JP5348677B1 - Fixing pressure roll and fixing device - Google Patents

Abstract

A low-heat capacity fixing pressure roll and a fixing device capable of suppressing variation in axial hardness while reducing roll hardness are provided.
A fixing pressure roll 1 used for a fixing unit of a fixing device includes a core body 11, an elastic layer 12 provided around the core body 11, and a release layer provided around the elastic layer 12. 13 and the elastic layer 12 is made of a cured silicone rubber that holds a void formed by a microresin balloon and a porous filler in a dispersed state.
[Selection] Figure 1

Description

  The present invention relates to a fixing pressure roll and a fixing device having an elastic layer made of silicone rubber, and is suitable for use in a fixing roll and a pressure roll of a fixing portion.

  In image forming apparatuses such as copying machines, facsimile machines, and laser beam printers, a fixing roll and a pressure roll are used in a fixing unit that fixes unfixed toner. Such a fixing pressure roll includes a metal core, an elastic layer made of silicone rubber, and a release layer made of fluororesin.

  In order to perform good fixing, it is effective to secure a wide fixing width and efficiently supply heat to the toner. For this reason, low-heat-capacity foamed silicone rubber is often used for the elastic layer of the fixing pressure roll, which has a low hardness and does not easily remove heat from a heat source built in an opposing fixing belt or the like. However, the foamed silicone rubber has a problem that the shape and size of the cells formed by the gas of the foaming agent are not uniform and the durability is inferior.

  Therefore, a method has been proposed in which a microresin balloon is blended with silicone rubber, and a cell is formed with the microresin balloon (see Patent Document 1). Further, ethylene glycol or the like is blended with the microresin balloon to destroy the microresin balloon or A method has been proposed in which pores are formed between cells by vaporization of glycol or the like to form a continuous bubble (see Patent Document 2).

  However, the method of forming cells with a microresin balloon has a problem that the degree of open cells is low and sufficient hardness reduction cannot be realized. In addition, the method of forming hole paths between cells with a microresin balloon and ethylene glycol has a problem in that the degree of dispersion of the hole paths varies and an axial hardness difference is likely to occur.

JP 2007-065424 A Japanese Patent No. 3969942

  In view of such circumstances, it is an object of the present invention to provide a fixing and pressing roll and a fixing device having a low heat capacity capable of suppressing variation in axial hardness while reducing roll hardness.

An aspect of the present invention that solves the above problem is a fixing pressure roll used in a fixing unit of a fixing device, and includes a core, an elastic layer provided around the core, and around the elastic layer. A release layer provided, and the elastic layer includes a void formed by a microresin balloon, porous silicon oxide, porous alumina, porous zeolite, porous zirconium oxide, porous titanium oxide, porous A porous filler that is at least one selected from the group consisting of porous magnesium oxide, porous zinc oxide, porous silicon nitride, porous calcium carbonate, porous calcium oxide, and porous aluminum nitride is held in a dispersed state curing silicone rubber is constructed, the space between is the fixing pressure roller characterized that you have been artificially communicated with each other by the porous filler.

According to the invention, the porous filler in the elastic layer uniformly and stably dispersed throughout the layer, for communicating in a pseudo manner a gap between formed by the micro-resin balloons each other, the porous elastic layer Can be improved and the hardness can be lowered. Thereby, it is possible to realize a fixing and pressure roll having a low heat capacity capable of suppressing the variation in the hardness in the axial direction while reducing the roll hardness (the hardness measured with the roll shape).

  Here, the porous filler is preferably at least one selected from the group consisting of porous silicon oxide and porous alumina.

  According to this, the porous filler is more uniformly and stably dispersed throughout the elastic layer. Thereby, the variation in the hardness in the axial direction can be further suppressed while lowering the roll hardness.

  Here, the inner diameter of the voids is preferably distributed in a range of 10 μm to 200 μm, and the average particle diameter of the porous filler is preferably 1 μm to 20 μm.

  According to this, the porous filler in the elastic layer can further improve the porosity of the elastic layer together with the void formed by the microresin balloon, and can reduce the hardness. Thereby, the variation in the hardness in the axial direction can be further suppressed while lowering the roll hardness.

  Another aspect of the present invention is a fixing device comprising the fixing pressure roll.

  According to this invention, since the fixing pressure roll that suppresses the variation in the axial hardness while suppressing the roll hardness is provided, it is possible to secure a wide fixing width and realize a fixing device having good fixing properties. it can.

  According to the present invention, it is possible to realize a fixing and pressure roll and a fixing device having a low heat capacity capable of suppressing variations in hardness in the axial direction while reducing the roll hardness. By using such a fixing pressure roll for the fixing unit, a wide fixing width can be secured and the toner fixing property can be improved.

FIG. 3 is a transverse sectional view and a longitudinal sectional view of a fixing pressure roll according to Embodiment 1. It is a schematic diagram showing the state where each space | gap formed with the micro resin balloon is quasi-communicatively connected by the porous filler. 1 is a cross-sectional view of a fixing device including a fixing pressure roll according to Embodiment 1. FIG. 6 is a cross-sectional view of a fixing device including a fixing pressure roll according to Embodiment 2. FIG. FIG. 5 is a cross-sectional view of a fixing device including a fixing pressure roll according to a third embodiment. 6 is a cross-sectional view of a fixing device including a fixing pressure roll according to Embodiment 4. FIG. 4 is a graph of a reaction force measurement result of a pressure roll according to Example 1. 2 is a SEM observation photograph of Example 1 and Comparative Example 1. It is a SEM observation photograph of Example 7 and Comparative Example 3.

  Hereinafter, the present invention will be described in detail based on embodiments.

(Embodiment 1)
The fixing pressure roll according to the present invention is suitable for use in a fixing unit of an image forming apparatus, and is used for fixing an unfixed toner image on a recording medium with heat and pressure in the fixing unit. is there. In this embodiment, a pressure roll is illustrated as an example of a fixing pressure roll.

  FIG. 1 is a transverse sectional view and a longitudinal sectional view of a pressure roll according to this embodiment. The pressure roll 1 includes a core body 11, an elastic layer 12 provided around the core body 11, and a release layer 13 provided around the elastic layer 12.

  The core body 11 is made of a metal or a resin material. The metal or resin material is not particularly limited as long as it can be used as the core of the pressure roll 1. Moreover, there is no restriction | limiting also about the shape of the core 11, and even if it is hollow, it does not need to be hollow.

  The elastic layer 12 is formed by dispersing voids formed by a micro resin balloon and a porous filler in a cured silicone rubber. Specifically, it is formed by curing a silicone rubber composition prepared by blending a silicone rubber with a microresin balloon and a porous filler. Thereby, although details will be described later, the micro resin balloon breaks, cracks, or contracts, and the portion where the micro resin balloon exists becomes a void. That is, in the present invention, the void formed by the microresin balloon means a space where the microresin balloon is present before the silicone rubber composition is cured, and the microresin balloon is destroyed after the silicone rubber composition is cured. It does not matter whether a microresin balloon is present in the space.

  Further, the size of the gap may change depending on how the microresin balloon is broken. Therefore, the size of the gap is almost the same as, or larger or smaller than, the average particle diameter of the initial microresin balloon. The microresin balloon needs to be destroyed at the time of curing, but the timing and state of the destruction can be controlled by appropriately changing the heating conditions at the time of curing. Therefore, heat curing may be performed in one step, or may be divided into two steps of primary heating and secondary heating.

  Further, the porous filler exists in a dispersed state as it is by heat curing, and the porous filler is dispersed in the matrix between the voids. In the present invention, since the porous filler is present in a dispersed state between the voids formed by the microresin balloon, each void is assumed to be in a state of being in pseudo communication with each other with the porous filler.

  FIG. 2 is a schematic view showing a state in which each void formed by the microresin balloon is quasi-communicated with a porous filler. The micro resin balloon 2 forms the void 3 in the elastic layer 12 in a state where it is broken, cracked or contracted due to breakage. FIG. 2 illustrates a gap 3 formed by contracting the microresin balloon 2. Since the porous filler 4 is uniformly dispersed in the matrix between the broken microresin balloons 2, the voids can be connected in a pseudo manner, and the porous filler 4 is porous together with the microresin balloon 2. Is expressed.

  The silicone rubber is not particularly limited as long as it is cured by heating to produce an elastic silicone rubber, and liquid silicone rubber or millable silicone rubber can be used. Such a silicone rubber can use what is marketed, and of course, you may use 2 or more types together.

  The micro resin balloon 2 is obtained by enclosing a liquefied gas or gas with a thermoplastic polymer shell. The micro resin balloon 2 used in the present invention is broken by heating to form the void 3 in the elastic layer 12. Specifically, when a silicone rubber composition containing a liquid or millable silicone rubber is cured, the thermoplastic polymer shell of the microresin balloon is broken into a broken state, a softened and cracked state, or a contracted state. . When the microresin balloon is broken due to cracking, the liquefied gas or gas contained in the thermoplastic polymer shell is volatilized and removed, and the above-described void is formed in the cracked microresin balloon portion. In addition, the micro resin balloon in a cracked state or a contracted state forms the above-described gap as it is.

  The micro-resin balloon can be used either an already-expanded one or an un-expanded one. However, in the case of liquid silicone rubber, it is preferable to use an already-expanded micro-resin balloon. It is preferable to use a resin balloon.

  The average particle size of the microresin balloon is in the range of about 6 μm to 45 μm for the unexpanded one and about 20 μm to 130 μm for the already inflated one. In addition, the average particle diameter of the micro resin balloon in the present invention is a value of a median diameter (D50) measured by a laser diffraction / scattering particle size distribution meter.

  In the case of an already inflated microresin balloon, the inner diameter of the void formed by the destruction of the microresin balloon is preferably about the same as or larger than the average particle diameter before destruction. Specifically, it is preferably distributed in the range of 10 μm to 200 μm, and more preferably in the range of 50 μm to 100 μm.

  In the case of an unexpanded microresin balloon, it is usually several times to several tens of times larger than the average particle size before breaking. For example, when an unexpanded microresin balloon having an average particle diameter of 10 μm to 16 μm is used, it is preferably distributed in the range of 20 μm to 200 μm, and more preferably in the range of 50 μm to 100 μm after breaking. . The distribution of the inner diameter refers to a range calculated by measuring the inner diameter of the void for each microresin balloon based on an electron micrograph. As such a micro resin balloon, a commercially available one can be used, and either unexpanded or already expanded may be used. Of course, two or more kinds may be used in combination. In addition, what is necessary is just to select the compounding quantity of a micro resin balloon suitably according to the kind of porous filler mentioned later, a particle size, etc.

  The porous filler means a material having a large pore volume and specific surface area, for example, porous silica, porous alumina, porous zeolite, porous zirconium oxide, porous titanium oxide, porous magnesium oxide, porous oxidation. Examples thereof include zinc, porous silicon nitride, porous calcium carbonate, porous calcium oxide, and porous aluminum nitride. Among these, it is preferable to use at least one selected from the group consisting of porous silica and porous alumina.

  The average particle size of the porous filler is preferably 1 μm to 20 μm, more preferably 1 μm to 5 μm. In addition, the average particle diameter of the porous filler in the present invention is a value measured by a coal counter method. Such a porous filler can use what is marketed, and of course, you may use 2 or more types together.

  The porous filler used in the present invention artificially communicates voids formed by micro resin balloons. The porous filler is uniformly and stably dispersed as it is in the elastic layer, and is uniformly present in the matrix between the voids formed by the destruction of the microresin balloon.

  Such a quasi-communication state is different from the continuous bubble state formed by vaporization of the conventional vaporization component, and the dispersion state does not vary and is uniformly formed over the entire elastic layer. . Therefore, the hardness of the elastic layer is lowered over the entire roll, and variations in hardness in the axial direction are suppressed.

  In addition, the thickness of the elastic layer 12 is 0.5 mm-20 mm, for example, Preferably, it is 2 mm-6 mm. This is for improving the toner fixing property and improving the image quality of the image.

  The release layer 13 is preferably made of a highly releasable synthetic resin material, and examples thereof include a fluororesin. Examples of the fluororesin include perfluoroalkoxy fluororesin (PFA), polytetrafluoroethylene (PTFE), tetrafluoroethylene / hexafluoropropylene copolymer (FEP), and tetrafluoroethylene / ethylene copolymer (ETFE). In particular, perfluoroalkoxy fluororesin (PFA) is preferable. Although there will be no restriction | limiting in particular if the thickness of a mold release layer is a thickness which can provide a high mold release property to a fixing pressure roll, For example, they are 1 micrometer-100 micrometers, Preferably, they are 10 micrometers-50 micrometers. Note that the release layer may not be provided.

  The fixing pressure roll according to the present invention includes an elastic layer with low hardness and little variation in axial hardness over the entire roll, so that a wide fixing width can be secured at the fixing portion, and toner fixing properties can be secured. Can be improved.

  Here, a method for producing the fixing pressure roll of the present invention will be described below.

  When the fixing pressure roll of the present invention is produced from a liquid silicone rubber composition, it can be produced by integrally molding the core body 11, the elastic layer 12 and the release layer 13 provided therearound. This can be manufactured by an extremely simple method as compared with the conventional manufacturing method in which the elastic layer 12 and the release layer 13 are formed in separate steps.

  In a conventional manufacturing method, specifically, a method of manufacturing a fixing pressure roll by blending a microresin balloon and ethylene glycol into liquid silicone rubber, a process of vaporizing ethylene glycol or the like in the process of forming an elastic layer is necessary. For this reason, the release layer must be formed after the elastic layer is formed. In the present invention, since the elastic layer and the release layer can be integrally formed, the number of steps can be reduced, and the manufacturing cost and the manufacturing time can also be reduced.

  First, a liquid silicone rubber composition is prepared by blending a liquid silicone rubber with a microresin balloon and a porous filler. Next, for example, the core body 11 is placed in a mold equipped with a PFA tube or the like as the release layer 13, and the liquid silicone rubber composition is injected around the core body 11, and the injected liquid silicone rubber composition The object is cured by heating.

  On the other hand, when the fixing pressure roll is manufactured from a millable silicone rubber composition, a microresin balloon and a porous filler are added to the millable silicone rubber to prepare a millable silicone rubber composition. Next, for example, a millable silicone rubber composition is extruded and inserted, and the core body 11 is inserted and cured by heating to form a release layer 13 made of a PFA tube or the like.

  By this heat curing, the microresin balloon in the liquid or millable silicone rubber composition is broken into a cracked state, a cracked state, or a contracted state, and the void 3 is formed in the elastic layer 12.

  In order to break the micro resin balloon into a broken state, a cracked state, or a contracted state, the heating temperature is preferably set to be equal to or higher than the softening temperature of the micro resin balloon shell, that is, the thermoplastic polymer.

  In the case where the fixing pressure roll is produced from the liquid silicone rubber composition, the liquid silicone rubber composition is heated and cured at a temperature lower than the softening temperature of the thermoplastic polymer, and then the temperature is higher than the softening temperature of the thermoplastic polymer. The microresin balloon may be broken by heating.

  The fixing pressure roll manufactured in this way has a low heat capacity with a low roll hardness throughout the roll and a small variation in axial hardness.

  This is because the porous filler is uniformly and stably dispersed as it is in the elastic layer, and the voids formed by the destruction of the microresin balloon form a pseudo communication state with the porous filler. This is due to

  In addition to using a PFA tube, the release layer may be formed by applying a coating solution, for example. Needless to say, even if the elastic layer and the release layer are not formed integrally, and manufactured in a separate process, a low-heat-capacity fixing pressure roll having low roll hardness and little variation in axial hardness can be manufactured.

  Next, the fixing device will be described.

  The fixing device 10 according to the present invention is mounted on an image forming apparatus and fixes an unfixed toner image on a recording medium with heat and pressure.

  FIG. 3 is a schematic cross-sectional view showing the fixing device according to the present embodiment. As shown in FIG. 3, the fixing device 10 includes a pressure roll 1 according to the first embodiment, a fixing belt 14 disposed facing the pressure roll 1, and a fixing belt at a position facing the pressure roll 1. The pressure member 15 is pressed against the pressure roll 1 from the inside to form a predetermined nip portion, and the heating unit 16 is configured to heat the fixing belt 14 to a predetermined temperature.

  The fixing belt 14 may be any belt that can form a predetermined nip portion by pressure contact with the opposing pressure roll 1. For example, the fixing belt 14 is formed on a metal substrate having at least one seamless electroformed belt and an inner peripheral surface of the metal substrate. A sliding layer, an elastic layer formed on the outer peripheral surface of the metal substrate, and a release layer formed on the outer peripheral surface of the elastic layer.

  The pressing member 15 is made of an elastic body such as rubber, resin, metal, and the like. A layer made of a fluororesin or the like may be formed on the surface as needed, or a sliding sheet, a groove, or the like may be provided. Moreover, the uneven | corrugated process may be given to the surface of the sliding sheet.

  The heating unit 16 may be any unit that can heat the fixing belt 14 and may be provided outside the fixing belt 14. Examples of the heating means 16 include a halogen heater, a heating wire heater, an infrared heater, and electromagnetic induction heat generation by an exciting coil (heat source). The heating means 16 may be built in the pressing member 15.

  The fixing device 10 according to the present invention includes a pressure roll 1 having a low heat capacity and a low roll capacity and a small variation in axial hardness. Accordingly, it is possible to realize a fixing device that can secure a wide fixing width and improve the toner fixing property in the fixing unit.

(Embodiment 2)
In the second embodiment, a fixing roll and a pressure roll are illustrated as examples of the fixing pressure roll. In addition, the same code | symbol is attached | subjected to the same member as Embodiment 1, and the overlapping description is abbreviate | omitted.

  FIG. 4 is a schematic cross-sectional view of a fixing device including a fixing roll and a pressure roll according to the second embodiment. As shown in FIG. 4, the fixing device 10 </ b> A includes a pressure roll 1, a fixing belt 14 disposed to face the pressure roll 1, and the pressure belt 1 from the inside instead of the pressing member. A fixing roll 1A that presses against the fixing roll 1A. Although not shown in the figure, the heating means is disposed outside the fixing roll 1A. The fixing pressure roll of the present invention can be used as the fixing roll 1A shown in FIG.

(Embodiment 3)
In the third embodiment, an inner roll and a pressure roll are illustrated as examples of the fixing pressure roll. In addition, the same code | symbol is attached | subjected to the same member as Embodiment 1, and the overlapping description is abbreviate | omitted.

  FIG. 5 is a schematic cross-sectional view of a fixing device including an inner roll and a pressure roll according to the third embodiment.

  As shown in FIG. 5, the fixing device 10 </ b> B includes a pressure roll 1, a fixing belt 14 disposed to face the pressure roll 1, and an inner that presses the fixing belt 14 against the pressure roll 1 from the inside. A roll 1B and a heating roll 17 incorporating a heating means are provided. Inside the fixing belt 14, an inner roll 1 </ b> B and a heating roll 17 incorporating a heating unit are disposed, and the fixing belt 14 is rotationally driven by the inner roll 1 </ b> B and the heating roll 17. The fixing pressure roll of the present invention can be used as the inner roll 1B shown in FIG.

(Embodiment 4)
In the fourth embodiment, a fixing roll and a pressure roll are illustrated as examples of the fixing pressure roll. The same members as those in the first embodiment are denoted by the same reference numerals, and redundant description is omitted.

  FIG. 6 is a schematic cross-sectional view of a fixing device including a fixing roll and a pressure roll according to the fourth embodiment.

  As shown in FIG. 6, the fixing device 10 </ b> C includes a pressure roll 1 and a fixing roll 1 </ b> C disposed to face the pressure roll 1. Although not shown, the fixing roll 1C has a heating means built therein. The fixing pressure roll of the present invention can be used as the fixing roll 1C shown in FIG.

  EXAMPLES Hereinafter, although an Example demonstrates this invention, this invention is not limited.

Example 1
The pressure roll 1 was manufactured in the following procedures. 100 parts by mass of liquid silicone rubber (Toray Dow Corning; DY35-796), 2.5 parts by mass of microresin balloon (Matsumoto Yushi Seiyaku; F-65DE: already expanded, average particle size 40 μm to 60 μm) and SiO ₂ porous 5 parts by mass of a porous filler (manufactured by AGS S-Tech; Sunsphere H-32, average particle diameter 3 μm, pore volume 2 mL / g, pore diameter 10 nm, specific surface area 700 m ² / g) is added for 10 minutes with a Hobart mixer. The liquid silicone rubber composition was prepared by stirring.

  An iron core with a diameter of 18 mm, coated and dried with a Toray Dow Corning primer, is placed on the lower flange, the inner surface is etched with liquid ammonia, and a Toray Dow Corning primer is coated and dried. The one mounted on the mold was covered.

  After the upper flange was placed and fixed, the liquid silicone rubber composition prepared with a casting machine was filled from the lower flange side and placed in a thermostatic bath at 130 ° C. for 30 minutes to cure the liquid silicone rubber.

  Then, it cooled and demolded. The depressurized roll was heated in a thermostatic bath at 230 ° C. for 10 hours, and the outer diameter provided with the core 11, the elastic layer 12 made of a cured silicone rubber composition, and the release layer 13 made of a PFA tube. A pressure roll 1 having a diameter of 30 mm was obtained.

  In addition to the production of the pressure roll 1, a test piece made of an elastic layer was produced in the same process as in Example 1. The test piece was prepared by pouring the prepared liquid silicone rubber composition into a 6 mm-thick test piece mold and press-molding it for 5 minutes with a hot plate at 130 ° C., and then placing it in a constant temperature bath at 230 ° C. for 10 hours.

(Example 2)
In Example 2, the pressure roll 1 was produced in the same process as in Example 1 except that the amount of the porous filler was 2.8 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced.

(Example 3)
In Example 3, the pressure roll 1 was produced in the same process as in Example 1 except that porous alumina was used as the porous filler. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced. In addition, the thing made from Iwatani Chemical Industry (RK-30, the average particle diameter of 0.7 micrometer, the specific surface area of 130 m < ² > / g) was used for the porous alumina.

Example 4
In Example 4, the pressure roll 1 was produced in the same process as in Example 3 except that the amount of the porous filler was 2.8 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced.

(Example 5)
In Example 5, the pressure roll 1 is the same as in Example 1 except that the average particle diameter of the microresin balloon is 90 μm to 130 μm larger than that of Example 1 and the blending amount of the microresin balloon is 3 parts by mass. Was made. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced. In addition, the micro resin balloon made from Matsumoto Yushi Seiyaku (F-80DE: already expanded, average particle diameter of 90 μm to 130 μm) was used.

(Example 6)
In Example 6, the pressure roll 1 was produced in the same process as Example 5 except that the amount of the porous filler was 2.8 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced.

  About Examples 7-10, the pressure roll 1 was manufactured in the following procedures.

(Example 7)
Millable silicone rubber (Shin-Etsu Chemical Co., Ltd .; X-30-3760U) 100 parts by mass, catalyst (Shin-Etsu Chemical Co., Ltd .; C-25A) 0.5 part by mass and vulcanizing agent (Shin-Etsu Chemical Co., Ltd .; C-25B) To 2.5 parts by mass, 2 parts by mass of a microresin balloon (manufactured by Matsumoto Yushi Seiyaku; F-36: unexpanded average particle diameter of 10 μm to 16 μm, average particle diameter after expansion of 70 μm to 100 μm) and SiO ₂ porous filler ( Made by AGS S-Itech; Sunsphere H-32, average particle diameter 1 μm, pore volume 2 mL / g, pore diameter 10 nm, specific surface area 700 m ² / g) 1 part by mass and mixed until uniform with two rolls A millable silicone rubber composition was prepared. Thereafter, using a crosshead type extruder, the millable silicone rubber composition was extruded into a tube shape together with an iron core having a diameter of 18 mm coated and dried with a Toray Dow Corning primer, and heated in a thermostat at 230 ° C. for 8 hours. . The roll was ground to an outer diameter of φ29.9 mm with a cylindrical grinder, and then an adhesive was applied to the surface and covered with a PFA tube to obtain a pressure roll 1 having an outer diameter of 30 mm.

  In addition to the production of the pressure roll 1, a test piece made of an elastic layer was produced in the same process as in Example 7. The test piece was produced by molding the prepared millable silicone rubber composition into a 10 mm thick sheet and heating it in a thermostatic bath at 230 ° C. for 8 hours.

(Example 8)
In Example 8, the pressure roll 1 was produced in the same process as Example 7, except that the amount of the porous filler was 3 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 7 was produced.

Example 9
In Example 9, the pressure roll 1 was produced in the same process as Example 7 except that the blending amount of the micro resin balloon was 3 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 7 was produced.

(Example 10)
In Example 10, the pressure roll 1 was produced in the same process as Example 7 except that the blending amount of the micro resin balloon was 3 parts by mass and the blending amount of the porous filler was 3 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 7 was produced.

(Comparative Example 1)
In Comparative Example 1, a pressure roll 1 was produced in the same process as in Example 1 except that no porous filler was used. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced.

(Comparative Example 2)
In Comparative Example 2, the pressure roll 1 was produced in the same process as in Examples 5 and 6 except that the average particle size of the microresin balloon was 90 μm to 130 μm larger than that in Example 1 and no porous filler was used. Moreover, the test piece which consists of an elastic layer similarly to Example 1 was produced. Note that the same microresin balloon as in Example 5 was used.

(Comparative Example 3)
In Comparative Example 3, the pressure roll 1 was produced in the same process as in Example 7 except that no porous filler was used. Moreover, the test piece which consists of an elastic layer similarly to Example 7 was produced.

(Comparative Example 4)
In Comparative Example 4, the pressure roll 1 was produced in the same process as in Example 7 except that the porous filler was not used and the blending amount of the micro resin balloon was changed to 3 parts by mass. Moreover, the test piece which consists of an elastic layer similarly to Example 7 was produced.

(Test Example 1)
The pressure roll 1 produced in Example 1 is attached to an evaluation machine for pressure roll, and durability is measured by measuring a reaction force change while rotating at a linear speed of 300 mm / sec in a state where the compression rate is 40% and heated to 150 ° C. Sexuality was evaluated.

  FIG. 7 is a measurement result of the reaction force change of the pressure roll. As shown in FIG. 7, it was confirmed that the pressure roll 1 manufactured according to the procedure of Example 1 had a sufficient durability with little reaction force change even after 300 hours.

(Test Example 2)
The hardness and specific gravity of the elastic body were evaluated by measuring the Asker C hardness and specific gravity of the test pieces (hereinafter referred to as “elastic bodies”) produced based on Examples 1 to 10 and Comparative Examples 1 to 4, respectively.

  The specific gravity was calculated as the weight per unit volume by calculating the weight and volume of liquid silicone rubber or millable silicone rubber, microresin balloon and porous filler, respectively.

  The Asker C hardness was measured using an Asker C hardness meter (manufactured by Kobunshi Keiki). The specific gravity was measured using an electronic hydrometer MD-200S (manufactured by A & D).

  Table 1 shows the structures of the liquid or millable silicone rubber compositions before curing of the elastic bodies of Examples 1 to 10 and Comparative Examples 1 to 4, and the measurement results of Asker C hardness and specific gravity.

  For Examples 1 and 2 consisting of an elastic body made by curing a liquid silicone rubber composition, that is, an elastic body containing a microresin balloon (average particle size 40 μm to 60 μm) and a porous filler, a porous filler is blended. Compared with the comparative example 1 which consists of an elastic body which has not been carried out, hardness became low and specific gravity also became small. Thereby, it turned out that hardness and specific gravity can be made low by mix | blending not only a micro resin balloon but a porous filler with an elastic body.

  In addition, Examples 1 and 2 were more easily deformed by finger pressure than Comparative Example 1. Thereby, it was guessed that the space | gap in Examples 1 and 2 was connected in a pseudo manner by the porous filler, and the hardness was reduced.

  Moreover, Example 1 (5 mass parts) with many compounding quantities of a porous filler becomes still lower in hardness and specific gravity compared with Example 2 (2.8 mass parts) with few compounding quantities of a porous filler. It was. Thereby, it turned out that the one where the compounding quantity of a porous filler is much can make hardness and specific gravity still lower.

  In Examples 3 and 4, it was found that the hardness of the elastic body can be reduced even if the porous filler is alumina. Moreover, from the hardness of Examples 3 and 4, it was found that the hardness could be lowered by increasing the blending amount of the porous filler.

  About Example 5 and 6 which consists of an elastic body which contains a micro resin balloon (average particle diameter of 90 micrometers-130 micrometers) and a porous filler, compared with the comparative example 2 which consists of an elastic body which is not mix | blending a porous filler, hardness is. It became low. Thereby, it turned out that hardness can be made low by mix | blending not only a micro resin balloon but a porous filler with an elastic body.

  Further, from the hardnesses of Examples 5 and 6, it was found that the hardness can be further reduced by increasing the blending amount of the porous filler.

  Moreover, even if it increased the average particle diameter of the micro resin balloon compared with Examples 1-4, it turned out that the hardness reduction of an elastic body is realizable by mix | blending a porous filler with an elastic body.

  For Examples 7 and 8 comprising an elastic body prepared by curing a millable silicone rubber composition, that is, an elastic body containing a microresin balloon (average particle diameter after expansion of 70 μm to 100 μm) and a porous filler, Compared with the comparative example 3 which consists of an elastic body which does not mix | blend a filler, hardness became low and specific gravity also became small. Similarly, in Examples 9 and 10 made of an elastic body including a micro resin balloon (average particle diameter after expansion of 70 μm to 100 μm) and a porous filler, the hardness is lower and the specific gravity is also smaller than that of Comparative Example 4. became. Thereby, it turned out that hardness and specific gravity can be made low by mix | blending not only a micro resin balloon but a porous filler with an elastic body.

  Further, Examples 7 and 8 were more easily deformed by finger pressure than Examples 3 and 9 and 10 were compared with Comparative Example 4. Thereby, it was estimated that the space | gap in Examples 7-10 was communicated in a pseudo manner with the porous filler, and the hardness was reduced.

  Moreover, Example 8 (3 mass parts) with many compounding quantities of a porous filler became still lower in hardness and specific gravity compared with Example 7 (1 mass part) with few compounding quantities of a porous filler. Similar results were obtained for the comparison of Examples 9 and 10. Thereby, it turned out that the one where the compounding quantity of a porous filler is much can make hardness and specific gravity still lower.

  As described above, it can be seen that by adding not only the micro resin balloon to the elastic body but also the porous filler, it is possible to improve the hardness and heat capacity of the cured silicone rubber composition, that is, the elastic body. It was.

  By mounting such a fixing pressure roll having an elastic layer made of an elastic body having a low hardness and a low heat capacity on the fixing device, a wide nip area can be secured in the fixing portion, and the toner fixing property can be improved. it can.

(Test Example 3)
The elastic bodies of Examples 1 and 7 and Comparative Examples 1 and 3 prepared by the above procedure were observed using a scanning electron microscope (SEM).

  8A and 8B show SEM photographs of the elastic body of Example 1 observed at magnifications of 500 times and 1000 times, respectively. FIG. 8C shows an SEM photograph of the elastic body of Comparative Example 1 observed at a magnification of 500 times. FIGS. 9A and 9B show SEM photographs of the elastic bodies of Example 7 and Comparative Example 3 observed at a magnification of 500 times, respectively.

  As shown in FIG. 8A, the elastic body of Example 1 produced by curing the liquid silicone rubber composition has a microresin balloon of about 20 μm to 50 μm over the entire layer. In the meantime, a plurality of small voids due to the porous filler of about 3 μm to 5 μm were formed over the entire layer.

  On the other hand, as shown in FIG. 9 (a), the elastic body (Example 7) produced by curing the millable silicone rubber composition is a microresin having a larger inner diameter than the microresin balloon shown in FIG. 8 (a). Balloons (about 50-100 μm) were present throughout the layer. This is due to the expansion of the unexpanded microresin balloon. In addition, a plurality of small voids due to the porous filler of about 3 μm to 5 μm were confirmed between the microresin balloons as in FIG.

  Further, the inner diameter of the void formed by the destruction of the microresin balloon (black portions in FIGS. 8 and 9) is about 20 μm to 50 μm in the case of the elastic body of Example 1, and in the case of Example 7, It was about 50 μm to 100 μm.

  In addition, from FIG. 8B and FIG. 9A, it is not possible to confirm whether the micro resin balloon is completely cracked and destroyed or contracted, but a part of the micro resin balloon is broken by cracks. It was confirmed that it remained.

  In contrast, as shown in FIGS. 8C and 9B, in the elastic bodies of Comparative Examples 1 and 3, the microresin balloon exists over the entire layer, but the microresin balloon is porous. Small voids due to the quality filler were not seen.

  As a result, for the elastic bodies of Examples 1 and 7, it was confirmed that the porous filler was uniformly dispersed between the micro resin balloons. Thereby, it was confirmed that the voids formed by the destruction of the microresin balloon are in pseudo communication with the porous filler.

DESCRIPTION OF SYMBOLS 1 Pressure roll 2 Micro resin balloon 3 Cavity 4 Porous filler 1A Fixing roll 1B Inner roll 1C Fixing roll 10 Fixing device 11 Core body 12 Elastic layer 13 Release layer 14 Fixing belt 15 Pressing member 16 Heating means 17 Heating roll

Claims (4)

A fixing pressure roll used in a fixing unit of a fixing device,
A core body, an elastic layer provided around the core body, and a release layer provided around the elastic layer,
The elastic layer includes a void formed by a microresin balloon, porous silicon oxide, porous alumina, porous zeolite, porous zirconium oxide, porous titanium oxide, porous magnesium oxide, porous zinc oxide, porous It is composed of a cured silicone rubber that holds in a dispersed state a porous filler that is at least one selected from the group consisting of silicon nitride, porous calcium carbonate, porous calcium oxide, and porous aluminum nitride ,
The gap between the fixing pressure roller, characterized in Rukoto mutually pseudo been communicated with by the porous filler. The fixing pressure roll according to claim 1 ,
The fixing pressure roll, wherein the porous filler is at least one selected from the group consisting of porous silicon oxide and porous alumina. In the fixing pressure roll according to claim 1 or 2 ,
The inner diameter of the gap is distributed in the range of 10 μm to 200 μm,
The fixing pressure roll, wherein the porous filler has an average particle diameter of 1 μm to 20 μm. Fixing apparatus characterized by comprising a fixing pressure roller as described in any one of claims 1-3.