JP5074247B2 - Red fish meat color preservation method and raw red fish meat - Google Patents
Red fish meat color preservation method and raw red fish meat Download PDFInfo
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Description
本発明は、肉色が褐色化しにくい生食用赤身魚肉、赤身魚肉の色調保持剤、及び赤身魚肉の色調保持方法に関する。 The present invention relates to a raw edible red fish meat whose meat color is not easily browned, a color preserver for red fish meat, and a method for maintaining the color tone of red fish meat.
切ったばかりのマグロの肉食は暗赤紫色をしている。これはマグロの筋肉色素ミオグロビンが、空気にふれていない時の色であるが、しばらく時間がたつと酸素とミオグロビンが結合し、鮮赤食に変化する。この状態のマグロが最もおいしそうに見え、商品価値が高い。しかし、さらに酸化が進むとオキシミオグロビンがメトミオグロビンに変化し、肉色が褐色になってしまう。これがメト化と呼ばれる現象であり、−35℃より温度が上がると急に進むようになる。家庭の冷凍庫の温度である−18℃程度では、冷凍保存している間にもメト化が進み、色が悪くなる。
このメト化の防止方法として、酸化防止剤、pH調整剤の使用等、種々の方法が提案されている(特許文献1〜3等参照)。
Freshly cut tuna carnivores are dark reddish purple. This is the color when tuna muscle pigment myoglobin is not exposed to the air, but after a while, oxygen and myoglobin combine and change to a fresh red diet. The tuna in this state looks the most delicious and has a high commercial value. However, as oxidation proceeds further, oxymyoglobin changes to metmyoglobin, and the meat color becomes brown. This is a phenomenon referred to as methotization, and proceeds rapidly when the temperature rises above -35 ° C. At about −18 ° C., which is the temperature of a freezer in a home, mettosis progresses even during freezing and the color becomes worse.
Various methods such as the use of an antioxidant and a pH adjuster have been proposed as methods for preventing this methotrelation (see Patent Documents 1 to 3, etc.).
本発明は、メト化あるいは褐色化しにくい、色調の保持された赤身魚肉を提供することを課題とする。 An object of the present invention is to provide a red fish meat having a color tone that is difficult to be methed or browned.
本発明は、(1)〜(5)の生食用赤身魚肉を要旨とする。
(1)アルカリ化剤及び二酸化ケイ素を添加した生食用赤身魚肉。
(2)魚肉のpHが6〜7になる量のアルカリ化剤と0.0125〜2.0重量%の二酸化ケイ素を添加した生食用赤身魚肉。
(3)さらに酸化防止剤を添加した(1)又は(2)の生食用赤身魚肉。
(4)赤身魚肉がマグロである(1)ないし(3)いずれかの生食用赤身魚肉。
(5)赤身魚肉がミンチ状魚肉である(1)ないし(4)いずれかの生食用赤身魚肉。
The gist of the present invention is the raw edible red fish meat of (1) to (5).
(1) Raw red fish meat to which an alkalizing agent and silicon dioxide are added.
(2) Raw red fish meat to which an alkalinizing agent in an amount that makes the pH of the fish meat 6 to 7 and 0.0125 to 2.0% by weight of silicon dioxide are added.
(3) The raw edible red fish meat according to (1) or (2), further added with an antioxidant.
(4) The red fish meat for raw consumption according to any one of (1) to (3), wherein the red fish meat is tuna.
(5) The red fish meat for raw consumption according to any one of (1) to (4), wherein the red fish meat is minced fish meat.
本発明は、(6)〜(7)の赤身魚肉の色調保持剤を要旨とする。
(6)アルカリ化剤及び二酸化ケイ素を含有する赤身魚肉の色調保持剤。
(7)さらに酸化防止剤を含有する(6)の色調保持剤。
The gist of the present invention is the color retention agent for red fish meat according to (6) to ( 7 ).
( 6 ) A color tone preserving agent for red fish meat containing an alkalizing agent and silicon dioxide.
( 7 ) The color-holding agent according to ( 6 ), further comprising an antioxidant.
本発明は、(8)〜(9)の赤身魚肉の色調保持方法を要旨とする。
(8)(6)又は(7)の色調保持剤を赤色魚肉に添加することを特徴とする赤身魚肉の色調保持方法。
(9)赤身魚肉に対して魚肉のpHが6〜7になる量のアルカリ化剤と0.0125〜2.0重量%の二酸化ケイ素を添加することを特徴とする赤身魚肉の色調保持方法。
The gist of the present invention is the method for maintaining the color tone of red fish meat according to any one of ( 8 ) to ( 9 ).
( 8 ) A method for maintaining the color tone of red fish meat, which comprises adding the color tone retention agent of (6) or (7) to red fish meat.
( 9 ) A method for maintaining the color tone of red fish meat, comprising adding an alkalizing agent in an amount such that the pH of the fish meat is 6 to 7 and 0.0125 to 2.0% by weight of silicon dioxide relative to the red fish meat.
本発明の生食用赤色魚肉は保存中の色調変化が抑制されており、通常の冷凍品の流通温度である−18℃前後で保存した場合にも、肉色の褐色化が遅く、長期の保存が可能である。 The raw red fish meat of the present invention has suppressed color change during storage, and even when stored at around −18 ° C., which is the distribution temperature of ordinary frozen products, browning of the meat color is slow and long-term storage is possible. Is possible.
本発明の赤身魚肉とは、マグロ、ブリ、アジ、イワシなどの魚肉、血合い部分などにミオグロビンを多く含む、通常赤い色調を有する赤身魚に属する魚の肉である。これらの魚肉では、ミオグロビンによる赤色が酸化により褐色に変色してしまうのが、品質上の問題となっている。本発明によりこの色調の変化を抑制することができる。特に刺身、ネギトロなどのような生食用の魚肉を冷凍保存する場合に有用である。マグロを例にすると、マグロは天然物でも養殖物でも良いが、漁獲後すぐ処理するのでなければ、−50℃以下で凍結保存された鮮度、色調の保持されたものを用いる。 The red fish meat of the present invention is a fish meat belonging to a red fish that usually has a red color tone and contains a large amount of myoglobin in fish such as tuna, yellowtail, horse mackerel, and sardines, and bloody portions. In these fish meats, the red color caused by myoglobin turns brown due to oxidation, which is a quality problem. According to the present invention, this change in color tone can be suppressed. This is particularly useful when freezing raw meat such as sashimi and negito. Taking tuna as an example, tuna may be a natural product or a cultured product, but if not processed immediately after catching, tuna that has been stored frozen at -50 ° C. or lower and that retains its color tone is used.
本発明において二酸化ケイ素とは、食品添加物として用いることのできる二酸化ケイ素であり、例えば、微粒二酸化ケイ素、微粒シリカゲルである。これらは食品に2%以下の添加が認められている。二酸化ケイ素の添加量は魚肉に対して0.0125〜2.0重量%であり、好ましくは、0.1〜1.0重量%である。 In the present invention, silicon dioxide is silicon dioxide that can be used as a food additive, for example, fine silicon dioxide and fine silica gel. The addition of 2% or less of these to food is permitted. The addition amount of silicon dioxide is 0.0125 to 2.0% by weight, preferably 0.1 to 1.0% by weight, based on the fish meat.
本発明においてアルカリ化剤とは魚肉のpHを調整するために用いるので、食品に添加することができるアルカリ化剤であれば何でも構わない。アルカリ化剤の強度によって使用量を調節する。アルカリ化剤としては、炭酸水素ナトリウム、炭酸ナトリウム、有機酸塩類などが例示されるが、弱アルカリであり、食品添加物として使用しやすい炭酸水素ナトリウム、炭酸ナトリウムが好ましい。魚肉のpHが6〜7、好ましくは6.3〜6.9になる用量のアルカリ化剤を魚肉に添加する。
例えば、pHを6〜7にするためには、用いるアルカリ化剤によるが魚肉重量あたり、およそ0.2〜1.0重量%添加する。例えば、炭酸水素ナトリウムであれば、刺身重量あたり、0.3〜0.8重量%、炭酸ナトリウムであれば、0.2〜0.6重量%添加するのが好ましい。味に影響しない範囲であれば、pHを高めにするほど、褐色化を防ぐ効果は高い。炭酸水素ナトリウムは濃度を高くすると苦味がでてくる。また、炭酸ナトリウムは臭みがでる。これらがでない範囲で使用する。
In the present invention, the alkalinizing agent is used to adjust the pH of fish meat, so any alkalinizing agent that can be added to foods may be used. The amount used is adjusted according to the strength of the alkalizing agent. Examples of the alkalizing agent include sodium hydrogen carbonate, sodium carbonate, organic acid salts, and the like, but sodium hydrogen carbonate and sodium carbonate which are weak alkalis and can be easily used as food additives are preferable. A dose of alkalinizing agent is added to the fish meat so that the pH of the fish meat is 6-7, preferably 6.3-6.9.
For example, in order to adjust the pH to 6 to 7, depending on the alkalizing agent to be used, about 0.2 to 1.0% by weight is added per fish weight. For example, it is preferable to add 0.3 to 0.8% by weight per sashimi weight for sodium bicarbonate and 0.2 to 0.6% by weight for sodium carbonate. If it is a range which does not affect a taste, the effect which prevents browning is so high that pH is made high. Sodium bicarbonate has a bitter taste when the concentration is increased. Sodium carbonate also has a smell. Use as long as these are not.
さらに、酸化防止剤を添加することにより、油脂の酸化も抑えることができ、褐色化も抑制され、保存性が高まる。酸化防止剤としては、食品に使用することができる安全で、味に影響しないものであれば何でも使用でき、アスコルビン酸、トコフェロール、カテキン類などが例示される。好ましくは、カテキン類、トコフェロールを用いる。特にトコフェロールは褐色化防止に有効である。酸化防止剤は、用いるものによるがおよそ0.01〜1.0重量%用いる。例えば、トコフェロールであれば、0.02〜0.3重量%程度が好ましい。 Furthermore, by adding an antioxidant, the oxidation of fats and oils can be suppressed, browning is also suppressed, and storage stability is enhanced. Any antioxidant can be used as long as it is safe and can be used for foods without affecting the taste, and examples thereof include ascorbic acid, tocopherol, and catechins. Preferably, catechins and tocopherol are used. In particular, tocopherol is effective in preventing browning. The antioxidant is used in an amount of about 0.01 to 1.0% by weight depending on what is used. For example, in the case of tocopherol, about 0.02 to 0.3% by weight is preferable.
本発明において赤身魚肉への二酸化ケイ素、アルカリ化剤の添加方法は、ネギトロのようなミンチ状の魚肉であれば、粉末あるいは水に混ぜて、混合撹拌する。また、刺身のような切り身であれば、水溶液にして浸漬、注入するか、粉末あるいは水に混ぜて、表面に噴霧、塗布などする。魚肉の表面を本発明の色調保持剤が覆う状態にできればどんな方法で添加してもよい。 In the present invention, the method of adding silicon dioxide and an alkalizing agent to red fish meat is mixed and stirred in powder or water if it is minced fish meat such as Negitro. In the case of a slice such as sashimi, it is immersed in an aqueous solution and poured, or mixed with powder or water and sprayed or applied to the surface. Any method may be used as long as the surface of the fish meat is covered with the color tone-retaining agent of the present invention.
以下に本発明の実施例を記載するが、本発明はこれらに何ら限定されるものではない。 Examples of the present invention will be described below, but the present invention is not limited thereto.
二酸化ケイ素の赤身魚肉の色調保持作用
冷凍まぐろ赤身肉を−5℃まで解凍し、サイレントカッターで約1分間カットしミンチ状にした。続いて、表1に示す配合(重量比率)でネギトロを作製した。油脂以外の各添加物は水溶液として添加し、続いて油脂を添加し、混合した。作製したネギトロは−40℃で凍結した。凍結したネギトロを−18℃で0〜120日保存した。保存後の各検体を室温で解凍した後、15℃保管中の経時変化を48時間まで確認し、メト化進行の程度を確認した。
使用した添加物は、炭酸ナトリウム(株式会社トクヤマ製、ソーダ灰ライト)、乳糖(Fronterra co-operative group ltd.製USP200 mesh)、ソルビット(日研化学株式会社製、ソルビトールFP50M)、デキストリン(三和澱粉工業株式会社製、サンデックス#70D)、微粒二酸化ケイ素(富士シリシア化学株式会社製、サイロページ720)である。
Maintaining the color tone of red meat of silicon dioxide Frozen tuna red meat was thawed to −5 ° C., cut with a silent cutter for about 1 minute, and minced. Subsequently, Negitro was prepared with the formulation (weight ratio) shown in Table 1. Each additive other than fats and oils was added as an aqueous solution, and then fats and oils were added and mixed. The prepared Negitro was frozen at -40 ° C. Frozen Negitro was stored at -18 ° C for 0-120 days. Each specimen after storage was thawed at room temperature, and then the change with time during storage at 15 ° C. was confirmed up to 48 hours, and the degree of progress of metrification was confirmed.
Additives used were sodium carbonate (Tokuyama Co., Ltd., soda ashlite), lactose (USP200 mesh manufactured by Fronterra co-operative group ltd.), Sorbit (Niken Chemical Co., Ltd., sorbitol FP50M), dextrin (Sanwa) Starch Kogyo Co., Ltd., Sandex # 70D), fine silicon dioxide (Fuji Silysia Chemical Co., Ltd., silo page 720).
目視による官能検査の結果を表2に示した。他の添加物と比較して、微粒二酸化ケイ素添加によりメト化が大きく抑制された。特に過酷な保存条件である−18℃において明らかな差が認められた。30日保管では解凍後24時間後でも評価4であり、60日保管しても解凍直後であれば、評価4であった。 Table 2 shows the results of visual sensory inspection. Compared with other additives, the addition of fine silicon dioxide significantly suppressed methation. In particular, a clear difference was observed at -18 ° C, which is a severe storage condition. In the case of storage for 30 days, the evaluation was 4 even 24 hours after thawing, and the evaluation was 4 if it was stored for 60 days and immediately after thawing.
微粒二酸化ケイ素の添加量
二酸化ケイ素の効果を添加量を変えて確認した。
冷凍まぐろ赤身肉を−5℃まで解凍し、サイレントカッターで約1分間カットしミンチ状にした。続いて、表3に示す配合(重量比率)でネギトロを作製した。油脂以外の各添加物は水溶液として添加し、続いて油脂を添加し、混合した。作製したネギトロは−40℃で凍結し、−40℃で2日間保管した。保存後のネギトロを室温で解凍した後、15℃保管中の経時変化を48時間まで確認し、メト化進行の程度を確認した。用いた添加物は実施例1と同じ製品である。
Addition amount of fine silicon dioxide The effect of silicon dioxide was confirmed by changing the addition amount.
The frozen tuna red meat was thawed to −5 ° C., cut with a silent cutter for about 1 minute, and minced. Subsequently, Negitro was prepared with the formulation (weight ratio) shown in Table 3. Each additive other than fats and oils was added as an aqueous solution, and then fats and oils were added and mixed. The prepared Negitro was frozen at −40 ° C. and stored at −40 ° C. for 2 days. After thawing Negitro after storage at room temperature, the time-dependent change during storage at 15 ° C. was confirmed up to 48 hours, and the degree of progress of methonation was confirmed. The additive used is the same product as in Example 1.
目視による官能検査の結果を表4に示す。微粒二酸化ケイ素は低用量でも効果を示し、特に0.1%〜1.0%の添加量で優れた結果であった。 Table 4 shows the results of the visual sensory test. Finely divided silicon dioxide was effective even at low doses, particularly excellent results with additions of 0.1% to 1.0%.
本発明の色調保持剤を添加した赤身魚肉は、通常の冷凍品の流通温度での褐色化が抑制されているので、商品価値が高く、保存期間も延長することができる。長期保存可能なマグロのネギトロなどを提供することができる。 The red fish meat added with the color-holding agent of the present invention has high commercial value because the browning at the distribution temperature of ordinary frozen products is suppressed, and the storage period can be extended. It is possible to provide tuna negitoro that can be stored for a long time.
Claims (9)
A method for maintaining the color tone of red fish meat, comprising adding an alkalinizing agent in an amount such that the pH of the fish meat is 6 to 7 and 0.0125 to 2.0% by weight of silicon dioxide relative to the red fish meat.
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