating device is low, organic matter and minerals in seawater adhere to the electrode surface of the electrolyzed water generating device and the electrolyzed water generation capacity decreases, or electrolyzed water generation Because of this, there is a problem that power consumption increases.

そこで、本特許出願人は、船舶のバラスト水タンクに海水を取水する取水流路と、前記バラスト水タンクのバラスト水を排水する排水流路と、前記取水流路に設けられた第1の濾過装置と、前記取水回路の前記第1の濾過装置の下流に設けられこの第1の濾過装置より濾過精度が高い第2の濾過装置と、前記取水回路の前記第2の濾過装置の下流に設けられて電解水を生成する電解水生成装置と、前記排水流路に設けられて前記バラスト水タンク内のバラスト水に含まれる塩素を除去する塩素除去装置と、前記電解水生成装置で生成された電解水を前記第2の濾過装置に供給する濾過装置洗浄手段とを設けたことを特徴とするバラスト水処理装置を提案している(特許文献2参照)。   Accordingly, the applicant of the present patent application provides a water intake channel for taking seawater into a ballast water tank of a ship, a drainage channel for discharging ballast water from the ballast water tank, and a first filtration provided in the water intake channel. A second filtering device provided downstream of the first filtration device of the intake circuit and having a higher filtration accuracy than the first filtration device; and provided downstream of the second filtration device of the intake circuit. Generated by the electrolyzed water generating device for generating electrolyzed water, the chlorine removing device for removing chlorine contained in the ballast water in the ballast water tank provided in the drainage flow path, and the electrolyzed water generating device. There has been proposed a ballast water treatment device provided with a filtration device cleaning means for supplying electrolyzed water to the second filtration device (see Patent Document 2).

このバラスト水処理装置では、海水の取水時には濾過装置で濾過された海水をバラスト水としてバラスト水タンクに供給すると共に、濾過された海水の一部を電解水生成装置によって次亜塩素酸を含む電解水としてバラスト水タンクに注入してバラスト水中の有害生物を不活性化又は死滅させるようにし、バラスト水の排水時にはバラスト水に含まれる塩素を塩素除去装置で除去し、バラスト水が排水されることによって積荷港の海域の環境が破壊しないようにしつつ、バラスト水の速やかな排水が可能となる。   In this ballast water treatment device, when seawater is taken, seawater filtered by the filtration device is supplied as ballast water to a ballast water tank, and a part of the filtered seawater is electrolyzed containing hypochlorous acid by an electrolyzed water generator. It is injected into the ballast water tank as water to inactivate or kill pests in the ballast water, and when ballast water is drained, the chlorine contained in the ballast water is removed by a chlorine removal device, and the ballast water is drained. As a result, the ballast water can be quickly drained while preventing the environment of the sea area of the cargo port from being destroyed.

また、濾過精度の低い第1の濾過装置を通してバラスト水の取水を速やかに行いつつ、濾過精度の高い第2の濾過装置を通して電解水の生成を行うと共に第2の濾過装置を電解水で洗浄することによって第2の濾過装置の濾過精度が低下しないようし、電解水生成装置の電極表面に海水中の有機物やミネラルが付着しないようにして電解水生成装置の電解水生成能力を長期にわたって維持することができる。   Also, while quickly taking in the ballast water through the first filtration device having a low filtration accuracy, the electrolytic water is generated through the second filtration device having a high filtration accuracy, and the second filtration device is washed with the electrolytic water. This prevents the filtration accuracy of the second filtration device from being lowered, and maintains the electrolyzed water generation capability of the electrolysis water generation device over a long period of time so that organic substances and minerals in seawater do not adhere to the electrode surface of the electrolysis water generation device. be able to.

特許第4262720号公報Japanese Patent No. 4262720 特願2010−038538号の願書に添付した明細書、特許請求の範囲及び図面Description, claims and drawings attached to the application for Japanese Patent Application No. 2010-038538

しかしながら、上述したバラスト水処理装置では、海水の取水時には濾過装置で濾過された海水をバラスト水としてバラスト水タンクに供給するとともに、濾過された海水の一部を電解水生成装置によって次亜塩素酸を含む電解水としてバラスト水タンクに注入する方式のため、電解水生成装置の電解水生成能力がバラスト水タンクのバラスト水の水量に見合った多量の電解水を生成できるものでなければならず、電解水生成装置が大型化してコスト高になるとともに、消費電量が嵩む問題があった。   However, in the above-described ballast water treatment apparatus, when seawater is taken, seawater filtered by the filtration apparatus is supplied to the ballast water tank as ballast water, and a part of the filtered seawater is hypochlorous acid by the electrolyzed water generation apparatus. Therefore, the electrolyzed water generating capacity of the electrolyzed water generating device must be capable of generating a large amount of electrolyzed water commensurate with the amount of ballast water in the ballast water tank. As the electrolyzed water generating device is enlarged and the cost is increased, there is a problem that the power consumption is increased.

そこで本発明は、電解水を利用してバラスト水中の有害生物を効率良く不活性化又は死滅させるようにし、積荷港でのバラスト水の排水が速やかに行えるようにしつつ、電解水生成部の小型化を図り、消費電力の低減が図れるようにすることを目的とする。   Therefore, the present invention uses electrolytic water to efficiently inactivate or kill pests in the ballast water, and quickly discharge the ballast water at the loading port, while reducing the size of the electrolytic water generation unit. The purpose is to reduce power consumption.

このため第1の発明に係るバラスト水処理装置は、船舶のバラスト水タンクに海水を取水する取水流路と、前記バラスト水タンクのバラスト水を排水する排水流路と、前記取水流路に設けられた第1の濾過装置と、前記第1の濾過装置の下流側の取水流路から分岐された分岐流路と、この分岐流路に順次設けられた前記第1の濾過装置より濾過精度が高い第2の濾過装置、電解水を生成する電解水生成部及びこの電解水生成部により生成された電解水を貯留する電解水貯留部と、前記排水流路に設けられ前記バラスト水タンクから排水されるバラスト水に含まれる塩素を除去する塩素除去装置と、バラスト水の取水時には前記電解水貯留部の電解水の前記取水流路への注入を制御すると共にバラスト水の排水時には前記塩素除去装置を制御する制御装置とを備え、前記電解水生成部は、前記第2の濾過装置を経た濾過水が供給される電解槽とこの電解槽に設けられた電解用電極と前記電解槽の電解水を循環させる循環ポンプとを備えた電解水生成部と、前期電解水貯留部は、前記電解槽から前記電解水生成部で生成された電解水のオーバーフローしたものを貯留し、前記第2の濾過装置はプランクトン、大腸菌等を除去・減少させる第1のフィルタとカルシウムイオン、マグネシウムイオン等を除去・減少させる第2のフィルタの2段のフィルタからなり、前記電解水生成部に供給される濾過水以外の前記第1のフィルタ及び第2のフィルタからの排出物はそれぞれ電解水注入部よりも上流側の前記取水流路に戻すようにしたことを特徴とする。
For this reason, the ballast water treatment apparatus according to the first aspect of the present invention is provided in a water intake passage for taking seawater into a ballast water tank of a ship, a drain passage for draining ballast water in the ballast water tank, and the water intake passage. The filtration accuracy is higher than that of the first filtration device, the branch flow channel branched from the intake flow channel on the downstream side of the first filtration device, and the first filtration device sequentially provided in the branch flow channel. A high second filtration device, an electrolyzed water generating unit for generating electrolyzed water, an electrolyzed water storage unit for storing electrolyzed water generated by the electrolyzed water generating unit, and drainage from the ballast water tank provided in the drainage channel A chlorine removing device for removing chlorine contained in the ballast water, and controlling the injection of the electrolytic water in the electrolytic water storage section into the water intake flow path when taking in the ballast water, and the chlorine removing device at the time of draining the ballast water Control And a control device, wherein the electrolytic water generating unit circulates the electrolytic water of the second electrolytic bath filtered water is supplied that has passed through the filtering device and the electrode for electrolysis provided in the electrolytic bath the electrolysis tank The electrolyzed water generating unit including the circulation pump and the electrolyzed water storage unit store the overflow of the electrolyzed water generated in the electrolyzed water generating unit from the electrolytic cell, and the second filtration device is plankton. The first filter for removing / reducing E. coli and the like and the second filter for removing / reducing calcium ions, magnesium ions, etc., except for the filtered water supplied to the electrolyzed water generation unit The discharged substances from the first filter and the second filter are respectively returned to the intake flow channel upstream of the electrolyzed water injection part .

また、第2のバラスト水処理装置に係る発明は、第1の発明において、前記制御装置は電解水が注入される前記取水流路に設けられた塩素濃度センサが検出する塩素濃度に基づいてポンプによる電解水注入を制御するとともに、前記排水流路に設けられた残留塩素濃度センサが検出する残留塩素濃度に応じて前記塩素除去装置を制御することを特徴とする。   Further, in the invention related to the second ballast water treatment device, in the first invention, the control device is a pump based on a chlorine concentration detected by a chlorine concentration sensor provided in the water intake passage into which the electrolytic water is injected. And controlling the chlorine removing device according to the residual chlorine concentration detected by the residual chlorine concentration sensor provided in the drainage flow path.

また、第3のバラスト水処理装置に係る発明は、第2の発明において、前記第2の濾過装置と前記電解水生成部との間の分岐流路には濾過水を貯留する貯留槽と、この貯留槽の濾過水を前記電解水生成部に供給するポンプとを設けたことを特徴とする。   Moreover, the invention which concerns on a 3rd ballast water treatment apparatus WHEREIN: In the 2nd invention, the storage tank which stores filtered water in the branch flow path between the said 2nd filtration apparatus and the said electrolyzed water production | generation part, A pump for supplying filtered water from the storage tank to the electrolyzed water generating unit is provided.

のバラスト水処理装置に係る発明は、第の発明において、前記第2の濾過装置は、10μm以上のプランクトン、大腸菌等を除去・減少させつつ、前記電解水生成部における電解水生成に必要な量の塩化物イオンを通過させることを特徴とする。
The invention relating to the fourth ballast water treatment device is that, in the first invention, the second filtration device is capable of generating electrolyzed water in the electrolyzed water generating unit while removing and reducing plankton, E. coli and the like of 10 μm or more. It is characterized by passing the required amount of chloride ions.

本発明によれば、電解水生成部の小型化を図り、消費電力の低減が図れるようにしながら電解水を利用してバラスト水中の有害生物を効率良く不活性化又は死滅させることができ、積荷港でのバラスト水の排水時にはバラスト水に含まれる塩素を塩素除去装置で除去してバラスト水の排水が速やかに行えるようにしつつ、バラスト水が排水されることによって積荷港の海域の環境が破壊されるのを確実に防止できる。   According to the present invention, it is possible to efficiently inactivate or kill pests in ballast water using electrolyzed water while reducing the size of the electrolyzed water generating unit and reducing power consumption. When draining ballast water at the port, the chlorine in the ballast water is removed with a chlorine removal device so that the ballast water can be drained quickly, while the ballast water is drained, which destroys the marine environment of the loading port. Can be surely prevented.

本発明の実施の形態の説明に適用されるバラスト水処理装置の概略構成説明図である。It is schematic structure explanatory drawing of the ballast water treatment apparatus applied for description of embodiment of this invention.

以下、本発明を実施するための形態について、図1を参照しながら説明する。本発明のバラスト水処理装置の実施形態を示す図1において、1はタンカー等の船舶に設けられて複数の収容室に区画されるも各室が連通したバラスト水を貯留するバラスト水タンク、2はバラスト水タンク1に海水を取水する取水流路2であり、取水流路2にはバラスト水ポンプ3と、例えばスプリング式フィルタ等の50μm以上のゴミ、砂、泥、海藻等を除去する第1の濾過装置4とが設けられている。5は排水流路で、一端がバラスト水タンク1に連結する第1の排水流路5Aと第2の排水流路5Bとを有し、これらを前記バラスト水ポンプ3及び排水バルブ6を介して連結することによりバラスト水タンク1のバラスト水を船舶外に排水する排水流路である。   Hereinafter, an embodiment for carrying out the present invention will be described with reference to FIG. In FIG. 1 which shows embodiment of the ballast water treatment apparatus of this invention, 1 is provided in ships, such as a tanker, is divided into several storage chambers, but the ballast water tank which stores the ballast water which each chamber connected, 2 Is a water intake passage 2 for taking seawater into the ballast water tank 1, and the water intake flow passage 2 removes dust, sand, mud, seaweed, etc. of 50 μm or more such as a spring type filter, for example. 1 filtration device 4 is provided. Reference numeral 5 denotes a drainage channel, which has a first drainage channel 5A and a second drainage channel 5B, one end of which is connected to the ballast water tank 1, via the ballast water pump 3 and the drain valve 6. It is the drainage flow path which drains the ballast water of the ballast water tank 1 outside a ship by connecting.

7は第1の濾過装置4の下流側の取水流路2の分岐部2Aに接続された分岐流路で、この分岐流路7には開閉弁8と、送水ポンプ9と、10μm以上のプランクトン、大腸菌等の殆どを除去・減少させるプレフィルタ10A(第1のフイルタ)及びカルシウムイオン、マグネシウムイオン等の不純物の70〜80%を除去・減少させるナノフィルタ10B(第2のフィルタ)の2段のフィルタからなり第1の濾過装置4より濾過精度が高い第2の濾過装置10と、貯留槽11と、定量ポンプ12と、電解水生成装置13とが順次設けられている。   Reference numeral 7 denotes a branch flow path connected to the branch portion 2A of the intake water flow path 2 on the downstream side of the first filtration device 4. The branch flow path 7 includes an opening / closing valve 8, a water supply pump 9, and a plankton of 10 μm or more. Two stages of a pre-filter 10A (first filter) that removes and reduces most of Escherichia coli and the like, and a nano filter 10B (second filter) that removes and reduces 70 to 80% of impurities such as calcium ions and magnesium ions A second filtering device 10, a storage tank 11, a metering pump 12, and an electrolyzed water generating device 13 are sequentially provided.

従って、前記第2の濾過装置10は、10μm以上のプランクトン、大腸菌等を除去・減少させつつ、後述する電解水生成部13Aにおける電解水生成に必要な量の塩化物イオンを通過させることとなる。   Accordingly, the second filtration device 10 allows passage of chloride ions in an amount necessary for electrolyzed water generation in the electrolyzed water generating unit 13A described later while removing / reducing plankton, E. coli and the like of 10 μm or more. .

前記電解水生成装置13は電解水生成部13Aと、電解水貯留部13Bとからなる。前記電解水生成部13Aは貯留槽11に貯留された濾過水が定量ポンプ12によって供給される電解槽14と、この電解槽14に設けられた電解用電極15と、電解槽14の電解水を循環させることによりナノフィルタ10Bで除去しきれなかったカルシウムイオン、マグネシウムイオン等の不純物がスケールとなって電解用電極15に付着するのを防止する循環ポンプ16とからなり、電解槽14から電解水生成部13Aで生成された次亜塩素酸を含む電解水のオーバーフローしたものは電解水貯留部13Bに貯留するようにしてある。また、電解槽貯留部13Bには水位検出用電極17が取り付けられると共に、電解水に含まれる水素ガス、塩素ガス等の気体を船外に排出するための排気管18が取り付けられている。   The electrolyzed water generating device 13 includes an electrolyzed water generating unit 13A and an electrolyzed water storage unit 13B. The electrolyzed water generating unit 13A uses an electrolyzer 14 to which filtered water stored in the reservoir 11 is supplied by a metering pump 12, an electrode 15 for electrolysis provided in the electrolyzer 14, and electrolyzed water in the electrolyzer 14. It comprises a circulation pump 16 that prevents impurities such as calcium ions and magnesium ions that could not be removed by the nanofilter 10B by being circulated and adhered to the electrode 15 for electrolysis. The overflow of the electrolyzed water containing hypochlorous acid generated by the generating unit 13A is stored in the electrolyzed water storing unit 13B. In addition, a water level detection electrode 17 is attached to the electrolytic cell reservoir 13B, and an exhaust pipe 18 for discharging a gas such as hydrogen gas or chlorine gas contained in the electrolytic water to the outside of the ship is attached.

前記電解槽貯留部13Bに貯留された電解水は流量計19、定量ポンプ20、及び開閉弁21が順次設けられた電解水注入管22を介して第1の濾過装置4の下流側の取水流路2の分岐部2Aよりもさらに下流側の取水流路2の電解水注入部2Bに注入されるようにしている。また、第1の濾過装置4の排出物は排出弁23及び第2の排出流路5Bを介して船外に排出されるようにしてある。   The electrolyzed water stored in the electrolyzer storage part 13B flows downstream from the first filtration device 4 through an electrolyzed water injection pipe 22 in which a flow meter 19, a metering pump 20, and an on-off valve 21 are sequentially provided. It is made to inject | pour into the electrolyzed water injection | pouring part 2B of the intake water flow path 2 further downstream from the branch part 2A of the path | route 2. As shown in FIG. The discharge from the first filtration device 4 is discharged out of the ship via the discharge valve 23 and the second discharge flow path 5B.

また、第2の濾過装置10のプレフィルタ10Aから排出弁24を介して排出される小さなゴミとナノフィルタ10Bから貯留槽11に供給される濾過水以外のナノフィルタ10Bからの約3分の2の排水は、排水管25を介して取水流路2の分岐部2Aと電解水注入部2Bとの間の排出物戻り部2Cを介して取水流路2に戻されている。   Further, about two-thirds from the nanofilter 10B other than the small dust discharged from the prefilter 10A of the second filtration device 10 via the discharge valve 24 and the filtered water supplied to the storage tank 11 from the nanofilter 10B. The drainage water is returned to the water intake channel 2 via the drainage pipe 25 via the discharge return part 2C between the branch portion 2A of the water intake channel 2 and the electrolyzed water injection part 2B.

26は電解水注入部2Bよりも下流側の取水流路2に設けられた塩素濃度センサ、27は排水流路5Aに設けられた残留塩素濃度センサ、28は残留塩素濃度センサ27の取付け位置よりも下流側の排水流路5Aにチオ硫酸ナトリウム水溶液等の中和剤をポンプ29を介して投入する塩素除去装置である。   26 is a chlorine concentration sensor provided in the intake flow path 2 on the downstream side of the electrolyzed water injection part 2B, 27 is a residual chlorine concentration sensor provided in the drainage flow path 5A, and 28 is an attachment position of the residual chlorine concentration sensor 27. This is a chlorine removing device in which a neutralizing agent such as an aqueous sodium thiosulfate solution is introduced into the downstream drainage flow path 5A through a pump 29.

なお、バラスト水処理装置を統括的に制御する制御装置(図示せず)が設けられ、ソーラバッテリ(図示せず)等を電源とし、バラスト水の取水及び排水と電解水生成部13Aの作動を制御し、更には塩素濃度センサ26が検出する塩素濃度に応じて電解水注入を制御するとともに、残留塩素濃度センサ27が検出する残留塩素濃度に応じて前記塩素除去装置28を制御する。例えば、ポンプ29のオン/オフデューティ制御を行い、開時間と閉時間との比を制御したり、ポンプ29の開度度合を制御することにより、残留塩素濃度センサ27が検出する残留塩素濃度に応じて前記塩素除去装置28を制御して、排水流路5Aへの中和剤の投入量を制御する。   In addition, a control device (not shown) for comprehensively controlling the ballast water treatment device is provided, and a solar battery (not shown) or the like is used as a power source to take in and discharge ballast water and operate the electrolyzed water generating unit 13A. In addition, the electrolyzed water injection is controlled according to the chlorine concentration detected by the chlorine concentration sensor 26, and the chlorine removing device 28 is controlled according to the residual chlorine concentration detected by the residual chlorine concentration sensor 27. For example, the on / off duty control of the pump 29 is performed to control the ratio between the open time and the close time, or the degree of opening of the pump 29, so that the residual chlorine concentration detected by the residual chlorine concentration sensor 27 is adjusted. In response, the chlorine removing device 28 is controlled to control the amount of neutralizing agent charged into the drainage flow path 5A.

そして、荷揚港において原油等の荷揚が行われた際に、バラスト水ポンプ3を運転すると、取水流路2の第1の濾過装置4で濾過された海水の一部(取水流路の流量の500分の1以上)は分岐部2Aから分岐流路7に入り、開閉弁8、送水ポンプ9を介して第2の濾過装置10のプレフィルタ10Aに入り、ここでプランクトン、大腸菌等の殆どが除去・減少される。そして、さらにナノフィルタ10Bに入り、ここでカルシウムイオン、マグネシウムイオン等の不純物の70〜80%が除去・減少される。そして、ナノフィルタ10Bを通過した濾過水は貯留槽11に貯留されたのち、定量ポンプ12を介して電解水生成部13Aの電解槽14に送られる。   When the ballast water pump 3 is operated when crude oil or the like is unloaded at the unloading port, a part of the seawater filtered by the first filtration device 4 of the intake channel 2 (the flow rate of the intake channel) 1/500 or more) enters the branch flow path 7 from the branch section 2A, enters the prefilter 10A of the second filtration device 10 via the on-off valve 8 and the water supply pump 9, where most of plankton, E. coli, etc. Removed and reduced. Then, it further enters the nanofilter 10B, where 70 to 80% of impurities such as calcium ions and magnesium ions are removed and reduced. And the filtered water which passed nano filter 10B is stored in the storage tank 11, and is sent to the electrolytic tank 14 of the electrolytic water production | generation part 13A via the metering pump 12. FIG.

前記ナノフィルタ10Bは濾過精度が高く、濾過水以外の残りの3分の2の水が排水管25を経て取水流路2に排水されるため、分岐流路7に流れるのが取水量の500分の1以上であって、ナノフィルタ10Bを通過するのがその3分の1であるから、ナノフィルタ13Bを通過する濾過水の流量は取水流路2の流量の1500分の1以上と僅かになるが、濾過水は貯留槽11に一旦貯留され、貯留槽11から定量ポンプ12で電解槽14に送られるため、第2の濾過装置10から電解槽14に濾過水を安定供給することができる。   The nanofilter 10B has high filtration accuracy, and the remaining two-thirds of water other than filtered water is drained to the water intake flow path 2 through the drain pipe 25, so that the water intake amount of 500 flows into the branch flow path 7. The flow rate of filtrate water passing through the nanofilter 13B is slightly more than 1 / 1500th of the flow rate of the intake channel 2 because it is one third or more and one third of that passes through the nanofilter 10B. However, since the filtered water is temporarily stored in the storage tank 11 and is sent from the storage tank 11 to the electrolytic tank 14 by the metering pump 12, the filtered water can be stably supplied from the second filtering device 10 to the electrolytic tank 14. it can.

電解水生成部13Aの電解槽14に供給される濾過された海水は電解用電極15により次亜塩素酸を含む電解水となり、この電解水は電解槽14からオーバーフローして電解槽貯留部13Bに貯留される。また、電解槽14の電解水は既に第2の濾過装置10によってプランクトンや大腸菌、カルシウムイオン、マグネシウムイオン等の不純物がナノレベルで除去・減少されたものであり、しかも電解槽14の電解水は循環ポンプ16で循環させているため(循環させながら電解している。)、電解槽14に僅かに残ったカルシウムイオン、マグネシウムイオン等の不純物がスケールとなって電解用電極15に付着しないようにでき、電解水生成部13の電解用電極15を長期にわたって良好に使用できるようにしている。   The filtered seawater supplied to the electrolyzer 14 of the electrolyzed water generator 13A becomes electrolyzed water containing hypochlorous acid by the electrode 15 for electrolysis, and this electrolyzed water overflows from the electrolyzer 14 and enters the electrolyzer reservoir 13B. Stored. Moreover, the electrolyzed water in the electrolyzer 14 is one in which impurities such as plankton, Escherichia coli, calcium ions, and magnesium ions have already been removed / reduced at the nano level by the second filtration device 10, and the electrolyzed water in the electrolyzer 14 is Since it is circulated by the circulation pump 16 (electrolysis is performed while being circulated), impurities such as calcium ions and magnesium ions slightly remaining in the electrolytic cell 14 become scales and do not adhere to the electrode 15 for electrolysis. The electrode 15 for electrolysis of the electrolyzed water generator 13 can be used satisfactorily for a long time.

電解槽貯留部13Bの次亜塩素酸を含む電解水は電解水注入管22の流量計19、定量ポンプ20及び開閉弁21を通って電解水注入部2Bを介して取水流路2に注入される。そして、ここで第1の濾過装置4を通過した大部分の海水と混合され、電解水を含むバラスト水となってバラスト水タンク1に供給される。このため、従来のように電解水生成装置で大量の電解水を生成してバラスト水タンク1に供給するものに比べて電解水生成部13Aを小型にすることができ、消費電力の小さなものを使用することができる。しかも、電解水生成部13Aで作られた電解水を電解水貯留部13Bに溜め、定量ポンプ20で取水流路2に注入しているので、電解水を取水流路2に安定供給することができる。   Electrolyzed water containing hypochlorous acid in the electrolytic cell reservoir 13B is injected into the intake flow path 2 through the flow meter 19, the metering pump 20 and the on-off valve 21 of the electrolytic water injection pipe 22 and the electrolytic water injection part 2B. The And it mixes with most seawater which passed the 1st filtration apparatus 4 here, and becomes ballast water containing electrolyzed water, and is supplied to the ballast water tank 1. FIG. For this reason, the electrolyzed water generating unit 13A can be made smaller than the conventional electrolyzed water generating device that generates a large amount of electrolyzed water and supplies it to the ballast water tank 1. Can be used. Moreover, since the electrolyzed water produced by the electrolyzed water generating unit 13A is stored in the electrolyzed water storage unit 13B and injected into the water intake channel 2 by the metering pump 20, the electrolyzed water can be stably supplied to the water channel 2. it can.

このようにして取水流路2の第1の濾過装置4を通過した海水の一部を分岐流路7に分流し、ここで第2の濾過装置10でナノレベルにまで濾過したのち、電解水生成部13Aで次亜塩素酸を含む電解水を生成し、電解水貯留部13Bに貯留してから取水流路2に注入し、第1の濾過装置4で濾過された大部分の海水と電解水とを混合してバラスト水としてバラスト水タンク1に供給するようにしたので、次亜塩素酸を含む電解水をバラスト水タンクに直接注入するものに比べて少量の電解水を取水流路2に注入しながら、バラスト水中の有害生物を不活性化又は死滅させるようにでき、電解水生成部13Aの小型化を図り、消費電力の低減が図れる。   In this way, a part of the seawater that has passed through the first filtration device 4 of the intake flow channel 2 is diverted to the branch flow channel 7, where it is filtered to the nano level by the second filtration device 10, and then electrolyzed water Electrolyzed water containing hypochlorous acid is generated in the generating unit 13A, stored in the electrolyzed water storage unit 13B, injected into the water intake channel 2, and electrolyzed with most seawater filtered by the first filtering device 4. Since the water is mixed and supplied to the ballast water tank 1 as ballast water, a small amount of the electrolyzed water is taken in compared with the case where the electrolyzed water containing hypochlorous acid is directly injected into the ballast water tank 2. The pests in the ballast water can be inactivated or killed while being injected into the battery, so that the electrolyzed water generator 13A can be downsized and the power consumption can be reduced.

また、制御装置はバラスト水の取水制御や電解水生成部13の作動、並びに電解水の注入の制御を行いながら、塩素濃度センサ26が検出する塩素濃度が高濃度(10mg/L以上)になったときには定量ポンプ20を停止するとともに、開閉弁21を閉じ、高濃度の電解水が過度に注入されないようにし、塩素濃度センサ26が検出する塩素濃度がある程度低下したら(例えば、1mg/L)、電解水の注入を再開させるようにしているので、取水時の取水流路2での電解水注入を適度に、かつ効率良く行うことができる。   In addition, the control device controls the intake of the ballast water, the operation of the electrolyzed water generation unit 13 and the control of the injection of the electrolyzed water, and the chlorine concentration detected by the chlorine concentration sensor 26 becomes a high concentration (10 mg / L or more). When the metering pump 20 is stopped, the on-off valve 21 is closed so that high-concentration electrolyzed water is not excessively injected, and the chlorine concentration detected by the chlorine concentration sensor 26 decreases to some extent (for example, 1 mg / L). Since the injection of the electrolyzed water is resumed, the electrolyzed water can be injected in the water intake flow path 2 at the time of water intake appropriately and efficiently.

また、電解水生成部13Aに供給される濾過水以外のプレフィルタ10A及びナノフィルタ10Bからの排出物は外部に排出されることなく、排出管25を通って取水流路2の電解水注入部2Bよりも上流側の排出物戻り部2Cに戻されるため、これらの排出物に含まれる有害生物等も電解水によって不活性化又は死滅させることができる。   Further, the discharged water from the prefilter 10A and the nanofilter 10B other than the filtered water supplied to the electrolytic water generating unit 13A is not discharged to the outside, and the electrolytic water injection unit of the water intake passage 2 passes through the discharge pipe 25. Since it is returned to the waste return part 2C upstream of 2B, pests and the like contained in these wastes can be inactivated or killed by the electrolyzed water.

積荷港でバラスト水ポンプ3を運転すると、バラスト水タンク1のバラスト水は汲み上げられて、排水流路5A,バラスト水ポンプ3、開かれた排水弁6及び排水流路5Bを通って船舶外に排出される。このとき、排出流路5Aを流れるバラスト水に含まれる残留塩素濃度が残留塩素濃度センサ27で検出され、ポンプ29の駆動を制御することにより検出された残留塩素濃度に応じた量の中和剤が塩素除去装置28から排水流路5Aに投入されるので、バラスト水に含まれる残留塩素が塩素除去装置28からの適量の中和剤投入によって効率良く除去され、バラスト水が排水されることによって積荷港の海域の環境を破壊しないようにしつつ、バラスト水を速やかに排出させることができる。   When the ballast water pump 3 is operated at the loading port, the ballast water in the ballast water tank 1 is pumped up and out of the ship through the drainage channel 5A, the ballast water pump 3, the open drain valve 6 and the drain channel 5B. Discharged. At this time, the residual chlorine concentration contained in the ballast water flowing through the discharge channel 5A is detected by the residual chlorine concentration sensor 27, and an amount of neutralizing agent according to the residual chlorine concentration detected by controlling the drive of the pump 29. Is introduced into the drainage flow path 5A from the chlorine removing device 28, so that the residual chlorine contained in the ballast water is efficiently removed by charging an appropriate amount of the neutralizing agent from the chlorine removing device 28, and the ballast water is drained. Ballast water can be discharged quickly without destroying the environment of the sea area of the loading port.

以上本発明の実施態様について説明したが、上述の説明に基づいて当業者にとって種々の代替例、修正又は変形が可能であり、本発明はその趣旨を逸脱しない範囲で前述の種々の代替例、修正又は変形を包含するものである。   Although the embodiments of the present invention have been described above, various alternatives, modifications, and variations can be made by those skilled in the art based on the above description, and the present invention is not limited to the various alternatives described above without departing from the spirit of the present invention. It includes modifications or variations.

1 バラスト水タンク
2 取水流路
2A 分岐部
2B 電解水注入部
2C 排出物戻り部
4 第1の濾過装置
5 排水流路
7 分岐流路
10 第2の濾過装置
10A プレフィルタ
10B ナノフィルタ
11 貯留槽
12 定量ポンプ
13 電解水生成装置
13A 電解水生成部
13B 電解水貯留部
14 電解槽
15 電解用電極
22 電解水注入管
26 塩素濃度センサ
27 残留塩素濃度センサ
28 塩素除去装置
DESCRIPTION OF SYMBOLS 1 Ballast water tank 2 Water intake flow path 2A Branch part 2B Electrolyzed water injection | pouring part 2C Waste return part 4 1st filtration apparatus 5 Drain flow path 7 Branch flow path 10 2nd filtration apparatus 10A Prefilter 10B Nano filter 11 Reservoir DESCRIPTION OF SYMBOLS 12 Metering pump 13 Electrolyzed water production | generation apparatus 13A Electrolyzed water production | generation part 13B Electrolyzed water storage part 14 Electrolyzer 15 Electrode 22 Electrolysis water injection pipe 26 Chlorine concentration sensor 27 Residual chlorine concentration sensor 28 Chlorine removal apparatus

Claims (4)

船舶のバラスト水タンクに海水を取水する取水流路と、前記バラスト水タンクのバラスト水を排水する排水流路と、前記取水流路に設けられた第1の濾過装置と、前記第1の濾過装置の下流側の取水流路から分岐された分岐流路と、この分岐流路に順次設けられた前記第1の濾過装置より濾過精度が高い第2の濾過装置、電解水を生成する電解水生成部及びこの電解水生成部により生成された電解水を貯留する電解水貯留部と、前記排水流路に設けられ前記バラスト水タンクから排水されるバラスト水に含まれる塩素を除去する塩素除去装置と、バラスト水の取水時には前記電解水貯留部の電解水の前記取水流路への注入を制御すると共にバラスト水の排水時には前記塩素除去装置を制御する制御装置とを備え、前記電解水生成部は、前記第2の濾過装置を経た濾過水が供給される電解槽とこの電解槽に設けられた電解用電極と前記電解槽の電解水を循環させる循環ポンプとを備えた電解水生成部と、前期電解水貯留部は、前記電解槽から前記電解水生成部で生成された電解水のオーバーフローしたものを貯留し、前記第2の濾過装置はプランクトン、大腸菌等を除去・減少させる第1のフィルタとカルシウムイオン、マグネシウムイオン等を除去・減少させる第2のフィルタの2段のフィルタからなり、前記電解水生成部に供給される濾過水以外の前記第1のフィルタ及び第2のフィルタからの排出物はそれぞれ電解水注入部よりも上流側の前記取水流路に戻すようにしたことを特徴とするバラスト水処理装置。 A water intake passage for taking seawater into a ballast water tank of a ship, a drain passage for draining ballast water in the ballast water tank, a first filtration device provided in the water intake passage, and the first filtration A branch flow path branched from a water intake flow path on the downstream side of the apparatus, a second filtration apparatus having higher filtration accuracy than the first filtration apparatus sequentially provided in the branch flow path, and electrolyzed water for generating electrolyzed water A generation unit and an electrolyzed water storage unit that stores electrolyzed water generated by the electrolyzed water generation unit, and a chlorine removal device that removes chlorine contained in the ballast water provided in the drainage channel and drained from the ballast water tank And a controller for controlling the injection of the electrolyzed water from the electrolyzed water reservoir into the water intake flow path when taking the ballast water and controlling the chlorine removing device when draining the ballast water , the electrolyzed water generating unit Said An electrolyzed water generation unit comprising an electrolyzer supplied with filtered water through the filtration device, an electrode for electrolysis provided in the electrolyzer, and a circulation pump for circulating the electrolyzed water in the electrolyzer; The unit stores the overflow of the electrolyzed water generated by the electrolyzed water generating unit from the electrolytic cell, and the second filter device removes and reduces plankton, Escherichia coli, etc., the first filter and calcium ions, It consists of a two-stage filter of a second filter that removes and reduces magnesium ions, etc., and the discharge from the first filter and the second filter other than the filtrate supplied to the electrolyzed water generating unit is electrolyzed. A ballast water treatment device, wherein the ballast water treatment device is configured to return to the intake flow channel upstream of the water injection portion . 前記制御装置は電解水が注入される前記取水流路に設けられた塩素濃度センサが検出する塩素濃度に基づいてポンプによる電解水注入を制御するとともに、前記排水流路に設けられた残留塩素濃度センサが検出する残留塩素濃度に応じて前記塩素除去装置を制御することを特徴とする請求項1に記載のバラスト水処理装置。 The control device controls the injection of electrolyzed water by a pump based on the chlorine concentration detected by a chlorine concentration sensor provided in the water intake passage into which electrolyzed water is injected, and the residual chlorine concentration provided in the drainage passage. The ballast water treatment device according to claim 1, wherein the chlorine removal device is controlled in accordance with a residual chlorine concentration detected by a sensor. 前記第2の濾過装置と前記電解水生成部との間の分岐流路には濾過水を貯留する貯留槽と、この貯留槽の濾過水を前記電解水生成部に供給するポンプとを設けたことを特徴とする請求項2に記載のバラスト水処理装置。 A branch passage between the second filtration device and the electrolyzed water generation unit is provided with a storage tank for storing filtered water, and a pump for supplying the filtered water from the storage tank to the electrolyzed water generation unit. The ballast water treatment apparatus according to claim 2. 前記第2の濾過装置は、10μm以上のプランクトン、大腸菌等を除去・減少させつつ、前記電解水生成部における電解水生成に必要な量の塩化物イオンを通過させることを特徴とする請求項に記載のバラスト水処理装置。 The second filtration device, according to claim 1, characterized in that 10μm or plankton, while removing and reducing Escherichia coli, etc., to pass the amount of chloride ions required for producing electrolyzed water in said electrolytic water generator The ballast water treatment device described in 1.
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