JP5524689B2 - Starch for seasoning, method for producing the same, and use thereof - Google Patents

Starch for seasoning, method for producing the same, and use thereof Download PDF

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JP5524689B2
JP5524689B2 JP2010094422A JP2010094422A JP5524689B2 JP 5524689 B2 JP5524689 B2 JP 5524689B2 JP 2010094422 A JP2010094422 A JP 2010094422A JP 2010094422 A JP2010094422 A JP 2010094422A JP 5524689 B2 JP5524689 B2 JP 5524689B2
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浩平 山田
博司 森
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Showa Sangyo Co Ltd
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Description

本発明はでん粉に関し、特に、調味料や粉末化基材に使用可能なでん粉に関する。   The present invention relates to starch, and in particular, to starch that can be used for seasonings and powdered substrates.

従来、吸湿性の高い調味料などを粉末化する際に、製造時や粉末化後の吸湿を抑える目的で粉末化基材が使用されてきた。粉末化基材には、デキストリンなどのでん粉の高度加水分解物や、酸化でん粉などが使用されてきた。それらは、吸湿を抑えなければならない程度に応じて使い分けられ、より吸湿性の高い調味料を粉末化する場合には酸化でん粉が使用されていた。
また、液状で流通、使用する調味料では、粘度調整の目的で各種の酸化でん粉や架橋でん粉など各種の化工澱粉が使用されている。
Conventionally, when a seasoning having high hygroscopicity is pulverized, a powdered base material has been used for the purpose of suppressing moisture absorption during production or after pulverization. As the powdered base material, highly hydrolyzed starches such as dextrin and oxidized starch have been used. They are properly used according to the degree to which moisture absorption must be suppressed, and oxidized starch is used when powdering seasonings with higher hygroscopicity.
In addition, various modified starches such as various types of oxidized starches and cross-linked starches are used in the seasonings to be distributed and used in liquid form for the purpose of viscosity adjustment.

特許第3458113号公報Japanese Patent No. 3458113 特開平11-243901号公報JP-A-11-243901 特開2003-219813号公報JP 2003-219813 A 特開2003-38119号公報JP 2003-38119 A 特開平5-3764号公報Japanese Patent Laid-Open No. 5-3764 特開平11−19509号公報Japanese Patent Laid-Open No. 11-19509

これまで粉末調味料の粉末化基材や液状調味料の粘度調整には、溶解後の透明性・粘度の点で優れる次亜塩素酸ナトリウムにて処理した酸化でん粉などが使用されてきた為、でん粉を塩酸や硫酸で軽度に処理した酸処理でん粉は殆ど使用されてこなかった。
しかし、酸化でん粉は、酸化の過程でカルボキシル基が導入され、でん粉分子が化学的に変性している。昨今、食品の天然物志向の高まりにより、酸化でん粉のように、天然分子が化学的に変性したものの、食品への使用を避けるという風潮がある。
さらに、酸化でん粉は、例えば粉末化基材として使用する場合は吸湿しない点では優れているが、風味調味料などの場合、粉末化される素材の風味をマスキングしてしまうという品質上の問題点があった。この品質上の問題は、液状調味料においても同様であった。
So far, the powdered base material of powder seasonings and the viscosity adjustment of liquid seasonings have been used for oxidized starch treated with sodium hypochlorite which is excellent in terms of transparency and viscosity after dissolution. The acid-treated starch which lightly processed the starch with hydrochloric acid or sulfuric acid has hardly been used.
However, in the oxidized starch, carboxyl groups are introduced during the oxidation process, and the starch molecules are chemically modified. Recently, due to the growing trend toward natural products in foods, natural molecules have been chemically modified, such as oxidized starch, but there is a tendency to avoid use in foods.
Furthermore, oxidized starch is excellent in that it does not absorb moisture when used as a powdered base material, for example, in the case of a flavor seasoning, etc., there is a quality problem that masks the flavor of the material to be powdered was there. This quality problem was also true for liquid seasonings.

酸処理でん粉とは、でん粉粒が残存した状態のまま酸処理剤(塩酸、硫酸などの鉱酸類)で酸処理した状態のでん粉であり、酸化でん粉のように置換基等の導入が無く、化学的変性が少ない。酸処理でん粉は、冷水で可溶ではなく、水溶液状で加熱することで糊化してある程度の粘度が出るが、原料でん粉よりは低粘度化した性質を持つでん粉である。しかし、従来の酸処理でん粉は風味立ちが悪いという欠点があった。
そこで、本発明は、風味立ちが良く、粉末化基材や液状調味料の粘度調整用としても使用可能なでん粉を提供することを主目的とする。
Acid-treated starch is starch that has been acid-treated with an acid-treating agent (mineral acids such as hydrochloric acid and sulfuric acid) with the starch granules remaining, and it does not introduce any substituents such as oxidized starch. There is little mechanical modification. Acid-treated starch is not soluble in cold water and is gelatinized by heating in an aqueous solution to give a certain viscosity, but is a starch having a property of lower viscosity than raw starch. However, the conventional acid-treated starch has a drawback of poor taste.
Therefore, the main object of the present invention is to provide a starch that has good flavor and can be used for adjusting the viscosity of a powdered base material or liquid seasoning.

上記課題を解決するために、本発明は、馬鈴薯でん粉を主原料とするでん粉原料が、鉱酸によって酸処理された調味料用でん粉であって、濃度20質量%、温度70℃、回転数60rpmでの粘度が13〜550mPa・sである調味料用でん粉を提供する。
本発明の調味料用でん粉と、粉末水飴とを含有させ、粉末水飴の含有量が30質量%以下の粉末化基材を作製することができる。また、本発明の調味料用でん粉と、イソマルトオリゴ糖とを含有させ、イソマルトオリゴ糖の含有量が10〜50質量%の調味液を作製することできる。
本発明の調味料用でん粉は、馬鈴薯でん粉を主原料とするでん粉原料を溶媒に分散し、でん粉スラリーとして、前記でん粉スラリーに、濃度10〜60質量%の鉱酸溶液を添加して、前記でん粉原料を酸処理することで製造できる。
また、本発明の調味料用でん粉と、調味料成分とを含む原料液を、噴霧、乾燥して粉末状の調味料を製造することもできる。
In order to solve the above-mentioned problem, the present invention is a starch for seasoning in which a starch raw material mainly composed of potato starch is acid-treated with mineral acid, and has a concentration of 20% by mass, a temperature of 70 ° C., and a rotational speed of 60 rpm. The starch for seasonings whose viscosity is 13-550 mPa * s is provided.
The starch for seasonings of this invention and a powdered starch syrup are contained, and the powdered base material whose content of a powdered starch syrup is 30 mass% or less can be produced. Moreover, the seasoning starch of this invention and isomaltoligosaccharide are contained, and the seasoning liquid whose content of isomaltoligosaccharide is 10-50 mass% can be produced.
The starch for seasoning of the present invention is obtained by dispersing a starch raw material containing potato starch as a main raw material in a solvent and adding a mineral acid solution having a concentration of 10 to 60% by mass to the starch slurry as a starch slurry. It can be produced by acid treatment of the raw material.
Moreover, the raw material liquid containing the starch for seasonings of this invention and a seasoning component can be sprayed and dried, and a powdery seasoning can also be manufactured.

本発明の調味料用でん粉は、従来の酸処理でん粉や酸化でん粉に比べて風味立ちが高い上、吸湿性が低いから、調味料等の粉末化基材、調味液等に広く使用することができる。   The seasoning starch of the present invention has a high flavor and low hygroscopicity compared to conventional acid-treated starch and oxidized starch, so it can be widely used in powdered base materials such as seasonings, seasoning liquids, etc. it can.

酸処理馬鈴薯でん粉A〜Gの30℃、40℃、50℃、60℃、70℃、80℃での粘度の測定結果を示すグラフ。The graph which shows the measurement result of the viscosity in 30 degreeC, 40 degreeC, 50 degreeC, 60 degreeC, 70 degreeC, and 80 degreeC of acid treatment potato starch AG.

本発明に用いるでん粉原料は、馬鈴薯でん粉を主原料するものであって、化学変性が加わり置換基が導入される酸化処理や酵素分解等の加水分解処理が行われておらず、でん粉粒が残存した状態のものを用いる。なお、主原料とは含有量が50質量%以上のことである。すなわち、でん粉原料は馬鈴薯でん粉を50質量%以上含む。
でん粉原料には、50質量%以下の範囲で、馬鈴薯でん粉以外の他のでん粉を添加することもできる。他のでん粉は特に限定されず、例えば、とうもろこしでん粉、甘藷でん粉、小麦でん粉、米でん粉、タピオカでん粉、サゴ椰子でん粉などのでん粉である。これらのでん粉は1種類をでん粉原料に添加してもよいし、2種類以上を同一のでん粉原料に添加してもよい。他のでん粉の添加量は特に限定されないが、馬鈴薯でん粉含有量が50質量%以上、より好ましくは80質量%以上となるように、添加量を抑えることが望ましい。
The starch raw material used in the present invention is mainly made from potato starch, and is not subjected to hydrolysis treatment such as oxidation treatment or enzymatic decomposition in which a substituent is introduced due to chemical modification, and starch granules remain. Use the one in the state. The main raw material means that the content is 50% by mass or more. That is, the starch raw material contains potato starch at 50% by mass or more.
In the starch raw material, starch other than potato starch can be added within a range of 50% by mass or less. Other starches are not specifically limited, For example, they are starches, such as corn starch, sweet potato starch, wheat starch, rice starch, tapioca starch, and sago eggplant starch. One type of these starches may be added to the starch raw material, or two or more types may be added to the same starch raw material. The amount of other starch added is not particularly limited, but it is desirable to suppress the amount added so that the potato starch content is 50% by mass or more, more preferably 80% by mass or more.

本発明の調味料用でん粉は、上記でん粉原料を酸処理剤で酸処理して得られる。酸処理剤は鉱酸(無機酸)である。酸処理剤としては、硫酸と塩酸のいずれか一方又は両方を用いることができるが、反応速度等の点から硫酸が最も好ましい。   The seasoning starch of the present invention is obtained by acid-treating the starch raw material with an acid treatment agent. The acid treatment agent is a mineral acid (inorganic acid). As the acid treatment agent, either one or both of sulfuric acid and hydrochloric acid can be used, and sulfuric acid is most preferable from the viewpoint of reaction rate and the like.

でん粉の酸処理方法は特に限定されない。でん粉の酸処理は、鉱酸の酸濃度1〜5質量%の水溶液に、粉体のでん粉を添加、攪拌するのが一般的ではあるが、本発明は、粉体のでん粉を水等の溶媒に分散したスラリー(懸濁液)に、濃度10〜60質量%の高濃度鉱酸を添加する方法がより適している。
でん粉スラリーに用いる溶媒は、水を50質量%以上含有する物であれば特に限定されない。その溶媒には、必要に応じて分散剤、pH調整剤等の添加剤を添加することもできる。
The acid treatment method for starch is not particularly limited. In the acid treatment of starch, powdered starch is generally added to an aqueous solution of mineral acid with an acid concentration of 1 to 5% by mass and stirred. A method of adding a high concentration mineral acid having a concentration of 10 to 60% by mass to the slurry (suspension) dispersed in is more suitable.
The solvent used for the starch slurry is not particularly limited as long as it contains 50% by mass or more of water. If necessary, additives such as a dispersant and a pH adjuster can be added to the solvent.

でん粉スラリーに高濃度鉱酸を添加した後は、温度20℃〜55℃、10〜50時間程度攪拌して酸処理を行うことができ、温度と時間を調整することで、濃度20質量%、温度70℃、回転数60rpmでの粘度が13〜550mPa・s(ミリパスカル秒)となる調味料用でん粉が得られる。なお、本発明で粘度測定に用いる溶媒は水である。
本発明の調味料用でん粉は、酸処理後、中和し、必要であれば水洗し、乾燥して得られる。中和に用いるアルカリ溶液も特に限定されず、水酸化ナトリウム水溶液、水酸化カリウム水溶液等を用いることができる。
After adding high-concentration mineral acid to the starch slurry, the acid treatment can be performed by stirring for about 10 to 50 hours at a temperature of 20 ° C to 55 ° C. By adjusting the temperature and time, the concentration is 20% by mass, A starch for seasoning having a viscosity of 13 to 550 mPa · s (millipascal second) at a temperature of 70 ° C. and a rotation speed of 60 rpm is obtained. In the present invention, the solvent used for viscosity measurement is water.
The starch for seasoning of the present invention is obtained by neutralizing after acid treatment, washing with water if necessary, and drying. The alkali solution used for neutralization is not particularly limited, and an aqueous sodium hydroxide solution, an aqueous potassium hydroxide solution, or the like can be used.

本発明の調味料用でん粉は、食品や調味料の風味をマスキングしない上、水等への溶解性が高く、溶解時の透明性も高いから、粉末調味料用の粉末化基材として非常に適している。ここで、粉末調味料とは、食品の風味付けに用いられる物の他、希釈物をそのまま摂食可能な粉末飲料類(清涼飲料水、スープ類等)も含む。
粉末調味料は、顆粒状又は粉状であって、1種以上の調味料成分と、本発明の調味料用でん粉とを含有する。調味料成分は、例えば、発酵調味料(醤油、味噌、酢、酒等)、タンパク質分解物(アミノ酸類)、酵母エキス、塩、甘味料(ブドウ糖、庶糖等)、香辛料(コショウ、唐辛子等)、油脂類(植物油、動物油)、抽出エキス(畜産物、農産物、又は海産物由来)等である。
The starch for seasoning of the present invention does not mask the flavor of foods and seasonings, has high solubility in water, etc., and has high transparency when dissolved, so it is very suitable as a powdered base material for powder seasonings. Is suitable. Here, the powder seasoning includes powder drinks (soft drinks, soups, etc.) that can be used as it is in addition to those used for flavoring foods.
The powder seasoning is granular or powdery and contains one or more seasoning ingredients and the seasoning starch of the present invention. Seasoning ingredients include, for example, fermented seasonings (soy sauce, miso, vinegar, sake, etc.), protein degradation products (amino acids), yeast extract, salt, sweeteners (glucose, sucrose, etc.), spices (pepper, chili, etc.) Oils and fats (vegetable oils, animal oils), extract extracts (derived from livestock products, agricultural products, or marine products).

粉末調味料の製造方法は特に限定されないが、例えば、本発明の調味料用でん粉を、1種類以上の調味料成分と混合して製造することができる。混合工程は、ローラーコンパクター、ロールプレス等を使用し、調味料成分と調味料用でん粉を圧縮成形し、顆粒状にしてもよい。調味料成分は粉状、液状のいずれも使用可能であり、調味料成分が液状の場合、単に調味料用でん粉と混合、吸収させて、粉末調味料を製造することもできる。液状調味料成分の量が多い場合は、混合後に乾燥工程が必要である。   Although the manufacturing method of a powder seasoning is not specifically limited, For example, the starch for seasonings of this invention can be mixed with one or more types of seasoning ingredients, and can be manufactured. In the mixing step, a roller compactor, a roll press or the like may be used, and the seasoning ingredients and the seasoning starch may be compression-molded into granules. The seasoning component can be either powdery or liquid. When the seasoning component is liquid, it can be simply mixed and absorbed with the starch for seasoning to produce a powder seasoning. When the amount of the liquid seasoning component is large, a drying step is necessary after mixing.

さらに、本発明の調味料用でん粉と、調味料成分とを含む原料液を乾燥して粉末調味料を製造することもできる。原料液は、本発明の調味料用でん粉と、1種以上の調味料成分とを含み、必要であれば水等の希釈剤を添加して作製される。調味料成分は粉状であっても、液状であってもよい。原料液には、分散安定剤、防腐剤、香料、老化防止剤、pH調整剤等の添加剤を添加してもよい。   Furthermore, a powdered seasoning can also be produced by drying a raw material solution containing the starch for seasoning of the present invention and a seasoning component. The raw material liquid includes the starch for seasoning of the present invention and one or more seasoning ingredients, and is prepared by adding a diluent such as water if necessary. The seasoning component may be powdery or liquid. You may add additives, such as a dispersion stabilizer, antiseptic | preservative, a fragrance | flavor, anti-aging agent, and a pH adjuster, to a raw material liquid.

原料液を乾燥する際の乾燥方法は特に限定されず、ドラムドライヤー法、エクストルーダー法、真空凍結乾燥、スプレードライヤー法等公知の方法を用いることができるが、粉体粒径の細かさ、成分劣化が少ない等の点で、スプレードライヤー法が最も適している。
スプレードライヤー法は、原料液を噴霧し、霧状の原料液を高温気体と接触させて乾燥する噴霧乾燥法である。スプレードライヤー法は、原料液の粘度が高すぎるとノズルに目詰まりが起こり、正常に噴出されない。原料液を希釈すれば粘度が下がるが、噴霧乾燥に時間がかかり、製造コストが高くなる。
The drying method for drying the raw material liquid is not particularly limited, and known methods such as a drum dryer method, an extruder method, a vacuum freeze-drying method, and a spray dryer method can be used. The spray dryer method is most suitable in terms of little deterioration.
The spray dryer method is a spray drying method in which a raw material liquid is sprayed and the mist-like raw material liquid is contacted with a high-temperature gas and dried. In the spray dryer method, when the viscosity of the raw material liquid is too high, the nozzles are clogged and are not ejected normally. If the raw material liquid is diluted, the viscosity decreases, but spray drying takes time and the production cost increases.

本発明の調味料用でん粉は、濃度20質量%、温度70℃、回転数60rpmでの粘度が13〜550mPa・sであり、一般的な使用量(5〜50質量%)で原料液に添加した場合、スプレードライヤー法で乾燥可能な程度に低粘度になる。従って、本発明の調味料用でん粉を用いれば、必要以上に原料液を希釈する必要がなく、通常の乾燥法で粉末調味料を製造することができる。   The seasoning starch of the present invention has a concentration of 20% by mass, a temperature of 70 ° C., a viscosity at a rotational speed of 60 rpm of 13 to 550 mPa · s, and is added to the raw material liquid in a general usage amount (5 to 50% by mass). In this case, the viscosity becomes low enough to be dried by a spray dryer method. Therefore, if the starch for seasonings of this invention is used, it is not necessary to dilute a raw material liquid more than necessary, and a powder seasoning can be manufactured with a normal drying method.

粉末化基材は、本発明の調味料用でん粉のみで構成してもよいが、原料液の粘度調整等の目的で、粉末化基材に粉末水飴を添加することもできる。粉末水飴の添加量が多い程、原料液の粘度が低くなるが、その添加量が粉末化基材全体の30質量%を超えると粉末調味料の吸湿性が高くなるので、粉末水飴の添加量は30質量%以下(0〜30質量%)が好ましい。
なお、粉末水飴は、でん粉の酸分解物又は酵素分解物であって、DE(Dextrose Equibalent)10〜40程度の分解物を脱水乾燥したものである。粉末水飴水溶液の粘度は、本発明の調味料用でん粉よりも低く、濃度20質量%、温度70℃、回転数60rpmで13Pa・s未満である。
The powdered base material may be composed only of the seasoning starch of the present invention, but powdered starch syrup can be added to the powdered base material for the purpose of adjusting the viscosity of the raw material liquid. The more the amount of powdered starch syrup is added, the lower the viscosity of the raw material liquid is. However, if the amount added exceeds 30% by mass of the entire powdered base material, the hygroscopicity of the powder seasoning increases. Is preferably 30% by mass or less (0 to 30% by mass).
The powder starch syrup is an acid decomposition product or an enzyme decomposition product of starch, and is a product obtained by dehydrating and drying a decomposition product of DE (Dextrose Equivalent) of about 10 to 40. The viscosity of the powdered syrup solution is lower than that of the seasoning starch of the present invention, and is less than 13 Pa · s at a concentration of 20 mass%, a temperature of 70 ° C., and a rotation speed of 60 rpm.

本発明の調味料用でん粉の用途は粉末化基材に限定されない。本発明の調味料用でん粉は、風味立ちが優れている上、水に溶解させた時の照り、ツヤ、粘度等の特性も優れているので、粉末化しない調味液(液状調味料)に使用することもできる。
調味液は、本発明の調味料用でん粉と、1種以上の調味料成分とを含有する液体であって、必要であれば水等の希釈剤を添加する。本発明の調味料用でん粉が使用可能な調味液は特に限定されず、調味液塗布剤(煎餅用タレ、焼肉用タレ、焼き鳥用タレ等)、ソース(ドレッシング)等である。また、調味液以外にも、飲料(清涼飲料水、スープ類)等に用いることもできる。
調味液には、本発明の調味料用でん粉と、調味料成分の他、分散安定剤、防腐剤、香料、老化防止剤、pH調整剤等の添加剤を添加してもよい。なお、調味液に用いる調味料成分も特に限定されず、粉末調味料と同様、多様なものを1種以上用いることができる。
The use of the seasoning starch of the present invention is not limited to a powdered substrate. The starch for seasoning of the present invention is excellent in flavor and has excellent characteristics such as shine, gloss and viscosity when dissolved in water, so it is used for non-powdered seasoning liquid (liquid seasoning) You can also
The seasoning liquid is a liquid containing the starch for seasoning of the present invention and one or more seasoning ingredients, and if necessary, a diluent such as water is added. The seasoning liquid in which the seasoning starch of the present invention can be used is not particularly limited, and examples thereof include seasoning liquid coating agents (such as sauce for rice crackers, sauce for grilled meat, sauce for grilled chicken), sauce (dressing), and the like. In addition to the seasoning liquid, it can also be used for beverages (soft drinks, soups) and the like.
In addition to the starch for seasonings of the present invention and seasoning ingredients, additives such as dispersion stabilizers, preservatives, fragrances, anti-aging agents, and pH adjusters may be added to the seasoning liquid. In addition, the seasoning component used for a seasoning liquid is not specifically limited, As well as a powder seasoning, 1 or more types of various things can be used.

調味液には、更に、イソマルトオリゴ糖のようなオリゴ糖を、粘度安定等の目的で添加してもよい。イソマルトオリゴ糖は、でん粉の分解物であって、α−1,6グルコシド結合を有する糖質で、とうもろこしでん粉を酵素分解、糖転移させて製造されるものが一般的である。イソマルトオリゴ糖の水溶液は本発明の調味料用でん粉よりも低粘度であり、濃度20質量%、温度70℃、回転数60rpmでの粘度が13Pa・s未満である。
イソマルトオリゴ糖の添加量は特に限定されないが、10質量%未満であると照りツヤや風味が劣る。また、その添加量が50質量%を超えると味に影響が出て、しかも、吸湿性が高くなるから、10〜50質量%が好ましい。
An oligosaccharide such as isomaltoligosaccharide may be further added to the seasoning liquid for the purpose of viscosity stabilization. The isomaltoligosaccharide is a decomposition product of starch and is generally a saccharide having an α-1,6 glucoside bond, which is produced by enzymatic decomposition and sugar transfer of corn starch. The aqueous solution of isomaltoligosaccharide has a lower viscosity than the starch for seasoning of the present invention, and the viscosity at a concentration of 20% by mass, a temperature of 70 ° C., and a rotation speed of 60 rpm is less than 13 Pa · s.
The amount of isomaltoligosaccharide added is not particularly limited, but if it is less than 10% by mass, the shine gloss and flavor are poor. Moreover, when the addition amount exceeds 50 mass%, a taste will be influenced and also hygroscopicity will become high, Therefore 10-50 mass% is preferable.

<でん粉原料の選定>
1.酸処理でん粉の調整:
とうもろこし、サゴ椰子、馬鈴薯、タピオカ、甘藷由来のでん粉100質量部に対して水110質量部を加え攪拌してスラリーとした後、50質量%硫酸溶液4.8質量部を添加し、スラリーを50℃、28時間攪拌し、酸処理を行った。苛性ソーダ水溶液を加えて中和し、更に水洗、脱水して水分13質量%まで乾燥して各種酸処理でん粉を調整した。
<Selection of starch material>
1. Preparation of acid-treated starch:
After adding 110 parts by mass of water to 100 parts by mass of starch derived from corn, sago, potato, tapioca, and sweet potato, the mixture was stirred to form a slurry, and then 4.8 parts by mass of a 50% by mass sulfuric acid solution was added to the slurry. The mixture was stirred at 28 ° C. for 28 hours for acid treatment. A caustic soda aqueous solution was added for neutralization, followed by washing with water, dehydration, and drying to a moisture content of 13% by mass to prepare various acid-treated starches.

2.測定方法
白度:粉体用白度計(株式会社ケット科学研究所製:C‐100‐3)使用
粘度:200mlのトールビーカーにでん粉40g(D.B.)を量り、水を加えて200gとする。水浴中で加熱攪拌し、90℃到達後、10分間撹拌を続ける。放冷後、水分補正を行い、各温度で粘度を測定する。回転粘度計(B型粘度計)を使用し、回転数60rpmで測定した。
透過率:200mlのトールビーカーにでん粉10g(D.B.)を量り、水を加えて200gとする。水浴中で加熱攪拌し、90℃到達後、10分間撹拌を続ける。30℃で30分間放冷後、水分補正を行い、720nmの吸光度を測定する。
安息角:電磁振動式安息角測定器(筒井理化学器械株式会社製:AOR‐57形)使用
得られた酸処理でん粉の特性は以下の通りであった。
2. Measuring method Whiteness: Whiteness meter for powder (Kett Science Laboratory Co., Ltd .: C-100-3) used Viscosity: Weigh 40 g (D.B.) starch into 200 ml tall beaker, add water and add 200 g And Stir in a water bath and continue stirring for 10 minutes after reaching 90 ° C. After standing to cool, the moisture is corrected and the viscosity is measured at each temperature. Using a rotational viscometer (B-type viscometer), the measurement was performed at a rotational speed of 60 rpm.
Transmittance: Weigh 10 g (D.B.) starch into a 200 ml tall beaker and add water to make 200 g. Stir in a water bath and continue stirring for 10 minutes after reaching 90 ° C. After allowing to cool at 30 ° C. for 30 minutes, moisture correction is performed and the absorbance at 720 nm is measured.
Angle of repose: Electromagnetic vibration type angle of repose measuring instrument (Tsutsuri Chemical Instruments Co., Ltd .: AOR-57 type) was used. The characteristics of the acid-treated starch were as follows.

Figure 0005524689
Figure 0005524689

酸処理とうもろこしでん粉、酸処理サゴ椰子でん粉は粘度が高く透過率も低いものであった。酸処理タピオカでん粉、酸処理甘藷でん粉は、粘度は低くなるが透過率が低く安息角の数値は大きく流動性の悪いものであった。酸処理馬鈴薯でん粉は粘度も十分低下し、安息角も比較的低く流動性も良かった。   The acid-treated corn starch and the acid-treated sago starch starch had high viscosity and low transmittance. Acid-treated tapioca starch and acid-treated sweet potato starch had low viscosity but low permeability and a large repose angle and poor fluidity. The acid-treated potato starch had a sufficiently reduced viscosity, a relatively low angle of repose and good fluidity.

<粉末調味料の試作>
上記各種原料でん粉を酸処理して得られた酸処理とうもろこしでん粉、酸処理サゴ椰子でん粉、酸処理馬鈴薯でん粉、酸処理タピオカでん粉、酸処理甘藷でん粉を用いて粉末和風調味料を調製した。配合は以下の通りとした。
<Prototype of powder seasoning>
Japanese-style seasonings were prepared using acid-treated corn starch, acid-treated sago coconut starch, acid-treated potato starch, acid-treated tapioca starch, and acid-treated sweet potato starch obtained by acid-treating the above various raw material starches. The composition was as follows.

酸処理でん粉: 49質量部
カツオエキス: 11質量部
鰹節粉末 : 25質量部
コンブ粉末 : 12質量部
酵母エキス : 3質量部
Acid-treated starch: 49 parts by weight Skipjack extract: 11 parts by weight Bud powder: 25 parts by weight Kombu powder: 12 parts by weight Yeast extract: 3 parts by weight

各素材を均一になるまで混合した後、ターボ工業株式会社製のローラーコンパクターで圧縮造粒して顆粒状粉末調味料を作成した。ローラーコンパクターは圧縮圧1.0t/cm、ロールクリアランス0.5mm、回転数15rpmで運転し粗粉砕後篩い分けして粒径0.3mm〜1.0mmの粉末和風調味料を作成した。
得られた粉末和風調味料を、濃度が2質量%となるように温水に溶解し、風味の立ち、溶液の透明性、総合評価に関する官能評価を行った。
官能評価は、10名の専門パネルにて評価し、評点法(5点:非常に良い、4点:良い、3点:普通、2点:少し悪い、1点:悪い)によって点数化した。以下に各種酸処理でん粉で調整した粉末調味料の評価の平均点数を示す。
After mixing each material until it became uniform, it was compressed and granulated with a roller compactor manufactured by Turbo Industry Co., Ltd. to prepare a granular powder seasoning. The roller compactor was operated at a compression pressure of 1.0 t / cm, a roll clearance of 0.5 mm, and a rotational speed of 15 rpm, and coarsely pulverized and sieved to prepare a powder Japanese-style seasoning having a particle size of 0.3 mm to 1.0 mm.
The obtained powder Japanese-style seasoning was dissolved in warm water so as to have a concentration of 2% by mass, and sensory evaluation was performed on flavor standing, transparency of the solution, and comprehensive evaluation.
The sensory evaluation was evaluated by a panel of 10 experts and scored by a rating method (5 points: very good, 4 points: good, 3 points: normal, 2 points: a little bad, 1 point: bad). The average score of the evaluation of the powder seasoning adjusted with various acid-treated starches is shown below.

Figure 0005524689
Figure 0005524689

これらの結果から酸処理馬鈴薯でん粉は、他の原料由来の酸処理でん粉に比べて風味の立ち、透明性、総合評価全ての項目で優れていた。   From these results, the acid-treated potato starch was superior to the acid-treated starch derived from other raw materials in terms of flavor, transparency, and overall evaluation.

<酸処理試験>
酸処理試験1:馬鈴薯でん粉100質量部に対して水110質量部を加え攪拌してスラリーとした後、60質量%硫酸溶液4.8質量部をスラリーに添加した。そのスラリーを50℃で5時間攪拌し、酸処理を行った。水酸化ナトリウム水溶液を加えて中和し、更に水洗、乾燥して酸処理馬鈴薯でん粉Aを得た。
<Acid treatment test>
Acid treatment test 1: 110 parts by mass of water was added to 100 parts by mass of potato starch and stirred to form a slurry, and then 4.8 parts by mass of a 60% by mass sulfuric acid solution was added to the slurry. The slurry was stirred at 50 ° C. for 5 hours for acid treatment. An aqueous sodium hydroxide solution was added to neutralize, followed by washing with water and drying to obtain acid-treated potato starch A.

酸処理試験2〜6:酸処理時間を5時間から10時間、20時間、28時間、32時間、40時間にそれぞれ変えて、酸処理馬鈴薯でん粉B、C、D、E、Fを得た。酸処理時間以外の条件は酸処理試験1と同じとした。   Acid treatment tests 2 to 6: Acid treatment potato starch B, C, D, E and F were obtained by changing the acid treatment time from 5 hours to 10 hours, 20 hours, 28 hours, 32 hours and 40 hours, respectively. Conditions other than the acid treatment time were the same as in the acid treatment test 1.

酸処理試験7:馬鈴薯でん粉100質量部に対して水110質量部を加え攪拌してスラリーとした後、60質量%硫酸溶液12質量部を添加し50℃で30時間攪拌し、酸処理を行った。水酸化ナトリウム水溶液を加えて中和し、更に水洗、乾燥して酸処理馬鈴薯でん粉Gを得た。   Acid treatment test 7: After adding 110 parts by weight of water to 100 parts by weight of potato starch and stirring to make a slurry, 12 parts by weight of 60% by weight sulfuric acid solution was added and stirred at 50 ° C. for 30 hours for acid treatment. It was. A sodium hydroxide aqueous solution was added to neutralize, and further washed with water and dried to obtain acid-treated potato starch G.

上記酸処理試験1〜7で得られた酸処理馬鈴薯でん粉A〜Gの30℃、40℃、50℃、60℃、70℃、80℃での粘度を測定した。その測定結果を図1のグラフに示す。
また得られた酸処理馬鈴薯でん粉A〜Gのでん粉の「かつお風味の立ち」について評価を行った。評価試験の結果を、濃度20質量%における30℃、70℃での粘度の測定結果と共に結果を以下に示す。
The viscosity at 30 ° C., 40 ° C., 50 ° C., 60 ° C., 70 ° C. and 80 ° C. of the acid-treated potato starch A to G obtained in the acid treatment tests 1 to 7 was measured. The measurement results are shown in the graph of FIG.
Moreover, it evaluated about "standing of bonito flavor" of the starch of the acid-treated potato starch A-G obtained. The results of the evaluation test are shown below together with the measurement results of the viscosity at 30 ° C. and 70 ° C. at a concentration of 20% by mass.

Figure 0005524689
Figure 0005524689

酸処理後の粘度(20質量%溶液、70℃、60rpm)が550mPa・sを超えたものと、13mPa・s未満のものは、風味の点でダシ風味をマスキングしてしまい調味料としての価値を下げてしまったが、酸処理後の粘度(20質量%溶液、70℃、60rpm)が13〜550mPa・sになるよう酸処理をした酸処理馬鈴薯でん粉は、官能評価の結果が3.2以上であり、風味立ちが優れているのが確認された。これらの中でも、酸処理馬鈴薯でん粉C〜Eは、風味評価の値が3.5を超えており、酸処理後の粘度(20質量%溶液、70℃、60rpm)は20〜55mPa・sがより風味立の点で優れていることが確認された。   When the viscosity after acid treatment (20% by mass solution, 70 ° C., 60 rpm) exceeds 550 mPa · s, and less than 13 mPa · s masks the dashi flavor in terms of flavor, the value as a seasoning The acid-treated potato starch that has been acid-treated so that the viscosity after acid treatment (20 mass% solution, 70 ° C., 60 rpm) is 13 to 550 mPa · s has a sensory evaluation result of 3.2. It was above and it was confirmed that the flavor standing is excellent. Among these, the acid-treated potato starch CE has a flavor evaluation value exceeding 3.5, and the viscosity after acid treatment (20% by mass solution, 70 ° C., 60 rpm) is more preferably 20 to 55 mPa · s. It was confirmed that it was excellent in terms of flavor.

さらに各温度における粘度挙動と風味の立ちの関係を見ると、20質量%のでん粉糊溶液を90℃に加熱してから、冷却していくと、60℃から50℃の範囲で急激(3000mPa・s以上)に粘度上昇するような酸処理度合いの酸処理でん粉、すなわち酸処理馬鈴薯でん粉C、酸処理馬鈴薯でん粉D、酸処理馬鈴薯でん粉Eは、さらに風味の立ちが良かった(図1を参照)。
以上の結果から、酸処理後の粘度(20質量%溶液、70℃、60rpm)が13〜550mPa・sであれば、調味料用でん粉として用いた場合の風味立ちがよく、それらの中でも、酸処理後の粘度(20質量%溶液、70℃、60rpm)が20〜55mPa.s、60℃から50℃への温度変化で3000mPa・s以上粘度上昇する物が特に風味立ちに優れていることが確認された。
なお、本試験で得られた酸処理馬鈴薯でん粉のDEを測定したところ、いずれも測定限界以下(DE0)であった。
Further, looking at the relationship between the viscosity behavior at each temperature and the standing of the flavor, when the starch paste solution of 20% by mass is heated to 90 ° C. and then cooled, it rapidly increases in the range of 60 ° C. to 50 ° C. (3000 mPa · The acid-treated starch having a degree of acid treatment that increases the viscosity to s or higher), that is, the acid-treated potato starch C, the acid-treated potato starch D, and the acid-treated potato starch E had a better flavor (see FIG. 1). .
From the above results, if the viscosity after acid treatment (20% by mass solution, 70 ° C., 60 rpm) is 13 to 550 mPa · s, the flavor when used as a starch for seasoning is good. The viscosity after treatment (20 mass% solution, 70 ° C., 60 rpm) is 20 to 55 mPa.s. It was confirmed that a product having a viscosity increase of 3000 mPa · s or more when the temperature was changed from 60 ° C. to 50 ° C. was particularly excellent in flavor.
In addition, when DE of the acid-treated potato starch obtained in this test was measured, all were below the measurement limit (DE0).

<酸処理方法の影響>
次に、酸処理でん粉を製造する際の酸の添加方法についても検討した。
酸処理試験8:馬鈴薯でん粉100質量部に対して水110質量部を加え攪拌してスラリーとした後、6質量%硫酸溶液48質量部を添加し50℃で28時間攪拌し、酸処理を行った。苛性ソーダ水溶液を加えて中和し、更に水洗、乾燥して酸処理馬鈴薯でん粉Hを得た。
<Influence of acid treatment method>
Next, the addition method of the acid at the time of manufacturing acid-treated starch was also examined.
Acid treatment test 8: After adding 110 parts by weight of water to 100 parts by weight of potato starch and stirring to make a slurry, 48 parts by weight of 6% by weight sulfuric acid solution was added and stirred at 50 ° C. for 28 hours for acid treatment. It was. An aqueous solution of caustic soda was added for neutralization, followed by washing with water and drying to obtain acid-treated potato starch H.

酸処理試験9:硫酸溶液の濃度を10質量%、添加量を28.8質量部に変えた以外は酸処理試験8と同じ方法で酸処理馬鈴薯でん粉Iを得た。   Acid treatment test 9: Acid-treated potato starch I was obtained in the same manner as in the acid treatment test 8 except that the concentration of the sulfuric acid solution was changed to 10% by mass and the addition amount was changed to 28.8 parts by mass.

酸処理試験10:硫酸溶液の濃度を36質量%、添加量を8質量部に変えた以外は酸処理試験8と同じ方法で酸処理馬鈴薯でん粉Jを得た。   Acid treatment test 10: Acid-treated potato starch J was obtained in the same manner as in the acid treatment test 8 except that the concentration of the sulfuric acid solution was changed to 36% by mass and the addition amount was changed to 8 parts by mass.

酸処理試験11:硫酸溶液の濃度を96質量%、添加量を3質量部に変えた以外は酸処理試験8と同じ方法で酸処理馬鈴薯でん粉Kを得た。   Acid treatment test 11: Acid-treated potato starch K was obtained in the same manner as in the acid treatment test 8 except that the concentration of the sulfuric acid solution was changed to 96% by mass and the addition amount was changed to 3 parts by mass.

酸処理試験12:2質量%硫酸溶液144質量部に馬鈴薯でん粉100質量部を加え、50℃、28時間攪拌し反応させた。反応後、水酸化ナトリウム水溶液にて中和し、水洗した後、乾燥することによって酸処理でん粉Lを得た。
上記酸処理試験8〜12で得られた酸処理馬鈴薯でん粉H〜Lと、上記酸処理試験4の酸処理馬鈴薯でん粉Dについて粘度とかつお風味の官能検査の結果及び作業適性を以下にまとめた。
Acid treatment test 12: 100 parts by mass of potato starch was added to 144 parts by mass of a 2% by mass sulfuric acid solution, and the mixture was stirred and reacted at 50 ° C. for 28 hours. After the reaction, the solution was neutralized with an aqueous sodium hydroxide solution, washed with water, and dried to obtain acid-treated starch L.
The acid-treated potato starch H to L obtained in the acid treatment tests 8 to 12 and the acid-treated potato starch D of the acid treatment test 4 are summarized as follows.

Figure 0005524689
Figure 0005524689

酸処理でん粉の製造方法としては、でん粉と水を混合しスラリー状にした後、そこに硫酸を添加して反応する硫酸添加法(酸処理馬鈴薯でん粉A〜G及びH〜K)と、希硫酸溶液にでん粉粉末を添加する希硫酸でん粉添加法がある(酸処理馬鈴薯でん粉L)。
でん粉に対する酸濃度が同じで酸添加方法の異なる酸処理馬鈴薯でん粉Dと酸処理馬鈴薯でん粉Lの風味の立ちを比較すると、スラリー状にしてから硫酸を添加した酸処理馬鈴薯でん粉Dの方が風味の立ちに優れていた(官能評価スコア:でん粉D=3.8、でん粉L=3.0)。
The acid-treated starch is produced by mixing a starch and water into a slurry, and then adding sulfuric acid to react with the sulfuric acid (acid-treated potato starch A to G and H to K), dilute sulfuric acid. There is a dilute sulfuric acid starch addition method in which starch powder is added to the solution (acid-treated potato starch L).
Comparing the standing of the flavors of acid-treated potato starch D and acid-treated potato starch L, which have the same acid concentration with respect to starch and different acid addition methods, acid-treated potato starch D to which sulfuric acid was added after slurrying was more flavorful. It was excellent in standing (sensory evaluation score: starch D = 3.8, starch L = 3.0).

また、硫酸添加法に使用する硫酸濃度によっても風味の違いが見られた。硫酸濃度が低いと希硫酸でん粉添加法に近い反応になるため、風味の立ちが悪くなることが分かった。すなわち硫酸濃度が6質量%の硫酸を加えて製造した酸処理馬鈴薯でん粉Hは、10質量%以上の濃硫酸を加えて製造した酸処理馬鈴薯でん粉I〜K及びDと比べてかつお風味の立ちが悪かった。
濃度96質量%の硫酸溶液を添加して製造した酸処理馬鈴薯でん粉Kは、かつお風味の立ちの点では良好であったが、硫酸濃度が高いため、硫酸溶液を加えると反応系が部分的に発熱してしまった。その結果、でん粉の糊化による可溶化が部分的に起こり、排水負荷の増加、更には製品歩留まりの低下につながり実際の製造には適さないことが分かった。以上のことから、酸処理には、濃度10質量%以上60質量%以下の鉱酸溶液が最も適していることが確認された。
Moreover, the difference in flavor was also seen by the sulfuric acid concentration used for the sulfuric acid addition method. It was found that when the sulfuric acid concentration is low, the reaction is similar to that of dilute sulfuric acid starch addition method, so that the flavor is not good. In other words, the acid-treated potato starch H produced by adding sulfuric acid having a sulfuric acid concentration of 6% by mass has a higher flavor and taste compared to the acid-treated potato starches I to K and D produced by adding 10% by mass or more of concentrated sulfuric acid. It was bad.
Acid-treated potato starch K produced by adding a sulfuric acid solution having a concentration of 96% by mass was good in terms of bonito flavor, but because the sulfuric acid concentration is high, when the sulfuric acid solution is added, the reaction system is partially I had a fever. As a result, it was found that solubilization due to gelatinization of starch partially occurred, resulting in an increase in drainage load and a decrease in product yield, which is not suitable for actual production. From the above, it was confirmed that a mineral acid solution having a concentration of 10% by mass to 60% by mass is most suitable for acid treatment.

<使用試験:粉末醤油>
酸処理馬鈴薯でん粉の利用方法としては、液体調味液の粉末化基材として使用する場合もある。ここでは粉末調味料として粉末醤油を試作して、他の粉末化基材との比較を行った。粉末醤油は一般的な製造方法によって行った。すなわち、調味料成分である丸大豆醤油(キッコーマン株式会社製)100質量部に対して、粉末化基材を20質量部加え分散させて原料液を作製し、その原料液を80℃で10分間加熱し、スプレードライヤー(入口温度180℃、出口温度95℃)にて噴霧乾燥し粉末醤油を得た。
<Use test: powdered soy sauce>
The acid-treated potato starch may be used as a powdered base material for liquid seasoning liquid. Here, powder soy sauce was made as a powder seasoning and compared with other powdered base materials. Powdered soy sauce was produced by a general production method. That is, 20 parts by mass of a powdered base material is added to 100 parts by mass of round soybean soy sauce (produced by Kikkoman Co., Ltd.), which is a seasoning ingredient, and dispersed to prepare a raw material liquid. It heated and spray-dried with the spray dryer (inlet temperature of 180 degreeC, exit temperature of 95 degreeC), and powdered soy sauce was obtained.

使用した粉末化基材は、
(1)馬鈴薯でん粉を次亜塩素酸ナトリウムで低粘度化した酸化でん粉、
(2)上記酸処理馬鈴薯でん粉E、
(3)酸処理馬鈴薯でん粉Eと粉末水飴(昭和産業(株)製:VIANDEX-L DE23)を8:2の質量比率で混合したもの、
(4)酸処理馬鈴薯でん粉Eと粉末水飴(昭和産業(株)製:VIANDEX-L DE23)を7:3の質量比率で混合したもの、
(5)酸処理馬鈴薯でん粉Eと粉末水飴(昭和産業(株)製:VIANDEX-L DE23)を6:4の質量比率で混合したもの、又は
(6)低分解粉末水飴(DE10)である。
The powdered substrate used was
(1) Oxidized starch obtained by reducing the viscosity of potato starch with sodium hypochlorite,
(2) Acid-treated potato starch E,
(3) Acid-treated potato starch E and powdered starch syrup (made by Showa Sangyo Co., Ltd .: VIANDEX-L DE23) mixed at a mass ratio of 8: 2,
(4) A mixture of acid-treated potato starch E and powdered syrup (made by Showa Sangyo Co., Ltd .: VIANDEX-L DE23) at a mass ratio of 7: 3,
(5) Acid-treated potato starch E and powdered starch syrup (made by Showa Sangyo Co., Ltd .: VIANDEX-L DE23) mixed at a mass ratio of 6: 4, or (6) low-decomposition powdered starch syrup (DE10).

スプレードライ前の溶液の粘度(80℃にてB型粘度計で測定)、及び得られた粉末醤油の2質量%溶液での風味の官能評価(専門パネル10名による5段階評価の平均点)、30℃相対湿度80%の恒温恒湿に24時間保管した際の固結状態(吸湿性)について評価を行った(◎:全く固結しない、○:僅かに固結、△:固結して塊になる、×:潮解して液状になる)。結果を以下に示す。   Viscosity of the solution before spray drying (measured with a B-type viscometer at 80 ° C.) and sensory evaluation of the flavor with a 2% by mass solution of the obtained powdered soy sauce (average score of five-level evaluation by 10 professional panels) The solidified state (hygroscopicity) when stored at a constant temperature and humidity of 80% relative humidity at 30 ° C. for 24 hours was evaluated (◎: not consolidated, ○: slightly consolidated, Δ: consolidated) To become a lump, x: deliquescent and liquid). The results are shown below.

Figure 0005524689
Figure 0005524689

スプレードライヤーで原料液を乾燥する際には粉末化基材の粘度が低いことが求められるが、上記(1)〜(6)いずれの粉末化基材を用いた場合もスプレードライヤーでの乾燥を行うことが出来た。風味については、酸処理馬鈴薯でん粉は酸化でん粉よりも風味が良く、固結しにくい特性を持ち、粉末化基材として優れた性質を示した。
また、粉末水飴を混合した(3)〜(5)の粉末化基材については、酸処理でん粉単体(2)よりも粘度・風味が改善された。(3)〜(5)の粉末化基材を用いた粉末醤油は、低DE粉末水飴(6)よりも固結し難く風味が優れていた。
When the raw material liquid is dried with a spray dryer, the powdered base material is required to have a low viscosity. However, when any of the above powdered base materials (1) to (6) is used, drying with the spray dryer is required. I was able to do it. As for the flavor, the acid-treated potato starch was better in flavor than the oxidized starch, had the characteristics of being hard to set, and showed excellent properties as a powdered substrate.
Moreover, about the powdered base material of (3)-(5) which mixed the powder starch syrup, the viscosity and flavor were improved rather than the acid-processed starch simple substance (2). Powdered soy sauce using the powdered base materials of (3) to (5) was harder to set than the low DE powdered syrup (6) and had a superior flavor.

<使用試験:煎餅たれ>
本発明の酸処理馬鈴薯でん粉は煎餅などの調味液塗布剤としての用途でも使用できる。
調味液塗布剤として、下記表6の配合で煎餅タレA〜Eを調整した。なお、酸処理でん粉としては、上記酸処理馬鈴薯でん粉Eを用いた。
<Use test: rice cracker>
The acid-treated potato starch of the present invention can also be used as a seasoning liquid coating agent such as rice crackers.
As a seasoning liquid coating agent, rice cracker sauces A to E were prepared according to the formulation shown in Table 6 below. The acid-treated potato starch E was used as the acid-treated starch.

Figure 0005524689
Figure 0005524689

上記表6の配合割合で、醤油、イソマルトオリゴ糖シラップ(昭和産業(株)製イソマルト500、水分含有量25質量%)、酸処理馬鈴薯でん粉、かつおエキスを混合した。80℃に加熱後、攪拌機(東京理化機械株式会社製)を用い、回転数800rpm、30分間で攪拌し、煎餅タレA、B、C、D、Eを調整した。攪拌の前後での粘度をB型粘度計にて測定し粘度変化を調べた。得られた煎餅タレを素焼きした煎餅(1枚平均質量10g)に2g塗布し、90℃で30分間乾燥し煎餅A、B、C、D、Eを得た。5種類の煎餅を25℃相対湿度40%で2週間保管して吸湿性、風味、食味、総合評価を評価した。結果を下記表7に示す。(◎:問題なく良好、○:許容される品質、△:やや問題あり、×:問題あり)   Soy sauce, isomaltoligosaccharide syrup (Isomalto 500, Showa Sangyo Co., Ltd., water content 25 mass%), acid-treated potato starch, and bonito extract were mixed at the blending ratios in Table 6 above. After heating to 80 ° C., using a stirrer (manufactured by Tokyo Rika Machinery Co., Ltd.), stirring was performed at a rotation speed of 800 rpm for 30 minutes to adjust rice cracker sauces A, B, C, D, and E. The viscosity before and after stirring was measured with a B-type viscometer to examine the change in viscosity. 2 g of the resulting rice cracker sauce was applied to an unglazed rice cracker (average weight of 10 g per sheet) and dried at 90 ° C. for 30 minutes to obtain rice crackers A, B, C, D, and E. Five kinds of rice crackers were stored at 25 ° C. and 40% relative humidity for 2 weeks to evaluate hygroscopicity, flavor, taste, and overall evaluation. The results are shown in Table 7 below. (◎: Good with no problem, ○: Acceptable quality, △: Somewhat problematic, ×: Problem)

Figure 0005524689
Figure 0005524689

また、煎餅タレCの配合において、イソマルトオリゴ糖シラップの代わりに、砂糖20質量部、みりん6質量部、水6部にて調製した後、煎餅に塗布後乾燥した煎餅も同時に調整し煎餅Fを得た。煎餅Cは風味、照り・つやの点で煎餅Fと同等以上に良好であった。
酸処理馬鈴薯でん粉で調整した煎餅タレの粘度は40℃、800rpmにて30分攪拌前後で殆ど変化がなく、実用上十分なシェア耐性を持っていた。(煎餅タレCの場合、攪拌前650mPa・s、攪拌後640mPa・s)。
酸処理馬鈴薯でん粉はイソマルトオリゴ糖と併用することで粘度の安定性を持ち、且つ醤油・かつお風味や、照り・ツヤに優れた煎餅用調味料塗布剤として利用できる。
In addition, in the blending of rice cracker sauce C, instead of isomaltoligosaccharide syrup, after preparing with 20 parts by weight of sugar, 6 parts by weight of mirin, and 6 parts of water, the dried rice cracker that was applied to the rice cracker and then dried was adjusted at the same time. Obtained. The rice cracker C was as good or better than the rice cracker F in terms of flavor, shine and gloss.
The viscosity of the rice cracker sauce prepared with acid-treated potato starch was almost unchanged before and after stirring for 30 minutes at 40 ° C. and 800 rpm, and had practically sufficient shear resistance. (In the case of rice cracker sauce C, 650 mPa · s before stirring and 640 mPa · s after stirring).
Acid-treated potato starch can be used as a seasoning coating agent for rice crackers having a stable viscosity when used in combination with isomaltoligosaccharide, and excellent in soy sauce, bonito flavor, shine, and gloss.

本発明の調味料用でん粉は、調味料、飲料等の食品分野だけではなく、動物用飼料、化粧品、医薬品等の粉末化基材、添加剤として広く使用することができる。   The starch for seasoning of the present invention can be widely used not only in the food field such as seasonings and beverages, but also as a powdered base material and additives for animal feed, cosmetics, pharmaceuticals and the like.

Claims (5)

馬鈴薯でん粉を主原料とするでん粉原料が、鉱酸によって酸処理された調味料用でん粉であり、
濃度20質量%、回転数60rpmでのB型粘度計により測定した粘度が、
温度30℃では測定不能なレベルの高粘度であって、温度50℃では4000mPa・sより高粘度であって、温度70℃では20〜550mPa・sである調味料用でん粉。
Starch raw material potato starch as the main raw material, Ri seasoning for starch der which is acid-treated with a mineral acid,
Concentration of 20 mass%, the viscosity was measured by B-type viscometer at rotation number 60 rpm,
Starch for seasoning which has a high viscosity that cannot be measured at a temperature of 30 ° C., a viscosity higher than 4000 mPa · s at a temperature of 50 ° C., and 20 to 550 mPa · s at a temperature of 70 ° C.
請求項1記載の調味料用でん粉と、粉末水飴とを含有し、
前記粉末水飴の含有量が30質量%以下である粉末化基材。
Containing the starch for seasoning according to claim 1 and powdered starch syrup,
A powdered base material having a content of the powder syrup of 30% by mass or less.
請求項1記載の調味料用でん粉と、イソマルトオリゴ糖とを含有し、
前記イソマルトオリゴ糖の含有量が10〜50質量%である調味液。
Containing the starch for seasoning according to claim 1 and isomaltoligosaccharide,
The seasoning liquid whose content of the said isomaltoligosaccharide is 10-50 mass%.
馬鈴薯でん粉を主原料とするでん粉原料を溶媒に分散し、でん粉スラリーとする工程の後、
前記でん粉スラリーに、濃度10〜60質量%の鉱酸溶液を添加して、前記でん粉原料を10〜32時間酸処理する工程によって、
濃度20質量%、温度70℃、回転数60rpmでのB型粘度計により測定した粘度が20〜550mPa・sであるでん粉を製造する調味料用でん粉の製造方法。
After the step of dispersing the starch raw material containing potato starch as the main raw material in a solvent to form a starch slurry,
By adding a mineral acid solution having a concentration of 10 to 60% by mass to the starch slurry and acid-treating the starch raw material for 10 to 32 hours ,
A method for producing a starch for seasoning, comprising producing a starch having a viscosity of 20 to 550 mPa · s as measured with a B-type viscometer at a concentration of 20% by mass, a temperature of 70 ° C., and a rotation speed of 60 rpm.
請求項4記載の方法で製造された調味料用でん粉と、調味料成分とを含む原料液を、噴
霧、乾燥して粉末状の調味料を製造する粉末調味料製造方法。
The powder seasoning manufacturing method which sprays and dries the raw material liquid containing the starch for seasonings manufactured by the method of Claim 4, and a seasoning component, and manufactures a powdery seasoning.
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