JP5229719B2 - Novel diamine compound, polyamic acid and imidized polymer produced using the same - Google Patents

Description

  The present invention relates to a novel diamine compound, and polyamic acid and imidized polymer produced using the same.

  Polyimides have many higher-order structures consisting of cyclic structures such as heterocycles and aromatic rings, molecular chains are difficult to move even at high temperatures, have many higher-order bonds such as double bonds, and interatomic bond energy The heat resistance of polyimide is different from that of various plastics for the reasons that the heterocycle and aromatic ring interact with each other in the polymer molecule and form a CT (Charge Transfer) complex and the cohesion is large. Among them, it is ranked highest.

  Furthermore, polyimide not only has excellent heat resistance, but also has high strength, high elasticity, excellent mechanical properties, high insulation, low dielectric properties, and excellent electrical properties, as well as chemical resistance, radiation resistance, and flame resistance. Is also excellent.

  In recent years, photosensitive polyimides have also been developed. Ultra-highly integrated semiconductors, tough and strong adhesive polyimides are used in space transportation machines, highly transparent polyimides are used in optical communication equipment, and injection moldable polyimides are used in automobiles. Used in heat-resistant sliding parts such as parts.

  As an example of using a polyimide having the above characteristics for an optical application, an example using a polyimide using a dianhydride containing a sulfur atom and a diamine not containing a sulfur atom as an optical waveguide (Patent Document 1) ; Example using a polyimide that uses a diacid anhydride containing no sulfur atom and a diamine containing a sulfur atom as a liquid crystal alignment film (Patent Document 2); Example (Patent Document 3) used as a rate material; and Example using a mixture of polyamic acid not containing a sulfur atom, titanium oxide particles and other specific compounds as a positive photosensitive resin composition (Patent Document 4) Etc. are known.

JP 2004-131684 A JP-A-5-263077 JP 2001-354853 A JP 2005-208465 A

  An object of the present invention is to provide a novel diamine compound for producing a polyimide having a higher refractive index and excellent transparency and heat resistance, a polyamic acid and a polyimide produced using the same.

［式（１）中、Ｒ^１はそれぞれ独立して炭素数１〜３のアルキル基を示し、ａはそれぞれ独立して０〜４の整数を示し、ｂはそれぞれ独立して０〜３の整数を示す。］
２．下記式（１−１）〜（１−４）で示される化合物からなる群から選択される上記１に記載のジアミン化合物。

３．請求項１又は２に記載の一般式（１）で示されるジアミン化合物と、テトラカルボン酸二無水物を重縮合させて得られるポリアミック酸。
４．前記テトラカルボン酸二無水物が、下記一般式（２）で示される化合物である上記３に記載のポリアミック酸。

［式（２）中、Ｒ^５は、４価の脂肪族基、４価の脂環族基又は４価の芳香族基を示す。］
５．下記一般式（３）で示される構造を有するポリアミック酸。

［式（３）中、Ｒは４価の脂肪族基、４価の脂環族基又は４価の芳香族基を示し、Ｒ^１はそれぞれ独立して炭素数１〜３のアルキル基を示し、ａはそれぞれ独立して０〜４の整数を示し、ｂはそれぞれ独立して０〜３の整数を示し、ｍは１〜１０００００の数を示す。］
６．上記４又は５に記載のポリアミック酸をイミド化したイミド化重合体。
７．下記一般式（４）で示される構造を有するイミド化重合体。

［式（４）中、Ｒは４価の脂肪族基、４価の脂環族基又は４価の芳香族基を示し、Ｒ^１はそれぞれ独立して炭素数１〜３のアルキル基を示し、ａはそれぞれ独立して０〜４の整数を示し、ｂはそれぞれ独立して０〜３の整数を示し、ｍは１〜１０００００の数を示す。］ That is, the present invention provides the following novel diamine compound, and a novel polyamic acid and imidized polymer comprising it and tetracarboxylic dianhydride.
1. A diamine compound represented by the following general formula (1).

[In Formula (1), each R ¹ independently represents an alkyl group having 1 to 3 carbon atoms, a represents each independently an integer of 0 to 4, and b represents an integer of 0 to 3 independently. Indicates. ]
2. The diamine compound according to 1 above, selected from the group consisting of compounds represented by the following formulas (1-1) to (1-4).

3. A polyamic acid obtained by polycondensation of a diamine compound represented by the general formula (1) according to claim 1 or 2 and tetracarboxylic dianhydride.
4). 4. The polyamic acid according to 3 above, wherein the tetracarboxylic dianhydride is a compound represented by the following general formula (2).

[In the formula (2), R ⁵ represents a tetravalent aliphatic group, a tetravalent alicyclic group or a tetravalent aromatic group. ]
5. A polyamic acid having a structure represented by the following general formula (3).

[In the formula (3), R represents a tetravalent aliphatic group, a tetravalent alicyclic group or a tetravalent aromatic group, and each R ¹ independently represents an alkyl group having 1 to 3 carbon atoms. , A each independently represents an integer of 0-4, b independently represents an integer of 0-3, and m represents a number of 1-100,000. ]
6). 6. An imidized polymer obtained by imidizing the polyamic acid according to 4 or 5 above.
7). An imidized polymer having a structure represented by the following general formula (4).

[In the formula (4), R represents a tetravalent aliphatic group, a tetravalent alicyclic group or a tetravalent aromatic group, and each R ¹ independently represents an alkyl group having 1 to 3 carbon atoms. , A each independently represents an integer of 0-4, b independently represents an integer of 0-3, and m represents a number of 1-100,000. ]

By using the novel diamine compound of the present invention, it is possible to provide a polyamic acid and an imidized polymer having a high refractive index and excellent transparency and heat resistance.
The novel polyamic acid and imidized polymer of the present invention are particularly suitable for optical applications requiring high refractive index, excellent transparency and heat resistance.
In the present invention, by using a novel diamine compound into which a sulfur atom is introduced, a high refractive index material capable of achieving both a high refractive index and high heat resistance can be provided.
By combining a novel diamine compound and an aliphatic or alicyclic tetracarboxylic dianhydride, an imidized polymer excellent in high refractive index, high transparency, and high heat resistance can be obtained.

  Hereinafter, the novel diamine compound of the present invention, the polyamic acid produced using the diamine compound, and the imidized polymer will be specifically described.

上記一般式（１）中のＲ^１はそれぞれ独立して炭素数１〜３のアルキル基を示し、ａ及びｂはそれぞれ基Ｒ^１の置換数を示し、ａはそれぞれ独立して０〜４の整数を示し、ｂはそれぞれ独立して０〜３の整数を示す。ａ及びｂは０であることが好ましい。 I. Diamine Compound The diamine compound of the present invention is a compound having a thianthrene skeleton and having a structure represented by the following general formula (1). By having a thianslene skeleton, the polyamic acid and imidized polymer produced using the skeleton can have a high refractive index.

R ¹ in the general formula (1) independently represents an alkyl group having 1 to 3 carbon atoms, a and b each represents the number of substitutions of the group R ¹ , and a is independently 0 to 4 An integer is shown, b shows an integer of 0-3 each independently. a and b are preferably 0.

In order to increase the reactivity of the amine moiety and allow the condensation reaction with tetracarboxylic dianhydride to proceed efficiently, it is preferable to have sulfide bonds at the 2nd and 7th positions of the thianthrene ring. That is, it is preferably 2,7-bis (4-aminophenylenesulfanyl) thianthrene represented by the following formula (1-1).

The diamine compound of the present invention can be produced as follows.
Step 1: Production of thianthrene skeleton A method for producing a thianthrene skeleton is known and can be produced according to a known method. For example, as shown in the following reaction formula, a halogen-substituted thiophenol derivative is condensed in the presence of sulfuric acid (fuming sulfuric acid or concentrated sulfuric acid) to obtain a dihalogen-substituted thianthrene derivative.

Step 2: Production of diamine compound In an aprotic polar solvent, anhydrous potassium carbonate and a p-aminothiophenol derivative are reacted to synthesize a potassium salt of a p-aminothiophenol derivative. A diamine compound represented by the general formula (1) can be produced by adding the dihalogen-substituted thianthrene derivative produced in Step 1 above.

で示される構造を有するテトラカルボン酸二無水物との重縮合反応によって得られる下記一般式（３）で示される構造を有する重合体である。

II. Polyamic acid The polyamic acid of the present invention is a polymer obtained by polycondensation reaction of the diamine compound of the present invention and tetracarboxylic dianhydride, preferably the following general formula (2)

It is a polymer which has a structure shown by following General formula (3) obtained by polycondensation reaction with the tetracarboxylic dianhydride which has a structure shown by these.

R in the above general formulas (2) and (3) is a tetravalent aliphatic group, a tetravalent alicyclic group or a tetravalent group corresponding to the residue obtained by removing the anhydride group from tetracarboxylic dianhydride. An aromatic group of
R ¹ in the general formula (3) independently represents an alkyl group having 1 to 3 carbon atoms, a and b each represents the number of substitutions of the group R ¹ , and a is independently 0 to 4 An integer is shown, b shows an integer of 0-3 each independently. a and b are preferably 0.
M in the said General formula (3) shows the number of 1-100,000, and it is preferable that it is 100-100000.

  The tetracarboxylic dianhydride represented by the general formula (2) is selected from the group consisting of aliphatic, alicyclic or aromatic tetracarboxylic dianhydrides, and has excellent transparency required for optical applications. An aliphatic or alicyclic tetracarboxylic dianhydride is more preferable because a polymer having properties can be obtained.

Specific examples of the aliphatic or alicyclic tetracarboxylic dianhydride include, for example, butanetetracarboxylic dianhydride, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 1,2,3, 4-cyclopentanetetracarboxylic dianhydride, 4,10-dioxatricyclo [6.3.1.0 ^2,7 ] dodecane-3,5,9,11-tetraone, 1,2,4,5 -Cyclohexanetetracarboxylic dianhydride, 2,3,5-tricarboxycyclopentylacetic acid dihydrate, 3,5,6-tricarboxynorbornane-2-acetic acid dianhydride, 2,3,4,5-tetrahydrofuran Tetracarboxylic dianhydride, 1,3,3a, 4,5,9b-hexahydro-5-tetrahydro-2,5-dioxo-3-furanyl) -naphtho [1,2-c] -furan-1,3 -Geo 5- (2,5-dioxotetrahydrofural) -3-methyl-3-cyclohexene-1,2-dicarboxylic dianhydride, bicyclo [2,2,2] -oct-7-ene-2,3 And aliphatic and alicyclic tetracarboxylic dianhydrides such as 5,6-tetracarboxylic dianhydride. Among these, butanetetracarboxylic dianhydride, 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 4,10-dioxatricyclo [6.3.1.0 ^2,7 ] dodecane- 3,5,9,11-tetraone, 2,3,5-tricarboxycyclopentyl acetic acid dianhydride, 5- (2,5-dioxotetrahydrofural) -3-methyl-3-cyclohexene-1,2-dicarboxylic acid Acid dianhydride and 1,3,3a, 4,5,9b-hexahydro-5-tetrahydro-2,5-dioxo-3-furanyl) -naphtho [1,2-c] -furan-1,3-dione 1,2,3,4-cyclobutanetetracarboxylic dianhydride, 4,10-dioxatricyclo [6.3.1.0 ^2,7 ] dodecane-3,5,9,11-tetraone 1, 2, 4, 5-cyclohexanetetracarboxylic dianhydride is particularly preferred.

  Specific examples of the aromatic tetracarboxylic dianhydride include pyromellitic dianhydride, 3,3 ′, 4,4′-benzophenonetetracarboxylic dianhydride, 3,3 ′, 4,4′-biphenyl Sulfonetetracarboxylic dianhydride, 1,4,5,8-naphthalenetetracarboxylic dianhydride, 2,3,6,7-naphthalenetetracarboxylic dianhydride, 3,3 ′, 4,4′- Biphenyl ether tetracarboxylic dianhydride, 3,3 ′, 4,4′-dimethyldiphenylsilane tetracarboxylic dianhydride, 3,3 ′, 4,4′-tetraphenylsilane tetracarboxylic dianhydride, 1 , 2,3,4-furantetracarboxylic dianhydride, 4,4′-bis (3,4-dicarboxyphenoxy) diphenyl sulfide dianhydride, 4,4′-bis (3,4-dicarboxyphene) Xyl) diphenylsulfone dianhydride, 4,4′-bis (3,4-dicarboxyphenoxy) diphenylpropane dianhydride, 4,4 ′-(hexafluoroisopropylidene) bis (phthalic acid) dianhydride, 3 , 3 ′, 4,4′-biphenyltetracarboxylic dianhydride, bis (phthalic acid) phenylphosphine oxide dianhydride, p-phenylene-bis (triphenylphthalic acid) dianhydride, m-phenylene-bis ( Aromatic tetracarboxylic such as triphenylphthalic acid dianhydride, bis (triphenylphthalic acid) -4,4′-diphenyl ether dianhydride, bis (triphenylphthalic acid) -4,4′-diphenylmethane dianhydride Mention may be made of acid dianhydrides. Among these, pyromellitic dianhydride, 3,3 ′, 4,4′-benzophenone tetracarboxylic dianhydride, 3,3 ′, 4,4′-biphenylsulfone tetracarboxylic dianhydride, 4 4,4 '-(Hexafluoroisopropylidene) bis (phthalic acid) dianhydride and 3,3', 4,4'-biphenyltetracarboxylic dianhydride are preferred.

  In addition, since a polyamic acid having a higher refractive index can be obtained, it is also preferable to use a tetracarboxylic dianhydride containing a sulfur atom. Examples of sulfur atom-containing acid anhydrides include 4,4 '-[p-thiobis (phenylene-sulfanyl)] diphthalic anhydride.

  In addition, in manufacture of the polyamic acid of this invention, other diamine can also be used together in the range which does not impair the effect of this invention other than the diamine compound shown by the said General formula (1). Examples of such a diamine compound include p-phenylenediamine, m-phenylenediamine, 4,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylethane, 4,4′-diaminodiphenyl sulfide, 4,4′- Diaminodiphenyl sulfone, 4,4′-diaminodiphenyl ether, 1,5-diaminonaphthalene, 3,3-dimethyl-4,4′-diaminobiphenyl, 4,4′-diaminobenzanilide, 3,4′-diaminodiphenyl ether, 3,3′-diaminobenzophenone, 3,4′-diaminobenzophenone, 4,4′-diaminobenzophenone, 2,2-bis [4- (4-aminophenoxy) phenyl] propane, 2,2-bis [4- (4-Aminophenoxy) phenyl] hexafluoropropane, 2 2-bis (4-aminophenyl) hexafluoropropane, 2,2-bis [4- (4-aminophenoxy) phenyl] sulfone, 1,4-bis (4-aminophenoxy) benzene, 1,3-bis ( 4-aminophenoxy) benzene, 1,3-bis (3-aminophenoxy) benzene, 9,9-bis (4-aminophenyl) -10-hydroanthracene, 9,9-bis (4-aminophenyl) fluorene, 4,4′-methylene-bis (2-chloroaniline), 2,2 ′, 5,5′-tetrachloro-4,4′-diaminobiphenyl, 2,2′-dichloro-4,4′-diamino- 5,5′-dimethoxybiphenyl, 3,3′-dimethoxy-4,4′-diaminobiphenyl, 4,4 ′-(p-phenylenediisopropylidene) bisaniline, 4,4 - it can be exemplified (m-phenylene-isopropylidene) bisaniline.

In addition, aromatic diamines having hetero atoms such as diaminotetraphenylthiophene; 1,1-metaxylylenediamine, 1,3-propanediamine, tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, heptamethylenediamine, octamethylene Diamine, Nonamethylenediamine, 4,4-Diaminoheptamethylenediamine, 1,4-Diaminocyclohexane, Isophoronediamine, Tetrahydrodicyclopentadienylenediamine, Hexahydro-4,7-methanoindanylene methylenediamine, Tricyclo [6 , 2,1,0 ^2.7 ] -undecylenedimethyldiamine and the like can also include aliphatic or alicyclic diamines.

  Of the diamines used in the production of the polyamic acid of the present invention, the proportion of the diamine compound of the present invention represented by the general formula (1) is preferably 50 mol% or more, more preferably 80 mol% or more. In order to achieve a high refractive index, it is particularly preferably 100 mol%.

The polycondensation reaction between the diamine compound represented by the general formula (1) and the tetracarboxylic dianhydride can be carried out under known methods and conditions. For example, the following method is preferred.
The polyamic acid of the present invention can be obtained as a solution by stirring and mixing the diamine compound and the acid dianhydride in an aprotic organic solvent such as N-methyl-2-pyrrolidone. For example, a diamine compound may be dissolved in an organic solvent, and acid dianhydride may be added thereto and mixed with stirring. Alternatively, a mixture of a diamine compound and acid dianhydride may be added to an organic solvent and mixed with stirring. May be. The reaction is usually performed at a temperature of 100 ° C. or lower, preferably 80 ° C. or lower, under normal pressure. However, the reaction may be performed under pressure or under reduced pressure as necessary. The reaction time varies depending on the diamine compound and acid dianhydride used, the organic solvent, the reaction temperature, etc., but is usually in the range of 4 to 24 hours.

式（４）中、Ｒ、Ｒ^１、ａ、ｂ及びｍは、上記一般式（３）で説明した通りである。 III. Imidized polymer The imidized polymer of the present invention is obtained by imidizing the polyamic acid of the present invention, and preferably has a structure represented by the following general formula (4).

In the formula (4), R, R ¹ , a, b and m are as described in the general formula (3).

  The method and reaction conditions for imidizing the polyamic acid of the general formula (3) are not particularly limited, and known methods and reaction conditions can be used. For example, as a heating imidation method, a method of heating to 250 to 350 ° C. for 1 to 6 hours to convert to an imidized polymer, 100 ° C. for 1 hour, 200 ° C. for 1 hour, and further 300 ° C. for 1 hour And a method of heating in stages. Furthermore, a dehydrating cyclization reagent comprising a carboxylic acid anhydride and a tertiary amine can also be used as chemical imidization. Examples of the dehydrating cyclization reagent include acetic anhydride-pyridine, acetic anhydride-triethylamine, and trifluoroacetic anhydride.

  The polyamic acid of the present invention has a high refractive index, and the imidized polymer of the present invention obtained by imidizing this also has a high refractive index, excellent transparency and heat resistance, and has a high refractive index and transparency. And is useful as a material for producing articles that require heat resistance.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further more concretely, this invention is not limited at all by these Examples.

攪拌機、還流冷却器及び窒素導入管を備えた反応容器に、４，４’−チオビスベンゼンチオール（５．００ｇ、０．０２ｍｏｌ）と４−ブロモフタル酸無水物（１０．００ｇ、０．０４４ｍｏｌ）、無水炭酸カリウム（６．０８ｇ、０．０４４ｍｏｌ）、そしてＮ，Ｎ−ジメチルホルムアミド（ＤＭＦ）（１００ｍＬ）を加え、１２０℃で１２時間反応させた。反応液を室温に戻し、白色の固体を濾取し、１６０℃で２４時間減圧乾燥した。得られた白色の固体に蒸留水（１００ｍＬ）と濃塩酸（１００ｍＬ）を加え、３時間の間、加熱攪拌した。得られた白色の固体を濾取し、１８０〜１９０℃で３時間加熱し黄色の固体を得た。 Production Example 1
4,4 ′-[p-thiobis (phenylene-sulfanyl)] diphthalic anhydride

In a reaction vessel equipped with a stirrer, a reflux condenser and a nitrogen introduction tube, 4,4′-thiobisbenzenethiol (5.00 g, 0.02 mol) and 4-bromophthalic anhydride (10.00 g, 0.044 mol) , Anhydrous potassium carbonate (6.08 g, 0.044 mol), and N, N-dimethylformamide (DMF) (100 mL) were added and reacted at 120 ° C. for 12 hours. The reaction solution was returned to room temperature, and a white solid was collected by filtration and dried under reduced pressure at 160 ° C. for 24 hours. Distilled water (100 mL) and concentrated hydrochloric acid (100 mL) were added to the obtained white solid, and the mixture was heated and stirred for 3 hours. The obtained white solid was collected by filtration and heated at 180 to 190 ° C. for 3 hours to obtain a yellow solid.

Yield: 7.8g
Yield: 71.9%
Melting point: 175.2 ° C (DSC)
FT-IR (KBr, cm < ^-1 >): 1847.5, 1778.0, 1604.4, 1473.3, 1326.8, 1257.4, 902.5, 817.7, 732.0
¹ H-NMR (300 MHz, DMSO-d ₆ , ppm): 7.45-7.49 (d, 4H), 7.52 to 7.55 (d, 4H), 7.56 (s, 2H), 7.60-7.63 (d, 2H), 7.83-7.85 (d, 2H)
Calcd _{C 28 H 14 O 6 S 3} : C, 61.98%; H, 2.60%
Measured value C, 62.23%; H, 2.97%

攪拌機、還流冷却器及び窒素導入管を備えた反応容器に、ｐ−フルオロチオフェノール（９．６１３ｇ、７５ｍｍｏｌ）に発煙硫酸１０〜５０ｍＬを加え、４０〜８０℃で１２〜２４時間反応させた。反応液を冷水に注ぎ、析出物を濾取し水洗した。得られた黄色の個体はエタノールを用いて再結晶し精製した。
融点：１５６．２℃（ＤＳＣ）
ＦＴ−ＩＲ（ＫＢｒ、ｃｍ^−１）：１５９２．９、１４５４．１、１２５３．５、１２０７．２、８９４．８、８５６．２、８０２．２
^１Ｈ−ＮＭＲ（３００ＭＨｚ、ＤＭＳＯ−ｄ_６、ｐｐｍ）：６．９６−７．０３（ｍ、２Ｈ）、７．２２−７．２５（ｍ、２Ｈ）、７．４１−７．４５（ｍ、２Ｈ） Production Example 2
2,7-difluorothianthrene

10-50 mL of fuming sulfuric acid was added to p-fluorothiophenol (9.613 g, 75 mmol) in a reaction vessel equipped with a stirrer, a reflux condenser and a nitrogen inlet tube, and reacted at 40-80 ° C. for 12-24 hours. The reaction solution was poured into cold water, and the precipitate was collected by filtration and washed with water. The obtained yellow solid was recrystallized and purified using ethanol.
Melting point: 156.2 ° C. (DSC)
FT-IR (KBr, cm ⁻¹ ): 1592.9, 1454.1, 1253.5, 1207.2, 894.8, 856.2, 802.2
¹ H-NMR (300 MHz, DMSO-d ₆ , ppm): 6.96-7.03 (m, 2H), 7.22-7.25 (m, 2H), 7.41-7.45 (m 2H)

攪拌機、還流冷却器、Ｄｅａｎ−Ｓｔａｒｋトラップ及び窒素導入管を備えた反応容器に、ｐ−アミノチオフェノール（９．３８９ｇ、７５ｍｍｏｌ）と無水炭酸カリウム（５．３９ｇ、３９ｍｍｏｌ）、そしてＮ−メチル−２−ピロリドン（３０ｍＬ、以下、ＮＭＰ）とトルエン（５０ｍＬ）を加え、１４０〜１４５℃で４時間反応させた。Ｄｅａｎ−Ｓｔａｒｋトラップで水を除去し、トルエンも減圧留去した。反応液を１２０℃まで冷却し、製造例２で製造した２，７−ジフルオロチアンスレン（７．５６９ｇ、３０ｍｍｏｌ）とＮＭＰ（１５ｍＬ）を加えた。その後、反応液を１７０℃で１２時間反応させた。反応液を室温まで戻し、反応液を冷水（５００ｍＬ）に注ぎ、黄色の析出物を濾取し水洗した。得られた黄色の個体はエタノールを用いて再結晶し精製した。得られた化合物のＩＲチャート、^１Ｈ−ＮＭＲ及び^１３Ｃ−ＮＭＲチャートをそれぞれ図１〜図３に示す。 <Synthesis of diamine having thianthrene skeleton>
Example 1
Synthesis of 2,7-bis (4-aminophenylenesulfanyl) thianthrene

In a reaction vessel equipped with a stirrer, reflux condenser, Dean-Stark trap and nitrogen inlet tube, p-aminothiophenol (9.389 g, 75 mmol), anhydrous potassium carbonate (5.39 g, 39 mmol), and N-methyl- 2-pyrrolidone (30 mL, hereinafter referred to as NMP) and toluene (50 mL) were added and reacted at 140 to 145 ° C. for 4 hours. Water was removed with a Dean-Stark trap, and toluene was distilled off under reduced pressure. The reaction solution was cooled to 120 ° C., and 2,7-difluorothianthrene (7.569 g, 30 mmol) produced in Production Example 2 and NMP (15 mL) were added. Thereafter, the reaction solution was reacted at 170 ° C. for 12 hours. The reaction solution was returned to room temperature, poured into cold water (500 mL), the yellow precipitate was collected by filtration and washed with water. The obtained yellow solid was recrystallized and purified using ethanol. The IR chart, ¹ H-NMR and ¹³ C-NMR chart of the obtained compound are shown in FIGS.

Yield: 10.34 g
Yield: 74.5%
Melting point: 185.2 ° C (DSC)
FT-IR (KBr, cm ⁻¹ ): 3428.8, 3332.4, 2360.4, 1619.9, 1592.9, 1565.9, 1492.6, 1442.5, 1361.5, 1292.1 1176.4, 1103.1, 817.7
¹ H-NMR (300 MHz, DMSO-d ₆ , ppm): 5.49 (s, 4H), 6.61-6.64 (d, 4H), 6.94-6.98 (d, 4H), 7.06 (s, 2H), 7.14-7.17 (d, 4H), 7.36-7.38 (d, 2H)
¹³ C-NMR (300 MHz, DMSO-d ₆ , ppm): 151.2, 142.2, 137.5, 136.7, 131.0, 129.9, 126.2, 125.9, 115.8 , 114.3
Calcd _{C 24 H 18 N 2 S 4} : C, 62.31%; H, 3.92%; N, 6.05%
Measured value C, 62.22%; H, 3.96%; N, 6.01%

実施例１で用いたｐ−アミノチオフェノールの代わりに、ｏ−アミノチオフェノールを用いた他は、実施例１と同様の方法で合成を行い、２，７−ビス（２−アミノフェニレンスルファニル）チアンスレンを得た。
収量：４．４７ｇ
収率：３２．２％
ＦＴ−ＩＲ（ＫＢｒ、ｃｍ^−１）：３４２９．１、３３３２．７、２３６０．５、１６２０．０、１５９３．１、１５６６．２、１４９２．７、１４４２．３、１３６１．３、１２９１．１、１１７７．０、１１０３．３、７５２．２ Example 2
Synthesis of 2,7-bis (2-aminophenylenesulfanyl) thianthrene

The synthesis was performed in the same manner as in Example 1 except that o-aminothiophenol was used instead of p-aminothiophenol used in Example 1, and 2,7-bis (2-aminophenylenesulfanyl) was synthesized. Obtained thienslen.
Yield: 4.47g
Yield: 32.2%
FT-IR (KBr, cm ⁻¹ ): 3429.1, 3332.7, 2360.5, 1620.0, 1593.1, 1566.2, 1492.7, 1442.3, 1361.3, 1291.1 1177.0, 1103.3, 752.2

実施例１で用いたｐ−アミノチオフェノールの代わりに、ｍ−アミノチオフェノールを用いた他は、実施例１と同様の方法で合成を行い、２，７−ビス（３−アミノフェニレンスルファニル）チアンスレンを得た。
収量：７．８７ｇ
収率：５６．７％
ＦＴ−ＩＲ（ＫＢｒ、ｃｍ^−１）：３４３０．２、３３３２．４、２３６０．４、１６１９．８、１５９３．３、１５６７．２、１４９３．０、１４４２．４、１３６２．０、１２９１．７、１１７７．４、１１０４．１、８１０．５ Example 3
Synthesis of 2,7-bis (3-aminophenylenesulfanyl) thianthrene

Synthesis was performed in the same manner as in Example 1 except that m-aminothiophenol was used instead of p-aminothiophenol used in Example 1, and 2,7-bis (3-aminophenylenesulfanyl) was synthesized. Obtained thienslen.
Yield: 7.87g
Yield: 56.7%
FT-IR (KBr, cm ⁻¹ ): 3430.2, 3332.4, 2360.4, 1619.8, 1593.3, 1567.2, 1493.0, 1442.4, 1362.0, 1291.7 1177.4, 1104.1, 810.5

実施例１で用いた２，７−ジフルオロチアンスレンの代わりに、３，６−ジフルオロチアンスレンを用いた他は、実施例１と同様の方法で合成を行い、２，７−ビス（３−アミノフェニレンスルファニル）チアンスレンを得た。
収量：８．４８ｇ
収率：６１．１％
ＦＴ−ＩＲ（ＫＢｒ、ｃｍ^−１）：３４３０．１、３３３２．３、２３６１．３、１６１９．９、１５９３．３、１５６７．２、１５２０．０、１４６０．４、１３６１．０、１２９２．６、１１７６．３、１１０３．１、８１７．６ Example 4
Synthesis of 3,6-bis (4-aminophenylenesulfanyl) thianthrene

Synthesis was performed in the same manner as in Example 1 except that 3,6-difluorothianthrene was used instead of 2,7-difluorothianthrene used in Example 1, and 2,7-bis (3- Aminophenylenesulfanyl) thianthrene was obtained.
Yield: 8.48g
Yield: 61.1%
FT-IR (KBr, cm ⁻¹ ): 3430.1, 3332.3, 2361.3, 1619.9, 1593.3, 1567.2, 1520.0, 1460.4, 1361.0, 1292.6 1176.3, 1103.1, 817.6

<Production of polyamic acid>
Example 5
In a reaction vessel equipped with a nitrogen introduction tube, 2,7-bis (4-aminophenylenesulfanyl) thianthrene (18.51 g, 40 mmol) (hereinafter referred to as APTT) and N-methyl-2-pyrrolidone (80 g) (hereinafter referred to as “APTT”). NMP) was added and stirred at room temperature until completely dissolved. Next, 1,2,3,4-cyclobutanetetracarboxylic dianhydride (7.84 g, 40 mmol) (hereinafter referred to as CBDA) and NMP (25 g) were added, and the mixture was stirred at room temperature for 24 hours. NMP solution A was obtained. An IR chart of the obtained polyamic acid is shown in FIG.

Examples 6-10
Polymerization was carried out in the same manner as in Example 5 except that acid anhydrides shown in Table 1 below were used instead of CBDA used in Example 5 to obtain NMP solutions of each polyamic acid.

Comparative Example 1
To a reaction vessel equipped with a nitrogen introduction tube, N-methyl-2-pyrrolidone (80 g) (NMP) was added to bis (p-aminophenyl) ether (8.01 g, 40 mmol) (hereinafter referred to as ODA) at room temperature. Stir to dissolve completely. Next, CBDA (7.84 g, 40 mmol) and NMP (25 g) were added and stirred at room temperature for 24 hours to obtain an NMP solution of polyamic acid.

<Creation of membrane>
An NMP solution of polyamic acid produced in Examples and Comparative Examples was dispensed on a 3 inch diameter 3 mm thick fused quartz substrate, spin coated to a thickness of about 8-12 μm, and applied at 280 ° C. in a nitrogen atmosphere. The film was obtained by heating for 1.5 hours.
An IR chart of the imidized polymer in the obtained film of Example 5 is shown in FIG. Moreover, the IR chart of the imidized polymer (PI-7 to PI-10) in the films of Examples 7 to 10 is shown in FIG.

<Evaluation of film properties>
The following characteristics were evaluated for the films obtained above. The results are shown in Table 1.

(1) Refractive Index Using a Metricon PC-2000 type prism coupler, the refractive index at a wavelength of 633 nm of the film obtained above was measured.

(2) Transmittance Using a U-3500 self-recording spectrophotometer manufactured by Hitachi, Ltd., transmittance (%) at wavelengths of 400 nm and 450 nm per 1 μm thickness of the film obtained above was measured.

(3) Heat resistance Using a DSC6300 manufactured by Seiko Instruments Inc. (temperature increase rate: 10 ° C./min, under nitrogen stream), the 5% weight reduction temperature of the film obtained above was measured. The case where the 5% weight loss temperature was 400 ° C. or higher was evaluated as heat resistance pass (◯).

Abbreviations in Table 1 represent the following.
APTT: 2,7-bis (4-aminophenylenesulfanyl) thianthrene; prepared in Example 1 ODA: bis (p-aminophenyl) ether 3SDEA: 4,4 ′-[p-thiobis (phenylene-sulfanyl)] diphthalic acid Anhydride; produced in Production Example 1 CBDA: 1,2,3,4-cyclobutanetetracarboxylic dianhydride CHDA: 1,2,4,5-cyclohexanetetracarboxylic dianhydride sBPDA: 3,3 ′, 4 , 4′-biphenyltetracarboxylic dianhydride aBPDA: 2,3 ′, 3,4′-biphenyltetracarboxylic dianhydride ODPA: 4,4′-oxydiphthalic dianhydride

  From the results in Table 1, it is understood that the polyamic acid and imidized polymer made from the diamine compound represented by the general formula (1) have a high refractive index, excellent transparency, and excellent heat resistance. .

The diamine compound of the present invention is useful as a raw material for producing an imidized polymer having a high refractive index and excellent transparency and heat resistance.
The polyamic acid and imidized polymer of the present invention are suitable as materials for producing optical members that are required to have a high refractive index and excellent transparency and heat resistance at the same time. Specifically, examples of the optical member include a coating material of a high refractive index material and a high refractive index material of an antireflection film, an optical waveguide, various lenses, and a sensitivity improving material for an image sensor.

2 is an IR chart of the diamine compound obtained in Example 1. 1 is a ¹ H-NMR chart of a diamine compound obtained in Example 1. 2 is a ¹³ C-NMR chart of a diamine compound obtained in Example 1. FIG. 6 is an IR chart of the polyamic acid obtained in Example 5. 3 is IR data of an imidized polymer obtained in Example 5. FIG. 6 is an IR chart of the polyamic acid obtained in Example 6. 3 is IR data of an imidized polymer obtained in Example 6. 4 is an IR chart of the polyamic acid obtained in Example 7. 6 is an IR chart of the polyamic acid obtained in Example 8. 6 is an IR chart of the polyamic acid obtained in Example 9. 4 is an IR chart of the polyamic acid obtained in Example 10. It is IR chart of each imidized polymer (PI-7-PI-10) obtained in Examples 7-10.

Claims (7)

A diamine compound represented by the following general formula (1).

[In Formula (1), each R ¹ independently represents an alkyl group having 1 to 3 carbon atoms, a represents each independently an integer of 0 to 4, and b represents an integer of 0 to 3 independently. Indicates. ] The diamine compound according to claim 1, which is selected from the group consisting of compounds represented by the following formulas (1-1) to (1-4).

  A polyamic acid obtained by polycondensation of a diamine compound represented by the general formula (1) according to claim 1 or 2 and tetracarboxylic dianhydride. The polyamic acid according to claim 3, wherein the tetracarboxylic dianhydride is a compound represented by the following general formula (2).

[In Formula (2), R shows a tetravalent aliphatic group, a tetravalent alicyclic group, or a tetravalent aromatic group. ] A polyamic acid having a structure represented by the following general formula (3).

[In the formula (3), R represents a tetravalent aliphatic group, a tetravalent alicyclic group or a tetravalent aromatic group, and each R ¹ independently represents an alkyl group having 1 to 3 carbon atoms. , A each independently represents an integer of 0-4, b independently represents an integer of 0-3, and m represents a number of 1-100,000. ]   An imidized polymer obtained by imidizing the polyamic acid according to claim 4. An imidized polymer having a structure represented by the following general formula (4).

[In the formula (4), R represents a tetravalent aliphatic group, a tetravalent alicyclic group or a tetravalent aromatic group, and each R ¹ independently represents an alkyl group having 1 to 3 carbon atoms. , A each independently represents an integer of 0-4, b independently represents an integer of 0-3, and m represents a number of 1-100,000. ]

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