JP5511404B2 - Soil disease control powder formulation and soil disease control method - Google Patents

Soil disease control powder formulation and soil disease control method Download PDF

Info

Publication number
JP5511404B2
JP5511404B2 JP2010010471A JP2010010471A JP5511404B2 JP 5511404 B2 JP5511404 B2 JP 5511404B2 JP 2010010471 A JP2010010471 A JP 2010010471A JP 2010010471 A JP2010010471 A JP 2010010471A JP 5511404 B2 JP5511404 B2 JP 5511404B2
Authority
JP
Japan
Prior art keywords
acid ester
soil
controlling soil
soil diseases
disease control
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2010010471A
Other languages
Japanese (ja)
Other versions
JP2011148723A (en
Inventor
眞三男 林
丈太郎 来田
司 大西
秀雄 川島
直哉 新井
淳郎 貴志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Agro Inc
Original Assignee
Mitsui Chemicals Agro Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Agro Inc filed Critical Mitsui Chemicals Agro Inc
Priority to JP2010010471A priority Critical patent/JP5511404B2/en
Priority to KR1020100131419A priority patent/KR101310030B1/en
Publication of JP2011148723A publication Critical patent/JP2011148723A/en
Application granted granted Critical
Publication of JP5511404B2 publication Critical patent/JP5511404B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Description

本発明は、土壌病害防除用粉粒製剤および土壌病害防除方法に関する。   The present invention relates to a powder preparation for controlling soil diseases and a method for controlling soil diseases.

従来より、作物を栽培する上での大きな障害の一つに作物の病害がある。病害の中でも特に土壌病原菌によって引き起こされる土壌病害の多くは難防除病害として問題となっており、作物栽培の集団化による連作により、被害がますます拡大する傾向にある。
これら土壌病害防除の薬剤の一つとして、従来から臭化メチル、クロルピクリン等の土壌薫蒸剤が利用されているが、そのガス剤という性質や毒性面から使用時の安全性に特別な注意が必要である。またガスの揮散を防ぐ為にプラスチックフィルムにより予め土壌を被覆する必要があり、作業方法としても非常に煩雑である。また、薬剤処理後は、薬害の発生を防ぐ為にガス抜き作業が必要であり、７〜２０日以上にわたって作物の植え付けができない期間があり、コスト面や生産性の面からも不利な点がある。また殺菌処理後は土壌中の微生物の密度が減少するため、病害の再感染に対して無力であり、一度感染すると病害の発生をより助長する危険性もある。
一方、土壌病害を防除する方法として、粉剤あるいは水和剤を土壌混和、潅注する方法が知られており、例えばＴＰＮ、フルスルファミド、フルアジナム等の粉剤あるいは水和剤が知られている。 Conventionally, crop diseases are one of the major obstacles to crop cultivation. Among the diseases, many of the soil diseases caused by the soil pathogens have become problems as difficult to control diseases, and the damage tends to be further increased by continuous cropping of crop cultivation.
As one of these soil disease control agents, soil fumigants such as methyl bromide and chloropicrin have been conventionally used. However, due to the nature and toxicity of the gas agents, special precautions have been taken with regard to safety during use. is necessary. Moreover, in order to prevent gas volatilization, it is necessary to coat | cover soil previously with a plastic film, and it is also very complicated as an operation method. In addition, after chemical treatment, degassing work is necessary to prevent the occurrence of chemical damage, and there is a period during which crops cannot be planted for 7 to 20 days or more, which is disadvantageous in terms of cost and productivity. is there. Moreover, since the density of microorganisms in the soil decreases after sterilization treatment, it is ineffective against reinfection of diseases, and once infected, there is a risk of further promoting the occurrence of diseases.
On the other hand, as a method for controlling soil diseases, a method in which a powder or wettable powder is mixed and irrigated with soil is known. For example, powder or wettable powder such as TPN, fursulfamide, and fluazinam are known.

粉剤を用いる土壌病害防除方法は、薬剤の均一な散布による薬効のばらつきが少ない反面、薬剤の粉立ちにより、散布時に薬剤が飛散（ドリフト）することによる作業者への薬剤の暴露の問題がある。このようなドリフトを抑えた製剤として、近年、粉剤ＤＬ等が開発されている。
また薬剤のドリフト防止の目的から、より飛散性の少ない剤形として、粒剤よりも粒径の小さい粒径０．０５〜０．３ｍｍの粉粒剤が知られている。このような粉粒剤は、水で希釈して用いる乳剤や水和剤に比べて使用が簡便で、かつ飛散（ドリフト）が抑制される。しかし、粉粒剤は、粉剤と比較して散布された薬剤の均一性が劣る場合があり、これによる効果のバラツキの問題や、製造コストが高いことがあり、実用化されたものが少ないのが現状である。
例えば、土壌病害防除用活性成分を含有する粉粒剤としてはダゾメット粉粒剤が知られているが、有効成分が土壌中で分解後ガス化して土壌を殺菌するという特殊なケースのものである。 The soil disease control method using powders has little variation in medicinal efficacy due to uniform spraying of drugs, but there is a problem of drug exposure to workers due to powder scattering during spraying due to powdering of drugs. . In recent years, powders DL and the like have been developed as preparations that suppress such drift.
In addition, for the purpose of preventing drug drift, a powder having a particle size of 0.05 to 0.3 mm having a particle size smaller than that of the granule is known as a dosage form with less scattering property. Such a granule is easier to use than emulsions and wettable powders diluted with water, and scattering (drift) is suppressed. However, there are cases where the uniformity of the sprayed drug is inferior compared to the powder, and there are few problems in practical use due to the problem of variation in the effect due to this and the manufacturing cost may be high. Is the current situation.
For example, Dazomet powder is known as a powder containing an active ingredient for controlling soil diseases, but it is a special case where the active ingredient decomposes in the soil and gasifies to disinfect the soil. .

また、粉剤の代替製剤として粉粒剤の一種である微粒剤Ｆが知られている。これは、担体に有効成分をバインダーでコーティングする方法で製造されることが多い。しかし、このようにして製造される微粒剤Ｆにおいても、完全にドリフトの問題は解決されているわけではない。
以上述べたようにドリフトの抑制は、薬効のバラツキやコスト高と相反する関係にある為、よりよい粉粒剤の提供が希求されている。 Further, as an alternative preparation of powder, fine granule F, which is a kind of powder, is known. This is often produced by a method in which an active ingredient is coated on a carrier with a binder. However, even in the fine granules F manufactured in this way, the problem of drift is not completely solved.
As described above, since the suppression of drift is in a contradictory relationship with the variation in medicinal effect and the high cost, provision of a better granule is desired.

上記に関連して、土壌病害防除用活性成分であるフルスルファミドを含む混合剤として、粉剤、粒剤、水和剤、フロアブル剤、乳剤が開示されている（例えば、特許文献１、２、３参照）。
また、噴霧造粒法を用いた農薬粒状組成物が知られている（例えば、特許文献４参照）。さらに樹脂酸系界面活性剤を含む農薬用効果増強組成物が知られている（例えば、特許文献５参照）。 In relation to the above, powders, granules, wettable powders, flowables, and emulsions are disclosed as a mixture containing fursulfamide, which is an active ingredient for controlling soil diseases (see, for example, Patent Documents 1, 2, and 3). ).
Moreover, the agricultural chemical granular composition using the spray granulation method is known (for example, refer patent document 4). Furthermore, the effect enhancement composition for agricultural chemicals containing a resin acid type surfactant is known (for example, refer patent document 5).

特開平０３−２２７９０４号公報Japanese Patent Laid-Open No. 03-227904 特開平０８−１９８７１０号公報JP 08-198710 A 特開平０８−１９８７１３号公報Japanese Patent Application Laid-Open No. 08-198713 特開２００７−３０８４８２号公報JP 2007-308482 A 特開平０８−１５１３０２号公報Japanese Patent Laid-Open No. 08-151302

特許文献１〜３には粉粒剤についての形式的な記載はあるものの、具体的な粉粒剤については特に開示はなされていない。また特許文献４の噴霧造粒法では、生産設備が大規模になり、また製造工程も簡便なものとはいえなかった。
本発明は、ドリフトが低減され、かつ薬効のバラツキによる効果不足の発生が抑制される土壌病害防除用粉粒製剤、および該土壌病害防除用粉粒製剤を用いる土壌病害防除方法を提供することを課題とする。 Although Patent Documents 1 to 3 have a formal description of the powder, no specific powder is disclosed. In addition, the spray granulation method of Patent Document 4 has a large production facility and cannot be said to be a simple manufacturing process.
The present invention provides a powder preparation for controlling soil diseases in which drift is reduced and occurrence of insufficient effects due to variations in medicinal effects is suppressed, and a soil disease control method using the powder preparation for controlling soil diseases. Let it be an issue.

前記課題を解決するための具体的手段は以下の通りである。
＜１＞ 土壌病害防除用活性成分と、鉱物担体と、ポリオキシエチレンロジン酸エステルおよびポリオキシエチレンポリオキシプロピレンロジン酸エステルから選ばれる少なくとも１種のポリオキシアルキレン樹脂酸エステルと、を含有し、前記ポリオキシアルキレン樹脂酸エステルの含有率が０．０１〜１重量％である土壌病害防除用粉粒製剤。
＜２＞ 前記ポリオキシアルキレン樹脂酸エステルは、オキシアルキレン基の総付加モル数が樹脂酸１モルに対して平均１〜２０モルである前記＜１＞に記載の土壌病害防除用粉粒製剤。 Specific means for solving the above problems are as follows.
<1> an active ingredient for controlling soil diseases, a mineral carrier, and at least one polyoxyalkylene resin acid ester selected from polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester , A granular preparation for controlling soil diseases, wherein the content of the polyoxyalkylene resin acid ester is 0.01 to 1% by weight .
< 2 > The granule preparation for controlling soil diseases according to <1> , wherein the polyoxyalkylene resin acid ester has an average addition mole number of oxyalkylene groups of 1 to 20 moles per mole of resin acid.

＜３＞ 前記鉱物担体に対する前記ポリオキシアルキレン樹脂酸エステルの含有率が、０．０１〜１．１１重量％である前記＜１＞又は＜２＞に記載の土壌病害防除用粉粒製剤。 < 3 > The granular preparation for controlling soil diseases according to <1> or <2> , wherein the content of the polyoxyalkylene resin acid ester with respect to the mineral carrier is 0.01 to 1.11% by weight.

＜４＞ 更に界面活性剤を含有する前記＜１＞〜＜３＞のいずれか１項に記載の土壌病害防除用粉粒製剤。
＜５＞ 前記界面活性剤が、ポリアルキレングリコールである前記＜４＞に記載の土壌病害防除用粉粒製剤。 < 4 > The powder preparation for controlling soil diseases according to any one of <1> to < 3 >, further containing a surfactant.
< 5 > The granular preparation for controlling soil diseases according to < 4 >, wherein the surfactant is polyalkylene glycol.

＜６＞ 前記土壌病害防除用活性成分が、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリド、３−クロロ−Ｎ−（３−クロロ−５−トリフルオロメチル−２−ピリジル）−α,α,α−トリフルオロ−２,６−ジニトロ−ｐ−トルイジン、および３−（３−ブロモ−６−フルオロ−２−メチルインドール−１−イルスルホニル）−Ｎ，Ｎ−ジメチル−１，２，４−トリアゾール−１−スルホンアミドから選ばれる少なくとも１種である前記＜１＞〜＜５＞のいずれか１項に記載の土壌病害防除用粉粒製剤。
＜７＞ 前記土壌病害防除用活性成分が、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリドである前記＜１＞〜＜６＞のいずれか１項に記載の土壌病害防除用粉粒製剤。
＜８＞ 鉱物担体およびポリオキシエチレンロジン酸エステルおよびポリオキシエチレンポリオキシプロピレンロジン酸エステルから選ばれる少なくとも１種のポリオキシアルキレン樹脂酸エステルを混合して、結合剤含有鉱物担体を得る第１の工程と、前記結合剤含有鉱物担体および土壌病害防除用活性成分を混合して、土壌病害防除用粉粒製剤を得る第２の工程と、を含む、前記ポリオキシアルキレン樹脂酸エステルの含有率が０．０１〜１重量％である土壌病害防除用粉粒製剤の製造方法。
＜９＞ 前記＜１＞〜＜７＞のいずれか１項に記載の土壌病害防除用粉粒製剤を、土壌に施用することを含む土壌病害防除方法。 < 6 > The active ingredient for controlling soil diseases is 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide, 3-chloro-N- (3-chloro- 5-trifluoromethyl-2-pyridyl) -α, α, α-trifluoro-2,6-dinitro-p-toluidine, and 3- (3-bromo-6-fluoro-2-methylindol-1-yl The powder for controlling soil diseases according to any one of <1> to < 5 >, which is at least one selected from (sulfonyl) -N, N-dimethyl-1,2,4-triazole-1-sulfonamide. Granule formulation.
< 7 > Any of <1> to < 6 >, wherein the active ingredient for controlling soil diseases is 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide. 2. A granular preparation for controlling soil diseases according to claim 1.
< 8 > A first carrier for obtaining a binder-containing mineral carrier by mixing a mineral carrier and at least one polyoxyalkylene resin acid ester selected from polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester . A content of the polyoxyalkylene resin acid ester comprising a step and a second step of mixing the binder-containing mineral carrier and the active ingredient for controlling soil diseases to obtain a powder preparation for controlling soil diseases The manufacturing method of the granular preparation for soil disease control which is 0.01 to 1 weight% .
< 9 > A soil disease control method comprising applying the soil disease control powder preparation according to any one of <1> to < 7 > to soil.

本発明によれば、ドリフトが低減され、かつ薬効のバラツキによる効果不足の発生が抑制される土壌病害防除用粉粒製剤、および該土壌病害防除用粉粒製剤を用いる土壌病害防除方法を提供することができる。   According to the present invention, there are provided a soil disease control powder formulation in which drift is reduced and occurrence of insufficient effects due to variation in medicinal effects is suppressed, and a soil disease control method using the soil disease control powder formulation. be able to.

本発明の土壌病害防除用粉粒製剤は、土壌病害防除用活性成分の少なくとも１種と、鉱物担体の少なくとも１種と、ポリオキシアルキレン樹脂酸エステルの少なくとも１種と、を含有する。
かかる構成であることにより、ドリフトが低減され、かつ薬効のバラツキによる効果不足の発生が抑制される。さらに土壌病害防除用活性成分が、粒径の小さい（例えば、４０μｍ以下）ものを含んでいても、粒径の小さい活性成分が鉱物担体から剥離して粉立ちが発生することが抑制される。 The granular preparation for controlling soil diseases of the present invention contains at least one active ingredient for controlling soil diseases, at least one mineral carrier, and at least one polyoxyalkylene resin acid ester.
With such a configuration, drift is reduced, and occurrence of insufficient effects due to variations in medicinal effects is suppressed. Furthermore, even if the active ingredient for controlling soil diseases contains an ingredient having a small particle size (for example, 40 μm or less), the active ingredient having a small particle size is prevented from peeling off from the mineral carrier and causing powdering.

（土壌病害防除用活性成分）
本発明に用いられる土壌病害防除用活性成分としては、土壌病害を防除可能な活性を有し、鉱物担体に担持可能なものであれば特に制限はない。例えば、有機塩素系化合物、スルホンアミド系化合物、シアノイミダゾール系化合物、フェニルピリジン系化合物、スルファモイルトリアゾール骨格を有する殺菌剤等を挙げることができる。
また本発明における土壌病害としては、土壌中に存在する細菌等に由来する病害であれば特に制限はない。具体的には例えば、根こぶ病、立枯病、疫病等を挙げることができる。 (Active ingredient for controlling soil diseases)
The active ingredient for controlling soil diseases used in the present invention is not particularly limited as long as it has an activity capable of controlling soil diseases and can be supported on a mineral carrier. For example, organochlorine compounds, sulfonamide compounds, cyanoimidazole compounds, phenylpyridine compounds, fungicides having a sulfamoyltriazole skeleton, and the like can be given.
In addition, the soil disease in the present invention is not particularly limited as long as it is a disease derived from bacteria or the like present in the soil. Specific examples include root-knot disease, withering disease, and plague.

上記のような土壌病害を防除可能な活性成分として、具体的には、ＴＰＮ（化合物名：テトラクロロイソフタロニトリル）、フルスルファミド（化合物名：２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリド）、シアゾファミド（化合物名：４−クロロ−２−シアノ−Ｎ，Ｎ−ジメチル−５−ｐ−トリルイミダゾール−１−スルホンアミド）、フルアジナム（化合物名：３−クロロ−Ｎ−（３−クロロ−５−トリフルオロメチル−２−ピリジル）−α,α,α−トリフルオロ−２,６−ジニトロ−ｐ−トルイジン）、アミスルブロム（化合物名：３−（３−ブロモ−６−フルオロ−２−メチルインドール−１−イルスルホニル）−Ｎ，Ｎ−ジメチル−１，２，４−トリアゾール−１−スルホンアミド）、などが挙げられる。
これらは１種単独でも、２種以上を組み合わせて用いてもよい。 Specific examples of active ingredients capable of controlling the above soil diseases include TPN (compound name: tetrachloroisophthalonitrile) and fursulfamide (compound name: 2 ′, 4-dichloro-α, α, α-tri Fluoro-4′-nitro-m-toluenesulfonanilide), cyazofamide (compound name: 4-chloro-2-cyano-N, N-dimethyl-5-p-tolylimidazole-1-sulfonamide), fluazinam (compound name) : 3-chloro-N- (3-chloro-5-trifluoromethyl-2-pyridyl) -α, α, α-trifluoro-2,6-dinitro-p-toluidine), amisulbrom (compound name: 3- (3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl) -N, N-dimethyl-1,2,4-triazole-1-sulfonamide), etc. Can be mentioned.
These may be used alone or in combination of two or more.

中でも、土壌病害防除活性の観点から、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリド、３−クロロ−Ｎ−（３−クロロ−５−トリフルオロメチル−２−ピリジル）−α,α,α−トリフルオロ−２,６−ジニトロ−ｐ−トルイジン、および３−（３−ブロモ−６−フルオロ−２−メチルインドール−１−イルスルホニル）−Ｎ，Ｎ−ジメチル−１，２，４−トリアゾール−１−スルホンアミドから選ばれる少なくとも１種であることが好ましく、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリドであることがより好ましい。   Among them, from the viewpoint of soil disease control activity, 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide, 3-chloro-N- (3-chloro-5- Trifluoromethyl-2-pyridyl) -α, α, α-trifluoro-2,6-dinitro-p-toluidine, and 3- (3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl) -N, N-dimethyl-1,2,4-triazole-1-sulfonamide is preferable, and 2 ′, 4-dichloro-α, α, α-trifluoro-4′- is preferable. More preferred is nitro-m-toluenesulfonanilide.

前記土壌病害防除用活性成分の含有量としては特に制限はないが、土壌病害防除活性の観点から、０．１〜１．０重量％であることが好ましく、０．１〜０．５重量％であることがより好ましい。
特に、土壌病害防除用活性成分が、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリドの場合は、０．１〜０．５重量％であることが好ましい。 Although there is no restriction | limiting in particular as content of the said active ingredient for soil disease control, From a viewpoint of soil disease control activity, it is preferable that it is 0.1 to 1.0 weight%, 0.1 to 0.5 weight% It is more preferable that
In particular, when the active ingredient for controlling soil diseases is 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide, it is 0.1 to 0.5% by weight. Preferably there is.

また本発明の土壌病害防除用粉粒製剤は、同時に発生する他の病害を防除するため、上記スルホンアミド系化合物やフェニルピリジン系化合物等の本発明に好適に用いられる化合物とは、異なる土壌病害防除効果を有する殺菌剤等をさらに含んで製剤化されていてもよい。そのような殺菌剤等としては、例えば、イソキサゾール、メプロニル、フルトラニル、ペンシクロン、リゾレックス、バリダマイシン等が挙げられる。
これら機能の異なる殺菌剤を併用することによって、一般に単独で使用される場合の含有量以下での使用が可能になる場合がある。これらの殺菌剤の含有量は殺菌剤の種類によって適宜選択できるが、例えば０．１〜３．０重量％とすることができる。 In addition, the granular preparation for controlling soil diseases of the present invention is different from the compounds suitably used in the present invention such as the sulfonamide compounds and phenylpyridine compounds in order to control other diseases occurring at the same time. It may be formulated by further containing a fungicide having a controlling effect. Examples of such bactericides include isoxazole, mepronil, flutolanil, pencyclon, lysolex, validamycin and the like.
By using these fungicides having different functions in combination, it may be possible to use at a content lower than that generally used alone. The content of these bactericides can be appropriately selected depending on the type of bactericides, and can be, for example, 0.1 to 3.0% by weight.

（鉱物担体）
前記鉱物担体としては、土壌病害防除用活性成分を担持可能なものであれば特に制限はなく、農薬組成物に通常用いられる鉱物担体を適宜選択して用いることができる。具体的には例えば、アタパルジャイト、珪砂、焼成珪藻土、ゼオライト、セピオライト、炭酸カルシウム、ベントナイト、タルクなどが挙げられる。中でも、ゼオライト、珪砂、炭酸カルシウムが好ましく、炭酸カルシウムがより好ましい。
これら鉱物担体は単独で使用してもよく、また、複数種を併用してもよい。 (Mineral carrier)
The mineral carrier is not particularly limited as long as it can carry an active ingredient for controlling soil diseases, and a mineral carrier usually used in agricultural chemical compositions can be appropriately selected and used. Specific examples include attapulgite, silica sand, calcined diatomaceous earth, zeolite, sepiolite, calcium carbonate, bentonite, and talc. Among these, zeolite, silica sand, and calcium carbonate are preferable, and calcium carbonate is more preferable.
These mineral carriers may be used alone or in combination.

前記鉱物担体の粒径としては、土壌病害防除用活性成分を担持可能であれば特に制限はない。例えば、０.０１〜０．７ｍｍとすることができ、０．０３〜０．６ｍｍであることが好ましく、０．０６〜０．４５ｍｍであることがより好ましい。
鉱物担体の粒径が前記範囲内であることで、飛散性をより効果的に抑制することができ、また、より良好な薬効の均一性を達成することができる。
尚、０．０５〜０．３ｍｍの粒径は、我が国においては粉粒剤に分類される。 The particle size of the mineral carrier is not particularly limited as long as it can carry an active ingredient for controlling soil diseases. For example, it can be set to 0.01 to 0.7 mm, preferably 0.03 to 0.6 mm, and more preferably 0.06 to 0.45 mm.
When the particle size of the mineral carrier is within the above range, the scattering property can be more effectively suppressed, and better uniformity of medicinal effect can be achieved.
In addition, the particle size of 0.05 to 0.3 mm is classified as a granule in Japan.

前記鉱物担体の含有量としては、土壌病害防除用粉粒製剤の全重量に対して、例えば、９０〜９９．５重量％とすることができ、９５〜９９重量％であることが好ましい。   As content of the said mineral carrier, it can be 90-99.5 weight% with respect to the total weight of the granular preparation for soil disease control, for example, and it is preferable that it is 95-99 weight%.

（ポリオキシアルキレン樹脂酸エステル）
本発明の土壌病害防除用粉粒製剤は、ポリオキシアルキレン樹脂酸エステルの少なくとも１種を含む。前記ポリオキシアルキレン樹脂酸エステルは、後述するように、例えば、前記鉱物担体上に前記土壌病害防除用活性成分を付着させる結合剤として作用すると考えられる。
これにより、本発明の土壌病害防除用粉粒製剤を土壌に施用する前は、活性成分が鉱物担体から剥離して粉立ちが発生することを抑制すると共に、土壌病害防除用粉粒製剤が土壌に施用された後は、土壌との混和などの物理的な刺激により容易に鉱物担体から剥離して、土壌に均一に混和可能となり、薬効の均一性に優れる。 (Polyoxyalkylene resin acid ester)
The granular preparation for controlling soil diseases of the present invention contains at least one polyoxyalkylene resin acid ester. As will be described later, the polyoxyalkylene resin acid ester is considered to act as a binder for attaching the active ingredient for controlling soil diseases onto the mineral carrier, for example.
Thereby, before applying the granular preparation for soil disease control of the present invention to the soil, the active ingredient is prevented from peeling off from the mineral carrier and the occurrence of powdering is suppressed, and the granular preparation for soil disease control is the soil. After being applied, it is easily peeled off from the mineral carrier by physical stimulation such as mixing with the soil, and can be mixed with the soil uniformly.

前記ポリオキシアルキレン樹脂酸エステルは、樹脂酸に酸化アルキレンを付加して製造することができる。具体的には、樹脂酸に酸化エチレンを付加して得られるポリオキシエチレン樹脂酸エステル、樹脂酸に酸化プロピレンを付加して得られるポリオキシプロピレン樹脂酸エステル、樹脂酸に酸化エチレンと酸化プロピレンを付加して得られるポリオキシエチレンポリオキシプロピレン樹脂酸エステルなどが挙げられる。
本発明においては、粉立ち抑制と薬効の均一性の観点から、ポリオキシエチレン樹脂酸エステルおよびポリオキシエチレンポリオキシプロピレン樹脂酸エステルから選ばれる少なくとも１種であることが好ましい。 The polyoxyalkylene resin acid ester can be produced by adding alkylene oxide to a resin acid. Specifically, polyoxyethylene resin acid ester obtained by adding ethylene oxide to resin acid, polyoxypropylene resin acid ester obtained by adding propylene oxide to resin acid, ethylene oxide and propylene oxide to resin acid Examples thereof include polyoxyethylene polyoxypropylene resin acid ester obtained by addition.
In the present invention, at least one selected from a polyoxyethylene resin acid ester and a polyoxyethylene polyoxypropylene resin acid ester is preferable from the viewpoints of powdering suppression and uniformity of medicinal effects.

前記樹脂酸としては、ロジン酸のようなジテルペン酸や、安息香酸やケイ皮酸などの芳香族カルボン酸とが挙げられる。本発明においては粉立ち抑制と薬効の均一性の観点から、ロジン酸であることが好ましい。
ロジン酸は、マツ属植物に含まれているモノカルボン酸系のジテルペン酸であり、アビエチン酸、ピマル酸等を主成分として含むものである。 Examples of the resin acid include diterpenic acid such as rosin acid, and aromatic carboxylic acid such as benzoic acid and cinnamic acid. In the present invention, rosin acid is preferred from the standpoint of powdering suppression and uniformity of drug efficacy.
Rosin acid is a monocarboxylic acid-based diterpenic acid contained in Pinus genus plants, and contains abietic acid, pimaric acid and the like as main components.

本発明においてポリオキシアルキレン樹脂酸エステルは、ポリオキシアルキレンロジン酸エステルであることが好ましい。ポリオキシアルキレンロジン酸エステルは、例えば、ロジン酸に酸化アルキレンを付加することによりポリオキシアルキレンロジン酸エステルを製造することができる。具体的には、ロジン酸に酸化エチレンを付加して得られるポリオキシエチレンロジン酸エステル、酸化プロピレンを付加して得られるポリオキシプロピレンロジン酸エステル、酸化エチレンと酸化プロピレンを付加して得られるポリオキシエチレンポリオキシプロピレンロジン酸エステルなどが挙げられる。
これらポリオキシアルキレン樹脂酸エステルの中でも、ポリオキシエチレンロジン酸エステル、ポリオキシエチレンポリオキシプロピレンロジン酸エステルが好ましく、更に、ポリオキシエチレンロジン酸エステル、ポリオキシエチレンポリオキシプロピレンロジン酸エステルがより好ましい。
尚、ポリオキシアルキレンロジン酸エステルは、工業的にも容易に入手可能であり、例えば、ＤＲＡシリーズ（東邦化学工業（株）製品）などが挙げられる。 In the present invention, the polyoxyalkylene resin acid ester is preferably a polyoxyalkylene rosin acid ester. For example, polyoxyalkylene rosin acid ester can be produced by adding alkylene oxide to rosin acid. Specifically, polyoxyethylene rosin acid ester obtained by adding ethylene oxide to rosin acid, polyoxypropylene rosin acid ester obtained by adding propylene oxide, and polyoxyethylene rosin acid ester obtained by adding ethylene oxide and propylene oxide. Examples thereof include oxyethylene polyoxypropylene rosin acid ester.
Among these polyoxyalkylene resin acid esters, polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester are preferable, and polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester are more preferable. .
The polyoxyalkylene rosin acid ester is easily available industrially, and examples thereof include the DRA series (product of Toho Chemical Industry Co., Ltd.).

前記ポリオキシアルキレン樹脂酸エステルにおいて、樹脂酸に対する酸化アルキレンの付加量としては特に制限はないが、粉立ち抑制と薬効の均一性の観点から、樹脂酸１モルに対して酸化アルキレンを１〜２０モル付加させたポリオキシアルキレン樹脂酸エステルが好ましく、樹脂酸１モルに対して酸化アルキレンを３〜１８付加させたポリオキシアルキレン樹脂酸エステルがより好ましい。   In the polyoxyalkylene resin acid ester, the amount of alkylene oxide added to the resin acid is not particularly limited, but from the viewpoint of powdering suppression and uniformity of medicinal effect, 1 to 20 alkylene oxides per 1 mol of resin acid. A polyoxyalkylene resin acid ester having a mole added thereto is preferable, and a polyoxyalkylene resin acid ester having 3 to 18 alkylene oxide added to 1 mol of a resin acid is more preferable.

ポリオキシアルキレン樹脂酸エステルの含有量は、付加した酸化アルキレンの種類に関係なく、土壌病害防除用粉粒製剤の全重量に対して０．０１〜１重量％の範囲の含有量であることが好ましく、０．０５〜０．８重量％であることがより好ましい。含有量が０．０１重量％以上であることで、使用時の飛散（ドリフト）抑制効果がより効果的に得られる。また、１重量％以下であることで、土壌混和後における活性成分の剥離がより良好になり、より効果的に所望の生物効果が向上する。   The content of the polyoxyalkylene resin acid ester may be a content in the range of 0.01 to 1% by weight based on the total weight of the powder preparation for controlling soil diseases, regardless of the type of added alkylene oxide. Preferably, it is 0.05 to 0.8% by weight. When the content is 0.01% by weight or more, the scattering (drift) suppression effect during use can be more effectively obtained. In addition, when the content is 1% by weight or less, exfoliation of the active ingredient after mixing with soil becomes better, and a desired biological effect is more effectively improved.

また本発明においては、前記鉱物担体に対するポリオキシアルキレン樹脂酸エステルの含有比率が０．０１〜１．１１重量％であることもまた好ましく、０．０５〜０．８９重量％であることがより好ましい。配合量が０．０１重量％以上であることで、使用時の飛散（ドリフト）抑制効果がより効果的に得られる。また、１．１１重量％以下であることで、土壌混和後における活性成分の剥離がより良好になり、生物効果の均一性がより向上する。   In the present invention, the content ratio of the polyoxyalkylene resin acid ester to the mineral carrier is also preferably 0.01 to 1.11% by weight, more preferably 0.05 to 0.89% by weight. preferable. When the blending amount is 0.01% by weight or more, the scattering (drift) suppression effect during use can be obtained more effectively. Moreover, by being 1.11 weight% or less, peeling of the active ingredient after soil mixing becomes better, and the uniformity of the biological effect is further improved.

本発明の土壌病害防除用粉粒製剤は、ポリオキシアルキレン樹脂酸エステルとして、ポリオキシエチレン樹脂酸エステルおよびポリオキシエチレンポリオキシプロピレン樹脂酸エステルから選ばれる少なくとも１種を、０．０１〜１重量％の範囲で含有することが好ましく、ポリオキシエチレンロジン酸エステルおよびポリオキシエチレンポリオキシプロピレンロジン酸エステルから選ばれる少なくとも１種を、０．０５〜０．８重量％の範囲で含有することがより好ましい。   In the granular preparation for controlling soil diseases of the present invention, 0.01 to 1 weight of at least one selected from polyoxyethylene resin acid ester and polyoxyethylene polyoxypropylene resin acid ester is used as the polyoxyalkylene resin acid ester. %, Preferably containing at least one selected from polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester in the range of 0.05 to 0.8% by weight. More preferred.

（その他の成分）
本発明の土壌病害防除用粉粒製剤は、前記土壌病害防除用活性成分、結合剤および鉱物担体に加えて、必要に応じてその他の成分をさらに含むことができる。その他の成分としては、一般的に農薬用助剤として公知の成分を適宜選択して含有することができる。その他の成分としての農薬用助剤は、例えば、結合剤の粘度、製剤の色、ｐＨ、鉱物担体微粉の凝集、固結防止、光安定性、施用後の土壌中での拡散性、浸透性などの各種効果を付与または調整する目的で使用することが出来る。 (Other ingredients)
The granular preparation for controlling soil diseases of the present invention may further contain other components as necessary in addition to the active component for controlling soil diseases, the binder and the mineral carrier. As other components, generally known components as agricultural chemical aids can be appropriately selected and contained. Agricultural aids as other components include, for example, binder viscosity, formulation color, pH, aggregation of mineral carrier fine powder, anti-caking, light stability, diffusibility in soil after application, permeability It can be used for the purpose of imparting or adjusting various effects such as.

その他の成分として具体的には、例えば、水、グリセリン、エチレングリコール、プロピレングリコール、ポリエチレングリコール、ポリプロピレングリコール、植物油（大豆油、綿実油など）、鉱物油（流動パラフィンなど）が挙げられ、その他、着色剤、ｐＨ調整剤、凝集剤（ドリレスＡ、ドリレスＢ、ドリレスＣなど）、鉱物微粉（多孔質珪酸など）、紫外線吸収剤、界面活性剤などを必要に応じ使用することができる。   Specific examples of other components include water, glycerin, ethylene glycol, propylene glycol, polyethylene glycol, polypropylene glycol, vegetable oil (soybean oil, cottonseed oil, etc.), mineral oil (liquid paraffin, etc.), and other coloring An agent, a pH adjuster, a flocculant (such as Doreless A, Doreless B, and Doreless C), mineral fine powder (such as porous silicic acid), an ultraviolet absorber, and a surfactant can be used as necessary.

−界面活性剤−
本発明の土壌病害防除用粉粒製剤は、界面活性剤の少なくとも１種をさらに含むことが好ましい。これにより生物効果の均一性がより向上し、また本発明の土壌病害防除用粉粒製剤をより効率的に製造することができる。
界面活性剤としては特に制限はなく、例えば、非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性剤、シリコーン系界面活性剤、フッ素系界面活性剤が挙げられる。中でも非イオン性界面活性剤を好適に用いることができる。非イオン性界面活性剤としては、ポリアルキレングリコール型界面活性剤、多価アルコール型界面活性剤、アセチレン系界面活性剤が挙げられるが、粉立ち抑制、効果の均一性および製造効率の観点から、ポリアルキレングリコールであることが好ましく、ポリエチレングリコールであることがより好ましい。 -Surfactant-
It is preferable that the granular preparation for controlling soil diseases of the present invention further contains at least one surfactant. Thereby, the uniformity of the biological effect is further improved, and the powder preparation for controlling soil diseases of the present invention can be produced more efficiently.
The surfactant is not particularly limited, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, silicone surfactants, and fluorine surfactants. Can be mentioned. Among these, nonionic surfactants can be preferably used. Examples of nonionic surfactants include polyalkylene glycol surfactants, polyhydric alcohol surfactants, and acetylene surfactants. From the viewpoints of dusting suppression, uniformity of effects, and production efficiency, Polyalkylene glycol is preferable, and polyethylene glycol is more preferable.

前記ポリアルキレングリコール型界面活性剤の分子量としては特に制限はないが、粉立ち抑制、効果の均一性および製造効率の観点から、重量平均分子量として２００〜６００であることが好ましく、３００〜５００であることがより好ましい。
さらにポリアルキレングリコール型界面活性剤の含有量としては、土壌病害防除用粉粒製剤の全重量に対して、０．０１〜1重量％であることが好ましく、０．０５〜０．８重量％であることがより好ましい。 Although there is no restriction | limiting in particular as molecular weight of the said polyalkylene glycol type surfactant, From a viewpoint of powdering suppression, the uniformity of an effect, and a manufacturing efficiency, it is preferable that it is 200-600 as a weight average molecular weight, and is 300-500. More preferably.
Furthermore, the content of the polyalkylene glycol surfactant is preferably 0.01 to 1% by weight, preferably 0.05 to 0.8% by weight, based on the total weight of the powder preparation for controlling soil diseases. It is more preferable that

本発明においては、界面活性剤として、重量平均分子量が２００〜６００であるポリアルキレングリコール型界面活性剤を、土壌病害防除用粉粒製剤の全重量に対して０．０１〜１重量％含むことが好ましく、重量平均分子量が３００〜５００であるポリエチレングリコールを、土壌病害防除用粉粒製剤の全重量に対して０．０５〜０．８重量％含むことがより好ましい。   In the present invention, as the surfactant, a polyalkylene glycol type surfactant having a weight average molecular weight of 200 to 600 is contained in an amount of 0.01 to 1% by weight based on the total weight of the granular preparation for controlling soil diseases. It is more preferable that 0.05 to 0.8% by weight of polyethylene glycol having a weight average molecular weight of 300 to 500 is included with respect to the total weight of the powder preparation for controlling soil diseases.

（製造方法）
本発明の土壌病害防除用粉粒製剤の製造方法としては、鉱物担体にポリオキシアルキレン樹脂酸エステルおよび土壌病害防除用活性成分を担持することができれば、特に制限はない。鉱物担体およびポリオキシアルキレン樹脂酸エステルを混合して、結合剤含有鉱物担体を得る第１の工程と、前記結合剤含有鉱物担体および土壌病害防除用活性成分を混合して、土壌病害防除用粉粒製剤を得る第２の工程とを含む土壌病害防除用粉粒製剤の製造方法であることが好ましい。
かかる製造方法で土壌病害防除用粉粒製剤を製造することにより、例えば、鉱物担体表面に、ポリオキシアルキレン樹脂酸エステルおよび土壌病害防除用活性成分が付着することで、土壌と混合する前における粉立ちを抑制し、さらに土壌と混合した後は土壌病害防除用活性成分が鉱物担体から剥離して、土壌中により均一に拡散する。 (Production method)
The method for producing a granular preparation for controlling soil diseases according to the present invention is not particularly limited as long as a polyoxyalkylene resin acid ester and an active ingredient for controlling soil diseases can be supported on a mineral carrier. A first step of mixing a mineral carrier and a polyoxyalkylene resin acid ester to obtain a binder-containing mineral carrier, and mixing the binder-containing mineral carrier and an active ingredient for controlling soil diseases to produce a powder for controlling soil diseases It is preferable that it is a manufacturing method of the granular preparation for soil disease control including the 2nd process of obtaining a granular preparation.
By producing a powder preparation for controlling soil diseases by such a production method, for example, a powder before mixing with soil by attaching a polyoxyalkylene resin acid ester and an active ingredient for controlling soil diseases to the surface of a mineral carrier. After suppressing the standing and further mixing with the soil, the active ingredient for controlling soil diseases peels off from the mineral carrier and diffuses more uniformly in the soil.

前記第１の工程において、ポリオキシアルキレン樹脂酸エステルは、鉱物担体と直接混合してもよく、またポリオキシアルキレン樹脂酸エステルと界面活性剤（好ましくは、ポリエチレングリコール）等とをあらかじめ混合して得られる結合剤プレミックスと、鉱物担体とを混合してもよい。本発明においては、製造効率の観点から、あらかじめ調製した結合剤プレミックスと鉱物担体とを混合することが好ましい。
本工程においてポリオキシアルキレン樹脂酸エステルは、例えば、鉱物担体表面に付着する。鉱物担体表面に付着したポリオキシアルキレン樹脂酸エステルは、土壌病害防除用活性成分をより効率的に鉱物担体に付着することができる。 In the first step, the polyoxyalkylene resin acid ester may be mixed directly with the mineral carrier, or the polyoxyalkylene resin acid ester and a surfactant (preferably polyethylene glycol) are mixed in advance. The resulting binder premix and a mineral carrier may be mixed. In the present invention, from the viewpoint of production efficiency, it is preferable to mix a binder premix prepared in advance and a mineral carrier.
In this step, the polyoxyalkylene resin acid ester adheres to the surface of the mineral carrier, for example. The polyoxyalkylene resin acid ester adhering to the surface of the mineral carrier can more efficiently adhere the active ingredient for controlling soil diseases to the mineral carrier.

前記結合剤プレミックスは、ポリオキシアルキレン樹脂酸エステルの少なくとも１種を含み、必要に応じてその他の成分をさらに含んで構成される。結合剤プレミックスに含まれるその他の成分としては、例えば、界面活性剤、有機溶剤等を挙げることができる。
結合剤プレミックスに含まれる界面活性剤は、既述の界面活性剤と同義であり、好ましい態様も同様である。 The binder premix includes at least one polyoxyalkylene resin acid ester, and further includes other components as necessary. Examples of other components contained in the binder premix include surfactants and organic solvents.
The surfactant contained in the binder premix is synonymous with the surfactant described above, and the preferred embodiment is also the same.

ポリオキシアルキレン樹脂酸エステルおよび鉱物担体を混合する方法としては通常用いられる一般的な混合機を特に制限なく用いることができる。具体的には、例えば、リボンミキサー、ナウターミキサー、ヘンシェルミキサーなどの各種混合翼を有する混合機を用いて混合することができる。   As a method of mixing the polyoxyalkylene resin acid ester and the mineral carrier, a commonly used general mixer can be used without particular limitation. Specifically, it can mix using the mixer which has various mixing blades, such as a ribbon mixer, a Nauter mixer, a Henschel mixer, for example.

前記第２の工程においては、第１の工程で得られた結合剤含有鉱物担体と、土壌病害防除用活性成分とを混合して、土壌病害防除用粉粒製剤を製造する。土壌病害防除用活性成分は結合剤含有鉱物担体と直接混合してもよく、また、あらかじめ調製した土壌病害防除用活性成分を含む土壌病害防除用活性成分プレミックスを結合剤含有鉱物担体と混合してもよい。   In the second step, the binder-containing mineral carrier obtained in the first step and the soil disease control active ingredient are mixed to produce a soil disease control powder formulation. The active ingredient for controlling soil diseases may be mixed directly with a binder-containing mineral carrier, or an active ingredient premix for controlling soil diseases containing a pre-prepared active agent for controlling soil diseases may be mixed with a mineral carrier containing a binder. May be.

前記土壌病害防除用活性成分プレミックスは、土壌病害防除用活性成分の少なくとも１種を含み、必要に応じてその他の成分をさらに含んで構成される。土壌病害防除用活性成分プレミックスに含まれるその他の成分としては、例えば、炭酸カルシウム、ホワイトカーボン等を挙げることができる。   The soil disease control active ingredient premix contains at least one kind of soil disease control active ingredient, and further contains other components as necessary. Examples of other components contained in the active ingredient premix for controlling soil diseases include calcium carbonate and white carbon.

結合剤含有鉱物担体と、土壌病害防除用活性成分とを混合する方法としては、前記第１の工程における混合方法と同様である。
また本発明においては、前記第１の工程と第２の工程を別々の混合手段を用いて順次行っても、同一の混合手段を用いて連続して行ってもよい。
また前記土壌病害防除用粉粒製剤の製造方法は、必要に応じてその他の工程をさらに含むことができる。前記その他の工程としては、例えば、加熱工程、冷却工程、乾燥工程等を挙げることができる。 The method for mixing the binder-containing mineral carrier and the active ingredient for controlling soil diseases is the same as the mixing method in the first step.
In the present invention, the first step and the second step may be performed sequentially using separate mixing means or may be performed continuously using the same mixing means.
Moreover, the manufacturing method of the said granular preparation for soil disease control can further include another process as needed. As said other process, a heating process, a cooling process, a drying process etc. can be mentioned, for example.

（土壌病害防除方法）
本発明の土壌病害防除方法は、前記土壌病害防除用粉粒製剤を土壌に施用することを含む。前記土壌病害防除用粉粒製剤を用いることで、施用における薬剤の飛散（ドリフト）を抑制することができ、さらには、均一性に優れる土壌病害防除効果を達成することができる。
土壌病害防除用粉粒製剤を土壌に施用する方法としては、通常用いられる粉粒剤の施用方法を特に制限なく適用することができる。具体的には、手撒きあるいは専用処理機を用いて前記土壌病害防除用粉粒製剤を土壌表面に散布後、土壌と混和する等の操作により施用することができるが、処理の方法はこれらに限定されるわけではない。 (Soil disease control method)
The soil disease control method of the present invention includes applying the soil disease control powder preparation to soil. By using the above-mentioned powder preparation for controlling soil diseases, scattering (drift) of the drug in application can be suppressed, and furthermore, the soil disease controlling effect excellent in uniformity can be achieved.
As a method of applying the powder preparation for controlling soil diseases to soil, a commonly used method of applying a powder can be applied without particular limitation. Specifically, the powder preparation for controlling soil diseases can be applied to the surface of the soil by hand or using a dedicated processing machine, and then applied by operations such as mixing with the soil. It is not limited.

本発明の土壌病害防除用粉粒製剤により、作業者への薬剤の暴露を低減し、また、目的環境以外への薬剤の飛散を低減させ、更に効果が安定した粉粒剤を提供することができる。また本発明の土壌病害防除用粉粒製剤においては、浸透移行性あるいは揮発性を有していない活性成分を用いた場合でも、土壌中における活性成分の濃度にバラツキが抑制され、均一な土壌病害防除効果を達成することができる。   The powder preparation for controlling soil diseases according to the present invention can reduce the exposure of the drug to the worker, reduce the scattering of the drug to other than the target environment, and provide a granule having a more stable effect. it can. Moreover, in the granular preparation for controlling soil diseases of the present invention, even when an active ingredient having no osmotic transfer property or volatility is used, variation in the concentration of the active ingredient in the soil is suppressed, and uniform soil disease A control effect can be achieved.

さらに本発明の土壌病害防除用粉粒製剤は、散布後の薬剤の土壌拡散性が良好で、濃度のバラツキによる防除効果の不安定性が抑制される。また処理後の降雨、土壌水分といった環境要因による防除効果の変動が抑制され、少量の薬剤量でも効果完成までの日数が低減される。さらに水で希釈せず直接施用することができるため、薬液を調製する手間や、専用の散布器具を必要とせず、水利の悪い場所でも使用することが可能である。   Furthermore, the powder preparation for soil disease control of the present invention has good soil diffusibility of the drug after spraying, and the instability of the control effect due to concentration variation is suppressed. In addition, fluctuations in the control effect due to environmental factors such as rain after treatment and soil moisture are suppressed, and the number of days until the effect is completed is reduced even with a small amount of drug. Furthermore, since it can be applied directly without diluting with water, it does not require the trouble of preparing a chemical solution or a special spraying device, and can be used even in places with poor water use.

以下、本発明を実施例により具体的に説明するが、本発明はこれらの実施例に限定されるものではない。尚、特に断りのない限り、「部」及び「％」は質量基準である。   EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, “part” and “%” are based on mass.

（製剤例１）フルスルファミド０．３％粉粒製剤の調製
ＫＥＮＭＩＸ ｃｈｅｆ（株式会社愛工舎工業所製）に、鉱物担体として炭酸カルシウム（Ａタンカル、粒径：５００μｍ以上０％、１５０μｍ以下１０．０％以下、旭鉱末株式会社製）１３３４．２５ｇおよび炭酸カルシウム（Ｋ−２５０、粒径：４２５μｍ以上１．０％以下、４５μｍ以下１９％以下、旭鉱末株式会社製）１５０ｇを仕込み、２分間混合した。
ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）３５．８１ｇ、ポリエチレングリコール（ＰＥＧ−４００、三洋化成工業株式会社製）６２．５６ｇおよびポリオキシプロピレンアルキルエーテル燐酸エステル（ドリレスＡ、日本乳化剤株式会社製）１．６３ｇを混合して結合剤プレミックスを予め調製した。
上記炭酸カルシウム混合物へ結合剤プレミックス６．４５ｇを加え、更に１５分間混合して、結合剤含有鉱物担体を得た。 (Formulation example 1) Preparation of a powder formulation of fursulfamide 0.3% KENMIX chef (manufactured by Aikosha Kogyo Co., Ltd.) as a mineral carrier, calcium carbonate (A tankal, particle size: 500 μm to 0%, 150 μm or less 10.0) % Or less, manufactured by Asahi Kou Sue Co., Ltd.) 1334.25 g and calcium carbonate (K-250, particle size: 425 μm or more and 1.0% or less, 45 μm or less 19% or less, manufactured by Asahi Kou Sue Co., Ltd.) 150 g Mixed for minutes.
Polyoxyethylene rosin acid ester (ethylene oxide addition mole number 15, manufactured by Toho Chemical Co., Ltd.) 35.81 g, polyethylene glycol (PEG-400, manufactured by Sanyo Chemical Industries Co., Ltd.) 62.56 g and polyoxypropylene alkyl ether phosphate ester (Dores A, manufactured by Nippon Emulsifier Co., Ltd.) 1.63 g was mixed to prepare a binder premix in advance.
The binder premix 6.45g was added to the said calcium carbonate mixture, and also mixed for 15 minutes, and the binder containing mineral support | carrier was obtained.

２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリド（フルスルファミド、純度９８％、三井化学株式会社製）５１．０１ｇ、炭酸カルシウム（ミクロンカルＳＴ−１３０、旭鉱末株式会社製）４１．７５ｇ、含水非晶質二酸化ケイ素（カープレックス＃８０Ｄ、デグサジャパン株式会社製）７．２４ｇを混合後、エアーミルにて粉砕して土壌病害防除用活性成分プレミックスを調製した。
上記結合剤含有鉱物担体に土壌病害防除用活性成分プレミックス９．３ｇを加え、更に１５分間混合し、求める土壌病害防除用粉粒製剤１５００ｇを得た。 51.01 g of 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide (fursulfamide, purity 98%, manufactured by Mitsui Chemicals), calcium carbonate (Microncal ST- 130, manufactured by Asahi-Kou Sue Co., Ltd.) 41.75 g, water-containing amorphous silicon dioxide (Carplex # 80D, manufactured by Degussa Japan Co., Ltd.) 7.24 g, and then pulverized with an air mill and active ingredient for controlling soil diseases A premix was prepared.
To the binder-containing mineral carrier, 9.3 g of an active ingredient premix for controlling soil diseases was added and further mixed for 15 minutes to obtain 1500 g of a granular formulation for controlling soil diseases.

（製剤例２）フルスルファミド０．３％粉粒製剤の調製
製剤例１において、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）を使用する代わりに、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数３、東邦化学工業株式会社製）を使用したこと以外は製剤例１と同様の操作を行い、土壌病害防除用粉粒製剤を得た。 (Formulation example 2) Preparation of flursulfamide 0.3% powder formulation In Formulation example 1, instead of using polyoxyethylene rosin acid ester (ethylene oxide addition mole number 15, Toho Chemical Co., Ltd.), polyoxyethylene Except for using rosin acid ester (3 moles of ethylene oxide added, manufactured by Toho Chemical Industry Co., Ltd.), the same operation as in Formulation Example 1 was performed to obtain a granular preparation for controlling soil diseases.

（製剤例３）フルスルファミド０．３％粉粒製剤の調製
製剤例１において、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）を使用する代わりに、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１２、東邦化学工業株式会社製）を使用したこと以外は、製造例１と同様の操作を行い、土壌病害防除用粉粒製剤を得た。 (Formulation Example 3) Preparation of Flursulfamide 0.3% Granule Formulation In Formulation Example 1, instead of using polyoxyethylene rosin acid ester (ethylene oxide addition mole number 15, Toho Chemical Co., Ltd.), polyoxyethylene Except having used rosin acid ester (the number of moles of addition of ethylene oxide, 12 manufactured by Toho Chemical Industry Co., Ltd.), the same operation as in Production Example 1 was performed to obtain a granular preparation for controlling soil diseases.

（製剤例４）フルスルファミド０．３％粉粒製剤の調製
製剤例１において、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）を使用する代わりに、ポリオキシエチレンポリオキシプロピレンロジン酸エステル（エチレンオキサイド付加モル数１２、プロピレンオキサイド付加モル数６、東邦化学工業株式会社製）を使用したこと以外は、製造例１と同様の操作を行い、土壌病害防除用粉粒製剤を得た。 (Formulation example 4) Preparation of flursulfamide 0.3% granule formulation In Formulation example 1, instead of using polyoxyethylene rosin acid ester (ethylene oxide addition mole number 15, Toho Chemical Co., Ltd.), polyoxyethylene Except for using polyoxypropylene rosin acid ester (12 moles of ethylene oxide added, 6 moles of propylene oxide added, manufactured by Toho Chemical Co., Ltd.) A granular formulation was obtained.

（製剤例５）フルスルファミド０．３％粉粒製剤の調製
製剤例１において、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）を使用する代わりに、ポリオキシエチレンポリオキシプロピレンロジン酸エステル（エチレンオキサイド付加モル数３、プロピレンオキサイド付加モル数３、東邦化学工業株式会社製）を使用したこと以外は、製剤例１と同様の操作を行い、土壌病害防除用粉粒製剤を得た。 (Formulation Example 5) Preparation of Flursulfamide 0.3% Granule Formulation In Formulation Example 1, instead of using polyoxyethylene rosin acid ester (ethylene oxide addition mole number 15, Toho Chemical Co., Ltd.), polyoxyethylene A powder for controlling soil diseases was prepared by the same operation as in Preparation Example 1 except that polyoxypropylene rosin acid ester (3 moles of ethylene oxide added, 3 moles of propylene oxide added, manufactured by Toho Chemical Co., Ltd.) was used. A granular formulation was obtained.

（製剤例６）フルアジナム０．５％粉粒製剤の調製
ＫＥＮＭＩＸ ｃｈｅｆ（株式会社愛工舎工業所製）に鉱物担体として炭酸カルシウム（Ａタンカル、粒径：５００μｍ以上０％、１５０μｍ以下１０．０％以下、旭鉱末株式会社製）１４２８．５５ｇおよび炭酸カルシウム（Ｋ−２５０、粒径：４２５μｍ以上１．０％以下、４５μｍ以下１９％以下、旭鉱末株式会社製）５０．００ｇを仕込み、２分間混合した。
ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）３７．４４ｇ、ポリエチレングリコール（ＰＥＧ−４００、三洋化成工業株式会社製品）６２．５６ｇを混合して結合剤プレミックを調製した。
上記炭酸カルシウム混合物へ結合剤プレミックス６．４５ｇを加え、更に１５分間混合して、結合剤含有鉱物担体を得た。 (Formulation Example 6) Preparation of 0.5% fluazinam powder formulation KENMIX chef (manufactured by Aikosha Kogyo Co., Ltd.) as a mineral carrier calcium carbonate (A tankal, particle size: 500 μm to 0%, 150 μm or less 10.0% Hereinafter, 1428.55 g manufactured by Asahi Kosue Co., Ltd. and 50.00 g of calcium carbonate (K-250, particle size: 425 μm or more and 1.0% or less, 45 μm or less 19% or less, manufactured by Asahi Kosue Co., Ltd.) Mix for 2 minutes.
Polyoxyethylene rosinic acid ester (ethylene oxide addition mole number 15, manufactured by Toho Chemical Industry Co., Ltd.) 37.44 g, polyethylene glycol (PEG-400, Sanyo Chemical Industries Co., Ltd. product) 62.56 g were mixed to produce a binder premix. Prepared.
The binder premix 6.45g was added to the said calcium carbonate mixture, and also mixed for 15 minutes, and the binder containing mineral support | carrier was obtained.

３−クロロ−Ｎ−（３−クロロ−５−トリフルオロメチル−２−ピリジル）−α,α,α−トリフルオロ−２,６−ジニトロ−ｐ−トルイジン（フルアジナム、純度９９％、合成品）５０．５１ｇ、炭酸カルシウム（ミクロンカルＳＴ−１３０、旭鉱末株式会社製）４２．４９ｇ、含水非晶質二酸化ケイ素（カープレックス＃８０Ｄ、デグサジャパン株式会社製）７．００ｇを混合後、エアーミルにて粉砕して土壌病害防除用活性成分プレミックスを調整した。
上記結合剤含有鉱物担体に土壌病害防除用活性成分プレミックス１５．００ｇを加え、更に１５分間混合し、求める土壌病害防除用粉粒製剤１５００ｇを得た。 3-chloro-N- (3-chloro-5-trifluoromethyl-2-pyridyl) -α, α, α-trifluoro-2,6-dinitro-p-toluidine (fluazinam, purity 99%, synthetic product) After mixing 50.51 g, calcium carbonate (Micron Cal ST-130, manufactured by Asahi Kou Sue Co., Ltd.) 42.49 g, hydrous amorphous silicon dioxide (Carplex # 80D, manufactured by Degussa Japan Co., Ltd.) 7.00 g, an air mill is mixed. The active ingredient premix for soil disease control was adjusted by pulverizing with.
To the binder-containing mineral carrier, 15.00 g of an active ingredient premix for controlling soil diseases was added and further mixed for 15 minutes to obtain 1500 g of a desired powder formulation for controlling soil diseases.

（製剤例７）アミスルブロム０．５％粉粒製剤の調製
製剤例６において、３−クロロ−Ｎ−（３−クロロ−５−トリフルオロメチル−２−ピリジル）−α,α,α−トリフルオロ−２,６−ジニトロ−ｐ−トルイジン（フルアジナム、純度９９％、合成品）を使用する代わりに、３−（３−ブロモ−６−フルオロ−２−メチルインドール−１−イルスルホニル）−Ｎ，Ｎ−ジメチル−１，２，４−トリアゾール−１−スルホンアミド（アミスルブロム、純度９９％、合成品）を使用したこと以外は、製剤例６と同様の操作を行い、土壌病害防除用粉粒製剤を得た。 (Formulation Example 7) Preparation of Amisulbrom 0.5% Granule Formulation In Formulation Example 6, 3-chloro-N- (3-chloro-5-trifluoromethyl-2-pyridyl) -α, α, α-trifluoro Instead of using -2,6-dinitro-p-toluidine (fluazinam, purity 99%, synthetic), 3- (3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl) -N, Except that N-dimethyl-1,2,4-triazole-1-sulfonamide (Amisulbrom, purity 99%, synthetic product) was used, the same procedure as in Formulation Example 6 was performed to prepare a granular preparation for controlling soil diseases. Got.

（製剤例８）
製剤例１において、ポリオキシエチレンロジン酸エステル（エチレンオキサイド付加モル数１５、東邦化学工業株式会社製）を含有する結合剤プレミックスを添加しなかったこと以外は、製剤例１と同様の操作を行い、土壌病害防除用粉粒製剤を得た。 (Formulation Example 8)
In Formulation Example 1, the same operation as Formulation Example 1 was performed except that a binder premix containing polyoxyethylene rosin acid ester (ethylene oxide addition mole number 15, manufactured by Toho Chemical Industry Co., Ltd.) was not added. To obtain a powder formulation for controlling soil diseases.

（製剤例９）
ＫＥＮＭＩＸ ｃｈｅｆ（株式会社愛工舎工業所製）に鉱物担体として炭酸カルシウム（Ａタンカル、粒径：５００μｍ以上０％、１５０μｍ以下１０．０％以下、旭鉱末株式会社製）１３３４．２５ｇおよび炭酸カルシウム（Ｋ−２５０、粒径：４２５μｍ以上１．０％以下、４５μｍ以下１９％以下、旭鉱末株式会社製）１５０ｇを仕込み、２分間混合した。次に、予め調製しておいたポリビニルアルコール２０％水溶液（ゴーセノールＧＬ−０５、日本合成化学工業株式会社製）６．４５ｇを加え、更に１５分間混合して、ポリビニルアルコールが付着した炭酸カルシウムを得た。 (Formulation Example 9)
KENMIX chef (manufactured by Aikosha Kogyo Co., Ltd.), calcium carbonate (A tankal, particle size: 500 μm or more, 0%, 150 μm or less, 10.0% or less, manufactured by Asahi Minesue Co., Ltd.) 1334.25 g and calcium carbonate 150 g (K-250, particle size: 425 μm or more and 1.0% or less, 45 μm or less and 19% or less, manufactured by Asahi Minesue Co., Ltd.) was charged and mixed for 2 minutes. Next, 6.45 g of a 20% aqueous solution of polyvinyl alcohol (GOHSENOL GL-05, manufactured by Nippon Synthetic Chemical Industry Co., Ltd.) prepared in advance is added and further mixed for 15 minutes to obtain calcium carbonate to which polyvinyl alcohol is adhered. It was.

２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリド（フルスルファミド、純度９８％、三井化学株式会社製）５１．０１ｇ、炭酸カルシウム（ミクロンカルＳＴ−１３０、旭鉱末株式会社製）４１．７５ｇ、含水非晶質二酸化ケイ素（カープレックス＃８０Ｄ、デグサジャパン株式会社製）７．２４ｇを混合後、エアーミルにて粉砕して土壌病害防除用活性成分プレミックスを調整した。
上記ポリビニルアルコールが付着した炭酸カルシウムに、土壌病害防除用活性成分プレミックス９．３ｇを加え、更に１５分間混合後、１昼夜風乾して土壌病害防除用粉粒製剤１４９５ｇを得た。 51.01 g of 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide (fursulfamide, purity 98%, manufactured by Mitsui Chemicals), calcium carbonate (Microncal ST- 130, manufactured by Asahi-Kou Sue Co., Ltd.) 41.75 g, water-containing amorphous silicon dioxide (Carplex # 80D, manufactured by Degussa Japan Co., Ltd.) 7.24 g, and then pulverized with an air mill and active ingredient for controlling soil diseases Adjusted the premix.
To the calcium carbonate to which the polyvinyl alcohol was attached, 9.3 g of an active ingredient premix for controlling soil diseases was added, and further mixed for 15 minutes, and then air-dried for 1 day to obtain 1495 g of a powder formulation for controlling soil diseases.

＜評価＞
上記製剤例１〜９、及び対照薬剤としてネビジン粉剤（フルスルファミド０．３％含有市販土壌病害防除剤、三井化学アグロ株式会社製）、フロンサイド粉剤（フルアジナム０．５％含有市販土壌病害防除剤、石原産業株式会社製）の浮遊性指数測定並びに植物に対する防除効果をポットで比較検討した。 <Evaluation>
Formulation examples 1-9, and nevidin powder (flusulfamide 0.3% -containing commercial soil disease control agent, manufactured by Mitsui Chemicals Agro Co., Ltd.), frontside powder (fluazinam 0.5% -containing commercial soil disease control agent, Ishihara Sangyo Co., Ltd.) and the control effect on plants were compared in pots.

（試験例１） 浮遊性指数測定
製剤例１〜９で調製した土壌病害防除用粉粒剤、及び市販対照薬剤（市販土壌病害防除剤）としてネビジン粉剤およびフロンサイド粉剤を用い、浮遊性指数の測定を実施した。浮遊性指数の測定は、「平成１４年１月１０日付け１３生産第３９８７号生産局長通知」による方法に準じて３回行い、その算術平均値を求めた。結果を表１に示す。
尚、浮遊性指数とは、農薬製剤のドリフト性（粉立ち性）を判断する指標として用いられ、数値が大きいほど粉立ち（飛散）が大きいことを意味する。 (Test Example 1) Measurement of buoyancy index Using a nevidin powder and a frontside powder as a soil disease control powder prepared in Formulation Examples 1 to 9 and a commercially available control drug (market soil disease control agent), Measurements were performed. The floatability index was measured three times in accordance with the method of “Notification of the 13th Production No. 3987 Director General on January 10, 2002”, and the arithmetic average value was obtained. The results are shown in Table 1.
The floatability index is used as an index for judging the drifting property (powdering property) of an agrochemical formulation, and means that the larger the numerical value, the larger the dusting (scattering).

Figure 0005511404
Figure 0005511404

表１からも明らかな通り、本発明に係る土壌病害防除用粉粒製剤である製剤例１〜製剤例７は、ポリビニルアルコールを結合剤として用いた製剤例８、および粉剤である市販対照薬剤（ネビジン粉剤、フロンサイド粉剤）と比較し、粉立ち（飛散）が大きく抑制された粉粒製剤であることが明らかである。   As is apparent from Table 1, Formulation Example 1 to Formulation Example 7 which are powder formulations for controlling soil diseases according to the present invention are Formulation Example 8 using polyvinyl alcohol as a binder, and a commercial control drug (powder) Compared with nevidin powder and fronside powder), it is clear that it is a powder formulation in which dusting (scattering) is greatly suppressed.

（試験例２） 土壌病害防除効果試験（ポット試験）
−コマツナ根こぶ病防除試験−
試験に用いたアブラナ科野菜根こぶ病菌（Ｐｌａｓｍｏｄｉｏｐｈｏｒａ ｂｒａｓｓｉｃａｅ）は次の様にして調製した。−２０℃の冷凍庫にて保存の罹病根に等倍以上の殺菌水を加え、ミキサーで５分間粉砕して得た磨砕液を４重ガーゼでろ過した。ろ液を２０００ｒｐｍで１０分間遠心分離し、上澄み部を捨て、沈降残渣に再度殺菌水を加え、ミキサーで均一化した。遠心分離する操作を２〜３回行って、休眠胞子を洗浄した後、得られた沈降休眠胞子を１×１０６個／ｇ土の胞子濃度になるように希釈して使用した。 (Test Example 2) Soil disease control effect test (pot test)
-Komatsuna clubroot control test-
The Brassicaceae vegetable root-knot fungus (Plasmodiophora brassicae) used for the test was prepared as follows. At least sterilized water was added to the diseased roots stored in a freezer at −20 ° C., and the ground solution obtained by pulverizing with a mixer for 5 minutes was filtered with quadruple gauze. The filtrate was centrifuged at 2000 rpm for 10 minutes, the supernatant was discarded, sterilized water was added again to the sedimentation residue, and the mixture was homogenized with a mixer. Centrifugation was performed 2-3 times to wash dormant spores, and the resulting settled dormant spores were diluted to a spore concentration of 1 × 10 6 / g soil and used.

調製した根こぶ病菌休眠胞子を土壌３ｋｇに滴下し、よく混和した。製剤例１〜９で調製した土壌病害防除用粉粒製剤の所定量を添加し、更に十分に混合した後、直径１５ｃｍの素焼き鉢３個に詰め、コマツナ（品種：黒葉晩生）種子２０粒を播種し、温室内で生育させた。播種後２週間頃までの間に生育の揃った１０本を残し、他は間引いた。播種６週間後に根部を掘り起こして水洗いし、根こぶ着生の有無とその発病程度を調査し、効果の判定を行った。尚、発病程度は以下に示す０〜４の５段階評価の発病指数で行い、発病度および防除価を以下の式１、式２によりそれぞれ求めた。試験結果を表２、表３に示す。尚、表２と表３は試験日が異なる。
また試験中に、地上部に現れる薬害の有無を肉眼観察にて行うと共に処理後６週間後の草丈により、薬害の発生を判断したが、いずれの製剤も薬害は観察されなかった。 The prepared root-knot fungus dormant spores were dropped into 3 kg of soil and mixed well. After adding a predetermined amount of the powder preparation for soil disease control prepared in Formulation Examples 1 to 9, and mixing well, it is packed in 3 unglazed pots with a diameter of 15 cm, and 20 seeds of Komatsuna (variety: Kuroba Late) seeds. Was sowed and grown in a greenhouse. Ten pieces of growth were kept until about two weeks after sowing, and the others were thinned out. Six weeks after sowing, the roots were dug up and washed, and the presence or absence of root nodules and the degree of disease occurrence were investigated, and the effect was determined. In addition, the disease severity was determined by the disease index of 5-step evaluation of 0 to 4 shown below, and the disease severity and the control value were determined by the following formulas 1 and 2, respectively. The test results are shown in Tables 2 and 3. Table 2 and Table 3 have different test dates.
In addition, during the test, the presence or absence of phytotoxicity appearing on the ground part was observed with the naked eye and the occurrence of phytotoxicity was judged by the plant height 6 weeks after the treatment, but no phytotoxicity was observed in any of the preparations.

−発病指数−
０：こぶ形成はなかった。
１：主根の末端、側根に小さなこぶが形成された。
２：主根の１／３以下未満が罹病した。
３：主根の１／３以上２／３未満が罹病した。
４：主根の２／３以上が罹病し、細根がほとんどなかった。 -Disease index-
0: No hump formation.
1: A small hump was formed at the end of the main root and at the side root.
2: Less than 1/3 or less of the main root was affected.
3: More than 1/3 and less than 2/3 of the main roots were affected.
4: More than 2/3 of the main roots were affected, and there were almost no fine roots.

発病度＝Σ（発病指数×指数別株数）／（４×全株数）×１００ ： （式１）
防除価＝（無処理の発病度−薬剤処理の発病度）／（無処理の発病度）×１００ ： （式２） Disease severity = Σ (morbidity index × number of strains by index) / (4 × total number of strains) × 100: (Formula 1)
Control value = (Untreated disease severity-Drug treatment disease severity) / (Untreated disease severity) × 100: (Formula 2)

Figure 0005511404
Figure 0005511404

Figure 0005511404
Figure 0005511404

表２、３に示す通り、本発明に係る土壌病害防除用粉粒製剤（製剤例１、２、３および５）はコマツナ根こぶ病に対して、従来の粉剤と同等の効果であることは明らかである。
以上の試験例で明らかなように、本発明の土壌病害防除用粉粒製剤は、薬液を調製する必要がなく使用が簡便かつ安全で、飛散（ドリフト）が抑制される。さらに、土壌病害防除用粉粒製剤を土壌と混和した際には、鉱物担体から土壌病害防除用活性成分が剥離し、土壌中に均一に分散することにより、薬剤の濃度にバラツキを生じることなく、安定した防除効果を発現する。 As shown in Tables 2 and 3, the soil disease control powder formulations (formulation examples 1, 2, 3 and 5) according to the present invention have the same effect as conventional powders against Komatsuna clubroot. it is obvious.
As is clear from the above test examples, the powder preparation for controlling soil diseases of the present invention does not require preparation of a chemical solution, is simple and safe to use, and suppresses scattering (drift). Furthermore, when the soil disease control powder formulation is mixed with soil, the active ingredient for soil disease control is peeled off from the mineral carrier and evenly dispersed in the soil without causing variations in the drug concentration. It exhibits a stable control effect.

Claims (9)

土壌病害防除用活性成分と、鉱物担体と、ポリオキシエチレンロジン酸エステルおよびポリオキシエチレンポリオキシプロピレンロジン酸エステルから選ばれる少なくとも１種のポリオキシアルキレン樹脂酸エステルと、を含有し、前記前記ポリオキシアルキレン樹脂酸エステルの含有率が０．０１〜１重量％である土壌病害防除用粉粒製剤。 An active ingredient for controlling soil diseases, a mineral carrier, and at least one polyoxyalkylene resin acid ester selected from polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester , A granular preparation for controlling soil diseases , wherein the content of oxyalkylene resin acid ester is 0.01 to 1% by weight . 前記ポリオキシアルキレン樹脂酸エステルは、オキシアルキレン基の総付加モル数が樹脂酸１モルに対して平均１〜２０モルである請求項１に記載の土壌病害防除用粉粒製剤。 The granular preparation for controlling soil diseases according to claim 1 , wherein the polyoxyalkylene resin acid ester has an average number of added moles of oxyalkylene groups of 1 to 20 moles per mole of resin acid. 前記鉱物担体に対する前記ポリオキシアルキレン樹脂酸エステルの含有比率が、０．０１〜１．１１重量％である請求項１又は請求項２に記載の土壌病害防除用粉粒製剤。 The granular preparation for controlling soil diseases according to claim 1 or 2 , wherein a content ratio of the polyoxyalkylene resin acid ester to the mineral carrier is 0.01 to 1.11% by weight. 更に界面活性剤を含有する請求項１〜請求項３のいずれか１項に記載の土壌病害防除用粉粒製剤。 The powder preparation for controlling soil diseases according to any one of claims 1 to 3 , further comprising a surfactant. 前記界面活性剤が、ポリアルキレングリコールである請求項４に記載の土壌病害防除用粉粒製剤。 The powder preparation for controlling soil diseases according to claim 4 , wherein the surfactant is polyalkylene glycol. 前記土壌病害防除用活性成分が、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリド、３−クロロ−Ｎ−（３−クロロ−５−トリフルオロメチル−２−ピリジル）−α,α,α−トリフルオロ−２,６−ジニトロ−ｐ−トルイジン、および３−（３−ブロモ−６−フルオロ−２−メチルインドール−１−イルスルホニル）−Ｎ，Ｎ−ジメチル−１，２，４−トリアゾール−１−スルホンアミドから選ばれる少なくとも１種である請求項１〜請求項５のいずれか１項に記載の土壌病害防除用粉粒製剤。 The active ingredient for controlling soil diseases is 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide, 3-chloro-N- (3-chloro-5-tri Fluoromethyl-2-pyridyl) -α, α, α-trifluoro-2,6-dinitro-p-toluidine, and 3- (3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl)- The granular preparation for controlling soil diseases according to any one of claims 1 to 5 , which is at least one selected from N, N-dimethyl-1,2,4-triazole-1-sulfonamide. 前記土壌病害防除用活性成分が、２’，４−ジクロロ−α,α,α−トリフルオロ−４’−ニトロ−ｍ−トルエンスルホンアニリドである請求項１〜請求項６のいずれか１項に記載の土壌病害防除用粉粒製剤。 The active ingredient for controlling soil diseases is 2 ′, 4-dichloro-α, α, α-trifluoro-4′-nitro-m-toluenesulfonanilide, according to any one of claims 1 to 6. The granular preparation for soil disease control as described. 鉱物担体およびポリオキシエチレンロジン酸エステルおよびポリオキシエチレンポリオキシプロピレンロジン酸エステルから選ばれる少なくとも１種のポリオキシアルキレン樹脂酸エステルを混合して、結合剤含有鉱物担体を得る第１の工程と、
前記結合剤含有鉱物担体および土壌病害防除用活性成分を混合して、土壌病害防除用粉粒製剤を得る第２の工程と、
を含む、前記ポリオキシアルキレン樹脂酸エステルの含有率が０．０１〜１重量％である土壌病害防除用粉粒製剤の製造方法。 A first step of obtaining a binder-containing mineral carrier by mixing a mineral carrier and at least one polyoxyalkylene resin acid ester selected from polyoxyethylene rosin acid ester and polyoxyethylene polyoxypropylene rosin acid ester ;
A second step of mixing the binder-containing mineral carrier and an active ingredient for controlling soil diseases to obtain a powder preparation for controlling soil diseases;
The manufacturing method of the granule formulation for soil disease control whose content rate of the said polyoxyalkylene resin acid ester is 0.01 to 1 weight% . 請求項１〜請求項７のいずれか１項に記載の土壌病害防除用粉粒製剤を、土壌に施用することを含む土壌病害防除方法。 A soil disease control method comprising applying the powder preparation for soil disease control according to any one of claims 1 to 7 to soil.
JP2010010471A 2010-01-20 2010-01-20 Soil disease control powder formulation and soil disease control method Active JP5511404B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2010010471A JP5511404B2 (en) 2010-01-20 2010-01-20 Soil disease control powder formulation and soil disease control method
KR1020100131419A KR101310030B1 (en) 2010-01-20 2010-12-21 Dust-granule mixture formulations for controlling soil-borne disease and soil-borne disease controlling method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2010010471A JP5511404B2 (en) 2010-01-20 2010-01-20 Soil disease control powder formulation and soil disease control method

Publications (2)

Publication Number Publication Date
JP2011148723A JP2011148723A (en) 2011-08-04
JP5511404B2 true JP5511404B2 (en) 2014-06-04

Family

ID=44536085

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010010471A Active JP5511404B2 (en) 2010-01-20 2010-01-20 Soil disease control powder formulation and soil disease control method

Country Status (2)

Country Link
JP (1) JP5511404B2 (en)
KR (1) KR101310030B1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160262379A1 (en) 2013-10-21 2016-09-15 Hicap Formulations Ltd. Controlled release formulations of herbicides

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5323383B2 (en) * 1972-01-14 1978-07-14
JPS55141402A (en) * 1979-04-23 1980-11-05 Sanyo Chem Ind Ltd Drift preventive for agricultural dust preparation
JPH02108605A (en) * 1988-10-19 1990-04-20 Toho Chem Ind Co Ltd Solid formulation of agricultural chemical having suppressed crystallizability
JP3126399B2 (en) * 1991-03-08 2001-01-22 武田薬品工業株式会社 Pesticide powder
JP3193595B2 (en) * 1995-06-26 2001-07-30 北興化学工業株式会社 Anti-drift and improved pesticide dust
ES2137016T3 (en) * 1995-08-29 1999-12-01 Du Pont CROP PROTECTION COMPOSITION INCLUDING A SOLID CROP PROTECTION PARTICLE COATED WITH A WATER INSOLUBLE COATING MATERIAL AND A CROP PROTECTION MIXTURE INCLUDING THE SAME.
TWI281852B (en) * 2003-07-18 2007-06-01 Mitsui Chemicals Inc Fungicidal aqueous suspension formulation for foliage application
CN101541948B (en) * 2006-11-08 2012-03-28 日本曹达株式会社 Microorganism capable of controlling plant diseases and plant disease-controlling agent using the microorganism
CL2007003329A1 (en) * 2006-11-21 2008-03-24 Mitsui Chemicals Inc COMPOSITION FOR THE CONTROL OF DANE PRODUCED BY INSECTS AND DISEASES IN PLANTS THAT INCLUDES A PENTIOPIRAD COMPOUND AND AT LEAST A FUNGICIDE COMPOSITE DIFFERENT FROM PENTIOPIRAD; METHOD OF PLANT DISEASE CONTROL THAT INCLUDES TO APPLY
JP5285388B2 (en) * 2008-10-24 2013-09-11 クミアイ化学工業株式会社 Fine-grained agricultural chemical composition and method for producing the same

Also Published As

Publication number Publication date
KR20110085866A (en) 2011-07-27
JP2011148723A (en) 2011-08-04
KR101310030B1 (en) 2013-09-24

Similar Documents

Publication Publication Date Title
JP6368701B2 (en) Aqueous herbicide concentrates of auxinic carboxylic acids with reduced eye irritation
JP6001643B2 (en) Use of 3-isoxazolidinone derivatives as selective herbicides for gramineous and cruciferous crops
JP2012527403A5 (en)
JP2007077044A (en) Suspensible agrochemical preparation
CN104970040A (en) Plant growth regulating composition for corns, preparation and application thereof
MX2013009264A (en) Stable formulation.
EA025265B1 (en) Chemical stabilization of iodosulfuron-methyl sodium salt by hydroxystearates
WO2012040802A2 (en) Synergistic combination of abamectin and bifenthrin, process of preparation thereof and uses, and method using the same
CN1038466C (en) Rice field herbcide composition
JP5511404B2 (en) Soil disease control powder formulation and soil disease control method
TWI739727B (en) Odor-reduced pyrethroid-organothiophosphate formulations
JP5280733B2 (en) Herbicidal aqueous suspension formulation with reduced phytotoxicity
CN109362743A (en) A kind of Herbicidal combinations and its application containing symetryne
JP2943003B2 (en) Field-acting herbicide composition and herbicidal method
WO2015070569A1 (en) Herbicide composition containing aminopyralid and nonanoic acid
JP2007520432A (en) Bactericidal effect enhancer composition and bactericidal composition containing the same
KR101784513B1 (en) Herbicide compositions for controlling pests of horticultural products comprising rare-earth elements as active ingredients and method for manufacturing the same
JP2012006849A (en) Sulfur suspension for controlling scab
CN105211093A (en) A kind of novel mixed herbicide
CN104839155B (en) A kind of spring rape field prevents and kill off spontaneous rape herbicidal composition
JP3063451B2 (en) Agricultural and horticultural drug having bactericidal and virucidal properties and bactericidal and virucidal method for agriculture and horticulture
JP3933887B2 (en) Plant powdery mildew control material and its use
CN104304259B (en) A kind of mixed herbicide and preparation method who comprises diflufenican and amicarbazone
TW201914427A (en) Herbicide, herbicidal aid and preparation method and implementation method thereof
JPH0710713A (en) Herbicide composition

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20121114

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20131212

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20131217

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140207

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20140304

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20140325

R150 Certificate of patent or registration of utility model

Ref document number: 5511404

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250