JP5043369B2 - Hair cosmetics - Google Patents
Hair cosmetics Download PDFInfo
- Publication number
- JP5043369B2 JP5043369B2 JP2006158945A JP2006158945A JP5043369B2 JP 5043369 B2 JP5043369 B2 JP 5043369B2 JP 2006158945 A JP2006158945 A JP 2006158945A JP 2006158945 A JP2006158945 A JP 2006158945A JP 5043369 B2 JP5043369 B2 JP 5043369B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- hair cosmetic
- cosmetic composition
- dihydroxyindole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003676 hair preparation Substances 0.000 title description 5
- 239000002537 cosmetic Substances 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- SGNZYJXNUURYCH-UHFFFAOYSA-N 5,6-dihydroxyindole Chemical compound C1=C(O)C(O)=CC2=C1NC=C2 SGNZYJXNUURYCH-UHFFFAOYSA-N 0.000 claims description 7
- YFTGOBNOJKXZJC-UHFFFAOYSA-N 5,6-dihydroxyindole-2-carboxylic acid Chemical compound OC1=C(O)C=C2NC(C(=O)O)=CC2=C1 YFTGOBNOJKXZJC-UHFFFAOYSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 235000006708 antioxidants Nutrition 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 235000010323 ascorbic acid Nutrition 0.000 claims description 3
- 229960005070 ascorbic acid Drugs 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 38
- -1 alkyl acrylamide Chemical compound 0.000 description 32
- 229920001577 copolymer Polymers 0.000 description 22
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000002243 precursor Substances 0.000 description 8
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 6
- 239000003380 propellant Substances 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 239000000443 aerosol Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000000118 hair dye Substances 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 230000003699 hair surface Effects 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 239000003915 liquefied petroleum gas Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 3
- 239000000982 direct dye Substances 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011550 stock solution Substances 0.000 description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000980 acid dye Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 229920006318 anionic polymer Polymers 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000000981 basic dye Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 239000001005 nitro dye Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229940012831 stearyl alcohol Drugs 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical class C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- UVHQXWILFGUDTA-LNKPDPKZSA-N (z)-4-ethoxy-4-oxobut-2-enoic acid;methoxyethene Chemical compound COC=C.CCOC(=O)\C=C/C(O)=O UVHQXWILFGUDTA-LNKPDPKZSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- RHBSVLZWJMBUBQ-UHFFFAOYSA-N 1-ethenyl-1h-imidazol-1-ium;chloride Chemical compound [Cl-].C=C[N+]=1C=CNC=1 RHBSVLZWJMBUBQ-UHFFFAOYSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 1
- NZKTVPCPQIEVQT-UHFFFAOYSA-N 2-[4-[(4-aminophenyl)diazenyl]-n-(2-hydroxyethyl)anilino]ethanol Chemical compound C1=CC(N)=CC=C1N=NC1=CC=C(N(CCO)CCO)C=C1 NZKTVPCPQIEVQT-UHFFFAOYSA-N 0.000 description 1
- PWKSKIMOESPYIA-UHFFFAOYSA-N 2-acetamido-3-sulfanylpropanoic acid Chemical compound CC(=O)NC(CS)C(O)=O PWKSKIMOESPYIA-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- JAUFWPNLLLUYNV-UHFFFAOYSA-N 3-(16-methylheptadecoxy)propane-1,2-diol Chemical compound CC(C)CCCCCCCCCCCCCCCOCC(O)CO JAUFWPNLLLUYNV-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- UXKLYBMQAHYULT-UHFFFAOYSA-N 4-(2-hydroxyethylamino)-3-nitrophenol Chemical compound OCCNC1=CC=C(O)C=C1[N+]([O-])=O UXKLYBMQAHYULT-UHFFFAOYSA-N 0.000 description 1
- HSDSBIUUVWRHTM-UHFFFAOYSA-N 4-(2-nitroanilino)phenol Chemical compound C1=CC(O)=CC=C1NC1=CC=CC=C1[N+]([O-])=O HSDSBIUUVWRHTM-UHFFFAOYSA-N 0.000 description 1
- VTXBLQLZQLHDIL-UHFFFAOYSA-N 4-(3-hydroxypropylamino)-3-nitrophenol Chemical compound OCCCNC1=CC=C(O)C=C1[N+]([O-])=O VTXBLQLZQLHDIL-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- NZDXSXLYLMHYJA-UHFFFAOYSA-M 4-[(1,3-dimethylimidazol-1-ium-2-yl)diazenyl]-n,n-dimethylaniline;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1N=NC1=[N+](C)C=CN1C NZDXSXLYLMHYJA-UHFFFAOYSA-M 0.000 description 1
- KEVCVWPVGPWWOI-UHFFFAOYSA-N 4-[(1,3-dimethylimidazol-1-ium-2-yl)diazenyl]aniline;chloride Chemical compound [Cl-].CN1C=C[N+](C)=C1N=NC1=CC=C(N)C=C1 KEVCVWPVGPWWOI-UHFFFAOYSA-N 0.000 description 1
- IQXUIDYRTHQTET-UHFFFAOYSA-N 4-amino-3-nitrophenol Chemical compound NC1=CC=C(O)C=C1[N+]([O-])=O IQXUIDYRTHQTET-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- RAUWPNXIALNKQM-UHFFFAOYSA-N 4-nitro-1,2-phenylenediamine Chemical compound NC1=CC=C([N+]([O-])=O)C=C1N RAUWPNXIALNKQM-UHFFFAOYSA-N 0.000 description 1
- JDWYRSDDJVCWPB-UHFFFAOYSA-N 5,6-dihydroxy-2,3-dihydro-1h-indole-2-carboxylic acid Chemical compound OC1=C(O)C=C2NC(C(=O)O)CC2=C1 JDWYRSDDJVCWPB-UHFFFAOYSA-N 0.000 description 1
- TWLMSPNQBKSXOP-UHFFFAOYSA-N 6358-09-4 Chemical compound NC1=CC([N+]([O-])=O)=CC(Cl)=C1O TWLMSPNQBKSXOP-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- MIWUTEVJIISHCP-UHFFFAOYSA-N HC Blue No. 2 Chemical compound OCCNC1=CC=C(N(CCO)CCO)C=C1[N+]([O-])=O MIWUTEVJIISHCP-UHFFFAOYSA-N 0.000 description 1
- GZGZVOLBULPDFD-UHFFFAOYSA-N HC Red No. 3 Chemical compound NC1=CC=C(NCCO)C([N+]([O-])=O)=C1 GZGZVOLBULPDFD-UHFFFAOYSA-N 0.000 description 1
- PNENOUKIPPERMY-UHFFFAOYSA-N HC Yellow No. 4 Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1OCCO PNENOUKIPPERMY-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 1
- HSWXSHNPRUMJKI-UHFFFAOYSA-N [8-[(2-methoxyphenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].COC1=CC=CC=C1N\N=C/1C2=CC([N+](C)(C)C)=CC=C2C=CC\1=O HSWXSHNPRUMJKI-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229940067573 brown iron oxide Drugs 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000004193 disodium 5'-ribonucleotide Substances 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 150000002476 indolines Chemical class 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940100554 isononyl isononanoate Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940074928 isopropyl myristate Drugs 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940075495 isopropyl palmitate Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- VGSVNUGKHOVSPK-UHFFFAOYSA-N leukoaminochrome Chemical compound C1=C(O)C(O)=CC2=C1NCC2 VGSVNUGKHOVSPK-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008099 melanin synthesis Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- LLLILZLFKGJCCV-UHFFFAOYSA-M n-methyl-n-[(1-methylpyridin-1-ium-4-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C=1C=CC=CC=1N(C)\N=C\C1=CC=[N+](C)C=C1 LLLILZLFKGJCCV-UHFFFAOYSA-M 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000004007 reversed phase HPLC Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 102200116936 rs72549407 Human genes 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000000264 sodium ferrocyanide Substances 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- STZCRXQWRGQSJD-UHFFFAOYSA-N sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonic acid Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- NRLLZRJXDKUVHM-UHFFFAOYSA-N tridecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCCCCC(C)C NRLLZRJXDKUVHM-UHFFFAOYSA-N 0.000 description 1
- NWKBFCIAPOSTKG-UHFFFAOYSA-M trimethyl-[3-[(3-methyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(=O)C1N=NC1=CC=CC([N+](C)(C)C)=C1 NWKBFCIAPOSTKG-UHFFFAOYSA-M 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、日常のヘアケア行動により毛髪表面をメラニン重合物で覆うことで簡単に白髪を目立たなくすることができる毛髪化粧料に関する。 The present invention relates to a hair cosmetic that can easily make gray hair inconspicuous by covering the hair surface with a melanin polymer by daily hair care behavior.
白髪を染めるには、ヘアカラー、ヘアマニキュア等の染毛剤を使用するのが一般的であるが、これら染毛剤を使用した染毛処理は、洗髪などの必要や周辺の汚れなどへの配慮から場所が限定されるとともに、処理方法が複雑で、また毛髪の色の急激な変化による染毛直後の不自然さや伸びてきた白髪との色の段差などの問題があった。 In order to dye white hair, it is common to use hair coloring agents such as hair color and hair nail polish. The location is limited due to consideration, the treatment method is complicated, and there are problems such as unnaturalness immediately after hair dyeing due to abrupt changes in hair color and color steps with the growing white hair.
また、本発明者らは、酵素とメラニン前駆体を用いた毛髪化粧料を提案している(特許文献1参照)。酵素を用いる利点は、メラニン前駆体の酸化速度を高め、塗布後短時間で容易に毛髪表面でメラニンが生成する点にある。しかし、酵素を用いた場合の欠点として、酵素の調製やその安定性を検討する必要があるなど、必ずしも十分なものとはいえなかった。また、メラニン前駆体の酵素による重合物は、色味のコントロールができず、色調も単調なものであった。 Moreover, the present inventors have proposed the hair cosmetics using an enzyme and a melanin precursor (refer patent document 1). The advantage of using the enzyme is that the oxidation rate of the melanin precursor is increased, and melanin is easily generated on the hair surface in a short time after application. However, the disadvantages of using an enzyme are not necessarily sufficient, such as the need to study the preparation of the enzyme and its stability. In addition, the polymer of the melanin precursor enzyme was unable to control the color, and the color tone was also monotonous.
本発明の目的は、日常のスタイリングなどの単回使用のヘアケア行動で、毛髪表面をメラニン重合物で覆うことで、使用場所や使用方法における煩わしさを無くし、簡単に白髪を目立たなくすることができ、数回の継続使用で髪を染めることができる毛髪化粧料を提供することにある。 The object of the present invention is to cover the hair surface with a melanin polymer in a single-use hair care action such as daily styling, so that the troublesomeness in the place of use and the method of use is eliminated and the gray hair is easily made inconspicuous. An object of the present invention is to provide a hair cosmetic that can be dyed by several continuous uses.
本発明者は、メラニン前駆体2種以上と造膜性ポリマー、アルカリ剤及び酸化防止剤を併用することにより、上記課題を解決できることを見出した。 This inventor discovered that the said subject can be solved by using together 2 or more types of melanin precursors, a film-forming polymer, an alkali agent, and antioxidant.
本発明は、次の成分(A)〜(D)を含有し、pHが8〜11である洗い流さないタイプの毛髪化粧料を提供するものである。 The present invention provides a hair cosmetic that contains the following components (A) to (D) and has a pH of 8 to 11 and is not washed away.
(A) 一般式(1)で表される化合物の2種以上 (A) Two or more compounds represented by the general formula (1)
〔式中、破線はπ結合の存在又は不存在を示し、R1は水酸基又はアセトキシ基を示し、R2は水素原子、−COOR(Rは水素原子、メチル基又はエチル基)又は−COO- X+(X+は陽イオン)を示し、R3は水素原子、アセチル基、メチル又はエチル基を示す。〕 [In the formula, the broken line indicates the presence or absence of a π bond, R 1 represents a hydroxyl group or an acetoxy group, R 2 represents a hydrogen atom, —COOR (R is a hydrogen atom, a methyl group or an ethyl group) or —COO −. X <+> (X <+> represents a cation), and R < 3 > represents a hydrogen atom, an acetyl group, a methyl or ethyl group. ]
(B) 造膜性ポリマー
(C) アルカリ剤
(D) 酸化防止剤
(B) Film-forming polymer
(C) Alkaline agent
(D) Antioxidant
本発明の毛髪化粧料は、日常のスタイリングによって簡単に白髪を染めることができ、使用場所、使用方法における煩わしさが無く、簡単に徐々に白髪を目立たなくすることができる。特に、酵素を用いることなくメラニンを生成させることで、安定性に優れた毛髪化粧料を製造することができる。 The hair cosmetic composition of the present invention can easily dye white hair by daily styling, and can be easily and gradually made inconspicuous without any inconvenience in the place of use and method of use. In particular, by producing melanin without using an enzyme, a hair cosmetic with excellent stability can be produced.
成分(A)である一般式(1)で表される化合物は、酸化されることによってメラニン色素に変換するインドール誘導体又はインドリン誘導体(メラニン前駆体)であり、本発明においては、その2種以上の組み合わせを用いる。一般式(1)で表される化合物としては、5,6-ジヒドロキシインドール、5,6-ジヒドロキシインドール-2-カルボン酸、5,6-ジヒドロキシインドリン、5,6-ジヒドロキシインドリン-2-カルボン酸が挙げられ、これらの2種以上を組み合わせることにより、染め上がりの色を調整することができる。特に、髪を自然な色合いに染める観点から、5,6-ジヒドロキシインドールを用いた組み合わせが好ましく、5,6-ジヒドロキシインドールと5,6-ジヒドロキシインドール-2-カルボン酸との組み合わせが最も好ましい。この両者を併用する場合のモル比は、50:50〜999:1、特に80:20〜99:1の範囲とすることが好ましい。ここで、5,6-ジヒドロキシインドール及び5,6-ジヒドロキシインドール-2-カルボン酸は、逆相HPLCにより定量することができる。 The compound represented by the general formula (1) as the component (A) is an indole derivative or indoline derivative (melanin precursor) that is converted into a melanin pigment by being oxidized, and in the present invention, two or more of them Use a combination of Examples of the compound represented by the general formula (1) include 5,6-dihydroxyindole, 5,6-dihydroxyindole-2-carboxylic acid, 5,6-dihydroxyindoline, and 5,6-dihydroxyindoline-2-carboxylic acid. By combining two or more of these, the dyed color can be adjusted. In particular, from the viewpoint of dyeing hair in a natural color, a combination using 5,6-dihydroxyindole is preferable, and a combination of 5,6-dihydroxyindole and 5,6-dihydroxyindole-2-carboxylic acid is most preferable. The molar ratio in the case of using both of these is preferably in the range of 50:50 to 999: 1, particularly 80:20 to 99: 1. Here, 5,6-dihydroxyindole and 5,6-dihydroxyindole-2-carboxylic acid can be quantified by reverse phase HPLC.
成分(A)の化合物の含有量は、白髪の隠蔽性や色移り、使用性の点から、本発明の毛髪化粧料中の0.01〜10重量%が好ましく、更には0.02〜5.0重量%、特に0.05〜2.0重量%が好ましい。 The content of the component (A) compound is preferably 0.01 to 10% by weight, more preferably 0.02 to 5.0% by weight in the hair cosmetic composition of the present invention, from the viewpoint of concealment, color transfer and usability of white hair. 0.05 to 2.0% by weight is preferred.
成分(B)の造膜性ポリマーは、髪の表面に被膜を形成して毛髪セット性を示すものである。造膜性ポリマーとしてはノニオンポリマー、カチオンポリマー、アニオンポリマー及び両性ポリマーが挙げられ、2種以上を併用してもよい。 The film-forming polymer of component (B) forms a film on the hair surface and exhibits hair setting properties. Examples of the film-forming polymer include nonionic polymers, cationic polymers, anionic polymers and amphoteric polymers, and two or more kinds may be used in combination.
ノニオンポリマーとしては、例えばルビスコールK12、17、30、60、80、90(以上、BASF社)、PVP K15、30、60、90(以上、GAF社)等のポリビニルピロリドン;ルビスコールVA28、37、55、64、73、VA37E(以上、BASF社)、PVP/VA E-735、E-635、E-535、E-335、S-630、W-735(以上、GAF社)等のポリビニルピロリドン/酢酸ビニル共重合体;ルビスコールVAP343(BASF社)等のポリビニルピロリドン/酢酸ビニル/プロピオン酸ビニル三元共重合体;Dowtex(ダウ・ケミカル社)等の酢酸ビニル/N-ビニル-5-メチル-2-オキサゾリン共重合体等が挙げられる。 Nonionic polymers include, for example, polyvinylpyrrolidone such as Rubiscol K12, 17, 30, 60, 80, 90 (above BASF), PVP K15, 30, 60, 90 (above GAF); Lubiscol VA28, 37 , 55, 64, 73, VA37E (above, BASF), PVP / VA E-735, E-635, E-535, E-335, S-630, W-735 (above, GAF) etc. Pyrrolidone / vinyl acetate copolymer; Polyvinylpyrrolidone / vinyl acetate / vinyl propionate terpolymer such as Rubiscol VAP343 (BASF); Vinyl acetate / N-vinyl-5- such as Dowtex (Dow Chemical) And methyl-2-oxazoline copolymer.
カチオンポリマーとしては、例えばルビカットFC370、FC550、FC905、HM552、MonoCP(以上、BASF社)等のビニルイミダゾリウムクロライド/ビニルピロリドン共重合体;セルカットH-100(粘度1000cps)、L-200(粘度100cps)(以上、ナショナル・スターチ社)等のヒドロキシエチルセルロース/ジメチルジアリルアンモニウムクロリド;ガフカット734、755N、755(以上、GAF社)等のビニルピロリドン/四級化ジメチルアミノエチルメタクリレート共重合体;ルビフレックス(BASF社)、コポリマー845、937、958(以上、GAF社)等のポリビニルピロリドン/アルキルアミノアクリレート共重合体;コポリマーVC-713(GAF社)等のポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体;ガフカットHS-100(ISP社)等のビニルピロリドン/メタクリルアミドプロピル塩化トリメチルアンモニウム共重合体;特開平2-180911号公報に記載の水溶性高分子化合物等のアルキルアクリルアミド/アクリレート/アルキルアミノアルキルアクリルアミド/ポリエチレングリコールメタクリレート共重合体、N-プロピオニルポリエチレンイミン/メチルポリシロキサン共重合体、アクリル酸アミド/アクリル酸/アルキルメタクリル酸/メトキシポリエチレングリコール共重合体、アクリル酸アミド/アクリル酸エステル共重合体等が挙げられる。 Examples of the cationic polymer include vinyl imidazolium chloride / vinyl pyrrolidone copolymers such as Rubycut FC370, FC550, FC905, HM552, MonoCP (above, BASF); Cellcut H-100 (viscosity 1000 cps), L-200 (viscosity) 100cps) (National Starch) hydroxyethyl cellulose / dimethyl diallylammonium chloride; Gaffcut 734, 755N, 755 (above, GAF) vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer; Rubyflex (BASF), polyvinyl pyrrolidone / alkylamino acrylate copolymers such as copolymers 845, 937, and 958 (above, GAF); polyvinyl pyrrolidone / alkyl amino acrylate / vinyl caprolactam copolymer such as copolymer VC-713 (GAF) Combined: Vinyl pyrrolidone such as Guffcut HS-100 (ISP) / Methramidopropyl trimethylammonium chloride copolymer; alkyl acrylamide / acrylate / alkyl aminoalkyl acrylamide / polyethylene glycol methacrylate copolymer such as water-soluble polymer compound described in JP-A-2-809911, N-propionyl polyethylene imine / Examples thereof include a methylpolysiloxane copolymer, an acrylic amide / acrylic acid / alkyl methacrylic acid / methoxypolyethylene glycol copolymer, and an acrylic amide / acrylic ester copolymer.
アニオンポリマーとしては、例えばガントレッツES-225、ES-425、SP-215(以上、GAF社)等のメチルビニルエーテル/無水マレイン酸アルキルハーフエステル共重合体;レジン28-1310(ナショナル・スターチ社)、ルビセットCA(BASF社)等の酢酸ビニル/クロトン酸共重合体;レジン28-2930(ナショナル・スターチ社)等の酢酸ビルニ/クロトン酸/ネオデカン酸ビニル共重合体;ルビセットCAP(BASF社)等の酢酸ビニル/クロトン酸/プロピオン酸ビニル共重合体;ADVANTAGECP(ISP社)等の酢酸ビニル/マレイン酸モノブチルエステル/イソポロニルアクリレート共重合体;プラスサイズL53P、L-75CB、L-9540B(互応化学社)、ダイヤホールド(三菱化学社)等の(メタ)アクリル酸/(メタ)アクリル酸エステル共重合体;ウルトラホールド8、ウルトラホールド・ストロング(以上、BASF社)、アンフォーマーV-42(ナショナル・スターチ社)等のアクリル酸/アクリル酸アルキルエステル/アルキルアクリルアミド共重合体;ルビフレックスVBM35(BASF社)等のポリビニルピロリドン/アクリレート/(メタ)アクリル酸共重合体等が挙げられる。 Examples of the anionic polymer include methyl vinyl ether / maleic anhydride alkyl half ester copolymers such as Gantrez ES-225, ES-425, SP-215 (above, GAF); Resin 28-1310 (National Starch), Vinyl acetate / crotonic acid copolymers such as Ruby Set CA (BASF); Virni acetate / crotonic acid / vinyl neodecanoate copolymers such as Resin 28-2930 (National Starch); Ruby Set CAP (BASF), etc. Vinyl acetate / crotonic acid / vinyl propionate copolymer; vinyl acetate / maleic acid monobutyl ester / isopolonyl acrylate copolymer such as ADVANTAGECP (ISP); plus size L53P, L-75CB, L-9540B (interaction) Chemical Co.), Diahold (Mitsubishi Chemical Co., Ltd.) and other (meth) acrylic acid / (meth) acrylic acid ester copolymers; Ultrahold 8, Ultraho Acrylic acid / alkyl acrylate / alkyl acrylamide copolymers such as Yold Strong (above BASF) and Unformer V-42 (National Starch); Polyvinylpyrrolidone such as Rubyflex VBM35 (BASF) / Examples thereof include acrylate / (meth) acrylic acid copolymers.
両性ポリマーとしては、例えばユカフォーマーM-75、SM(三菱化学社)等のN-メタクリロイルオキシエチル-N,N-ジメチルアンモニウム-α-N-メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体;ユカフォーマーAM-75、AM75S/SM(以上、三菱化学社)等のジアルキルアミノエチルメタクリレート/メタクリル酸アルキルエステル共重合体のモノクロル酢酸両性化物;アンフォーマー28-4910、LV-71(以上、ナショナル・スターチ社)等のアクリル酸ヒドロキシプロピル/メタクリル酸ブチルアミノエチル/アクリル酸オクチルアミド共重合体等が挙げられる。 Examples of amphoteric polymers include N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymers such as Yuka Former M-75 and SM (Mitsubishi Chemical); Yuka Former AM -75, AM75S / SM (above, Mitsubishi Chemical Corporation) and other dialkylaminoethyl methacrylate / methacrylic acid alkyl ester copolymer monochloroacetic acid amphoteric products; Anformer 28-4910, LV-71 (above, National Starch Co., Ltd.) ) And other hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymers.
これらの造膜性ポリマーのうち、(メタ)アクリル系ポリマーが好ましく、この中でもN-メタクリロイル-N,N-ジメチルアンモニウム-α-N-メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体(例えば、三菱化学社、ユカフォーマーSM)が好ましい。 Of these film-forming polymers, (meth) acrylic polymers are preferable, and among them, N-methacryloyl-N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer (for example, Mitsubishi Chemical Company, Yucaformer SM) is preferred.
成分(B)の造膜性ポリマーの含有量は、本発明の毛髪化粧料中の0.01〜40重量%、特に0.5〜10重量%が好ましい。 The content of the film-forming polymer of component (B) is preferably 0.01 to 40% by weight, particularly preferably 0.5 to 10% by weight, in the hair cosmetic composition of the present invention.
成分(C)のアルカリ剤としては、モノエタノールアミン等のアルカーノールアミン類、炭酸グアニジン等のグアニジン塩類、水酸化ナトリウム、水酸化カルシウム等の無機塩類、炭酸ナトリウム、クエン酸ナトリウム、乳酸ナトリウム等の有機酸塩などが好ましい。アンモニア(水)は、臭いの点で好ましくない。これらの中で、メラニンの生成速度の点で、アルカーノールアミン類、グアニジン塩類が好ましく、特にモノエタノールアミン、炭酸グアニジンが好ましく、炭酸グアニジンが重合速度の点で最も好ましい。 Examples of the alkaline agent of component (C) include alkanolamines such as monoethanolamine, guanidine salts such as guanidine carbonate, inorganic salts such as sodium hydroxide and calcium hydroxide, sodium carbonate, sodium citrate, and sodium lactate. Organic acid salts and the like are preferred. Ammonia (water) is not preferred in terms of odor. Of these, alkanolamines and guanidine salts are preferable from the viewpoint of melanin production rate, monoethanolamine and guanidine carbonate are particularly preferable, and guanidine carbonate is most preferable from the viewpoint of polymerization rate.
成分(C)のアルカリ剤は、単独で又は2種以上を組み合わせて使用することができ、その含有量は、本発明の毛髪化粧料中の0.01〜10重量%が好ましく、更には0.02〜8.0重量%、特に0.05〜5.0重量%が好ましい。 The alkali agent of component (C) can be used alone or in combination of two or more, and the content thereof is preferably 0.01 to 10% by weight in the hair cosmetic composition of the present invention, and more preferably 0.02 to 8.0. % By weight, especially 0.05 to 5.0% by weight is preferred.
成分(D)の酸化防止剤としては、通常の染毛剤に使用される酸化防止剤を使用することができ、例えば、亜硫酸、アスコルビン酸、チオグリコール酸、L-システイン、N-アセチル-L-システイン及びそれらの塩が好ましいものとして挙げられ、特にアスコルビン酸、亜硫酸及びこれらの塩は、成分(A)の安定化に寄与するだけでなく、染色力をも向上させるため、好ましい。 As the antioxidant of component (D), an antioxidant used in a normal hair dye can be used, for example, sulfurous acid, ascorbic acid, thioglycolic acid, L-cysteine, N-acetyl-L -Cysteine and their salts are preferred, and ascorbic acid, sulfurous acid and their salts are particularly preferred because they not only contribute to the stabilization of component (A) but also improve the dyeing power.
成分(D)の酸化防止剤は、単独で又は2種以上を組み合わせて使用することができ、その含有量は、東洋人の白髪を隠蔽するのに好適な赤みのない黒色に染色する点から、本発明の毛髪化粧料中の0.01〜2重量%、特に0.05〜1重量%が好ましい。 The antioxidant of component (D) can be used alone or in combination of two or more, and its content is from the point of dyeing reddish black suitable for concealing Oriental white hair In the hair cosmetic composition of the present invention, 0.01 to 2% by weight, particularly 0.05 to 1% by weight is preferable.
本発明の毛髪化粧料には、成分(A)に加え、追加の染料成分として、前記メラニン前駆体(1)から酸化重合により生成したメラニンを含有させることもできる。このメラニンとしては、特に5,6-ジヒドロキシインドール及び5,6-ジヒドロキシインドール-2-カルボン酸の少なくとも一方からなる酸化重合物であって分子量1000以上のものが好ましい。このメラニンを本発明の染毛剤組成物に含有させるには、メラニン前駆体(1)からあらかじめ重合物を調製した後、本発明の毛髪化粧料に配合しても、またメラニン前駆体(1)を配合し毛髪化粧料を調製する際に空気に触れることでメラニンを生成させてもよい。このメラニン生成物は、黒〜茶色の固形物として、白髪を隠蔽する効果を有するので、本発明の毛髪化粧料の一時染めとしての機能を補完することができる。そのため、その含有量は、本発明の毛髪化粧料の0.01〜50重量%が好ましく、更には0.1〜30重量%、特に0.5〜20重量%が好ましい。 In addition to component (A), the hair cosmetic composition of the present invention can also contain melanin produced from the melanin precursor (1) by oxidative polymerization as an additional dye component. As this melanin, an oxidation polymer composed of at least one of 5,6-dihydroxyindole and 5,6-dihydroxyindole-2-carboxylic acid having a molecular weight of 1000 or more is particularly preferable. In order to contain this melanin in the hair dye composition of the present invention, a polymer is prepared in advance from the melanin precursor (1) and then blended in the hair cosmetic composition of the present invention. ) May be mixed with the air to produce melanin. Since this melanin product has the effect of concealing gray hair as a black to brown solid, the function as a temporary dyeing of the hair cosmetic composition of the present invention can be complemented. Therefore, the content is preferably 0.01 to 50% by weight of the hair cosmetic composition of the present invention, more preferably 0.1 to 30% by weight, and particularly preferably 0.5 to 20% by weight.
また、本発明の毛髪化粧料には、更に通常染毛剤に使用されている直接染料を含有させてもよい。 Further, the hair cosmetic composition of the present invention may further contain a direct dye that is usually used in hair dyes.
直接染料としては、酸性染料、ニトロ染料、分散染料、塩基性染料、特開2003-342139号公報記載の直接染料等が挙げられる。酸性染料としては、青色1号、紫色401号、黒色401号、だいだい色205号、赤色227号、赤色106号、黄色203号、酸性橙3等が挙げられ、ニトロ染料としては、2-ニトロパラフェニレンジアミン、2-アミノ-6-クロロ-4-ニトロフェノール、3-ニトロ-p-ヒドロキシエチルアミノフェノール、4-ニトロオルトフェニレンジアミン、4-アミノ-3-ニトロフェノール、4-ヒドロキシプロピルアミノ-3-ニトロフェノール、HC青2、HC橙1、HC赤1、HC黄2、HC黄4、HC黄5、HC赤3、N,N-ビス-(2-ヒドロキシエチル)-2-ニトロパラフェニレンジアミン等が挙げられ、分散染料としては、分散紫1、分散青1、分散黒9等が挙げられ、塩基性染料としては、塩基性青99、塩基性茶16、塩基性茶17、塩基性赤76、塩基性赤51、塩基性黄57、塩基性黄87、塩基性橙31等が挙げられる。 Examples of the direct dye include acid dyes, nitro dyes, disperse dyes, basic dyes, and direct dyes described in JP-A-2003-342139. Examples of acid dyes include blue No. 1, purple No. 401, black No. 401, orange color No. 205, red No. 227, red No. 106, yellow No. 203, acidic orange 3, etc., and nitro dyes include 2-nitro Paraphenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, 4-nitroorthophenylenediamine, 4-amino-3-nitrophenol, 4-hydroxypropylamino- 3-nitrophenol, HC blue 2, HC orange 1, HC red 1, HC yellow 2, HC yellow 4, HC yellow 5, HC red 3, N, N-bis- (2-hydroxyethyl) -2-nitropara Examples include disperse dyes such as disperse purple 1, disperse blue 1, disperse black 9, etc., and basic dyes include basic blue 99, basic tea 16, basic tea 17, and base. Basic red 76, basic red 51, basic yellow 57, basic yellow 87, basic orange 31 and the like.
本発明の毛髪化粧料に直接染料を含有させる場合、その含有量は、本発明の毛髪化粧料中の0.001〜5重量%、特に0.01〜3重量%が好ましい。 When the hair cosmetic of the present invention contains a dye directly, the content thereof is preferably 0.001 to 5% by weight, particularly 0.01 to 3% by weight in the hair cosmetic of the present invention.
また、本発明の毛髪化粧料には、更に顔料を含有させてもよい。顔料としては、赤色221号、赤色226号、青色404号、黄色401号等の有機顔料;及び二酸化チタン、褐色酸化鉄、ベンガラ、雲母チタン、オキシ塩化ビスマス等の無機顔料を使用することができる。 The hair cosmetic composition of the present invention may further contain a pigment. As the pigment, organic pigments such as Red No. 221, Red No. 226, Blue No. 404, and Yellow No. 401; and inorganic pigments such as titanium dioxide, brown iron oxide, red iron oxide, bengara, titanium mica, and bismuth oxychloride can be used. .
本発明の毛髪化粧料には、使用時の塗布性をなめらかにするため、また上記顔料を分散させるため、更に界面活性剤を含有させることができる。そのような界面活性剤としては、アルキルベンゼンスルホン酸塩、アルキル又はアルケニルエーテル硫酸塩、アルキル又はアルケニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン酸塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α-スルホン脂肪酸塩、N-アシルアミノ酸型界面活性剤、リン酸モノ又はジエステル型界面活性剤、スルホコハク酸エステル等のアニオン界面活性剤;イミダゾリン系、カルボベタイン系、アミドベタイン系、スルホベタイン系、ヒドロキシスルホベタイン系又はアミドスルホベタイン系両性界面活性剤等の両性界面活性剤;ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルケニルエーテル、高級脂肪酸ショ糖エステル、ポリグリセリン脂肪酸エステル、高級脂肪酸モノエタノールアミド又はジエタノールアミド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンソルビット脂肪酸エステル、アルキルサッカライド系界面活性剤、アルキルアミンオキサイド、アルキルアミドアミンオキサイド等の非イオン界面活性剤;イミダゾリン開環型第四級アンモニウム塩、モノ長鎖アルキル第四級アンモニウム塩、ジ長鎖アルキル第四級アンモニウム塩等のカチオン界面活性剤などが挙げられる。これらの界面活性剤のアニオン性残基の対イオンとしては、ナトリウム、カリウム等のアルカリ金属イオン、カルシウム、マグネシウム等のアルカリ土類金属イオン、アンモニウムイオン、炭素数2又は3のアルカノール基を1〜3個有するアルカノールアミン(例えばモノエタノールアミン、ジエタノールアミン、トリエタノールアミン、トリイソプロパノールアミンなど)を挙げることができる。またカチオン性残基の対イオンとしては、塩素、臭素、沃素等のハロゲンイオン及びメトサルフェート、サッカリネートイオンを挙げることができる。 The hair cosmetic composition of the present invention may further contain a surfactant in order to make the coatability during use smooth and to disperse the pigment. Such surfactants include alkyl benzene sulfonates, alkyl or alkenyl ether sulfates, alkyl or alkenyl sulfates, olefin sulfonates, alkane sulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylic acids. Salts, α-sulfone fatty acid salts, N-acyl amino acid type surfactants, phosphate mono- or diester type surfactants, sulfosuccinic acid esters and the like; imidazoline series, carbobetaine series, amide betaine series, sulfobetaine series , Amphoteric surfactants such as hydroxysulfobetaine or amidosulfobetaine amphoteric surfactants; polyoxyalkylene alkyl ethers, polyoxyalkylene alkenyl ethers, higher fatty acid sucrose esters, polyglycerin fatty acid esters, Nonionic surface activity such as grade fatty acid monoethanolamide or diethanolamide, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, alkyl saccharide surfactant, alkylamine oxide, alkylamidoamine oxide Agents: Cationic surfactants such as imidazoline ring-opening quaternary ammonium salts, mono-long-chain alkyl quaternary ammonium salts, and di-long-chain alkyl quaternary ammonium salts. As counter ions of the anionic residues of these surfactants, alkali metal ions such as sodium and potassium, alkaline earth metal ions such as calcium and magnesium, ammonium ions, alkanol groups having 2 or 3 carbon atoms, Examples thereof include three alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, and triisopropanolamine. Examples of the counter ion of the cationic residue include halogen ions such as chlorine, bromine and iodine, and methosulfate and saccharinate ions.
これらの界面活性剤は、単独で又は2種以上を組み合わせて使用することができ、またその含有量は、本発明の毛髪化粧料中の0.1〜15重量%、特に0.5〜8重量%が好ましい。 These surfactants can be used alone or in combination of two or more, and the content thereof is preferably 0.1 to 15% by weight, particularly 0.5 to 8% by weight in the hair cosmetic composition of the present invention. .
更に、本発明の毛髪化粧料には、コンディショニング剤として、油剤を含有させることができる。油剤としては、スクワレン、スクワラン、流動パラフィン、流動イソパラフィン、シクロパラフィン等の炭化水素類;ヒマシ油、カカオ油、ミンク油、アボガド油、オリーブ油等のグリセリド類;ミツロウ、鯨ロウ、ラノリン、カルナウバロウ等のロウ類;パルミチン酸イソプロピル、ミリスチン酸イソプロピル、ミリスチン酸オクチルドデシル、ラウリン酸ヘキシル、乳酸セチル、モノステアリン酸プロピレングリコール、オレイン酸オレイル、2-エチルヘキサン酸ヘキサデシル、イソノナン酸イソノニル、イソノナン酸トリデシル等のエステル類;カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、オレイン酸、ヤシ油脂肪酸、イソステアリル酸、イソパルミチン酸等の高級脂肪酸類;ミリスチルアルコール、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、2-オクチルドデカノール、セトステアリルアルコール等の高級アルコール類;その他イソステアリルグリセリルエーテル、ポリオキシプロピレンブチルエーテルなどが挙げられる。これらのうち、高級アルコール類が好ましく、特にミリスチルアルコール、セチルアルコール、ステアリルアルコールが好ましい。これら油剤は、2種以上を併用することもでき、その含有量は、本発明の毛髪化粧料中の0.2〜2重量%が好ましく、更には0.3〜1.8重量%、特に0.5〜1.5重量%が好ましい。 Furthermore, the hair cosmetic composition of the present invention can contain an oil as a conditioning agent. Oils include hydrocarbons such as squalene, squalane, liquid paraffin, liquid isoparaffin, cycloparaffin; glycerides such as castor oil, cacao oil, mink oil, avocado oil, olive oil; beeswax, whale wax, lanolin, carnauba wax, etc. Waxes: Esters such as isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, isononyl isononanoate, tridecyl isononanoate Higher fatty acids such as capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil fatty acid, isostearyl acid, isopalmitic acid; myristyl al Lumpur, cetyl alcohol, stearyl alcohol, behenyl alcohol, 2-octyldodecanol, higher alcohols such as cetostearyl alcohol; Other isostearyl glyceryl ether, polyoxypropylene butyl ether. Of these, higher alcohols are preferable, and myristyl alcohol, cetyl alcohol, and stearyl alcohol are particularly preferable. These oil agents can be used in combination of two or more, and the content thereof is preferably 0.2 to 2% by weight, more preferably 0.3 to 1.8% by weight, particularly 0.5 to 1.5% by weight in the hair cosmetic composition of the present invention. preferable.
また、本発明の毛髪化粧料には、増粘剤を含有させることもできる。増粘剤としては、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリルアミド、ポリエチレンオキシド、メチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルメチルセルロース、キサンタンガム、ヒドロキシプロピルキサンタンガム、カチオン化グアーガム、カチオン化セルロース等の有機系増粘剤や、無機系のベントナイト系増粘剤、ベーマイト等の含水酸化物等が使用できる。 Moreover, the hair cosmetic composition of the present invention may contain a thickener. As thickeners, organic thickeners such as polyvinyl alcohol, polyvinylpyrrolidone, polyacrylamide, polyethylene oxide, methylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, xanthan gum, hydroxypropylxanthan gum, cationized guar gum, and cationized cellulose, and inorganic Bentonite thickeners based on water, hydrous oxides such as boehmite, and the like can be used.
本発明の毛髪化粧料には、その他、通常の染毛剤や毛髪化粧料に用いられる成分、例えば保湿剤、紫外線吸収剤、pH調整剤、安定化剤、緩衝剤、香料、感触向上剤、キレート剤、可溶化剤、防腐剤等を、目的に応じ、適宜配合することができる。本発明の毛髪化粧料は、以上の成分を水性媒体中に溶解して製造されるが、水性媒体としては水のほか、エタノール、イソプロピルアルコール等の低級アルコール類が挙げられる。 In the hair cosmetic of the present invention, other components used in normal hair dyes and hair cosmetics, such as humectants, ultraviolet absorbers, pH adjusters, stabilizers, buffers, fragrances, touch improvers, Chelating agents, solubilizers, preservatives, and the like can be appropriately blended depending on the purpose. The hair cosmetic composition of the present invention is produced by dissolving the above components in an aqueous medium, and examples of the aqueous medium include water and lower alcohols such as ethanol and isopropyl alcohol.
成分(A)のメラニン前駆体は、塩基性条件で空気中の酸素により酸化されメラニン色素に変換する。このため、本発明の毛髪化粧料のpHは、8〜11、好ましくは8.5〜11の範囲に調整する。 The melanin precursor of component (A) is oxidized by oxygen in the air under basic conditions and converted to a melanin pigment. For this reason, pH of the hair cosmetics of this invention is adjusted to the range of 8-11, Preferably 8.5-11.
本発明の洗い流さないタイプの毛髪化粧料としては、ヘアスタイリング剤、ヘアコンディショニング剤等の形態とするのが好ましく、ポンプスプレー、ポンプフォーム等の容器に充填した形態で使用するのが簡便であるが、より好ましくは、エアゾールスプレー、エアゾールフォーム等の加圧容器に封入された形態で使用するのが良い。エアゾールの噴射剤としては、例えば、液化石油ガス(LPG)、ジメチルエーテル(DME)、炭酸ガス、窒素ガス、これらの混合物等を使用するのが好ましく、特に、LPG、DME、又はLPGとDMEの混合ガスを使用するのが好ましい。噴射剤は、毛髪化粧料/噴射剤の混合重量比率が、(99.5〜40)/(0.5〜60)、特に(95〜80)/(5〜20)となる範囲で使用するのが好ましい。また毛髪化粧料/噴射剤が(5〜70)/(95〜30)、特に(20〜60)/(80〜40)の比率で噴射剤を多量に含有するヘアスプレーとして使用してもよい。 The non-washing-type hair cosmetic of the present invention is preferably in the form of a hair styling agent, hair conditioning agent, etc., and it is easy to use in a form filled in a container such as pump spray or pump foam. More preferably, it may be used in a form enclosed in a pressurized container such as aerosol spray or aerosol foam. As an aerosol propellant, it is preferable to use, for example, liquefied petroleum gas (LPG), dimethyl ether (DME), carbon dioxide gas, nitrogen gas, or a mixture thereof, and in particular, LPG, DME, or a mixture of LPG and DME. It is preferable to use a gas. The propellant is preferably used in such a range that the hair cosmetic / propellant mixing weight ratio is (99.5-40) / (0.5-60), particularly (95-80) / (5-20). Further, the hair cosmetic / propellant may be used as a hair spray containing a large amount of propellant at a ratio of (5-70) / (95-30), particularly (20-60) / (80-40). .
実施例1〜3及び比較例1〜2
表1に示す組成に従ってエアゾール型毛髪化粧料の原液を調製し、この原液をエアゾール用相溶性ビン(東京高分子社)に詰めてクリンチした後、原液:ガス比=90:10(重量比)となるように噴射剤として0.2MPaのジメチルエーテルを充填し、エアゾール型毛髪化粧料を得た。
得られた毛髪化粧料につき、以下に示す評価を行った。結果を表1に併記する。
Examples 1-3 and Comparative Examples 1-2
An aerosol-type hair cosmetic stock solution is prepared according to the composition shown in Table 1, and this stock solution is packed in an aerosol compatible bottle (Tokyo Polymer Co., Ltd.) and clinched, and then the stock solution: gas ratio = 90: 10 (weight ratio) As a propellant, 0.2 MPa dimethyl ether was filled to obtain an aerosol type hair cosmetic.
The obtained hair cosmetics were evaluated as follows. The results are also shown in Table 1.
・白髪隠蔽性及び色調:
中国人女性の白髪トレス5gに毛髪化粧料1gを塗布し、15分放置後、洗い流さずに、白髪の隠れ具合及びその色調を評価した。白髪隠蔽性の評価は、専門パネラー5人の評価により良好とした人数が3人以上○:良好、2〜1人△:普通、0人×:不良の三段階とした。
・ White hair concealment and color:
1 g of hair cosmetic was applied to 5 g of white hair traces of a Chinese woman, and after standing for 15 minutes, the hiding condition of the white hair and its color tone were evaluated without washing away. The evaluation of the gray hair concealment was made in three stages: three or more people who were good according to the evaluation of five professional panelists: ○: good, 2-1 people Δ: normal, 0 people ×: bad.
・染色性:
白髪隠蔽性の評価に用いたトレスをシャンプー、水洗、風乾した。この操作を5回繰り返した後(塗布、放置、シャンプー、水洗、風乾の5回繰り返した後)、染色性を評価した。評価は、○:良好、△:普通、×:不良の三段階とした。
・ Dyeability:
The tress used for the evaluation of the gray hair hiding property was shampooed, washed with water and air-dried. After repeating this operation five times (after repeating coating, leaving, shampooing, washing with water, and air drying five times), the dyeability was evaluated. The evaluation was made into three stages: ○: good, Δ: normal, ×: poor.
・保存安定性:
各エアゾール型毛髪化粧料をエアゾール容器に充填し、45℃にて2週間保存後の組成物の外観、吐出性能及び染毛性を製造直後のものと比較、評価した。評価は、専門パネラー5人により行い、○:良好とした人数が3人以上(良好)、△:良好とした人数が2〜1人(普通)、×:良好とした人数が0人(不良)の三段階とした。
・ Storage stability:
Each aerosol-type hair cosmetic was filled in an aerosol container, and the appearance, discharge performance, and hair dyeability of the composition after storage at 45 ° C. for 2 weeks were compared and evaluated with those immediately after production. Evaluation is carried out by 5 expert panelists. ○: 3 or more people are good (good), △: 2 to 1 people are normal (normal), X: 0 people are good (bad) ).
Claims (3)
(A) 5,6-ジヒドロキシインドール及び5,6-ジヒドロキシインドール-2-カルボン酸
(B) 造膜性ポリマー
(C) アルカリ剤
(D) アスコルビン酸又はその塩と亜硫酸又はその塩とを含む酸化防止剤 It contains the following components (A) to (D), the molar ratio of 5,6-dihydroxyindole to 5,6-dihydroxyindole-2-carboxylic acid is 80:20 to 99: 1, and the pH is 8 to 11 der is, pressure vessel type hair cosmetic composition is not washed off Ru that encapsulated form der to.
(A) 5,6-dihydroxyindole and 5,6-dihydroxyindole-2-carboxylic acid
(B) Film-forming polymer
(C) Alkaline agent
(D) Antioxidant containing ascorbic acid or a salt thereof and sulfurous acid or a salt thereof
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006158945A JP5043369B2 (en) | 2006-06-07 | 2006-06-07 | Hair cosmetics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006158945A JP5043369B2 (en) | 2006-06-07 | 2006-06-07 | Hair cosmetics |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007326805A JP2007326805A (en) | 2007-12-20 |
JP5043369B2 true JP5043369B2 (en) | 2012-10-10 |
Family
ID=38927532
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006158945A Expired - Fee Related JP5043369B2 (en) | 2006-06-07 | 2006-06-07 | Hair cosmetics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5043369B2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW200950813A (en) | 2008-05-21 | 2009-12-16 | Kao Corp | Hair setting method |
JP5548384B2 (en) * | 2008-05-21 | 2014-07-16 | 花王株式会社 | Hair cosmetics |
JP6045325B2 (en) * | 2012-12-12 | 2016-12-14 | 花王株式会社 | Hair cosmetics |
EP3714868A4 (en) | 2017-11-20 | 2021-08-25 | Kao Corporation | Cosmetic hair preparation |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1333690C (en) * | 1988-05-12 | 1994-12-27 | Thomas Matthew Schultz | Process for dyeing hair by the sequential treatment with metal ion containing composition and dye composition containing 5,6-dihydroxyindole-2-carboxylic acid |
JP2002047144A (en) * | 2000-07-31 | 2002-02-12 | Kao Corp | Hair cosmetic |
JP4886117B2 (en) * | 2001-04-23 | 2012-02-29 | 花王株式会社 | Aerosol hair dye composition |
-
2006
- 2006-06-07 JP JP2006158945A patent/JP5043369B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2007326805A (en) | 2007-12-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5507786B2 (en) | Hair cosmetics | |
EP2033625B1 (en) | One-part hair dye composition | |
EP2030606B1 (en) | One-pack hair dye composition | |
KR101441698B1 (en) | One-pack hair dye composition | |
KR101665987B1 (en) | Hair dye | |
JP7105156B2 (en) | hair dyeing method | |
JP5213162B2 (en) | Air oxidation hair dye | |
JP6577459B2 (en) | Oxidative dyeing method using a composition rich in fatty substances and containing a metal catalyst and a coupler | |
EP3229756B1 (en) | Hair dyeing process using at least one dye, a titanium salt and an anionic thickening polymer | |
JP6045325B2 (en) | Hair cosmetics | |
WO2014020167A2 (en) | Dye composition comprising at least one sulfonic compound and a thickening polymer, dyeing process and suitable device | |
JP5043369B2 (en) | Hair cosmetics | |
JP5252784B2 (en) | Aerosol type one-component hair dye composition | |
JP2018188376A (en) | Hair dye | |
JP5363700B2 (en) | Aerosol type one-component hair dye composition | |
JP2017178907A (en) | Oxidation hair dye composition | |
JP5043368B2 (en) | Hair cosmetics | |
JP4598930B2 (en) | Hair dye composition | |
JP3916236B2 (en) | Hair bleaching composition and hair dye composition | |
JP2009040740A (en) | Aqueous hairdressing composition | |
JP7098247B2 (en) | Hair cosmetic composition | |
JP7085355B2 (en) | Dyes and hair dyes | |
JP7182378B2 (en) | hair dye | |
WO2023052513A1 (en) | Composition comprising an oxidative dye and amine salt | |
WO2023054557A1 (en) | Composition comprising an oxidatve dye and alkalizing agent |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090526 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110413 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110426 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110627 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20120214 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120514 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20120522 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120710 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120712 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 5043369 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150720 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |