JP5559651B2 - Glass blank manufacturing method for magnetic recording medium glass substrate, magnetic recording medium glass substrate manufacturing method, and magnetic recording medium manufacturing method - Google Patents

Description

  The present invention relates to a glass blank manufacturing method for a magnetic recording medium glass substrate, a magnetic recording medium glass substrate manufacturing method, and a magnetic recording medium manufacturing method.

  As a method for producing a magnetic recording medium glass substrate (magnetic disk substrate), typically, (1) a method of producing a molten glass lump through a press molding step of press molding a molten glass lump with a pair of press molds (hereinafter referred to as “ (Referred to as Patent Documents 1 and 2), and (2) a method of producing a glass sheet through a step of cutting it into a disk shape by a float method, a downdraw method, etc. It may be referred to as “sheet-like glass cutting method” (see Patent Document 3).

  In the conventional sheet-shaped glass cutting method exemplified in Patent Document 3, a lapping process (rough polishing process) and a polishing process (precision polishing process) are performed as a polishing process after a disk processing process for processing sheet glass on a disk. ) To obtain a magnetic recording medium glass substrate. However, the sheet-like glass cutting method disclosed in Patent Document 3 discloses that the lapping process (rough polishing process) is omitted and only the polishing process (precision polishing process) is performed as the polishing process.

  On the other hand, in the conventional press methods exemplified in Patent Documents 1 and 2, normally, after the molten glass lump is disposed on the lower mold, the upper mold and the lower mold are used to vertically move the molten glass lump. The magnetic recording medium is further subjected to a press forming process by press forming a molten glass lump by applying a pressing force (hereinafter also referred to as “vertical direct press”), followed by a lapping process, a polishing process, etc. A glass substrate is obtained.

  Here, in the press method shown in Patent Document 2, a method of placing a cooling upper die on a press-molded product after press molding in order to obtain a plate-shaped glass with a small warp while preventing a decrease in productivity. Has been proposed. In this method, the cooling state of the upper and lower surfaces of the press-molded product is balanced by using an upper die for cooling.

  Further, in the press method shown in Patent Document 2, in addition to the vertical direct press, the press molding process is performed by applying a pressing force from the horizontal direction to the molten glass lump by a pair of press molding dies arranged in the horizontal direction. It has also been proposed to carry out the method by an addition method (hereinafter sometimes referred to as “horizontal direct press”).

JP 2009-149477 A (Claim 1, paragraph number 0012, etc.) Patent No. 4380379 (paragraph 0031, FIGS. 1 to 9 etc.) Japanese Unexamined Patent Publication No. 2003-36528 (FIGS. 3 to 6, FIG. 8, etc.)

  On the other hand, in order to increase the productivity of the magnetic recording medium glass substrate, the lapping process performed mainly for the purpose of ensuring the flatness and thickness uniformity of the magnetic recording medium glass substrate and adjusting the plate thickness is omitted. Or shortening the time is very effective. This is because the wrapping process requires a wrapping apparatus for implementation, increasing the number of steps for producing a magnetic recording medium glass substrate and increasing the processing time. In addition, the lapping process may cause cracks on the glass surface, and the present situation is that the omission of the lapping process is being studied. Here, from the viewpoint of omitting the wrapping process or shortening the time, the sheet-like glass cutting method is compared with the press method, and the sheet-like glass with high flatness produced by the float method, down-draw method, etc. is used. The sheet-shaped glass cutting method for processing is more advantageous. However, the press method has an advantage that the glass utilization efficiency is higher than the sheet-like glass cutting method.

  Wrapping when producing a magnetic recording medium by applying post-processing to a glass blank for a magnetic recording medium glass substrate (hereinafter sometimes simply referred to as “glass blank”) produced using a vertical direct press. In order to omit the process or shorten the time, it is necessary to reduce the thickness deviation of the glass blank and to increase the flatness. Here, when manufacturing a glass blank by the vertical direct press, the temperature of the lower mold is set to a temperature sufficiently lower than the temperature of the molten glass lump so that the high-temperature molten glass lump does not melt. Therefore, the molten glass block is deprived of heat from the surface in contact with the lower mold until the press molding is started after the molten glass block is arranged on the lower mold. Therefore, the viscosity of the lower surface of the molten glass block arranged on the lower mold is locally increased. As a result, the press molding is performed on the molten glass lump in which a large viscosity distribution (temperature distribution) is generated, and thus a portion that is difficult to stretch is generated by pressing. Moreover, the cooling rate after press molding also differs for each part of the glass molded body that has been press-molded and stretched into a plate shape. For this reason, in the glass blank produced using a vertical direct press, plate | board thickness deviation increases or flatness tends to fall. Considering the mechanism described above, as shown in Patent Document 1, even in the case of a vertical direct press using an upper mold for cooling, the increase in the thickness deviation and the decrease in flatness of the glass blank are drastically reduced. It is difficult to suppress it.

  On the other hand, in the horizontal direct press exemplified in Patent Document 2, when the molten glass lump comes into contact with the press mold, it is pressed into a plate shape substantially simultaneously. That is, compared with the vertical direct press, the horizontal direct press has a uniform viscosity distribution of the molten glass lump at the time of press molding, and therefore it is easy to stretch the molten glass lump thinly and uniformly. For this reason, in comparison with the vertical direct press, in principle, it is considered that the horizontal direct press is easier to drastically suppress the increase in the plate thickness deviation and the decrease in flatness of the glass blank.

  On the other hand, with the further improvement of the recording density of magnetic recording media in recent years, the thickness deviation and flatness of glass magnetic recording medium glass substrates and glass blanks used for the production of magnetic recording media should be further improved. Is required. However, when the present inventors diligently examined, the glass blank produced by using the horizontal direct press described in Patent Document 2 could not meet the above-mentioned needs particularly in terms of flatness. .

  This invention is made | formed in view of the said situation, The glass blank manufacturing method for magnetic recording medium glass substrates which can produce the glass blank excellent in flatness, and magnetic recording medium glass substrate manufacture using the same It is an object of the present invention to provide a method and a magnetic recording medium manufacturing method.

The above-mentioned subject is achieved by the following present invention. That is,
The method for producing a glass blank for a magnetic recording medium glass substrate according to the present invention includes a first press mold and a first press mold in which a molten glass lump that is falling is arranged opposite to the direction intersecting the falling direction of the molten glass lump. A first press step of pressing into a plate by pressing with a second press mold, and a plate glass formed between the first press mold and the second press mold with the first press The second press step that continues to be pressed by the mold and the second press mold, and after passing through the second press step, the first press mold and the second press mold are separated, A glass blank for a magnetic recording medium glass substrate is produced through at least a take-out step of taking out the glass sheet sandwiched between the first press mold and the second press mold, and at least the first press step And second press During the implementation period, the temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold are substantially the same. In the first pressing step, Pressing the molten glass lump after bringing the press molding surface of the first press mold and the press molding surface of the second press mold substantially into contact with the molten glass lump, and the second The duration of the pressing step is controlled so that the flatness of the glass blank for a magnetic recording medium glass substrate is 10 μm or less.
Here, in the first aspect of the present invention, it is further characterized in that at least a region in contact with the glass sheet of the press forming surfaces of the first press mold and the second press mold is a substantially flat surface. To do.
The second aspect of the present invention is further characterized in that the pressing pressure in the second pressing step is decreased with time.

  In one embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the duration of the second pressing step is set so that the temperature of the plate glass at the end of the second pressing step is at least a plate shape. It is preferable to select the temperature to be equal to or lower than the temperature obtained by adding 10 ° C. to the strain point of the glass material constituting the glass.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the molten glass is suspended from the glass outlet, and the tip of the molten glass flow that continuously flows out downward in the vertical direction is provided. It is preferable to include a molten glass lump forming step of forming a molten glass lump by cutting.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the viscosity of the molten glass is preferably in the range of 500 dPa · s to 1050 dPa · s.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the first press mold and the second press mold are opposed to the direction perpendicular to the falling direction of the molten glass lump. It is preferable that they are arranged.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the press forming surfaces of the first press mold and the second press mold immediately before the first press step are performed. The absolute value of the in-plane temperature difference is preferably in the range of 0 ° C to 100 ° C.

In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate according to the first aspect of the present invention, it is preferable that the pressing pressure in the second pressing step is decreased with time.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the press pressure is set to the temperature of the sheet glass sandwiched between the first press mold and the second press mold. However, it is preferable to decrease when the glass material constituting the plate-like glass is lowered to the range of the yield point ± 30 ° C.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, during the second pressing step, one surface of the sheet glass and the press molding surface of the first press mold It is preferable that the other side of the sheet glass and the press molding surface of the second press mold are always closely adhered without any gap.

  In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention, the duration of the second pressing step is controlled so that the flatness of the glass blank for the magnetic recording medium glass substrate is 4 μm or less. It is preferable to do.

In another embodiment of the method for producing a glass blank for a magnetic recording medium glass substrate of the second aspect of the present invention, the region of the first press mold and the press molding surface of the second press mold that is in contact with at least the plate glass However, it is preferable that it is a substantially flat surface.

The method for producing a magnetic recording medium glass substrate of the present invention includes at least a polishing step for polishing the main surface of the glass blank for a magnetic recording medium glass substrate produced by the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention. characterized by manufacturing to Rukoto a magnetic recording medium glass substrate.

  In one embodiment of the method for producing a magnetic recording medium glass substrate of the present invention, the duration of the second pressing step is set such that the temperature of the plate glass at the end of the second pressing step is at least a plate glass. It is preferable that the temperature be selected to be equal to or lower than the temperature obtained by adding 10 ° C. to the strain point of the glass material to be formed.

  In another embodiment of the method for producing a magnetic recording medium glass substrate of the present invention, it is preferable that the flatness of the glass blank for the magnetic recording medium glass substrate and the flatness of the magnetic recording medium glass substrate are substantially the same.

The method for producing a magnetic recording medium of the present invention includes at least a polishing step for polishing the main surface of the glass blank for a magnetic recording medium glass substrate produced by the method for producing a glass blank for a magnetic recording medium glass substrate of the present invention. to produce a recording medium glass substrate, further, at least through the magnetic recording layer forming step of forming a magnetic recording layer on the magnetic recording medium glass substrate, and wherein, manufacturing to Rukoto the magnetic recording medium.

  In one embodiment of the method for producing a magnetic recording medium of the present invention, the duration of the second pressing step is set so that the temperature of the plate glass at the end of the second pressing step constitutes at least the plate glass. It is preferable to select the temperature to be equal to or lower than the temperature obtained by adding 10 ° C. to the strain point of the glass material.

  In another embodiment of the method for producing a magnetic recording medium of the present invention, the flatness of the glass blank for a magnetic recording medium glass substrate and the flatness of the magnetic recording medium glass substrate are preferably substantially the same.

  ADVANTAGE OF THE INVENTION According to this invention, the glass blank manufacturing method for magnetic recording medium glass substrates which can produce the glass blank excellent in flatness, the magnetic recording medium glass substrate manufacturing method using the same, and magnetic recording medium manufacture A method can be provided.

In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining a part of all the processes. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. It is a schematic cross section which shows an example of the molten glass lump in the fall. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. In an example of the manufacturing method of the glass blank of this embodiment, it is a schematic cross section explaining the other part of all the processes. It is a schematic cross section which shows an example of the press-molding die used for the manufacturing method of the glass blank of this embodiment.

(Method for producing glass blank for magnetic recording medium glass substrate)
The method for producing a glass blank for a magnetic recording medium glass substrate according to the present embodiment (hereinafter sometimes abbreviated as “a method for producing a glass blank”) refers to a falling molten glass lump with respect to the falling direction of the molten glass lump. The first press mold and the second press mold that are pressed by the first press mold and the second press mold that are arranged to face each other in a crossing direction and molded into a plate shape, and the first press mold and the second press mold A second press step in which the sheet glass formed between the mold and the second press mold is continuously pressed with the first press mold and the second press mold; And taking out the sheet glass sandwiched between the first press mold and the second press mold by separating the press mold and the second press mold and Glass bra for recording medium glass substrate The temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold at least during the execution period of the first press process and the second press process Are substantially the same, and in the first pressing step, the press molding surface of the first press mold and the press molding surface of the second press mold are brought into contact with the molten glass block almost simultaneously. Pressing the molten glass lump after allowing, and
The duration of the second pressing step is controlled so that the flatness of the glass blank is 10 μm or less. Here, in the present specification, “magnetic recording medium glass substrate” means a glass substrate for a magnetic recording medium made of amorphous glass (amorphous glass).

  In the manufacturing method of the glass blank of this embodiment, in the first pressing step, the temperature is sufficiently higher than the strain point of the glass material in the first pressing process, and the molten glass lump that maintains the state of being easily deformed is used. Press to form a plate. Here, after the press molding surface of the first press mold and the press molding surface of the second press mold are brought into contact with the molten glass mass almost simultaneously, the molten glass mass is pressed. In addition, during the period of the first press step and the second press step, the temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold Are substantially identical. For this reason, both sides of the molten glass block being formed into a plate shape in the first press step and the plate glass in a state of being sandwiched between a pair of press molds in the second press step are always symmetrical. It will continue to be cooled. For this reason, in the manufacturing method of the glass blank of this embodiment, compared with the vertical direct press which press-molds the molten glass lump in a state where the viscosity distribution is generated by being in contact with the lower mold for a long time, A temperature difference between both surfaces of the plate glass hardly occurs, and a decrease in flatness due to the temperature difference between both surfaces can be surely suppressed.

  On the other hand, the plate glass immediately after finishing the first pressing step has high temperature and high fluidity (low viscosity). For this reason, it is in the state which flat glass tends to deform | transform very easily and flatness tends to deteriorate. However, in the second press step that is performed following the first press step, the glass sheet formed between the first press mold and the second press mold is used as the first press step. Continue pressing with the mold and the second press mold. At this time, the duration of the second pressing step is controlled so that the flatness of the glass blank is 10 μm or less. In addition, it is preferable to control the continuation time of a 2nd press process so that the flatness of a glass blank may be 4 micrometers or less. Therefore, the flatness of the produced glass blank can be made more excellent. In addition, when the duration of a 2nd press process is short, distortion will arise in the plate glass of a cooling process by disturbance, and the said distortion will worsen the flatness of a glass blank. Therefore, the duration of the second pressing process is changed, the flatness of the obtained glass blank is measured, and as a result, the duration of the second pressing process is set so that the flatness is 10 μm or less, and the glass A blank is manufactured. However, if the duration of the second pressing step is too long, the productivity is lowered. Therefore, the duration of the second pressing step may be set in consideration of the flatness and productivity of the glass blank. From these viewpoints, the duration of the second pressing step is specifically preferably in the range of 2 to 40 seconds, and preferably in the range of 2 to 30 seconds.

  Further, in order to control the flatness of the glass blank to 10 μm or less, in the second pressing step, the sheet glass is brought to a temperature range in which the fluidity of the sheet glass is lost and deformation is virtually impossible. It is particularly preferred to select the duration of the second pressing step so as to continue pressing. In this case, the glass sheet can be solidified while maintaining a state in which the deformation of the glass sheet immediately after the first pressing step is suppressed. Therefore, the flatness of the produced glass blank can be made more excellent. Here, the duration in the second pressing step is equal to or lower than the temperature at which the temperature of the plate glass at the end of the second pressing step is 10 ° C. added to the strain point of the glass material constituting the plate glass. It is preferable to select such that the temperature is equal to or lower than the temperature obtained by adding 5 ° C. to the strain point, and further preferable to select so as to be equal to or lower than the strain point. On the other hand, the lower limit temperature of the temperature of the sheet glass at the end of the second pressing step is not particularly limited, but it is practical from the viewpoint of suppressing the productivity reduction due to the increase in time required for the second pressing step. In addition, the strain point is preferably higher than the strain point. Therefore, it is preferable that the upper limit value of the duration time in the second pressing step is also selected from this viewpoint.

  In the manufacturing method of the glass blank of the present embodiment, at least during the execution period of the first press step and the second press step, the temperature of the press forming surface of the first press mold and the second press mold It is necessary that the temperature of the press molding surface is substantially the same. Here, “substantially the same” means that the absolute value of the temperature difference between the temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold is within 10 ° C. It means that there is. The absolute value of this temperature difference is more preferably within 5 ° C, most preferably 0 ° C. Here, when there is a temperature distribution in the press molding surface, the “temperature of the press molding surface” means a temperature near the center of the press molding surface. For reference, in the vertical direct press method, the absolute value of the temperature difference between the upper mold press surface and the lower mold press surface during the press molding of the molten glass lump is also determined by the press molding conditions. However, it is generally about 50 ° C to 100 ° C.

  In the first pressing step, the molten glass lump is brought into contact with the molten glass lump substantially simultaneously with the press molded surface of the first press mold and the press molded surface of the second press mold. Press. Here, “substantially simultaneously contact” means that the absolute value of the time difference between the time when the molten glass block and one press-molded surface are in contact with the point when the molten glass block and the other press-formed surface are in contact with each other. It means within 0.1 seconds. The absolute value of this time difference is more preferably within 0.05 seconds, and most preferably 0 seconds. For reference, in the vertical direct press method, the time required for the molten glass lump to contact the upper press forming surface after the molten glass lump contacts the upper press forming surface depends on the press forming conditions. Although it depends, it is generally about 1.5 seconds to 3 seconds.

  In addition, in the conventional vertical direct press, after the molten glass lump is formed into a sheet glass with the upper mold and the lower mold, the sheet glass is continuously pressed with the upper mold and the lower mold. If cooled to the vicinity of the strain point, a significant improvement in the flatness of the glass blank can be expected. However, in this case, since the time required for press-molding one glass blank is greatly increased, a significant reduction in productivity is unavoidable and lacks practicality (see Patent Document 1, paragraph 0009). For this reason, in the vertical direct press, the applicant of the present application abandoned the adoption and practical application of a technology for cooling the glass sheet to the vicinity of the strain point in a state where the glass sheet is continuously pressed by the upper mold and the lower mold. In addition, various alternative technologies such as the use of an upper mold for cooling as exemplified in Patent Document 1 have attempted to achieve both productivity and improvement in flatness of a glass blank.

  For this reason, the first press mold is as early as possible even when mass-producing glass blanks by horizontal direct press, which is the same press method as the vertical direct press in that press molding is performed by a pair of press molds. It is considered that it is extremely important to separate the glass plate from the second press mold and take out the sheet glass. Thereby, after the molten glass lump has been formed into a sheet glass, it is easy to achieve both the productivity and the improvement of the flatness of the glass blank. Therefore, when mass-producing glass blanks by horizontal direct pressing, after the molten glass lump becomes plate-like glass, the plate-like glass is heated until the temperature becomes equal to or lower than the temperature obtained by adding 10 ° C. to the strain point. Implementation of the second pressing step that continues to press the glassy glass is considered to be lacking practically only by significantly reducing the productivity of the glass blank. However, as a result of intensive studies by the present inventors, it has been found that even if the second pressing step is performed in the horizontal direct press, the productivity is not lowered so much as to impair the practicality. The reason is as follows.

  First, in the vertical direct press, a molten glass lump is disposed in a lower mold, and then press molding is performed. For this reason, a molten glass lump in which a large temperature distribution (viscosity distribution) has been brought into contact with the lower mold for a long time must be press-formed by the upper mold and the lower mold. On the other hand, in the horizontal direct press, the molten glass lump that is falling is press-molded so as to be sandwiched between a pair of press-molding dies. That is, since the molten glass lump does not continue to contact one of the press molds until the press molding is started, as a result, the temperature distribution (viscosity distribution) of the molten glass lump at the start of press molding is Extremely uniform. Therefore, in order to produce a glass blank of the same thickness by horizontal direct press and vertical direct press, in order to stretch the molten glass lump thinly and evenly by press molding, vertical direct press compared to horizontal direct press Then, in consideration of the temperature distribution of the molten glass lump, it is necessary to set the average temperature of the molten glass lump higher. For this reason, the temperature difference between the average temperature of the molten glass lump and the strain point at the start of press molding is larger in the vertical direct press than in the horizontal direct press. This fact (first fact) is that, after the molten glass block is formed into a plate shape, the molten glass block and the horizontal direct press and the vertical direct press are used for cooling to near the strain point. If the cooling rate of the glass sheet is the same, it means that the horizontal direct press can cool in a shorter time than the vertical direct press.

  The cooling rate of the molten glass lump and the sheet glass is determined by the temperature of the pair of press molds in contact with the molten glass lump, assuming that the heat capacity of the press mold is the same regardless of the press method. The That is, at the start of press molding, the cooling rate increases if a low-temperature press mold is used, and the cooling rate decreases if a high-temperature press mold is used. Here, in the vertical direct press, since the lower mold and the molten glass lump are in contact for a long time before the press molding is started, the lower mold is melted until the press molding is started. It will be heated by the glass lump. Therefore, in the vertical direct press, press molding is always started in a state where one of the press molds (lower mold) is at a high temperature. This fact (second fact) means that it is much easier to increase the cooling rate of the molten glass lump and the sheet glass in the horizontal direct press than in the vertical direct press.

  Therefore, considering the above two facts, the time required to cool the molten glass lump into a plate shape and then cool down to the vicinity of the strain point is much greater with the horizontal direct press than with the vertical direct press. Obviously, it can be shortened. Therefore, even if the second pressing step is performed in the horizontal direct press, the productivity is not lowered so much as to impair the practicality that occurs in the vertical direct press.

  Although the manufacturing method of the glass blank of this embodiment demonstrated above will not be specifically limited if it includes at least a 1st press process, a 2nd press process, and an extraction process, Usually, a molten glass lump formation process is carried out. It is preferable to have. Below, each process including a molten glass lump formation process is demonstrated in detail. In the following description, description of points already described above is omitted.

-Molten glass lump formation process-
In the molten glass lump forming step, a molten glass lump that is an object of press molding is produced. Although it is not particularly limited as a method for producing a molten glass lump, usually, by dropping the molten glass from the glass outlet and cutting the tip of the molten glass flow that continuously flows out downward in the vertical direction, A molten glass lump is formed. It should be noted that a pair of shear blades can be used for cutting performed so as to separate the tip from the molten glass stream. The viscosity of the molten glass is not particularly limited as long as the viscosity is suitable for cutting of the tip portion or press molding, but is usually controlled to a constant value within a range of 500 dPa · s to 1050 dPa · s. It is preferable.

  Next, a specific example of the molten glass lump forming step will be described in detail with reference to the drawings. In the molten glass lump forming step, as shown in FIG. 1, a molten glass flow 20 is provided from a glass outlet 12 provided at the lower end of a molten glass outlet pipe 10 whose upper end is connected to a molten glass supply source (not shown). Is continuously discharged downward in the vertical direction. On the other hand, below the glass outlet 12, the first shear blade (lower blade) 30 and the second shear blade (upper blade) 40 are melted on both sides of the molten glass flow 20, respectively. It arrange | positions in the direction substantially orthogonal to the central axis D of the direction where the glass flow 20 hangs down. The lower blade 30 and the upper blade 40 are each orthogonal to the central axis D, and in the drawing, are orthogonal to the direction of the arrow X1 that proceeds from the left side to the right side, and the central axis D. And it moves to the front-end | tip part 22 side of the molten glass flow 20 from the both sides of the molten glass flow 20 by moving to the arrow X2 direction which advances from the right side to the left side in the figure. In addition, the viscosity of the molten glass flow 20 is controlled by adjusting the temperature of the molten glass outflow pipe 10 or the molten glass supply source upstream thereof.

  Further, the lower blade 30 and the upper blade 40 are provided on the substantially plate-like main body portions 32 and 42 and the end portions of the main body portions 32 and 42, and a molten glass flow that continuously flows downward in the vertical direction. It has the blade parts 34 and 44 which cut | disconnect the front-end | tip part 22 of 20 from the direction substantially orthogonal to the direction where the molten glass flow 20 hangs down. The upper surface 34U of the blade portion 34 and the lower surface 44B of the blade portion 44 form a surface that substantially coincides with the horizontal plane, and the lower surface 34B of the blade portion 34 and the upper surface 44U of the blade portion 44 intersect with the horizontal plane. An inclined surface is formed. In addition, the lower blade 30 and the upper blade 40 are arranged so that the upper surface 34U of the blade part 34 and the lower surface 44B of the blade part 44 are at substantially the same height with respect to the vertical direction.

  Next, as shown in FIG. 2, the upper blade 34U and the lower surface 44B of the blade portion 44 are moved further by moving the lower blade 30 and the upper blade 40 in the directions of the arrow X1 and the arrow X2, respectively. Move the lower blade 30 and the upper blade 40 in the horizontal direction so that they partially overlap with each other with almost no gap. That is, the lower blade 30 and the upper blade 40 are perpendicularly intersected with the central axis D. As a result, the lower blade 30 and the upper blade 40 penetrate into the molten glass flow 20 to the vicinity of the central axis D, and the tip 22 is cut as a substantially spherical molten glass lump 24. FIG. 2 shows a state in which the front end portion 22 is separated from the main body portion of the molten glass flow 20 as a molten glass lump 24. And as shown in FIG. 3, the molten glass lump 24 cut | disconnected from the molten glass flow 20 falls further to the downward Y1 side of a perpendicular direction.

-First pressing process-
In the first pressing step, the first press molding die and the second press molding in which the molten glass lump 24 shown in FIG. 3 is arranged to face each other in the direction intersecting the dropping direction of the molten glass lump 24. Press with a mold and mold into a plate. Here, the first press mold and the second press mold are opposed to each other in a direction substantially perpendicular to the falling direction of the molten glass lump 24 so as to form an angle within a range of 90 degrees ± 1 degree. It is preferable that they are arranged opposite to each other in a direction perpendicular to the direction in which the molten glass lump 24 falls. Thus, by arranging the pair of press molds so as to face the falling direction of the molten glass lump 24, it is easier to press the molten glass lump 24 from both sides and form it into a plate shape.

  Further, the temperature of the press molding surfaces of the first press mold and the second press mold immediately before the first press step is 10 ° C. at the strain point of the glass material constituting the molten glass lump 24. The temperature is preferably equal to or lower than the added temperature, and more preferably equal to or lower than the temperature obtained by adding 5 ° C. to the strain point of the glass material constituting the molten glass lump 24. By setting the temperature of the press-molded surface within the above-described range, it is possible to reliably suppress fusion of the molten glass lump 24 and the press-molded surface during press molding. The lower limit value of the temperature of the press molding surfaces of the first press mold and the second press mold immediately before the first press step is not particularly limited, but is due to the rapid cooling of the molten glass lump 24. From the practical point of view, such as preventing cracking of the glass blank and preventing a significant decrease in stretchability of the molten glass lump 24 due to a sudden increase in viscosity during press molding, it is above the strain point of the glass material constituting the molten glass lump 24. Preferably there is.

  Moreover, the absolute value of the difference between the temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold immediately before the first pressing step is 0 ° C. to It is preferably within the range of 10 ° C, more preferably within the range of 0 ° C to 5 ° C, and particularly preferably 0 ° C. In this case, it can suppress more reliably that the temperature difference in both surfaces of the plate glass formed in plate shape by the press of the molten glass lump 24 arises, and, as a result, flatness can be improved more.

  Moreover, the absolute value of the in-plane temperature difference between the press molding surfaces of the first press mold and the second press mold immediately before the first press step is in the range of 0 ° C to 100 ° C. It is preferably within the range of 0 ° C. to 50 ° C., particularly preferably 0 ° C. By setting the temperature distribution in the press molding surface within the above-described range, it becomes easier to stretch the molten glass lump 24 thinly and uniformly during press molding. As a result, even when a glass blank having a thinner plate thickness is manufactured, it is easier to obtain a glass blank that has excellent flatness and a small plate thickness deviation. The “in-plane temperature of the press-molded surface” means a temperature measured in the maximum region where the press-molded surface and the molten glass lump 24 stretched into a plate shape come into contact with each other during press molding.

  Next, the first pressing step will be described more specifically with reference to the drawings. First, as shown in FIG. 4, the molten glass lump 24 shown in FIG. 3 includes a first press mold 50 and a second press that are opposed to each other in a direction orthogonal to the falling direction Y <b> 1 of the molten glass lump 24. It enters between the molds 60. Here, the first press molding die 50 and the second press molding die 60 before the press molding are arranged symmetrically with respect to the dropping direction Y1 and spaced apart from each other in the orthogonal direction. ing. The molten glass lump 24 is press-molded by pressing the molten glass lump 24 from both sides at the timing when the molten glass lump 24 reaches the vicinity of the central portion in the vertical direction of the first press mold 50 and the second press mold 60. The first press mold 50 is moved in the direction of the arrow X1 perpendicular to the drop direction Y1 and proceeds from the left side to the right side in the figure, and the second press mold 60 is dropped. It moves in the direction of the arrow X2 that is orthogonal to the direction Y1 and proceeds from the right side to the left side in the figure. The moving speed of the first press mold 50 in the arrow X1 direction and the moving speed of the second press mold 60 in the arrow X2 direction are set to be the same or substantially the same.

  Here, the press molds 50 and 60 include press mold main bodies 52 and 62 having a substantially disk shape, and guide members 54 and 64 arranged so as to surround the outer peripheral ends of the press mold main bodies 52 and 62. Have. 4 is a cross-sectional view, the guide members 54 and 64 are drawn so as to be positioned on both upper and lower sides of the press mold main bodies 52 and 62 in FIG. Further, the description of the drive member that moves the press mold 50 in the direction of the arrow X1 and moves the press mold 60 in the direction of the arrow X2 is omitted in the drawing.

  One surface of the press mold body 52, 62 is a press molding surface 52A, 62A. In FIG. 4, the first press mold 50 and the second press mold 60 are arranged to face each other so that the press molding surfaces 52 </ b> A and 62 </ b> A face each other. Further, the guide member 54 is provided with a guide surface 54A at a height position slightly protruding in the X1 direction with respect to the press molding surface 52A, and the guide member 64 is slightly in the X2 direction with respect to the press molding surface 62A. 64 A of guide surfaces are provided in the height position which protruded only. For this reason, in the press molding, the guide surface 54A and the guide surface 64A come into contact with each other, so that a gap is formed between the press molding surface 52A and the press molding surface 62A. For this reason, this gap thickness is the thickness of the molten glass lump 24 that is press-molded between the first press mold 50 and the second press mold 60, that is, the thickness of the glass blank. . Further, the press molding surfaces 52A and 62A are formed so that the molten glass lump 24 is formed into the press molding surface 52A of the first press molding die 50 and the press molding surface 62A of the second press molding die 60 by performing the first pressing step. When the sheet is completely spread in the vertical direction and formed into a sheet glass, areas (melted glass stretching areas) S1 and S2 of the press-formed surfaces 52A and 62A that are in contact with at least the above sheet glass. However, it forms so that a substantially flat surface may be comprised. In the example shown in FIG. 4, the entire surface of the press molding surface 52A including the molten glass stretching region S1 and the press molding surface 62A including the molten glass stretching region S2 is a flat surface having a normal and substantially zero curvature. Make up. In addition, the flat surface has only minute unevenness formed by performing normal flattening processing or mirror polishing processing when manufacturing a press mold, and is larger than these minute unevenness. There are no protrusions and / or recesses.

  The glass blank is produced by pressing the molten glass lump 24 by pressing it with the press molding surfaces 52A and 62A. For this reason, the surface roughness of the press molding surfaces 52A and 62A and the surface roughness of the main surface of the glass blank are substantially equal. The surface roughness (centerline average roughness Ra) of the main surface of the glass blank is 0.01 to 10 μm in performing scribing performed as a post-process described later and grinding using a diamond sheet. Since it is desirable to make it into the range, it is preferable that the surface roughness (centerline average roughness Ra) of the press-molded surface is also in the range of 0.01 to 10 μm.

  The molten glass lump 24 shown in FIG. 4 further falls downward and enters between the two press molding surfaces 52A and 62A. Then, as shown in FIG. 5, when the press molding surfaces 52 </ b> A and 62 </ b> A that are parallel to the drop direction Y <b> 1 reach the vicinity of the substantially central portion in the up and down direction, 62A is contacted simultaneously or substantially simultaneously.

  Here, the drop distance is determined in consideration of the point that it becomes difficult to press-mold due to the increase in viscosity of the molten glass lump 24 during dropping, or the drop speed becomes too high to cause fluctuations in the press position. Preferably, it is selected within the range of 1000 mm or less, more preferably selected within the range of 500 mm or less, further preferably selected within the range of 300 mm or less, and most preferably selected within the range of 200 mm or less. preferable. The lower limit of the drop distance is not particularly limited, but is preferably 100 mm or more for practical use. The “fall distance” is the moment when the tip 22 is separated as the molten glass lump 24 as illustrated in FIG. 2, that is, from the position where the lower blade 30 and the upper blade 40 overlap in the vertical direction. As shown in FIG. 5, the position of the press molding start time (the moment of start of press molding), that is, the distance to the vicinity of the substantially central portion in the diametrical direction of the press molding surfaces 52A and 62A parallel to the drop direction Y1. means.

  Thereafter, as shown in FIG. 6, when the molten glass lump 24 is continuously pressed from both sides by the first press mold 50 and the second press mold 60, the molten glass lump 24 becomes the molten glass lump 24 and The press molding surfaces 52A and 62A are spread out with a uniform thickness around the position where they first contact. Then, as shown in FIG. 7, the press molding surfaces 52A and 62A are kept pressed by the first press molding die 50 and the second press molding die 60 until the guide surface 54A comes into contact with the guide surface 64A. In between, it is formed into a disk-shaped or substantially disk-shaped plate glass 26.

  Here, the plate-like glass 26 shown in FIG. 7 has substantially the same shape and thickness as the finally obtained glass blank. And the size and shape of both surfaces of the sheet glass 26 correspond with the size and shape of molten glass extending | stretching area | region S1, S2 (in FIG. 7, not shown). In addition, the time required for the guide surface 54A and the guide surface 64A shown in FIG. 7 to come into contact with each other from the state at the start of press molding shown in FIG. 5 (hereinafter, referred to as “press molding time” in some cases). .) Is preferably within 0.1 seconds from the viewpoint of thinning the molten glass lump 24. Further, when the press molding is performed, the guide surface 54A and the guide surface 64A are in contact with each other, so that it is easy to maintain the parallel state between the press molding surface 52A and the press molding surface 62A. In addition, although the minimum of press molding time is not specifically limited, It is preferable that it is 0.05 second or more practically.

  The press mold 50 shown in FIGS. 4 to 7 has a press mold body 52 and a guide member 54, and the press mold 60 has the same structure. However, the pair of press molds used in the glass blank manufacturing method of the present embodiment is limited to the type shown in FIGS. 4 to 7 as long as the molten glass lump 24 can be press molded into a plate shape. Not. For example, as a pair of press molds, a type (guide member-less type) constituted by press mold main bodies 52 and 62 excluding the guide members 54 and 64 from the press molds 50 and 60 shown in FIGS. It may be used. The press molds 50 and 60 shown in FIGS. 4 to 7 may be an integrated type in which the press mold main bodies 52 and 62 and the guide members 54 and 64 are integrally formed. It may be a separate type configured as a member. When the press molds 50 and 60 are separate mold types, in the first pressing step, the press mold body 52 and the guide member 54 move simultaneously and integrally in the direction of the arrow X1, and the press mold body 62 and the guide member 64 move simultaneously and integrally in the direction of the arrow X2.

  Since the press molds 50 and 60 have guide members 54 and 64, respectively, the press molding surface 52A and the press molding surface 62A are in a state where the guide member 54 and the guide member 64 are in contact with each other as shown in FIG. Are kept parallel. For this reason, as shown in FIGS. 4 to 6, in the process in which the press mold 50 moves in the arrow X1 direction and the press mold 60 moves in the arrow X2 direction, the press mold surface 52A and the press mold surface 62A Even if the parallel state cannot be maintained, it is easy to make the thickness deviation of the obtained glass blank very small. Therefore, in the drive device that drives the press molds 50 and 60, the press molding surface 52A and the press molding surface 62A always maintain an accurate parallel state in the series of processes shown in FIGS. Control ability to control is not required.

-Second press process-
In the second pressing step, the sheet glass 26 formed between the first press mold 50 and the second press mold 60 is used as the first press mold 50 and the second press mold 60. Continue to press. That is, the glass sheet 26 is continuously pressed by the first press mold 50 and the second press mold 60 while maintaining the state immediately after the first press step shown in FIG. 7 is completed. At this time, the duration of the second pressing step is controlled so that the flatness of the glass blank is 10 μm or less.

  It should be noted that the press molding surface 52A and the press molding surface immediately after the start of the first pressing step where the press molding surfaces 52A and 62A are in contact with the molten glass lump 24 until the second pressing step is completed. The temperature of the glass (molten glass lump 24 and plate glass 26) positioned between 62A and 62A is generally about 1200 ± 50 ° C. to 480 ° C. ± 20 ° C., although it depends on the glass material used for press molding. To a large extent. In addition to this, in the second pressing step, the pressing of the sheet glass 26 is continued, so that the fluidity of the sheet glass 26 also decreases with the passage of time. In particular, when the pressing of the glass sheet 26 is continued until the temperature becomes equal to or lower than the temperature obtained by adding 10 ° C. to the strain point of the glass material constituting the glass sheet 26, the fluidity of the glass sheet 26 is almost completely lost. . Therefore, in the second pressing step, thermal contraction in the radial direction of the sheet glass 26 proceeds with such a significant decrease in temperature. On the other hand, in the second pressing step, the press-molded surfaces 52A and 62A that are in contact with both surfaces of the plate-like glass 26 continue to absorb the heat of the plate-like glass 26 and thermally expand in the plane direction. It is considered that when sufficient heat is absorbed from the glass 26, the thermal expansion in the planar direction is stopped, or the heat contracts gradually.

  That is, in the second pressing step, there is a difference in the degree of thermal expansion / contraction between both members between the both surfaces of the sheet glass 26 and the press molding surfaces 52A, 62A. For this reason, in the second pressing step, the force to extend the radial direction of the sheet glass 26 by the press molding surfaces 52A, 62A on both surfaces of the sheet glass 26 which is being thermally contracted, that is, A force in the opposite direction to the heat shrinkage acts. However, in the second pressing step, the fluidity of the sheet glass 26 is greatly reduced as the second pressing process proceeds. Therefore, if excessive stress acts on the sheet glass 26, the plate glass 26 is brittlely fractured. Is likely to occur. For this reason, if a force in the direction opposite to the thermal shrinkage always acts on both surfaces of the plate glass 26, excessive stress acts in the plane direction of the plate glass 26 and the plate glass 26 is broken. Become.

  In order to prevent such cracking of the glass sheet 26, (1) As a material constituting the press molds 50 and 60, a material having a thermal expansion coefficient close to that of the glass material constituting the glass sheet 26 is used. (2) In the second pressing step, it is conceivable to cool the temperature of the sheet glass 26 and the temperatures of the press molding surfaces 52A and 62A in synchronization. However, since the second pressing step involves a significant temperature change, it is necessary to make the cooling rate very small when performing the cooling as described above. However, in this case, the time required for carrying out the second pressing step is greatly increased, so that the mass productivity is greatly reduced and there is a possibility that the practicality is lacking.

  Considering the points described above, in order to more reliably prevent cracking of the sheet glass 26 in the second pressing step, it is preferable to decrease the pressing pressure with time in the second pressing step. . In this case, the friction coefficient between the both surfaces of the sheet glass 26 and the press-molded surfaces 52A and 62A decreases due to the decrease in the press pressure. As a result, slip occurs between the both surfaces of the sheet glass 26 and the press molding surfaces 52A and 62A, and a force in the opposite direction to the heat shrinkage that causes cracking acts on both surfaces of the sheet glass 26. It becomes easy to block. Here, “the press pressure decreases with time” means not only when the press pressure decreases with the lapse of time in the second pressing process, but also with the press pressure temporarily with the lapse of time. Even when increasing or maintaining a constant value, when the change in the pressing pressure with respect to time is approximated by a linear equation, the case where the slope becomes negative is also included. Further, the press pressure may be decreased stepwise with the passage of time, or may be continuously decreased with the passage of time.

  When the press pressure is decreased step by step with time, the temperature of the sheet glass 26 sandwiched between the first press mold 50 and the second press mold 60 is reduced. It is preferable that the glass material constituting the plate-like glass 26 is reduced when it falls within the range of the yield point ± 30 ° C. Thereby, the crack of the sheet glass 26 can be more effectively suppressed by a relatively simple operation of the pressing pressure. In this case, from the viewpoint of achieving both balanced suppression of cracking of the glass sheet 26 and suppression of deterioration of flatness in a well-balanced manner, the pressing pressure is 1% to 10% after the reduction, assuming that the pressure before the reduction is 100%. It is preferable to be in the range of about%.

  Further, in the second pressing step, instead of decreasing the pressing pressure with time, the pressing pressure may be changed into a wave shape with time. In this case, for example, the press pressure can be periodically changed over time, such as a rectangular wave shape or a sine wave shape. In this case, the coefficient of friction between the both surfaces of the sheet glass 26 and the press-molded surfaces 52A and 62A decreases when the press pressure is near the minimum value over time. As a result, slip occurs between the both surfaces of the sheet glass 26 and the press molding surfaces 52A and 62A, and a force in the opposite direction to the heat shrinkage that causes cracking acts on both surfaces of the sheet glass 26. It becomes easy to block.

  In the second pressing step, the plate-like glass 26 undergoes heat shrinkage not only in the diameter direction but also in the thickness direction. For this reason, a slight gap may be generated between the press-molding surface 52A, the press-molding surface 62A, and the sheet glass 26 during the second pressing step. In this case, compared with the case where the press molding surface 52A and the press molding surface 62A are in close contact with the plate-like glass 26, when the gap is generated, the heat conduction efficiency between the two members is lowered. As a result, a temperature distribution is likely to occur on both sides or in the plane of the sheet glass 26. Such a temperature distribution causes a viscosity distribution (fluidity unevenness) in the plate-like glass 26, so that the plate-like glass 26 is likely to be warped and deteriorates the flatness of the obtained glass blank. It becomes easy.

  Considering the points described above, during the second pressing step, the one surface of the sheet glass 26 and the press molding surface 52A of the first press mold 50 are always closely adhered without any gaps. It is preferable that the other surface of the plate glass 26 and the press molding surface 62A of the second press mold 60 are always closely adhered without any gap. In this case, as the pair of press molds, press molds excellent in followability of the press molding surface against thermal shrinkage in the thickness direction of the sheet glass 26 can be used. As such a press mold, specifically, a guide member-less press mold composed of press mold bodies 52, 62 obtained by removing the guide members 54, 64 from the press molds 50, 60, Separate type press molding dies 50 and 60 in which the press mold main bodies 52 and 62 and the guide members 54 and 64 are configured as separate members can be used. In the case of using the separate-type press molds 50 and 60, in the second pressing step, only the press mold body 52 is pressed in the arrow X1 direction, and only the press mold body 62 is pressed in the arrow X2 direction. Thus, a pressing pressure is applied to the sheet glass 26.

-Extraction process-
After the second press step, the first press mold 50 and the second press mold 60 are separated from each other and between the first press mold 50 and the second press mold 60. An extraction step of taking out the sandwiched sheet glass 26 is performed. This extraction step can be performed, for example, as described below. First, as shown in FIG. 8, the first press mold 50 is moved in the arrow X2 direction so as to separate the first press mold 50 and the second press mold 60 from each other. The press mold 60 is moved in the arrow X1 direction. Thereby, the press-molding surface 62A and the sheet glass 26 are released. Next, as shown in FIG. 9, the press molding surface 52 </ b> A and the plate glass 26 are released from the mold, and the plate glass 26 is dropped to the lower side Y <b> 1 in the vertical direction and taken out. In addition, when releasing the press molding surface 52A and the plate-like glass 26, it is possible to release the plate-like glass 26 by applying a force from the outer peripheral direction of the plate-like glass 26. In this case, the sheet glass 26 can be taken out without applying a large force. At the time of taking out, the press molding surface 52A and the plate glass 26 may be released, and then the press molding surface 62A and the plate glass 26 may be released. Finally, the extracted plate-like glass 26 is annealed as necessary to reduce and remove the distortion, thereby obtaining a base material for processing the magnetic recording medium glass substrate, that is, a glass blank.

-Glass blank-
The flatness of the glass blank obtained by the glass blank manufacturing method of the present embodiment described above can be made 10 μm or less, and it is extremely easy to make it 4 μm or less. The flatness is preferably 4 μm or less from the viewpoint of omitting or shortening post-processes performed mainly for improving flatness such as a lapping process.

-Press mold-
The material constituting the press molds 50 and 60 is preferably a metal or an alloy in consideration of heat resistance, workability, and durability. In this case, considering the temperature of the molten glass, the heat resistance temperature of the metal or alloy constituting the press molds 50 and 60 is preferably 1000 ° C. or higher, more preferably 1100 ° C. or higher. Specifically, the material constituting the press molds 50 and 60 is preferably spheroidal graphite cast iron (FCD), alloy tool steel (such as SKD61), high speed steel (SKH), cemented carbide, colmonoy, stellite, and the like. In press molding, the press molds 50 and 60 may be cooled using a cooling medium such as water or air to suppress an increase in the temperature of the press molds 50 and 60. Further, in order to make the temperature distribution in the press molding surfaces 52A, 62A uniform, the vicinity of the center of the press molding surfaces 52A, 62A is cooled using a cooling medium, and / or the press mold 50 is used. Further, a heating member such as a heater may be disposed on the outer peripheral side of 60 to heat the outer edge side of the press molding surfaces 52A and 62A.

  Moreover, the area | region (molten glass extending | stretching area | region S1, S2) which contacts at least the sheet glass 26 of the press molding surfaces 52A and 62A of the 1st press mold 50 and the 2nd press mold 60 is a glass blank, for example. The surface may have a surface on which a large uneven portion such as a convex portion for forming a V-shaped groove having a depth of about 1/3 to 1/4 of the plate thickness may be formed. A surface is preferred. Note that the entire pressing surfaces 52A and 62A may be substantially flat surfaces. This is because when a large V-shaped groove is formed in the glass blank, crack defects presumed to be caused by stress concentration in the V-shaped groove portion are likely to occur. In addition to this, when large irregularities are formed in the molten glass stretching regions S1 and S2, thermal contraction in the radial direction of the sheet glass 26 in the second pressing step is hindered. For this reason, excessive stress is generated in the planar direction of the sheet glass 26, and the sheet glass 26 is easily broken.

  Here, the “substantially flat surface” means a surface having a very small curvature such as a slight convex surface or a concave surface in addition to a normal flat surface having substantially zero curvature. In addition, it is naturally allowed that the “substantially flat surface” has minute irregularities formed by performing a normal flattening process or a mirror polishing process when manufacturing a press mold. However, larger protrusions and / or recesses may be provided as necessary as compared with the minute unevenness.

  Here, the convex portion larger than the minute irregularities is substantially point-like having a height of 20 μm or less with a small possibility of causing deterioration of flow resistance or promoting partial cooling of the molten glass lump. And / or a substantially linear protrusion is acceptable. The height is preferably 10 μm or less, and more preferably 5 μm or less. Further, the convex portion larger than the minute unevenness is not substantially punctiform and substantially linear, and the convex shape is a trapezoidal shape with a minimum width of the top surface of several millimeters or more, or In the case of a dome-shaped convex part having the same height and size as this trapezoidal convex part, the flow resistance is deteriorated as described above, or partial cooling of the molten glass lump is promoted. Therefore, the height is allowed to be 50 μm or less. The height is preferably 30 μm or less, and more preferably 10 μm or less. Further, from the viewpoint of suppressing the occurrence of cracks due to stress concentration at the intersection of the bottom surface and side surface of the trapezoidal convex portion, the side surface of the trapezoidal convex portion has an inclination angle of 0.5 with respect to the top surface. It is preferable to form a plane that forms an angle of less than or equal to a degree, or a curved surface with this plane as a concave surface. The angle is more preferably 0.1 degrees or less.

  Further, the larger concave portion compared with the minute concave and convex portions has a substantially point-like shape having a depth of 20 μm or less so as not to cause deterioration of the fluidity of the molten glass flowing into the concave portion during press molding. Or if it is a substantially linear recessed part, it will be accept | permitted. The depth is preferably 10 μm or less, and more preferably 5 μm or less. Further, the concave portion larger than the minute unevenness is not substantially punctiform or substantially linear, and the concave portion having an inverted trapezoidal shape with a minimum width of the top surface of several millimeters or more, or In the case of an inverted dome-shaped recess having the same height and size as the inverted trapezoidal recess, the possibility of causing the above-described deterioration in fluidity is reduced, so the depth is 50 μm or less. If that is acceptable. The depth is preferably 30 μm or less, and more preferably 10 μm or less. Further, from the viewpoint of suppressing the occurrence of cracks due to stress concentration at the intersection between the bottom surface and the side surface of the trapezoidal convex portion, the inclination angle of the side surface of the trapezoidal convex portion is 0.5 degrees with respect to the bottom surface. It is preferable to form a plane having the following angle, or a curved surface with this plane as a concave surface. The angle is more preferably 0.1 degrees or less.

  In the glass blank manufacturing method of the present embodiment, as described above, as a press mold, (1) a guide member-less press mold, (2) press mold main bodies 52 and 62 and guide members 54 and 64 are used. Are integrally formed press forming dies 50, 60, and (3) a separate type press forming die in which press forming die main bodies 52, 62 and guide members 54, 64 are formed as separate members. 50, 60, etc. can be used. Among these three types of press molds, it is most preferable to use the separate type press molds 50 and 60 from the viewpoint of achieving the highest balance between higher flatness and smaller thickness deviation. .

  Here, it is preferable that the separation-type press molds 50 and 60 have a structure shown below. That is, the separation-type press mold 50 (or press mold 60) is disposed so as to be opposed to the press mold surface 52A and the press mold body 52 having a press mold surface 52A substantially orthogonal to the horizontal direction. When pressed to the other press mold 60, the distance between the press mold surfaces 52 </ b> A and 62 </ b> A of the pair of press molds 50 and 60 is reduced by contacting a part of the other press mold 60. The guide member 54 having at least a function of keeping constant, the press mold main body 52 and the guide member 54 are simultaneously extruded in the direction substantially orthogonal to the press molding surface 52A and toward the other press mold 60 side. After the guide member 54 and a part of the other press mold 60 are brought into contact with each other by the first extruding member and the first extruding member, the press mold main body 52 is A direction scan molding surface 52A substantially perpendicular, and preferably comprises a second pushing member for pushing the other of the pressing mold 60 side, at least.

  FIG. 10 is a schematic cross-sectional view showing an example of a press mold used in the method for manufacturing a glass blank for a magnetic recording medium glass substrate of the present embodiment. Specifically, the separation type press molds 50 and 60 are shown in FIG. It is a figure which shows an example. In FIG. 10, the same components as those shown in FIGS. 4 to 9 are denoted by the same reference numerals. 10 is a view corresponding to the press mold 50, but the press mold 60 can employ the same structure. Here, the main part of the press mold 50 </ b> S includes a press mold main body 52, a guide member 54, a first push member 56, and a second push member 58. The central axes of the respective members (in the drawing, the alternate long and short dash line X) coincide with each other, and the central axes substantially coincide with the horizontal direction.

  Here, the press-molding die main body 52 is composed of a cylindrical body having one end surface forming a circular press-molding surface 52A. In addition, although the shape of the press-molding die main body 52 is a columnar shape in the example illustrated in FIG. 10, the shape is not particularly limited as long as it is a substantially columnar shape. In the example shown in FIG. 10, the press-molding surface 52A is a substantially flat surface.

  The guide member 54 has a length in the axial direction X that is longer than the length in the axial direction X of the press-molding die main body 52 made of a cylindrical body, and accommodates the press-molding die main body 52 on the inner peripheral side. When extruded by 56, one end surface (guide surface 54A) is composed of a cylindrical body that comes into contact with a guide member (not shown in the drawing) constituting the other press mold. Here, the difference between the length of the guide member 54 and the length of the press mold body 52 in the axial direction X, in other words, the height difference H between the guide surface 54A and the press molding surface 52A in the axial direction X is the glass to be produced. This corresponds to approximately half the blank thickness. The shape of the guide member 54 is cylindrical, but the shape is not particularly limited as long as it is cylindrical.

  The 1st extrusion member 56 is comprised from the disk shaped member. Here, one surface (extruded surface 56A) of the disc-shaped first extruding member 56 is the other end surface (extruded surface 52B) of the press mold main body 52 and the other end surface (extruded surface) of the guide member 54. It consists of a flat surface in contact with the surface 54B). In addition, a through hole 56 </ b> H that penetrates in the thickness direction of the first extrusion member 56 is provided in a part of a region facing the extruded surface 52 </ b> B of the press mold main body 52. The surface 56B opposite to the extrusion surface 56A is connected to a first drive device (not shown). For this reason, during press molding, the first driving device simultaneously pushes the press mold body 52 and the guide member 54 through the first pusher member 56 in the axial direction X in the drawing. It can be extruded from the side where the member 56 is disposed to the side where the press mold main body 52 and the guide member 54 are disposed.

  In the example shown in FIG. 10, the shape of the first pushing member 56 is a disc shape, but the shape is not particularly limited as long as it is substantially plate-shaped. The through hole 56H is provided as a hole having a circular opening along the center axis X of the press mold main body 52 and the first extrusion member 56. However, the extruded surface 52B of the press mold main body 52 is provided. If it is a part of the area | region which opposes, the arbitrary number of through-holes 56H can be provided in the arbitrary positions of the 1st extrusion member 56. FIG. Moreover, the opening shape of the through-hole 56H can also be selected suitably. However, it is particularly preferable that the through hole 56H is provided point-symmetrically with respect to the central axis X of the press mold main body 52.

  The second pushing member 58 is disposed in the through hole 56 </ b> H, and is composed of a rod-like member connected to the pushed surface 52 </ b> B side of the press mold main body 52. In the example shown in FIG. 10, the second pushing member 58 has a cylindrical bar shape, but the shape is not particularly limited as long as the press mold main body 52 can be moved in the X-axis direction. Note that the end opposite to the one end connected to the extruded surface 52B side of the second pushing member 58 is connected to a second drive device (not shown). For this reason, during press molding, only the press mold main body 52 is pressed from the side where the second extruding member 58 is disposed by the second driving device via the second extruding member 58. It can be extruded along the axial direction X to the side where 52 is arranged.

-Glass material-
The glass material used in the method for producing a glass blank of the present embodiment has physical properties suitable as a magnetic recording medium glass substrate, in particular, a high thermal expansion coefficient, high rigidity, heat resistance, etc., and a horizontal direct press. If it is easy to press-form into a plate shape, there is no particular limitation. The thermal expansion coefficient is desirably close to the thermal expansion coefficient of the holder that holds the magnetic recording medium. Specifically, the average linear expansion coefficient at 100 to 300 ° C. is preferably 70 × 10 ⁻⁷ / ° C. or more, more preferably 75 × 10 ⁻⁷ / ° C. or more, and 80 × 10 ⁻⁷ / ° C. It is more preferable that the temperature is not lower than ° C., and it is even more preferable that the temperature is 85 × 10 ⁻⁷ / ° C. or higher. The upper limit of the average linear expansion coefficient is not particularly limited, but is practically preferably 120 × 10 ⁻⁷ / ° C. or less. A glass material having high rigidity is desired from the viewpoint of reducing the deflection generated during high-speed rotation of the magnetic recording medium. Specifically, the Young's modulus is preferably 70 GPa or more, more preferably 75 GPa or more, and 80 GPa. More preferably, it is more preferably 85 GPa or more. The upper limit of the Young's modulus is not particularly limited, but is practically preferably 120 GPa or less. Furthermore, since a substrate can be processed at a high temperature during the production process of a magnetic recording medium by using a glass material having excellent heat resistance, the glass transition temperature of the glass material is preferably 600 ° C. or higher, and 610 ° C. The above is more preferable, 620 ° C. or higher is further preferable, and 630 ° C. or higher is more preferable. The upper limit of the glass transition temperature is not particularly limited, but is preferably 780 ° C. or lower from a practical viewpoint such as suppressing the temperature during press molding from becoming high. Use of a glass material having a high thermal expansion coefficient, high rigidity, and heat resistance is effective in obtaining a glass substrate suitable for a magnetic recording medium having a high recording density.

As the composition of the glass material, a composition that can easily realize physical properties suitable as a magnetic recording medium glass substrate can be appropriately selected. For example, the glass composition of a conventional glass material for vertical direct press can be appropriately selected, but an aluminosilicate glass Is preferably selected. In addition, as an aluminosilicate glass, since it is easy to make heat resistance, high rigidity, and a high thermal expansion coefficient compatible with balance, especially the composition shown below is especially preferable. That is, the glass composition of this glass (hereinafter referred to as “glass composition 1”) is:
In mol% display,
The SiO ₂ 50~75%,
Al ₂ O ₃ 0-5%
Li ₂ O 0-3%,
ZnO 0-5%,
A total of 3 to 15% of at least one component selected from Na ₂ O and K ₂ O,
A total of 14 to 35% of at least one component selected from MgO, CaO, SrO and BaO, and
₂ to 9% in total of at least one component selected from ZrO ₂ , TiO ₂ , La ₂ O ₃ , Y ₂ O ₃ , Yb ₂ O ₃ , Ta ₂ O ₅ , Nb ₂ O ₅ and HfO ₂ ;
Including
The molar ratio {(MgO + CaO) / (MgO + CaO + SrO + BaO)} is in the range of 0.8 to 1, and the molar ratio {Al ₂ O ₃ / (MgO + CaO)} is in the range of 0 to 0.30.

The preferable range of the average linear expansion coefficient of the glass composition 1 at 100 to 300 ° C. is 70 × 10 ⁻⁷ / ° C. or more, the preferable range of the glass transition temperature is 630 ° C. or more, and the preferable range of the Young's modulus is 80 GPa or more. Glass composition 1 is suitable as a material for an energy-assisted magnetic recording medium glass substrate using a high Ku magnetic material.

As a glass material having a high thermal expansion coefficient, excellent acid resistance and alkali resistance, little alkali elution from the substrate surface, and suitable for chemical strengthening, it has the following glass composition (hereinafter referred to as “glass composition 2”). Things can be shown. That is, the glass composition 2 is
In mol% display,
SiO ₂ and Al ₂ O ₃ in total 70 to 85%, provided that the content of SiO ₂ is 50% or more, the content of Al ₂ O ₃ is 3% or more,
Li ₂ O, Na ₂ O and K ₂ O in total 10% or more,
1 to 6% in total of MgO and CaO, provided that the content of CaO is greater than the content of MgO.
ZrO ₂ , TiO ₂ , La ₂ O ₃ , Y ₂ O ₃ , Yb ₂ O ₃ , Ta ₂ O ₅ , Nb ₂ O ₅ and HfO ₂ in total exceeding 0% and 4% or less,
It is a composition containing.

(Method for manufacturing magnetic recording medium glass substrate)
The manufacturing method of the magnetic recording medium glass substrate of this embodiment manufactures a magnetic recording medium glass substrate at least through a polishing step of polishing the main surface of the glass blank produced by the glass blank manufacturing method of this embodiment. It is characterized by. Specific examples of the respective steps when processing a glass blank to form a magnetic recording medium glass substrate will be described in more detail below.

  First, scribing is performed on a glass blank obtained by press molding. Scribe is a glass blank that is cut into two concentric circles (inner concentric circle and outer concentric circle) with a scriber made of super steel alloy or diamond particles on the surface of the glass blank in order to make the molded glass blank into a ring shape of a predetermined size. This refers to providing a line (linear scratch). The glass blank scribed in two concentric shapes is partially heated, and the difference in thermal expansion of the glass removes the outer portion of the outer concentric circle and the inner portion of the inner concentric circle. As a result, a perfect circular disk-shaped glass is obtained. In the case of a glass blank, when the outer diameter is substantially the same as the outer diameter of the final magnetic recording medium glass substrate (magnetic disk glass substrate) (when the size can be corrected only by end face polishing described later). The coring may be performed on the central portion that becomes a circular hole instead of the scribing process.

  When scribing, if the roughness of the main surface of the glass blank is 1 μm or less, a cutting line can be suitably provided using a scriber. In addition, when the roughness of the main surface of a glass blank exceeds 1 micrometer, a scriber may not follow surface unevenness | corrugation and it may become difficult to provide a cutting line uniformly. In this case, scribing is performed after the main surface of the glass blank is smoothed.

  Next, shape processing of the scribed glass is performed. Shape processing includes chamfering (chamfering of the outer peripheral end and the inner peripheral end). In chamfering, chamfering is performed on the outer peripheral end and inner peripheral end of the ring-shaped glass with a diamond grindstone.

  Next, the end surface of the disk-shaped glass is polished. In the end surface polishing, the inner peripheral side end surface and the outer peripheral side end surface of the glass are mirror-finished by brush polishing. At this time, a slurry containing fine particles such as cerium oxide as free abrasive grains is used. Preventing the occurrence of ion precipitation that causes corrosion such as sodium and potassium by removing contamination such as dirt, damage or scratches attached to the end surface of the glass by end face polishing Can do.

  Next, 1st grinding | polishing is given to the main surface of disk-shaped glass. The first polishing is intended to remove scratches and distortions remaining on the main surface. The machining allowance by the first polishing is, for example, about several μm to 10 μm. Since it is not necessary to perform a grinding process with a large machining allowance, the glass is not scratched or distorted due to the grinding process. Therefore, the machining allowance in the first polishing process is small.

  In the first polishing step and the second polishing step described later, a double-side polishing apparatus is used. The double-side polishing apparatus is an apparatus that performs polishing by using a polishing pad and relatively moving a disk-shaped glass and a polishing pad. The double-side polishing apparatus includes a polishing carrier mounting portion having an internal gear and a sun gear that are driven to rotate at a predetermined rotation ratio, and an upper surface plate and a lower surface plate that are driven to rotate reversely with respect to the polishing carrier mounting portion. Have A polishing pad, which will be described later, is attached to the surfaces of the upper and lower surface plates facing the disk-shaped glass. The polishing carrier mounted so as to mesh with the internal gear and the sun gear revolves around the sun gear while rotating around the sun gear.

  Each of the polishing carriers holds a plurality of disc-shaped glasses. The upper surface plate is movable in the vertical direction, and presses the polishing pad against the main surfaces of the front and back surfaces of the disk-shaped glass. Then, while supplying a slurry (polishing liquid) containing abrasive grains (polishing material), the planetary gear motion of the polishing carrier and the upper surface plate and the lower surface plate rotate reversely to each other, so that the disk-shaped glass and the polishing pad The main surfaces of the front and back surfaces of the disk-shaped glass are polished. In the first polishing step, for example, a hard resin polisher is used as the polishing pad, and for example, cerium oxide abrasive grains are used as the abrasive.

  Next, the disk-shaped glass after the first polishing is chemically strengthened. For example, a molten salt of potassium nitrate can be used as the chemical strengthening solution. In chemical strengthening, the chemical strengthening solution is heated to, for example, 300 ° C. to 400 ° C., and the cleaned glass is preheated to, for example, 200 ° C. to 300 ° C., and then the glass is placed in the chemical strengthening solution, for example, 3 hours to 4 hours. Soaked. The immersion is preferably performed in a state of being housed in a holder so that a plurality of glasses are held at the end faces so that both main surfaces of the glass are chemically strengthened.

  In this way, by immersing the glass in the chemical strengthening solution, sodium ions on the surface layer of the glass are respectively replaced with potassium ions having a relatively large ionic radius in the chemical strengthening solution, and the thickness of about 50 to 200 μm. A compressive stress layer is formed. As a result, the glass is strengthened and has good impact resistance. Note that the chemically strengthened glass is washed. For example, after washing with sulfuric acid, it is washed with pure water, IPA (isopropyl alcohol) or the like.

  Next, second polishing is performed on the chemically strengthened and sufficiently cleaned glass. The machining allowance by the second polishing is, for example, about 1 μm.

  The second polishing is intended to finish the main surface into a mirror surface. In the second polishing step, as with the first polishing step, the disc-shaped glass is polished using a double-side polishing apparatus. The polishing abrasive grains contained in the polishing liquid (slurry) to be used and the composition of the polishing pad Is different. In the second polishing step, the grain size of the abrasive grains to be used is made smaller than in the first polishing step, and the hardness of the polishing pad is made softer. For example, in the second polishing step, for example, a soft foamed resin polisher is used as the polishing pad, and as the abrasive, for example, cerium oxide abrasive grains or colloidal silica that are finer than the cerium oxide abrasive grains used in the first polishing step are used.

  The disk-shaped glass polished in the second polishing process is washed again. In cleaning, a neutral detergent, pure water, and IPA are used. By the second polishing, for example, a glass substrate for a magnetic disk having a main surface flatness of 4 μm or less and a main surface roughness (Ra) of 0.2 nm or less is obtained. Thereafter, each layer such as a magnetic layer is formed on the glass substrate for magnetic disk to produce a magnetic disk.

  In addition, although a chemical strengthening process is performed between a 1st grinding | polishing process and a 2nd grinding | polishing process, it is not limited to this order. As long as a 2nd grinding | polishing process is performed after a 1st grinding | polishing process, a chemical strengthening process can be arrange | positioned suitably. For example, the order of the first polishing process, the second polishing process, and the chemical strengthening process (hereinafter, process order 1) may be used. However, in the process order 1, since the surface unevenness | corrugation which may arise by a chemical strengthening process is not removed, the process order of a 1st grinding | polishing process, a chemical strengthening process, and a 2nd grinding | polishing process is more preferable.

  When manufacturing the magnetic recording medium glass substrate, the flatness of the glass blank used for processing and the flatness of the produced magnetic recording medium glass substrate can be made substantially the same. As flatness required for a magnetic recording medium glass substrate, for example, a glass substrate of 2.5 inches has recently been required to have a flatness of 10 μm or less. This is because it can be easily achieved by the glass blank produced by the method. Here, “the flatness of the glass blank used for processing and the flatness of the produced magnetic recording medium glass substrate are substantially the same” means that the required magnetic recording medium glass substrate (glass substrate for magnetic disk) ) Is 100%, it means that the flatness of the glass blank is 105% or less.

  In addition, when the flatness of the glass blank used for processing and the flatness of the produced magnetic recording medium glass substrate are substantially the same, a process carried out mainly for improving flatness such as a lapping process. Can be omitted.

(Method of manufacturing magnetic recording medium)
The magnetic recording medium manufacturing method of the present embodiment has undergone at least a magnetic recording layer forming step of forming a magnetic recording layer on the magnetic recording medium glass substrate produced by the magnetic recording medium glass substrate manufacturing method of the present embodiment, A magnetic recording medium is manufactured.

  Magnetic recording media are called magnetic disks, hard disks, etc., internal storage devices (such as fixed disks) such as desktop PCs, server computers, notebook PCs, and mobile PCs, and portable recording and playback that records and plays back images and / or audio. It is suitable for an internal storage device of a device, an in-vehicle audio recording / reproducing device, and the like.

For example, at least an adhesion layer, an underlayer, a magnetic layer (magnetic recording layer), a protective layer, and a lubricating layer are stacked on the main surface of a magnetic recording medium glass substrate in order from the side closer to the main surface. It can be configured. For example, a magnetic recording medium glass substrate is introduced into a depressurized film forming apparatus, and an adhesion layer to a magnetic layer are sequentially formed on the main surface of the magnetic recording medium glass substrate in an Ar atmosphere by a DC magnetron sputtering method. . For example, CrTi can be used as the adhesion layer, and CrRu can be used as the underlayer. After the above film formation, a magnetic recording medium can be formed by forming a protective layer using C ₂ H ₄ gas, for example, by the CVD method, and performing nitriding treatment in which nitrogen is introduced into the surface in the same chamber. it can. Thereafter, for example, PFPE (polyfluoropolyether) is applied onto the protective layer by a dip coating method, whereby a lubricating layer can be formed.

  The size of the magnetic recording medium is not particularly limited, but since the magnetic recording medium glass substrate is made of a glass material with excellent impact resistance, it is convenient to carry and may be exposed to external impacts. A size of 2.5 inches or less is preferred.

  EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited to the following examples.

<< Production of Glass Blank >>
In each example and comparative example, several hundred or more glass blanks (diameter: about 75 mm, thickness: about 0.9 mm) for producing a 2.5 inch size magnetic recording medium glass substrate were continuously produced.

(Example A1)
The molten glass lump formation process, the 1st press process, the 2nd press process, and the extraction process were implemented by the process shown in FIGS. 1-9, and the glass blank was produced. The viscosity of the molten glass flowing out from the glass outlet 12 is adjusted to 700 dPa · s, and the first press mold 50 and the second press mold 60 are orthogonal to the dropping direction of the molten glass lump 24. The drop distance was set to 150 mm.

Here, the main physical property value and composition of the glass material used for preparation of the glass blank are as follows.
Glass transition temperature: 495 ° C
・ Bend point: 550 ℃
・ Strain point: 490 ℃
Composition: Composition corresponding to glass composition 2

  Moreover, the concrete implementation conditions of a 1st press process and a 2nd press process, and the detail of the press molds 50 and 60 used for press molding are as follows.

-Conditions for the first pressing process-
The temperature of the press molding surface 52A immediately before the first press process is 500 ° C., the temperature of the press molding surface 62A just before the first press process is 500 ° C., and the surface of the press molding surface 52A just before the first press process is performed. The internal temperature difference was set to 50 ° C., and the in-plane temperature difference of the press-molded surface 62A immediately before the first pressing step was set to 50 ° C. The press molds 50 and 60 were driven such that the press molding surface 52A and the press molding surface 62A were in contact with the molten glass lump 24 at the same time. The press molding time was 0.07 seconds. Note that the temperature of the press molding surfaces 52A and 62A was monitored by a thermocouple disposed at a depth of 1 mm from the press molding surfaces 52A and 62A. This thermocouple is one at the center of the press molding surfaces 52A and 62A and one at a position of a radius of 30 mm from the center and at 0 °, 90 °, 180 ° and 270 ° in the circumferential direction. Is arranged.

-Implementation conditions for the second pressing process-
When the duration of the second press step was adjusted and the flatness of the obtained glass blank was measured, when the duration of the second press step was 2 seconds or longer, the flatness of the glass blank was 4 μm. . Therefore, the duration of the second pressing process was set to 2 seconds. The temperature (extraction temperature) of the sheet glass 26 at the end of the second pressing step is 495 ° C. The pressing pressure during the second pressing step was set to always maintain 0.5 MPa. The temperature of the sheet glass 26 is a value obtained on the assumption that the temperature is measured by a thermocouple arranged at the center of the press molding surfaces 52A and 62A. In this way, the duration of the second pressing step was controlled using the flatness of the glass blank as an index to obtain a glass blank with excellent flatness.

-Press mold-
The press mold 50 was made of cast iron and used as an integral type in which a press mold main body 52 and a guide member 54 were integrally configured. Also, the press mold 50 was an integral type similar to the press mold 60. The press molding surfaces 52A and 62A are completely flat surfaces. Further, in the integrated type press molds 50 and 60 used, cooling water is supplied into the press mold main bodies 52 and 62 so that the temperature of the press mold surfaces 52A and 62A and the in-plane temperature distribution can be controlled. A flow passage is provided, and a heater is disposed on the outer peripheral side of the press molds 50 and 60. Here, regarding the flow rate of the cooling water and the heating conditions of the heater, the difference between the temperature of the press molding surface 52A of the press mold 50 and the temperature of the press molding surface 62A of the press mold 60 is always within ± 10 ° C. Control was done to maintain range.

(Example A2)
A glass blank was produced in the same manner as in Example A1, except that the duration of the second pressing step was further increased and the plate glass extraction temperature was set to 490 ° C.

(Example A3)
A glass blank was used in the same manner as in Example A1, except that a separate mold type in which the press mold main bodies 52 and 62 and the guide members 54 and 64 were configured as separate members was used as the press molds 50 and 60. Produced.

(Example A4)
A glass blank was produced in the same manner as in Example A3 except that the pressing pressure during the second pressing step was reduced with time. Note that the press pressure was controlled to be 50% when the temperature of the sheet glass 26 reached the yield point of −25 ° C., with the reference immediately after the start of the second pressing step (100%).

(Example A5)
A glass blank was produced in the same manner as in Example A3 except that the pressing pressure during the second pressing step was reduced with time. Note that the press pressure was controlled to be 50% when the temperature of the sheet glass 26 reached the yield point + 25 ° C., with the reference immediately after the start of the second pressing step (100%).

(Example A6)
A glass blank was produced in the same manner as in Example A3 except that the pressing pressure during the second pressing step was reduced with time. Note that the pressing pressure was controlled to be 50% when the temperature of the sheet glass 26 reached the yield point + 40 ° C., with the reference immediately after the start of the second pressing step (100%).

(Example A7)
A glass blank was produced in the same manner as in Example A3 except that the pressing pressure during the second pressing step was reduced with time. Note that the press pressure was controlled to be 50% when the temperature of the sheet glass 26 reached the yield point of −40 ° C., with the reference immediately after the start of the second pressing step (100%).

(Example A8)
A glass blank was produced in the same manner as in Example A3 except that the pressing pressure during the second pressing step was reduced with time. Note that the press pressure was controlled to be 50% when the temperature of the sheet glass 26 reached the yield point, with the reference immediately after the start of the second pressing step (100%).

(Comparative Example A1)
A glass blank was produced in the same manner as in Example A1 except that the duration of the second pressing step was set to less than 2 seconds and the plate glass extraction temperature was set to 520 ° C.

(Comparative Example A2)
A glass blank was produced in the same manner as in Example A1, except that the second pressing step was omitted.

(Comparative Example A3)
A glass blank was produced by vertical direct pressing using the same glass material as used in Example A1. For the production of the glass blank, twelve lower molds are arranged at equal intervals along the outer peripheral edge, and at the time of pressing, a rotary table that rotates while alternately repeating movement and stop every 30 degrees in one direction is provided. A press device was used. Further, when 12 lower mold stop positions corresponding to 12 lower molds arranged on the outer peripheral edge of the rotary table are numbered P1 to P12 along the rotation direction of the rotary table, The following members are respectively arranged on the lower die press surface or the lower die side at the following lower die stop position.
Lower mold stop position P1: Molten glass supply device Lower mold stop position P2: Upper mold / Lower mold stop position P9: Extraction means (vacuum suction device)

  In this press apparatus, a predetermined amount of molten glass is supplied onto the lower mold at the lower mold stop position P1, and at the lower mold stop position P2, the molten glass is press-molded into a sheet glass by the upper mold and the lower mold. Then, plate glass (glass blank) is taken out at the lower mold stop position P9. Further, when the lower mold moves to the stop positions P2 to P9, a soaking / cooling process is performed, and when moving to the stop positions P9 to P12, the lower mold is preheated using a heater. .

  The materials of the upper mold and the lower mold, and the smoothness and flatness of the press molding surface were the same as those of the press molds 50 and 60 used in Example A1. Note that the viscosity of the molten glass immediately before being supplied onto the lower mold located at the lower mold stop position P1 was adjusted to 500 dPa · s.

-Conditions for pressing process-
The details of the conditions for carrying out the pressing process are as follows. The temperature of the upper die press molding surface immediately before the pressing process is 380 ° C., the temperature of the lower die pressing surface immediately before the pressing step is 480 ° C., and the in-plane temperature difference of the upper die pressing surface just before the pressing step is 30 ° C. The in-plane temperature difference of the lower die press-molding surface immediately before the pressing process was set to 30 ° C. The upper mold was driven downward two seconds after a predetermined amount of molten glass was supplied onto the lower mold. Further, the time (press molding time) from when the upper die contacts the molten glass on the lower die until the upper die and the lower die are separated from each other was set to 0.3 seconds. When the pressing process was carried out under the conditions described above, the temperature (extraction temperature) of the sheet glass at the end of the pressing process was 500 ° C. In addition, the temperature of the press molding surface of the upper mold and the lower mold was monitored by a thermocouple disposed at a position 5 mm deep from the press molding surface. One thermocouple is disposed at the center of the press molding surface and one thermocouple at a radius of 15 mm from the center and at 0 °, 90 °, 180 °, and 270 ° in the circumferential direction. Yes.

(Comparative Example A4)
A glass blank was produced in the same manner as in Comparative Example A3, except that the press molding time was extended so that the extraction temperature was 495 ° C. In addition, since the production speed was very slow and there was no practicality, the press was stopped when several tens of glass blanks were produced.

(Comparative Example A5)
As a pressing apparatus, an apparatus similar to the pressing apparatus used in Comparative Example A3 was used except that an upper mold for cooling was further arranged on the pressing surface at the lower mold stop position P3. The upper mold for cooling has substantially the same structure as the upper mold for press molding disposed on the press surface at the lower mold stop position P2. Here, the pressing step performed at the lower mold stop position P2 was performed under the same conditions as in Comparative Example A3.

  Moreover, about the period when the lower mold | type is stopped in the lower mold | type stop position P3, the distance which is the extent which the upper mold | type for cooling pre-heated to about 480 degreeC is not contacted with the sheet glass arrange | positioned on the lower mold The state where it was made to approach was maintained.

(Evaluation)
About the glass blank produced in each Example and comparative example, flatness, a crack, and productivity were evaluated. The results are shown in Tables 1 and 2. In addition, the temperature between the press-molding surfaces during the execution of the first press step and the second press step in all Examples and Comparative Examples A1 and A2 in which glass blanks were produced by horizontal direct press was 550 ° C. or less at the maximum. Yes, the temperature between the press-molding surfaces during the pressing process in Comparative Examples A3 to A5 in which glass blanks were produced by vertical direct pressing was in the range of 450 ° C to 500 ° C.

  In addition, the evaluation method of flatness shown in Table 1 and Table 2, and the evaluation method and evaluation criteria of crack and productivity are as follows.

-Flatness-
The flatness was measured by using a three-dimensional shape measuring device (manufactured by COMS Corporation, high-precision three-dimensional shape measuring system, MAP-3D), and an average value of the flatness of ten samples was obtained.

-Cracking-
When 1000 glass blanks were produced continuously, the obtained glass blanks were counted, and the occurrence rate of cracks was determined. The evaluation criteria for the evaluation results shown in Table 1 and Table 2 are as follows.
A: The occurrence rate of cracks is 0%
B: Crack generation rate exceeds 0% and 1% or less C: Crack generation rate exceeds 1% and 2% or less D: Crack generation rate is 2% or more

-Productivity-
The number of glass blanks produced per unit time when 1000 glass blanks were produced continuously was determined. The evaluation criteria for the evaluation results shown in Table 1 and Table 2 are as follows.
A: The number of produced sheets per hour is 3420 or more B: The number of produced sheets per hour is 3240 or more and less than 3420 sheets C: The number of produced sheets per hour is 3060 or more and less than 3240 sheets D: The number of produced sheets per hour Less than 3060

<< Preparation of Magnetic Recording Medium Glass Substrate and Magnetic Recording Medium >>
<Example B1>
The glass blank produced in Example A1 was annealed to reduce and remove strain. Next, scribing was performed on the outer peripheral portion and the central hole portion of the magnetic recording medium glass substrate. By such processing, two concentric grooves were formed on the outer side and the outer side. Subsequently, the scribe-processed part was heated partially, the crack was generated along the scribe-processed groove | channel by the difference in thermal expansion of glass, and the outer part and inner part of the outer concentric circle were removed. Thereby, a disc-shaped glass having a perfect circle shape was obtained.

  Next, the shape of the disk-shaped glass was processed by chamfering or the like, and end face polishing was further performed. Next, after subjecting the main surface of the disk-shaped glass to first polishing, the glass was immersed in a chemical strengthening solution and chemically strengthened. After chemical strengthening, the glass that was sufficiently washed was subjected to the second polishing. After the second polishing step, the disk-shaped glass was washed again to produce a magnetic recording medium glass substrate. The obtained magnetic recording medium glass substrate had an outer diameter of 65 mm, a center hole diameter of 20 mm, a thickness of 0.8 mm, and a main surface roughness of 0.2 nm or less.

  Note that in the production of the magnetic recording medium glass substrate, as described above, a process performed mainly for improving flatness such as a lapping process was omitted. However, the flatness of the glass blank used for processing was 4 μm, the flatness of the produced magnetic recording medium glass substrate was 4 μm, and there was almost no difference between the flatness of the two. The flatness of the magnetic recording medium glass substrate was measured in the same manner as the flatness of the glass blank.

  Next, using the produced magnetic recording medium glass substrate, an adhesion layer, an underlayer, a magnetic layer, a protective layer, and a lubricating layer are formed in this order on the main surface of the magnetic recording medium glass substrate. Obtained. First, an adhesion layer, a base layer, and a magnetic layer were sequentially formed in an Ar atmosphere by a DC magnetron sputtering method using a vacuum-deposited film forming apparatus. At this time, the adhesion layer was formed using a CrTi target so as to be an amorphous CrTi layer having a thickness of 20 nm. Subsequently, a 10 nm thick layer made of amorphous CrRu was formed as a base layer by a DC magnetron sputtering method in an Ar atmosphere using a single wafer / stationary facing film forming apparatus. The magnetic layer was formed at a film forming temperature of 400 ° C. using an FePt or CoPt target so as to be an amorphous FePt or CoPt layer having a thickness of 200 nm. The magnetic recording medium after film formation up to the magnetic layer was transferred from the film forming apparatus to a heating furnace and annealed at a temperature of 650 to 700 ° C.

  Subsequently, a protective layer made of hydrogenated carbon was formed by a CVD method using ethylene as a material gas. Thereafter, a lubricating layer using PFPE (perfluoropolyether) was formed by a dip coating method. The thickness of the lubricating layer was 1 nm. A magnetic recording medium was obtained by the above manufacturing process.

  The flatness of the obtained magnetic recording medium was 4 μm, which was almost the same as the flatness of the magnetic recording medium glass substrate used for the production of the magnetic recording medium. The flatness of the magnetic recording medium was measured in the same manner as the flatness of the glass blank.

<Comparative Example B1>
A magnetic recording medium glass substrate was produced using the glass blank produced in Comparative Example A1. In the production of the magnetic recording medium glass substrate, magnetic recording was performed in the same manner as in Example B1, except that the lapping step was further performed by setting the grinding allowance to 50 μm after the end face polishing and before the first polishing. A medium glass substrate was produced. The obtained magnetic recording medium glass substrate had an outer diameter of 65 mm, a center hole diameter of 20 mm, a thickness of 0.8 mm, and a main surface roughness of 0.2 nm or less. The flatness of the glass blank used for processing was 15 μm, the flatness of the produced magnetic recording medium glass substrate was 4 μm, and it was confirmed that the flatness was greatly improved.

  Next, a magnetic recording medium glass substrate was produced in the same manner as in Example B1 using the obtained magnetic recording medium glass substrate. The flatness of the obtained magnetic recording medium was 4 μm, which was almost the same as the flatness of the magnetic recording medium glass substrate used for the production of the magnetic recording medium.

<Comparative Example B2>
A magnetic recording medium glass substrate and a magnetic recording medium were produced in the same manner as in Comparative Example B1 except that the lapping step was omitted. The flatness of the obtained magnetic recording medium glass substrate and magnetic recording medium was substantially the same as the flatness of the glass blank used for processing.

<Comparative Example B3>
A magnetic recording medium glass substrate and a magnetic recording medium were produced in the same manner as in Comparative Example B1, except that the glass blank produced in Comparative Example A5 was used. The obtained magnetic recording medium glass substrate had an outer diameter of 65 mm, a center hole diameter of 20 mm, a thickness of 0.8 mm, and a main surface roughness of 0.2 nm or less. The flatness of the glass blank used for processing was 15 μm, the flatness of the produced magnetic recording medium glass substrate was 4 μm, and it was confirmed that the flatness was greatly improved.

  Next, using the obtained magnetic recording medium glass substrate, a magnetic recording medium glass substrate was produced in the same manner as in Comparative Example B1. The flatness of the obtained magnetic recording medium was 4 μm, which was almost the same as the flatness of the magnetic recording medium glass substrate used for the production of the magnetic recording medium.

<Comparative Example B4>
A magnetic recording medium glass substrate and a magnetic recording medium were produced in the same manner as in Comparative Example B3 except that the lapping step was omitted. The flatness of the obtained magnetic recording medium glass substrate and magnetic recording medium was substantially the same as the flatness of the glass blank used for processing.

DESCRIPTION OF SYMBOLS 10 Molten glass outflow pipe 12 Glass outflow port 20 Molten glass flow 22 Tip part 24 Molten glass lump 26 Sheet glass 30 Lower blade (shear blade)
32 Main body portion 34 Blade portion 34U Upper surface 34B (blade portion) Lower surface 40 (blade portion) Lower surface 40 Upper blade (shear blade)
42 Main body portion 44 Blade portion 44U Upper surface 44B (blade portion) lower surface 50 (blade portion) lower surface 50 First press mold 50S Press mold 52 Press mold body 52A Press mold surface 52B Extruded surface 54 Guide member 54A Guide surface 54B Extruded surface 56 First extruded member 56A Extruded surface 56B Surface 56H opposite to the extruded surface 56A Through hole 58 Second extruded member 60 Second press mold 62 Press mold body 62A Press mold surface 64 Guide member 64A guide surface

Claims (18)

A molten glass lump that is falling is pressed by a first press mold and a second press mold that are arranged opposite to each other in a direction intersecting the dropping direction of the molten glass lump, and is molded into a plate shape. Pressing process,
A plate-like glass formed between the first press mold and the second press mold,
A second pressing step in which pressing continues with the first press mold and the second press mold;
After passing through the second press step, the first press mold and the second press mold are separated, and between the first press mold and the second press mold. An extraction step of taking out the sandwiched glass sheet;
Through at least a glass blank for a magnetic recording medium glass substrate,
At least during the implementation period of the first press step and the second press step, the temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold Are substantially the same,
In the first pressing step, after the press molding surface of the first press molding die and the press molding surface of the second press molding die are brought into contact with the molten glass lump substantially simultaneously, the melting is performed. the glass mass is pressed,
Controlling the duration of the second pressing step so that the flatness of the glass blank for the magnetic recording medium glass substrate is 10 μm or less , and
A glass blank for a magnetic recording medium glass substrate , wherein at least a region in contact with the glass sheet of the first press mold and the second press mold has a substantially flat surface. Manufacturing method. In the manufacturing method of the glass blank for magnetic recording medium glass substrates of Claim 1,
A method for producing a glass blank for a magnetic recording medium glass substrate, wherein the pressing pressure in the second pressing step is decreased over time. A molten glass lump that is falling is pressed by a first press mold and a second press mold that are arranged opposite to each other in a direction intersecting the dropping direction of the molten glass lump, and is molded into a plate shape. Pressing process,
A plate-like glass formed between the first press mold and the second press mold,
A second pressing step in which pressing continues with the first press mold and the second press mold;
After passing through the second press step, the first press mold and the second press mold are separated, and between the first press mold and the second press mold. An extraction step of taking out the sandwiched glass sheet;
Through at least a glass blank for a magnetic recording medium glass substrate,
At least during the implementation period of the first press step and the second press step, the temperature of the press molding surface of the first press mold and the temperature of the press molding surface of the second press mold Are substantially the same,
In the first pressing step, after the press molding surface of the first press molding die and the press molding surface of the second press molding die are brought into contact with the molten glass lump substantially simultaneously, the melting is performed. Press the glass lump ,
Controlling the duration of the second pressing step so that the flatness of the glass blank for the magnetic recording medium glass substrate is 10 μm or less , and
A method for producing a glass blank for a magnetic recording medium glass substrate , wherein the pressing pressure in the second pressing step is decreased over time . In the manufacturing method of the glass blank of Claim 3,
A glass blank for a magnetic recording medium glass substrate, wherein at least a region of the press forming surface of the first press mold and the second press mold that contacts the plate glass is a substantially flat surface. Manufacturing method. In the manufacturing method of the glass blank for magnetic recording medium glass substrates as described in any one of Claims 2-4,
The temperature of the plate glass sandwiched between the first press mold and the second press mold is the yield point of the glass material constituting the plate glass ± 30 ° C. A method for producing a glass blank for a glass substrate for a magnetic recording medium, wherein the glass blank is reduced when the temperature falls within the range. In the manufacturing method of the glass blank for magnetic recording medium glass substrates as described in any one of Claims 1-5 ,
The duration of the second pressing step is the temperature at which the temperature of the plate glass at the end of the second pressing step is at least 10 ° C. added to the strain point of the glass material constituting the plate glass. A method for producing a glass blank for a glass substrate for a magnetic recording medium, which is selected so as to satisfy the following conditions. In the manufacturing method of the glass blank for magnetic recording medium glass substrates as described in any one of Claims 1-6 ,
Including a molten glass lump forming step of forming the molten glass lump by suspending the molten glass from the glass outlet and cutting the tip of the molten glass flow continuously flowing out downward in the vertical direction. A method for producing a glass blank for a magnetic recording medium glass substrate. In the manufacturing method of the glass blank for magnetic recording medium glass substrates of Claim 7 ,
The method for producing a glass blank for a magnetic recording medium glass substrate, wherein the molten glass has a viscosity of 500 dPa · s to 1050 dPa · s. In the manufacturing method of the glass blank for magnetic recording medium glass substrates as described in any one of Claims 1-8 ,
A glass blank for a magnetic recording medium glass substrate, wherein the first press mold and the second press mold are disposed to face each other in a direction orthogonal to a falling direction of the molten glass lump. Production method. The method of manufacturing a magnetic recording medium glass glass blank substrate according to any one of claims 1-9,
The temperature of the press molding surfaces of the first press mold and the second press mold immediately before the first pressing step is 10 ° C. at the strain point of the glass material constituting the molten glass lump. The manufacturing method of the glass blank for magnetic-recording-medium glass substrates characterized by the below-mentioned temperature added. In the manufacturing method of the glass blank for magnetic recording medium glass substrates as described in any one of Claims 1-10 ,
During the execution of the second pressing step, the one surface of the sheet glass and the press molding surface of the first press mold are always closely adhered to each other, and the other surface of the sheet glass is A method for producing a glass blank for a glass substrate of a magnetic recording medium, characterized in that the press molding surface of the second press mold is always closely adhered without any gap. In the claims 1-11 in any one method of manufacturing a magnetic recording medium glass glass blank substrate according to the,
A method for producing a glass blank for a magnetic recording medium glass substrate, wherein the duration of the second pressing step is controlled so that the flatness of the glass blank for a magnetic recording medium glass substrate is 4 μm or less. Magnetic recording through at least a polishing step of polishing the main surface of the glass blank for a magnetic recording medium glass substrate produced by the method for producing a glass blank for a magnetic recording medium glass substrate according to any one of claims 1 to 12. the method of manufacturing a magnetic recording medium glass substrate, wherein manufacturing to Rukoto medium glass substrate. In the manufacturing method of the glass blank for magnetic recording medium glass substrates of Claim 13 ,
The duration of the second pressing step is the temperature at which the temperature of the plate glass at the end of the second pressing step is at least 10 ° C. added to the strain point of the glass material constituting the plate glass. A method for producing a glass substrate for a magnetic recording medium, characterized in that the following is selected. In the manufacturing method of the magnetic-recording-medium glass substrate of Claim 13 or 14 ,
A method for producing a magnetic recording medium glass substrate, wherein the flatness of the glass blank for the magnetic recording medium glass substrate and the flatness of the magnetic recording medium glass substrate are substantially the same. Magnetic recording through at least a polishing step of polishing the main surface of the glass blank for a magnetic recording medium glass substrate produced by the method for producing a glass blank for a magnetic recording medium glass substrate according to any one of claims 1 to 12. Manufacturing a medium glass substrate,
The magnetic recording medium of the magnetic recording layer forming step of forming a magnetic recording layer on a glass substrate at least through method of manufacturing a magnetic recording medium characterized manufacture to Rukoto the magnetic recording medium. In the manufacturing method of the glass blank for magnetic recording medium glass substrates of Claim 16 ,
The duration of the second pressing step is the temperature at which the temperature of the plate glass at the end of the second pressing step is at least 10 ° C. added to the strain point of the glass material constituting the plate glass. A method of manufacturing a magnetic recording medium, characterized in that the following is selected. The method of manufacturing a magnetic recording medium according to claim 16 or 17 ,
A method for producing a magnetic recording medium, wherein the flatness of the glass blank for the magnetic recording medium glass substrate and the flatness of the magnetic recording medium glass substrate are substantially the same.

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