JP5096832B2 - Magnetic recording medium - Google Patents

Description

  The present invention relates to a magnetic recording medium provided with at least one or more magnetic layers in which ferromagnetic fine powder and a binder are dispersed on a nonmagnetic support.

  Ferromagnetic powders such as γ-iron oxide, Co-containing iron oxide, chromium oxide, and ferromagnetic metal powder are used as tape-like magnetic recording media for audio, video, and computers, and disk-like magnetic recording media such as flexible disks. A magnetic recording medium in which a magnetic layer dispersed in a binder is provided on a support is used. In general, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), or the like is used as the support used in the magnetic recording medium. Since these supports are stretched and highly crystallized, they have high mechanical strength and excellent solvent resistance.

  The magnetic layer obtained by applying a coating solution in which ferromagnetic powder is dispersed in a binder to a support has a high degree of filling with high ferromagnetic powder, small elongation at break, and is brittle. And may be peeled off from the support. Therefore, an undercoat layer is provided on the support and the magnetic layer is strongly bonded onto the support.

  Further, it has been proposed to improve the smoothness of the magnetic layer or improve the coating film strength by including an inorganic filler in the undercoat layer (see Patent Documents 1 to 4). However, the magnetic recording media disclosed in Patent Documents 1 to 4 have a problem that sufficient electromagnetic conversion characteristics, smoothness and strength cannot be obtained.

JP 2004-5890 A Japanese Patent Application Laid-Open No. 2004-272941 JP 2004-303328 A Japanese Patent Laid-Open No. 1-213829

  The problem to be solved by the present invention is to provide a magnetic recording medium excellent in coating film smoothness, electromagnetic conversion characteristics, surface abnormality suppression effect, and humidity expansion coefficient suppression.

The problem to be solved by the present invention has been solved by the following means <1>. It is described below together with <2> and <3> which are preferred embodiments.
<1> On a nonmagnetic support, a radiation-cured layer obtained by curing a layer containing a radiation-curable compound and an inorganic powder by radiation irradiation, and a magnetic layer in which a ferromagnetic powder is dispersed in a binder, In order, the inorganic powder has an average particle diameter of 5 nm to 50 nm, the inorganic powder is surface-treated with two or more types of silane coupling agents, and the two or more types of silane coupling agents Among them, at least one includes a (meth) acryloyl group, and the content of the inorganic powder in the radiation-cured layer is 30% by volume to 60% by volume,
<2> The magnetic recording medium according to claim 1, wherein the silane coupling agent is represented by the formula (1):
(X) _4-n- Si- (Y) _n (1)
Here, X is an alkyl group having 4 to 18 carbon atoms, a phenyl group, an acryloxy group, or a (meth) acryloxyalkyl group having 4 to 22 carbon atoms, and Y is OCH ₃ , OC ₂ H ₅ or OC. ₃ H ₇ and n is 2 or 3.
<3> The magnetic recording medium according to claim 1, further comprising a nonmagnetic layer in which a nonmagnetic powder is dispersed in a binder between the radiation-cured layer and the magnetic layer.

  According to the present invention, it is possible to provide a magnetic recording medium excellent in coating film smoothness, electromagnetic conversion characteristics, surface abnormality suppression effect, and humidity expansion coefficient suppression.

The magnetic recording medium of the present invention comprises a radiation-cured layer obtained by curing a layer containing a radiation-curable compound and an inorganic powder on a nonmagnetic support, and a magnetic material in which a ferromagnetic powder is dispersed in a binder. Layers in this order, the inorganic powder has an average particle diameter of 5 nm to 50 nm, the inorganic powder is surface-treated with two or more types of silane coupling agents, Among the silane coupling agents, at least one contains a (meth) acryloyl group, and the content of the inorganic powder in the radiation-cured layer is 30% by volume to 60% by volume. .
Hereinafter, the present invention will be described in detail.

The magnetic recording medium of the present invention has a radiation-cured layer irradiated with a radiation-curable compound on a nonmagnetic support.
Since radiation curable compounds are generally low molecular weight monomers and oligomers and have low viscosity and easy coating leveling, excellent smoothness can be obtained. However, such a radiation-cured layer is low in strength, the protrusion on the back of the tape creates a dent on the tape surface, and the humidity expansion is large. Especially in computer magnetic recording media, the dimensions change in the storage environment. An error may occur.
The magnetic recording medium of the present invention contains an inorganic powder in the radiation-cured layer, and has the effect of suppressing the above-described temperature expansion. Moreover, the layer which has high intensity | strength and low temperature-humidity expansion can be obtained by including the inorganic powder surface-coated with the silane coupling agent in the radiation hardening layer.

When the surface-coated inorganic powder has a highly hydrophobic alkyl chain, the hydrophobicity of the inorganic powder increases. Therefore, when a radiation curable compound having a lower hydrophobicity than the inorganic powder is used, the compatibility between the inorganic powder and the radiation curable compound is reduced, and when the radiation cured layer is formed, such as May cause surface abnormalities.
The magnetic recording medium of the present invention has an inorganic powder surface treated with a silane coupling agent having an acryloyl group that binds to a radiation curable compound at the time of curing together with a silane coupling agent having a highly hydrophobic alkyl chain in the radiation-cured layer. By coating, even when a radiation curable compound having a lower hydrophobicity than that of the inorganic powder is used, the surface abnormality is suppressed and there is an effect of achieving both suppression of temperature and humidity expansion and smoothness.

I. Radiation-cured layer In the present invention, the radiation-cured layer is a layer obtained by curing a radiation-curable compound-containing layer by radiation irradiation, and contains an inorganic powder surface-treated with a silane coupling agent.

1. Radiation curable compound In the present invention, the radiation curable compound contained in the radiation curable layer refers to a compound having a property of being polymerized or crosslinked and polymerized and cured when irradiated with radiation such as ultraviolet rays or electron beams. The reaction of the radiation curable compound does not proceed unless energy (ultraviolet ray or electron beam) is applied from the outside. For this reason, the coating liquid containing the radiation curable compound has a stable viscosity unless irradiated with ultraviolet rays or electron beams, and can obtain high coating smoothness. In addition, since the reaction proceeds instantaneously by irradiation with high energy radiation such as ultraviolet rays or electron beams, a high coating strength can be obtained with a coating solution containing a radiation curable compound.
The radiation used in the present invention includes various types of radiation such as electron beams (β rays), ultraviolet rays, X rays, γ rays, and α rays.

As the radiation curable compound, for example, a (meth) acrylate compound ((meth) acrylic ester obtained by reacting a polyhydric alcohol with a carboxylic acid represented by acrylic acid or methacrylic acid and a compound having a radiation curable functional group. And urethane acrylate obtained by reacting a polyhydric alcohol with a compound having a radiation-curable functional group and a group that reacts with a hydroxyl group represented by 2-isocyanatoethyl acrylate or 2-isocyanatoethyl methacrylate.
In addition, those obtained by reacting a diisocyanate compound or a terminal isocyanate prepolymer with a compound having a radiation curable functional group and a group that reacts with an isocyanate group represented by hydroxyethyl (meth) acrylate or hydroxybutyl (meth) acrylate. It can be illustrated.
Here, “(meth) acrylate” is a general term for acrylate and methacrylate. “(Meth) acrylic acid” is a general term for acrylic acid and methacrylic acid. same as below.

  As said polyhydric alcohol, polyester polyol, polyether polyol, polycarbonate polyol, polyolefin polyol, polyether ester polyol other than the diol used as a conventionally well-known polyurethane raw material can be used. As the diisocyanate compound, those known as polyurethane raw materials can be used.

Examples of polyfunctional (meth) acrylic acid esters include trimethylolpropane tri (meth) acrylate, trimethylolethane tri (meth) acrylate, ditrimethylolpropane tetra (meth) acrylate, glycerin tri (meta) ) Acrylate, pentaerythritol tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol tetra (meth) acrylate dipropionate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate and its Examples include ethylene oxide and propylene oxide modified products.
As bifunctional ones, 1,3-butanediol di (meth) acrylate, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, diethylene glycol di (meth) acrylate, Examples include polyethylene glycol di (meth) acrylate, neopentyl glycol dimethacrylate, and cyclopentadienyl alcohol di (meth) acrylate.
Among these, a preferable radiation curable compound is a bifunctional to hexafunctional monomer, and a radiation curable compound having an acryloyl group or a methacryloyl group is preferable. Moreover, as a functional group, since it is excellent in polymerizability, an acryloyl group is preferable to a methacryloyl group.

Moreover, since the structure of the radiation curable compound is excellent in the balance between mechanical strength and hygroscopicity of the obtained magnetic recording medium, aliphatic and alicyclic diacrylates are preferable.
Preferred examples of the aliphatic group include hexamethylenediol diacrylate (hexanediol diacrylate), 2-ethyl-2-butyl-1,3-propanediol diacrylate, 3-methylpentanediol diacrylate, and 2-methyloctanediol. Examples include diacrylate, nonanediol diacrylate, hydroxypivalic acid neopentyl glycol diacrylate, and urethane diacrylate of trimethylhexamethylene diisocyanate.

  Moreover, as a preferable example of an alicyclic system, cyclohexane dimethanol diacrylate, limonene alcohol diacrylate, tricyclodecane dimethanol diacrylate, dimer diol diacrylate, 5-ethyl-2- (2-hydroxy-1,1) '-Dimethylethyl) -5- (hydroxymethyl) -1,3-dioxane diacrylate, tetrahydrofuran dimethanol diacrylate, 3,9-bis (1,1-dimethyl-2-hydroxyethyl) 2,4,8, Examples include 10-tetraoxaspiro [5,5] -undecanediacrylate. Among these, 5-ethyl-2- (2-hydroxy-1,1'-dimethylethyl) -5- (hydroxymethyl) -1,3-dioxane diacrylate is preferable.

  Examples of (meth) acrylates other than the above polyfunctional esters include epoxy (meth) acrylate, polysiloxane poly (meth) acrylate, polyamide poly (meth) acrylate, polyether (meth) acrylate, urethane (meth) acrylate, and the like. Although not, urethane (meth) acrylate is preferable.

  The radiation curable compound used in the present invention is preferably EBECRYL4858 (manufactured by Daicel Cytec Co., Ltd.), R604 (manufactured by Nippon Kayaku Co., Ltd.) and D310 (manufactured by Nippon Kayaku Co., Ltd.). More preferably, it is EBECRYL4858.

  In the present invention, known radiation curable compounds described in “applied technology of low-energy electron beam irradiation (issued by CMC)”, “UV / EB curing technology (issued by General Technology Center Co., Ltd.)”, etc. A radiation curable compound such as a (meth) acrylate compound may be used.

  In addition, a monofunctional (meth) acrylate may be added in an inferior amount as necessary for reasons such as viscosity adjustment and improvement in adhesion to the substrate. As such monofunctional (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxybutyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 2-hydroxypentyl (Meth) acrylate, 4-hydroxypentyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, ethoxyethyl (meth) acrylate, N-hydroxymethyl (meth) acrylamide, N-methoxymethyl (meth) acrylamide and the like can be mentioned. . The use amount of these monofunctional (meth) acrylates is preferably 0% by weight to 40% by weight of the entire radiation curable compound, and more preferably 0% by weight to 30% by weight in consideration of scratch resistance and the like.

  The molecular weight of the radiation curable compound used in the present invention is preferably 200 to 1,000. It is preferable for the molecular weight to be in the above-mentioned range since an unreacted product does not precipitate on the surface of the coating film, a good viscosity can be obtained, and sufficient smoothness can be obtained.

In the present invention, the viscosity of the radiation curable compound is preferably 1,000 mPa · s to 50,000 mPa · s. More preferably, it is 1,000 mPa * s-20,000 mPa * s, More preferably, it is 1,000 mPa * s-10,000 mPa * s. It is preferable that the viscosity of the radiation curable compound is in the above range since a magnetic recording medium having excellent smoothness can be obtained.
Moreover, it is preferable that a radiation hardening layer hardens the radiation-curable compound and the surface-treated inorganic powder, without using a binder.

2. Inorganic powder The magnetic recording medium of the present invention comprises an inorganic powder whose surface is treated with two or more silane coupling agents. The inorganic powder has an average particle diameter of 5 nm to 50 nm and is surface-treated with two or more types of silane coupling agents. At least one of the two or more types of silane coupling agents is (meta ) It contains an acryloyl group.
Here, the inorganic powder is not particularly limited, and a known inorganic powder can be appropriately selected and used. For example, a metal oxide, a metal carbonate, a metal sulfate, a metal nitride, a metal carbide, It can be selected from inorganic compounds such as metal sulfides.

  Specific examples of the material of the inorganic powder include α-alumina, β-alumina, γ-alumina, θ-alumina, silicon dioxide, silicon carbide, chromium oxide, cerium oxide, and α-oxidation with an α conversion rate of 90% or more. Iron, goethite, corundum, silicon nitride, titanium carbide, titanium dioxide, tin oxide, magnesium oxide, tungsten oxide, zirconium oxide, boron nitride, zinc oxide, calcium carbonate, calcium sulfate, barium sulfate, molybdenum disulfide, etc. alone or Used in combination. Among these, silicon dioxide, α-iron oxide, and titanium dioxide are preferable, and silicon dioxide is particularly preferable because of its particle size, small particle size distribution, and many means for imparting functions. Cyclohexanone, MEK (methyl ethyl ketone), toluene Colloidal silica dispersed in isopropyl alcohol, MIBK (methyl isobutyl ketone) or the like is most preferable.

The average particle diameter (primary particle diameter) of the inorganic powder surface-treated with the silane coupling agent is 5 nm to 50 nm. It is more preferably 5 nm to 25 nm, and further preferably 5 nm to 20 nm. It is preferable for the average particle diameter to be in the above range since a magnetic recording medium having excellent smoothness can be obtained.
The shape of the inorganic powder subjected to the surface treatment with the silane coupling agent is not particularly limited, and those having a needle shape, an elliptical shape, a spherical shape, a laminated shape, and the like can be used. In addition, it is preferable to appropriately select the average particle size of the inorganic powder so that the average particle size of the treated inorganic powder is within the above range. In addition, since the particle size of the inorganic powder hardly changes even by the surface treatment with the silane coupling agent, the average particle size of the inorganic powder after the treatment approximates the particle size of the inorganic powder before the surface treatment. it can.

3. Silane Coupling Agent for Surface Treatment of Inorganic Powder In the magnetic recording medium of the present invention, the radiation-cured layer is an inorganic material in which at least one silane coupling agent is surface-treated with two or more silane coupling agents having an acryloyl group. Contains powder.
The inorganic powder used in the present invention is surface-treated by dehydrating or dealcoholizing the OH group on the surface of the inorganic powder and the silane coupling agent represented by the formula (1).

Can be used in the present invention (meth) acryloyl group (-COCH = CH ₂ or _{-COC (CH 3) = CH 2} ) a silane coupling agent having at least one on the silicon atom of (meth) acryloyl groups It is preferable that it is a silane coupling agent. Moreover, it is preferable that the silane coupling agent which has a (meth) acryloyl group is a silane coupling agent which has a (meth) acryloxy group.
Specific examples of the silane coupling agent having a (meth) acryloxy group that can be used in the present invention include (meth) acryloxytrimethoxysilane, (meth) acryloxypropyltrimethoxysilane, and (meth) acryloxyoctyl. Trimethoxysilane can be preferably exemplified, and acryloxypropyltrimethoxysilane and acryloxyoctyltrimethoxysilane can be more preferably exemplified.

Specific examples of the silane coupling agent other than the silane coupling agent having a (meth) acryloyl group that can be used in the present invention include methyltrimethoxysilane, dimethyldimethoxysilane, trimethylmethoxysilane, methyltriethoxysilane, Dimethyldiethoxysilane, hexyltrimethoxysilane, hexyltriethoxysilane, hexyltripropoxysilane, decyltrimethoxysilane, dodecyltrimethoxysilane, myristyltrimethoxysilane, octyltrimethoxysilane, stearyltrimethoxysilane, phenyltrimethoxysilane, Benzyltrimethoxysilane, propyltrimethoxysilane, aminopropyltrimethoxysilane, vinyltrimethoxylane, vinyltriethoxysilane, styryltrimeth Shishiran, glycidoxypropyltrimethoxysilane, aminopropyltrimethoxysilane, mercaptopropyltrimethoxysilane, isocyanate propyl trimethoxysilane, ureidopropyltrimethoxysilane, isocyanate propyl trimethoxysilane and the like can be preferably exemplified.
The silane coupling agent that can be used in the present invention is more preferably a trimethoxy silane coupling agent. Moreover, it is preferable that the silane coupling agent which has a (meth) acryloyl group which can be used for this invention is a silane coupling agent which has an acryloyl group.

Moreover, it is preferable that the silane coupling agent which can be used for this invention is a compound represented by the following formula | equation (1).
(X) _4-n- Si- (Y) _n (1)
Here, X is an alkyl group having 4 to 22 carbon atoms, a phenyl group, a (meth) acryloxy group, or a (meth) acryloxyalkyl group having 4 to 22 carbon atoms, and Y is OCH ₃ , OC ₂ H ₅ or OC. ₃ H ₇ and n is 2 or 3.
X in Formula (1) is preferably an alkyl group having 4 to 22 carbon atoms, a phenyl group, a (meth) acryloxy group, or a (meth) acryloxyalkyl group having 4 to 22 carbon atoms, and has 6 to 18 carbon atoms. It is more preferable that they are an alkyl group, a phenyl group, a (meth) acryloxy group, or a (meth) acryloxyalkyl group having 5 to 10 carbon atoms.
Y in formula (1) is more preferably OCH ₃ or OC ₂ H ₅ , and more preferably OCH ₃ .
N in the formula (1) is preferably 3.
Of the silane coupling agents represented by the formula (1), trimethoxysilanes are preferred because of the ease of dehydration or dealcohol condensation in the surface treatment process. Examples of the silane coupling agents include hexyltrimethoxysilane and decyl. Trimethoxysilane, dodecyltrimethoxysilane, myristyltrimethoxysilane, octyltrimethoxysilane, stearyltrimethoxysilane, phenyltrimethoxysilane, acryloxypropyltrimethoxysilane and acryloxyoctyltrimethoxysilane are particularly preferred.

The surface treatment of the inorganic powder with the silane coupling agent is preferably performed in a solution. A solution in which a silane coupling agent is dissolved and a solution containing inorganic powder or inorganic powder (preferably a dispersion of inorganic powder) are mixed, and ultrasonic, stirrer, homogenizer, dissolver, planetary mixer, paint shaker It is preferable to carry out the treatment while stirring and dispersing using a sand grinder or a kneader.
As the solvent for dissolving the silane coupling agent, an organic solvent having a large polarity is preferable. Specific examples include known solvents such as alcohols, ketones and esters, with alcohols and ketones being preferred. These may be used alone or in combination with a plurality of organic solvents.
The silane coupling agent is preferably added in an amount of 10 to 40 parts by weight, more preferably 15 to 30 parts by weight, based on 100 parts by weight of the inorganic powder. When the amount of the silane coupling agent is within the above range, the surface treatment is favorably performed, which is preferable.

A radiation hardening layer contains 30 volume%-60 volume% of inorganic powder surface-treated with the silane coupling agent. More preferably, it is 40 volume%-50 volume%.
Although radiation shrinkage causes several percent volume shrinkage (curing shrinkage) of the radiation curable compound, the above volume percent can be estimated from the volume from which the solvent and the like are removed in the radiation cured layer before curing.
The content of the inorganic powder after treatment in the radiation-cured layer can be calculated by performing SEM observation of the radiation-cured layer at 50,000 times after FIB (focused ion beam) cutting of the cross section of the magnetic recording medium. .

The inorganic powder surface-treated with a silane coupling agent is preferably an organic solvent-dispersed silica sol treated with a silane coupling agent. Here, the organic solvent-dispersed silica sol is obtained by dispersing anhydrous silicic acid (anhydrous silicon dioxide) in an organic solvent.
Examples of the organic solvent that is the dispersion medium include cyclohexanone, MEK, toluene, isopropyl alcohol, and MIBK. Among these, cyclohexanone is preferable. The inorganic powder surface-treated with a silane coupling agent is preferably an organic solvent-dispersed silica sol because good dispersibility can be obtained.

4). Radiation irradiation As the radiation used in the present invention, an electron beam or ultraviolet rays can be used. When ultraviolet rays are used, it is necessary to add a photopolymerization initiator to the above compound. In the case of electron beam curing, a polymerization initiator is unnecessary, and the penetration depth is also deep, which is preferable.

  As the electron beam accelerator, a scanning system, a double scanning system, or a curtain beam system can be adopted, but a curtain beam system that can obtain a large output at a relatively low cost is preferable. As the electron beam characteristics, the acceleration voltage is preferably 30 kV to 1,000 kV, more preferably 50 kV to 300 kV, and the absorbed dose is preferably 0.5 Mrad (5 kGy) to 20 Mrad (200 kGy), more preferably 1 Mrad. It is (10 kGy) or more and 10 Mrad (100 kGy) or less. An acceleration voltage of 30 kV or more is preferable because a sufficient amount of energy transmission can be obtained. Moreover, it is preferable that it is 1,000 kV or less because energy efficiency used for polymerization is good and economical.

It is preferable that the atmosphere in which the electron beam is irradiated has an oxygen concentration of 200 ppm or less by nitrogen purge. It is preferable for the oxygen concentration to be 200 ppm or less because crosslinking in the vicinity of the surface and inhibition of the curing reaction do not occur.
A mercury lamp is suitably used as the ultraviolet light source. The mercury lamp is preferably used at a speed of 0.3 m / min to 20 m / min using a lamp of 20 W / cm to 240 W / cm or less. In general, the distance between the substrate and the mercury lamp is preferably 1 cm to 30 cm.

  A radical photopolymerization initiator is used as a photopolymerization initiator used for ultraviolet curing. For details, for example, those described in “New Polymer Experimental Science Vol. 2 Chapter 6 Light / Radiation Polymerization” (published by Kyoritsu Shuppan 1995, edited by Polymer Society) can be used. Examples of photo radical polymerization initiators include aromatic ketones. Specific examples include acetophenone, benzophenone, anthraquinone, benzoin ethyl ether, benzyl methyl ketal, benzyl ethyl ketal, benzoin isobutyl ketone, hydroxydimethylphenyl ketone, 1-hydroxycyclohexyl. Examples include phenyl ketone and 2,2-diethoxyacetophenone. The mixing ratio of the radical photopolymerization initiator is preferably 0.5 to 20 parts by weight, more preferably 2 to 15 parts by weight, and even more preferably 3 parts by weight with respect to 100 parts by weight of the radiation curable compound. Parts to 10 parts by weight. It is preferable that the mixing ratio of the photopolymerization initiator is within the above range because good curability can be obtained.

  Radiation curing equipment and conditions are described in “UV / EB Curing Technology” (published by General Technology Center Co., Ltd.) and “Applied Technology for Low Energy Electron Beam Irradiation” (2000, issued by CMC Co., Ltd.). The well-known thing can be used.

5. Carbon black In the present invention, it is also preferable to add carbon black to the radiation-cured layer.
The addition of carbon black is preferable because the surface electrical resistance Rs, which is a known effect, can be lowered, the light transmittance can be reduced, and a desired micro Vickers hardness can be obtained. On the other hand, it is also a preferred embodiment that no carbon black is added.

As the type of carbon black, furnace for rubber, thermal for rubber, black for color, acetylene black and the like can be used. The carbon black of the radiation-cured layer should be optimized for the following characteristics depending on the desired effect, and the effect may be obtained more when used in combination.
The specific surface area of carbon black is preferably 100 m ² / g or more and 500 m ² / g or less, more preferably 150 m ² / g or more and 400 m ² / g or less. Dibutyl phthalate (DBP) oil absorption is preferably 20 ml / 100 g or more and 400 ml / 100 g or less, more preferably 30 ml / 100 g or more and 200 ml / 100 g or less. The particle size of carbon black is preferably 5 nm or more and 80 nm or less, more preferably 10 nm or more and 50 nm or less, and further preferably 10 nm or more and 40 nm or less. The pH of the carbon black is preferably 2 or more and 10 or less, the water content is preferably 0.1% or more and 10% or less, and the tap density is preferably 0.1 g / ml or more and 1 g / ml or less. .

Specific examples of carbon black used in the present invention include BLACKPEARLS 2000, 1300, 1000, 900, 800, 880, 700, VULCAN XC-72, manufactured by Cabot Corporation, # 3050B, # 3150B, # 3250B manufactured by Mitsubishi Kasei Kogyo Co., Ltd. , # 3750B, # 3950B, # 950, # 650B, # 970B, # 850B, MA-600, MA-230, # 4000, # 4010, CONDUCTEX SC, Raven 8800, 8000, 7000, 5750, manufactured by Conlongbia Carbon Co., Ltd. 5250, 3500, 2100, 2000, 1800, 1500, 1255, 1250, and Ketjen Black EC manufactured by Akzo Corporation.
Carbon black may be surface-treated with a dispersant or the like, or may be used after being grafted with a resin, or may be obtained by graphitizing a part of the surface. Moreover, before adding carbon black to a coating material, you may disperse | distribute to a radiation-curable compound previously.
These carbon blacks are preferably used in an amount not exceeding 50% by weight with respect to the inorganic powder, and are preferably used in an amount not exceeding 40% by weight of the total weight of the radiation-cured layer. These carbon blacks can be used alone or in combination.
The carbon black that can be used in the present invention can be referred to, for example, “Carbon Black Handbook” (edited by Carbon Black Association).

6). Properties (thickness) of radiation-cured layer
In the present invention, the thickness of the radiation-cured layer is preferably 0.1 μm to 1.0 μm, more preferably 0.3 μm to 0.7 μm. In addition, the thickness of a radiation hardening layer is the thickness after drying. When the thickness of the radiation-cured layer is within the above range, it is preferable to obtain sufficient smoothness because the adhesion to the support is good.

(Elastic modulus)
In the present invention, the elastic modulus of the radiation-cured layer is preferably 1.5 GPa to 10 GPa. It is preferable for the elastic modulus to be in the above-mentioned range since a good coating film strength can be obtained without causing adhesion failure of the coating film.

(Average roughness)
In the present invention, the average roughness (Ra) at a cutoff value of 0.25 mm of the radiation-cured layer is preferably 1 nm to 2 nm. It is preferable for the average roughness to be in the above-mentioned range since sufficient smoothness of the magnetic layer can be obtained without causing a sticking failure to the pass roll in the coating process.

II. Magnetic Layer The magnetic recording medium of the present invention has a magnetic layer in which ferromagnetic powder is dispersed in a binder on a nonmagnetic support.
1. Ferromagnetic powder In the magnetic recording medium of the present invention, as a ferromagnetic powder, a needle-shaped ferromagnetic material having a major axis length of 20 nm to 50 nm, a flat magnetic material having a plate diameter of 10 nm to 50 nm, a spherical shape having a diameter of 10 nm to 50 nm, or It is preferable to use an elliptical magnetic material. Each will be described below.
(1) Acicular ferromagnet As the ferromagnetic powder used in the magnetic recording medium of the present invention, an acicular ferromagnet having a major axis length of 20 nm to 50 nm or less can be used. Examples of the acicular ferromagnet include an acicular ferromagnetic metal powder such as cobalt-containing ferromagnetic iron oxide or ferromagnetic alloy powder, and a BET specific surface area (S _BET ) of preferably 40 m ² / g to 80 m ^2. / g, more preferably 50m ² / g~70m ² / g. The crystallite size is preferably 12 nm to 25 nm, more preferably 13 nm to 22 nm, and particularly preferably 14 nm to 20 nm. The major axis length is preferably 20 nm to 50 nm, more preferably 20 nm to 40 nm.

  Examples of the ferromagnetic powder include Fe, Fe—Co, Fe—Ni, and Co—Ni—Fe containing yttrium, and the yttrium content in the ferromagnetic powder is a ratio of yttrium atoms to iron atoms (Y / Fe) is preferably 0.5 atom% to 20 atom%, and more preferably 5 atom% to 10 atom%. Within the above range, the ferromagnetic powder can be increased in σs, good magnetic characteristics can be obtained, and electromagnetic conversion characteristics are good, which is preferable. Furthermore, within a range of 20 atomic% or less with respect to 100 atomic% of iron, aluminum, silicon, sulfur, scandium, titanium, vanadium, chromium, manganese, copper, zinc, molybdenum, rhodium, palladium, tin, antimony, boron, Barium, tantalum, tungsten, rhenium, gold, lead, phosphorus, lanthanum, cerium, praseodymium, neodymium, tellurium, bismuth, and the like can be included. Further, the ferromagnetic metal powder may contain a small amount of water, hydroxide or oxide.

An example of the manufacturing method of the ferromagnetic powder which introduce | transduced cobalt and yttrium used for this invention is shown.
An example in which iron oxyhydroxide obtained by blowing an oxidizing gas into an aqueous suspension in which a ferrous salt and an alkali are mixed is used as a starting material can be given.
As the kind of this iron oxyhydroxide, α-FeOOH is preferable. The production method is as follows. Ferrous salt is neutralized with alkali hydroxide to form an aqueous suspension of Fe (OH) ₂ , and oxidizing gas is blown into this suspension to form acicular α-FeOOH. There is one manufacturing method. On the other hand, there is a second production method in which ferrous salt is neutralized with alkali carbonate to form an aqueous suspension of FeCO ₃ , and oxidizing gas is blown into this suspension to form spindle-shaped α-FeOOH. Such an iron oxyhydroxide is obtained by reacting a ferrous salt aqueous solution and an alkaline aqueous solution to obtain an aqueous solution containing ferrous hydroxide and oxidizing it by air oxidation or the like. Is preferred. In this case, Ni salt, alkaline earth element salt such as Ca salt, Ba salt, Sr salt, Cr salt, Zn salt, etc. may coexist in the ferrous salt aqueous solution, and such salt is appropriately selected. Thus, the particle shape (axial ratio) and the like can be prepared.

  As the ferrous salt, ferrous chloride, ferrous sulfate and the like are preferable. As the alkali, sodium hydroxide, aqueous ammonia, ammonium carbonate, sodium carbonate and the like are preferable. Moreover, as a salt which can coexist, chlorides, such as nickel chloride, calcium chloride, barium chloride, strontium chloride, chromium chloride, zinc chloride, are preferable.

  Next, when introducing cobalt into iron, before introducing yttrium, an aqueous solution of a cobalt compound such as cobalt sulfate or cobalt chloride is stirred and mixed into the iron oxyhydroxide slurry. After preparing a slurry of iron oxyhydroxide containing cobalt, an aqueous solution containing a compound of yttrium can be added to the slurry and mixed by stirring.

  In addition to yttrium, neodymium, samarium, praseodymium, lanthanum, gadolinium, and the like can be introduced into the ferromagnetic powder of the present invention. These can be introduced using chlorides such as yttrium chloride, neodymium chloride, samarium chloride, praseodymium chloride, lanthanum chloride, nitrates such as neodymium nitrate and gadolinium nitrate, and these are used in combination of two or more. Also good.

The coercive force (Hc) of the ferromagnetic metal powder is preferably 159.2 kA / m to 238.8 kA / m (2,000 Oe to 3,000 Oe), more preferably 167.2 kA / m to 230.8 kA / m (2,100 Oe to 2,900 Oe).
The saturation magnetic flux density is preferably 150 mT to 300 mT (1,500 G to 3,000 G), and more preferably 160 mT to 290 mT (1,600 G to 2,900 G). The saturation magnetization ([sigma] s) is preferably a ^{100A · m 2 / kg~170A · m} 2 / kg (100emu / g~170emu / g), more preferably ^{110A · m 2 / kg~160A · m} 2 / kg (110 emu / g to 160 emu / g).

The SFD (switching field distribution) of the magnetic material itself is preferably small and is preferably 0.8 or less. When the SFD is 0.8 or less, the electromagnetic conversion characteristics are good, the output is high, the magnetization reversal is sharp, the peak shift is small, and it is suitable for high-density digital magnetic recording. In order to reduce the Hc distribution, there are methods such as improving the particle size distribution of goethite in the ferromagnetic metal powder, using monodispersed α-Fe ₂ O ₃ , and preventing sintering between particles.

(2) Flat magnetic body As the flat magnetic body having a plate diameter of 10 to 50 nm that can be used in the present invention, hexagonal ferrite powder is preferable.
Examples of hexagonal ferrite include barium ferrite, strontium ferrite, lead ferrite, calcium ferrite substitution, and Co substitution. Specific examples include magnetoplumbite type barium ferrite and strontium ferrite, magnetoplumbite type ferrite whose particle surface is coated with spinel, and magnetoplumbite type barium ferrite and strontium ferrite partially containing a spinel phase. Other than the predetermined atoms, Al, Si, S, Sc, Ti, V, Cr, Cu, Y, Mo, Rh, Pd, Ag, Sn, Sb, Te, Ba, Ta, W, Re, Au, Hg , Pb, Bi, La, Ce, Pr, Nd, P, Co, Mn, Zn, Ni, Sr, B, Ge, Nb, Zr, and Zn may be included. In general, an element added with an element such as Co—Zn, Co—Ti, Co—Ti—Zr, Co—Ti—Zn, Ni—Ti—Zn, Nb—Zn—Co, Sb—Zn—Co, Nb—Zn, etc. Can be used. Some raw materials and manufacturing methods contain specific impurities.

The particle size is preferably 10 nm to 50 nm in terms of hexagonal plate diameter. When reproducing with a magnetoresistive head, it is necessary to reduce the noise, and the plate diameter is preferably 40 nm or less. If the plate diameter is in the above range, stable magnetization can be expected without thermal fluctuation. In addition, since noise is reduced, it is suitable for high density magnetic recording.
The plate ratio (plate diameter / plate thickness) is preferably 1 or more and 15 or less, and more preferably 2 or more and 7 or less. In the above range, the orientation is sufficient, stacking between particles hardly occurs, and noise is reduced. BET specific surface area of the particle size range showing a 10m ² / g~200m ² / g. The specific surface area is generally signified as an arithmetic calculation value from the particle plate diameter and plate thickness. The crystallite size is preferably 50 to 450 mm, more preferably 100 to 350 mm. The distribution of the particle plate diameter and plate thickness is usually as narrow as possible. Although numerical conversion is difficult, it can be compared by randomly measuring 500 particles from a particle TEM photograph. In many cases, the distribution is not a normal distribution, but when calculated and expressed as a standard deviation with respect to the average size, it is preferable that σ / average size = 0.1 to 2.0. In order to sharpen the particle size distribution, the particle generation reaction system is made as uniform as possible, and the generated particles are subjected to a distribution improvement process. For example, a method of selectively dissolving ultrafine particles in an acid solution is also known.

The coercive force Hc measured with a magnetic material can be made up to about 39.8 kA / m to 398 kA / m (500 Oe to 5,000 Oe). A higher Hc is advantageous for high-density recording, but is limited by the capacity of the recording head. Usually, it is about 63.7 kA / m to 318.4 kA / m (800 Oe to 4,000 Oe), but preferably 119.4 kA / m (1,500 Oe) to 278.6 kA / m (3,500 Oe). When the saturation magnetization of the head exceeds 1.4 Tesla, it is preferably 159.2 kA / m (2,000 Oe) or more.
Hc can be controlled by the particle size (plate diameter / plate thickness), the type and amount of contained elements, the substitution site of the elements, the particle generation reaction conditions, and the like. The saturation magnetization σs is 40 A · m ² / kg or more and 80 A · m ² / kg or less (40 emu / g to 80 emu / g). σs is preferably higher, but tends to be smaller as the particles become finer. In order to improve σs, it is well known to combine spinel ferrite with magnetoplumbite ferrite and to select the type and amount of elements contained. It is also possible to use W-type hexagonal ferrite.

  When dispersing the magnetic material (magnetic powder), the surface of the magnetic material particles is also treated with a material suitable for the dispersion medium and polymer. As the surface treatment material, an inorganic compound or an organic compound is used. Typical examples of the main compound include oxides or hydroxides such as Si, Al, and P, various silane coupling agents, and various titanium coupling agents. The amount is 0.1% to 10% with respect to the magnetic substance. The pH of the magnetic material is also important for dispersion. Usually, it is about 4 to 12, and there are optimum values depending on the dispersion medium and polymer, but about 6 to 10 is selected from the chemical stability and storage stability of the medium. Water contained in the magnetic material also affects the dispersion. Although there is an optimum value depending on the dispersion medium and polymer, 0.01% to 2.0% is usually selected.

  The hexagonal ferrite can be manufactured by (1) mixing a metal oxide replacing barium oxide, iron oxide, iron and boron oxide as a glass forming substance so as to have a desired ferrite composition, and then melting and quenching. Glass crystallization method to obtain barium ferrite crystal powder by making it amorphous and then reheating treatment, (2) neutralizing barium ferrite composition metal salt solution with alkali, Hydrothermal reaction method to obtain barium ferrite crystal powder by liquid phase heating at 100 ° C or higher after removal, washing, drying and grinding, (3) neutralizing barium ferrite composition metal salt solution with alkali, by-product There is a coprecipitation method in which barium ferrite crystal powder is obtained by drying, treating at 1,100 ° C. or less, and pulverizing, but the production method is not limited.

(3) Spherical or elliptical magnetic body As the spherical or elliptical magnetic body, an iron nitride-based ferromagnetic powder having Fe ₁₆ N ₂ as a main phase is preferable. In addition to Fe and N atoms, Al, Si, S, Sc, Ti, V, Cr, Cu, Y, Mo, Rh, Pd, Ag, Sn, Sb, Te, Ba, Ta, W, Re, Au, Hg, It may contain atoms such as Pb, Bi, La, Ce, Pr, Nd, P, Co, Mn, Zn, Ni, Sr, B, Ge, and Nb. The content of N with respect to Fe is preferably 1.0 atomic percent to 20.0 atomic percent.
The iron nitride is preferably spherical or elliptical, and the major axis / minor axis ratio is preferably 1-2. Preferably BET specific surface area (S _BET) is 30m ² / g~100m ² / g, more preferably 50m ² / g~70m ² / g. The crystallite size is preferably 12 nm to 25 nm, and more preferably 13 nm to 22 nm.
The saturation magnetization σs is preferably 50 A · m ² / kg (50 emu / g) to 200 A · m ² / kg (200 emu / g). More preferably, it is 70 A · m ² / kg (70 emu / g) to 150 A · m ² / kg (150 emu / g).

2. Binders Binders used in the magnetic layer include polyurethane resins, polyester resins, polyamide resins, vinyl chloride resins, acrylic resins copolymerized with styrene, acrylonitrile, methyl methacrylate, cellulose resins such as nitrocellulose, epoxy A resin, a phenoxy resin, polyvinyl acetal, polyvinyl alkylal resin such as polyvinyl butyral, or the like can be used alone or in combination. Among these, polyurethane resins, acrylic resins, cellulose resins, and vinyl chloride resins are preferable.

The binder preferably has a functional group (polar group) adsorbed on the surface of the powder in order to improve the dispersibility of the ferromagnetic powder and nonmagnetic powder. Preferred functional groups include —SO ₃ M, —SO ₄ M, —PO (OM) ₂ , —OPO (OM) ₂ , —COOM, ═NSO ₃ M, ═NRSO ₃ M, —NR ¹ R ² , —N. ⁺ R ¹ R ² R ³ X- ^{and the} like. Here, M is hydrogen or an alkali metal such as Na or K, R is an alkylene group, R ¹ , R ² or R ³ is an alkyl group or a hydroxyalkyl group or hydrogen, and X is a halogen such as Cl or Br. The amount of the functional group in the binder is preferably 10 μeq / g to 200 μeq / g, more preferably 30 μeq / g to 120 μeq / g. Within the above range, good dispersibility can be obtained, which is preferable.

In addition to the adsorptive functional group, the binder is preferably provided with a functional group having an active hydrogen such as an —OH group in order to react with an isocyanate curing agent to form a crosslinked structure and improve the coating film strength. A preferred amount is from 0.1 meq / g to 2 meq / g.
The molecular weight of the binder is preferably 10,000 to 200,000 in terms of weight average molecular weight, and more preferably 20,000 to 100,000. Within the above range, the coating film strength is sufficient, the durability is good, and the dispersibility is improved, which is preferable.

  Polyurethane resins which are preferable binders are described in detail in, for example, “Polyurethane Resin Handbook” (edited by Keiji Iwata, 1986, Nikkan Kogyo Shimbun). Usually, long-chain diols and short-chain diols (referred to as chain extenders) And an addition polymerization of a diisocyanate compound. As the long-chain diol, a polyester diol having a molecular weight of 500 to 5,000, a polyether diol, a polyether ester diol, a polycarbonate diol, a polyolefin diol, and the like are preferably used. Depending on the type of this long-chain polyol, it is called polyester urethane, polyether urethane, polyether ester urethane, polycarbonate urethane or the like.

The polyester diol can be obtained by polycondensation of an aliphatic dibasic acid such as adipic acid, sebacic acid or azelaic acid, or an aromatic dibasic acid such as isophthalic acid, orthophthalic acid, terephthalic acid or naphthalenedicarboxylic acid with glycol. Examples of the glycol component include ethylene glycol, 1,2-propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 3-methyl-1,5-pentanediol, 1,6- There are hexanediol, 2,2-dimethyl-1,3-propanediol, 1,8-octanediol, 1,9-nonanediol, cyclohexanediol, cyclohexanedimethanol, hydrogenated bisphenol A and the like. As the polyester diol, polycaprolactone diol and polyvalerolactone diol obtained by ring-opening polymerization of lactones such as ε-caprolactone and γ-valerolactone can also be used.
The polyester diol is preferably one having a branched side chain or one obtained from an aromatic or alicyclic raw material from the viewpoint of hydrolysis resistance.

Polyether diols include polyethylene glycol, polypropylene glycol, polytetramethylene glycol, aromatic glycols such as bisphenol A, bisphenol S, bisphenol P, hydrogenated bisphenol A, and alicyclic diols, and alkylene oxides such as ethylene oxide and propylene oxide. There are those obtained by addition polymerization.
These long-chain diols can be used in combination of a plurality of types.

  The short chain diol can be selected from the same group of compounds as exemplified in the glycol component of the polyester diol. In addition, when a small amount of trifunctional or higher polyhydric alcohol such as trimethylolethane, trimethylolpropane, pentaerythritol, etc. is used in combination, a polyurethane resin having a branched structure is obtained and the viscosity of the solution is lowered, or the isocyanate group is increased by increasing the OH group at the end of the polyurethane. Curability with the system curing agent can be enhanced.

Diisocyanate compounds include MDI (diphenylmethane diisocyanate), 2,4-TDI (tolylene diisocyanate), 2,6-TDI, 1,5-NDI (naphthalene diisocyanate), TODI (tolidine diisocyanate), p-phenylene diisocyanate, XDI ( Aromatic diisocyanates such as xylylene diisocyanate, transcyclohexane 1,4-diisocyanate, HDI (hexamethylene diisocyanate), IPDI (isophorone diisocyanate), H ₆ XDI (hydrogenated xylylene diisocyanate), H ₁₂ MDI (hydrogenated diphenylmethane diisocyanate) ) And other aliphatic and alicyclic diisocyanates.

A preferred composition of the long chain diol / short chain diol / diisocyanate in the polyurethane resin is (80 to 15% by weight) / (5 to 40% by weight) / (15 to 50% by weight).
The urethane group concentration of the polyurethane resin is preferably 1 meq / g to 5 meq / g, more preferably 1.5 meq / g to 4.5 meq / g. It is preferable for the urethane group concentration to be within the above range because high mechanical strength is obtained, solution viscosity is good, and good dispersibility is obtained.
The glass transition temperature of the polyurethane resin is preferably 0 ° C. or higher and 200 ° C. or lower, more preferably 40 ° C. to 160 ° C. It is preferable for the glass transition temperature to be in the above-mentioned range since high durability can be obtained, good calendar formability can be obtained, and good electromagnetic conversion characteristics can be obtained.

  As a method of introducing the above-mentioned adsorptive functional group (polar group) into the polyurethane resin, a method using a functional group as a part of a monomer of a long-chain diol, a method using a part of a short-chain diol, or after polymerizing a polyurethane, There is a method of introducing a polar group by molecular reaction.

As the vinyl chloride resin, a vinyl chloride monomer copolymerized with various monomers is used.
Copolymer monomers include fatty acid vinyl esters such as vinyl acetate and vinyl propionate, and acrylates such as methyl (meth) acrylate, ethyl (meth) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, and benzyl (meth) acrylate. , Methacrylates, allyl methyl ether, allyl ethyl ether, allyl propyl ether, allyl butyl ether, and other alkyl allyl ethers, other styrene, α-methyl styrene, vinylidene chloride, acrylonitrile, ethylene, butadiene, acrylamide, and co-functional groups. As polymerization monomers, vinyl alcohol, 2-hydroxyethyl (meth) acrylate, polyethylene glycol (meth) acrylate, 2-hydroxypropyl (meth) Chryrate, 3-hydroxypropyl (meth) acrylate, polypropylene glycol (meth) acrylate, 2-hydroxyethyl allyl ether, 2-hydroxypropyl allyl ether, 3-hydroxypropyl allyl ether, p-vinylphenol, maleic acid, maleic anhydride Acrylic acid, methacrylic acid, glycidyl (meth) acrylate, allyl glycidyl ether, phosphoethyl (meth) acrylate, sulfoethyl (meth) acrylate, p-styrene sulfonic acid, and Na salts and K salts thereof are used.
The composition of the vinyl chloride monomer in the vinyl chloride resin is preferably 60% by weight to 95% by weight. Within the above range, good mechanical strength can be obtained, solvent solubility is good, and good dispersibility can be obtained for a suitable solution viscosity.

The preferred amount of the functional group for enhancing the curability with the adsorption functional group (polar group) and the polyisocyanate curing agent is as described above. As a method for introducing these functional groups, the above-mentioned functional group-containing monomers may be copolymerized, or after copolymerizing a vinyl chloride resin, the functional groups may be introduced by a polymer reaction.
The preferable degree of polymerization is 200 to 600, more preferably 240 to 450. Within the above range, it is preferable because good mechanical strength can be obtained and good dispersibility can be obtained for a suitable solution viscosity.

A curing agent can be used to crosslink and cure the binder used in the present invention to increase the mechanical strength and heat resistance of the coating film. A preferred curing agent is a polyisocyanate compound. The polyisocyanate compound is preferably a triisocyanate or higher polyisocyanate.
Specifically, a compound obtained by adding 3 moles of TDI (tolylene diisocyanate) to trimethylolpropane (TMP), a compound obtained by adding 3 moles of HDI (hexamethylene diisocyanate) to TMP, and 3 moles of IPDI (isophorone diisocyanate) to TMP Adduct type polyisocyanate compounds, such as compounds obtained by adding 3 moles of XDI (xylylene diisocyanate) to TMP. TDI condensed isocyanurate type trimer, TDI condensed isocyanurate pentamer, TDI condensed isocyanurate heptamer, and mixtures thereof. HDI isocyanurate type condensate, IPDI isocyanurate type condensate. There is also Crude MDI.
Among these, a compound obtained by adding 3 moles of TDI to TMP, an isocyanurate type trimer of TDI, and the like are preferable.

In addition to the isocyanate curing agent, a radiation curable curing agent such as an electron beam or an ultraviolet ray may be used. In this case, a curing agent having two or more, preferably three or more acryloyl groups or methacryloyl groups in the molecule as a radiation curable functional group can be used. Examples include TMP (trimethylolpropane) triacrylate, pentaerythritol tetraacrylate, and urethane acrylate oligomer. In this case, it is preferable to introduce a (meth) acryloyl group into the binder in addition to the curing agent. In the case of ultraviolet curing, a photosensitizer is also used in combination.
It is preferable to add 0 to 80 parts by weight of the curing agent with respect to 100 parts by weight of the binder. It is preferable for it to be in the above range since the dispersibility is good.

  In the case of a magnetic layer, the addition amount of the binder is preferably 5 to 30 parts by weight and more preferably 10 to 20 parts by weight with respect to 100 parts by weight of the ferromagnetic powder.

Additives can be added to the magnetic layer in the present invention as necessary. Examples of the additive include an abrasive, a lubricant, a dispersant / dispersion aid, an antifungal agent, an antistatic agent, an antioxidant, a solvent, and carbon black.
Examples of these additives include molybdenum disulfide, tungsten disulfide, graphite, boron nitride, graphite fluoride, silicone oil, silicone having a polar group, fatty acid-modified silicone, fluorine-containing silicone, fluorine-containing alcohol, fluorine-containing ester, Polyolefin, polyglycol, polyphenyl ether, phenylphosphonic acid, benzylphosphonic acid group, phenethylphosphonic acid, α-methylbenzylphosphonic acid, 1-methyl-1-phenethylphosphonic acid, diphenylmethylphosphonic acid, biphenylphosphonic acid, benzylphenylphosphon Acid, α-cumylphosphonic acid, toluylphosphonic acid, xylylphosphonic acid, ethylphenylphosphonic acid, cumenylphosphonic acid, propylphenylphosphonic acid, butylphenylphosphonic acid, heptyl Aromatic ring-containing organic phosphonic acids such as phenylphosphonic acid, octylphenylphosphonic acid, nonylphenylphosphonic acid and alkali metal salts thereof, octylphosphonic acid, 2-ethylhexylphosphonic acid, isooctylphosphonic acid, isononylphosphonic acid, isodecyl Alkylphosphonic acids such as phosphonic acid, isoundecylphosphonic acid, isododecylphosphonic acid, isohexadecylphosphonic acid, isooctadecylphosphonic acid, isoeicosylphosphonic acid and alkali metal salts thereof, phenyl phosphate, benzyl phosphate, phosphorus Phenethyl phosphate, α-methylbenzyl phosphate, 1-methyl-1-phenethyl phosphate, diphenylmethyl phosphate, biphenyl phosphate, benzylphenyl phosphate, α-cumyl phosphate, toluyl phosphate, xylyl phosphate, phosphate Ethylphenyl, Aromatic phosphates such as cumenyl phosphate, propylphenyl phosphate, butylphenyl phosphate, heptylphenyl phosphate, octylphenyl phosphate, nonylphenyl phosphate, and alkali metal salts thereof, octyl phosphate, 2-ethylhexyl phosphate , Isooctyl phosphate, isononyl phosphate, isodecyl phosphate, isoundecyl phosphate, isododecyl phosphate, isohexadecyl phosphate, isooctadecyl phosphate, isoeicosyl phosphate, and alkali metal salts thereof, alkylsulfonic acid Esters and alkali metal salts thereof, fluorine-containing alkyl sulfates and alkali metal salts thereof, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, elaidic acid, erucic acid, etc. Monobasic fatty acids and metal salts thereof which may contain or be branched from an unsaturated bond having a prime number of 10 to 24, or butyl stearate, octyl stearate, amyl stearate, isooctyl stearate, octyl myristate, lauric acid One base which may contain or be branched from an unsaturated bond having 10 to 24 carbon atoms such as butyl, butoxyethyl stearate, anhydrosorbitan monostearate, anhydrosorbitan distearate, anhydrosorbitan tristearate 1- to 6-valent alcohols that may contain or be branched from a fatty acid and an unsaturated bond having 2 to 22 carbon atoms, alkoxy alcohols or alkylene oxides that may contain or be branched from an unsaturated bond having 12 to 22 carbon atoms Consisting of any one of the monoalkyl ethers of the polymer Bruno fatty acid esters, difatty acid esters or polyvalent fatty acid esters, fatty acid amides having 2 to 22 carbon atoms, and aliphatic amines having 8 to 22 carbon atoms can be used. In addition to the above hydrocarbon groups, alkyl groups, aryl groups, and aralkyl groups substituted with nitro groups and groups other than hydrocarbon groups such as halogen-containing hydrocarbons such as F, Cl, Br, CF ₃ , CCl ₃ , and CBr ₃ You may have something.

  In addition, nonionic surfactants such as alkylene oxide, glycerin, glycidol, and alkylphenol ethylene oxide adducts, cyclic amines, ester amides, quaternary ammonium salts, hydantoin derivatives, heterocycles, phosphonium, sulfonium and other cations Surfactants, anionic surfactants containing acidic groups such as carboxylic acid, sulfonic acid and sulfate ester groups, amino acids, aminosulfonic acids, sulfuric or phosphate esters of amino alcohols, and amphoteric surfactants such as alkylbetaine type Agents can also be used. These surfactants are described in detail in “Surfactant Handbook” (published by Sangyo Tosho Co., Ltd.).

The dispersant, lubricant, and the like are not necessarily pure, and may contain impurities such as isomers, unreacted materials, side reaction products, decomposition products, and oxides in addition to the main components. These impurities are preferably 30% by weight or less, more preferably 10% by weight or less.
Specific examples of these additives include, for example, manufactured by NOF Corporation: NAA-102, castor oil hardened fatty acid, NAA-42, cation SA, Naimine L-201, Nonion E-208, Anon BF, Anon LG, Takemoto Oil and fat: FAL-205, FAL-123, Shin Nippon Chemical Co., Ltd .: NJ Lube OL, Shin-Etsu Chemical: TA-3, Lion Armor: Armide P, Lion: Duomin TDO, Nisshin Oil : BA-41G, Sanyo Kasei Co., Ltd .: Profan 2012E, New Pole PE61, Ionette MS-400, and the like.

  In the present invention, known organic solvents can be used in the magnetic layer. The organic solvent is an arbitrary ratio of ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, cyclohexanone, isophorone, alcohols such as methanol, ethanol, propanol, butanol, isobutyl alcohol, isopropyl alcohol, methylcyclohexanol, Esters such as methyl acetate, butyl acetate, isobutyl acetate, isopropyl acetate, ethyl lactate and glycol acetate, glycol ethers such as glycol dimethyl ether, glycol monoethyl ether and dioxane, aromatic hydrocarbons such as benzene, toluene, xylene and cresol , Methylene chloride, ethylene chloride, carbon tetrachloride, chloroform, ethylene chlorohydrin, chlorobenzene, dichlorobenzene, etc. Chlorinated hydrocarbons, N, can be used N- dimethylformamide, hexane, tetrahydrofuran or the like.

  These organic solvents are not necessarily 100% pure, and may contain impurities such as isomers, unreacted materials, side reaction products, decomposition products, oxides, and moisture in addition to the main components. These impurities are preferably 30% or less, more preferably 10% or less. The organic solvent used in the present invention is preferably the same in the magnetic layer and the nonmagnetic layer. The amount added may be changed. Use non-magnetic layers with high surface tension solvents (cyclohexanone, dioxane, etc.) to increase coating stability. Specifically, the arithmetic average value of the upper layer solvent composition may not fall below the arithmetic average value of the nonmagnetic layer solvent composition. It is essential. In order to improve dispersibility, it is preferable that the polarity is somewhat strong, and it is preferable that 50% or more of a solvent having a dielectric constant of 15 or more is included in the solvent composition. The solubility parameter is preferably 8 or more and 11 or less.

  These dispersants, lubricants, and surfactants used in the magnetic layer in the present invention can be properly used in the magnetic layer and the nonmagnetic layer described later as needed. For example, of course, the dispersant is not limited to the example shown here, but the dispersant has a property of adsorbing or binding with a polar group, and in the magnetic layer, mainly on the surface of the ferromagnetic powder, as will be described later. In the nonmagnetic layer, it is presumed that the organophosphorus compound adsorbed or bonded to the surface of the nonmagnetic powder mainly by the polar group and once adsorbed is difficult to desorb from the surface of metal or metal compound. Accordingly, the surface of the ferromagnetic powder of the present invention or the nonmagnetic powder surface described later is in a state of being coated with an alkyl group, an aromatic group, etc., so the affinity of the ferromagnetic powder or nonmagnetic powder for the binder resin component And the dispersion stability of the ferromagnetic powder or non-magnetic powder is also improved. In addition, since it exists in a free state as a lubricant, the non-magnetic layer and the magnetic layer use fatty acids having different melting points to control the bleeding to the surface. It is conceivable that the stability of coating is improved by controlling the amount of the surfactant, and the lubricating effect is improved by increasing the amount of lubricant added in the nonmagnetic layer. All or a part of the additives used in the present invention may be added in any step during the production of the coating solution for the magnetic layer or nonmagnetic layer. For example, when mixing with a ferromagnetic powder before the kneading step, when adding at a kneading step with a ferromagnetic powder, a binder and a solvent, when adding at a dispersing step, when adding after dispersing, when adding just before coating, etc. There is.

  In addition, carbon black can be added to the magnetic layer in the present invention as necessary. As carbon black, the same carbon black as that used in the radiation-cured layer can be used.

  Carbon black can be used alone or in combination. When carbon black is used, it is preferably used in an amount of 0.1 to 30% by weight based on the weight of the ferromagnetic powder. Carbon black functions to prevent the magnetic layer from being charged, reduce the coefficient of friction, impart light-shielding properties, and improve the film strength. These differ depending on the carbon black used. Therefore, these carbon blacks used in the present invention change the type, amount, and combination in the magnetic layer, and depending on the purpose based on the above-mentioned characteristics such as particle size, oil absorption, conductivity, pH, etc. Of course, it is possible to use them properly, but they should be optimized in each layer.

III. Nonmagnetic Layer The magnetic recording medium of the present invention may have a nonmagnetic layer containing a binder and a nonmagnetic powder between the radiation-cured layer and the magnetic layer. Moreover, you may mix carbon black with a nonmagnetic powder as needed with a nonmagnetic layer.

1. Nonmagnetic powder Magnetic powder may be used for the nonmagnetic layer as long as the lower layer is substantially nonmagnetic, but it is preferable to use nonmagnetic powder.
The nonmagnetic powder that can be used in the nonmagnetic layer may be an inorganic substance or an organic substance. Examples of the inorganic substance include metals, metal oxides, metal carbonates, metal sulfates, metal nitrides, metal carbides, and metal sulfides.

Specifically, titanium oxide such as titanium dioxide, cerium oxide, tin oxide, tungsten oxide, ZnO, ZrO ₂ , SiO ₂ , Cr ₂ O ₃ , α-alumina, β-alumina having an α conversion of 90 to 100%, γ-alumina, α-iron oxide, goethite, corundum, silicon nitride, titanium carbide, magnesium oxide, boron nitride, molybdenum disulfide, copper oxide, MgCO ₃ , CaCO ₃ , BaCO ₃ , SrCO ₃ , BaSO ₄ , silicon carbide Titanium carbide or the like is used alone or in combination of two or more. Preferable are α-iron oxide and titanium oxide.

The shape of the nonmagnetic powder may be any of acicular, spherical, polyhedral and plate shapes.
The crystallite size of the nonmagnetic powder is preferably 4 nm to 1 μm, and more preferably 40 nm to 100 nm. If the crystallite size is in the above numerical range, it is preferable because dispersion does not become difficult and the surface roughness is suitable.
The average particle size of these non-magnetic powders is preferably 5 nm to 2 μm. However, if necessary, non-magnetic powders having different average particle sizes may be combined, or even a single non-magnetic powder may have a wide particle size distribution. It can also have an effect. Particularly preferred nonmagnetic powder has an average particle size of 10 nm to 200 nm. If the average particle size is in the above numerical range, it is preferable because the dispersion is good and the surface roughness is suitable.

The specific surface area of the nonmagnetic powder preferably is 1m ² / g~100m ² / g, more preferably 5m ² / g~70m ² / g, more preferably 10m ² / g~65m ² / g is there. A specific surface area within the above numerical range is preferred because it has a suitable surface roughness and can be dispersed with a desired amount of binder.
The oil absorption using dibutyl phthalate (DBP) is preferably 5 ml / 100 g to 100 ml / 100 g, more preferably 10 ml / 100 g to 80 ml / 100 g, and still more preferably 20 to 60 ml / 100 g.
Specific gravity becomes like this. Preferably it is 1-12, More preferably, it is 3-6. The tap density is preferably 0.05 g / ml to 2 g / ml, more preferably 0.2 g / ml to 1.5 g / ml. If the tap density is within the above numerical range, it is preferable because the number of scattered particles is small, the operation is easy, and it tends to be difficult to adhere to the apparatus.

The pH of the nonmagnetic powder is preferably 2 to 11, but the pH is particularly preferably 6 to 9. If pH is the said numerical range, since a friction coefficient will not become large by high temperature, under high humidity, or liberation of a fatty acid, it is preferable.
The water content of the nonmagnetic powder is preferably 0.1 wt% to 5 wt%, more preferably 0.2 wt% to 3 wt%, and still more preferably 0.3 wt% to 1.5 wt%. If the water content is in the above numerical range, it is preferable because the dispersion is good and the viscosity of the paint after dispersion is stable.
The ignition loss is preferably 20% by weight or less, and the ignition loss is preferably small.

When the nonmagnetic powder is an inorganic powder, the Mohs hardness is preferably 4-10. If the Mohs hardness is in the above numerical range, it is preferable because durability can be secured. Stearic acid (SA) adsorption capacity of the nonmagnetic powder is preferably in 1μmol / m ² ~20μmol / m ² or less, more preferably from ^{2μmol / m 2 ~15μmol / m 2} .
The heat of wetting of the nonmagnetic powder into water at 25 ° C. is preferably in the range of 20 μJ / cm ^{2 to} 60 μJ / cm ² (200 erg / cm ^{2 to} 600 erg / cm ² ). Further, it is preferable to use a solvent within the range of heat of wetting.
The amount of water molecules on the surface at 100 ° C. to 400 ° C. is suitably 1/100 to 10/100 °. The pH of the isoelectric point in water is preferably 3-9.

The surface of these nonmagnetic powders is preferably surface-treated with Al ₂ O ₃ , SiO ₂ , TiO ₂ , ZrO ₂ , SnO ₂ , Sb ₂ O ₃ and ZnO. Particularly preferred for dispersibility are Al ₂ O ₃ , SiO ₂ , TiO ₂ , and ZrO ₂ , but more preferred are Al ₂ O ₃ , SiO ₂ , and ZrO ₂ . These may be used in combination or may be used alone. Further, a surface-treated layer co-precipitated according to the purpose may be used on the surface of the nonmagnetic powder, or a method of first treating with alumina and then treating the surface layer with silica, or vice versa. You can also. The surface treatment layer may be a porous layer depending on the purpose, but it is generally preferable that the surface treatment layer is homogeneous and dense.

Specific examples of the nonmagnetic powder used for the nonmagnetic layer in the present invention include, for example, Showa Denko Nanotite, Sumitomo Chemical HIT-100, ZA-G1, Toda Kogyo DPN-250, DPN-250BX, DPN-245, DPN-270BX, DPB-550BX, DPN-550RX Titanium oxide made by Ishihara Sangyo TTO-51B, TTO-55A, TTO-55B, TTO-55C, TTO-55S, TTO-55D, SN-100, MJ- 7, α-iron oxide E270, E271, E300, STT-4D, STT-30D, STT-30, STT-65C, manufactured by Titanium Industry, MT-100S, MT-100T, MT-150W, MT-500B, T -600B, T-100F, T-500HD, etc. are mentioned. Sakai Chemical FINEX-25, BF-1, BF-10, BF-20, ST-M, Dowa Mining DEFIC-Y, DEFIC-R, Nippon Aerosil AS2BM, TiO ₂ P25, Ube Industries 100A, 500A, Examples thereof include Y-LOP manufactured by Titanium Industry and those obtained by firing the same. Particularly preferred nonmagnetic powders are titanium dioxide and α-iron oxide.

Carbon black can be mixed in the nonmagnetic layer together with nonmagnetic powder to lower the surface electrical resistance, reduce the light transmittance, and obtain the desired μ Vickers hardness. Μ Vickers hardness of the nonmagnetic layer is preferably to ^{25kg / mm 2 ~60kg / mm 2} , more preferably to adjust the head contact, and a ^{30kg / mm 2 ~50kg / mm 2} , a thin film hardness meter (NEC Using HMA-400), a diamond triangular pyramid needle with a ridge angle of 80 degrees and a tip radius of 0.1 μm can be used for the tip of the indenter. It is standardized that the light transmittance is generally 3% or less for absorption of infrared rays having a wavelength of about 900 nm, for example, 0.8% or less for a VHS magnetic tape. For this purpose, rubber furnace, rubber thermal, color black, acetylene black and the like can be used.

The specific surface area of the carbon black used in the non-magnetic layer in the present invention is preferably 100m ² / g~500m ² / g, more preferably 150m ² / g~400m ² / g, a dibutyl phthalate (DBP) oil absorption is preferably It is 20 ml / 100g-400ml / 100g, More preferably, it is 30ml / 100g-200ml / 100g. The particle size of carbon black is preferably 5 nm to 80 nm, more preferably 10 nm to 50 nm, and still more preferably 10 nm to 40 nm. The carbon black preferably has a pH of 2 to 10, a moisture content of 0.1% to 10%, and a tap density of 0.1 g / ml to 1 g / ml.

  Specific examples of carbon black that can be used for the nonmagnetic layer in the present invention include BLACKPEARLS 2000, 1300, 1000, 900, 800, 880, 700, VULCAN XC-72, manufactured by Mitsubishi Kasei Kogyo Co., Ltd. 3050B, # 3150B, # 3250B, # 3750B, # 3950B, # 950, # 650B, # 970B, # 850B, MA-600, Columbia Carbon's CONDUCTEX SC, RAVEN8800, 8000, 7000, 5750, 5250, 3500, 2100 2000, 1800, 1500, 1255, 1250, Ketjen Black EC manufactured by Akzo Corporation, and the like.

  Moreover, you may mix carbon black with a nonmagnetic powder as needed with a nonmagnetic layer. Carbon black may be surface-treated with a dispersant or the like, or may be used after being grafted with a resin, or may be obtained by graphitizing a part of the surface. Moreover, before adding carbon black to a coating material, you may disperse | distribute with a binder beforehand. These carbon blacks are preferably used in a range not exceeding 50% by weight with respect to the inorganic powder and not exceeding 40% of the total weight of the nonmagnetic layer. These carbon blacks can be used alone or in combination. The carbon black that can be used in the nonmagnetic layer of the present invention can be referred to, for example, “Carbon Black Handbook” edited by Carbon Black Association.

  Further, an organic powder can be added to the nonmagnetic layer according to the purpose. Examples of such organic powder include acrylic styrene resin powder, benzoguanamine resin powder, melamine resin powder, and phthalocyanine pigment, but polyolefin resin powder, polyester resin powder, polyamide resin powder, polyimide resin, and the like. Resin powder and polyfluorinated ethylene resin can also be used. As the production method, those described in JP-A Nos. 62-18564 and 60-255827 can be used.

IV. Nonmagnetic Supports Examples of the nonmagnetic support that can be used in the present invention include known ones such as biaxially stretched polyethylene terephthalate, polyethylene naphthalate, polyamide, polyamideimide, and aromatic polyamide. Among these, polyethylene terephthalate, polyethylene naphthalate, and polyamide are preferable.
These supports may be subjected in advance to corona discharge, plasma treatment, easy adhesion treatment, heat treatment and the like. The surface roughness of the nonmagnetic support that can be used in the present invention is preferably 3 to 10 nm with a center average roughness Ra at a cutoff value of 0.25 mm.

V. Backcoat layer Generally, magnetic tape for computer data recording is strongly required to have repeated running characteristics as compared with video tape and audio tape. In order to maintain such high storage stability, a backcoat layer can be provided on the surface of the nonmagnetic support opposite to the surface on which the nonmagnetic layer and the magnetic layer are provided. The coating material for the backcoat layer can be prepared by dispersing particle components such as an abrasive and an antistatic agent and a binder in an organic solvent. Various inorganic pigments and carbon black can be used as the particle component. Moreover, as a binder, resin, such as a nitrocellulose, a phenoxy resin, a vinyl chloride resin, a polyurethane, can be used individually or in mixture, for example.

VI. Layer Configuration In the configuration of the magnetic recording medium used in the present invention, the thickness of the radiation-cured layer is preferably 0.1 μm to 1.0 μm, more preferably 0.3 μm to 0.7 μm, as described above. Moreover, the preferable thickness of a nonmagnetic support body is 3 micrometers-80 micrometers. The thickness of the backcoat layer provided on the surface opposite to the surface on which the nonmagnetic layer and the magnetic layer of the nonmagnetic support are provided is preferably 0.1 μm to 1.0 μm, more preferably 0. .2 μm to 0.8 μm.

  The thickness of the magnetic layer is optimized depending on the saturation magnetization amount, head gap length, and recording signal band of the magnetic head to be used, and is preferably 0.01 μm to 0.20 μm, more preferably. It is 0.02 μm to 0.15 μm. The thickness variation rate of the magnetic layer is preferably within ± 50%, and more preferably within ± 40%. There may be at least one magnetic layer, and the magnetic layer may be separated into two or more layers having different magnetic characteristics, and a configuration related to a known multilayer magnetic layer can be applied.

  Moreover, the thickness of the nonmagnetic layer is preferably 0.2 μm to 3.0 μm, more preferably 0.3 μm to 2.5 μm, and still more preferably 0.4 μm to 2.0 μm. The non-magnetic layer of the magnetic recording medium of the present invention exhibits its effect if it is substantially non-magnetic. For example, even if it contains a small amount of magnetic material as an impurity or intentionally, This shows the effect of the invention and can be regarded as substantially the same configuration as the magnetic recording medium of the invention. Note that “substantially the same” means that the residual magnetic flux density of the nonmagnetic layer is 10 mT (100 G) or less or the coercive force is 7.96 kA / m (100 Oe) or less. It means not having.

VII. Manufacturing Method The step of manufacturing the magnetic layer coating liquid for the magnetic recording medium used in the present invention comprises at least a kneading step, a dispersing step, and a mixing step provided as necessary before and after these steps. Each process may be divided into two or more stages. All raw materials such as ferromagnetic hexagonal ferrite powder or ferromagnetic metal powder, non-magnetic powder, binder, carbon black, abrasive, antistatic agent, lubricant, solvent used in the present invention are in the beginning or middle of any process. It may be added. In addition, individual raw materials may be added in two or more steps. For example, polyurethane may be divided and added in a kneading step, a dispersing step, and a mixing step for adjusting the viscosity after dispersion. In order to achieve the object of the present invention, a conventional known manufacturing technique can be used as a partial process. In the kneading step, it is preferable to use a kneading force such as an open kneader, a continuous kneader, a pressure kneader, or an extruder. When using a kneader, the range is 15 to 500 parts by weight with respect to 100 parts by weight of ferromagnetic powder or non-magnetic powder and all or part of the binder (however, 30% or more of the total binder is preferred) and ferromagnetic powder. It is preferable that the kneading process is performed. Details of these kneading treatments are described in JP-A-1-106338 and JP-A-1-79274. Further, glass beads can be used to disperse the liquid for the magnetic layer and the liquid for the nonmagnetic layer. Such glass beads are preferably zirconia beads, titania beads, and steel beads, which are high specific gravity dispersion media. The particle diameter and filling rate of these dispersion media are optimized. A well-known thing can be used for a disperser.

  In the method for producing a magnetic recording medium of the present invention, for example, a magnetic layer coating solution is applied to the surface of a nonmagnetic support under running so as to have a predetermined film thickness. Here, a plurality of coating solutions for magnetic layers may be applied sequentially or simultaneously, and a lower magnetic layer coating solution and an upper magnetic layer coating solution may be applied sequentially or simultaneously. When a non-magnetic layer is provided below the magnetic layer coating solution or the magnetic layer, the coating machine for applying the non-magnetic layer coating solution includes air doctor coating, blade coating, rod coating, extrusion coating, and air knife coating. A squeeze coat, an impregnation coat, a reverse roll coat, a transfer roll coat, a gravure coat, a kiss coat, a cast coat, a spray coat, a spin coat and the like can be used. As for these, for example, “Latest Coating Technology” (May 31, 1983) issued by General Technology Center Co., Ltd. can be referred to.

In the case of a magnetic tape, the magnetic layer coating liquid coating layer is formed by subjecting the ferromagnetic powder contained in the magnetic layer coating liquid coating layer to a magnetic field orientation process in the longitudinal direction using a cobalt magnet or a solenoid. In the case of a disk, a sufficiently isotropic orientation may be obtained even without non-orientation without using an orientation device, but known random methods such as alternately arranging cobalt magnets obliquely and applying an alternating magnetic field with a solenoid. It is preferable to use an alignment device. In the case of a ferromagnetic metal powder, the isotropic orientation is generally preferably in-plane two-dimensional random, but can also be three-dimensional random with a vertical component. In the case of hexagonal ferrite, in general, it tends to be in-plane and vertical three-dimensional random, but in-plane two-dimensional random is also possible. Further, isotropic magnetic characteristics can be imparted in the circumferential direction by using a well-known method such as a counter-polarized magnet and making it vertically oriented. In particular, when performing high density recording, vertical alignment is preferable. Moreover, it is good also as circumferential orientation using a spin coat.
It is preferable to be able to control the drying position of the coating film by controlling the temperature, air volume, and coating speed of the drying air, the coating speed is 20 m / min to 1,000 m / min, and the drying wind temperature is 60 ° C. The above is preferable. Moreover, moderate preliminary drying can also be performed before entering a magnet zone.

After being dried, the coating layer is subjected to a surface smoothing treatment. For the surface smoothing process, for example, a super calendar roll or the like is used. By performing the surface smoothing treatment, voids generated by removing the solvent during drying disappear and the filling rate of the ferromagnetic powder in the magnetic layer is improved, so that a magnetic recording medium having high electromagnetic conversion characteristics can be obtained. it can.
As the calendering roll, it is preferable to use a heat-resistant plastic roll such as epoxy, polyimide, polyamide, and polyamideimide. Moreover, it can also process with a metal roll. The magnetic recording medium of the present invention has an extremely excellent smoothness with a center surface average roughness of preferably 0.1 nm to 4.0 nm, more preferably 0.5 nm to 3.0 nm, at a cutoff value of 0.25 mm. It is preferable that the surface has As the method, for example, as described above, a magnetic layer formed by selecting a specific ferromagnetic powder and a binder is subjected to the calendar treatment. As the calendering conditions, the temperature of the calender roll is preferably 60 ° C. to 100 ° C., more preferably 70 ° C. to 100 ° C., particularly preferably 80 ° C. to 100 ° C., and the pressure is preferably 100 kg / cm to 500 kg / cm. More preferably, it is 200 kg / cm to 450 kg / cm, and particularly preferably it is carried out by operating under conditions of 300 kg / cm to 400 kg / cm.

  As a means for reducing the heat shrinkage rate, there are a method in which heat treatment is performed in a web shape while handling with low tension, and a method in which heat treatment is performed in a form in which tapes are laminated such as a state of being incorporated in a bulk or a cassette (thermo treatment). The former is less affected by protrusions on the surface of the backcoat layer, but the heat shrinkage rate cannot be greatly reduced. On the other hand, the latter thermo-treatment can greatly improve the heat shrinkage rate, but if it is strongly influenced by the projections on the surface of the backcoat layer, the magnetic layer becomes rough, causing a decrease in output and an increase in noise. In particular, a high-output, low-noise magnetic recording medium can be supplied as a magnetic recording medium with a thermo process. The obtained magnetic recording medium can be cut into a desired size using a cutting machine, a punching machine, or the like.

VIII. Physical Properties The saturation magnetic flux density of the magnetic layer of the magnetic recording medium used in the present invention is preferably 100 mT to 300 mT (1,000 G to 3,000 G). The coercive force (Hr) of the magnetic layer is preferably 143.3 kA / m to 318.4 kA / m (1,800 to 4,000 Oe), more preferably 159.2 kA / m to 278.6 kA. / M (2,000 Oe to 3,500 Oe). The coercive force distribution is preferably narrow, and SFD and SFDr are preferably 0.6 or less, and more preferably 0.2 or less.

The friction coefficient with respect to the head of the magnetic recording medium used in the present invention is preferably 0.5 or less, more preferably 0.3 or less at a temperature of −10 ° C. to 40 ° C. and a humidity of 0% to 95%. The charging position is preferably −500 V to +500 V. The elastic modulus at 0.5% elongation of the magnetic layer is preferably 0.98 GPa to 19.6 GPa (100 kg / mm ^{2 to} 2,000 kg / mm ² ) in each in-plane direction, and the breaking strength is preferably 98 MPa to ^{686MPa (10kg / mm 2 ~70kg /} mm 2), the elastic modulus of the magnetic recording medium is preferably 0.98GPa~14.7GPa each plane direction ^{(100kg / mm 2 ~1,500kg / mm} 2), the residual The thermal shrinkage at any temperature of preferably 0.5% or less and 100 ° C. or less is preferably 1% or less, more preferably 0.5% or less, and most preferably 0.1% or less.

The glass transition temperature of the magnetic layer (the maximum point of the loss modulus of dynamic viscoelasticity measured at 110 Hz) is preferably 50 ° C. to 180 ° C., and that of the nonmagnetic layer is preferably 0 ° C. to 180 ° C. The loss elastic modulus is preferably in the range of 1 × 10 ⁷ to 8 × 10 ⁸ Pa (1 × 10 ⁸ dyne / cm ² to 8 × 10 ⁹ dyne / cm ² ), and the loss tangent is 0.2 or less. It is preferable. A loss tangent of 0.2 or less is preferred because adhesion failure is unlikely to occur. These thermal characteristics and mechanical characteristics are preferably almost equal within 10% in each in-plane direction of the medium.
The residual solvent contained in the magnetic layer is preferably 100 mg / m ² or less, more preferably 10 mg / m ² or less. The porosity of the coating layer is preferably 30% by volume or less, more preferably 20% by volume or less for both the nonmagnetic layer and the magnetic layer. The porosity is preferably small in order to achieve high output, but it may be better to ensure a certain value depending on the purpose. For example, in the case of a disk medium in which repeated use is important, the storage stability is often preferable when the porosity is large.

The center surface surface roughness Ra measured by optical interference using a digital optical profmeter of the magnetic layer is preferably 4.0 nm or less, more preferably 3.0 nm or less, and even more preferably 2.0 nm or less. It is. The maximum height SR _max of the magnetic layer is 0.5 μm or less, the ten-point average roughness SRz is 0.3 μm or less, the center plane peak height SRp is 0.3 μm or less, and the center plane valley depth SRv is 0.3 μm or less. The center surface area ratio SSr is preferably 20% to 80%, and the average wavelength Sλa is preferably 5 μm to 300 μm. The surface protrusions of the magnetic layer can be arbitrarily set within the range of 0 to 2,000 per 100 μm ² with a size of 0.01 μm to 1 μm, which makes it possible to set electromagnetic conversion characteristics and friction coefficient. Is preferably optimized. These can be easily controlled by controlling the surface properties by the filler of the support, the particle size and amount of the powder added to the magnetic layer, the roll surface shape of the calendering treatment, and the like. The curl is preferably within ± 3 mm.

It is easily estimated that these physical characteristics can be changed between the nonmagnetic layer and the magnetic layer in the magnetic recording medium of the present invention depending on the purpose. For example, the elastic modulus of the magnetic layer is increased to improve the storage stability, and at the same time, the elastic modulus of the nonmagnetic layer is made lower than that of the magnetic layer to improve the contact of the magnetic recording medium with the head.
The magnetic recording medium of the present invention is not particularly limited with respect to a head for reproducing a signal magnetically recorded on the magnetic recording medium, but is preferably used for an MR head. When the MR head is used for reproducing the magnetic recording medium of the present invention, the MR head is not particularly limited, and for example, a GMR head or a TMR head can be used. The head used for magnetic recording is not particularly limited, but the saturation magnetization is preferably 1.0 T or more, and more preferably 1.5 T or more.

  Hereinafter, the present invention will be described more specifically with reference to examples. It should be noted that the components, ratios, operations, order, and the like shown here can be changed without departing from the spirit of the present invention, and should not be limited to the following examples. Further, “parts” in the examples represents parts by weight unless otherwise specified.

Example 1
<Inorganic powder silane coupling agent treatment>
Colloidal silica (methanol dispersion) (PL1-MA, manufactured by Fuso Chemical Industry Co., Ltd.) having an average primary particle size of 12 nm is heated to 80 ° C., butanol is added dropwise while evaporating methanol, solvent substitution is performed, and butanol dispersion sol Got.
Next, after adding 20% by weight of acetic acid to butanol sol, hexyltrimethoxysilane and acryloxypropyltrimethoxysilane were added to each colloidal silica (solid content) at 10% by weight for 2 hours. Surface treatment was performed by stirring at 130 ° C.
Next, the mixture was heated to 140 ° C., and cyclohexanone was dropped while evaporating butanol to obtain a cyclohexanone sol substituted with a solvent.

<Preparation of coating solution for radiation-cured layer>
The average pore size of the radiation-curable compound and cyclohexanone sol (solid content 15% by weight) shown in Table 1 were diluted with cyclohexanone and MEK so that the total solid content concentration was 20% by weight and stirred for 20 minutes. It filtered with a 0.1 micrometer filter and prepared the coating liquid for radiation hardening layers.

<Preparation of magnetic paint (magnetic layer coating solution)>
Ferromagnetic alloy powder (composition: Co 100 atomic%, Co 20 atomic%, Al 9 atomic%, Y 6 atomic%, Hc 175 kA / m, crystallite size 11 nm, BET specific surface area (S _BET ) 70 m ² / g, long axis length 45 nm, σs 111 emu / g) 100 parts by pulverization with an open kneader for 10 minutes, and then polyurethane resin solution (polyester polyurethane containing 70 μeq / g SO ₃ Na group, Tg = 100 ° C., Mw 70,000) 15 parts ( Kneaded for 60 minutes, then added 2 parts of abrasive (Al ₂ O ₃ , particle size 0.3 μm), 2 parts of carbon black (particle size 40 nm), 200 parts of methyl ethyl ketone / toluene = 1/1 sand mill For 360 minutes.
Add 2 parts of butyl stearate, 1 part of stearic acid and 50 parts of cyclohexanone, stir and mix for another 20 minutes, and then filter using a filter having an average pore size of 1 μm to obtain a magnetic paint (coating liquid for magnetic layer). Prepared.

<Preparation of nonmagnetic coating for lower layer (coating liquid for nonmagnetic layer)>
85 parts of α-Fe ₂ O ₃ (average particle size 0.15 μm, S _BET 52 m ² / g, surface-treated Al ₂ O ₃ , SiO ₂ , pH 6.5 to 8.0) was pulverized with an open kneader for 10 minutes, Subsequently, a compound obtained by adding hydroxyethyl sulfonate sodium salt to a copolymer of vinyl chloride / vinyl acetate / glycidyl methacrylate = 86/9/5 (SO ₃ Na = 6 × 10 ⁻⁵ eq / g, epoxy = 10 ⁻³ eq / g, Mw 30,000) and polyurethane resin solution (SO ₃ Na group-containing polyester polyurethane, Tg = 100 ° C., Mw 70,000) 10 parts (solid content), 60 parts cyclohexanone 60 parts Next, 200 parts of methyl ethyl ketone / cyclohexanone = 6/4 was added and dispersed in a sand mill for 120 minutes. Add 2 parts of butyl stearate, 1 part of stearic acid and 50 parts of methyl ethyl ketone, and further stir and mix for 20 minutes, and then filter using a filter having an average pore size of 1 μm to form a non-magnetic coating for the lower layer (for non-magnetic layer Coating solution) was prepared.

The coating for the radiation-cured layer is applied to the surface of a polyethylene terephthalate support having a thickness of 7 μm and a center average surface roughness Ra of 3.1 nm using a coil bar so that the thickness after drying is 0.5 μm. The film surface was irradiated with an electron beam with an acceleration voltage of 120 KV so that the absorbed dose was 20 KGy (kilo gray) and cured.
Then, after drying the non-magnetic coating material for the lower layer (non-magnetic layer coating solution) on the radiation-cured layer and further the magnetic coating material (coating solution for the magnetic layer) thereon, the thickness after drying becomes 0.5 μm and 0.1 μm, respectively. Thus, simultaneous multilayer coating was performed using a reverse roll. With magnetic coating in an undried state, magnetic field orientation is performed with a 5,000 gauss Co magnet and a 4,000 gauss solenoid magnet, and the solvent is dried to form a metal roll-metal roll-metal roll-metal roll-metal roll- After performing a calendar process by a combination of a metal roll and a metal roll (speed 100 m / min, linear pressure 300 kg / cm, temperature 90 ° C.), it was slit to 1/2 inch (12.7 mm) width.

(Examples 2-15, Comparative Examples 1-10)
It was produced in the same manner as in Example 1 except that the radiation curable compound and the inorganic powder were changed to those described in Table 1 or 2.
In addition, content of the inorganic powder surface-treated with the silane coupling agent is content (volume%) in the radiation-cured layer after curing.

Here, the surface treating agent and the radiation curable compound shown in Table 1 are as follows.
<Radiation curable compound>
EB4858: EBYCRYL4858 (manufactured by Daicel Cytec Co., Ltd.)
Urethane acrylate, number of functional groups 2, molecular weight 450, 7,000 mPa · s (25 ° C.), solubility parameter (SP value) 9.5 or more R604: 5-ethyl-2- (2-hydroxy-1,1′-dimethylethyl) ) -5- (Hydroxymethyl) -1,3-dioxane diacrylate (manufactured by Nippon Kayaku Co., Ltd.)

Ｄ３１０：ジペンタエリスリトールテトラアクリレートジプロピオネート（日本化薬（株）製）

D310: Dipentaerythritol tetraacrylate dipropionate (manufactured by Nippon Kayaku Co., Ltd.)

<Surface treatment of inorganic powder>
Acr-TMS: acryloxyalkyltrimethoxysilane (n = 3, 8)

Hex-TMS: Hexyltrimethoxysilane De-TMS: Decyltrimethoxysilane S-TMS: Stearyltrimethoxysilane Ph-TMS: Phenyltrimethoxysilane Hex-TES: Hexyltriethoxysilane Hex-TPS: Hexyltripropoxysilane

Here, the average particle diameter of the inorganic powder surface-treated with the silane coupling agent is a state of silica sol after the surface treatment with the silane coupling agent, and a concentrated particle size analyzer (FPAR-1000, manufactured by Otsuka Electronics Co., Ltd.) It measured using.
In addition, the content of the inorganic powder surface-treated with the silane coupling agent in the radiation-cured layer (processed inorganic powder) is FIB-cut the cross section of the obtained magnetic recording medium, and then the SEM observation of the radiation-cured layer is performed. The measurement was performed at 50,000 times and measured by image analysis.

(Measuring method)
The magnetic recording media produced in Examples 1-15 and Comparative Examples 1-10 were evaluated as follows.
(1) Smoothness On the surface of the magnetic layer, the center average roughness in an area of 250 μm × 250 μm was defined as Ra under the condition of a cutoff of 0.25 mm by optical interference using a digital optical profilometer.

(2) Electromagnetic conversion characteristics A recording head (MIG gap 0.15 μm, 1.8T) and a reproducing MR head were attached to a drum tester for measurement.
The reproduction output when measured at a relative speed of 1 to 3 m / min between the head and the medium and a surface recording density of 0.57 Gbit / inch ² (0.88 Mbit / mm ² ) was measured, and the relative value was set to 0 dB as Comparative Example 1. Indicated.

(3) Humidity expansion coefficient A sample obtained by cutting the tape 30 mm in the width direction and 5 mm in the longitudinal direction was set in a TMA apparatus and aged at 30 ° C. and 0 to 90% RH for 24 hours. After aging, the dimensional change in the TD direction at a temperature of 30 ° C. to 40 ° C. was measured, and the humidity expansion coefficient was determined by the following equation.
Humidity expansion coefficient = ((medium length at 90% RH−medium length at 0% RH) / medium length at 0% RH) / humidity change (90% RH−0% RH)
The TD direction means the width direction of the magnetic recording medium.
The unit of the temperature expansion coefficient is ppm / RH.

(4) Planarity The tape was observed with a differential interference microscope. Those with surface abnormalities such as repellency and cracks were considered defective, and those without repellency and cracks were considered excellent.

(5) Sliding edge damage The tape was repeatedly contacted at a sliding speed of 2 m / sec under a load of 100 g (T1) by bringing the magnetic layer surface into contact with an AlTiC cylindrical rod in a 40 ° C. and 10% RH environment. The tape edge after sliding to 000 passes was observed with an optical microscope and evaluated according to the following rank.
Excellent: No edge damage Good: There is edge damage but no radiation-cured layer is missing. Bad: Radiation-cured layer is missing.

Claims (3)

On a nonmagnetic support, a radiation-cured layer obtained by curing a layer containing a radiation-curable compound and an inorganic powder by irradiation, and a magnetic layer in which a ferromagnetic powder is dispersed in a binder are provided in this order. ,
The inorganic powder has an average particle size of 5 nm to 20 nm,
It is surface treated by the inorganic powder is two different silane coupling agents,
Of the two different silane coupling agents, it is one of (meth) acrylo trimethoxysilane, which another silane coupling agent is represented by formula (1),
The silane coupling agent represented by the formula (1) is contained in an amount of 20 to 80 parts by weight with respect to a total of 100 parts by weight of the two different types of silane coupling agents,
Content of the said inorganic powder in the said radiation hardening layer is 30 volume%-60 volume%, The magnetic recording medium characterized by the above-mentioned.
(X) _4-n- Si- (Y) _n (1)
Here, X is an alkyl group having 6 to 18 carbon atoms, a phenyl group, a (meth) acryloxy group, or a (meth) acryloxyalkyl group having 5 to 10 carbon atoms, and Y is OCH ₃ or OC ₂ H _5. Or OC ₃ H ₇ , and n is 2 or 3.   The radiation curable compound is a (meth) acrylic acid ester obtained by reacting a polyhydric alcohol with (meth) acrylic acid, and a urethane obtained by reacting a polyhydric alcohol with 2-isocyanatoethyl (meth) acrylate (meth) 2. The magnetic recording medium according to claim 1, wherein the magnetic recording medium is an acrylate or a compound obtained by reacting a diisocyanate compound or a terminal isocyanate prepolymer with hydroxyethyl (meth) acrylate or hydroxybutyl (meth) acrylate.   The magnetic recording medium according to claim 1, further comprising a nonmagnetic layer in which a nonmagnetic powder is dispersed in a binder between the radiation-cured layer and the magnetic layer.