JP5247256B2 - Inkjet recording liquid - Google Patents

Description

  The present invention relates to an inkjet recording liquid.

  The ink jet recording method performs recording by ejecting ink droplets from a large number of nozzles formed on an ink jet head, and the noise during the recording operation is low, the running cost is low, and various recording media are used. On the other hand, it is widely used because it can record high-quality images.

  Various recording media such as plain paper, coated paper, glossy paper, OHP sheet, and back print film are commercially available for recording by the ink jet recording method. However, they are inexpensive for business use in general offices. Often plain paper is used. As the required characteristics at this time, it is possible to reduce or suppress a curl (paper warp or curl) phenomenon that occurs when a large amount of ink is applied to the paper while satisfying the normally required characteristics. Here, not only curling during recording but also relaxation and suppression of post-recording curl caused by drying and evaporation of moisture after recording become important.

In relation to the above, an ink containing a diglycerin derivative is known as an ink that has no image omission or unevenness and good fixability (see, for example, Patent Document 1).
Further, as a method of reducing or suppressing the occurrence of curling, for example, a method of suppressing curling by using a water-based ink containing a low-polar solvent at 30% or more based on the total weight of the ink is known ( For example, see Patent Document 2).
Japanese Patent Laid-Open No. 10-168373 JP 2007-152873 A

However, the ink described in Patent Document 1 cannot suppress curling. In addition, the ink described in Patent Document 2 tends to deteriorate storage stability.
An object of the present invention is to provide an inkjet recording liquid that can suppress the occurrence of curling, has good storage stability, and can suppress the occurrence of image deformation.

Specific means for solving the above problems are as follows.
<1> a step of applying a liquid containing one or more organic acids or polyvalent metal salts to a recording medium;
The recording medium provided with the liquid contains water, a colorant, and a water-soluble organic solvent represented by the following general formula (1), and contains a water-soluble organic solvent having an SP value of 27.5 or less. Applying an inkjet recording liquid having a rate of 70% by mass or more based on the total amount of the water-soluble organic solvent.

(In the formula, R represents an alkyleneoxy group having 2 to 5 carbon atoms, k, l, m, and n each represents an integer representing the number of repeating alkyleneoxy groups, and k + 1 + m + n = 0 to 50).
<2> a step of applying a liquid containing one or more organic acids or polyvalent metal salts to the intermediate transfer member;
An intermediate transfer body to which the liquid is applied contains water, a colorant, and a water-soluble organic solvent represented by the general formula (1), and has an SP value of 27.5 or less. A step of applying an inkjet recording liquid having a content of 70% by mass or more based on the total amount of the water-soluble organic solvent ;
Transferring the ink image formed on the intermediate transfer member to a recording medium .
<3> The inkjet recording method according to <1> or <2>, wherein the content of the water-soluble organic solvent represented by the general formula (1) in the inkjet recording liquid is 5% by mass or more and less than 30% by mass. .
<4> The inkjet recording method according to any one of <1> to <3>, wherein the inkjet recording liquid further contains self-dispersing polymer particles.

<5> The self-dispersing polymer particles include a polymer having a carboxyl group, an acid value (mgKOH / g) of 25 to 100, and a structural unit derived from an aromatic group-containing (meth) acrylate monomer The inkjet recording method according to <4>, wherein the amount is 10% by mass to 95% by mass .

  According to the present invention, it is possible to provide an ink jet recording liquid that can suppress the occurrence of curling, has good storage stability, and can suppress the occurrence of image deformation.

<Inkjet recording liquid>
The inkjet recording liquid of the present invention (hereinafter sometimes simply referred to as “ink”) includes water, at least one coloring material, and at least one water-soluble organic solvent represented by the following general formula (1). And the content of the water-soluble organic solvent having an SP value of 27.5 or less is 70% by mass or more based on the total water-soluble organic solvent.
With the above configuration, curling can be suppressed even when an image is recorded on plain paper other than ink jet dedicated paper, general-purpose coated paper, or the like by the ink jet method. Further, the storage stability of the ink is further improved, and the occurrence of deformation of the formed image can be suppressed.

  In the formula, R represents an alkyleneoxy group having 1 to 5 carbon atoms. k, l, m, and n each represent an integer indicating the number of repeating alkyleneoxy groups, and k + l + m + n = 0 to 50.

The ink jet recording liquid of the present invention may comprise a surfactant, polymer particles (preferably self-dispersing polymer particles), and other components as necessary in addition to the above essential components.
The ink jet recording liquid of the present invention can be used for full color image formation. In order to form a full color image, a magenta color ink, a cyan color ink, and a yellow color ink can be used, and a black color ink may be further used to adjust the color tone. Further, red, green, blue and white inks other than yellow, magenta and cyan color inks, and so-called special color inks in the printing field can be used.

[Water-soluble organic solvent]
The ink jet recording liquid of the present invention contains at least one water-soluble organic solvent represented by the general formula (1) (hereinafter sometimes referred to as “first water-soluble organic solvent”).
In the present invention, the water-soluble organic solvent means an organic solvent that dissolves 5 g or more in 100 g of water at room temperature and normal pressure.

  In general formula (1), R represents an alkyleneoxy group having 1 to 5 carbon atoms, and from the viewpoint of curling suppression, an alkyleneoxy group having 2 to 4 carbon atoms is preferable, and an alkylene having 2 to 3 carbon atoms. More preferred is an oxy group.

K, l, m, and n each represent an integer representing the number of repeating alkyleneoxy groups, and the sum of k to n (k + l + m + n) is 0 to 50. The total of k to n is preferably 4 to 40 from the viewpoint of curling suppression and storage stability.
In the present invention, the sum of k to n being 0 means that the water-soluble organic solvent represented by the general formula (1) is diglycerin. In addition, in the water-soluble organic solvent represented by the general formula (1), the sum of k to n is 1, when a hydrogen atom is removed from any one of the four hydroxyl groups of diglycerin and a hydroxyalkyl group Is a substituted water-soluble organic solvent, and the sum of k to n is 2 means that a hydrogen atom is removed from two of the four hydroxyl groups of diglycerin and the hydroxyalkyl group is substituted. It means a water-soluble organic solvent or a water-soluble organic solvent having a hydroxyalkyloxyalkyl group substituted by removing a hydrogen atom from one of the four hydroxyl groups of diglycerin.

  Furthermore, the water-soluble organic solvent represented by the general formula (1) in the present invention is preferably a water-soluble organic solvent represented by the following general formula (1a).

In the formula, R ¹ represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, k, l, m, and n each represent an integer indicating the number of repetitions, and k + 1 + m + n = 0 to 50.
In the present invention, from the viewpoint of curling suppression, storage stability, and image deformation suppression, R ¹ is preferably a hydrogen atom or a methyl group, and k + 1 + m + n = 4 to 40.

  Among the water-soluble organic solvents represented by the general formula (1), a water-soluble organic solvent having a sum of k to n of 1 or more can be produced, for example, by adding alkylene oxide to the hydroxyl group of diglycerin. . There is no restriction | limiting in particular in the position to which an alkylene oxide is added, You may add to all four hydroxyl groups of diglycerin, or you may add only to one part.

  Specific examples of the water-soluble organic solvent represented by the general formula (1) include diglycerin, polyoxypropylene diglyceryl ether (SC-P series) manufactured by Sakamoto Pharmaceutical Co., Ltd., polyoxyethylene diglyceryl ether (SC- E series).

There is no restriction | limiting in particular in the content rate of the water-soluble organic solvent represented by General formula (1) in the inkjet recording liquid of this invention, For example, it can be 5 mass% or more. From the viewpoint of storage stability and image deformation suppression, the content is preferably 5% by mass or more and less than 30% by mass, and more preferably 5% by mass or more and 25% by mass or less.
In the present invention, the water-soluble organic solvent represented by the general formula (1) may be used alone or in combination of two or more.

  In the present invention, the water-soluble organic solvent represented by the general formula (1) is an alkyleneoxy group having 2 to 3 carbon atoms from the viewpoint of curling suppression, storage stability, and image deformation suppression, and k, The total of l, m, and n is preferably 4 to 40, and the content in the ink jet recording liquid is preferably 5% by mass or more and less than 30% by mass.

  The ink jet recording liquid of the present invention is characterized in that the content of a water-soluble organic solvent having an SP value of 27.5 or less is 70% by mass or more based on the total amount of water-soluble organic solvents. Thereby, generation | occurrence | production of curl can be suppressed more effectively.

The SP value in the present invention means a solubility parameter (SP value) of a solvent, and is a value represented by the square root of the molecular cohesive energy. The SP value is described in Polymer Handbook (Second Edition), Chapter IV, Solubility Parameter Values, and this value is used as the SP value in the present invention. Moreover, a unit is (MPa) ^1/2 and points out the value in 25 degreeC.
In addition, R.D. F. The value calculated by the method described in Fedors, Polymer Engineering Science, 14, p147 (1967) is used as the SP value in the present invention.

  In the present invention, the content of the water-soluble organic solvent having an SP value of 27.5 or less is 70% by mass or more with respect to the total water-soluble organic solvent. On the other hand, it is preferably 80% by mass or more, and more preferably 90% by mass or more. When the said content rate is less than 70 mass%, the curl suppression effect falls.

  In the present invention, the structure of the water-soluble organic solvent having an SP value of 27.5 or less is not particularly limited, and may be a structure represented by the general formula (1) or a structure other than that. . Further, the SP value of the water-soluble organic solvent having an SP value of 27.5 or less is preferably 16 to 27.5, more preferably 18 to 26.5, from the viewpoint of curling suppression effect.

Although the specific example of the water-soluble organic solvent represented by General formula (1) and its SP value is shown below, this invention is not limited to these.
POP (4) diglyceryl ether (SP value 26.1, for example, SC-P400 (manufactured by Sakamoto Pharmaceutical Co., Ltd.)),
POP (9) diglyceryl ether (SP value 22.7, for example, SC-P750 (manufactured by Sakamoto Pharmaceutical Co., Ltd.)),
POE (20) diglyceryl ether (SP value 22.4, for example, SC-E1000 (manufactured by Sakamoto Pharmaceutical Co., Ltd.)),
POE (40) diglyceryl ether (SP value 21.0, for example, SC-E2000 (manufactured by Sakamoto Pharmaceutical Co., Ltd.)).

Further, a water-soluble organic solvent having an SP value other than the water-soluble organic solvent represented by the general formula (1) having a SP value of 27.5 or less (hereinafter sometimes referred to as “second water-soluble organic solvent”) and its SP value Specific examples of these are shown below, but the present invention is not limited thereto.
Hexaoxypropylene glyceryl ether (SP value 23.2, for example, GP-400 (manufactured by Sanyo Chemical Industries)),
Nonoxypropylene glyceryl ether (SP value 21.7, for example, GP-600 (manufactured by Sanyo Chemical Industries)),
Heptaoxypropylene glycol (SP value 21.2, for example, PP-400 (manufactured by Sanyo Chemical Industries, Ltd.)),
Pentaoxyethylene pentaoxypropylene butyl ether (SP value 18.8, for example, 50HB-100 (manufactured by Sanyo Chemical Industries, Ltd.)),
Decaoxyethylene heptaoxypropylene butyl ether (SP value 18.8, for example, 50HB-260 (manufactured by Sanyo Chemical Industries)),
Dodecaoxyethylene dodecaoxypropylene butyl ether (SP value 18.8, for example, 50HB-400 (manufactured by Sanyo Chemical Industries)),
Decaoxyethylene triacontoxypropylene butyl ether (SP value 18.7, for example, PE-62 (manufactured by Sanyo Chemical Industries)),
Pentacosaoxyethylene triacontoxypropylene butyl ether (SP value 18.8, for example, PE-64 (manufactured by Sanyo Chemical Industries)).

Diethylene glycol monoethyl ether (DEGmEE) (SP value 22.4)
Diethylene glycol monobutyl ether (DEGmBE) (SP value 21.5)
Diethylene glycol diethyl ether (DEGdEE) (SP value 16.8)
Triethylene glycol monobutyl ether (TEGmBE) (SP value 21.1)
Propylene glycol monoethyl ether (PGmEE) (SP value 22.3)
Dipropylene glycol (DPG) (SP value 27.1)
Dipropylene glycol monomethyl ether (DPGmME) (SP value 21.3)
Tripropylene glycol (TPG) (SP value 24.7, for example, PP-200 (manufactured by Sanyo Chemical Industries))
1,2-hexanediol (SP value 27.4)
Trioxypropylene glyceryl ether (SP value 26.4, for example, GP-250 (manufactured by Sanyo Chemical Industries))
Dioxyethylenedioxypropylene butyl ether (SP value 20.1, for example, 50HB-55 (manufactured by Sanyo Chemical Industries))

There is no restriction | limiting in particular as content rate of the 2nd water-soluble organic solvent in the inkjet recording liquid of this invention. For example, it can be 0 to 40% by mass, preferably 0 to 25% by mass with respect to the ink jet recording liquid.
The second water-soluble organic solvent can be used alone or in combination of two or more.

In the ink jet recording liquid of the present invention, in addition to the water-soluble organic solvent having an SP value of 27.5 or less, a water-soluble organic solvent having an SP value of more than 27.5 (hereinafter referred to as “a water-soluble organic solvent”) (Sometimes referred to as “third water-soluble organic solvent”).
By including the third water-soluble organic solvent, the drying prevention effect, the wetting effect, or the penetration promoting effect can be obtained more effectively.

Here, the drying prevention effect and the wetting effect mean an effect that can prevent clogging due to drying of the inkjet ink at the ink ejection port of the nozzle. As the drying inhibitor and wetting agent, a water-soluble organic solvent having a vapor pressure lower than that of water is preferable.
Further, the penetration promoting effect means an effect of allowing the ink to penetrate into paper better, and a water-soluble organic solvent is preferably used.

  Examples of the third water-soluble organic solvent in the present invention include glycerin, 1,2,6-hexanetriol, trimethylolpropane, ethylene glycol, propylene glycol, diethylene glycol (DEG), triethylene glycol, tetraethylene glycol, penta Ethylene glycol, 2-butene-1,4-diol, 2-ethyl-1,3-hexanediol, 2-methyl-2,4-pentanediol, 1,2-octanediol, 1,2-pentanediol, 4 -Alkanediols (polyhydric alcohols) such as methyl-1,2-pentanediol; glucose, mannose, fructose, ribose, xylose, arabinose, galactose, aldonic acid, glucitol, maltose, cellobiose, lactose, sucrose, Sugars such as rehalose and maltotriose; sugar alcohols; hyaluronic acids; so-called solid wetting agents such as ureas; alkyl alcohols having 1 to 4 carbon atoms such as ethanol, methanol, butanol, propanol, isopropanol; ethylene glycol monomethyl ether , Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether, diethylene glycol mono-n-propyl ether, ethylene glycol mono-iso-propyl ether, diethylene glycol mono-iso-propyl ether, ethylene glycol mono -N-butyl ether, ethylene glycol mono-t-butyl ether, 1-methyl-1- Toxibutanol, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-t-butyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-iso-propyl ether, dipropylene glycol monoethyl ether, dipropylene glycol Glycol ethers such as mono-n-propyl ether and dipropylene glycol mono-iso-propyl ether; 2-pyrrolidone, N-methyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, formamide, acetamide, Examples thereof include dimethyl sulfoxide, sorbit, sorbitan, acetin, diacetin, triacetin, sulfolane and the like, and one or more of these are used. be able to.

  Among them, polyhydric alcohols are useful for the purpose of drying inhibitors and wetting agents. For example, glycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, 1,3-butanediol, 2, 3-butanediol, 1,4-butanediol, 3-methyl-1,3-butanediol, 1,5-pentanediol, tetraethylene glycol, 1,6-hexanediol, 2-methyl-2,4-pentane Examples include diol, polyethylene glycol, 1,2,4-butanetriol, 1,2,6-hexanetriol, and the like. These may be used individually by 1 type and may use 2 or more types together.

  For the purpose of the penetration enhancer, a polyol compound is preferable. Examples of the aliphatic diol include 2-ethyl-2-methyl-1,3-propanediol, 3,3-dimethyl-1,2-butanediol, 2,2-diethyl-1,3-propanediol, 2-methyl-2-propyl-1,3-propanediol, 2,4-dimethyl-2,4-pentanediol, 2,5-dimethyl-2,5 -Hexanediol, 5-hexene-1,2-diol, 2-ethyl-1,3-hexanediol and the like. Among these, preferred examples include 2-ethyl-1,3-hexanediol and 2,2,4-trimethyl-1,3-pentanediol.

The third water-soluble organic solvent used in the present invention may be used alone or in combination of two or more.
The content of the total water-soluble organic solvent in the ink jet recording liquid of the present invention is preferably 1 to 40% by mass with respect to the total mass of the ink jet recording liquid, from the viewpoints of ink storage stability and ejection properties. More preferably, it is 5-30 mass%, and it is still more preferable that it is 10-25 mass%.

  The amount of water used in the inkjet recording liquid of the present invention is not particularly limited, but is preferably 10% by mass to 99% by mass, and more preferably 30% by mass to 80% by mass. More preferably, it is 50 mass% or more and 70 mass% or less.

[Color material]
The ink jet recording liquid of the present invention contains at least one color material (hereinafter sometimes referred to as “colorant”). The coloring material is not particularly limited as long as it has a function of forming an image by coloring, and pigments, dyes, and colored fine particles can be used. Of these, water-dispersible pigments are preferred.

Specific examples of the water-dispersible pigment include the following pigments (1) to (4).
(1) An encapsulated pigment, that is, a polymer emulsion in which a pigment is contained in polymer fine particles. More specifically, the pigment is coated with a hydrophilic water-insoluble resin and is made hydrophilic by a resin layer on the pigment surface. A pigment is dispersed in water.
(2) Self-dispersing pigments, that is, pigments having at least one hydrophilic group on the surface and exhibiting at least one of water dispersibility and water solubility in the absence of a dispersant, more specifically, mainly carbon black Etc. are hydrophilized by surface oxidation treatment so that the pigment alone is dispersed in water.
(3) A resin-dispersed pigment, that is, a pigment dispersed with a water-soluble polymer compound having a weight average molecular weight of 50,000 or less.
(4) A surfactant-dispersed pigment, that is, a pigment dispersed by a surfactant.
Among them, preferable examples include (1) encapsulated pigment and (2) self-dispersing pigment, and particularly preferable examples include (1) encapsulated pigment.

  The encapsulated pigment will be described in detail. The encapsulated pigment resin is not limited, but is a high molecular compound having self-dispersibility or solubility in a mixed solvent of water and water-soluble organic and having an anionic group (acidic). Is preferred. This resin usually has a number average molecular weight of about 1,000 to 100,000, and particularly preferably about 3,000 to 50,000. Further, it is preferable that this resin is dissolved in an organic solvent to form a solution. When the number average molecular weight of the resin is within this range, the function as a coating film in the pigment or as a coating film in the ink composition can be sufficiently exhibited. The resin is preferably used in the form of an alkali metal or organic amine salt.

Specific examples of encapsulated pigment resins include thermoplastic, thermosetting or modified acrylic, epoxy, polyurethane, polyether, polyamide, unsaturated polyester, phenol, silicone, and fluorine-based resins. Molecular compounds, polyvinyl chloride, vinyl acetate, polyvinyl alcohol, polyvinyl butyral, etc., polyesters such as alkyd resin, phthalic acid resin, melamine resin, melamine formaldehyde resin, aminoalkyd cocondensation resin, urea resin, urea resin, etc. Examples thereof include amino materials, or materials having an anionic group such as copolymers or mixtures thereof.
Among the above resins, anionic acrylic resins include, for example, acrylic monomers having an anionic group (hereinafter referred to as anionic group-containing acrylic monomers), and other monomers that can be copolymerized with these monomers as necessary. Is obtained by polymerization in a solvent. Examples of the anionic group-containing acrylic monomer include an acrylic monomer having one or more anionic groups selected from the group consisting of a carboxyl group, a sulfonic acid group, and a phosphonic group. Among these, an acrylic monomer having a carboxyl group Is particularly preferred.

Specific examples of the acrylic monomer having a carboxyl group include acrylic acid, methacrylic acid, crotonic acid, ethacrylic acid, propylacrylic acid, isopropylacrylic acid, itaconic acid, fumaric acid and the like. Among these, acrylic acid or methacrylic acid is preferable.
The encapsulated pigment can be produced by a conventional physical or chemical method using the above-described components. According to a preferred embodiment of the present invention, JP-A-9-151342, JP-A-10-140065, JP-A-11-209672, JP-A-11-172180, JP-A-10-25440, or JP-A-11-43636. It can be produced by the method disclosed in the issue.

In the present invention, the colorant is preferably an encapsulated pigment (water-dispersible pigment) dispersed by a phase inversion method.
The phase inversion method refers to, for example, a self-dispersing (phase inversion emulsification) method in which a mixed melt of a resin having self-dispersing ability or solubility and a pigment is dispersed in water. Here, the mixed melt means a mixed state without dissolving, a mixed state with dissolved, or a state including both of these states. A more specific production method of the “phase inversion method” may be the same as that disclosed in JP-A-10-140065.

In the present invention, self-dispersing pigments can also be mentioned as preferred examples. The self-dispersing pigment refers to a large number of hydrophilic functional groups and / or salts thereof (hereinafter referred to as dispersibility-imparting groups) on the pigment surface, either directly or indirectly via an alkyl group, an alkyl ether group, an aryl group, or the like. A pigment that is bonded and dispersible in an aqueous medium without a dispersant. Here, “dispersed in an aqueous medium without a dispersant” refers to a state in which the pigment can be dispersed in an aqueous medium without using a dispersant for dispersing the pigment.
Inks containing a self-dispersing pigment as a colorant do not need to contain a dispersant as described above that is contained in order to disperse a normal pigment. It is easy to prepare ink that is excellent in ejection stability.
Examples of dispersibility-imparting groups to be bonded to the surface of the self-dispersion _{pigment, -COOH, -CO, -OH, -SO} 3 H, -PO 3 H 2 and can quaternary ammonium and exemplary salts thereof, these Is produced by bonding (grafting) an active species having a dispersibility-imparting group or a dispersibility-imparting group to the surface of the pigment by subjecting the pigment as a raw material to physical treatment or chemical treatment. Examples of the physical treatment include vacuum plasma treatment. Examples of the chemical treatment include a wet oxidation method in which the pigment surface is oxidized with an oxidizing agent in water, and a method in which a carboxyl group is bonded via a phenyl group by bonding p-aminobenzoic acid to the pigment surface. It can be illustrated.
In the present invention, preferred examples include self-dispersing pigments that are surface-treated by oxidation treatment with hypohalous acid and / or hypohalite or oxidation treatment with ozone. Commercially available products can also be used as the self-dispersing pigment, such as MicroJet CW-1 (trade name; manufactured by Orient Chemical Co., Ltd.), CAB-O-JET200, CAB-O-JET300 (above trade names). ; Manufactured by Cabot Corporation).

(Pigment)
There is no restriction | limiting in particular as a pigment used in this invention, According to the objective, it can select suitably, For example, any of an organic pigment and an inorganic pigment may be sufficient.
Examples of the organic pigment include azo pigments, polycyclic pigments, dye chelates, nitro pigments, nitroso pigments, and aniline black. Among these, azo pigments and polycyclic pigments are more preferable. Examples of the azo pigments include azo lakes, insoluble azo pigments, condensed azo pigments, and chelate azo pigments. Examples of the polycyclic pigment include phthalocyanine pigments, perylene pigments, perinone pigments, anthraquinone pigments, quinacridone pigments, dioxazine pigments, indigo pigments, thioindigo pigments, isoindolinone pigments, and quinofullerone pigments. Examples of the dye chelates include basic dye chelates and acidic dye chelates.
Examples of the inorganic pigment include titanium oxide, iron oxide, calcium carbonate, barium sulfate, aluminum hydroxide, barium yellow, cadmium red, chrome yellow, and carbon black. Among these, carbon black is particularly preferable. In addition, as said carbon black, what was manufactured by well-known methods, such as a contact method, a furnace method, and a thermal method, is mentioned, for example.

  Specific examples of carbon black include Raven7000, Raven5750, Raven5250, Raven5000 ULTRAII, Raven3500, Raven2000, Raven1500, Raven1250, Raven1200, Raven1170, Raven1170, Raven1170, Raven1170, Raven1170, Raven1170, Raven1170, Raven1170, Raven1170 (Manufactured by Carbon), Regal 400R, Regal 330R, Regal 660R, Mogu L, Black Pearls L, Monarch 700, Monarch 800, Monarch 880, Monarch 900, Monarch 1000, Monarch 1100, Monarc 1300, Monarch 1400 (above Cabot), Color Black FW1, Color Black FW2, Color Black FW2V, Color Black 18, Color Black FW200, Color Black S150, Color Black S150, Color Black S150, Color Black S150, Color Black FW200, Color Black FW2 , Printex 140U, Printex 140V, Special Black 6, Special Black 5, Special Black 4A, Special Black 4 (manufactured by Degussa), No. 25, no. 33, no. 40, no. 45, no. 47, no. 52, no. 900, no. 2200B, no. 2300, MCF-88, MA600, MA7, MA8, MA100 (manufactured by Mitsubishi Chemical Corporation) and the like can be mentioned, but the invention is not limited thereto.

  Examples of the organic pigment that can be used in the present invention include C.I. I. Pigment Yellow 1, 2, 3, 4, 5, 6, 7, 10, 11, 12, 13, 14, 14C, 16, 17, 24, 34, 35, 37, 42, 53, 55, 65, 73, 74, 75, 81, 83, 93, 95, 97, 98, 100, 101, 104, 108, 109, 110, 114, 117, 120, 128, 129, 138, 150, 151, 153, 154, 155, 180 etc. are mentioned.

  Examples of magenta ink pigments include C.I. I. Pigment Red 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 21, 22, 23, 30, 31, 32, 37, 38, 39, 40, 48 (Ca), 48 (Mn), 48: 2, 48: 3, 48: 4, 49, 49: 1, 50, 51, 52, 52: 2, 53: 1, 53, 55, 57 (Ca), 57: 1, 60, 60: 1, 63: 1, 63: 2, 64, 64: 1, 81, 83, 87, 88, 89, 90, 101 (Bengara) ), 104, 105, 106, 108 (cadmium red), 112, 114, 122 (quinacridone magenta), 123, 146, 149, 163, 166, 168, 170, 172, 177, 178, 179, 184, 185, 190, 193, 202, 209, 2 9,269, etc., and C. I. Pigment violet 19, especially C.I. I. Pigment Red 122 is preferable.

Further, as pigments for cyan ink, C.I. I. Pigment Blue 1, 2, 3, 15, 15: 1, 15: 2, 15: 3, 15:34, 16, 17: 1, 22, 25, 56, 60, C.I. I. Bat blue 4, 60, 63 and the like. I. Pigment Blue 15: 3 is preferable.
The above pigments may be used alone or in combination of a plurality selected from the above-mentioned groups or between the groups.

(Dispersant)
In the present invention, a nonionic compound, an anionic compound, a cationic compound, an amphoteric compound, and the like can be used as the dispersant used in the encapsulated pigment or the resin dispersion pigment.
Examples thereof include a copolymer of monomers having an α, β-ethylenically unsaturated group. Examples of monomers having an α, β-ethylenically unsaturated group include ethylene, propylene, butene, pentene, hexene, vinyl acetate, allyl acetate, acrylic acid, methacrylic acid, crotonic acid, crotonic acid ester, itaconic acid, itacone Acid monoester, maleic acid, maleic acid monoester, maleic acid diester, fumaric acid, fumaric acid monoester, vinyl sulfonic acid, styrene sulfonic acid, sulfonated vinyl naphthalene, vinyl alcohol, acrylamide, methacryloxyethyl phosphate, bismethacryloxy Styrene derivatives such as ethyl phosphate, methacryloxyethyl phenyl acid phosphate, ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, styrene, α-methylstyrene, vinyltoluene , Vinylcyclohexane, vinylnaphthalene, vinylnaphthalene derivatives, alkyl acrylates that may be substituted with aromatic groups, phenyl esters of acrylate, alkyl methacrylates that may be substituted with aromatic groups, phenyl esters of methacrylic acid, methacryl Acid cycloalkyl ester, crotonic acid alkyl ester, itaconic acid dialkyl ester, maleic acid dialkyl ester, vinyl alcohol, and derivatives of the above compounds.

A copolymer obtained by copolymerizing a single monomer or a plurality of monomers having the α, β-ethylenically unsaturated group is used as a polymer dispersant. Specifically, acrylic acid alkyl ester-acrylic acid copolymer, methacrylic acid alkyl ester-methacrylic acid copolymer, styrene-alkyl acrylic acid ester-acrylic acid copolymer, styrene-methacrylic acid phenyl ester-methacrylic acid, Styrene-methacrylic acid cyclohexyl ester-methacrylic acid copolymer, styrene-styrenesulfonic acid copolymer, styrene-maleic acid copolymer, styrene-methacrylic acid copolymer, styrene-acrylic acid copolymer, vinylnaphthalene-maleic Examples include acid copolymers, vinyl naphthalene-methacrylic acid copolymers, vinyl naphthalene-acrylic acid copolymers, polystyrene, polyester, and polyvinyl alcohol.
The dispersant in the present invention is preferably 2,000-60,000 in terms of weight average molecular weight. In the dispersant of the present invention, the ratio of the amount added to the pigment is preferably in the range of 10% to 100% by mass ratio. The added amount of the dispersant is more preferably 20% or more and 70% or less, and further preferably 40% or more and 50% or less.

  The content of the color material in the ink jet recording liquid of the present invention is preferably 0.1 to 15% by mass and more preferably 1 to 10% by mass from the viewpoint of image density and image storage stability.

[Surfactant]
The ink jet recording liquid of the present invention can contain at least one surfactant. The surface tension of the ink jet recording liquid can be adjusted by adding a surfactant. As the surfactant, any of nonionic, cationic, anionic, and betaine surfactants may be used. The addition amount of the surfactant is preferably an amount for adjusting the surface tension of the ink of the present invention to 20 to 60 mN / m, more preferably 20 to 45 mN / m, and still more preferably, in order to eject droplets well by inkjet. The amount can be adjusted to 25 to 40 mN / m.
As the surfactant in the present invention, a compound having a structure having both a hydrophilic part and a hydrophobic part in the molecule can be used effectively. Anionic surfactants, cationic surfactants, amphoteric surfactants can be used. Any of the nonionic surfactants can be used. Furthermore, the above-mentioned polymer substance (polymer dispersing agent) can also be used as a surfactant.

Specific examples of anionic surfactants include sodium dodecylbenzenesulfonate, sodium lauryl sulfate, sodium alkyldiphenyl ether disulfonate, sodium alkylnaphthalenesulfonate, sodium dialkylsulfosuccinate, sodium stearate, potassium oleate, sodium dioctyl. Sulfosuccinate, sodium polyoxyethylene alkyl ether sulfate, sodium polyoxyethylene alkyl ether sulfate, sodium polyoxyethylene alkyl phenyl ether sulfate, sodium dialkylsulfosuccinate, sodium stearate, sodium oleate, t-octylphenoxyethoxypolyethoxyethyl Examples include sodium sulfate, etc., and select one or more of these Rukoto can.
Specific examples of the nonionic surfactant include, for example, polyoxyethylene lauryl ether, polyoxyethylene octyl phenyl ether, polyoxyethylene oleyl phenyl ether, polyoxyethylene nonyl phenyl ether, oxyethylene / oxypropylene block copolymer, t- Examples include octylphenoxyethyl polyethoxyethanol, nonylphenoxyethyl polyethoxyethanol, and the like, and one or more of these can be selected.
Examples of the cationic surfactant include tetraalkylammonium salts, alkylamine salts, benzalkonium salts, alkylpyridium salts, imidazolium salts, and the like. Specific examples thereof include dihydroxyethyl stearylamine and 2-heptadecenyl. -Hydroxyethyl imidazoline, lauryl dimethyl benzyl ammonium chloride, cetyl pyridinium chloride, stearamide methyl pyridium chloride and the like.
The amount of the surfactant added to the ink jet recording liquid in the invention is not particularly limited, but is preferably 1% by mass or more, more preferably 1 to 10% by mass, and still more preferably 1 to 3%. % By mass.

[Polymer particles]
The ink jet recording liquid of the present invention can contain at least one polymer particle. Ink fixability can be improved by containing polymer particles.
Examples of the polymer particles in the present invention include thermoplastic, thermosetting or modified acrylic, epoxy, polyurethane, polyether, polyamide, unsaturated polyester, phenol, silicone, or fluorine. Resins, polyvinyl resins such as vinyl chloride, vinyl acetate, polyvinyl alcohol or polyvinyl butyral, polyester resins such as alkyd resins and phthalic resins, melamine resins, melamine formaldehyde resins, aminoalkyd co-condensation resins, urea resins, urea resins And the like, or particles of a resin having an anionic group such as a copolymer or a mixture thereof. Among these, anionic acrylic resins include, for example, an acrylic monomer having an anionic group (anionic group-containing acrylic monomer) and, if necessary, other monomers copolymerizable with the anionic group-containing acrylic monomer. Obtained by polymerization in a solvent. Examples of the anionic group-containing acrylic monomer include an acrylic monomer having one or more selected from the group consisting of a carboxyl group, a sulfonic acid group, and a phosphonic group. Among them, an acrylic monomer having a carboxyl group (for example, acrylic acid) Methacrylic acid, crotonic acid, ethacrylic acid, propylacrylic acid, isopropylacrylic acid, itaconic acid, fumaric acid and the like), and acrylic acid or methacrylic acid is particularly preferred.

  The polymer particles in the present invention are preferably self-dispersing polymer particles having a carboxyl group from the viewpoint of ejection stability and liquid stability (particularly dispersion stability) when a colorant (particularly pigment) described later is used. Self-dispersing polymer particles are more preferred. Self-dispersing polymer particles are water-insoluble polymers that can be dispersed in an aqueous medium by the functional groups (particularly acidic groups or salts thereof) of the polymer itself in the absence of other surfactants, By means of water-insoluble polymer particles containing no free emulsifier.

Here, the dispersed state refers to both an emulsified state (emulsion) in which a water-insoluble polymer is dispersed in an aqueous medium and a dispersed state (suspension) in which a water-insoluble polymer is dispersed in an aqueous medium in a solid state. It includes the state of.
The water-insoluble polymer in the present invention is preferably a water-insoluble polymer that can be in a dispersed state in which the water-insoluble polymer is dispersed in a solid state from the viewpoint of aggregation speed and fixability when a liquid composition is used.

  The dispersion state of the self-dispersing polymer particles in the present invention refers to a solution obtained by dissolving 30 g of a water-insoluble polymer in 70 g of an organic solvent (for example, methyl ethyl ketone), and a neutralizing agent capable of neutralizing 100% of the salt-forming group of the water-insoluble polymer. After mixing and stirring (apparatus: stirring apparatus with stirring blade, rotation speed 200 rpm, 30 minutes, 25 ° C.) (sodium hydroxide if the salt-forming group is anionic, acetic acid if cationic) and 200 g of water The state in which even after removing the organic solvent from the mixed solution, it can be visually confirmed that the dispersed state exists stably at 25 ° C. for at least one week.

  The water-insoluble polymer means a polymer having a dissolution amount of 10 g or less when the polymer is dried at 105 ° C. for 2 hours and then dissolved in 100 g of water at 25 ° C., and the dissolution amount is preferable. Is 5 g or less, more preferably 1 g or less. The dissolution amount is the dissolution amount when neutralized with sodium hydroxide or acetic acid according to the kind of the salt-forming group of the water-insoluble polymer.

  The aqueous medium is configured to contain water, and may contain a hydrophilic organic solvent as necessary. In the present invention, it is preferably composed of water and 0.2% by mass or less of a hydrophilic organic solvent with respect to water, and more preferably composed of water.

  The main chain skeleton of the water-insoluble polymer is not particularly limited. For example, a vinyl polymer or a condensation polymer (epoxy resin, polyester, polyurethane, polyamide, cellulose, polyether, polyurea, polyimide, polycarbonate, etc.) is used. it can. Of these, vinyl polymers are particularly preferred.

Preferable examples of the vinyl polymer and the monomer constituting the vinyl polymer include those described in JP-A Nos. 2001-181549 and 2002-88294. In addition, radical transfer of vinyl monomers using dissociable groups (or substituents that can be induced to dissociable groups), polymerization initiators, and iniferters, or dissociable groups on either initiators or terminators A vinyl polymer in which a dissociable group is introduced at the end of a polymer chain by ionic polymerization using a compound having (or a substituent that can be derived from a dissociable group) can also be used.
Moreover, as a suitable example of the monomer which comprises a condensation type polymer and a condensation type polymer, what is described in Unexamined-Japanese-Patent No. 2001-247787 can be mentioned.

  The self-dispersing polymer particles in the present invention preferably contain a water-insoluble polymer containing a hydrophilic constituent unit and a constituent unit derived from an aromatic group-containing monomer from the viewpoint of self-dispersibility.

The hydrophilic structural unit is not particularly limited as long as it is derived from a hydrophilic group-containing monomer, and even if it is derived from one kind of hydrophilic group-containing monomer, it contains two or more hydrophilic groups. It may be derived from a monomer. The hydrophilic group is not particularly limited, and may be a dissociable group or a nonionic hydrophilic group.
In the present invention, the hydrophilic group is preferably a dissociable group and more preferably an anionic dissociable group from the viewpoint of promoting self-dispersion and the stability of the formed emulsified or dispersed state. Examples of the dissociable group include a carboxyl group, a phosphoric acid group, and a sulfonic acid group. Among them, a carboxyl group is preferable from the viewpoint of fixability when an ink composition is configured.

The hydrophilic group-containing monomer in the present invention is preferably a dissociable group-containing monomer from the viewpoints of self-dispersibility and aggregation, and is a dissociable group-containing monomer having a dissociable group and an ethylenically unsaturated bond. It is preferable.
Examples of the dissociable group-containing monomer include an unsaturated carboxylic acid monomer, an unsaturated sulfonic acid monomer, and an unsaturated phosphoric acid monomer.

Specific examples of the unsaturated carboxylic acid monomer include acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid, citraconic acid, and 2-methacryloyloxymethyl succinic acid. Specific examples of the unsaturated sulfonic acid monomer include styrene sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, 3-sulfopropyl (meth) acrylate, and bis- (3-sulfopropyl) -itaconate. It is done. Specific examples of unsaturated phosphoric acid monomers include vinylphosphonic acid, vinyl phosphate, bis (methacryloxyethyl) phosphate, diphenyl-2-acryloyloxyethyl phosphate, diphenyl-2-methacryloyloxyethyl phosphate, dibutyl-2- Examples include acryloyloxyethyl phosphate.
Among the dissociable group-containing monomers, unsaturated carboxylic acid monomers are preferable and acrylic acid and methacrylic acid are more preferable from the viewpoints of dispersion stability and ejection stability.

The self-dispersing polymer particles in the present invention preferably contain a polymer having a carboxyl group from the viewpoint of self-dispersibility and agglomeration speed when contacted with the treatment liquid, and have a carboxyl group and an acid value (mgKOH / g It is more preferable that the polymer contains 25-100. Furthermore, the acid value is more preferably from 25 to 80, and particularly preferably from 30 to 65, from the viewpoints of self-dispersibility and the aggregation rate when contacted with the treatment liquid.
In particular, when the acid value is 25 or more, the stability of self-dispersibility is good, and when it is 100 or less, the cohesiveness is improved.

The aromatic group-containing monomer is not particularly limited as long as it is a compound containing an aromatic group and a polymerizable group. The aromatic group may be a group derived from an aromatic hydrocarbon or a group derived from an aromatic heterocycle. In the present invention, an aromatic group derived from an aromatic hydrocarbon is preferable from the viewpoint of particle shape stability in an aqueous medium.
The polymerizable group may be a condensation polymerizable polymerizable group or an addition polymerizable polymerizable group. In the present invention, from the viewpoint of particle shape stability in an aqueous medium, an addition polymerizable group is preferable, and a group containing an ethylenically unsaturated bond is more preferable.

  The aromatic group-containing monomer in the present invention is preferably a monomer having an aromatic group derived from an aromatic hydrocarbon and an ethylenically unsaturated bond. The aromatic group-containing monomer may be used alone or in combination of two or more.

Examples of the aromatic group-containing monomer include phenoxyethyl (meth) acrylate, benzyl (meth) acrylate, phenyl (meth) acrylate, and a styrene monomer. Of these, aromatic group-containing (meth) acrylate monomers are preferred from the viewpoint of the balance between the hydrophilicity and hydrophobicity of the polymer chain and the ink fixability, and include phenoxyethyl (meth) acrylate, benzyl (meth) acrylate, and phenyl (meth). At least one selected from acrylates is more preferable, and phenoxyethyl (meth) acrylate and benzyl (meth) acrylate are more preferable.
“(Meth) acrylate” means acrylate or methacrylate.

The self-dispersing polymer particles in the present invention include a structural unit derived from an aromatic group-containing (meth) acrylate monomer, and the content is preferably 10% by mass to 95% by mass. When the content of the aromatic group-containing (meth) acrylate monomer is 10% by mass to 95% by mass, the stability of the self-emulsification or dispersion state can be improved, and further the increase in ink viscosity can be suppressed.
In the present invention, from the viewpoints of stability in a self-dispersing state, stabilization of particle shape in an aqueous medium due to hydrophobic interaction between aromatic rings, and reduction in the amount of water-soluble components due to appropriate hydrophobicization of particles. More preferably, the content is from mass% to 90 mass%, more preferably from 15 mass% to 80 mass%, and particularly preferably from 25 mass% to 70 mass%.

  The self-dispersing polymer particles in the present invention can be constituted using, for example, a structural unit derived from an aromatic group-containing monomer and a structural unit derived from a dissociable group-containing monomer. Furthermore, other structural units may be further included as necessary.

The monomer that forms the other structural unit is not particularly limited as long as it is a monomer copolymerizable with the aromatic group-containing monomer and the dissociable group-containing monomer. Among these, an alkyl group-containing monomer is preferable from the viewpoint of flexibility of the polymer skeleton and ease of control of the glass transition temperature (Tg).
Examples of the alkyl group-containing monomer include methyl (meth) acrylate, ethyl (meth) acrylate, isopropyl (meth) acrylate, n-propyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, alkyl (meth) acrylates such as t-butyl (meth) acrylate, hexyl (meth) acrylate, ethylhexyl (meth) acrylate; hydroxymethyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) Ethylenically unsaturated monomers having a hydroxyl group such as acrylate, 4-hydroxybutyl (meth) acrylate, hydroxypentyl (meth) acrylate, hydroxyhexyl (meth) acrylate; Dialkylaminoalkyl (meth) acrylates such as ru (meth) acrylate; N-hydroxyalkyl (meth) such as N-hydroxymethyl (meth) acrylamide, N-hydroxyethyl (meth) acrylamide, N-hydroxybutyl (meth) acrylamide Acrylamide; N-methoxymethyl (meth) acrylamide, N-ethoxymethyl (meth) acrylamide, N- (n-, iso) butoxymethyl (meth) acrylamide, N-methoxyethyl (meth) acrylamide, N-ethoxyethyl (meta And (meth) acrylamides such as N-alkoxyalkyl (meth) acrylamides such as acrylamide and N- (n-, iso) butoxyethyl (meth) acrylamide.

  The molecular weight range of the water-insoluble polymer constituting the self-dispersing polymer particles in the present invention is preferably 3000 to 200,000, more preferably 5000 to 150,000, and more preferably 10,000 to 100,000 in terms of weight average molecular weight. More preferably it is. By setting the weight average molecular weight to 3000 or more, the amount of water-soluble components can be effectively suppressed. Moreover, self-dispersion stability can be improved by making a weight average molecular weight into 200,000 or less.

  The weight average molecular weight is measured by gel permeation chromatography (GPC). GPC uses HLC-8020GPC (manufactured by Tosoh Corporation), TSKgel, Super Multipore HZ-H (manufactured by Tosoh Corporation, 4.6 mm ID × 15 cm) as columns, and THF (tetrahydrofuran) as an eluent. ) Is used. The conditions are as follows: the sample concentration is 0.35 / min, the flow rate is 0.35 ml / min, the sample injection amount is 10 μl, the measurement temperature is 40 ° C., and an IR detector is used. In addition, the calibration curve is “standard sample TSK standard, polystyrene” manufactured by Tosoh Corporation: “F-40”, “F-20”, “F-4”, “F-1”, “A-5000”, It is prepared from 8 samples of “A-2500”, “A-1000”, “n-propylbenzene”.

The water-insoluble polymer constituting the self-dispersing polymer particle in the present invention is a structural unit derived from an aromatic group-containing (meth) acrylate monomer (preferably phenoxyethyl (meth) acrylate) from the viewpoint of controlling the hydrophilicity / hydrophobicity of the polymer. It is preferable that 15-80 mass% of the total mass of a self-dispersing polymer particle is included as a copolymerization ratio for the structural unit derived from and / or the structural unit derived from benzyl (meth) acrylate.
In addition, the water-insoluble polymer has a constitution derived from a carboxyl group-containing monomer having a copolymerization ratio of 15 to 80% by mass of a constitutional unit derived from an aromatic group-containing (meth) acrylate monomer from the viewpoint of controlling the hydrophilicity / hydrophobicity of the polymer. And a structural unit derived from an alkyl group-containing monomer (preferably a structural unit derived from an alkyl ester of (meth) acrylic acid), and a structural unit derived from phenoxyethyl (meth) acrylate and / or Alternatively, a structural unit derived from benzyl (meth) acrylate as a copolymerization ratio of 15 to 80% by mass, a structural unit derived from a carboxyl group-containing monomer, and a structural unit derived from an alkyl group-containing monomer (preferably (meth) A structural unit derived from an alkyl ester having 1 to 4 carbon atoms of acrylic acid) More preferably, the acid value is 25 to 100 and the weight average molecular weight is preferably 3000 to 200,000, the acid value is 25 to 95, and the weight average molecular weight is 5000 to 150,000. It is more preferable that

  Specific examples of the water-insoluble polymer constituting the self-dispersing polymer particles are listed below as exemplary compounds B-01 to B-19, but the present invention is not limited thereto. In addition, the parenthesis represents the mass ratio of the copolymerization component.

B-01: Phenoxyethyl acrylate / methyl methacrylate / acrylic acid copolymer (50/45/5)
B-02: Phenoxyethyl acrylate / benzyl methacrylate / isobutyl methacrylate / methacrylic acid copolymer (30/35/29/6)
B-03: Phenoxyethyl methacrylate / isobutyl methacrylate / methacrylic acid copolymer (50/44/6)
B-04: Phenoxyethyl acrylate / methyl methacrylate / ethyl acrylate / acrylic acid copolymer (30/55/10/5)
B-05: benzyl methacrylate / isobutyl methacrylate / methacrylic acid copolymer (35/59/6)
B-06: Styrene / phenoxyethyl acrylate / methyl methacrylate / acrylic acid copolymer (10/50/35/5)
B-07: benzyl acrylate / methyl methacrylate / acrylic acid copolymer (55/40/5)
B-08: Phenoxyethyl methacrylate / benzyl acrylate / methacrylic acid copolymer (45/47/8)
B-09: Styrene / phenoxyethyl acrylate / butyl methacrylate / acrylic acid copolymer (5/48/40/7)
B-10: benzyl methacrylate / isobutyl methacrylate / cyclohexyl methacrylate / methacrylic acid copolymer (35/30/30/5)
B-11: Phenoxyethyl acrylate / methyl methacrylate / butyl acrylate / methacrylic acid copolymer (12/50/30/8)
B-12: benzyl acrylate / isobutyl methacrylate / acrylic acid copolymer (93/2/5)
B-13: Styrene / phenoxyethyl methacrylate / butyl acrylate / acrylic acid copolymer (50/5/20/25)
B-14: Styrene / butyl acrylate / acrylic acid copolymer (62/35/3)
B-15: Methyl methacrylate / phenoxyethyl acrylate / acrylic acid copolymer (45/51/4)
B-16: Methyl methacrylate / phenoxyethyl acrylate / acrylic acid copolymer (45/49/6)
B-17: Methyl methacrylate / phenoxyethyl acrylate / acrylic acid copolymer (45/48/7)
B-18: Methyl methacrylate / phenoxyethyl acrylate / acrylic acid copolymer (45/47/8)
B-19: Methyl methacrylate / phenoxyethyl acrylate / acrylic acid copolymer (45/45/10)

  The method for producing the water-insoluble polymer constituting the self-dispersing polymer particles in the present invention is not particularly limited. For example, emulsion polymerization is carried out in the presence of a polymerizable surfactant to obtain a surfactant and a water-insoluble polymer. Examples include a method of covalent bonding, and a method of copolymerizing a monomer mixture containing the hydrophilic group-containing monomer and the aromatic group-containing monomer by a known polymerization method such as a solution polymerization method or a bulk polymerization method. Among the polymerization methods, a solution polymerization method is preferable and a solution polymerization method using an organic solvent is more preferable from the viewpoint of aggregation rate and droplet ejection stability when an ink composition is used.

  The self-dispersing polymer particles in the present invention include a polymer synthesized in an organic solvent from the viewpoint of aggregation rate, and the polymer has a carboxyl group (preferably having an acid value of 20 to 100). Part or all of the carboxyl groups of the polymer are preferably neutralized and prepared as a polymer dispersion having water as a continuous phase. That is, the production of the self-dispersing polymer particles in the present invention includes a step of synthesizing a polymer in an organic solvent and a dispersion step of making an aqueous dispersion in which at least a part of the carboxyl groups of the polymer is neutralized. It is preferable to do so.

The dispersion step preferably includes the following step (1) and step (2).
Step (1): Step of stirring a mixture containing a polymer (water-insoluble polymer), an organic solvent, a neutralizing agent, and an aqueous medium Step (2): Step of removing the organic solvent from the mixture

The step (1) is preferably a treatment in which a polymer (water-insoluble polymer) is first dissolved in an organic solvent, then a neutralizing agent and an aqueous medium are gradually added, mixed and stirred to obtain a dispersion. In this way, by adding a neutralizing agent and an aqueous medium to a water-insoluble polymer solution dissolved in an organic solvent, a self-dispersing polymer having a particle size with higher storage stability without requiring strong shearing force. Particles can be obtained.
There is no restriction | limiting in particular in the stirring method of this mixture, Dispersing machines, such as a generally used mixing stirring apparatus and an ultrasonic disperser, a high-pressure homogenizer, can be used as needed.

Preferred examples of the organic solvent include alcohol solvents, ketone solvents, and ether solvents.
Examples of the alcohol solvent include isopropyl alcohol, n-butanol, t-butanol, ethanol and the like. Examples of the ketone solvent include acetone, methyl ethyl ketone, diethyl ketone, and methyl isobutyl ketone. Examples of ether solvents include dibutyl ether and dioxane. Among these solvents, ketone solvents such as methyl ethyl ketone and alcohol solvents such as isopropyl alcohol are preferable. It is also preferable to use isopropyl alcohol and methyl ethyl ketone in combination for the purpose of moderating the polarity change during the phase inversion from oil to water. By using this solvent in combination, it is possible to obtain self-dispersing polymer particles having a fine particle size with high dispersion stability without aggregation and sedimentation and fusion between particles.

  The neutralizing agent is used so that a part or all of the dissociable group is neutralized and the self-dispersing polymer forms a stable emulsified or dispersed state in water. When the self-dispersing polymer of the present invention has an anionic dissociative group (for example, a carboxyl group) as a dissociable group, the neutralizing agent used is basic such as an organic amine compound, ammonia, or an alkali metal hydroxide. Compounds. Examples of organic amine compounds include monomethylamine, dimethylamine, trimethylamine, monoethylamine, diethylamine, triethylamine, monopropylamine, dipropylamine, monoethanolamine, diethanolamine, triethanolamine, N, N-dimethyl-ethanolamine, N, N-diethyl-ethanolamine, 2-dimethylamino-2-methyl-1-propanol, 2-amino-2-methyl-1-propanol, N-methyldiethanolamine, N-ethyldiethanolanine, monoisopropanolamine, di Examples include isopropanolamine and triisopropanolamine. Examples of the alkali metal hydroxide include lithium hydroxide, sodium hydroxide, and potassium hydroxide. Among these, sodium hydroxide, potassium hydroxide, triethylamine, and triethanolamine are preferable from the viewpoint of stabilizing the dispersion of the self-dispersing polymer particles of the present invention in water.

  These basic compounds are preferably used in an amount of 5 to 120 mol%, more preferably 10 to 110 mol%, still more preferably 15 to 100 mol%, based on 100 mol% of the dissociable group. . By setting it as 15 mol% or more, the effect which stabilizes dispersion | distribution of the particle | grains in water expresses, and there exists an effect which reduces a water-soluble component by setting it as 100 mol% or less.

  In the step (2), the aqueous dispersion of the self-dispersing polymer particles is obtained by distilling off the organic solvent from the dispersion obtained in the step (1) by a conventional method such as distillation under reduced pressure and phase-inversion into an aqueous system. A dispersion can be obtained. The organic solvent in the obtained aqueous dispersion has been substantially removed, and the amount of the organic solvent is preferably 0.2% by mass or less, more preferably 0.1% by mass or less.

The average particle size of the polymer particles (particularly self-dispersing polymer particles) is preferably in the range of 10 to 400 nm, more preferably in the range of 10 to 200 nm, still more preferably in the range of 10 to 100 nm, and particularly preferably in terms of volume average particle size. It is the range of 10-50 nm. Manufacturability is improved by having an average particle diameter of 10 nm or more. Moreover, storage stability improves by setting it as an average particle diameter of 400 nm or less. Moreover, there is no restriction | limiting in particular regarding the particle size distribution of a polymer particle, Any of what has a wide particle size distribution or a monodispersed particle size distribution may be sufficient. Further, two or more water-insoluble particles may be mixed and used.
The average particle size and particle size distribution of the polymer particles are determined by measuring the volume average particle size by a dynamic light scattering method using a nanotrack particle size distribution measuring device UPA-EX150 (manufactured by Nikkiso Co., Ltd.). It is

The content of the polymer particles (particularly self-dispersing polymer particles) in the liquid composition is preferably 1 to 30% by mass with respect to the liquid composition from the viewpoint of glossiness of the image, More preferably, it is 15 mass%.
The polymer particles (particularly self-dispersing polymer particles) can be used singly or in combination of two or more.

[Other ingredients]
The ink jet recording liquid of the present invention may contain other additives. Other additives include, for example, ultraviolet absorbers, anti-fading agents, anti-mold agents, pH adjusters, rust inhibitors, antioxidants, emulsion stabilizers, preservatives, antifoaming agents, viscosity modifiers, and dispersion stabilizers. Known additives such as agents and chelating agents are included.

  Examples of the UV absorber include benzophenone UV absorbers, benzotriazole UV absorbers, salicylate UV absorbers, cyanoacrylate UV absorbers, nickel complex salt UV absorbers, and the like.

  As the antifading agent, various organic and metal complex antifading agents can be used. Organic anti-fading agents include hydroquinones, alkoxyphenols, dialkoxyphenols, phenols, anilines, amines, indanes, chromans, alkoxyanilines, heterocycles, etc. Complex, zinc complex and the like.

  Antifungal agents include sodium dehydroacetate, sodium benzoate, sodium pyridinethione-1-oxide, p-hydroxybenzoic acid ethyl ester, 1,2-benzisothiazolin-3-one, sodium sorbate, sodium pentachlorophenol, etc. Can be mentioned. These are preferably used in the ink in an amount of 0.02 to 1.00% by mass.

  The pH adjusting agent is not particularly limited as long as it can adjust the pH to a desired value without adversely affecting the prepared inkjet recording liquid, and can be appropriately selected according to the purpose. Amines (eg, diethanolamine, triethanolamine, 2-amino-2-ethyl-1,3-propanediol), alkali metal hydroxides (eg, lithium hydroxide, sodium hydroxide, potassium hydroxide), ammonium Examples thereof include hydroxides (for example, ammonium hydroxide and quaternary ammonium hydroxides), phosphonium hydroxides, alkali metal carbonates, and the like.

  Examples of the rust inhibitor include acidic sulfite, sodium thiosulfate, ammonium thiodiglycolate, diisopropylammonium nitrite, pentaerythritol tetranitrate, and dicyclohexylammonium nitrite.

  Examples of the antioxidant include phenol antioxidants (including hindered phenol antioxidants), amine antioxidants, sulfur antioxidants, phosphorus antioxidants, and the like.

  Examples of the chelating agent include sodium ethylenediaminetetraacetate, sodium nitrilotriacetate, sodium hydroxyethylethylenediaminetriacetate, sodium diethylenetriaminepentaacetate, sodium uramil diacetate and the like.

(Physical properties of ink jet recording liquid)
The surface tension of the ink jet recording liquid of the present invention is preferably 20 mN / m or more and 60 mN / m or less. More preferably, it is 20 mN or more and 45 mN / m or less, More preferably, it is 25 mN / m or more and 40 mN / m or less. The surface tension can be adjusted to a desired range by containing a surfactant, for example.

  In addition, the viscosity at 20 ° C. of the inkjet recording liquid of the present invention is preferably 5 mPa · s or more and 20 mPa · s or less, more preferably 5.5 mPa · s or more and less than 18 mPa · s, and more preferably Preferably, it is 6 mPa · s or more and less than 16 mPa · s. Furthermore, the viscosity at 40 ° C. of the inkjet recording liquid of the present invention is preferably 3 mPa · s or more and 15 mPa · s or less, more preferably 3.5 mPa · s or more and less than 12 mPa · s, and further preferably 4 mPa · s or more. The viscosity, which is less than 10 mPa · s, can be adjusted to a desired range by changing, for example, the molecular weight or content of the water-soluble organic solvent. In this invention, it can adjust to a desired range more easily by including the said 1st water-soluble organic solvent.

<Inkjet recording method>
As a preferred ink jet recording method for the present invention, a known image receiving material such as plain paper, resin-coated paper, for example, JP-A-8-169172, JP-A-8-27693, JP-A-2-276670, JP-A-7-276789, JP-A-9-323475, JP-A-62-238783, JP-A-10-153989, JP-A-10-217473, JP-A-10-235995 10-337947, 10-217597, 10-337947, etc. Form images on inkjet paper, film, electrophotographic co-paper, fabric, glass, metal, ceramics, etc. The method of doing is mentioned. In addition, the description of paragraph numbers 0093 to 0105 in JP-A No. 2003-306623 can be applied as an ink jet recording method preferable for the present invention.

  In forming an image, a polymer latex compound may be used in combination for the purpose of giving glossiness or water resistance or improving weather resistance. The timing of applying the latex compound to the image receiving material may be before, after, or simultaneously with the application of the colorant, and therefore the addition location may be in the image receiving paper. It may be in ink or may be used as a liquid material of polymer latex alone. Specifically, JP 2002-166638 (Japanese Patent Application 2000-363090), JP 2002-121440 (Japanese Patent Application 2000-315231), JP 2002-154201 (Japanese Patent Application 2000-354380), JP 2002-144696 ( The methods described in Japanese Patent Application No. 2000-343944) and Japanese Patent Application Laid-Open No. 2002-080759 (Japanese Patent Application No. 2000-268952) can be preferably used.

As an example of a preferable image forming method using the inkjet recording liquid of the present invention, an inkjet recording method including the following steps can be exemplified.
1st process: The process of providing the liquid composition which improves printability to a recording medium.
Second step: a step of applying an inkjet recording liquid to the recording medium to which the liquid composition has been applied.
Other steps: Other steps are not particularly limited and may be appropriately selected depending on the purpose.
For example, a drying removal process, a heat fixing process, etc. are mentioned. The drying removal step is not particularly limited except that the ink solvent in the ink jet recording liquid applied to the recording medium is removed by drying, and can be appropriately selected according to the purpose. The heat fixing step is not particularly limited except that the latex particles contained in the ink used in the ink jet recording method are melt-fixed, and can be appropriately selected depending on the purpose.

As another example of a preferable image forming method in the present invention,
1st process: The process of providing the liquid composition which improves printability to an intermediate transfer body.
Second step: a step of applying an ink jet recording liquid to the intermediate transfer body to which the liquid composition has been applied.
Third step: a step of transferring an ink image formed on the intermediate transfer member to a recording medium.
Other steps: Other steps are not particularly limited and may be appropriately selected depending on the purpose. For example, a drying removal process, a heat fixing process, etc. are mentioned.

(Liquid composition for improving printability)
As an ink jet recording method using the ink jet recording liquid of the present invention, an ink jet recording method including a step of applying a liquid composition for improving printability to a recording medium can be given as a preferred example.
As a preferred example of the liquid composition that improves the printability, a liquid composition that generates aggregates by changing the pH of the inkjet recording liquid can be exemplified. The pH of the liquid composition is preferably 1 to 6, more preferably 2 to 5, and still more preferably 3 to 5.

Examples of the aggregating component for aggregating the pigment include polyvalent metal salts, organic acids, polyallylamine and derivatives thereof.
Examples of the polyvalent metal salt include alkaline earth metals belonging to Group 2 of the periodic table (eg, magnesium, calcium), transition metals belonging to Group 3 of the periodic table (eg, lanthanum), and Group 13 of the periodic table. Mention may be made of salts of cations (for example, aluminum) and lanthanides (for example, neodymium). As these metal salts, carboxylate (formic acid, acetic acid, benzoate, etc.), nitrate, chloride, and thiocyanate are suitable. Among them, preferred are calcium salts or magnesium salts of carboxylic acids (formic acid, acetic acid, benzoates, etc.), calcium salts or magnesium salts of nitric acid, calcium chloride, magnesium chloride, and calcium salts or magnesium salts of thiocyanic acid.

  Examples of the organic acid include polyacrylic acid, acetic acid, glycolic acid, malonic acid, malic acid, maleic acid, ascorbic acid, succinic acid, glutaric acid, fumaric acid, citric acid, tartaric acid, lactic acid, sulfonic acid, and orthophosphoric acid. , Pyrrolidone carboxylic acid, pyrone carboxylic acid, pyrrole carboxylic acid, furan carboxylic acid, pyridine carboxylic acid, coumaric acid, thiophene carboxylic acid, nicotinic acid, derivatives of these compounds, or salts thereof are preferably selected. be able to.

The aggregating components can be used alone or in combination of two or more.
As content in the aqueous liquid composition of the aggregation component which aggregates a pigment, 1-10 mass% is preferable, More preferably, it is 1.5-7 mass%, More preferably, it is the range of 2-6 mass%. is there.

  EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, “part” and “%” are based on mass.

<Example 1>
-Preparation of inkjet recording liquid-
[Preparation of pigment (coloring material) dispersion]
(Preparation of polymer dispersant P-1)
To a 1000 ml three-necked flask equipped with a stirrer and a condenser, 88 g of methyl ethyl ketone was added and heated to 72 ° C. under a nitrogen atmosphere. Here, 50 g of methyl ethyl ketone was mixed with 0.85 g of dimethyl 2,2′-azobisisobutyrate, 60 g of benzyl methacrylate, A solution in which 10 g of methacrylic acid and 30 g of methyl methacrylate were dissolved was dropped over 3 hours. After completion of the dropwise addition, the reaction was further continued for 1 hour, and then a solution in which 0.42 g of dimethyl 2,2′-azobisisobutyrate was dissolved in 2 g of methyl ethyl ketone was added, heated to 78 ° C. and heated for 4 hours. The obtained reaction solution was reprecipitated twice in a large excess of hexane, and the precipitated resin was dried to obtain 96 g of a polymer dispersant P-1.
The composition of the obtained resin was confirmed by ¹ H-NMR, and the weight average molecular weight (Mw) determined by GPC was 44600. Furthermore, when the acid value of this polymer was calculated | required by the method of JIS specification (JISK0070: 1992), it was 65.2 mgKOH / g.

(Preparation of cyan dispersion)
10 parts of Pigment Blue 15: 3 (Phthalocyanine-A220 manufactured by Dainichi Seika Co., Ltd.), 5 parts of the polymer dispersant P-1 obtained above, 42 parts of methyl ethyl ketone, and 1 mol / L NaOH aqueous solution 5.5 parts and 87.2 parts of ion-exchanged water were mixed and dispersed with a bead mill using 0.1 mmΦ zirconia beads for 2 to 6 hours.
Methyl ethyl ketone was removed from the obtained dispersion at 55 ° C. under reduced pressure, and a part of water was removed to obtain a cyan dispersion having a pigment concentration of 10.2%.
As described above, a cyan dispersion liquid as a coloring material was prepared.

[Preparation of self-dispersing polymer particles]
360.0 g of methyl ethyl ketone was charged into a 2-liter three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas inlet tube, and the temperature was raised to 75 ° C. While maintaining the temperature in the reaction vessel at 75 ° C., 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and “V-601” (manufactured by Wako Pure Chemical Industries, Ltd.) A mixed solution consisting of 44 g was added dropwise at a constant speed so that the addition was completed in 2 hours. After completion of the dropwise addition, a solution consisting of 0.72 g of “V-601” and 36.0 g of methyl ethyl ketone was added, stirred for 2 hours at 75 ° C., and then a solution consisting of 0.72 g of “V-601” and 36.0 g of isopropanol was added. After stirring at 75 ° C. for 2 hours, the temperature was raised to 85 ° C., and stirring was further continued for 2 hours. The weight average molecular weight (Mw) of the obtained copolymer was 64000 (calculated in terms of polystyrene by gel permeation chromatography (GPC), columns used were TSKgel SuperHZM-H, TSKgel SuperHZ4000, TSKgel SuperHZ200 (manufactured by Tosoh Corporation)), The acid value was 38.9 (mgKOH / g).
Next, 668.3 g of the polymerization solution was weighed, 388.3 g of isopropanol and 145.7 ml of 1 mol / L NaOH aqueous solution were added, and the temperature in the reaction vessel was raised to 80 ° C. Next, 720.1 g of distilled water was added dropwise at a rate of 20 ml / min to disperse in water. Thereafter, the temperature in the reaction vessel was maintained at 80 ° C. for 2 hours, 85 ° C. for 2 hours, and 90 ° C. for 2 hours under atmospheric pressure, and then the reaction vessel was depressurized, and isopropanol, methyl ethyl ketone, and distilled water totaled 913. 7 g was distilled off to obtain an aqueous dispersion (emulsion) of self-dispersing polymer fine particles (P-2) having a solid content concentration of 28.0%. In addition, the number of each structural unit of the compound example (P-2) shown below represents mass ratio.

  Using the color material (cyan dispersion) obtained above, the first water-soluble organic solvent, the surfactant, and water, each component was mixed so that the final ink composition would be the following ink composition. . This was passed through a 5 μm membrane filter to prepare ink 1 (inkjet recording liquid).

(Composition of ink 1)
Cyan pigment (Pigment Blue 15: 3): 3%
Polymer dispersant P-1: 1.5%
Self-dispersing polymer particle P-2: 6%
POP (4) diglyceryl ether (SC-P400)
(First water-soluble organic solvent, Sakamoto Pharmaceutical Co., Ltd.): 30%
Orphin E1010 (manufactured by Nissin Chemical, surfactant): 1%
Ion exchange water: 58.5%

<Examples 2 to 11>
In Example 1, the first water-soluble organic solvent, and the types of the second water-soluble organic solvent and the third water-soluble organic solvent (hereinafter sometimes referred to as “other water-soluble organic solvents”), and Ink 2 to Ink 11 were prepared in the same manner as in Example 1 except that the content was changed as shown in Table 1 below.

<Comparative Examples 1-2>
Ink 12 to Ink 13 in Example 1, except that the types and contents of the first water-soluble organic solvent and other water-soluble organic solvents were changed as shown in Table 1 below. Was made.

<Evaluation>
[Curl property]
The curling properties of the ink jet recording liquid prepared above were evaluated as follows.
<Inkjet recording apparatus>
As an ink jet recording apparatus, a DMP-2831 (manufactured by Fujifilm Daimatics Co., Ltd.) was used (the cartridge was remodeled so that 10 pl discharge (DMC-11610) can be supplied from the outside).

<Recording medium>
As a recording medium, the following colorless ink composition (liquid composition for improving printability) was applied at 5 g / m to Tokishi Art Double Sided N (84.9 g / m ² product) (Mitsubishi Paper Co., Ltd.). ² was applied with an application bar and dried at 60 ° C. and 15 m / s for 1 minute.
The colorless ink composition was prepared by mixing the following materials.
(Colorless ink composition)
・ Citric acid: 15g
・ Orphine E1010 (manufactured by Nissin Chemical Industry Co., Ltd)
・ Ion-exchanged water ... 84g

<Curl evaluation>
The recording medium after solid printing with an ink coating amount of 5 g / m ² was cut into 5 × 50 mm so that the curl direction was 50 mm to prepare a sample. Thereafter, the sample was left under conditions of a temperature of 25 ° C. and a humidity of 50%, and the curvature C of the sample was measured as follows. Table 1 shows the results of evaluation of curling properties according to the following evaluation criteria.

~ Measurement method of curvature ~
The curvature C of the sample after coating the inkjet recording liquid was measured in an environment of 25 ° C. and a relative humidity of 50%. Note that the curl value is expressed as in the following formula 1, assuming that the curl is an arc of a circle having a radius R.
C = 1 / R (m) (Formula 1)

~Evaluation criteria~
(Double-circle): The curvature C of the sample 10 minutes after apply | coating did not exceed 20.
○: The curvature C of the sample one day after application did not exceed 20.
(Triangle | delta): The curvature C of the sample 7 days after apply | coating did not exceed 20.
X: The curvature C of the sample 7 days after application exceeded 20

[Preservation]
The temperature of the inkjet recording liquid (ink 1 to ink 13) prepared above was adjusted to 25 ° C. Using a vibration viscometer (BROOKFIELD, DV-II + VISCOMETER), the ink was measured in a stock solution at 25 ° C. and 25% relative humidity at 25 ° C. using a cone plate (φ35 mm). An average value of data in a range of 20 to 90% and a rotational speed in a range of 0.5 to 100 rpm was taken as a measurement value. The measured value immediately after the preparation was taken as ink viscosity 1.
Next, a part of the ink jet recording liquid (ink 1 to ink 13) is collected in a glass sample bottle, left in a sealed state at 60 ° C. for 2 weeks, and then stored in the same manner as above. Viscosity 2 was measured. At the same time, the state of the ink liquid was visually observed.
The variation rate {100− (ink viscosity 2 / ink viscosity 1) × 100} of the measured ink viscosity before and after the storage was calculated. In addition to the results of visual observation after storage, ink storage stability was evaluated according to the following evaluation criteria.

~Evaluation criteria~
(Double-circle): The variation rate of the ink viscosity was less than ± 15%, and no change in the ink was observed.
○: The variation rate of the ink viscosity was ± 15% or more and less than ± 30%, and no change in the ink liquid was observed.
Δ: The variation rate of the ink viscosity was ± 30% or more and less than ± 50%, and no change in the ink liquid was observed.
X: The variation rate of the ink viscosity was ± 50% or more, or separation or gelation of the ink liquid was observed.

[Image deformability]
For the ink jet recording liquids (ink 1 to ink 13) prepared above, the image deformability of the ink was evaluated as follows using the ink jet recording apparatus and the recording medium used in the above [curl property] evaluation.
A sample printed in a solid size of 5 cm × 5 cm (in which the amount of ink applied was 10 g / m ² ) was dried and fixed and heated at 90 ° C. for 10 seconds. The acceptability of image unevenness was determined according to the following evaluation criteria, and image deformability was evaluated.
-Evaluation criteria-
A: No unevenness was visually observed even after drying and fixing.
◯: No unevenness was visually observed after drying, but unevenness was observed after fixing.
Δ: Unevenness was not visually observed before drying, but unevenness was confirmed after drying.
X: Unevenness was visually observed before drying and before fixing.

  From Table 1, it can be seen that the ink jet recording liquid of the present invention showed a good curl suppressing effect. It can also be seen that the ink storage stability is good and the occurrence of image deformation can be suppressed.

Claims (5)

Applying a liquid containing one or more organic acids or polyvalent metal salts to a recording medium;
The recording medium provided with the liquid contains water, a colorant, and a water-soluble organic solvent represented by the following general formula (1), and contains a water-soluble organic solvent having an SP value of 27.5 or less. Applying an inkjet recording liquid having a rate of 70% by mass or more based on the total amount of the water-soluble organic solvent.

(In the formula, R represents an alkyleneoxy group having 2 to 5 carbon atoms, k, l, m, and n each represents an integer representing the number of repeating alkyleneoxy groups, and k + 1 + m + n = 0 to 50). Applying a liquid containing one or more organic acids or polyvalent metal salts to the intermediate transfer member;
The intermediate transfer body to which the liquid is applied contains water, a coloring material, and a water-soluble organic solvent represented by the following general formula (1), and has a SP value of 27.5 or less. A step of applying an inkjet recording liquid having a content of 70% by mass or more based on the total amount of the water-soluble organic solvent ;
Transferring the ink image formed on the intermediate transfer member to a recording medium .

(In the formula, R represents an alkyleneoxy group having 2 to 5 carbon atoms, k, l, m, and n each represents an integer representing the number of repeating alkyleneoxy groups, and k + 1 + m + n = 0 to 50). The inkjet recording method according to claim 1 or 2, wherein a content of the water-soluble organic solvent represented by the general formula (1) in the inkjet recording liquid is 5% by mass or more and less than 30% by mass. The inkjet recording method according to any one of claims 1 to 3, wherein the inkjet recording liquid further contains self-dispersing polymer particles. The self-dispersing polymer particles include a polymer having a carboxyl group, an acid value (mgKOH / g) of 25 to 100, and a content of structural units derived from an aromatic group-containing (meth) acrylate monomer of 10 The inkjet recording method according to claim 4, wherein the inkjet recording method is from mass% to 95 mass% .