JP5424536B2 - How to use konjac - Google Patents

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JP5424536B2
JP5424536B2 JP2007086041A JP2007086041A JP5424536B2 JP 5424536 B2 JP5424536 B2 JP 5424536B2 JP 2007086041 A JP2007086041 A JP 2007086041A JP 2007086041 A JP2007086041 A JP 2007086041A JP 5424536 B2 JP5424536 B2 JP 5424536B2
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konjac
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poorly water
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聖一 村上
可人 弓長
房代 木内
重信 渋田
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昭和商事株式会社
星和株式会社
株式会社錬農水産
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Description

本発明は新規なコンニャクの利用方法に関する。   The present invention relates to a novel method of using konjac.

コンニャクを利用して加熱又は冷凍又は乾燥により水難溶ゲル又は水難膨潤性になる加工物を得る方法には既に公知の方法(特許文献1、特許文献2)がある。
特開昭60−221054 特開昭60−141250
There are already known methods (Patent Literature 1 and Patent Literature 2) for obtaining a water-insoluble gel or a water-swellable processed material by heating, freezing, or drying using konjac.
JP 60-221054 JP 60-141250 A

しかしながら、前記従来方法は50℃未満で2時間以上の放置時間を要するなど実際の食品製造工程では採用しにくい使用方法であった。
これは通常の食品に使用されるコンニャク精粉は粒子径が60〜80メッシュと比較的大きいため、水に溶解するのに60分〜120分要することと、コンニャク精粉とアルカリ剤混合後pH値の減少が大きいために50℃未満の放置時間ではゲル化しない程度の低めのpHで混合し、放置時間を長く調整しているためである。
近年、健康志向の高まりとともにコンニャクの有効利用方法が種々提案されているが、実際の製造工程に採用されやすい形態とはなっていないのが現状である。
However, the conventional method is difficult to adopt in an actual food manufacturing process because it requires a standing time of 2 hours or more at less than 50 ° C.
This is because konjac flour used in normal foods has a relatively large particle size of 60-80 mesh, so it takes 60-120 minutes to dissolve in water, and the pH after mixing konjac flour with an alkaline agent This is because the decrease in the value is large and mixing is performed at a low pH that does not cause gelation in the standing time of less than 50 ° C., and the standing time is adjusted to be long.
In recent years, various methods for effectively using konjac have been proposed along with an increase in health consciousness, but the current situation is that the form is not easily adopted in an actual manufacturing process.

本発明は以上の従来方法の問題点を解消し、実際の食品製造工程に即したコンニャクの利用方法を提供することを目的として創作されたものであり、以下のコンニャクを利用した水難溶化食品又は水難膨潤化食品の製造工程において、第1工程における適当含水混合物に使用するアルカリ性物質として塩基性塩類、塩基性アミノ酸の単独又は2種以上を使用するとともに、これらの量を第1工程において適当含水混合物がゲル化しない範囲内とし、この場合のアルカリ性物質の効力低下を防止するためにpH緩衝剤としてグリシンを使用することにより、第1工程における放置時間を5分以上90分未満内に短縮することを可能としたことを特徴とする。
(1) 微粉化コンニャク粉を多糖類で造粒したコンニャク素材とアルカリ性物質との適当含水混合物を、下限は該混合物が凍結しない温度、上限は50℃未満に調整した温度条件下で一定時間放置して液状もしくはゾル状の加工物を得る第1工程、
(2) 第1工程で得た液状もしくはゾル状の加工物を他の物質と混合し、それを加熱又は冷凍又は乾燥することにより、多種多様な用途のある水難溶化食品又は水難膨潤化食品を得る第2工程。
The present invention is to solve the above conventional method, which has been created for the purpose of providing a method of using suited to actual food manufacturing process konjac, poorly water soluble food or by using the following konjac In the production process of poorly swollen food, basic salts or basic amino acids are used alone or in combination of two or more as alkaline substances to be used in the appropriate water-containing mixture in the first step, and these amounts are appropriately determined in the first step. By setting glycine as a pH buffering agent within the range where the mixture does not gel, and preventing a decrease in the efficacy of the alkaline substance in this case, the standing time in the first step is shortened to 5 minutes or more and less than 90 minutes. It is possible to do that.
(1) Appropriate water-containing mixture of konjac raw material and alkaline substance granulated from pulverized konjac flour with polysaccharide, left for a certain time under the temperature condition where the lower limit is the temperature at which the mixture does not freeze and the upper limit is adjusted to less than 50 ° C A first step of obtaining a liquid or sol workpiece,
(2) The liquid or sol processed product obtained in the first step is mixed with other substances and heated, frozen or dried to produce a poorly water-soluble or low-swelling food with various uses. A second step to obtain.

本願発明者等は、
(a)コンニャク素材として微粉化コンニャクを多糖類で造粒したものを使用する、
(b)アルカリ性物質とpH緩衝剤を併用する、
(c)pH緩衝剤の少なくとも1 種はグリシンを使用する、
ことを着想し、以上の方法により放置処理時間を5分以上90分未満の間で任意に調整することを可能とし、上記課題を効果的に解決することに成功した。
The inventors of this application
(A) Use pulverized konjac granulated with polysaccharides as konjac material,
(B) A combination of an alkaline substance and a pH buffer,
(C) at least one of the pH buffering agents uses glycine,
With this in mind, it was possible to arbitrarily adjust the standing treatment time between 5 minutes and less than 90 minutes by the above method, and succeeded in effectively solving the above problems.

本発明によればコンニャク素材とアルカリ性物質との適当含水混合物を、温度条件として下限は該混合物が凍結しない温度、上限は50℃未満に調整し放置処理後加熱又は冷凍又は乾燥することにより水難溶性ゲル又は水難膨潤性になる加工物を得、該加工物を他の物質と混合し、それを加熱又は冷凍又は乾燥することにより多種多様な用途のある水難溶化食品又は水難膨潤化食品として収得することを特徴とするコンニャクの利用方法において、放置処理時間を5分以上90分未満の間の任意の時間に短縮することにより実際の食品製造工程に即した新規なコンニャクの利用方法を提供することが出来る。   According to the present invention, a suitable water-containing mixture of a konjac material and an alkaline substance has a low water solubility by adjusting the temperature condition such that the lower limit is a temperature at which the mixture does not freeze, the upper limit is less than 50 ° C., and after standing treatment, heating or freezing or drying. A processed product that becomes a gel or poorly water-swellable is obtained, and the processed product is mixed with other substances, and then heated, frozen, or dried to obtain a water-solubilized food or a water-swellable food that has a wide variety of uses. In the use method of konjac characterized by the above, to provide a new use method of konjac in accordance with the actual food manufacturing process by shortening the neglect processing time to an arbitrary time between 5 minutes and less than 90 minutes I can do it.

微粉化コンニャク粉を得るには、コンニャク精粉を液体窒素で超低温にして粉砕する方法、コンニャク精粉をエチルアルコール水溶液に懸濁後湿式研磨機で粉砕する方法などがあるが極端な粘度低下が無ければ方式は問わない。又、こんにゃく精粉の粒子径は60〜80メッシュであるが、本発明に使用する微粉化こんにゃく粉は100メッシュパス以上であれば良い。   There are two ways to obtain finely pulverized konjac powder: pulverizing konjac fine powder with liquid nitrogen at ultra-low temperature, pulverizing konjac fine powder in an ethyl alcohol aqueous solution and then pulverizing with a wet polisher. If there is not, system does not matter. Moreover, although the particle diameter of konjac refined powder is 60-80 mesh, the micronized konjac powder used for this invention should just be 100 mesh pass or more.

微粉化コンニャク粉は水溶液にしようとした場合水に部分的に溶解し、いわゆるママコになりやすいため本発明では多糖類で造粒したコンニャク素材を使用する。微粉化コンニャク粉と多糖類の粉体混合では粒子径を揃える等均一に混合しないと多糖類がママコになり逆効果になることが多い。   When pulverized konjac powder is made into an aqueous solution, it partially dissolves in water and tends to be so-called mamaco. Therefore, in the present invention, a konjac material granulated with a polysaccharide is used. In powder mixing of pulverized konjac powder and polysaccharides, if the particles are not uniformly mixed, for example, the particle size is uniform, the polysaccharides often become mako and have an adverse effect.

造粒に使用する多糖類は水に接触した時にすぐ溶解するものであれば良く、例えば次の中から1種又は2種以上選択される。
アルギン酸ナトリウム、アルギン酸プロピレングリコールエステル、グアガム、ローカストビーンガム、キサンタンガム、カラギーナン、アラビアガム、サイリュームシードガム、プルラン、メチルセルロース、カルボキシメチルセルロース、ペクチン、デキストリン、α澱粉
又、造粒方法は流動層式造粒法等方式を問わない。
The polysaccharide used for granulation should just melt | dissolve immediately when it contacts with water, for example, 1 type (s) or 2 or more types are selected from the following.
Sodium alginate, propylene glycol alginate, guar gum, locust bean gum, xanthan gum, carrageenan, gum arabic, silium seed gum, pullulan, methylcellulose, carboxymethylcellulose, pectin, dextrin, α-starch It doesn't matter what the method is.

アルカリ性物質としては水溶液がアルカリ性を示す食品添加物であれば良いが、例えば次の中から1種又は2種以上選択される。
水酸化ナトリウム、炭酸ナトリウム、水酸化カルシウム、酸化カルシウム、リン酸ナトリウム、リン酸カリウム、貝殻焼成カルシウム、塩基性アミノ酸
The alkaline substance may be any food additive in which the aqueous solution exhibits alkalinity. For example, one or more kinds are selected from the following.
Sodium hydroxide, sodium carbonate, calcium hydroxide, calcium oxide, sodium phosphate, potassium phosphate, shell calcined calcium, basic amino acid

本発明のコンニャク素材加工物は他の物質と均一に混合するため、液状もしくはゾル状であることが要求される。そのためアルカリ性物質の添加量はいわゆる伝統食品としてのこんにゃくの製造で使用されるアルカリ性物質に比べ少ない使用量となるため、コンニャク素材と混合後のアルカリ素材の効力低下が速く、コンニャク精粉の溶解速度の問題と併せて前記特許文献1及び特許文献2では長時間の放置時間を必要とした。   The processed konjac material of the present invention is required to be in a liquid or sol form so as to be uniformly mixed with other substances. Therefore, the amount of alkaline substance added is less than the amount of alkaline substance used in the production of konjac as a so-called traditional food. In addition to the above problem, Patent Document 1 and Patent Document 2 require a long standing time.

コンニャク素材の溶解速度の問題は上記方法で解決したがアルカリ性物質の効力低下の問題は緩衝剤の併用により解決をした。
アルカリ性物質とともに用いられる緩衝剤としては有機酸類、炭酸水素ナトリウム、リン酸2水素ナトリウム、リン酸2水素カリウム等から1種又は2種以上選択されるが、本発明ではグリシンを必須成分とする。
The problem of dissolution rate of konjac material was solved by the above method, but the problem of reduced potency of alkaline substance was solved by the combined use of buffer.
The buffer used together with the alkaline substance is selected from one or more of organic acids, sodium hydrogen carbonate, sodium dihydrogen phosphate, potassium dihydrogen phosphate and the like. In the present invention, glycine is an essential component.

本発明において、上記コンニャク素材よりの加工物を他の物質と混合し、それを加熱又は冷凍又は乾燥することにより多種多様な用途のある水難溶化食品又は水難膨潤化食品として収得する内容は次の如きものである。   In the present invention, the content obtained as a poorly water-soluble food or a poorly water-swelled food having a wide variety of uses by mixing a processed product from the konjac material with other substances and heating or freezing or drying it is as follows. It is like this.

まず、他の物質とは例えば次の食品類である。
穀類、芋及び澱粉類、砂糖及び甘味類、豆類、種実類、野菜類、きのこ類、藻類、魚介類、肉類、卵類、乳類、油脂類、菓子類、嗜好飲料類、調味料及び香辛料類、調理加工食品類
水難溶化食品、水難膨潤化食品に関しては以下実施例をもって説明するが本発明はこれ等の実施例によって何ら限定されるものではない。
First, the other substances are, for example, the following foods.
Cereals, rice cakes and starches, sugar and sweets, beans, seeds, vegetables, mushrooms, algae, seafood, meat, eggs, milk, fats and oils, confectionery, beverages, seasonings and spices Examples of cooked foods, cooked foods, poorly water-soluble foods, and poorly water-swelled foods will be described below with reference to examples, but the present invention is not limited to these examples.

[実施例1]
水100部に炭酸ナトリウム、炭酸水素ナトリウム、グリシンを溶解しpHを11. 3に調整した。これに微粉化こんにゃく粉をデキストリンで造粒したコンニャク素材(コンニャク粉含量40%)6部を混合し水温15℃で30分放置し、第1工程の加工物を得た。この時点での加工物のpHは11. 2であり、pH値の低下はほとんど無かった。
前記の第1工程の加工物を折り径60mmのケーシングに充填し、両端を結さつ、80℃の湯浴で40分加熱をした後冷水にて冷却すると、水難溶性ゲルを得ることができた
[Example 1]
Sodium carbonate, sodium bicarbonate, and glycine were dissolved in 100 parts of water to adjust the pH to 11.3. To this, 6 parts of konjac material (konjac powder content 40%) obtained by granulating micronized konjac powder with dextrin was mixed and allowed to stand at a water temperature of 15 ° C. for 30 minutes to obtain a processed product of the first step . The pH of the processed product at this point was 11.2, and there was almost no decrease in pH value.
Was filled in a casing of the workpiece folding diameter 60mm of the first step, forming the ends bills, cooling result, the Rukoto give hardly water-soluble gel at cold water after 40 minutes heated in a water bath at 80 ° C. I did it .

[比較例1]
水100部に炭酸ナトリウムを溶解しpHを11. 3に調製した。これに微粉化こんにゃく粉をデキストリンで造粒したコンニャク素材(コンニャク粉含量40%)6部を混合し、水温15℃で30分放置し加工物を得た。この時点でのpHは10. 4でありpH値が減少していた。これを折り径60mmのケーシングに充填し両端を結さつ、80℃の湯浴で40分加熱をした後、冷水にて冷却したがゲル状物を得ることは出来なかった。
[Comparative Example 1]
Sodium carbonate was dissolved in 100 parts of water to adjust the pH to 11.3. To this, 6 parts of a konjac material (konjac powder content 40%) obtained by granulating pulverized konjac powder with dextrin was mixed and allowed to stand at a water temperature of 15 ° C. for 30 minutes to obtain a processed product. The pH at this point was 10.4, and the pH value was decreasing. This was filled into a casing with a folding diameter of 60 mm, both ends were connected, heated in a hot water bath at 80 ° C. for 40 minutes, and then cooled with cold water, but a gel-like product could not be obtained.

[比較例2]
水100部に炭酸ナトリウム、炭酸水素ナトリウムを溶解しpHを11. 3に調整した。これに微粉化こんにゃく粉をデキストリンで造粒したコンニャク素材(コンニャク粉含量40%)6部を混合し、水温15℃で30分放置し加工物を得た。この時点でのpHは10. 6でありpH値が減少していた。これを厚さ5mmのシート状に成型し−20℃の冷凍庫で冷凍し、24時間後解凍したがゲル状物は得られなかった。
[Comparative Example 2]
Sodium carbonate and sodium hydrogen carbonate were dissolved in 100 parts of water to adjust the pH to 11.3. To this, 6 parts of a konjac material (konjac powder content 40%) obtained by granulating pulverized konjac powder with dextrin was mixed and allowed to stand at a water temperature of 15 ° C. for 30 minutes to obtain a processed product. The pH at this point was 10.6, and the pH value was decreasing. This was molded into a 5 mm thick sheet, frozen in a -20 ° C freezer, and thawed 24 hours later, but no gel was obtained.

[比較例3]
水100部に水酸化カルシウムを溶解しpHを11. 3に調整した。これに微粉化こんにゃく粉をデキストリンで造粒したコンニャク素材(コンニャク粉含量40%)6部を混合し、水温15℃で30分放置し加工物を得た。この時点でのpHは10. 2でありpH値が減少していた。これを通風乾燥機を使用し80℃で1時間乾燥し乾燥シートを得、5cm角に切り、15℃の水に1時間浸漬したがシート状の形態を保つことが出来ず水中で膨潤した。
[Comparative Example 3]
Calcium hydroxide was dissolved in 100 parts of water to adjust the pH to 11.3. To this, 6 parts of a konjac material (konjac powder content 40%) obtained by granulating pulverized konjac powder with dextrin was mixed and allowed to stand at a water temperature of 15 ° C. for 30 minutes to obtain a processed product. The pH at this point was 10.2, and the pH value was decreasing. This was dried using an air dryer at 80 ° C. for 1 hour to obtain a dried sheet, which was cut into 5 cm squares and immersed in water at 15 ° C. for 1 hour, but the sheet-like form could not be maintained and swollen in water.

[実施例2]
[実施例1] で得た第1工程の加工物100部と塩摺りしたスケソウすり身100部を擂潰機で混合し、折り径60mmのケーシングに充填し両端を結さつ、80℃の湯浴で40分加熱をし水難溶化食品を得た。
[Example 2]
[Example 1] 100 parts of the processed product of the first step and 100 parts of ground salmon surimi were mixed with a crusher, filled into a casing with a folding diameter of 60 mm, and joined at both ends. It was heated in a bath for 40 minutes to obtain a poorly water-soluble food.

[実施例3]
[実施例1] で得た第1工程の加工物を厚さ5mmのシート状に成型し−20℃の冷凍庫で冷凍した。24時間後解凍し水難溶性ゲルを得た。
[Example 3]
The processed product of the first step obtained in [Example 1] was molded into a sheet having a thickness of 5 mm and frozen in a -20 ° C freezer. After 24 hours, the gel was thawed to obtain a poorly water-soluble gel.

[実施例4]
[実施例1] で得た第1工程の加工物100部と豚挽き肉100部、コーンスターチ10部をニーダーで練り合わせ、厚さ3mm, 30cm平方のシートにして−20℃の冷凍庫で冷凍した。24時間後解凍し、豚肉の水難溶性シートを得た。
[Example 4]
100 parts of the processed product obtained in [Example 1], 100 parts of minced pork, and 10 parts of corn starch were kneaded with a kneader, made into a 3 mm thick, 30 cm square sheet, and frozen in a -20 ° C freezer. After 24 hours, thawing was performed to obtain a poorly water-soluble pork sheet.

[実施例5]
[実施例1] で得た第1工程の加工物を厚さ5mmのシート状に成型した。これを通風乾燥機を使用し80℃で1時間乾燥し乾燥シートを得た。これを5cm角に切り15℃の水に1時間浸漬したがシート状の形態を保っており水難膨潤性シートを得た。
[Example 5]
The processed product of the first step obtained in [Example 1] was molded into a sheet having a thickness of 5 mm. This was dried at 80 ° C. for 1 hour using a ventilation dryer to obtain a dried sheet. This was cut into 5 cm squares and immersed in water at 15 ° C. for 1 hour, but the sheet-like form was maintained and a poorly water-swellable sheet was obtained.

[実施例6]
市販海苔に[実施例1] で得た第1工程の加工物を薄く塗布した。これを通風乾燥機を使用し40℃で乾燥し、耐水性の強化された乾燥海苔を得た。
[Example 6]
The processed product of the first step obtained in [Example 1] was thinly applied to commercial seaweed. This was dried at 40 ° C. using a ventilation dryer to obtain dried seaweed with enhanced water resistance.

Claims (1)

以下の製造工程において、第1工程における適当含水混合物に使用するアルカリ性物質として塩基性塩類、塩基性アミノ酸の単独又は2種以上を使用するとともに、これらの量を第1工程において適当含水混合物がゲル化しない範囲内とし、この場合のアルカリ性物質の効力低下を防止するためにpH緩衝剤としてグリシンを使用することにより、第1工程における放置時間を5分以上90分未満内に短縮することを可能としたことを特徴とするコンニャクを利用した水難溶化食品又は水難膨潤化食品の製造方法。
(1) 微粉化コンニャク粉を多糖類で造粒したコンニャク素材とアルカリ性物質との適当含水混合物を、下限は該混合物が凍結しない温度、上限は50℃未満に調整した温度条件下で一定時間放置して液状もしくはゾル状の加工物を得る第1工程、
(2) 第1工程で得た液状もしくはゾル状の加工物を他の物質と混合し、それを加熱又は冷凍又は乾燥することにより、多種多様な用途のある水難溶化食品又は水難膨潤化食品を得る第2工程。
In the following production process, basic salts and basic amino acids are used alone or in combination of two or more as alkaline substances to be used in the appropriate water-containing mixture in the first step. and within a range not of, by using glycine as a pH buffer in order to prevent the efficacy decrease of the alkaline substance in this case, allows to shorten the exposure time in the first step in less than 5 minutes or more 90 minutes A method for producing a poorly water-soluble food or a poorly water-swelled food using konjac, characterized in that
(1) Appropriate water-containing mixture of konjac raw material and alkaline substance made by granulating micronized konjac flour with polysaccharide, left at a temperature lower than the temperature at which the mixture is not frozen and upper temperature adjusted to less than 50 ° C for a certain period of time A first step of obtaining a liquid or sol workpiece,
(2) The liquid or sol processed product obtained in the first step is mixed with other substances and heated, frozen or dried to produce a poorly water-soluble or low-swelling food with various uses. A second step to obtain.
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