JP5063901B2 - Thermoplastic resin composition - Google Patents

Description

  The present invention relates to a thermoplastic resin composition comprising a thermoplastic resin that does not form an anisotropic molten phase and a liquid crystalline polymer that can form an anisotropic molten phase.

  In recent years, there has been a remarkable increase in functionality and performance of digital devices such as mobile phones, digital cameras, and mobile terminals. A structure common to these devices includes a liquid crystal display and an information recording medium.

  In general, a liquid crystal display (LCD) is composed of an LCD panel composed of a glass substrate, a transparent electrode, a liquid crystal, and a color filter, and a backlight ling. ) To provide a reflector, a fluorescent lamp, a light guide panel, a diffusion sheet, a prism sheet and the function of the reflector while supporting the whole It consists of two main parts of a backlight unit comprising a backlight frame. The said back light frame has the shape by which the opening part was provided in the rectangular-shaped surface on the function. The larger the ratio of the openings, the larger the area of the liquid crystal surface relative to the size of the liquid crystal display itself. Further, the thinner the rectangular surface, the thinner the liquid crystal display itself. For this reason, the ratio of the openings is larger, and the thickness of the rectangular surface is generally reduced.

  In addition, various types of information recording media such as SD cards, compact flashes, smart media, and memory sticks are available. These information recording media are small in size and have a high recording capacity with a memory capacity exceeding several MB.

  These information recording media can still be realized in a compact size, but in the future, it will be essential to reduce the recording media mounting space by increasing the functionality, performance and miniaturization of devices that use recording media. There is a need for further downsizing and thinning.

  As described above, materials used for liquid crystal display components and information recording media are required to have high fluidity, rigidity, and impact resistance so that the functions can be effectively performed even though the thickness is small. It should also have heat resistance, dimensional stability and flame retardance that can withstand the heat generated by the backlight. As a material having such characteristics, a polycarbonate resin has been representative so far.

  Polycarbonate resin has superior low-temperature impact resistance, self-extinguishing properties, electrical properties, transparency, dimensional stability and thermal stability compared to other resins. As engineering plastics, office automation equipment, It has been used extensively in electrical and electronic products. However, since the polycarbonate resin has low fluidity, there is an increasing number of situations in which it cannot cope with frames and information recording media that are becoming thinner. In order to compensate for such low fluidity, high-temperature processing and high-speed high-pressure processing are applied during injection molding. The range is limited.

  On the other hand, as a technique for improving fluidity from the viewpoint of materials, alloying of polycarbonate resin and ABS resin has been studied. For example, in Patent Document 1, polycarbonate / ABS excellent in molding processability is obtained by blending a polycarbonate resin, an ABS graft copolymer, and two kinds of acrylonitrile / styrene copolymers having a specified molecular weight distribution at a specific ratio. Although it has been shown that an alloy composition can be obtained, its heat resistance is not sufficient.

In addition, as shown in Patent Document 2, a resin composition in which a liquid crystalline resin is blended with a polycarbonate resin exhibits good thin-wall moldability, but if the blending ratio is not examined, the weld portion breaks down due to a decrease in weld strength. In addition, since it causes peeling of the surface layer of the molded product, the function as a product cannot be satisfied.
JP 11-293102 A JP 2002-249656 A

  The present invention solves the problems of the prior art, has high fluidity, has high dimensional stability such as no deformation after molding, is excellent in rigidity, impact resistance, heat resistance, etc., and has a thickness. An object of the present invention is to provide a thermoplastic resin composition that can effectively perform functions as a liquid crystal display component or a recording medium even though it is thin.

  In order to achieve the above object, the present inventors have intensively searched for and studied a material having high flow, high rigidity and high heat resistance, and as a result, thermoplasticity which does not form an anisotropic melt phase exhibiting a specific melt viscosity. A specific amount of liquid crystalline polymer is added to the resin, a specific phosphorus oxoacid monoester or diester is added, and the melt viscosity ratio between the thermoplastic resin and the liquid crystalline polymer can be controlled within a specific range, thereby reducing the thickness. The inventors have found that this is possible and have completed the present invention.

That is, the present invention
(A) Thermoplastic resin that does not form an anisotropic melt phase with a melt viscosity of 100 to 300 Pa · s as measured by a capillary rheometer at 300 ° C and a shear rate of 1000 sec ^-1 using a nozzle with an inner diameter of 1 mm and a length of 20 mm 91-99% by weight and
(B) 100 parts by weight of a resin composition comprising 1 to 9% by weight of a liquid crystalline polymer capable of forming an anisotropic molten phase,
(C) 0.001 to 2 parts by weight of one or more selected from the phosphorooxo acid monoesters and diesters represented by the following general formulas (I) and (II): (B) Liquid crystalline polymer is dispersed in particles. A thermoplastic resin composition,
The melt viscosity ratio (Aη) / (Bη) of the component (A) and the component (B) is 3.2 by capillary rheometer measurement using a nozzle with an inner diameter of 1 mm and a length of 20 mm at 300 ° C. and a shear rate of 1000 sec ^−1. It is -4.0, It is a thermoplastic resin composition characterized by the above-mentioned.

(X) _n P (= O) (OR) _3-n (I)
(X) _n P (OR) _3-n (II)
[Wherein, n is 1 or 2, X is a hydrogen atom, a hydroxyl group, or a monovalent organic group, and a plurality of them may be the same or different. R 2 is a monovalent or divalent organic group, and in a plurality of cases, they may be the same or different. ]

Hereinafter, the present invention will be described in detail. The thermoplastic resin (A) that does not form an anisotropic melt phase used in the present invention needs to be a thermoplastic resin that can be melt-processed at 300 ° C. Specifically, melt processing at 300 ° C means that the melt viscosity is 100 to 300 Pa · s as measured by a capillary rheometer at 300 ° C and a shear rate of 1000 sec ^-1 using a nozzle with an inner diameter of 1 mm and a length of 20 mm. It means that processing can be performed without satisfying the range and deteriorating to an unacceptable property.

  Examples of the thermoplastic resin (A) include polyolefin (co) polymers such as polyethylene, polypropylene and poly-4-methyl-1-pentene, polyester resins such as polyethylene terephthalate resin, polybutylene terephthalate resin and polycarbonate resin. , Polyamide resins, ABS resins, polyarylene sulfide resins, polyacrylates, and resins mainly composed of these resins. Among these, polyester resins such as polyethylene terephthalate resin, polybutylene terephthalate resin, and polycarbonate resin are preferable, and polycarbonate resins having relatively low molding shrinkage and linear expansion are particularly preferable.

  In the present invention, the polycarbonate resin preferably used as the thermoplastic resin (A) is an aromatic homopolymer having a carbonate structure and obtained by reacting an aromatic dihydric phenol compound with phosgene or carbonic acid diester. Or a copolycarbonate is mentioned. Here, examples of the aromatic dihydric phenol compound include 2,2-bis (4-hydroxyphenyl) propane, 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane, and bis (4-hydroxy). Phenyl) butane, 1,1-bis (4-hydroxyphenyl) ethane, 2,2-bis (4-hydroxyphenyl) butane, 2,2-bis (4-hydroxy-3,5-diphenyl) butane, 2, 2-bis (4-hydroxy-3,5-diethylphenyl) propane, 1,1-bis (4-hydroxyphenyl) cyclohexane, 1-phenyl-1,1-bis (4-hydroxyphenyl) ethane, etc. can be used. These can be used alone or as a mixture. Of these, 2,2-bis (4-hydroxyphenyl) propane is preferred.

  The liquid crystalline polymer (B) used in the present invention refers to a melt processable polymer having a property capable of forming an optically anisotropic melt phase, and the polymer molecular chains are regularly formed by receiving shear stress in the molten state. It has the property of taking a parallel arrangement. Such polymer molecules are generally elongated, flat, fairly rigid along the long axis of the molecule, and have a plurality of chain extension bonds that are usually either coaxial or parallel. It is. The property of the anisotropic molten phase can be confirmed by a conventional polarization inspection method using an orthogonal polarizer. More specifically, the anisotropic molten phase can be confirmed by using a Leitz polarizing microscope and observing a molten sample placed on a Leitz hot stage under a nitrogen atmosphere at a magnification of 40 times. When the liquid crystalline polymer applicable to the present invention is inspected between crossed polarizers, the polarized light is normally transmitted even in the molten stationary state, and optically anisotropic.

  The liquid crystalline polymer (B) is not particularly limited, but is preferably an aromatic polyester or an aromatic polyester amide, and is an aromatic polyester or a polyester partially containing the aromatic polyester amide in the same molecular chain. Is also in that range. They preferably have a logarithmic viscosity (IV) of at least about 2.0 dl / g, more preferably 2.0-10.0 dl / g when dissolved in pentafluorophenol at 60 ° C. at a concentration of 0.1% by weight. .) Are used.

  The aromatic polyester or aromatic polyester amide as the liquid crystalline polymer (B) applicable to the present invention is particularly preferably at least one selected from the group consisting of aromatic hydroxycarboxylic acids, aromatic hydroxyamines and aromatic diamines. An aromatic polyester or aromatic polyester amide having the above compound as a constituent component.

More specifically,
(1) A polyester mainly composed of one or more aromatic hydroxycarboxylic acids and derivatives thereof;
(2) mainly (a) one or more of aromatic hydroxycarboxylic acids and derivatives thereof; and (b) one or more of aromatic dicarboxylic acids, alicyclic dicarboxylic acids and derivatives thereof; c) Polyester comprising at least one or more of aromatic diol, alicyclic diol, aliphatic diol and derivatives thereof;
(3) mainly (a) one or more aromatic hydroxycarboxylic acids and derivatives thereof; (b) one or more aromatic hydroxyamines, aromatic diamines and derivatives thereof; and (c). A polyesteramide comprising one or more of aromatic dicarboxylic acid, alicyclic dicarboxylic acid and derivatives thereof;
(4) mainly (a) one or more aromatic hydroxycarboxylic acids and derivatives thereof; (b) one or more aromatic hydroxyamines, aromatic diamines and derivatives thereof; and (c). One or more of aromatic dicarboxylic acid, alicyclic dicarboxylic acid and derivatives thereof; and (d) at least one or more of aromatic diol, alicyclic diol, aliphatic diol and derivatives thereof, and The polyesteramide which consists of, etc. are mentioned. Furthermore, you may use a molecular weight modifier together with said structural component as needed.

  Preferred examples of the specific compound constituting the liquid crystalline polymer (B) applicable to the present invention include aromatic hydroxycarboxylic acids such as p-hydroxybenzoic acid and 6-hydroxy-2-naphthoic acid, 2,6- Aromatic diols such as dihydroxynaphthalene, 1,4-dihydroxynaphthalene, 4,4′-dihydroxybiphenyl, hydroquinone, resorcinol, compounds represented by the following general formula (V) and the following general formula (VI); terephthalic acid, isophthal Aromatic dicarboxylic acids such as acids, 4,4′-diphenyldicarboxylic acid, 2,6-naphthalenedicarboxylic acid and compounds represented by the following general formula (VII); aromatics such as p-aminophenol and p-phenylenediamine Examples include amines.

(However, X: alkylene (C ₁ ~C _4), alkylidene, -O-, -SO -, - SO 2 -, -S -, - CO- than group selected, Y :-( CH _{2) n} - (a group selected from n = 1 to 4) and —O (CH ₂ ) _n O— (n = 1 to 4))
A particularly preferred liquid crystalline polymer (B) to which the present invention is applied is an aromatic polyester containing p-hydroxybenzoic acid and 6-hydroxy-2-naphthoic acid as main structural unit components.

  The molded product in which the liquid crystalline polymer (B) is micro-dispersed in the form of fibers or needles in the matrix phase of the thermoplastic resin (A) is kneaded with an ordinary extruder, and the liquid crystalline polymer (B) is thermoplastic resin. If the thermoplastic resin composition in which particles are dispersed in the matrix phase of (A) is injection-molded, it can be obtained by the shearing force at that time, but the proportion of the liquid crystalline polymer (B) is larger than that of the thermoplastic resin (A). In some cases, the matrix phase is inverted, and even if the matrix phase is not inverted, if the amount of the liquid crystalline polymer (B) is large, the amount of the liquid crystalline polymer present in the weld part of the molded product increases. This is not preferable because it causes a decrease in weld strength. Further, as described above, it is important for the purpose of reinforcing the thermoplastic resin (A) that the liquid crystalline polymer (B) is dispersed in a fibrous form in the thermoplastic resin (A). It is not preferable that the liquid crystalline polymer (B) has a fibrous structure in the vicinity of the surface layer because it causes surface layer peeling.

In order to solve this problem, it is necessary that the liquid crystalline polymer (B) has a particulate dispersion state in the vicinity of the surface layer of the molded product and exhibits a fibrous dispersion state inside the molded product. In order to satisfy all of such thin-wall fluidity, rigidity, weld strength, and surface peeling, it is necessary to control the melt viscosity of the thermoplastic resin (A) and the amount of the liquid crystal polymer (B) very strictly. There is. Therefore, in the present invention, the melt viscosity of the thermoplastic resin (A) is 100 to 300 Pa · s in capillary rheometer measurement using a nozzle having an inner diameter of 1 mm and a length of 20 mm at 300 ° C. and a shear rate of 1000 sec ^−1. , Preferably 160 to 180 Pa · s, and the blending amount of the liquid crystalline polymer (B) is 1 to 9% by weight with respect to 91 to 99% by weight of the thermoplastic resin (A). is necessary. When the melt viscosity of the thermoplastic resin (A) is less than 100 Pa · s, the weld strength is inferior, and when it exceeds 300 Pa · s, surface peeling may occur. Further, if the blending amount of the liquid crystalline polymer (B) is less than 1% by weight, the desired thin-wall fluidity cannot be obtained, and if it exceeds 9% by weight, problems occur in weld strength and surface layer peeling.

  When the thermoplastic resin (A) is a polycarbonate resin, the preferred viscosity average molecular weight is 17500-18900.

In addition, the melt viscosity ratio of component (A) and component (B) is also important. Using a nozzle with an inner diameter of 1 mm and a length of 20 mm, melting by capillary rheometer measurement at 300 ° C and a shear rate of 1000 sec ^-1 is used. When the viscosity ratio (Aη) / (Bη) is in the range of 3.2 to 4.0, both the thin wall fluidity, the weld strength, and the surface layer peeling can be achieved.

  Furthermore, in the present invention, as described above, it is necessary to add a phosphorus compound in order to fiberize the liquid crystalline polymer (B) during molding. In particular, when the thermoplastic resin (A) that does not form an anisotropic molten phase is a polycarbonate resin, the liquid crystalline polymer and the polycarbonate resin do not disperse in an island shape and may not be fiberized even by injection molding. The effect is remarkable. Examples of the phosphorus compound include phosphorus oxo acid monoester and diester (C), which are substances represented by the following general formulas (I) and (II).

(X) _n P (= O) (OR) _3-n (I)
(X) _n P (OR) _3-n (II)
[Wherein, n is 1 or 2, X is a hydrogen atom, a hydroxyl group, or a monovalent organic group, and a plurality of them may be the same or different. R 2 is a monovalent or divalent organic group, and in a plurality of cases, they may be the same or different. ]
In general, phosphonate compounds, phosphinate compounds, phosphonite compounds, phosphinite compounds, and organophosphorus compounds containing these structural elements in the molecule are applicable.

  Specific examples of phosphonate compounds include dimethyl phosphonate, diethyl phosphonate, dibutyl phosphonate, di (ethylhexyl) phosphonate, didecyl phosphonate, dipalmityl phosphonate, distearyl phosphonate, dilauryl phosphonate, diphenyl phosphonate, dibenzyl phosphonate, ditoluyl Phosphonate, di (nonylphenyl) phosphonate, dioleyl phosphonate, dimethylmethylphosphonate, diethylmethylphosphonate, di (ethylhexyl) methylphosphonate, dipalmitylmethylphosphonate, distearylmethylphosphonate, dilaurylmethylphosphonate, diphenylmethylphosphonate, dimethylphenyl Phosphonate, diethylphenylphosphonate, di (ethylhexyl ) Phenyl phosphonate, dipalmityl phosphonate, distearyl phosphonate, dilauryl phosphonate, diphenyl phenyl phosphonate, dibenzyl phosphonate and the like.

  Specific examples of the phosphinate compound include, for example, methyl phosphinate, ethyl phosphinate, butyl phosphinate, ethyl hexyl phosphinate, palmityl phosphinate, stearyl phosphinate, lauryl phosphinate, phenyl phosphinate, benzyl phosphinate, toluyl phosphinate, Nonylphenyl phosphinate, oleyl phosphinate, ethyl methyl phosphinate, ethyl dimethyl phosphinate, (ethyl hexyl) methyl phosphinate, (ethyl hexyl) dimethyl phosphinate, palmityl methyl phosphinate, palmityl dimethyl phosphinate, stearyl methyl phosphinate, Stearyl dimethyl phosphinate, lauryl methyl phosphinate, lauryl dimethyl phosphite Phenate, phenylmethyl phosphinate, ethyl phenyl phosphinate, (ethylhexyl) phenyl phosphinate, palmityl phenyl phosphinate, stearyl phenyl phosphinate, stearyl diphenyl phosphinate, lauryl phenyl phosphinate, lauryl diphenyl phosphinate, phenyl phenyl phosphinate, Examples thereof include benzyl phenyl phosphinate.

  Specific examples of the phosphonite compound include, for example, dimethyl phosphonite, diethyl phosphonite, dibutyl phosphonite, di (ethylhexyl) phosphonite, didecyl phosphonite, dipalmityl phosphonite, distearyl phosphonite, dilauryl phosphonite, diphenyl phosphonite. Knight, Dibenzylphosphonite, Ditoluylphosphonite, Di (nonylphenyl) phosphonite, Dioleylphosphonite, Dimethylmethylphosphonite, Diethylmethylphosphonite, Di (ethylhexyl) methylphosphonite, Dipalmitylmethylphosphonite, Di Stearylmethylphosphonite, dilaurylmethylphosphonite, diphenylmethylphosphonite, dimethylphenylphosphonite, diethylphenylphosphonite, di (ethylhexyl) ) Phenyl phosphonite, dipalmityl phenyl phosphonite, distearyl phenyl phosphonite, dilauryl phenyl phosphonite, diphenyl phenyl phosphonite, dibenzyl phenyl phosphonite, and the like.

  Specific examples of the phosphinite compound include, for example, methyl phosphinite, ethyl phosphinite, butyl phosphinite, ethylhexyl phosphinite, palmityl phosphinite, stearyl phosphinite, lauryl phosphinite, phenyl phosphinite, Benzylphosphinite, toluylphosphinite, nonylphenylphosphinite, oleylphosphinite, ethylmethylphosphinite, ethyldimethylphosphinite, (ethylhexyl) methylphosphinite, (ethylhexyl) dimethylphosphinite, pal Methyl methylphosphinite, palmityl dimethylphosphinite, stearylmethylphosphinite, stearyldimethylphosphinite, laurylmethylphosphinite, lauryldimethylphosphine Nite, phenylmethylphosphinite, ethylphenylphosphinite, (ethylhexyl) phenylphosphinite, palmitylphenylphosphinite, stearylphenylphosphinite, stearyldiphenylphosphinite, laurylphenylphosphinite, lauryldiphenylphosphine Examples thereof include finite, phenylphenylphosphinite, and benzylphenylphosphinite. Among these, phosphonic acid esters represented by the general formula (III) are particularly preferably used.

H (OH) _m P (= O) (OR ') _2-m (III)
[Wherein, m is 0 or 1 and R ′ is a monovalent organic group. ]
As the phosphorus compound (C), an organic phosphorus compound containing the above-described phosphonate, phosphinate, phosphonite, or phosphinite structural element in the molecule can also be used. Specific examples thereof include the following compounds.

  The amount of the specific phosphorus compound (C) is 0.001 to 2 to 100 parts by weight of a resin composition comprising (A) 91 to 99% by weight of a thermoplastic resin and (B) 1 to 9% by weight of a liquid crystalline polymer. Part by weight, particularly preferably 0.01 to 0.5 part by weight. If the blending amount is less than 0.001 part by weight, the effect of making the liquid crystalline polymer being molded into a fiber is small, and if the blending amount exceeds 2 parts by weight, the material properties are rather lowered.

  In addition, additives such as nucleating agents, pigments such as carbon black, antioxidants, stabilizers, plasticizers, lubricants, mold release agents and flame retardants are added to the thermoplastic resin composition to achieve desired properties. The imparted composition is also included in the thermoplastic resin composition referred to in the present invention.

  In order to produce such a thermoplastic resin composition, each component may be blended in the above composition ratio and kneaded. Usually, it is kneaded with an extruder, extruded into a pellet, and used for injection molding or the like, but is not limited to extrusion with such an extruder. The information recording medium component of the present invention is easily molded from the composite resin composition by a normal molding method, for example, injection molding.

  The molded product thus obtained is (A) a molded product in which (B) liquid crystalline polymer is dispersed in an island shape in a thermoplastic resin, and in particular, (B) liquid crystalline polymer in the surface layer portion within 50 μm from the surface of the molded product. The average major axis of the particles is 30 μm or less, and even if it is thin, it has sufficient fluidity to fill the mold. It can be formed without any problem without causing peeling of the skin layer, and it does not cause torsional deformation. In addition, the number of gates can be reduced as compared with the conventional products by taking advantage of the excellent moldability, so that the weight of the runner can be reduced and it can be said that it is extremely economical.

  For this reason, it is most suitable as a material for liquid crystal display parts or information recording medium parts, which are becoming increasingly thin in recent years, including TV monitors, digital cameras, camera-integrated VTRs, mobile phones, PDAs, notebook computers, etc. This is useful for personal digital assistants.

EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the present invention is not limited thereto.
Examples 1-5
First, two types of polycarbonate resins (manufactured by Teijin Chemicals Ltd., Panlite L1225L; 300 ° C., melt viscosity 225 Pa · s at a shear rate of 1000 sec ⁻¹ , viscosity average molecular weight 19700 and Panlite CM1000; 300 ° C., shear rate 1000 sec) ^-1 melt viscosity of 90 Pa · s and viscosity average molecular weight of 16000) were pellet blended to prepare a polycarbonate resin having the melt viscosity shown in Table 1. To this polycarbonate resin, liquid crystal polymer (manufactured by Polyplastics Co., Ltd., A950) and distearyl hydrogen phosphite (Johoku Chemical Industry Co., Ltd., JP218SS) are added in the amounts shown in Table 1, and a 30 mm twin screw extruder. Was melt kneaded at a resin temperature of 300 ° C. and pelletized to obtain the desired resin composition.

  In the extrusion process, care was taken so that air would not be mixed into the kneaded product during the extrusion and the oxidation conditions were not met, and the target resin composition was prepared while removing volatile components from the vent by decompression.

Subsequently, the following evaluation was performed using the obtained resin composition.
(Melt viscosity)
Using a capillary rheometer having a nozzle with an inner diameter of 1 mm and a length of 20 mm, measurement was performed at 300 ° C. and a shear rate of 1000 sec ⁻¹ .
(Peel test)
A test piece having a thickness of 0.8 mm was molded from the pellets with an injection molding machine having a resin temperature of 300 ° C. Then, the peeling test which peels after sticking an adhesive tape on the test piece surface was done. After the peel test, the area of the peeled part was measured using an image processing measuring machine (LUZEX-FS manufactured by Nireco), and (the area of the peeled part / the area of the test piece) was calculated. It can be said that the smaller this value, the smaller the area of the peeled portion and the better the peel characteristics.
(Weld strength)
A 0.8 mm thick welded piece was molded from the above pellets with an injection molding machine having a resin temperature of 300 ° C., and the weld strength was measured in accordance with ISO178.
(Bar flow length)
A bar flow mold having a width of 5 mm and a thickness of 0.3 mm was molded at a resin temperature of 300 ° C. and an injection pressure of 200 MPa, and the flow length was measured.
(Flexural modulus)
A test piece having a thickness of 0.8 mm was molded from the pellets with an injection molding machine having a resin temperature of 300 ° C., and the flexural modulus was measured according to ISO178 D 790.
(Particle size of liquid crystalline polymer)
From a 0.8 mm thick test piece with a weld, a 0.5 μm thick thin piece was cut out in the flow direction, and the liquid crystalline polymer particles were observed with a polarizing microscope. For the particle diameter, an average major axis was measured using an image processing measuring machine (LUZEX-FS manufactured by Nireco).
Comparative Examples 1-5
As shown in Table 1, when the addition amount of the liquid crystalline polymer exceeds the provisions of the present invention (Comparative Example 1), the melt viscosity ratio between the polycarbonate resin and the liquid crystalline polymer does not satisfy the present provisions (Comparative Examples 2, 3). 5 (in addition, the polycarbonate resin used in Comparative Example 5 is Lexan 141 manufactured by General Electric Co., Ltd. used in Examples of JP-A-2002-249656)), when no liquid crystalline polymer is added (Comparative Example 4) ) And the like, resin compositions were prepared and evaluated.

Claims (6)

(A) Thermoplastic resin that does not form an anisotropic melt phase with a melt viscosity of 100 to 300 Pa · s as measured by a capillary rheometer at 300 ° C and a shear rate of 1000 sec ^-1 using a nozzle with an inner diameter of 1 mm and a length of 20 mm 91-99% by weight and
(B) 100 parts by weight of a resin composition comprising 1 to 9% by weight of a liquid crystalline polymer capable of forming an anisotropic molten phase,
(C) 0.001 to 2 parts by weight of one or more selected from the phosphorooxo acid monoesters and diesters represented by the following general formulas (I) and (II): (B) Liquid crystalline polymer is dispersed in particles. A thermoplastic resin composition,
The melt viscosity ratio (Aη) / (Bη) of the component (A) and the component (B) is 3.2 by capillary rheometer measurement using a nozzle with an inner diameter of 1 mm and a length of 20 mm at 300 ° C. and a shear rate of 1000 sec ^−1. A thermoplastic resin composition characterized by being -4.0.
(X) _n P (= O) (OR) _3-n (I)
(X) _n P (OR) _3-n (II)
[Wherein, n is 1 or 2, X is a hydrogen atom, a hydroxyl group, or a monovalent organic group, and a plurality of them may be the same or different. R 2 is a monovalent or divalent organic group, and in a plurality of cases, they may be the same or different. ]   (A) The thermoplastic resin composition according to claim 1, wherein the thermoplastic resin that does not form an anisotropic melt phase is a polycarbonate resin.   (A) The thermoplastic resin composition according to claim 2, wherein the polycarbonate resin has a viscosity average molecular weight of 17500 to 18900. (C) The thermoplastic resin composition according to any one of claims 1 to 3, wherein the phosphorous oxo acid monoester and diester are phosphonic acid esters represented by the following general formula (III).
H (OH) _m P (= O) (OR ') _2-m (III)
[Wherein, m is 0 or 1 and R ′ is a monovalent organic group. ] (C) The thermoplastic resin composition according to any one of claims 1 to 3 , wherein the phosphorous oxo acid monoester and diester are phosphonic acid esters represented by the following general formula (IV).

[Wherein Y is a divalent α, ω-dioxy organic group. ]   A molded article obtained by molding the thermoplastic resin composition according to any one of claims 1 to 5, wherein (A) a liquid crystalline polymer is dispersed in an island-like manner in (A) a thermoplastic resin. A molded product in which the average major axis of (B) liquid crystalline polymer particles in the surface layer portion within 50 μm from the surface of the molded product is 30 μm or less.