JP5291891B2 - Manufacturing method of conductive roller - Google Patents
Manufacturing method of conductive roller Download PDFInfo
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- JP5291891B2 JP5291891B2 JP2007115688A JP2007115688A JP5291891B2 JP 5291891 B2 JP5291891 B2 JP 5291891B2 JP 2007115688 A JP2007115688 A JP 2007115688A JP 2007115688 A JP2007115688 A JP 2007115688A JP 5291891 B2 JP5291891 B2 JP 5291891B2
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- 238000004519 manufacturing process Methods 0.000 title claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 87
- 239000011248 coating agent Substances 0.000 claims description 46
- 238000000576 coating method Methods 0.000 claims description 46
- 239000002904 solvent Substances 0.000 claims description 42
- 239000007788 liquid Substances 0.000 claims description 22
- 239000011347 resin Substances 0.000 claims description 21
- 229920005989 resin Polymers 0.000 claims description 21
- 239000012046 mixed solvent Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 230000002093 peripheral effect Effects 0.000 claims description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 9
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 6
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 24
- 238000001035 drying Methods 0.000 description 11
- 238000007665 sagging Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
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- Dry Development In Electrophotography (AREA)
- Electrophotography Configuration And Component (AREA)
- Electrostatic Charge, Transfer And Separation In Electrography (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
本発明は、シャフトの周面に直接、もしくはシャフトの外側に配置された弾性層の周面に、樹脂と溶剤とよりなる塗工液を塗布して導電性ローラを製造する方法に関する。 The present invention relates to a method of manufacturing a conductive roller by applying a coating liquid composed of a resin and a solvent directly on a peripheral surface of a shaft or on a peripheral surface of an elastic layer disposed outside the shaft.
複写機やプリンタ等の電子写真方式を用いた画像形成装置においては、電荷を感光ドラムに供給する帯電ローラ、トナーを感光ドラムに供給する現像ローラ、トナーによる顕像を紙に転写する転写ローラ等、種々の導電性ローラが用いられており、これらの導電性ローラの多くは、シャフトの周面に直接、もしくは、シャフトの外側に配置された弾性層の周面に、樹脂と溶剤とよりなる塗工液を塗布して樹脂層を形成することにより製造されている。そして上記塗工液を調合するにあたっては、多くの場合、溶剤としてトルエンが用いられている（例えば、特許文献１参照。）。
しかしながら、昨今の環境問題から、有害性のあるトルエンを使用しないことが望まれており、それに代替することのできる溶剤が必要とされているものの、トルエンは、塗膜を乾燥させる際の乾燥速度を最適にすることが容易であるため、塗装ムラや塗膜のダレ等を起こしにくく、コスト的にも乾燥速度の点においても、これを代わることのできる溶剤は未だみつかっていない。 However, due to recent environmental problems, it is desired not to use harmful toluene, and although a solvent that can replace it is required, toluene is the drying speed when drying the coating film. Therefore, it is difficult to cause uneven coating and sagging of the coating film, and no solvent that can replace this has been found yet in terms of cost and drying speed.
本発明は、このような問題に鑑みてなされたものであり、トルエンに代わることができ、しかも、塗装ムラや塗膜のダレ等の現象を発生させることのない溶剤を用いて樹脂層を形成する導電性ローラの製造方法を提供することを目的とする。 The present invention has been made in view of such problems, and can be used in place of toluene, and the resin layer is formed using a solvent that does not cause phenomena such as coating unevenness and sagging of the coating film. An object of the present invention is to provide a method for manufacturing a conductive roller.
＜１＞は、シャフトの周面に直接、もしくはシャフトの外側に配置された弾性層の周面に、樹脂と溶剤とよりなる塗工液をディップ方式にて塗布して導電性ローラを製造する方法において、
前記溶剤として、20℃における蒸気圧がトルエンより高い溶剤と、20℃における蒸気圧がトルエンより低い溶剤とを、混合比７：３〜３：７（但し、５：５を除く）で混合させてなる混合溶剤を用いることを特徴とする導電性ローラの製造方法である。
<1> is a method of manufacturing a conductive roller by applying a coating liquid composed of a resin and a solvent by a dipping method directly on the peripheral surface of the shaft or on the peripheral surface of the elastic layer disposed outside the shaft. In the method
As the solvent, a solvent having a vapor pressure at 20 ° C. higher than that of toluene and a solvent having a vapor pressure at 20 ° C. lower than that of toluene are mixed at a mixing ratio of 7: 3 to 3: 7 (excluding 5: 5). A method for producing a conductive roller, comprising using the mixed solvent.
＜２＞は、＜１＞において、20℃における蒸気圧がトルエンより高い前記溶剤として、メチルエチルケトンを用い、20℃における蒸気圧がトルエンより低い前記溶剤として、メチルイソブチルケトンを用いる導電性ローラの製造方法である。 <2> is the production of a conductive roller according to <1>, wherein methyl ethyl ketone is used as the solvent having a vapor pressure at 20 ° C. higher than that of toluene, and methyl isobutyl ketone is used as the solvent having a vapor pressure at 20 ° C. lower than that of toluene. Is the method.
＜３＞は、＜１＞もしくは＜２＞において、前記塗工液を、室温20〜30℃、かつ、湿度50〜70%の条件下、10〜960秒間空気を当てて乾燥させる導電性ローラの製造方法である。 <3> is a conductive roller according to <1> or <2>, wherein the coating liquid is dried by applying air for 10 to 960 seconds under conditions of room temperature of 20 to 30 ° C. and humidity of 50 to 70%. It is a manufacturing method.
＜１＞によれば、溶剤として、20℃における蒸気圧がトルエンより高い溶剤と、20℃における蒸気圧がトルエンより低い溶剤とを混合させてなる混合溶剤を用いるので、塗工液の乾燥速度をトルエンと同等のものにすることができ、その結果、塗装ムラ防止と、塗膜のダレの抑制とを両立させることができ、トルエンを使わなくとも、良好に樹脂層を形成することのできる導電性ローラの製造方法を提供することができる。また、20℃における蒸気圧がトルエンより高い溶剤と、20℃における蒸気圧がトルエンより低い溶剤との混合比を7:3〜3:7（但し、5:5を除く）の範囲としたので、塗工液の乾燥速度を一層好ましいものに最適化することができ、塗装ムラをさらに効果的に防止するとともに、塗膜のダレも有効に抑制することができる。 <1> According to <1>, since a mixed solvent obtained by mixing a solvent having a vapor pressure at 20 ° C. higher than that of toluene and a solvent having a vapor pressure at 20 ° C. lower than that of toluene is used, the drying speed of the coating liquid Can be made equivalent to toluene, and as a result, it is possible to achieve both prevention of coating unevenness and suppression of sagging of the coating film, and a resin layer can be satisfactorily formed without using toluene. A method for manufacturing a conductive roller can be provided. Moreover, the mixing ratio of the solvent whose vapor pressure at 20 ° C is higher than that of toluene and the solvent whose vapor pressure at 20 ° C is lower than that of toluene is set in the range of 7: 3 to 3: 7 (excluding 5: 5). In addition, the drying speed of the coating liquid can be optimized to a more preferable one, and coating unevenness can be more effectively prevented and the sagging of the coating film can be effectively suppressed.
＜２＞によれば、20℃における蒸気圧がトルエンより高い前記溶剤として、ＭＥＫを用い、20℃における蒸気圧がトルエンより低い前記溶剤として、ＭＩＢＫを用いるので、コスト的にもトルエンと同等の溶剤を得ることができる。 According to <2>, MEK is used as the solvent having a vapor pressure at 20 ° C. higher than that of toluene, and MIBK is used as the solvent having a vapor pressure at 20 ° C. lower than that of toluene. A solvent can be obtained.
本発明の実施形態について、図に基づいて説明する。図１は、本発明に係る導電性ローラを示す断面図であり、導電性ローラ１０はシャフト１の周囲に樹脂層３を配置して構成されるが、シャフト１と樹脂層３との間に弾性層２を含む複数の層を配置することもでき、図示の場合においける導電性ローラ１０は、シャフト１の外側に1層の弾性層２と１層の樹脂層３とが配置されている。
Embodiments of the present invention will be described with reference to the drawings. FIG. 1 is a cross-sectional view showing a conductive roller according to the present invention. The conductive roller 10 is configured by disposing a
そして、樹脂層３を形成するには、図２に概念図で示すように、形成途中の導電性ローラを回転させながら、塗工液を、その弾性層２の外周面にスプレーして樹脂層を形成するスプレー法や、アプリケーションロールを弾性層に接触させて、タンクからくみ上げられた塗工液を弾性層の外周面に塗布するローラコータ法や、図３に概念図で示すように、タンク１１に収容された塗工液１２に、形成途中の導電性ローラを浸漬させて、塗工液を弾性層２の外側に塗布するディップ法によって塗膜を形成し、そのあと、この塗膜を乾燥させるのが一般的であり、本発明は、ディップ法によって塗膜を形成するに際し、塗工液の溶剤として、トルエンに代えて、20℃における蒸気圧がトルエンより高い溶剤と、20℃における蒸気圧がトルエンより低い溶剤との混合物を用いることを特徴としており、このことによって、有害であるトルエンを使うことなく、塗布ムラと塗膜のダレを発生させない点においてトルエンと同等の性能を具えさせることができる。
And in order to form the
すなわち、塗工液の乾燥速度は、溶剤の常温における蒸気圧に大きく依存するが、この蒸気圧が高く乾燥速度の速すぎる溶剤を用いた場合には、塗膜がレベリングを完了する前に固化してしまい塗布ムラを生じやすく、一方、蒸気圧が低く乾燥速度が遅すぎる溶剤を用いた場合には、レベリングは十分行われるけれども固化する前に液が垂れてしまい、この場合も望ましい塗膜を形成することができなくなってしまう。したがって、混合溶剤として重要なことは常温における混合溶剤の蒸気圧がトルエンに極めて近いことであり、このような溶剤の組み合わせして、表１におけるＡ群（20℃における蒸気圧がトルエンより高い溶剤）より選択した溶剤の１種類以上と、表１におけるＢ群より選択した溶剤の１種類以上とを混合させた混合溶剤を用いる必要があり、特に、Ａ群の中でもＭＥＫを、Ｂ群のなかではＭＩＢＫを用いた場合には、コストの点において好ましい。 In other words, the drying speed of the coating solution largely depends on the vapor pressure of the solvent at room temperature. However, if a solvent having a high vapor pressure and an excessively high drying speed is used, the coating is solidified before the leveling is completed. However, if a solvent with a low vapor pressure and a drying rate that is too slow is used, leveling will be sufficient, but the liquid will drip before solidification. Can no longer be formed. Therefore, what is important as a mixed solvent is that the vapor pressure of the mixed solvent at room temperature is very close to that of toluene. By combining such solvents, the group A in Table 1 (solvent having a higher vapor pressure at 20 ° C. than toluene). ) It is necessary to use a mixed solvent obtained by mixing one or more types of solvents selected from the above and one or more types of solvents selected from Group B in Table 1. Then, when MIBK is used, it is preferable in terms of cost.
また、上記混合溶剤を調合するに際して、それらの混合比を7:3〜3:7の範囲にとどめるのが好ましく、20℃における蒸気圧の高い溶剤の割合がこの範囲より大きくなると速く乾燥しすぎて塗布ムラの点でやや劣る結果を生じやすく、一方、20℃における蒸気圧の低い溶剤の割合がこの範囲より大きくなると乾燥速度が遅くなりすぎて塗膜のダレをやや生じやすくなる。 Further, when preparing the above mixed solvent, it is preferable to keep the mixing ratio in the range of 7: 3 to 3: 7, and when the ratio of the solvent having a high vapor pressure at 20 ° C. is larger than this range, it is dried too quickly. However, when the proportion of the solvent having a low vapor pressure at 20 ° C. is larger than this range, the drying rate becomes too slow, and the coating film tends to be slightly sag.
なお、導電性ローラの特性上、塗工液用の樹脂として、アクリル系樹脂、もしくは、ウレタン系樹脂が広く用いられており、上記混合溶剤は、これらの樹脂を用いた塗工液に対して最適な乾燥速度を付与することができ、本発明に係る混合溶剤は、これらの樹脂と組み合わせて用いるのが好ましい。 In addition, due to the characteristics of the conductive roller, acrylic resins or urethane resins are widely used as the resin for the coating liquid, and the above mixed solvent is used for coating liquids using these resins. An optimal drying rate can be imparted, and the mixed solvent according to the present invention is preferably used in combination with these resins.
塗工液として、樹脂と溶剤の他に、種々の充填剤を添加することもできるが、この場合の充填剤としては、ポリエチレン、ポリウレタン等のポリマーや、シリカ等の無機系充填剤を用いるのが好ましい。また、溶剤濃度としては、30〜90wt%の範囲とするのが好ましい。 As the coating liquid, various fillers can be added in addition to the resin and the solvent. In this case, as the filler, polymers such as polyethylene and polyurethane, and inorganic fillers such as silica are used. Is preferred. The solvent concentration is preferably in the range of 30 to 90 wt%.
塗膜を乾燥させる際の条件として、空気を当てて乾燥させる風乾によるのが好ましく、その際、局排設備下で室温20〜30℃、かつ、湿度50〜70%に保持するようにし、風乾時間としては10〜960秒とするのが好ましい。 As the conditions for drying the coating film, it is preferable to use air drying by applying air to the coating. At that time, keep it at room temperature 20-30 ° C and humidity 50-70% under local exhaust equipment, and air dry The time is preferably 10 to 960 seconds.
樹脂と導電性カーボンと、混合溶剤とよりなり塗工液を、シャフトの周囲に形成されたポリウレタン製弾性層の周囲にディップ方式にて塗布したあと、オーブンにて加熱して乾燥させることにより帯電ローラを作成し、この帯電ローラをこれに対応するレーザプリンタカートリッジに組み込んで、実際の黒ベタ画像およびハーフトーン画像を印刷した。
塗工液の樹脂材料としてアクリル樹脂を用い、また、混合溶剤としては、MEKとＭＩＢＫとを混合したものを用い、各サンプルごとに混合比を変化させた。塗工液における樹脂成分100質量部に対して、溶剤は50〜70質量部、導電性カーボンは3〜10質量部を配合した。
A coating solution consisting of a resin, conductive carbon, and mixed solvent is applied by dipping on the polyurethane elastic layer formed around the shaft, and then heated by an oven to dry it. A roller was prepared, and the charging roller was incorporated into a corresponding laser printer cartridge to print an actual black solid image and a halftone image.
An acrylic resin was used as a resin material for the coating liquid, and a mixture of MEK and MIBK was used as a mixed solvent, and the mixing ratio was changed for each sample. 50 to 70 parts by mass of the solvent and 3 to 10 parts by mass of the conductive carbon were blended with 100 parts by mass of the resin component in the coating liquid.
評価については、塗布状態について塗布ムラおよび塗膜のダレの状態を目視で判定する塗膜評価を行うとともに、黒ベタ画像およびハーフトーン画像における画像品質を目視で判定する画像評価を行った。各サンプルにおける、MEKとＭＩＢＫとの混合比および各種評価結果を表２に示す。表２の判定結果において、「○」は合格品を、「×」は不合格品を、そして、「△」は合格品だが「○」より明らかに劣る品質のものであるとして、３段階での評価を行った。 As for the evaluation, the coating state evaluation for visually determining the coating unevenness and the sagging state of the coating film with respect to the coating state was performed, and the image evaluation for visually determining the image quality in the solid black image and the halftone image was performed. Table 2 shows the mixing ratio of MEK and MIBK and various evaluation results in each sample. In the judgment results of Table 2, “○” is a pass product, “×” is a reject product, and “△” is a pass product but is clearly inferior to “○” in three stages. Was evaluated.
表２から明らかなように、20℃における蒸気圧がトルエンより高い溶剤もしくは低い溶剤単独では、合格品を得ることができず、20℃における蒸気圧がトルエンより高い溶剤と低い溶剤とを混合したものを使う場合、それらの混合比が7:3〜3:7の間であれば、全く問題のない樹脂層を形成することができる。 As is clear from Table 2, a solvent having a higher or lower vapor pressure at 20 ° C. than a toluene alone cannot obtain an acceptable product, and a solvent having a higher vapor pressure at 20 ° C. than a toluene is mixed with a lower solvent. When using those, if the mixing ratio thereof is between 7: 3 and 3: 7, a resin layer having no problem can be formed.
１ シャフト
２ 弾性層
３ 樹脂層
５ スプレーノズル
１０ 導電性ローラ
１１ 塗工液タンク
１２ 塗工液
DESCRIPTION OF
Claims (3)
前記溶剤として、20℃における蒸気圧がトルエンより高い溶剤と、20℃における蒸気圧がトルエンより低い溶剤とを、混合比７：３〜３：７（但し、５：５を除く）で混合させてなる混合溶剤を用いることを特徴とする導電性ローラの製造方法。 In a method of manufacturing a conductive roller by applying a coating liquid consisting of a resin and a solvent by a dip method directly on the peripheral surface of the shaft or on the peripheral surface of the elastic layer disposed outside the shaft,
As the solvent, a solvent having a vapor pressure at 20 ° C. higher than that of toluene and a solvent having a vapor pressure at 20 ° C. lower than that of toluene are mixed at a mixing ratio of 7: 3 to 3: 7 (excluding 5: 5). A method for producing a conductive roller, comprising using a mixed solvent.
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| JP2007115688A JP5291891B2 (en) | 2007-04-25 | 2007-04-25 | Manufacturing method of conductive roller |
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| Publication Number | Publication Date |
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| JP2008272603A JP2008272603A (en) | 2008-11-13 |
| JP5291891B2 true JP5291891B2 (en) | 2013-09-18 |
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| JP3271218B2 (en) * | 1993-11-09 | 2002-04-02 | 東海ゴム工業株式会社 | Conductive roll |
| JP4061777B2 (en) * | 1999-06-04 | 2008-03-19 | 株式会社カネカ | Manufacturing method of rubber roller having coating layer |
| JP2001305850A (en) * | 2000-04-25 | 2001-11-02 | Ricoh Co Ltd | Toner carrier and method of image developing using the same |
| JP4294240B2 (en) * | 2001-09-21 | 2009-07-08 | 株式会社リコー | Spray coating method, method for producing parts for electrophotographic apparatus, and electrophotographic apparatus using the same |
| JP2004301872A (en) * | 2003-03-28 | 2004-10-28 | Bando Chem Ind Ltd | Developing roller for electrophotographic apparatus |
| JP4530660B2 (en) * | 2003-12-26 | 2010-08-25 | 株式会社ブリヂストン | Coating composition for conductive roller and conductive roller |
| JP2006234899A (en) * | 2005-02-22 | 2006-09-07 | Canon Chemicals Inc | Manufacturing method for conductive member and roller for electrophotographic device |
| JP2007057612A (en) * | 2005-08-22 | 2007-03-08 | Fujifilm Corp | Nonglare antireflective film and manufacturing method therefor, polarizer using the same nonglare antireflective film, liquid crystal display device using the same polarizer, and liquid crystal display device |
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2007
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