JP4931344B2 - Connected grid substrate for lead-acid battery - Google Patents
Connected grid substrate for lead-acid battery Download PDFInfo
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- JP4931344B2 JP4931344B2 JP2004367032A JP2004367032A JP4931344B2 JP 4931344 B2 JP4931344 B2 JP 4931344B2 JP 2004367032 A JP2004367032 A JP 2004367032A JP 2004367032 A JP2004367032 A JP 2004367032A JP 4931344 B2 JP4931344 B2 JP 4931344B2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Description
本発明は、複数枚の格子基板を同時に得られる鉛蓄電池用の格子基板に関するものである。 The present invention relates to a lattice substrate for a lead storage battery that can simultaneously obtain a plurality of lattice substrates.
例えば自動車の始動用に用いられる鉛蓄電池は多数枚の極板を用いて構成された極板群と多量の電解液を電槽内に収納して製造されている。用いられる極板は格子基板にペースト状活物質を塗布充填して得られるが、この格子基板は格子目形状の中骨部とその外側を囲む枠骨と該枠骨から突出した耳部と、更に必要により耳部を形成した枠骨とは対向する枠骨に突出形成される足部とから構成されるものである。そしてこの格子基板は例えば溶融した鉛合金を鋳造して得られる。 For example, a lead-acid battery used for starting an automobile is manufactured by storing a group of electrode plates composed of a large number of electrode plates and a large amount of electrolyte in a battery case. The electrode plate used is obtained by applying and filling a paste-form active material on a lattice substrate, and this lattice substrate is a lattice-shaped central bone portion, a frame bone surrounding the outer portion, and an ear portion protruding from the frame bone, Further, if necessary, the frame bone formed with the ear portion is composed of a foot portion formed to protrude from the opposite frame bone. The lattice substrate is obtained, for example, by casting a molten lead alloy.
これら格子基板は、一枚ずつ鋳造するのではなく、2枚或いはそれ以上の複数枚を耳部で互いに連結した状態で一度に鋳造して得ることがある。(特許文献1) These lattice substrates are not cast one by one, but may be obtained by casting a plurality of two or more at a time in a state where they are connected to each other at the ears. (Patent Document 1)
これら複数枚連結された連結格子基板は鋳造後直ちに一枚に切断させることはなくこのままの状態で搬送されてペースト状活物質を充填する工程やその後の乾燥・熟成工程等に搬送される際に最終的には切断除去される捨て耳と称する比較的広幅な懸垂用捨て耳が連結格子基板の最外側の上端に位置する部分に一体に鋳造され、該捨て耳を搬送時たとえば搬送用チェーンに係合して連結格子基板を懸垂して搬送したり、懸垂棚のフレームに懸垂して熟成されるが、図2に示される様に、一枚の格子基板2の耳部23が該格子基板2の枠骨22の一端ではなく中ほどに形成された内耳格子基板の場合は、懸垂用捨て耳11で懸垂した場合に自重により点線示の様に変形することがある。この変形した連結格子基板は最終工程で所定寸法に切断されて使用されるものであるが、その際に所定形状に切断できず、耳部長さに長短のバラツキが生じたり、枠骨の無いものが製造されたりするといった工程内不良が発生するといった問題がある。 These connected lattice substrates connected to each other are not cut into one piece immediately after casting, but are transported as they are and when they are transported to the process of filling the paste-like active material, the subsequent drying / aging process, etc. Finally, a relatively wide suspension throwing ear called a cutting ear to be cut and removed is integrally cast on a portion located at the uppermost outermost end of the connecting grid substrate. Engage and suspend the connected grid substrate to carry it, or hang it on the frame of the suspension shelf and mature it. As shown in FIG. 2, the ears 23 of one grid substrate 2 are connected to the lattice substrate. In the case of the inner ear lattice substrate formed in the middle instead of one end of the second frame bone 22, it may be deformed as shown by the dotted line due to its own weight when suspended by the suspension throwing ear 11. The deformed connected grid substrate is used after being cut into a predetermined size in the final process, but cannot be cut into a predetermined shape at that time, and the length of the ear part varies, and there is no frame bone. There is a problem that in-process defects occur, such as in manufacturing.
本発明は上記従来の課題を解消したもので、懸垂時に懸垂用捨て耳の上端となる部分の取り付け位置を、一枚の格子基板の耳部の上端の取り付け位置と同じあるいはそれより下方に形成したものである。 The present invention solves the above-described conventional problems, and the attachment position of the upper end of the suspension ear for suspension is formed to be the same as or lower than the attachment position of the upper end of the ear part of one lattice substrate. It is a thing.
このことにより、懸垂時該懸垂用捨て耳に掛かる上向きの応力によっても耳部によって連結格子基板が変形しようとする力に抗することが出来て変形を防止することが出来るものと思われる。 Accordingly, it is considered that even when the suspension is suspended, it is possible to resist the force that the connecting grid substrate is deformed by the ear portion even by the upward stress applied to the hanging discarding ear, and the deformation can be prevented.
連結格子基板の懸垂用捨て耳を係合して連結格子基板を懸垂状態にしても、該連結格子基板の変形が少なく、切断時に所定形状に正しく切断し得て工程内不良を減少させることができる等の効果がある。 Even if the connection grid substrate is suspended by engaging the suspension tab for suspension of the connection grid substrate, the connection grid substrate is less deformed and can be correctly cut into a predetermined shape at the time of cutting, thereby reducing defects in the process. There are effects such as being able to.
図1は本発明の実施形態を示す図である。1は連結格子基板で、この連結格子基板1は四角い点線イで囲んだ部分が一枚の内耳格子基板2でこの内耳格子基板2が複数枚連結された形で鋳造されている。この内耳格子基板2は縦骨と横骨が多数マス目状に配された中骨部21とその周りを四角形に囲む4本のやや太い枠骨22と該枠骨22の一辺からその一端ではなく中ほどから突出して形成される耳部23とから構成されるものである。これら内耳格子基板2を互いにその耳部23で連結して、該耳部23で連結した状態を少なくとも有すると共に互いに隣り合う内耳格子基板2の対向する枠骨の各辺間で連結されている。なお、3はこの枠骨の辺間で連結する連結部である。 FIG. 1 is a diagram showing an embodiment of the present invention. Reference numeral 1 denotes a connected grid substrate, and the connected grid substrate 1 is cast in a form in which a portion surrounded by a square dotted line a is a single inner ear lattice substrate 2 and a plurality of inner ear lattice substrates 2 are connected. This inner ear lattice substrate 2 has a middle bone portion 21 in which a large number of vertical and horizontal bones are arranged in a grid, four slightly thick frame bones 22 surrounding the rectangle in a square shape, and from one side of the frame bone 22 to one end thereof. It is comprised from the ear | edge part 23 which protrudes from the middle rather than . These inner ear lattice substrates 2 are connected to each other by their ear portions 23, and at least have a state of being connected by the ear portions 23, and are connected between the sides of the opposing frame bones of the adjacent inner ear lattice substrates 2. In addition, 3 is a connection part connected between the sides of this frame bone.
この連結格子基板1の両最外側に位置する内耳格子基板の枠骨22には突出して懸垂用捨て耳11が一体に鋳造されている。そして、懸垂用捨て耳11が枠骨22から突出する上端の位置12を単位格子基板2が互いに連結される耳部23が枠骨22から突出する該耳部23の上端位置24と同一又はそれより下位に位置する様にしたものである。 The suspension throwing ears 11 are integrally cast so as to protrude from the frame bone 22 of the inner ear lattice substrate located on both outermost sides of the connection lattice substrate 1. Further, the upper end position 12 at which the suspension throwing ear 11 protrudes from the frame bone 22 is the same as or equal to the upper end position 24 of the ear portion 23 at which the unit lattice substrate 2 is connected to each other. It is designed to be positioned at a lower level.
図1の例では8枚の内耳格子基板2を一体に鋳造したもので、2枚の内耳格子基板2を互いにその耳部23で連結したもの2組を左右に隣り合わせて隣り合う枠骨22の一辺を連結部3で連結したものを2段組合せ、各段の隣り合う枠骨22の各辺を連結部3で連結し、両最側端に位置する枠骨22の一辺に懸垂用捨て耳11を一体に形成して連結格子基板1を構成したものである。この場合、懸垂用捨て耳11が枠骨22から突出する上端の位置12と内耳格子基板2が互いに連結される耳部23が枠骨22から突出する該耳部23の上端位置24とは同じ高さ即ち同一とした。 In the example of FIG. 1, eight inner ear lattice substrates 2 are integrally cast, and two sets of inner ear lattice substrates 2 connected to each other at their ears 23 are adjacent to each other in the left and right sides. A combination of two stages in which one side is connected by the connecting part 3, each side of the adjacent frame bones 22 of each stage is connected by the connecting part 3, and a hanging ear for suspension is attached to one side of the frame bone 22 located at both extreme ends. 11 is integrally formed to constitute the connected grid substrate 1. In this case, the position 12 of the upper end where the suspension ear 11 protrudes from the frame bone 22 is the same as the position 24 of the ear 23 where the ear 23 where the inner ear lattice substrate 2 is connected to each other protrudes from the frame bone 22. The height or the same.
この様な連結格子基板は、例えばこれら形状の掘り込みを入れた移動型と固定型とを互いに当接して形成された空間に溶融鉛合金を流し込むブックモールド鋳造法等により簡単に得ることができる。 Such a connected grid substrate can be easily obtained by, for example, a book mold casting method in which a molten lead alloy is poured into a space formed by abutting a movable mold and a fixed mold each having a digging of these shapes. .
この様にして得た連結格子基板を300枚、工程に流してペースト状活物質を充填し、乾燥と熟成等をして該懸垂用捨て耳を搬送用チェーンやフレームに懸垂した後、切断工程で、懸垂用捨て耳や連結部を切断除去して一枚の内耳格子基板2を得、一枚ずつの極板(活物質を充填した格子基板)の寸法を詳細に測定した結果、連結格子基板の最上部に懸垂用捨て耳を形成した場合に比べ、極板の変形量、即ち耳部長さが所定の長さでなかったり、枠骨が四角形でなかったり、枠骨が細くなったり或いは無くなっていたりした結果、所定寸法からずれた寸法のずれ量は約60%も減少し、極板工程内の不良率を約70%減少させることが出来た。 300 connected grid substrates thus obtained are poured into the process, filled with a paste-like active material, dried and matured, etc., and the hanging ears are suspended on a transportation chain or frame, and then a cutting process. Thus, the inner ear lattice substrate 2 is obtained by cutting and removing the suspension ears and the connecting portions, and the dimensions of each electrode plate (lattice substrate filled with active material) are measured in detail. Compared to the case where a hanging ear for suspension is formed on the uppermost part of the substrate, the deformation amount of the electrode plate, that is, the length of the ear part is not a predetermined length, the frame bone is not square, the frame bone is thinned, or As a result, the amount of deviation from the predetermined size was reduced by about 60%, and the defect rate in the electrode plate process was reduced by about 70%.
なお、懸垂用捨て耳の上端の位置を耳部上端位置それより下位に位置する様にしたものでも同様の効果があった。 The same effect was obtained even when the upper end position of the hanging ear for suspension was positioned lower than the upper end position of the ear.
更に、上記に連結格子基板において、懸垂用捨て耳11が枠骨22から突出する上端の位置12を内耳格子基板2が互いに連結される耳部23が枠骨22から突出する該耳部23の上端位置24と同一にしたものであるが、この位置に図1に示される用に中骨部の縦骨か横骨の少なくとも1本を位置させた場合は、そうでないものより効果がある。 Further, in the above-described connected grid substrate, the upper end position 12 at which the suspension throwing ear 11 protrudes from the frame bone 22 is located at the ear portion 23 at which the inner ear lattice substrate 2 is connected to each other. Although it is the same as the upper end position 24, if at least one of the longitudinal bone or the transverse bone of the middle bone portion is positioned at this position as shown in FIG.
1 連結格子基板
11 懸垂用捨て耳
12 懸垂用捨て耳の上端位置
2 内耳格子基板
21 中格子
22 枠骨
23 耳部
24 耳部の上端位置
以上
DESCRIPTION OF SYMBOLS 1 Connection grid board | substrate 11 Suspension ear 12 Suspension ear upper end position 2 Inner ear lattice board 21 Middle lattice 22 Frame 23 Ear part 24 Above upper end position of ear part
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JP5241264B2 (en) * | 2008-02-19 | 2013-07-17 | 古河電池株式会社 | Control valve type lead storage battery manufacturing method |
JP4963696B2 (en) * | 2008-10-16 | 2012-06-27 | 古河電池株式会社 | Connected grid substrate for lead-acid battery |
JP5347672B2 (en) * | 2009-04-14 | 2013-11-20 | 新神戸電機株式会社 | Suspension board for lead acid battery |
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JPH0760683B2 (en) * | 1989-01-20 | 1995-06-28 | 古河電池株式会社 | Continuous manufacturing method of grid substrate for lead acid battery |
JP4822583B2 (en) * | 2000-12-27 | 2011-11-24 | 古河電池株式会社 | Method for manufacturing a lead-acid battery plate |
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