JP5301024B2 - Method for producing coffee-containing beverage - Google Patents

Method for producing coffee-containing beverage Download PDF

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JP5301024B2
JP5301024B2 JP2012256324A JP2012256324A JP5301024B2 JP 5301024 B2 JP5301024 B2 JP 5301024B2 JP 2012256324 A JP2012256324 A JP 2012256324A JP 2012256324 A JP2012256324 A JP 2012256324A JP 5301024 B2 JP5301024 B2 JP 5301024B2
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利幸 赤地
寛之 加藤
清史 川井
隆文 角久間
美奈 山崎
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Daiwa Can Co Ltd
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本発明はコーヒー含有飲料の製造方法に関し、特に加熱殺菌時の香りの劣化を抑制しつつ、コーヒー本来の自然な香りを有するとともに、酸味と苦みの呈味バランスに優れたコーヒー含有飲料を製造する方法に関する。   The present invention relates to a method for producing a coffee-containing beverage, and in particular, produces a coffee-containing beverage that has a natural natural scent of coffee and an excellent balance between sourness and bitterness while suppressing deterioration of the scent during heat sterilization. Regarding the method.

コーヒーは古くから飲用されている嗜好飲料であり、その独特の香りが愛飲されている重要な要因となっている。コーヒーには各種の香気成分が含まれているが、これらの香気成分は不安定で、加熱処理により容易に劣化してしまうことが知られている。現在、様々なコーヒー飲料製品が存在するが、製造工程において殺菌処理のため、高温での加熱処理が必要であり、コーヒーの淹れたての香りを保持することは非常に難しかった。   Coffee is a favorite beverage that has been drunk since ancient times, and its unique scent is an important factor in drinking. It is known that coffee contains various fragrance components, but these fragrance components are unstable and easily deteriorate by heat treatment. Currently, there are various coffee beverage products, but heat treatment at a high temperature is required for the sterilization process in the manufacturing process, and it has been very difficult to maintain the fresh scent of coffee.

このような課題を解決するため、従来、様々な方法が提案されている。例えば、コーヒー抽出液をpH3.0〜5.5の条件で加熱殺菌することによって、加熱殺菌時の香気成分の劣化を抑制するコーヒー飲料の殺菌方法が提案されている(特許文献1参照)。しかしながら、この方法では、コーヒー抽出物の加熱殺菌の際にpH調整のための酸性成分(例えば、クエン酸等)を添加する必要があり、また、加熱殺菌工程によるpH低下により最終製品のpHは3.0〜5.5よりもさらに低くなるため、香りは良好であっても、酸味と苦みの呈味バランスが著しく悪く、コーヒー飲料としては決して美味なものとは言えなかった。   In order to solve such a problem, various methods have been conventionally proposed. For example, a coffee beverage sterilization method that suppresses deterioration of aroma components during heat sterilization by heat sterilization of a coffee extract under a pH of 3.0 to 5.5 has been proposed (see Patent Document 1). However, in this method, it is necessary to add an acidic component (for example, citric acid) for adjusting the pH at the time of heat sterilization of the coffee extract, and the pH of the final product is reduced due to the pH decrease by the heat sterilization process. Since it becomes lower than 3.0-5.5, even if the fragrance is good, the taste balance between sourness and bitterness is remarkably bad, and it cannot be said that the coffee beverage is delicious.

また、乳成分及び乳化剤を含む第1の飲料成分を加熱殺菌するとともに、コーヒー抽出液を含む第2の飲料成分を第1の飲料成分よりもゆるやかな条件で加熱殺菌し、第1の飲料成分と第2の飲料成分を無菌条件下で混合して乳入りの清涼飲料(コーヒー飲料)を製造する方法も提案されている(特許文献2参照)。この方法は、コーヒー飲料を含む成分をよりゆるやかな条件で加熱殺菌することで、コーヒーの香りや味の劣化を低く抑えるというものであるものの、コーヒーの香り成分の劣化を十分に抑制することはできておらず、香り、味ともに十分に満足のいくものは得られてはいなかった。   Moreover, while heat-sterilizing the 1st drink component containing a milk component and an emulsifier, the 2nd drink component containing a coffee extract is heat-sterilized on conditions gentler than a 1st drink component, The 1st drink component A method of producing a soft drink (coffee beverage) containing milk by mixing the second beverage component and the second beverage component under aseptic conditions has also been proposed (see Patent Document 2). Although this method is to sterilize the ingredients containing coffee beverages under milder conditions to suppress the deterioration of coffee aroma and taste, it does not sufficiently suppress the deterioration of coffee aroma ingredients. It wasn't done, and there wasn't a product that was sufficiently satisfying in both aroma and taste.

特開2004−73071号JP 2004-73071 A 特開平11−221013号JP-A-11-2221013

本発明の課題は、加熱殺菌時の香りの劣化を抑制しつつ、コーヒー本来の自然な香りを有するとともに、酸味と苦みの呈味バランスに優れたコーヒー含有飲料の製造方法を提供することにある。   An object of the present invention is to provide a method for producing a coffee-containing beverage that has a natural aroma of coffee and an excellent balance of sourness and bitterness while suppressing deterioration of the aroma during heat sterilization. .

上記課題を解決するために、本発明者らが検討を行った結果、第1液としてコーヒー抽出液をpH4.5〜5.5の条件下で高温短時間加熱殺菌した後冷却して無菌タンクへ送液し、別途第2液としてpH調整剤を含む他の飲料成分を混合して高温短時間加熱殺菌した後冷却して無菌タンクへ送液し、最後に無菌環境下で第1液と第2液とを混合してpHを調整することによって、コーヒー本来の自然な香りを有するとともに、酸味と苦みの呈味バランスに優れたコーヒー含有飲料が得られることを見出し、本発明を完成するに至った。   As a result of investigations by the present inventors to solve the above-mentioned problems, the coffee extract as the first liquid is sterilized by heating at high temperature and short time under the condition of pH 4.5 to 5.5, and then cooled to an aseptic tank. The other beverage components containing the pH adjuster are separately mixed as the second solution, sterilized by heating at a high temperature for a short time, cooled and sent to the aseptic tank, and finally the first solution in an aseptic environment. By adjusting the pH by mixing with the second liquid, it is found that a coffee-containing beverage having a natural aroma of coffee and an excellent taste balance between sourness and bitterness can be obtained, and the present invention is completed. It came to.

すなわち、本発明にかかるコーヒー含有飲料の製造方法は、第1液として、コーヒー抽出液をpH4.5〜5.5の条件下で、121℃以上、1分以内の条件で高温短時間加熱殺菌し、その後冷却する第1液殺菌工程と、第2液として、塩基性のpH調整剤を含む飲料成分を、121℃以上、1分以内の条件で高温短時間加熱殺菌し、その後冷却する第2液殺菌工程と、前記各工程により得られた第1液と第2液とを無菌環境下で混合し、pHを5.2〜7.0に調整する混合工程とを備え、前記混合工程において、第1液と、第1液以外の飲料成分との混合比が、容積比で、第1液:第1液以外の飲料成分=1:3〜3:1の範囲であることを特徴とするものである。
また、前記コーヒー含有飲料の製造方法において、前記混合工程において、第1液と、第1液以外の飲料成分との混合比が、容積比で、第1液:第1液以外の飲料成分=1:2〜2:1の範囲であることが好適である。
また、前記コーヒー含有飲料の製造方法において、さらに、第3液として、コーヒー抽出液及びpH調整剤を含まない他の飲料成分を、121℃以上、1分以内の条件で高温短時間加熱殺菌し、その後冷却する第3液殺菌工程を備え、前記混合工程において、第1液と第2液と第3液とを無菌環境下で混合し、pHを調整することができる。
That is, in the method for producing a coffee-containing beverage according to the present invention, as a first liquid, a coffee extract is sterilized by heating at a high temperature for a short time at a temperature of 121 ° C. or more and within 1 minute under a condition of pH 4.5 to 5.5. Then, the first liquid sterilization step to be cooled and the beverage component containing a basic pH adjuster as the second liquid are sterilized by heating at a temperature of 121 ° C. or higher and within 1 minute for a short time, and then cooled. A two-component sterilization step, and a mixing step of mixing the first and second liquids obtained in the respective steps under an aseptic environment and adjusting the pH to 5.2 to 7.0, the mixing step In the above, the mixing ratio of the first liquid and the beverage components other than the first liquid is a volume ratio, and the first liquid: beverage components other than the first liquid = 1: 3 to 3: 1. It is what.
Moreover, in the said manufacturing method of a coffee containing drink, in the said mixing process, the mixing ratio of 1st liquid and drink components other than 1st liquid is a volume ratio, 1st liquid: Beverage components other than 1st liquid = A range of 1: 2 to 2: 1 is preferred.
Further, in the method for producing a coffee-containing beverage, as the third liquid, another beverage component not containing a coffee extract and a pH adjuster is sterilized by heating at a temperature of 121 ° C. or higher and within 1 minute for a short time. Then, a third liquid sterilization step for cooling is provided, and in the mixing step, the first liquid, the second liquid, and the third liquid can be mixed in an aseptic environment to adjust the pH.

た、前記コーヒー含有飲料の製造方法において、前記第2液及び第3液が乳成分を含まない場合、前記混合工程後のpHが5.2〜6.0に調整されることが好適である。
また、前記コーヒー含有飲料の製造方法において、前記第2液又は第3液が乳成分を含む場合、前記混合工程後のpHが6.0〜7.0に調整されることが好適である。
Also, in the manufacturing method of the coffee-containing beverage, and when the second liquid and the third liquid contains no dairy ingredients, pH after the mixing step preferably be adjusted to 5.2 to 6.0 is there.
Moreover, in the said manufacturing method of a coffee containing drink, when the said 2nd liquid or 3rd liquid contains a milk component, it is suitable that pH after the said mixing process is adjusted to 6.0-7.0.

本発明のコーヒー含有飲料の製造方法によれば、第1液としてコーヒー抽出液をpH4.5〜5.5の条件下で高温短時間加熱殺菌し、第2液としてpH調整剤を含む飲料成分を高温短時間加熱殺菌し、第1液と第2液とを無菌環境下で混合してpHを調整することによって、加熱殺菌時の香りの劣化を抑制しつつ、コーヒー本来の自然な香りを有するとともに、酸味と苦みの呈味バランスに優れたコーヒー含有飲料が得られる。   According to the method for producing a coffee-containing beverage of the present invention, a beverage component containing a coffee extract as a first liquid under high temperature and short time heat sterilization under conditions of pH 4.5 to 5.5 and a pH adjuster as a second liquid. By sterilizing the coffee at a high temperature for a short time and mixing the first and second liquids in an aseptic environment to adjust the pH, while suppressing the deterioration of the aroma during the heat sterilization, A coffee-containing beverage that has an excellent balance between sourness and bitterness is obtained.

試料1A〜1Cのコーヒー含有飲料の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the coffee containing drink of sample 1A-1C. 試料1D〜1Fのコーヒー含有飲料の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the coffee containing drink of sample 1D-1F. 試料2Aのコーヒー含有飲料の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the coffee containing drink of sample 2A. 試料2Bのコーヒー含有飲料の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the coffee containing drink of sample 2B. 試料2Cのコーヒー含有飲料の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the coffee containing drink of the sample 2C. 試料3のコーヒー含有飲料の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the coffee containing drink of the sample 3. FIG.

以下、本発明について詳細に説明する。
本発明の方法において、第1液として使用されるコーヒーの抽出液としては、例えば、公知の方法にてコーヒー豆を熱水抽出して得られた抽出液、あるいは他の方法により得られたコーヒーエキスが用いられる。なお、コーヒー抽出液は、濃縮あるいは希釈によって、コーヒー固形分濃度を適宜調整してもよい。本発明の方法においては、第1液として、コーヒー抽出液をpH4.5〜5.5の条件下で高温短時間加熱殺菌に供する必要がある。なお、コーヒー抽出液のpHは、コーヒー豆の品種、産地、焙煎度等により異なるものの、一般的におよそpH4.5〜6.0の範囲である。このため、コーヒー抽出液がpH4.5〜5.5の範囲内であれば、pH調整を行なわずにそのままの状態で高温短時間加熱殺菌することができ、本発明の方法においては、別途の酸性成分(すなわち、pH調整剤)の添加によるpH調整を行わないことが望ましい。例えば、クエン酸等のpH調整剤を添加することによって製品の風味を著しく損なってしまう場合がある。また、pHが5.5を超えてしまうコーヒー抽出液の場合、例えば、コーヒー豆の品種や焙煎度等を選択することによって、別途pH調整剤の添加を行うことなく、pH4.5〜5.5の範囲となるように条件設定することもできる。
Hereinafter, the present invention will be described in detail.
In the method of the present invention, the coffee extract used as the first liquid is, for example, an extract obtained by hot water extraction of coffee beans by a known method, or coffee obtained by other methods. Extract is used. In addition, you may adjust coffee solid content concentration suitably for a coffee extract by concentration or dilution. In the method of the present invention, it is necessary to subject the coffee extract as a first liquid to high-temperature and short-time heat sterilization under the condition of pH 4.5 to 5.5. The pH of the coffee extract is generally in the range of about pH 4.5 to 6.0, although it varies depending on the type of coffee beans, the production area, the roasting degree, and the like. For this reason, if the coffee extract is in the range of pH 4.5 to 5.5, it can be sterilized by heating at a high temperature for a short time without adjusting the pH. It is desirable not to adjust the pH by adding an acidic component (that is, a pH adjusting agent). For example, the addition of a pH adjusting agent such as citric acid may significantly impair the flavor of the product. Further, in the case of a coffee extract whose pH exceeds 5.5, for example, by selecting a variety of coffee beans, a roasting degree, etc., pH 4.5 to 5 without adding a pH adjusting agent separately. It is also possible to set conditions so as to be in the range of .5.

なお、コーヒーの香気成分の劣化抑制方法として、加熱殺菌時のpHを3.0〜5.5の範囲に調整することが有効であることが知られている(特開2004−73071号)。この方法によれば、加熱殺菌時のコーヒーの香気成分の保持についてのみを鑑みると、pHのより低い4.0付近の領域で加熱殺菌を行なうことが望ましいと言える。しかしながら、このような低いpH域で加熱殺菌を行うと、香りの保持効果は高いものの、最終的な製品のpHを適宜調整したとしても製品の呈味バランスが崩れてしまい、味の悪いコーヒー含有飲料となってしまう。加えて、低pH域へと調整するために、例えば、クエン酸等の酸性成分を添加する必要があり、また、結果として最終的なpH調整を行うためのpH調整剤の量も増加することとなるため、これらの添加成分も製品の風味を悪くする原因となり得る。これに対して、本発明の方法は、pH4.5〜5.5の条件下で高温短時間加熱殺菌を行うことによって、コーヒーの香り成分をできるだけ保持しつつ、酸味と苦みの呈味バランスにも優れたコーヒー含有飲料を得ることができる。   In addition, it is known that it is effective to adjust the pH at the time of heat sterilization to the range of 3.0-5.5 as a method for suppressing deterioration of the aroma component of coffee (Japanese Patent Laid-Open No. 2004-73071). According to this method, it can be said that it is desirable to perform heat sterilization in a region around 4.0 where the pH is lower, considering only the retention of coffee aroma components during heat sterilization. However, when heat sterilization is performed in such a low pH range, although the scent retention effect is high, even if the final product pH is adjusted as appropriate, the taste balance of the product is lost, and the coffee containing bad taste is contained. It becomes a drink. In addition, in order to adjust to a low pH range, for example, it is necessary to add an acidic component such as citric acid, and as a result, the amount of the pH adjusting agent for performing final pH adjustment also increases. Therefore, these additive components may also cause the product to become unsavory. On the other hand, the method of the present invention achieves a balanced taste of sourness and bitterness while retaining the scent component of coffee as much as possible by performing heat sterilization at a high temperature for a short time under the condition of pH 4.5 to 5.5. Excellent coffee-containing beverages can be obtained.

また、第2液として使用されるコーヒー抽出液以外の飲料成分としては、pH調整剤を含む他の飲料成分を予め混合して用いられる。第2液に含まれる飲料成分としては、pH調整剤のほか、例えば、乳成分、糖類、甘味料、酸化防止剤、乳化剤、増粘剤、着色料、香料等が含まれる。これらの飲料成分は、高温短時間加熱殺菌の前に予め混合してしておく必要がある。また、乳成分を含む場合には、乳化剤や増粘剤を溶解・混合後、乳化処理を実施しておくことが望ましい。   Moreover, as beverage components other than the coffee extract used as the second liquid, other beverage components including a pH adjuster are mixed in advance and used. The beverage component contained in the second liquid includes, for example, milk components, sugars, sweeteners, antioxidants, emulsifiers, thickeners, colorants, flavors and the like in addition to the pH adjuster. These beverage components need to be mixed in advance before high-temperature and short-time heat sterilization. Moreover, when a milk component is included, it is desirable to carry out an emulsification treatment after dissolving and mixing an emulsifier and a thickener.

第2液において用いられるpH調整剤については、一般に飲料に使用されるpH調整剤であればどのようなpH調整剤でもよく、特に制限はない。ただし、本発明においては、pHを上げていく方向に調整することになるため、実質的に塩基性のpH調整剤を用いることになる。一般に飲料に使用される塩基性のpH調整剤としては、重曹等の炭酸塩が挙げられる。   The pH adjusting agent used in the second liquid may be any pH adjusting agent as long as it is generally used in beverages, and is not particularly limited. However, in the present invention, since the pH is adjusted in the increasing direction, a substantially basic pH adjusting agent is used. A basic pH adjuster generally used in beverages includes carbonates such as baking soda.

また、必要に応じて、第2液に含まれ得るpH調整剤以外の飲料成分について、別途第3液として混合し、第2液とは別に高温短時間加熱殺菌を行なってもよい。加熱殺菌後の第3液は、第1液、第2液とともに混合され、製品全体の最終pHが調整される。この場合、それぞれの成分の安定性を考慮した上で、第2液と第3液の配合成分及び配合割合を決定することが望ましい。第3液に含まれる飲料成分としては、前記第2液と同様(pH調整剤を除く)、例えば、乳成分、糖類、甘味料、酸化防止剤、乳化剤、増粘剤、着色料、香料等が含まれる。第3液を別途設けることによって、pH調整剤を含む第2液のみ、あるいはその他の第3液のみの配合成分を、必要に応じて、それぞれ個別に変更することができ、コーヒー含有飲料の成分変更が容易になる。   In addition, if necessary, beverage components other than the pH adjuster that can be contained in the second liquid may be separately mixed as the third liquid, and may be sterilized by heating at high temperature and short time separately from the second liquid. The third liquid after heat sterilization is mixed with the first liquid and the second liquid, and the final pH of the entire product is adjusted. In this case, it is desirable to determine the blending components and blending ratios of the second liquid and the third liquid in consideration of the stability of each component. The beverage component contained in the third liquid is the same as the second liquid (excluding the pH adjuster), for example, milk components, sugars, sweeteners, antioxidants, emulsifiers, thickeners, colorants, fragrances, etc. Is included. By separately providing the third liquid, only the second liquid containing the pH adjuster, or the other third liquid-only blending components can be individually changed as necessary, and the components of the coffee-containing beverage Easy to change.

第1液と第2液(及び第3液)との混合比は、容積比で、第1液:第2液(及び第3液)=1:3〜3:1の範囲であることが好ましく、さらに好ましくは1:2〜2:1の範囲である(別途第3液を設ける場合には、第2液と第3液の容積の合計として容積比を計算する)。なお、第1液と第2液(及び第3液)に含まれる成分の濃度は、混合後の最終製品における成分濃度に合わせて設定されるため、それぞれの成分が濃縮された状態で含まれている。このため、第1液として用いられるコーヒー抽出液は、第1液と第2液(及び第3液)との混合比に応じたコーヒー成分濃度(固形分濃度)に予め調整される必要がある。例えば、容積比で第1液:第2液(及び第3液)=1:1とすると、第1液のコーヒー成分濃度及び第2液(及び第3液)のその他の成分の濃度はそれぞれ最終製品の2倍以上の濃度に調整されることになる。ここで、コーヒー成分の濃度がより高い状態で高温短時間加熱殺菌を行うことによって、加熱殺菌処理による香りや味の劣化を低く抑えることができる。これに対して、pH調整剤を含む第2液の比率が極端に少ないと、第1液におけるコーヒー成分濃度は最終製品とほぼ同程度となるため、コーヒー成分の濃縮による加熱殺菌時の劣化を抑制する効果はほとんど期待できない。したがって、第1液におけるコーヒー成分の濃縮という観点からも、第1液と第2液(及び第3液)との混合比を上記範囲とすることが好ましい。   The mixing ratio of the first liquid and the second liquid (and the third liquid) is a volume ratio, and the first liquid: the second liquid (and the third liquid) = 1: 3 to 3: 1. More preferably, it is in the range of 1: 2 to 2: 1 (when a third liquid is separately provided, the volume ratio is calculated as the sum of the volumes of the second liquid and the third liquid). In addition, since the density | concentration of the component contained in 1st liquid and 2nd liquid (and 3rd liquid) is set according to the component density | concentration in the final product after mixing, each component is contained in the concentrated state. ing. For this reason, the coffee extract used as the first liquid needs to be adjusted in advance to a coffee component concentration (solid content concentration) corresponding to the mixing ratio of the first liquid and the second liquid (and the third liquid). . For example, when the first liquid: second liquid (and third liquid) = 1: 1 in the volume ratio, the coffee component concentration of the first liquid and the concentration of the other components of the second liquid (and third liquid) are respectively The concentration will be adjusted to more than twice the final product. Here, by performing high-temperature and short-time heat sterilization in a state where the concentration of the coffee component is higher, deterioration of aroma and taste due to heat sterilization treatment can be suppressed to a low level. On the other hand, if the ratio of the second liquid containing the pH adjuster is extremely small, the concentration of the coffee component in the first liquid is almost the same as that of the final product. The suppression effect can hardly be expected. Therefore, also from the viewpoint of concentration of the coffee component in the first liquid, it is preferable that the mixing ratio of the first liquid and the second liquid (and the third liquid) be in the above range.

本発明で行われる第1液と第2液(及び第3液)の加熱殺菌の方法としては、後工程で無菌条件下での混合工程が必要であることから、予め製品を充填・密封した状態で行われる従来のレトルト殺菌法は適用できない。このため、本発明においては、高温短時間加熱殺菌法(UHT殺菌法)が用いられる。高温短時間加熱殺菌の方法は、プレート式、チューブ式等の間接加熱方式が選択できる。第1液と第2液(及び第3液)の殺菌順序はいずれが先であっても構わないが、飲料成分中に乳成分を含む場合には、乳成分の殺菌よりも先もしくは同時にpH調整剤を殺菌しておく必要がある。   As the method of heat sterilization of the first liquid and the second liquid (and the third liquid) performed in the present invention, a mixing process under aseptic conditions is necessary in the subsequent process, so the product is filled and sealed in advance. The conventional retort sterilization method performed in the state cannot be applied. For this reason, in this invention, a high temperature short time heat sterilization method (UHT sterilization method) is used. As a method for high temperature and short time heat sterilization, an indirect heating method such as a plate type or a tube type can be selected. The first liquid and the second liquid (and third liquid) may be sterilized in any order, but when the beverage component contains a milk component, the pH before or simultaneously with the sterilization of the milk component. It is necessary to sterilize the conditioner.

第1液と第2液(及び第3液)の高温短時間加熱殺菌の条件は、混合後の製品のpHで発育し得る微生物を考慮して殺菌条件を設定した上で、第1液、第2液(及び第3液)ともに同一の殺菌条件(加熱温度、加熱保持時間)で殺菌を行うことが望ましい。より具体的には、121℃以上、1分以内の条件で加熱殺菌を行うことが望ましい。121℃未満であると、例えば、1分以内といった短時間の加熱では十分な殺菌を行うことができず、結果として長時間の加熱処理を行なう必要があるため、コーヒーの香りや味が劣化してしまう場合がある。また、第1液と第2液(及び第3液)の殺菌時のpHは異なるため、商業的殺菌の意図で殺菌条件を設定する際には、最終製品のpHを目安として第1液と第2液(及び第3液)の殺菌条件を同一にすることが望ましい。さらに、第1液、第2液(及び第3液)ともに同一の殺菌条件(加熱温度、加熱保持時間)とすることで、工程内で同一の殺菌装置(加熱装置)を使用することができ、工程を簡易化することができるという利点もある。   The conditions of the high temperature and short time heat sterilization of the first liquid and the second liquid (and the third liquid) set the sterilization conditions in consideration of microorganisms that can grow at the pH of the product after mixing, then the first liquid, It is desirable that the second liquid (and the third liquid) be sterilized under the same sterilization conditions (heating temperature, heating holding time). More specifically, it is desirable to perform heat sterilization under conditions of 121 ° C. or more and 1 minute or less. When the temperature is lower than 121 ° C., for example, heating for a short time such as within 1 minute cannot perform sufficient sterilization, and as a result, it is necessary to perform heat treatment for a long time. May end up. In addition, since the pH at the time of sterilization of the first liquid and the second liquid (and the third liquid) is different, when setting the sterilization conditions for the purpose of commercial sterilization, It is desirable that the second liquid (and the third liquid) have the same sterilization conditions. Furthermore, the same sterilization apparatus (heating apparatus) can be used in the process by setting the first liquid and the second liquid (and the third liquid) to the same sterilization conditions (heating temperature, heating holding time). There is also an advantage that the process can be simplified.

高温短時間加熱殺菌された第1液と第2液(及び第3液)は無菌条件下のミキシングタンクへと送液され、当該ミキシングタンク内で両者が混合されて、最終製品のpHへと調整される。製品液のpHは、飲用に適しており、かつ製品の貯蔵安定性に適したpH域に設定される。なお、高温短時間加熱殺菌によるpH低下によって、通常、第1液の加熱殺菌後のpHは処理前よりも0.1〜0.5程度低下することが一般的であり、pH4.5〜5.5よりもさらに低くなっている。これに対して、予め設定された量のpH調整剤を含む第2液を混合することによって、最終製品として適したpH域へと調整されることになる。例えば、乳成分を含まないコーヒー含有飲料の場合、pHが5.2未満では酸味が強く感じられ、苦みとの呈味バランスが悪い。一方で、pHが6.0を超えると、酸味が弱く感じられ、新鮮味の無い古びた呈味となる。したがって、製品液のpHを5.2〜6.0の間になるように、第2液のpH調整剤の量を調整することが望ましい。これに対して、乳成分を含むミルクコーヒー飲料の場合、pHが6.0未満であると、乳由来タンパク質の等電点が存在するpH領域となるため、乳化状態が損なわれ易くなり、貯蔵安定性が失われる。一方で、pHが7.0を超えると、乳成分とコーヒー固形分の量によっては、乳成分に含まれるκカゼインとβラクトグロブリンによるチオール=ジスルフィド交換反応によって、乳タンパクの凝集が生じ易くなり、貯蔵安定性が失われる。したがって、製品のpHが6.0〜7.0の間になるように、第2液のpH調整剤の量を調整することが望ましい。   The first and second liquids (and the third liquid) that have been sterilized by heating at a high temperature for a short time are sent to a mixing tank under aseptic conditions, and both are mixed in the mixing tank to reach the pH of the final product. Adjusted. The pH of the product liquid is set to a pH range suitable for drinking and suitable for storage stability of the product. In general, the pH after heat sterilization of the first liquid is generally about 0.1 to 0.5 lower than that before treatment due to the pH decrease due to high temperature and short time heat sterilization, and the pH is 4.5 to 5 It is even lower than .5. On the other hand, by mixing the second liquid containing a preset amount of the pH adjusting agent, the pH is adjusted to a pH range suitable for the final product. For example, in the case of a coffee-containing beverage that does not contain a milk component, if the pH is less than 5.2, the acidity is strongly felt and the taste balance with bitterness is poor. On the other hand, when the pH exceeds 6.0, the acidity is felt weak and the taste becomes old with no freshness. Therefore, it is desirable to adjust the amount of the pH adjuster of the second liquid so that the pH of the product liquid is between 5.2 and 6.0. On the other hand, in the case of milk coffee beverages containing milk components, if the pH is less than 6.0, the pH is in the region where the isoelectric point of milk-derived protein is present, so that the emulsified state is easily impaired and stored. Stability is lost. On the other hand, when the pH exceeds 7.0, depending on the amount of milk component and coffee solids, milk protein aggregation is likely to occur due to thiol = disulfide exchange reaction between κ casein and β lactoglobulin contained in the milk component. , Storage stability is lost. Therefore, it is desirable to adjust the amount of the pH adjuster of the second liquid so that the pH of the product is between 6.0 and 7.0.

無菌条件下のミキシングタンク内で混合された製品液は、無菌条件下で予め殺菌された容器内に無菌的に充填され、無菌条件下で密封されることで、コーヒー含有飲料の最終製品となる。   The product liquid mixed in the mixing tank under aseptic conditions is aseptically filled in a container sterilized in advance under aseptic conditions and sealed under aseptic conditions to become the final product of the coffee-containing beverage. .

試料1A〜1F
焙煎したコーヒー豆1.2kgを90℃の熱水で抽出し、直ちに冷却した後、ろ過および遠心分離を行って、抽出液9.2kgを得た。つづいて得られた抽出液を希釈してコーヒー固形量1.3%に調整した。得られたコーヒー抽出液のpHは5.3であった。
Samples 1A-1F
1.2 kg of roasted coffee beans were extracted with hot water at 90 ° C. and immediately cooled, followed by filtration and centrifugation to obtain 9.2 kg of an extract. Subsequently, the obtained extract was diluted to adjust the coffee solid content to 1.3%. The pH of the obtained coffee extract was 5.3.

〈試料1A〉 以上で得られたコーヒー抽出液に予めpH調整剤を添加してpHを5.8に調整し、130℃30秒の高温短時間加熱殺菌を行ったものを試料1Aとした。
〈試料1B〉 以上で得られたコーヒー抽出液をpH無調整のまま(pH5.3)、130℃30秒の高温短時間加熱殺菌を行ったものを試料1Bとした。
〈試料1C〉 以上で得られたコーヒー抽出液を第1液として、pH無調整のまま(pH5.3)で130℃30秒の高温短時間加熱殺菌を行い、別途pH調整剤を含む第2液を130℃30秒の殺菌条件にて殺菌して、無菌条件下、第1液と第2液とを1:1の混合比(容積比)で混合してpHを5.6に調整したものを試料1Cとした。
〈試料1D〉 以上で得られたコーヒー抽出液にpH調整剤を添加してpH4.4に調整した第1液を130℃30秒の条件で高温短時間加熱殺菌し、別途pH調整剤を含む第2液を130℃30秒の殺菌条件にて殺菌して、無菌条件下、第1液と第2液とを1:1の混合比(容積比)で混合してpHを5.7に調整したものを試料1Dとした。
〈試料1E〉 以上で得られたコーヒー抽出液にpH調整剤を添加してpH3.5に調整した第1液を130℃30秒の条件で高温短時間加熱殺菌し、別途pH調整剤を含む第2液を130℃30秒の殺菌条件にて殺菌して、無菌条件下、第1液と第2液とを1:1の混合比(容積比)で混合してpHを5.7に調整したものを試料1Eとした。
〈試料1F〉 加熱殺菌処理をしていないpH無調整のコーヒー抽出液を試料1A〜1Eと同じコーヒー濃度に調整したものを標準試料として試料1Fとした(pH5.3)。
<Sample 1A> A sample obtained by adding a pH adjuster to the coffee extract obtained as described above to adjust the pH to 5.8 in advance and sterilizing by heating at 130 ° C. for 30 seconds for a short time was designated as Sample 1A.
<Sample 1B> The coffee extract obtained above was subjected to high-temperature and short-time heat sterilization at 130 ° C. for 30 seconds with no pH adjustment (pH 5.3), which was designated as Sample 1B.
<Sample 1C> The coffee extract obtained above is used as the first liquid, and is sterilized by heating at 130 ° C. for 30 seconds at a temperature of 30 ° C. with no pH adjustment (pH 5.3). The liquid was sterilized under sterilization conditions of 130 ° C. for 30 seconds, and the pH was adjusted to 5.6 by mixing the first liquid and the second liquid at a mixing ratio (volume ratio) of 1: 1 under aseptic conditions. This was designated as Sample 1C.
<Sample 1D> The first liquid adjusted to pH 4.4 by adding a pH adjuster to the coffee extract obtained above is sterilized by heating at a high temperature for a short time at 130 ° C. for 30 seconds, and additionally contains a pH adjuster. The second liquid is sterilized under a sterilization condition of 130 ° C. for 30 seconds, and the first liquid and the second liquid are mixed at a mixing ratio (volume ratio) of 1: 1 under aseptic conditions to adjust the pH to 5.7. The adjusted sample was designated as Sample 1D.
<Sample 1E> The first liquid adjusted to pH 3.5 by adding a pH adjuster to the coffee extract obtained above is sterilized by heating at 130 ° C. for 30 seconds at a high temperature for a short time, and additionally contains a pH adjuster. The second liquid is sterilized under a sterilization condition of 130 ° C. for 30 seconds, and the first liquid and the second liquid are mixed at a mixing ratio (volume ratio) of 1: 1 under aseptic conditions to adjust the pH to 5.7. The adjusted sample was designated as Sample 1E.
<Sample 1F> A non-pH-adjusted coffee extract that was not heat sterilized and adjusted to the same coffee concentration as Samples 1A to 1E was designated as Sample 1F (pH 5.3).

なお、pH調整剤の添加量は、pH調整剤を添加しない試料1B、1Fを除き、最終pHが5.6〜5.7になるように添加量を調整した。
図1Aに上記試料1A〜1Cの製造方法のフローチャートを、図1Bに上記試料1D〜1Fの製造方法のフローチャート示す。
The addition amount of the pH adjuster was adjusted so that the final pH was 5.6 to 5.7, except for Samples 1B and 1F to which no pH adjuster was added.
FIG. 1A shows a flowchart of the manufacturing method of the samples 1A to 1C, and FIG. 1B shows a flowchart of the manufacturing method of the samples 1D to 1F.

試料1A〜1Fのコーヒー飲料について、20名(男女各10名)のパネラーによって各種官能評価(香りの強さ、香りの良さ、苦み、酸味、すっきり感、味の濃さ)を行った。各評価項目に対する採点は7段階評価で行い、10名の採点の平均点で示した。評価結果を下記表1に示す。   For the coffee beverages of Samples 1A to 1F, various sensory evaluations (strength of fragrance, good fragrance, bitterness, sourness, refreshing feeling, richness of taste) were performed by 20 (10 men and women) panelists. The scoring for each evaluation item was carried out by a seven-step evaluation, and was indicated by the average score of 10 people. The evaluation results are shown in Table 1 below.

Figure 0005301024
Figure 0005301024

上記表1に示す結果の通り、コーヒー液のpHを5.8に調整した後に高温短時間加熱殺菌を行った試料1Aでは、香り・呈味に関する評価点が低くなっていた。また、コーヒー液(pH5.3)のpH調整を行わずに高温短時間加熱殺菌を行った試料1Bでは、香りに関する評価点は高いものの、苦みに対して酸味を強く感じる評価となっており、総合評価では低い結果となった。これに対して、pH5.3(無調整)のコーヒー液を第1液として高温短時間加熱殺菌した後、別途加熱殺菌したpH調整剤を含む第2液と無菌条件下で混合してpHを5.6に調整した試料1Cでは、試料1Bと同じく香りに関する評価点が高く、呈味に関する評価点も苦みと酸味のバランスがよいため、総合評価も試料1A、1Bと比べて高い結果となり、また、未殺菌処理の標準試料である試料1Fに最も近い評価となった。また、pHを4.4〜3.5に調整したコーヒー液を第1液として高温短時間殺菌した後、別途加熱殺菌したpH調整剤を含む第2液と混合してpHを5.7に調整した試料1D,1Eでは、香りに関する評価は高かったものの、最終pHを同程度に調整しているにもかかわらず、苦味と酸味の呈味バランスが悪く、すっきり感、味の濃さといった評価でも十分な評価結果が得られず、総合評価では試料1Cと比べて劣る結果となった。
As shown in Table 1, the sample 1A, which was sterilized by high-temperature and short-time heat after adjusting the pH of the coffee liquor to 5.8, had low evaluation points regarding aroma and taste. In addition, in the sample 1B that has been sterilized by heating at high temperature and short time without adjusting the pH of the coffee liquid (pH 5.3), although the evaluation point regarding the fragrance is high, it is an evaluation that strongly feels sourness against bitterness, is a comprehensive evaluation was the low have the results. On the other hand, after sterilizing by heating at a high temperature for a short time using a coffee solution having a pH of 5.3 (no adjustment) as a first solution, the pH is adjusted by mixing with a second solution containing a pH adjuster that has been separately sterilized by heating. In the sample 1C adjusted to 5.6, the evaluation point regarding the fragrance is high as in the case of the sample 1B, and the evaluation point regarding taste has a good balance between bitterness and sourness, so the overall evaluation is also higher than the samples 1A and 1B. Moreover, it became the evaluation nearest to the sample 1F which is a standard sample of non-sterilization treatment. Also, after the coffee liquid whose pH is adjusted to 4.4 to 3.5 is sterilized as a first liquid for a short time at a high temperature, it is mixed with a second liquid containing a pH adjuster that has been separately sterilized by heating to a pH of 5.7. In the prepared samples 1D and 1E, although the evaluation regarding the fragrance was high, the balance between bitterness and sourness was poor, although the final pH was adjusted to the same level, evaluation such as a refreshing feeling and a strong taste However, sufficient evaluation results could not be obtained, and the overall evaluation was inferior to Sample 1C.

試料2A〜2C
下記表2に示す配合にしたがって、ミルクコーヒー飲料の製造を行った。

Figure 0005301024
Samples 2A-2C
A milk coffee beverage was produced according to the formulation shown in Table 2 below.
Figure 0005301024

焙煎したコーヒー豆20kgを90℃の熱水で抽出し、直ちに冷却した後、ろ過および遠心分離を行って、抽出液110.4kgを得た。つづいて得られた抽出液を希釈してコーヒー固形量1.3%に調整した。得られたコーヒー抽出液のpHは5.3であった。   20 kg of roasted coffee beans were extracted with hot water at 90 ° C. and immediately cooled, followed by filtration and centrifugation to obtain 110.4 kg of an extract. Subsequently, the obtained extract was diluted to adjust the coffee solid content to 1.3%. The pH of the obtained coffee extract was 5.3.

〈試料2A〉 以上で得られたコーヒー抽出液に、乳成分、糖類、乳化剤、pH調整剤等の各飲料成分を溶解、調合してpHを6.8に調整し、乳化処理を行った後、130℃30秒の高温短時間加熱殺菌を行ったものを試料Aとした。
〈試料2B〉 以上で得られたコーヒー抽出液に予めpH調整剤を添加してpHを6.8に調整した第1液を130℃30秒の条件で高温短時間加熱殺菌し、別途乳成分、糖類、乳化剤等の各飲料成分を溶解、調合した第2液を予め乳化処理を行った後、130℃30秒の条件で高温短時間加熱殺菌し、無菌条件下、第1液と第2液とを1:1の混合比(容積比)で混合したものを試料2Bとした。
〈試料2C〉 以上で得られたコーヒー抽出液を第1液として、pH無調整のまま(pH5.3)で130℃30秒の高温短時間加熱殺菌を行い、別途乳成分、糖類、乳化剤、pH調整剤等の各飲料成分を溶解、調合した第2液を予め乳化処理を行った後、130℃30秒で高温短時間加熱殺菌し、無菌条件下、第1液と第2液とを1:1の混合比(容積比)で混合してpHを6.6に調整したものを試料2Cとした。
<Sample 2A> After each beverage component such as milk components, sugars, emulsifiers and pH adjusters is dissolved and prepared in the coffee extract obtained above, the pH is adjusted to 6.8, and the emulsification treatment is performed. Sample A was subjected to high-temperature and short-time heat sterilization at 130 ° C. for 30 seconds.
<Sample 2B> The first liquid obtained by previously adding a pH adjuster to the coffee extract obtained above and adjusting the pH to 6.8 is sterilized by heating at 130 ° C for 30 seconds at a high temperature for a short time, and a separate milk component The second liquid prepared by dissolving and preparing each beverage component such as sugar, emulsifier and the like is preliminarily emulsified and then heat-sterilized at 130 ° C. for 30 seconds for a short period of time. Sample 2B was prepared by mixing the liquid with a mixing ratio (volume ratio) of 1: 1.
<Sample 2C> The coffee extract obtained above is used as the first liquid, and sterilized by heating at 130 ° C. for 30 seconds with no pH adjustment (pH 5.3). Separate milk components, sugars, emulsifiers, After emulsifying the second liquid prepared by dissolving and blending each beverage component such as a pH adjuster in advance, the liquid is sterilized by heating at 130 ° C. for 30 seconds for a short time, and the first liquid and the second liquid are mixed under aseptic conditions. Sample 2C was prepared by mixing at a mixing ratio (volume ratio) of 1: 1 and adjusting the pH to 6.6.

なお、pH調整剤の添加量は、各試料の最終pHが6.5〜6.6になるように添加量を調整した。
図2A〜2Cに、上記試料2A〜2Cのコーヒー含有飲料の製造方法のフローチャートを示す。
In addition, the addition amount of the pH adjuster was adjusted so that the final pH of each sample was 6.5 to 6.6.
The flowchart of the manufacturing method of the coffee containing drink of the said samples 2A-2C is shown to FIG.

試料2A〜2Cについて、20名(男女各10名)のパネラーによる官能評価を行った。各評価項目に対する採点は7段階評価で行い、10名の採点の平均点で示した。評価結果を下記表3に示す。   For samples 2A to 2C, sensory evaluation was performed by 20 (10 men and women) panelists. The scoring for each evaluation item was carried out by a seven-step evaluation, and was indicated by the average score of 10 people. The evaluation results are shown in Table 3 below.

Figure 0005301024
Figure 0005301024

上記表3に示す結果の通り、全ての原料を溶解、調合後に高温短時間加熱殺菌を行った試料2Aでは、香り・呈味に関する評価点が比較的低くなった。また、コーヒー液を予めpH調整して第1液として高温短時間加熱殺菌を行い、その後、別途高温短時間加熱殺菌した他の飲料成分を含む第2液を混合した試料2Bでは、試料2Aに比べると香りに関する評価が若干高くなったが、総合的な評価としては十分なものとは言えなかった。一方で、コーヒー液のpH調整を行わずに第1液として高温短時間加熱殺菌を行なった後、別途高温短時間加熱殺菌したpH調整剤を含む他の飲料成分を第2液として無菌条件下で混合してpH調整を行った試料2Cでは、試料2A、2Bと比べて香りに関する評価点が高い結果となった。糖類や乳成分といったコーヒー以外の原料の影響のため、呈味に関する評価では試料2Aから2Cの間でそれほど大きな差は見られなかったものの、香りを含めた総合評価では試料2Cが最も良い評価となった。   As shown in Table 3 above, in the sample 2A in which all raw materials were dissolved and sterilized by heating at high temperature and short time after preparation, the evaluation points regarding aroma and taste were relatively low. In addition, in the sample 2B in which the pH of the coffee liquid is adjusted in advance and sterilized by heating at a high temperature for a short time as the first liquid, and then mixed with a second liquid containing other beverage components that have been separately heat sterilized at a high temperature for a short time, Although the evaluation about fragrance became a little high compared with it, it could not be said that it was sufficient as a comprehensive evaluation. On the other hand, after the high temperature and short time heat sterilization as the first liquid without adjusting the pH of the coffee liquid, the other liquid components including the pH adjusting agent which has been separately sterilized by high temperature and short time are used as the second liquid aseptic conditions. In sample 2C, the pH of which was mixed by adjusting the pH, the evaluation point regarding the fragrance was higher than in samples 2A and 2B. Due to the influence of ingredients other than coffee such as sugars and milk components, there was no significant difference between samples 2A and 2C in the evaluation regarding taste, but sample 2C was the best evaluation in the comprehensive evaluation including aroma. became.

試料3
焙煎したコーヒー豆20kgを90℃の熱水で抽出し、直ちに冷却した後、ろ過および遠心分離を行って、抽出液110.4kgを得た。つづいて得られた抽出液を希釈してコーヒー固形量1.3%に調整した。得られたコーヒー抽出液のpHは5.3であった。
Sample 3
20 kg of roasted coffee beans were extracted with hot water at 90 ° C. and immediately cooled, followed by filtration and centrifugation to obtain 110.4 kg of an extract. Subsequently, the obtained extract was diluted to adjust the coffee solid content to 1.3%. The pH of the obtained coffee extract was 5.3.

以上で得られたコーヒー抽出液を第1液として、pH無調整のまま(pH5.3)で140℃30秒の高温短時間加熱殺菌を行った。pH調整剤を適量含む水溶液を第2液として、140℃30秒の条件で高温短時間加熱殺菌した。さらに、乳成分、糖類、乳化剤等の各飲料成分を第3液として、溶解、冷却、乳化処理を行った後、140℃30秒の高温短時間加熱殺菌を行った。無菌条件下、第1液:第2液:第3液とを1:0.2:0.8の混合比(容積比)で混合し、最終pHを6.6に調整したものを試料3とした。
図3に、上記試料3のコーヒー含有飲料の製造方法のフローチャートを示す。
The coffee extract obtained above was used as the first liquid and sterilized by heating at a high temperature and a short time of 140 ° C. for 30 seconds with no pH adjustment (pH 5.3). An aqueous solution containing an appropriate amount of a pH adjuster was used as the second liquid, and the mixture was sterilized by heating at a high temperature for a short time at 140 ° C. for 30 seconds. Furthermore, each beverage component such as milk components, sugars, and emulsifiers was dissolved, cooled, and emulsified using the third liquid, and then sterilized by heating at 140 ° C. for 30 seconds for a short time. Sample 3 was prepared by mixing the first liquid: second liquid: third liquid at a mixing ratio (volume ratio) of 1: 0.2: 0.8 under aseptic conditions and adjusting the final pH to 6.6. It was.
In FIG. 3, the flowchart of the manufacturing method of the coffee containing drink of the said sample 3 is shown.

以上で得られた試料3のコーヒー含有飲料は、上記試料2Cと同様に、コーヒー本来の自然な香りを有しており、酸味と苦みの呈味バランスにも優れていた。   The coffee-containing beverage of Sample 3 obtained as described above had the natural scent of coffee as in Sample 2C, and was excellent in the taste balance between sourness and bitterness.

Claims (5)

第1液として、コーヒー抽出液をpH4.5〜5.5の条件下で、121℃以上、1分以内の条件で高温短時間加熱殺菌し、その後冷却する第1液殺菌工程と、
第2液として、塩基性のpH調整剤を含む飲料成分を、121℃以上、1分以内の条件で高温短時間加熱殺菌し、その後冷却する第2液殺菌工程と、
前記各工程により得られた第1液と第2液とを無菌環境下で混合し、pHを5.2〜7.0に調整する混合工程と
を備え
前記混合工程において、第1液と、第1液以外の飲料成分との混合比が、容積比で、第1液:第1液以外の飲料成分=1:3〜3:1の範囲である
ことを特徴とするコーヒー含有飲料の製造方法。
As the first liquid, a first liquid sterilization step in which the coffee extract is sterilized by heating at a temperature of 121 ° C. or higher and within 1 minute under conditions of pH 4.5 to 5.5, and then cooled,
As a second liquid, a second liquid sterilization step in which a beverage component containing a basic pH adjuster is sterilized by heating at a high temperature for a short time at a temperature of 121 ° C. or more and within 1 minute, and then cooled,
Mixing the first liquid and the second liquid obtained in each of the steps in a sterile environment, and adjusting the pH to 5.2 to 7.0 ,
In the mixing step, the mixing ratio of the first liquid and the beverage components other than the first liquid is a volume ratio, and the first liquid: beverage components other than the first liquid = 1: 3 to 3: 1. <br/> A method for producing a coffee-containing beverage characterized by the above.
前記混合工程において、第1液と、第1液以外の飲料成分との混合比が、容積比で、第1液:第1液以外の飲料成分=1:2〜2:1の範囲であることを特徴とする請求項1に記載のコーヒー含有飲料の製造方法 In the mixing step, the mixing ratio of the first liquid and the beverage components other than the first liquid is a volume ratio, and the first liquid: beverage components other than the first liquid = 1: 2 to 2: 1. The method for producing a coffee-containing beverage according to claim 1 . さらに、第3液として、コーヒー抽出液及びpH調整剤を含まない他の飲料成分を、121℃以上、1分以内の条件で高温短時間加熱殺菌し、その後冷却する第3液殺菌工程を備え、
前記混合工程において、第1液と第2液と第3液とを無菌環境下で混合し、pHを調整することを特徴とする請求項1又は2に記載のコーヒー含有飲料の製造方法。
Further, as the third liquid, there is provided a third liquid sterilization step in which the coffee extract and other beverage components not containing the pH adjuster are sterilized by heating at a temperature of 121 ° C. or higher and within 1 minute for a short time and then cooled. ,
In the mixing step, the first liquid and the second liquid and the third liquid are mixed in a sterile environment, a manufacturing method of a coffee-containing beverage according to claim 1 or 2, characterized in that to adjust the pH.
前記第2液及び第3液が乳成分を含まず、前記混合工程後のpHが5.2〜6.0に調整されることを特徴とする請求項1から3のいずれかに記載のコーヒー含有飲料の製造方法。   The coffee according to any one of claims 1 to 3, wherein the second liquid and the third liquid do not contain milk components, and the pH after the mixing step is adjusted to 5.2 to 6.0. The manufacturing method of a containing drink. 前記第2液又は第3液が乳成分を含み、前記混合工程後のpHが6.0〜7.0に調整されることを特徴とする請求項1から3のいずれかに記載のコーヒー含有飲料の製造方法。
The said 2nd liquid or 3rd liquid contains a milk component, and the pH after the said mixing process is adjusted to 6.0-7.0, Coffee content in any one of Claim 1 to 3 characterized by the above-mentioned. A method for producing a beverage.
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