JP4954589B2 - Method for producing surface-treated steel sheet and heat drying apparatus - Google Patents

Description

  The present invention relates to a method for manufacturing a surface-treated steel sheet and a heating and drying apparatus, and more particularly to a method for manufacturing an organic non-chromate steel sheet not containing chromium and a heating and drying apparatus used in the manufacturing method.

  Conventionally, hot-dip galvanized steel sheets with chromate treatment have been widely used as surface-treated steel sheets used in home appliances. Recently, in consideration of environmental problems, organic non-chromate steel sheets, which are chromate substitute materials, are used. Development is thriving. Of these, surface-treated steel sheets that have been coated with hot-dried galvanized steel sheets, such as polyolefin resins and polyurethane resins with excellent blackening resistance and fingerprint resistance, are promising.

  However, such a surface-treated steel sheet needs to be dried and baked at a high temperature of 100 ° C. or higher after coating in order to improve stability by using a resin curing or crosslinking reaction. Conventionally, such drying and baking processes have been performed by a hot air drying method. However, in the hot air drying method, the heating efficiency is poor and only the vicinity of the surface of the coating is heated, so that the heat penetrates into the coating. It was difficult to heat uniformly. In addition, when heating at the same rate of temperature increase as in the conventional hot air drying method, it takes a long time to reach the target temperature. Therefore, rapid heating was necessary for efficient production.

  Here, examples of the rapid heating technique include induction heating (IH) and near infrared heating (NIR). Induction heating can be performed rapidly according to various requirements by selecting an appropriate AC power source and coil shape. However, it is more expensive than other heating methods and is not considered economical. On the other hand, near infrared is a heat source having a wavelength of 0.72 to 2.0 μm, and it is easy to control the output, and has better thermal energy permeability than mid-infrared and far-infrared, and is an economical heating method. Known as.

  Patent document 1 is mentioned as an example which heats the post-processing film of a plated steel plate by near infrared rays. In Patent Document 1, (1) a surface-treated steel sheet on which an aqueous resin, for example, an acrylic olefin resin or a polyurethane resin ([0039]) is formed, is heated (2) by a near infrared furnace ([0049] etc. ), (3) Achieving a temperature of 50 to 250 ° C., more preferably 70 to 200 ° C., followed by drying and baking ([0051]).

  However, with the technique disclosed in Patent Document 1, it is possible to rapidly heat the coating film by near-infrared heating. However, if excessive heating is performed, only the surface of the coating film is dried. In some cases, coating film defects called Therefore, until now, in order to prevent the occurrence of cracks, it has been unavoidable to limit the heating rate to 40 ° C./sec or less. As a result, when performing continuous processing, the heating equipment must be lengthened or the traveling speed of the steel sheet to be processed must be slowed down. .

  Furthermore, the shape of the near-infrared heaters that are usually on the market are mostly rod-shaped and spherical, so if the object to be heated heats a large area such as a steel plate, multiple heaters must be arranged appropriately. , Uneven heating may occur. In other words, overheated parts cause heat shrinkage of the resin and cause distortion, while conversely underheated parts may cause the resin to not be sufficiently fused to the plated steel sheet and cause poor adhesion. There is.

  As a method for preparing a plurality of rod-shaped near-infrared heaters and heating a carrier material having a large area, for example, Patent Document 2 discloses. Patent Document 2 discloses a technique in which when a thermoplastic resin sheet is heated with a near-infrared heater, the heating area is divided into several blocks and the temperature of the heater is controlled by each block. However, when the technique described in Patent Document 2 is used, it has been difficult to apply in terms of accuracy to uniformly heat a plated steel sheet coated with an organic resin.

JP 2000-248380 A JP-A-11-268111

  Therefore, the present invention has been made in view of such problems, and a method for manufacturing a surface-treated steel sheet that is heated and dried after an organic non-chromate resin film is applied on a plated steel sheet, and a heating and drying apparatus used in the manufacturing method In this case, even if it is rapidly heated and dried to a high target temperature of, for example, 100 ° C. or higher, for example, at a rapid heating rate of over 40 ° C./sec, the occurrence of coating defects is prevented over the entire surface of the coating film, and the steel plate is made uniform. The purpose is to heat.

  In order to solve the above-mentioned problems, the present inventor has conducted intensive studies on a phenomenon in which a plate-like steel sheet coated with a specific resin is heated at high speed by near-infrared heating. It has been found that the peak wavelength of the emitted energy is related. Specifically, the present inventor has shown that the peak wavelength of a near infrared heater that has been commercially available is a value up to 1.2 μm at the shortest, whereas a heater that emits a shorter peak wavelength in a specific region. It was found that the use of can raise the temperature rapidly without generating armpits.

  Further, the present inventor has found that the steel sheet surface can be heated uniformly regardless of the output of the filament by optimizing the arrangement conditions of the filament that emits near infrared rays.

The gist of the present invention completed based on these findings is as follows.
(1) After applying at least one aqueous resin selected from an aqueous polyolefin resin and an aqueous polyurethane resin on the surface of the plated steel sheet, using near infrared rays having a peak wavelength of radiant energy of 0.7 to 1.0 μm, A method for producing a surface-treated steel sheet, comprising forming a coating film by heating the plated steel sheet to 150 to 160 ° C. at a heating rate of 50 to 200 ° C./sec.
(2) A method of heating and drying a surface-treated steel sheet that heat- drys at least one aqueous resin selected from a water-based polyolefin resin and a water-based polyurethane resin applied to a plated steel sheet, and is along the width direction of the plated steel sheet Are arranged at intervals of 15 to 25 mm, and includes a filament that emits near infrared rays having a peak wavelength of radiant energy of 0.7 to 1.0 μm, and the distance between the filament and the plated steel sheet is 50 to 200 mm, From the center in the width direction of the plated steel sheet, the filament is between 40 and 60 mm away from both ends of the plated steel sheet, and the plated steel sheet is heated at a heating rate of 50 to 200 ° C./sec. Whether to use each filament for heating according to the width of the plated steel sheet to heat to 160 ° C And controlling, heating and drying method of the surface treated steel sheet according to (1).
(3) The method for heating and drying a surface-treated steel sheet according to (2), wherein a plurality of the filaments are arranged along the traveling direction of the steel sheet.
(4) The method for heating and drying a surface-treated steel sheet according to (2) or (3), further comprising a detection unit that detects a position of an end in the width direction of the plated steel sheet.

  According to the present invention, in a method for producing a surface-treated steel sheet and a heating and drying apparatus used in the production method, heating can be performed without causing coating defects as in the prior art even when the organic non-chromate coated steel sheet is rapidly heated. Can be dried. In addition, according to the present invention, since the entire surface of the steel sheet to be treated can be heated and dried uniformly, it becomes possible to ensure the secondary adhesion of the paint, the corrosion resistance after strong alkaline degreasing, and the like.

  Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the present specification and drawings, components having substantially the same functional configuration are denoted by the same reference numerals, and redundant description is omitted.

(Method for producing surface-treated steel sheet according to one embodiment of the present invention)
In the method for producing a surface-treated steel sheet according to an embodiment of the present invention, after applying a coating liquid containing at least one aqueous resin selected from an aqueous polyolefin resin and an aqueous polyurethane resin, the peak wavelength of radiant energy is 0. This is a method of forming a coating film by heating a plated steel sheet to 150 to 160 ° C. at a temperature rising rate of 50 to 200 ° C./sec using a near infrared ray of 7 to 1.0 μm.

  In the method for producing a surface-treated steel sheet according to this embodiment, as described above, at least one aqueous resin selected from an aqueous polyolefin resin and an aqueous polyurethane resin is used as the organic resin to be coated. This is because these water-based resins are superior in blackening resistance and fingerprint resistance among non-chromate organic resins.

  The aqueous resin can be applied by a commonly used application method, and for example, a roll coater, a spray, a ringer roll, a bar coater, dipping or the like can be used.

  Moreover, in this embodiment, it heats using the near infrared rays whose peak wavelength of a radiant energy is 0.7-1.0 micrometer. Here, in a heating device using near infrared rays, generally, the radiant energy of the near infrared rays varies depending on the temperature of the filament, and has a peak of radiant energy at a predetermined wavelength. The wavelength when this radiant energy has a peak is called the peak wavelength. Hereinafter, the reason for using near infrared rays in the above peak wavelength range will be described.

  Conventionally, a heating device using near infrared rays (for example, a commercially available device called a near infrared heater) is composed of an electric heating element having a filament, and is used at a filament temperature of around 2500 ° C. It was almost. This is because, generally, when the temperature is increased to 2500 ° C. or more, the life of the filament may be remarkably shortened.

  The near-infrared heater described in the above-mentioned Patent Document 1 also has no specific description about the filament temperature in the document, but the present inventor has a temperature of the near-infrared heater filament of about 2500 ° C. It is confirmed experimentally that it is.

  Here, the temperature of the filament is related to the energy and wavelength distribution emitted from the near-infrared heater, and is generally known as Planck's law expressed by the following formula (1).

Ｃ_１（定数）＝５．９５４４×１０^７
Ｃ_２（定数）＝１．４３８７×１０^４
λ：波長〔μｍ〕
Ｔ：フィラメントの温度〔Ｋ〕
ε：放射率〔−〕
Ｅ_λ＝放射エネルギー〔Ｗ／（ｍ^２・μｍ）〕

C ₁ (constant) = 5.9544 × 10 ⁷
C ₂ (constant) = 1.4387 × 10 ⁴
λ: Wavelength [μm]
T: Filament temperature [K]
ε: Emissivity [-]
E _λ = radiant energy [W / (m ² · μm)]

  In addition, the relationship between the peak wavelength and the temperature of the filament is represented by the following formula (2) called the Wien transition law derived from Planck's law.

Peak wavelength [μm] = 2897.6 / filament temperature (absolute temperature) [T]
... (2)

  According to the Planck's law and the Wien's transition law, it can be seen that the near-infrared peak wavelength used in a conventional near-infrared heater having a filament temperature of 2500 ° C. is about 1.2 μm. The present inventor found that the conventional near-infrared heater having a peak wavelength of about 1.2 μm generates cracks when the temperature is rapidly raised, but when heating is performed using near-infrared light having a peak wavelength of 1.0 μm or less. It has been experimentally confirmed that it is possible to quickly raise the temperature without generating any armpits. Details of this experiment will be described later.

  As described above, the reason why the peak does not occur when the peak wavelength is 1.0 μm or less is that when the peak wavelength exceeds 1.0 μm, the surface of the organic resin coating is preferentially heated and dried. It is believed that there is. Therefore, if the peak wavelength is 1.0 μm or less, the organic resin coating film can be heated uniformly, and even when heated rapidly, the occurrence of cracks can be prevented.

  Even if the same near-infrared heater is used, the temperature of the filament changes depending on the input power. As a result, the peak wavelength shifts to the short wavelength side when the output is large, and to the long wavelength side when the output is small. However, since the variable range of the deviation is not so large, there is almost no effect on the presence or absence of occurrence.

  On the other hand, the peak wavelength of near-infrared is set to 0.7 μm or more in order to output near-infrared light having a peak wavelength of less than 0.7 μm, the temperature of the filament is about 4000 K (rather than the melting point of tungsten constituting the filament). This is because the filament life is remarkably shortened at such a high temperature, which makes it technically difficult.

  Further, the heating rate of the steel sheet was set to 200 ° C./sec, as can be seen from the results of the experiment shown in FIG. 1, even when the peak wavelength was 1.0 μm or less, the heating rate was 200 ° C./sec. This is because when the time exceeds sec, there is a risk of occurrence of wrinkles or uneven drying. On the other hand, the lower limit of the heating rate of the steel sheet is not particularly limited, but if the heating rate is slow, it takes a long time to reach the target temperature. Is preferably 50 ° C./sec or more.

  Moreover, it is preferable that the ultimate temperature of a plated steel plate is 150-160 degreeC from a viewpoint of ensuring the coating secondary adhesiveness and the corrosion resistance after strong alkali degreasing which are the characteristics requested | required of the film | membrane of a plated steel plate. That is, when the temperature reached by the plated steel sheet exceeds 160 ° C., the resin is distorted by thermal shrinkage when the resin is cooled from the temperature after drying (160 ° C.) to room temperature, and the plated steel sheet is covered. Since the strength of the organic resin is weakened, the secondary adhesion of the paint may not be ensured. On the other hand, when the temperature reached by the plated steel sheet is less than 150 ° C, the cross-linking bond in the organic resin is insufficient, and the fusion force between the organic resin and the plated steel sheet is insufficient. May not be possible.

  The paint secondary adhesion is distinguished from the paint primary adhesion. The paint primary adhesion is the paint adhesion without applying a load after coating, whereas the paint secondary adhesion is It means the paint adhesion after applying a load corresponding to the user environment after painting. As an evaluation method, for example, for paint primary adhesion, there is a method of performing tape peeling evaluation after painting. For paint secondary adhesion, for example, a method of tape peeling evaluation after being immersed in boiling water for a predetermined time after painting. There is.

  In addition, it is necessary to ensure the corrosion resistance after strong alkaline degreasing because the user who has obtained the surface-treated steel sheet manufactured by the method according to this embodiment usually performs the degreasing treatment before coating. The degreasing liquid used for the degreasing treatment ranges from a weak alkali having a pH of about 9 to a strong alkali having a pH of about 13, and the higher the pH, the more easily the plating layer (eg, Zn) dissolves and the corrosion resistance deteriorates. It is necessary to ensure corrosion resistance after degreasing.

  Thus, in the manufacturing method of the surface-treated steel sheet according to the present embodiment, the ultimate temperature of the plated steel sheet is a narrow temperature of 150 to 160 ° C. in order to ensure the characteristics of paint secondary adhesion and corrosion resistance after strong alkaline degreasing. It is important to manage within a range (10 ° C.).

  Moreover, it is preferable that the film thickness after drying of the organic resin film coat | covered with a plated steel plate is 0.7-2.0 micrometers. When dried by the method according to this embodiment, if the film thickness after drying exceeds 2.0 μm, the electrical resistance increases and the weldability deteriorates, which is not preferable. On the other hand, if the film thickness after drying is less than 0.7 μm, it is not preferable because sufficient corrosion resistance cannot be secured.

(Configuration of the heating and drying apparatus according to an embodiment of the present invention)
Next, based on FIG. 1, the structure of the heat drying apparatus 10 used for the manufacturing method of the surface treatment steel plate which concerns on one Embodiment of this invention is demonstrated. 1A is a plan view showing the configuration of the heating and drying apparatus 10 according to one embodiment of the present invention, and FIG. 1B is a cross-sectional view taken along line AA in FIG. 1 (c) is a cross-sectional view taken along the line BB of (a).

  As shown in FIG. 1, a heating and drying apparatus 10 is an apparatus for heating and drying an organic resin coated on a plated steel sheet S, and includes a reflecting plate 12, a near infrared heater 14 including a filament inside, an air The nozzle 16 and the glass 18 are mainly provided.

  The plated steel sheet S has a width of about 1100 to 1500 mm, passes through it at 30 to 300 m / min, and is heated while passing under the near-infrared heater 14.

  The reflector 12 is provided to efficiently perform heating by the near infrared heater 14 and is disposed so as to cover the upper surface side of the near infrared heater 14. Near infrared rays radiated from the near infrared heater 14 directly hit the plated steel sheet S, and partly hit the plated steel sheet S after being reflected by the reflector 12. Moreover, in this embodiment, although the reflecting plate 12 is formed in the substantially W shape in cross section, the plated steel plate S can be heated more uniformly by forming in this way a substantially W shape. . However, the shape of the reflecting plate 12 is not limited to a substantially W shape, and any structure can be used as long as the near infrared ray radiated from the near infrared heater 14 can be reflected and applied to the plated steel sheet S. There may be.

  The near-infrared heater 14 has a filament (not shown) disposed therein, and a gas such as halogen is present in the surroundings. For example, the near-infrared heater 14 having a length in the direction parallel to the sheet passing direction of the plated steel sheet S is about 250 mm and having an output of about 3 to 5 kW can be used.

  Further, as described above, the near infrared ray emitted from the filament has a peak wavelength of radiant energy of 0.7 to 1.0 μm from the viewpoint of preventing the occurrence of coating defects such as armpits and the life of the filament. Is preferred.

  The filament which concerns on this embodiment radiates | emits near infrared rays, the longitudinal direction is parallel to the plate | board passing direction of the plated steel plate S, and the plurality is arrange | positioned along the width direction of the plated steel plate S at intervals of 15-25 mm. As described above, the interval between adjacent filaments is set to 15 to 25 mm along the width direction of the plated steel sheet S. If the interval between the filaments is less than 15 mm, the number of filaments to be used increases, which is uneconomical. In addition, it is not preferable because the diameter of the near-infrared heater 14 needs to be reduced and becomes technically difficult. On the other hand, if the spacing between the filaments exceeds 25 mm, temperature unevenness occurs in the width direction of the plated steel sheet S, and a high-output heater that is difficult to manufacture with the current technology is not preferable.

  In addition, the distance between the filament according to the present embodiment and the plated steel sheet S is configured to be 50 to 200 mm as shown in FIG. As described above, the distance between the filament and the plated steel sheet S is set to 50 to 200 mm. If the distance between the filament and the plated steel sheet S is less than 50 mm, the plated steel sheet S flutters up and down while moving, This is not preferable because there is a risk of damage to equipment such as the near infrared heater 14. On the other hand, when the distance between the filament and the plated steel sheet S exceeds 200 mm, the heating efficiency is deteriorated, and it is not preferable because a large-power near-infrared heater 14 and a near-infrared heater 14 need to be added.

  In the heating and drying apparatus 10 according to the present embodiment, in order to heat with the filament between the both ends of the plated steel sheet S from the center in the width direction of the plated steel sheet S to the position 40 to 60 mm away from the outside, plating is performed. Whether or not each filament is used for heating is controlled according to the width of the steel sheet S.

  In the present embodiment, the reason why the filament used for heating is between the both ends of the plated steel sheet S and the position separated by 40 to 60 mm outward is to prevent a temperature drop at the end of the plated steel sheet S. Moreover, it is for heating the outer side rather than the edge part of the plated steel plate S. Moreover, if it is set to 40-60 mm, if less than 40 mm, the end portion of the plated steel sheet S is not sufficiently heated, and the temperature difference between the central portion and the end portion of the plated steel sheet S becomes too large. On the other hand, if it exceeds 60 mm, the end portion of the plated steel sheet S is excessively heated, and the temperature difference between the central portion and the end portion of the plated steel sheet S becomes too large.

  Moreover, it is preferable that a plurality of filaments according to the present embodiment are arranged along the traveling direction of the plated steel sheet S. By comprising in this way, even if it speeds up a plate | board speed, it can heat to target target temperature.

  The details of the method for controlling whether or not each filament is used for heating will be described later.

  The air nozzle 16 is provided to ventilate the inside of the heating and drying apparatus 10. That is, the air nozzle 16 is used to prevent the moisture in the heating and drying apparatus 10 from rising due to the water evaporated from the organic resin coating film, and the air evaporation rate from being slowed down. It plays the role of sending air from the nozzle 16 and removing moisture to the outside.

  The glass 18 is disposed between the filament and the plated steel sheet S in order to protect the near infrared heater 14 described above and allow the air fed from the air nozzle 16 to flow smoothly.

(Filament control method)
As mentioned above, although the structure of the heat drying apparatus 10 which concerns on this embodiment was demonstrated, based on FIGS. 2-4, the detail of the control method of whether each filament mentioned above is used for a heating next is demonstrated. . 2 is an explanatory diagram schematically showing the configuration of the heating and drying apparatus according to the present embodiment, FIG. 3 is a flowchart showing the filament control method according to the present embodiment, and FIG. It is explanatory drawing which shows the specific example using the control method of the filament which concerns on embodiment.

  As shown in FIG. 2, N near infrared heaters for heating the plated steel sheet S being passed are provided symmetrically with respect to the center of the heating and drying apparatus (near infrared heaters 14-0 to 14-0). 14-N). In addition, the width of the coil of the filament changes during heating, and the plated steel sheet S walks (meanders), so the position of the end in the width direction of the plated steel sheet S is detected before or after the heating and drying device. The detection part (sensor) 20 to perform can be provided. The near-infrared heaters 14-0 to 14-N to be used are selected based on the signal from the detection unit 20. Hereinafter, the filament control method according to the present embodiment will be described.

  Here, before starting the control of the filament, the filament is located between the both ends of the plated steel sheet S and a position separated by a predetermined distance α (= 40 to 60 mm) from the center in the width direction of the plated steel sheet S. In order to control the heating, a distance α (hereinafter referred to as “protruding heating width”) α protruding outward from both ends of the plated steel sheet S is determined in advance.

  After the start of the filament control, first, a predetermined protrusion heating width α (see FIG. 2) is read (step S102). Next, the distance W (see FIG. 2) from the center of the heating device detected by the detection unit 20 to the end of the plated steel sheet S is read (step S104). Note that either step S102 or step S104 may be performed first.

Next, W + α calculated from the overheating heating width α and the distance W read in step S102 and step S104, and the distance (H = 0-N) from the center of the heating and drying apparatus to the i-th (i = 0 to N) near-infrared heater 14-i. _i ) is compared (step S106). The process of step S106 is started from i = 0, that is, from the near infrared heater 14-0 disposed at the center of the heating device.

Determination processing in step S106 (step S108) results, when W + alpha is greater than or equal to _{H i (W + α ≧ H} i) uses i-th near infrared heaters 14-i (to ON heater) so (Step S110).

Next, the distance (H _{i + 1} ) from the center of the heating / drying apparatus to the i + 1th near-infrared heater 14-i + 1 is compared with W + α (step S112). If W + α is equal to or higher than H _{i + 1} (W + α ≧ H _{i + 1} ) as a result of the determination in step S112 (step S108), the i + 1th near infrared heater 14-i + 1 is used (the heater is turned on). Control (step S110).

The above steps S108 to S112 are repeated until the determination of step S108 is performed for all the near infrared heaters 14-0 to 14-N up to the Nth near infrared heater 14-N. That is, the above-described processing is sequentially performed from the near-infrared heater 14-0 at the center of the heating and drying apparatus (0th) to the outermost (Nth) near-infrared heater 14-N. However, the result of the determination in step S108, W + alpha is less than _{H i (W + α <H} i) in the case, not using the i-th near infrared heaters 14-i (to OFF heater) controlled so as to ( Step S114), the filament control is terminated.

  As a result, for example, as shown in FIG. 4, the near infrared heaters 14-1 to 14-6 located at a position separated by α mm from the end of the plated steel sheet S are used for heating (the heater is turned on). ), The near-infrared heater 14-7 outside the position separated by α mm from the end of the plated steel sheet S is controlled not to be used for heating (the heater is turned off). In FIG. 4, as an example, the number of near-infrared heaters is seven on one side (N = 7), the heater ON state is black, and the heater OFF state is white. It is shown.

  The processing from the above steps S102 to S114 is repeated for a certain time (for example, a short time of less than 1 second).

  Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited only to the following examples.

(Relationship between peak wavelength of near infrared rays and occurrence of armpits)
First, the results of examining the presence or absence of the occurrence of cracks by changing the peak wavelength of the near infrared ray used for heating will be described. First, the conditions of this experiment will be described. The hot dip galvanized steel sheet was immersed in a 2% aqueous solution of a 50 ° C. degreasing agent (Fine Cleaner 301, manufactured by Nippon Parkerizing Co., Ltd.) for 30 seconds, and then washed and degreased in running water. Next, a coating agent in which silica particles were added as an antirust agent to an aqueous resin composed of polyolefin and polyurethane was applied with a bar coater so that the film thickness after drying was 1.0 μm, and heated with a near infrared heater. The result is shown in FIG. FIG. 5 is a graph showing the relationship between the heating rate of the steel sheet, the peak wavelength of near infrared rays, and the presence or absence of occurrence of cracks.

  As shown in FIG. 5, when the peak wavelength of near infrared rays was 1.0 μm or less, no crack was generated even when the temperature rising rate was increased to 200 ° C./sec. On the other hand, when the peak wavelength of the near infrared ray exceeds 1.0 μm, the cracks are remarkably easily generated. When the peak wavelength of the conventional near infrared heater is 1.2 μm, the heating rate is set to 50 ° C. It has been found that when the temperature is higher than ° C./sec, a crack occurs. In addition, the evaluation of the presence or absence of armpits was performed visually.

  From these results, it was suggested that when the near infrared peak wavelength is 1.0 μm or less, the occurrence of cracks can be prevented even when the temperature is rapidly increased.

(Relationship between heating conditions and coating properties)
Next, the results of examining the relationship between heating conditions (heating temperature (temperature reached by the steel sheet) and rate of temperature increase) and coating film properties (coating secondary adhesion and corrosion resistance after strong alkaline degreasing) will be described. The result is shown in FIG. FIG. 6 is a graph showing the relationship between the heating temperature and the heating rate and the coating film characteristics.

  Here, in this example, the evaluation of the paint secondary adhesion and the corrosion resistance after strong alkaline degreasing were performed as follows.

  That is, regarding the secondary adhesion of the paint, after applying a melamine alkyd paint (Amirac # 1000, manufactured by Nippon Paint Co., Ltd.) to the surface of the surface-treated steel plate used as a sample so as to have a dry film thickness of 20 μm. A pre-painted test plate was prepared by baking at 120 ° C. for 25 minutes. After being left overnight, the coated test plate was immersed in boiling water for 30 minutes, taken out, and left for 1 day. Next, a grid cut crease with a 1 mm interval is placed on a painted test plate, and Erichsen 7 mm is extruded. Cellophane tape (registered trademark of Nichiban Co., Ltd.) is applied to the extruded portion, and the state of the coating film after forced peeling is observed. Observed. A rating of 10 (no peeling) to 1 (complete peeling) was given stepwise depending on the remaining rate of the coating film. Of these, those with a rating of 9 and 10 were considered to have good paint secondary adhesion.

  Moreover, about the corrosion resistance after strong alkali degreasing, the SST test (JIS-Z2371) was done after sticking and covering the end surface and the back surface of the surface-treated steel sheet used as a sample. Then, observe the occurrence of white rust after 120 hours, evaluate the ratio (%) of the white rust occurrence area, and remove the white rust occurrence area ratio (white rust area ratio) of 5% or less with strong alkaline degreasing. Good post-corrosion resistance.

  As a result, as shown in FIG. 6, when the heating rate is 50 to 200 ° C./sec, if the heating temperature exceeds 160 ° C., the secondary adhesion of the paint becomes poor and the heating temperature is less than 150 ° C. Then, it was found that the corrosion resistance was poor after strong alkaline degreasing. This suggests that the heating temperature (attainment temperature) of the steel sheet needs to be in the temperature range of 150 to 160 ° C. in order to ensure the film characteristics of the organic resin applied to the plated steel sheet. In this experiment, coating defects such as armpits did not occur, and the appearance of the film was good.

(Examination of control range from steel plate edge to heater)
Next, the results of studying the distance α from the edge of the plated steel plate to the outermost heater used will be described. In this examination, the number of heaters was 68, the distance between each heater was 20 mm, the distance between the plated steel plate and the heater was 150 mm, and the width of the plated steel plate was 1250 mm. The results are shown in FIG. FIG. 7 is a graph showing the relationship between the temperature difference ΔT (° C.) in the width direction of the steel plate and the distance α (mm) from the end of the steel plate to the outermost heater used.

  If the width of the heater is too wide relative to the width of the plated steel plate, the temperature at the end of the plated steel plate increases, and if the width of the heater is too narrow relative to the width of the plated steel plate, the temperature at the end of the plated steel plate decreases. In order to set an appropriate temperature range, that is, a temperature difference in the width direction of the plated steel sheet within 10 ° C. (the appropriate range of the temperature of the plated steel plate is 150 to 160 ° C.), as shown in FIG. It was found that the distance α from the outermost heater to the outermost heater to be used must be about 40 to 60 mm.

  As mentioned above, although preferred embodiment of this invention was described referring an accompanying drawing, it cannot be overemphasized that this invention is not limited to this example. It will be apparent to those skilled in the art that various changes and modifications can be made within the scope of the claims, and these are naturally within the technical scope of the present invention. Understood.

(A) is a top view which shows the structure of the heat drying apparatus 10 which concerns on one Embodiment of this invention, (b) is AA sectional drawing of (a), (c) is (a). It is BB sectional drawing. It is explanatory drawing which shows roughly the structure of the heat drying apparatus which concerns on one Embodiment of this invention. It is a flowchart which shows the control method of the filament which concerns on one Embodiment of this invention. It is explanatory drawing which shows the specific example using the control method of the filament which concerns on one Embodiment of this invention. It is a graph which shows the relationship between the temperature increase rate of a steel plate, the peak wavelength of near-infrared rays, and the presence or absence of occurrence of cracks. It is a graph which shows the relationship between heating temperature and temperature rising rate, and a coating-film characteristic. It is a graph which shows the relationship between the temperature difference (DELTA) T (degreeC) of the width direction of a steel plate, and the distance (alpha) (mm) from the steel plate edge part to the outermost heater currently used.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 Heating and drying apparatus 12 Reflecting plate 14 Near-infrared heater 16 Air nozzle 18 Glass 20 Detection part (sensor)
S plated steel sheet

Claims (4)

  After applying at least one aqueous resin selected from an aqueous polyolefin resin and an aqueous polyurethane resin to the surface of the plated steel sheet, the plated steel sheet is obtained by using near infrared rays having a peak wavelength of radiant energy of 0.7 to 1.0 μm. Is heated to 150 to 160 ° C. at a heating rate of 50 to 200 ° C./sec to form a coating film. A method of heating and drying a surface-treated steel sheet, wherein at least one aqueous resin selected from an aqueous polyolefin resin and an aqueous polyurethane resin applied to a plated steel sheet is heated and dried.
A plurality of filaments that are arranged at intervals of 15 to 25 mm along the width direction of the plated steel sheet and emit near infrared rays having a peak wavelength of radiant energy of 0.7 to 1.0 μm,
The distance between the filament and the plated steel sheet is 50 to 200 mm,
From the center in the width direction of the plated steel sheet, the filament is between 40 and 60 mm away from both ends of the plated steel sheet, and the plated steel sheet is heated at a heating rate of 50 to 200 ° C./sec. The method for heating and drying a surface-treated steel sheet according to claim 1, wherein whether or not each filament is used for heating is controlled in accordance with the width of the plated steel sheet in order to heat to 160 ° C. The method for heating and drying a surface-treated steel sheet according to claim 2, wherein a plurality of the filaments are arranged along the traveling direction of the steel sheet. The method for heating and drying a surface-treated steel sheet according to claim 2 or 3, further comprising a detection unit for detecting a position of an end in the width direction of the plated steel sheet.

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