JP4907145B2 - Liquid crystal panel and liquid crystal display device - Google Patents

Description

  The present invention relates to a liquid crystal panel having a liquid crystal cell, a polarizer, and an optical element. The present invention also relates to a liquid crystal display device using the liquid crystal panel.

  Liquid crystal display devices are attracting attention for their features such as thinness, light weight, and low power consumption. Mobile devices such as mobile phones and watches; OA devices such as personal computer monitors and laptop computers; and home appliances such as video cameras and liquid crystal televisions. Widely popular. This is because technical innovations are overcoming the drawbacks of changing display characteristics depending on the angle at which the screen is viewed and not operating at high or very low temperatures. However, the properties required for each application have changed as the applications are diverse. For example, in a conventional liquid crystal display device, it has been considered that the display characteristics should have a contrast ratio of white / black display of about 10 in an oblique direction. This definition is derived from the contrast ratio of black ink printed on white paper such as newspapers and magazines. However, in a stationary type large color television application, several people see the screen at the same time, and thus a display that can be seen even better from different viewing angles is required. For a liquid crystal display device, light leakage in black display causes a sharp decrease in contrast ratio, so it is important to reduce light leakage in all directions. If such a technical problem is not improved in a large color television application, a person watching the screen will feel uncomfortable and tired.

Conventionally, various retardation films are used in liquid crystal display devices. For example, there is a method of improving the contrast ratio in the oblique direction by disposing a retardation film having a refractive index ellipsoid of nx>nz> ny on one side or both sides of an in-plane switching (IPS) type liquid crystal cell. It is disclosed (for example, see Patent Document 1). However, the display characteristics of the liquid crystal display device obtained by such a technique did not satisfy the level required for large color television applications.
JP-A-11-305217

  The present invention has been made to solve such problems, and an object thereof is to provide a liquid crystal display device having a high contrast ratio in an oblique direction.

  As a result of intensive studies to solve the above problems, the present inventors have found that the above object can be achieved by a liquid crystal panel shown below, and have completed the present invention.

The liquid crystal panel of the present invention includes a liquid crystal cell, a first polarizer disposed on one side of the liquid crystal cell, and the first polarized light disposed between the liquid crystal cell and the first polarizer. A positive C plate adhered to the surface of the child via an adhesive layer, a biaxial optical element disposed between the liquid crystal cell and the positive C plate, and disposed on the other side of the liquid crystal cell. And at least a second polarizer,
The absorption axis direction of the first polarizer is substantially perpendicular to the absorption axis direction of the second polarizer;
The positive C plate has a refractive index ellipsoid of nz> nx≈ny,
In the biaxial optical element, the refractive index ellipsoid has a relationship of nx>nz> ny, Re [590] is greater than 10 nm and less than or equal to 250 nm, and the slow axis direction thereof is the first polarized light. Ri absorption axis direction substantially parallel der child,
It said liquid crystal cell, Ru comprises a liquid crystal layer containing liquid crystal molecules an electric field is oriented in homogeneous molecular alignment in the absence of:
However, Re [590] is an in-plane retardation value measured with light having a wavelength of 590 nm at 23 ° C., the refractive index in the slow axis direction is nx, the refractive index in the fast axis direction is ny, and the thickness direction is The refractive index is nz.

  In a preferred embodiment, the initial alignment direction of the liquid crystal cell is substantially parallel to the absorption axis direction of the second polarizer.

  In a preferred embodiment, the initial alignment direction of the liquid crystal cell is substantially orthogonal to the absorption axis direction of the first polarizer and the slow axis direction of the biaxial optical element.

In a preferred embodiment, the positive C plate satisfies the following formulas (1) and (2):
Re [590] <10 nm (1)
Rth [590] <− 10 nm (2)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively.

  In a preferred embodiment, the positive C plate includes a solidified layer or a cured layer of a liquid crystalline composition containing a calamitic liquid crystal compound aligned in a homeotropic molecular arrangement.

  In a preferred embodiment, the positive C plate includes a polymer film containing a cellulosic resin.

In a preferred embodiment, the biaxial optical element satisfies the following formula (3):
10 nm <Rth [590] <Re [590] (3)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively.

In a preferred embodiment, the biaxial optical element satisfies the following formula (4):
0.2 ≦ Rth [590] / Re [590] ≦ 0.9 (4)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively.

  In a preferred embodiment, the biaxial optical element includes a retardation film containing a polycarbonate resin.

  According to another aspect of the present invention, a liquid crystal display device is provided. The liquid crystal display device includes the liquid crystal panel.

  In a preferred embodiment, the liquid crystal display device is used in a television.

  In the liquid crystal panel of the present invention, a positive C plate in which a refractive index ellipsoid has a relationship of nz> nx≈ny and a biaxial optical element in which a refractive index ellipsoid has a relationship of nx> nz> ny are specified. Arranged in a positional relationship. A liquid crystal display device including at least such a liquid crystal panel has a contrast ratio in an oblique direction that is significantly higher than that of a conventional liquid crystal display device.

A. 1 is a schematic cross-sectional view of a liquid crystal panel according to a preferred embodiment of the present invention. FIG. 2A is a schematic perspective view when this liquid crystal panel adopts the O mode, and FIG. 2B is a schematic perspective view when this liquid crystal panel adopts the E mode. It should be noted that for the sake of easy understanding, the ratios of the vertical, horizontal, and thickness of each component in FIG. 1 and FIGS. 2A and 2B are described differently from the actual ones.

  The liquid crystal panel 100 is disposed between the liquid crystal cell 10, the first polarizer 21 disposed on one side of the liquid crystal cell 10, and the liquid crystal cell 10 and the first polarizer 21. A positive C plate 30, a biaxial optical element 40 disposed between the liquid crystal cell 10 and the positive C plate 30, and a second polarizer 22 disposed on the other side of the liquid crystal cell 10. At least. The absorption axis direction of the first polarizer 21 is substantially orthogonal to the absorption axis direction of the second polarizer 22. In the positive C plate 30, the refractive index ellipsoid has a relationship of nz> nx≈ny. In the biaxial optical element 40, the refractive index ellipsoid has a relationship of nx> nz> ny, and the slow axis direction thereof is substantially parallel to the absorption axis direction of the first polarizer 21. However, the refractive index in the slow axis direction is nx, the refractive index in the fast axis direction is ny, and the refractive index in the thickness direction is nz.

  Practically, the outer side of the first polarizer 21 and the second polarizer 22 (the side opposite to the side including the liquid crystal cell), the first polarizer 21 and the positive C plate 30, or the first Any appropriate protective layer (not shown) may be disposed between the second polarizer 22 and the liquid crystal cell 10. The protective layer is preferably substantially optically isotropic. A liquid crystal display device including such a liquid crystal panel has a feature that a contrast ratio in an oblique direction is remarkably higher than that of a conventional liquid crystal display device.

  The liquid crystal panel of the present invention may be a so-called O mode or a so-called E mode. The “O-mode liquid crystal panel” refers to a liquid crystal panel in which the absorption axis direction of the polarizer disposed on the backlight side of the liquid crystal cell and the initial alignment direction of the liquid crystal cell are parallel to each other. The “E mode liquid crystal panel” refers to a liquid crystal panel in which the absorption axis direction of a polarizer disposed on the backlight side of the liquid crystal cell and the initial alignment direction of the liquid crystal cell are orthogonal to each other. Referring to FIG. 2A, in the case of an O-mode liquid crystal panel, preferably, the first polarizer 21, the positive C plate 30, and the biaxial optical element 40 are disposed on the viewing side of the liquid crystal cell 10, The second polarizer 22 is disposed on the backlight side of the liquid crystal cell. Referring to FIG. 2B, in the case of an E-mode liquid crystal panel, the first polarizer 21, the positive C plate 30, and the biaxial optical element 40 are preferably disposed on the backlight side of the liquid crystal cell 10. The second polarizer 22 is disposed on the viewing side of the liquid crystal cell.

  The liquid crystal panel of the present invention is not limited to the above embodiment. For example, other constituent members may be disposed between the constituent members illustrated in FIG. Hereinafter, each member and each layer constituting the liquid crystal panel of the present invention will be described in detail.

B. Liquid Crystal Cell Referring to FIG. 1, a liquid crystal cell 10 used in the present invention includes a pair of substrates 11 and 11 ′ and a liquid crystal layer 12 as a display medium sandwiched between the substrates 11 and 11 ′. One substrate (active matrix substrate) 11 ′ includes a switching element (typically a TFT) for controlling the electro-optical characteristics of the liquid crystal, a scanning line for supplying a gate signal to the active element, and a signal line for supplying a source signal. Are provided (both not shown). The other substrate (color filter substrate) 11 is provided with a color filter. The color filter may be provided on the active matrix substrate 11 ′. Alternatively, for example, when an RGB three-color light source is used for the backlight of the liquid crystal display device as in the field sequential method, the color filter can be omitted. A distance (cell gap) between the substrate 11 and the substrate 11 ′ is controlled by a spacer (not shown). An alignment film (not shown) made of polyimide, for example, is provided on the side of the substrate 11 and the substrate 11 ′ in contact with the liquid crystal layer 12.

  The liquid crystal cell 10 preferably includes a liquid crystal layer including liquid crystal molecules aligned in a homogeneous molecular arrangement in the absence of an electric field. In such a liquid crystal layer (as a result, a liquid crystal cell) typically has a refractive index ellipsoid having a relationship of nx> ny≈nz (however, the in-plane refractive index is nx, ny, and the thickness direction) The refractive index is nz). In this specification, ny≈nz includes not only the case where ny and nz are completely the same, but also the case where ny and nz are substantially the same. In addition, the “initial alignment direction of the liquid crystal cell” refers to a direction in which the in-plane refractive index of the liquid crystal layer is maximized as a result of alignment of the liquid crystal molecules contained in the liquid crystal layer in the absence of an electric field.

  The initial alignment direction of the liquid crystal cell is preferably substantially parallel to the absorption axis direction of the second polarizer. In this specification, “substantially parallel” means that the angle formed by the initial alignment direction of the liquid crystal cell and the absorption axis direction of the second polarizer is 0 ° ± 2.0 °. The angle is preferably 0 ° ± 1.0 °, and more preferably 0 ° ± 0.5 °. The initial alignment direction of the liquid crystal cell is preferably substantially orthogonal to the absorption axis direction of the first polarizer and the slow axis direction of the biaxial optical element. In the present specification, “substantially orthogonal” means an angle formed by the initial alignment direction of the liquid crystal cell, the absorption axis direction of the first polarizer, and the slow axis direction of the biaxial optical element. Each include 90 ° ± 2.0 °, preferably 90 ° ± 1.0 °, and more preferably 90 ° ± 0.5 °.

  Typical examples of drive modes using a liquid crystal layer in which the refractive index ellipsoid has a relationship of nx> ny≈nz include in-plane switching (IPS) mode, fringe field switching (FFS) mode, and ferroelectric liquid crystal (FLC) mode. Is mentioned. Specific examples of the liquid crystal used in such a drive mode include nematic liquid crystal and smectic liquid crystal. For example, a nematic liquid crystal is used for the IPS mode and the FSS mode, and a smectic liquid crystal is used for the FLC mode.

  The IPS mode uses a voltage-controlled birefringence (ECB) effect, nematic liquid crystal aligned in a homogeneous molecular arrangement in the absence of an electric field, for example, a counter electrode and a pixel electrode formed of metal. The substrate is caused to respond with an electric field (also referred to as a transverse electric field) parallel to the substrate. More specifically, for example, Techno Times Publishing “Monthly Display July” p. 83-p. 88 (1997 edition) and “Liquid Crystal vol.2 No. 4” published by the Japanese Liquid Crystal Society. 303-p. 316 (1998 edition), in the normally black system, the initial alignment direction of the liquid crystal cell is aligned with the absorption axis direction of the polarizer on one side, and the upper and lower polarizing plates are arranged orthogonally. If it does, the transmittance | permeability becomes small in the state without an electric field, and a black display is obtained. On the other hand, in a state where there is an electric field, the liquid crystal molecules rotate while keeping parallel to the substrate, whereby the transmittance increases according to the rotation angle, and white display is obtained. In this specification, the IPS mode is a super-in-plane switching (S-IPS) mode or an advanced super-in-plane switching (AS-IPS) mode that employs a V-shaped electrode, a zigzag electrode, or the like. Is included. As a commercially available liquid crystal display device adopting the IPS mode as described above, for example, Hitachi, Ltd. 20V wide liquid crystal television trade name “Wooo”, Eyama Corp. 19 type liquid crystal display trade name “ProLite E481S-1” ", 17 type TFT liquid crystal display manufactured by Nanao Co., Ltd., trade name" FlexScan L565 "and the like.

  The FFS mode uses a voltage-controlled birefringence (ECB) effect, and nematic liquid crystal aligned in a homogeneous molecular arrangement in the absence of an electric field, for example, with a counter electrode formed of a transparent conductor A response is generated by an electric field parallel to the substrate generated by the pixel electrode and a parabolic electric field. Note that such an electric field in the FFS mode is also referred to as a fringe electric field. This fringe electric field can be generated by setting the distance between the counter electrode formed of a transparent conductor and the pixel electrode to be narrower than the distance between the upper and lower substrates (cell gap). More specifically, for example, SID (Society for Information Display) 2001 Digest, p. 484-p. As described in 487 and JP 2002-031812, in the normally black method, the alignment direction of the liquid crystal cell is aligned with the absorption axis of the polarizer on one side, so that the upper and lower polarizing plates If they are arranged orthogonally, the transmittance is reduced in the absence of an electric field, and a black display is obtained. On the other hand, in a state where there is an electric field, the liquid crystal molecules rotate while keeping parallel to the substrate, whereby the transmittance increases according to the rotation angle, and white display is obtained. In this specification, the FFS mode includes an advanced fringe field switching (A-FFS) mode and an ultra fringe field switching (U-FFS) mode employing a V-shaped electrode, a zigzag electrode, or the like. To do. As a commercially available liquid crystal display device that employs the FFS mode as described above, for example, “M1400”, a product name of Tablet PC manufactured by Motion Computing, Inc., may be mentioned.

  The FLC mode utilizes, for example, the property that when a ferroelectric chiral smectic liquid crystal is sealed between electrode substrates having a thickness of about 1 μm to 2 μm, it exhibits two stable molecular orientation states. The liquid crystal molecules are caused to respond by rotating in parallel with the substrate. In the FLC mode, black and white display can be obtained on the same principle as the IPS mode and the FFS mode. Furthermore, the FLC mode has a feature that the response speed is faster than other drive modes. In this specification, the FLC mode includes a surface stabilization (SS-FLC) mode, an antiferroelectric (AFLC) mode, a polymer stabilization (PS-FLC) mode, and a V-characteristic (V-FLC). ) Mode.

  The liquid crystal molecules aligned in the homogeneous molecular arrangement are those in which the alignment vector of the liquid crystal molecules is aligned in a parallel and uniform manner with respect to the substrate plane as a result of the interaction between the aligned substrate and the liquid crystal molecules. Say things. In the present specification, “homogeneous molecular arrangement” includes a case where the alignment vector of the liquid crystal molecules is slightly tilted with respect to the substrate plane, that is, the liquid crystal molecules have a pretilt. When the liquid crystal molecules have a pretilt, the pretilt angle is preferably 10 ° or less. When the pretilt angle is in the above range, a liquid crystal display device having a high contrast ratio can be obtained.

  Any appropriate liquid crystal can be adopted as the nematic liquid crystal depending on the purpose. For example, the nematic liquid crystal may have a positive or negative dielectric anisotropy. As a nematic liquid crystal with positive dielectric anisotropy, for example, “ZLI-4535” manufactured by Merck & Co., Inc. As a nematic liquid crystal having a negative dielectric anisotropy, for example, trade name “ZLI-2806” manufactured by Merck & Co., Inc. may be mentioned. The birefringence of the nematic liquid crystal measured with light having a wavelength of 589 nm at 23 ° C. is usually 0.05 to 0.30. The birefringence can be obtained from the difference (ne-no) by aligning liquid crystal molecules uniformly and uniformly, measuring the extraordinary refractive index (ne) and the ordinary refractive index (no). .

Any appropriate smectic liquid crystal may be employed depending on the purpose. Preferably, the smectic liquid crystal has an asymmetric carbon atom in a part of a molecular structure and exhibits ferroelectricity (also referred to as a ferroelectric liquid crystal). Examples of the smectic liquid crystal exhibiting ferroelectricity include p-decyloxybenzylidene-p′-amino-2-methylbutylcinnamate, p-hexyloxybenzylidene-p′-amino-2-chloropropylcinnamate, 4- o- (2-methyl) -butylresorcylidene-4′-octylaniline and the like can be mentioned. Alternatively, a commercially available ferroelectric liquid crystal can be used as it is. Examples of the commercially available ferroelectric liquid crystal include a product name ZLI-5014-000 (electric capacity 2.88 nF, spontaneous polarization −2.8 C / cm ² ) manufactured by Merck, and a product name ZLI-5014-100 (manufactured by Merck). Electric capacity 3.19 nF, spontaneous polarization -20.0 C / cm ² ), trade name FELIX-008 (electric capacity 2.26 nF, spontaneous polarization -9.6 C / cm ² ) manufactured by Hoechst.

  An appropriate value can be selected as the cell gap (substrate interval) of the liquid crystal cell depending on the purpose. The cell gap is preferably 1 μm to 7 μm. By setting the cell gap of the liquid crystal cell within the above range, a liquid crystal display device with a short response time can be obtained.

C. Polarizer In this specification, a polarizer refers to an element capable of converting natural light or polarized light into arbitrary polarized light. Any appropriate polarizer may be employed as the polarizer used in the present invention. Preferably, the polarizer converts natural light or polarized light into linearly polarized light. Such a polarizer usually has a function of allowing incident light to pass through one of the two polarized components when the incident light is divided into two orthogonal components, and absorbing the other polarized component. , At least one function selected from the functions of reflecting and scattering.

  The thickness of the polarizer may be appropriately selected depending on the purpose. The thickness of the polarizer is usually 5 μm to 80 μm.

C-1. Optical Properties of Polarizer The transmittance at a wavelength of 550 nm (also referred to as single transmittance) measured at 23 ° C. of the polarizer is preferably 41% or more, more preferably 43% or more. Note that the theoretical upper limit of the single transmittance is 50%, and the realizable upper limit is 46%. The degree of polarization is preferably 99.8% or more, and more preferably 99.9 or more. The theoretical upper limit of the degree of polarization is 100%. By setting the single transmittance and the polarization degree within the above ranges, a liquid crystal display device having a high contrast ratio in the front direction can be obtained.

  The hue of the polarizer used in the present invention according to National Bureau of Standards (NBS); the a value (single a value) is preferably −2.0 or more, more preferably −1.8 or more. Note that the ideal value of the a value is zero. The hue of the polarizer according to National Bureau of Standards (NBS); b value (single b value) is preferably 3.8 or less, more preferably 3.5 or less. Note that the ideal value of the b value is zero. By setting the a value and b value of the polarizer to values close to 0, a liquid crystal display device with vivid colors of the display image can be obtained.

The single transmittance, polarization degree, and hue can be measured using a spectrophotometer [product name “DOT-3” manufactured by Murakami Color Research Laboratory Co., Ltd.]. As a specific method for measuring the degree of polarization, the parallel transmittance (H ₀ ) and orthogonal transmittance (H ₉₀ ) of the polarizer are measured, and the formula: degree of polarization (%) = {(H ₀ −H ₉₀ ) / (H ₀ + H ₉₀ )} ^1/2 × 100. The parallel transmittance (H ₀ ) is a value of the transmittance of a parallel laminated polarizer prepared by superposing two identical polarizers so that their absorption axes are parallel to each other. The orthogonal transmittance (H ₉₀ ) is a value of the transmittance of an orthogonal laminated polarizer produced by superposing two identical polarizers so that their absorption axes are orthogonal to each other. In addition, these transmittance | permeability is Y value which performed visibility correction | amendment by the 2 degree visual field (C light source) of JlS Z 8701-1982.

C-2. Referring to FIGS. 2A and 2B, any appropriate method may be adopted as a method of arranging the first polarizer 21 and the second polarizer 22 depending on the purpose. obtain. The first polarizer 21 is preferably attached to the surface of the positive C plate 30 with an adhesive layer (not shown) provided on the side facing the liquid crystal cell 10. The second polarizer 22 is preferably attached to the surface of the liquid crystal cell 10 by providing an adhesive layer (not shown) on the side facing the liquid crystal cell 10. When an arbitrary optical element is disposed between the liquid crystal cell 10 and the second polarizer 22, the second polarizer 22 is attached to the surface of the arbitrary optical element. In the liquid crystal panel of the present invention, the first polarizer and the second polarizer may be the same or different from each other.

  By sticking the polarizer in this way, when it is incorporated in a liquid crystal display device, the absorption axis direction of the polarizer is prevented from deviating from a predetermined position, or each optical element adjacent to the polarizer is It is possible to prevent rubbing and scratching. Furthermore, since adverse effects of reflection and refraction generated at the interface between the polarizer and each adjacent optical element can be reduced, a liquid crystal display device capable of displaying a clear image can be obtained. In the present specification, the “adhesive layer” means that the surfaces of adjacent optical elements and polarizers are joined and integrated with an adhesive force and an adhesive time that do not adversely affect practical use. If there is, there is no particular limitation. Specific examples of the adhesive layer include an adhesive layer and an anchor coat layer. The adhesive layer may have a multilayer structure in which an anchor coat layer is formed on the surface of an adherend and an adhesive layer is formed thereon.

  The first polarizer 21 is arranged so that the absorption axis direction thereof is substantially perpendicular to the absorption axis direction of the second polarizer 22 facing the first polarizer 21. In this specification, “substantially orthogonal” includes an angle formed by the absorption axis direction of the first polarizer 21 and the absorption axis direction of the second polarizer 22 includes 90 ° ± 2.0 °. Preferably, it is 90 ° ± 1.0 °, and more preferably 90 ° ± 0.5 °.

  The thickness of the adhesive layer can be appropriately selected depending on the purpose. The thickness of the adhesive layer is usually 0.1 μm to 50 μm. By setting the thickness of the adhesive layer in the above range, the optical element and the polarizer to be joined do not float or peel off, and an adhesive force and an adhesive time that do not have a practically adverse effect can be obtained.

  As the material for forming the adhesive layer, an appropriate adhesive or anchor coating agent can be appropriately selected according to the type and purpose of the adherend. Specific examples of adhesives include solvent-based adhesives, emulsion-type adhesives, pressure-sensitive adhesives, rehumidifying adhesives, polycondensation-type adhesives, solventless adhesives, and film-like adhesives according to the classification by shape. Agents, hot melt adhesives, and the like. According to the classification by chemical structure, synthetic resin adhesives, rubber adhesives, and natural product adhesives can be mentioned. The adhesive includes a viscoelastic substance (also referred to as an adhesive) that exhibits an adhesive force that can be sensed by pressure contact at room temperature.

  When a polymer film containing a polyvinyl alcohol-based resin as a main component is used as the polarizer, the material forming the adhesive layer is preferably a water-soluble adhesive. As the water-soluble adhesive, a water-soluble adhesive mainly composed of a polyvinyl alcohol-based resin is preferably used. A commercially available adhesive can be used as it is for the adhesive layer. Or a solvent and an additive can also be mixed and used for a commercially available adhesive agent. As an adhesive mainly composed of a commercially available polyvinyl alcohol resin, for example, “GOHSEIMER Z200” manufactured by Nippon Synthetic Chemical Industry Co., Ltd. may be mentioned.

  The water-soluble adhesive may further contain a crosslinking agent. Examples of the crosslinking agent include amine compounds, aldehyde compounds, methylol compounds, epoxy compounds, isocyanate compounds, and polyvalent metal salts. A commercially available crosslinking agent can be used as it is. Commercially available cross-linking agents include amine compounds manufactured by Mitsubishi Gas Chemical Co., Ltd., trade name “metaxylene diamine”, aldehyde compounds manufactured by Nippon Synthetic Chemical Industries, Ltd. The trade name “Watersol” and the like can be mentioned.

C-3. Optical film used for polarizer Any appropriate polarizing film is selected as the optical film used for the polarizer. The polarizer can be obtained by, for example, a stretched polymer film mainly composed of a polyvinyl alcohol resin containing iodine or a dichroic dye. Or
As disclosed in US Pat. No. 5,523,863, an O-type polarizer in which a liquid crystalline composition containing a dichroic substance and a liquid crystal compound is aligned in a certain direction, or US Pat. No. 6,049,428. It is also possible to use an E-type polarizer in which lyotropic liquid crystal is aligned in a certain direction, as disclosed in Japanese Patent.

  Preferably, the polarizer is a stretched film of a polymer film mainly composed of a polyvinyl alcohol resin containing iodine or a dichroic dye. Since such a polarizer has a high degree of polarization, a liquid crystal display device having a high contrast ratio in the front direction can be obtained as a result. The polymer film containing the polyvinyl alcohol resin as a main component is produced, for example, by the method described in JP 2000-315144 A [Example 1]. Alternatively, a commercially available polymer film can be used as it is. Commercially available polymer films include, for example, “Kuraray Vinylon Film” manufactured by Kuraray Co., Ltd., “Tocero Vinylon Film” manufactured by Tosero Co., Ltd., and “Nichigo” manufactured by Nippon Synthetic Chemical Industry Co., Ltd. Vinylon film "and the like.

  As said polyvinyl alcohol-type resin, what saponified the vinyl ester-type polymer obtained by superposing | polymerizing a vinyl ester-type monomer, and using the vinyl ester unit as a vinyl alcohol unit can be used. Examples of the vinyl ester monomers include vinyl formate, vinyl acetate, vinyl propionate, vinyl valelate, vinyl laurate, vinyl stearate, vinyl benzoate, vinyl pivalate, vinyl versatate, and the like.

  As the average degree of polymerization of the polyvinyl alcohol-based resin, an appropriate value can be appropriately selected according to the purpose. The average degree of polymerization of the polyvinyl alcohol resin is usually 1200 to 3600. The average degree of polymerization can be determined according to JIS K 6726-1994.

  The saponification degree of the polyvinyl alcohol-based resin is usually 95.0 mol% to 99.9 mol% from the viewpoint of durability of the polarizer. The saponification degree indicates the proportion of units that are actually saponified to vinyl alcohol units among the units that can be converted to vinyl alcohol units by saponification. The saponification degree of the polyvinyl alcohol resin can be determined according to JIS K 6726-1994.

  The polymer film mainly composed of the polyvinyl alcohol-based resin used in the present invention preferably contains a polyhydric alcohol as a plasticizer. The polyhydric alcohol is used for the purpose of further improving the dyeability and stretchability of the polarizer. Examples of the polyhydric alcohol include ethylene glycol, glycerin, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and trimethylolpropane. These may be used alone or in combination of two or more. The content (weight ratio) of the polyhydric alcohol is usually more than 0 and 30 with respect to 100 of the total solid content of the polyvinyl alcohol resin.

  The polymer film containing the polyvinyl alcohol resin as a main component can further contain a surfactant. The surfactant is used for the purpose of further improving the dyeability and stretchability of the polarizer. Examples of the surfactant include an anionic surfactant, a cationic surfactant, and a nonionic surfactant. The surfactant is preferably a nonionic surfactant. Examples of the nonionic surfactant include lauric acid diethanolamide, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, lauric acid monoisopropanolamide, oleic acid monoisopropanolamide, and the like. As content (weight ratio) of the said surfactant, it is more than 0 and 5 or less with respect to the polyvinyl alcohol-type resin 100 normally.

  Any appropriate dichroic material can be adopted. In this specification, “dichroism” refers to optical anisotropy in which light absorption differs in two directions, ie, an optical axis direction and a direction orthogonal thereto. Examples of the dichroic dye include red BR, red LR, red R, pink LB, rubin BL, Bordeaux GS, sky blue LG, lemon yellow, blue BR, blue 2R, navy RY, green LG, violet LB, and violet. B, Black H, Black B, Black GSP, Yellow 3G, Yellow R, Orange LR, Orange 3R, Scarlet GL, Scarlet KGL, Congo Red, Brilliant Violet BK, Spura Blue G, Spura Blue GL, Spura Orange GL, Direct Sky Blue, Direct First Orange S, First Black, etc. are mentioned.

  An example of a method for manufacturing a polarizer will be described with reference to FIG. FIG. 3 is a schematic view showing the concept of a typical production process of a polarizer used in the present invention. For example, a polymer film 301 mainly composed of a polyvinyl alcohol-based resin is drawn out from the feed-out unit 300, immersed in an iodine aqueous solution bath 310, and tensioned in the film longitudinal direction by rolls 311 and 312 having different speed ratios. While being subjected to swelling and dyeing processes. Next, it is immersed in a bath 320 of an aqueous solution containing boric acid and potassium iodide, and subjected to a crosslinking treatment while tension is applied in the longitudinal direction of the film with rolls 321 and 322 having different speed ratios. The film subjected to the crosslinking treatment is immersed in an aqueous solution bath 330 containing potassium iodide by rolls 331 and 332 and subjected to a water washing treatment. The water-washed film is dried by the drying means 340 so that the moisture content is adjusted and taken up by the take-up unit 360. The polarizer 350 can be obtained by stretching the polymer film containing the polyvinyl alcohol resin as a main component to 5 to 7 times the original length through these steps.

  As the moisture content of the polarizer 350, an appropriate value can be appropriately selected according to the purpose. The moisture content is usually 10% to 30%. By setting the moisture content within the above range, a polarizer having excellent appearance uniformity can be obtained.

D. Positive C plate In this specification, “positive C plate” means a refractive index ellipse when the refractive index in the slow axis direction is nx, the refractive index in the fast axis direction is ny, and the refractive index in the thickness direction is nz. A positive uniaxial optical element whose body has a relationship of nz> nx≈ny. Ideally, the positive C plate has an optical axis in the normal direction. In the present specification, nx≈ny includes not only the case where nx and ny are completely the same, but also the case where nx and ny are substantially the same. Here, “when nx and ny are substantially the same” includes a case where the in-plane retardation value (Re [590]) is less than 10 nm. When the refractive index ellipsoid: nz> nx≈ny is expressed by Re [590] and Rth [590], the positive C plate satisfies the following expressions (1) and (2).
Re [590] <10 nm (1)
Rth [590] <− 10 nm (2)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively.

  In the present invention, the positive C plate is used together with the biaxial optical element to reduce light leakage in the oblique direction of the liquid crystal panel. Normally, a liquid crystal panel in which two polarizers are arranged on both sides of a liquid crystal cell so that their absorption axes are orthogonal to each other causes light leakage in an oblique direction, and the liquid crystal panel has a long side of 0 °. There is a tendency that the amount of light leakage becomes maximum at 45 ° azimuth and 135 ° azimuth in an oblique direction. The liquid crystal panel of the present invention can reduce the amount of light leakage by using the positive C plate and the biaxial optical element in a specific positional relationship. As a result, the liquid crystal panel has a high contrast ratio in the oblique direction. A display device can be obtained.

  Referring to FIGS. 2A and 2B, the positive C plate 30 is disposed between the liquid crystal cell 10 and the first polarizer 21. In the positive C plate 30, when nx and ny are completely the same, no phase difference value is generated in the plane, so that the slow axis is not detected. In this case, the positive C plate 30 can be arranged regardless of the absorption axis direction of the first polarizer 21 and the slow axis direction of the biaxial optical element 40. Even if nx and ny are substantially the same, if nx and ny are slightly different, a slow axis may be detected (a slight in-plane phase difference value occurs). In this case, the positive C plate 30 is preferably arranged so that the slow axis direction thereof is substantially parallel or substantially orthogonal to the absorption axis direction of the first polarizer 21. In this specification, “substantially parallel” means that the angle formed between the slow axis direction of the positive C plate 30 and the absorption axis direction of the first polarizer 21 is 0 ° ± 2.0 °. In some cases, it is preferably 0 ° ± 1.0 °, more preferably 0 ° ± 0.5 °. The term “substantially orthogonal” includes the case where the angle formed by the slow axis direction of the positive C plate 30 and the absorption axis direction of the first polarizer 21 is 90 ° ± 2.0 °. , Preferably 90 ° ± 1.0 °, and more preferably 90 ° ± 0.5 °. When the positive C plate has an in-plane retardation value, the smaller the deviation of the angle between the slow axis direction of the positive C plate and the absorption axis direction of the first polarizer, the more the front and oblique directions are. A liquid crystal display device having a high contrast ratio can be obtained.

D-1. Optical Characteristics of Positive C Plate In this specification, Re [590] refers to an in-plane retardation value measured with light having a wavelength of 590 nm at 23 ° C. Here, “in-plane retardation value” means an in-plane retardation value when the optical element is composed of a single retardation film, and the optical element includes a retardation film. Means an in-plane retardation value of the entire laminate. Re [590] is expressed by the formula: Re [590, where the refractive index in the slow axis direction and the fast axis direction of the optical element at a wavelength of 590 nm is nx and ny, respectively, and d (nm) is the thickness of the optical element. ] = (Nx−ny) × d. The slow axis means the direction in which the in-plane refractive index is maximum.

  Re [590] of the positive C plate is less than 10 nm, preferably 5 nm or less, and more preferably 2 nm or less. The theoretical lower limit of Re [590] of the positive C plate is 0 nm.

  In this specification, Rth [590] refers to a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C. Rth [590] is expressed by the formula: Rth [590] = (nx) where the refractive index in the slow axis direction and thickness direction of the optical element at a wavelength of 590 nm is nx and nz, respectively, and d (nm) is the thickness of the optical element. −nz) × d. The slow axis refers to the direction in which the in-plane refractive index is maximum.

The Rth [590] of the positive C plate can be appropriately selected according to the value of Re [590] of a biaxial optical element described later. Preferably, Rth [590] of the positive C plate is the sum of the absolute value (| Rth [590] |) of Rth [590] of the positive C plate and Re [590] of the biaxial optical element (R _SUM ) is set to 180 nm to 300 nm. More preferably as the R _SUM is 200Nm～280nm, most preferably 220Nm～260nm. By setting it as said range, the function which each optical element has is demonstrated synergistically, and the contrast ratio of a diagonal direction can be obtained still higher.

  Rth [590] of the positive C plate is preferably −200 nm to −15 nm or less, more preferably −150 nm to −20 nm, particularly preferably −120 nm to −25 nm, most preferably −100 nm to -30 nm.

Re [590] and Rth [590] can be measured using a product name “KOBRA21-ADH” manufactured by Oji Scientific Instruments. In-plane retardation value (Re) at a wavelength of 590 nm at 23 ° C., retardation value measured by tilting 40 degrees with the slow axis as the tilt axis (R40), optical element thickness (d), and average refractive index of the optical element Using the rate (n0), nx, ny and nz can be obtained by computer numerical calculation from the following formulas (i) to (iv), and then Rth can be calculated by formula (iv). Here, φ and ny ′ are represented by the following equations (v) and (vi), respectively.
Re = (nx−ny) × d (i)
R40 = (nx−ny ′) × d / cos (φ) (ii)
(Nx + ny + nz) / 3 = n0 (iii)
Rth = (nx−nz) × d (iv)
φ = sin ⁻¹ [sin (40 °) / n0] (v)
ny ′ = ny × nz [ny ² × sin ² (φ) + nz ² × cos ² (φ)] ^1/2 (vi)

D-2. Means for Placing Positive C Plate Referring to FIG. 1, any appropriate method may be adopted as a method for arranging positive C plate 30 according to the purpose. Preferably, an adhesive layer (not shown) is provided between the positive C plate 30 and the first polarizer 21 and between the positive C plate 30 and the biaxial optical element 40, respectively. Each optical element is affixed. In this way, by filling the gaps between the optical elements with the adhesive layer, the optical axes of the optical elements can be prevented from shifting when they are incorporated into a liquid crystal display device, or the optical elements can be rubbed and damaged. Can be prevented. Furthermore, since the adverse effects of reflection and refraction generated at the interface between the layers of each optical element can be reduced, a liquid crystal display device capable of displaying a clear image can be obtained.

  The thickness of the adhesive layer can be appropriately selected depending on the purpose. The thickness of the adhesive layer is usually 0.1 μm to 50 μm. By setting the thickness of the adhesive layer in the above range, the optical element and the polarizer to be joined do not float or peel off, and an adhesive force and an adhesive time that do not have a practically adverse effect can be obtained.

  As a material for forming the adhesive layer, an appropriate material can be appropriately selected from those exemplified in the section C-2. Preferably, the material forming the adhesive layer is a pressure-sensitive adhesive (also referred to as an acrylic pressure-sensitive adhesive) having an acrylic polymer as a base polymer. It is because it is excellent in transparency, adhesiveness, weather resistance, and heat resistance. A commercially available double-sided optical tape can be used as it is for the adhesive layer. As a commercially available optical double-sided tape, for example, trade name “SK-2057” manufactured by Soken Chemical Co., Ltd. may be mentioned.

D-3. Configuration of Positive C Plate The configuration (laminated structure) of the positive C plate used in the present invention is not particularly limited as long as it satisfies the optical characteristics described in the above section D-1. Specifically, the positive C plate may be a retardation film alone or a laminate composed of two or more retardation films. Preferably, the positive C plate is composed of a single retardation film or two retardation films. When the positive C plate is a laminate, an adhesive layer may be included. When the laminate includes two or more retardation films, these retardation films may be the same or different. The details of the retardation film will be described later in section D-4.

  Rth [590] of the retardation film used for the positive C plate can be appropriately selected depending on the number of the retardation films used. For example, when the positive C plate is composed of the retardation film alone, it is preferable that Rth [590] of the retardation film is equal to Rth [590] of the positive C plate. Therefore, the retardation value of the adhesive layer used when the positive C plate is laminated on the first polarizer or the liquid crystal cell is preferably as small as possible. For example, when the positive C plate is a laminate including two or more retardation films, the sum of Rth [590] of each retardation film is equal to Rth [590] of the positive C plate. It is preferable to design as follows. More specifically, for example, a positive C plate having Rth [590] of −100 nm can be obtained by laminating two retardation films having Rth [590] of −50 nm. Alternatively, a retardation film having Rth [590] of −20 nm and a retardation film having Rth [590] of −80 nm may be laminated. At this time, when the two retardation films have in-plane retardation values (Re [590]), it is preferable that the two retardation films have the slow axis directions orthogonal to each other. Laminated. This is because the in-plane retardation value can be reduced. In addition, for the sake of simplicity, only the case where the number of retardation films is two or less is illustrated, but it goes without saying that the present invention can be applied to a laminate including three or more retardation films.

  The total thickness of the positive C plate is usually 0.2 μm to 200 μm, although it varies depending on the configuration.

D-4. Retardation film used for positive C plate Arbitrary appropriate thing can be used as a retardation film used for positive C plate. The retardation film is preferably a film that is excellent in transparency, mechanical strength, thermal stability, moisture shielding properties, and the like and is less likely to cause optical unevenness due to strain.

  The thickness of the retardation film can vary depending on the number of laminated films. Typically, the total thickness of the obtained positive C plate is preferably set to be 0.2 μm to 200 μm. For example, when the positive C plate is composed of a single retardation film, the thickness of the retardation film is preferably 0.2 μm to 200 μm (that is, equal to the total thickness of the positive C plate). In addition, for example, when the positive C plate is a laminate of two retardation films, the thickness of each retardation film may be any appropriate as long as the sum is a preferable overall thickness of the positive C plate. Thickness can be employed. Therefore, the thickness of each retardation film may be the same or different. In one embodiment in the case of laminating two retardation films, the thickness of one retardation film is preferably 0.1 μm to 100 μm.

The transmittance of the retardation film measured with light having a wavelength of 590 nm at 23 ° C. is usually 80% or more, and preferably 90% or more. The positive C plate preferably has the same light transmittance. The theoretical upper limit of the transmittance is 100%, and the realizable upper limit is 96%.
Preferably, the positive C plate used in the present invention includes a solidified layer or a cured layer of a liquid crystalline composition containing a calamitic liquid crystal compound aligned in a homeotropic molecular arrangement as a retardation film.

  In this specification, “homeotropic molecular alignment” refers to a state in which liquid crystal compounds contained in a liquid crystalline composition are aligned in parallel and uniformly with respect to the film normal direction. The “calamitic liquid crystal compound” has a rod-shaped mesogen group in the molecular structure, and a side difference (for example, an alkylene having 2 to 10 carbon atoms) via an ether bond or an ester bond on one side or both sides of the mesogen group. Group). Examples of the rod-shaped mesogen group include a biphenyl group, a phenylbenzoate group, a phenylcyclohexane group, an azoxybenzene group, an azomethine group, an azobenzene group, a phenylpyrimidine group, a diphenylacetylene group, a diphenylbenzoate group, a bicyclohexane group, and a cyclohexylbenzene. Group, terphenyl group and the like. In addition, the terminal of these mesogenic groups may have substituents, such as a cyano group, an alkyl group, an alkoxy group, a halogen group, for example. Among these, the calamitic liquid crystal compound is preferably a biphenyl group or a phenylbenzoate group as the mesogenic group.

  In the present specification, the “liquid crystalline composition” refers to a liquid crystal phase exhibiting liquid crystallinity. Examples of the liquid crystal phase include a nematic liquid crystal phase, a smectic liquid crystal phase, a cholesteric liquid crystal phase, and a columnar liquid crystal phase. The “solidified layer” refers to a solidified state in which a liquid crystalline composition in a softened, molten or solution state is cooled. The “cured layer” is a layer in which a part or all of the liquid crystalline composition is cross-linked by heat, catalyst, light and / or radiation to be in a stable state of infusible or hardly soluble. Say. In addition, the said hardened layer includes what became the hardened layer via the solidified layer of a liquid crystalline composition.

  The liquid crystal compound may be either a temperature transition type (thermotropic) liquid crystal in which a liquid crystal phase develops due to a temperature change or a concentration transition type (lyotropic) liquid crystal in which a liquid crystal phase develops depending on the concentration of a solute in a solution state. Note that the above-described temperature transition type liquid crystal has a phase transition from a crystalline phase (or glass state) to a liquid crystal phase, a reversible tautomatic (enantotropic) phase transition liquid crystal, or a single change in which a liquid crystal phase appears only in a temperature lowering process ( Monotropic) phase transition liquid crystals. Preferably, the calamitic liquid crystal compound used for the positive C plate is a temperature transition type (thermotropic) liquid crystal and exhibits a nematic liquid crystal phase. This is because it has high transparency and is excellent in productivity, workability, quality and the like when forming a film.

  The calamitic liquid crystal compound may be a polymer substance having a mesogenic group in the main chain and / or side chain (also referred to as a polymer liquid crystal), or a low molecular substance having a mesogenic group in a part of the molecular structure (low molecule). (Also referred to as liquid crystal). The polymer liquid crystal can fix the molecular alignment state only by cooling from the liquid crystal state. Therefore, it has the characteristics that the productivity at the time of forming the film is high and the heat resistance, mechanical strength, and chemical resistance of the formed film are excellent. Since the low molecular liquid crystal is excellent in orientation, it has a feature that a highly transparent film can be easily obtained.

  More preferably, the positive C plate includes a solidified layer or a cured layer of a liquid crystalline composition including a calamitic liquid crystal compound aligned in a homeotropic molecular arrangement, and the calamitic liquid crystal compound is included in at least one part of the molecular structure. Has one polymerizable functional group. Particularly preferably, the calamitic liquid crystal compound has two polymerizable functional groups in a part of the molecular structure. When such a liquid crystal compound is used, the mechanical strength of the retardation film is increased by crosslinking the polymerizable functional group by a polymerization reaction, and a retardation film having excellent thermal stability and dimensional stability can be obtained. . As a low molecular liquid crystal having one mesogenic group and two polymerizable functional groups in a part of the molecular structure, for example, a product name “Paliocolor LC242” (Δn = 0.13) manufactured by BASF or a product name manufactured by HUNSUMAN “CB483” (Δn = 0.08) and the like.

  Any appropriate functional group can be selected as the polymerizable functional group. Examples of the polymerizable functional group include an acryloyl group, a methacryloyl group, an epoxy group, and a vinyl ether group. The polymerizable functional group is preferably an acryloyl group or a methacryloyl group. Since such a polymerizable functional group has high reactivity, a retardation film excellent in transparency, mechanical strength, thermal stability, and dimensional stability can be obtained.

  The thickness of the solidified layer or the cured layer of the liquid crystalline composition containing the calamitic liquid crystal compound aligned in the homeotropic molecular arrangement is appropriately selected depending on the retardation value to be designed and the birefringence of the liquid crystal compound. obtain. The thickness is preferably 0.2 μm to 10 μm, and more preferably 0.2 μm to 5 μm. By setting it as the above range, a thin retardation film having excellent optical uniformity can be obtained.

  The birefringence of the solidified layer or the cured layer of the liquid crystalline composition containing the calamitic liquid crystal compound aligned in the homeotropic molecular arrangement, measured with light having a wavelength of 589 nm at 23 ° C., is preferably 0.04 to 0.20. And more preferably 0.07 to 0.14. By setting the birefringence within the above range, a retardation film that satisfies the optical characteristics described in the above section D-1 and that is thin and excellent in optical uniformity can be obtained.

  The solidified layer or the cured layer of the liquid crystalline composition containing the calamitic liquid crystal compound aligned in the homeotropic molecular arrangement may further contain a polymer liquid crystal represented by the following general formula (I). The polymer liquid crystal is used for the purpose of improving the orientation of the liquid crystal compound.

  In the general formula (I), l is an integer of 14 to 20, and when the sum of m and n is 100, m is 50 to 70 and n is 30 to 50.

  The content (weight ratio) of the polymer liquid crystal is preferably 10 to 40 with respect to the total solid content 100 of the solidified layer or cured layer of the liquid crystalline composition containing the calamitic liquid crystal compound aligned in the homeotropic molecular arrangement. More preferably, it is 15-30.

  A solidified layer or a cured layer of a liquid crystalline composition containing a calamitic liquid crystal compound aligned in a homeotropic molecular arrangement can be obtained, for example, through the following (Step 1) to (Step 3). Specifically, (Step 1) a step of subjecting the surface of the substrate (also referred to as a temporary support) to vertical alignment treatment, (Step 2) a liquid crystalline composition on the surface of the substrate subjected to the vertical alignment treatment And a step of orienting the calamitic liquid crystal compound in the liquid crystalline composition in a homeotropic molecular arrangement, and (step 3) drying and solidifying the liquid crystalline composition. . Preferably, the retardation film is produced through (step 4) a step of irradiating ultraviolet rays to cure the liquid crystalline composition after the above (step 1) to (step 3). The substrate is usually peeled off before the solidified layer or cured layer of the liquid crystalline composition is put to practical use. When it is used for a liquid crystal display device and does not have an adverse effect on practical use, a laminate of a substrate and a solidified layer or a cured layer of a liquid crystalline composition can be used as a positive C plate as it is.

  An example of a method for producing a positive C plate will be described with reference to FIG. In this step, the base material 402 is supplied from the feeding unit 401, conveyed by the guide roll 403, and the alignment agent solution or dispersion is applied in the first coater unit 404. The base material coated with the alignment agent is sent to the first drying means 405, and the solvent is evaporated to form an alignment agent layer (also referred to as alignment film) on the surface. Next, the substrate 406 on which the alignment film is formed is applied with a solution or dispersion liquid of the liquid crystalline composition in the second coater unit 407. The substrate coated with this liquid crystalline composition comprises a calamitic liquid crystal compound in which the solvent is evaporated by the second drying means 408 and the surface thereof is aligned in a homeotropic molecular arrangement. A solidified layer is formed. Next, the substrate 409 on which the solidified layer of the liquid crystalline composition is formed is sent to the ultraviolet irradiation unit 410, and the surface of the solidified layer of the liquid crystalline composition is irradiated with ultraviolet rays, so that the liquid crystalline composition A cured layer is formed. The ultraviolet irradiation unit 410 typically includes an ultraviolet lamp 412 and a temperature control unit 411. Next, the base material 413 on which the cured layer is formed is wound up by the winding unit 414.

  The positive C plate used in the present invention may be a polymer film as long as it satisfies the optical characteristics described in the above section D-1. As a polymer film suitable for the positive C plate, for example, a biaxially stretched film of a polymer film exhibiting negative intrinsic birefringence described in Tosoh Research and Technical Report Vol. 48 (2004 edition), Examples thereof include a polymer film containing a cellulose-based resin in which Rth [590] described in paragraphs [0074] to [0091] of JP-A No. 120352 is negative.

E. Biaxial optical element In the present specification, “biaxial optical element” means that the refractive index in the slow axis direction is nx, the refractive index in the fast axis direction is ny, and the refractive index in the thickness direction is nz. An optical element in which nx, ny, and nz are different and the refractive index ellipsoid has a relationship of nx ≠ ny ≠ nz (where nx ≠ nz). In the biaxial optical element used in the present invention, the refractive index ellipsoid has a relationship of nx>nz> ny. When the relationship of the refractive index ellipsoid; nx>nz> ny is expressed by Re [590] and Rth [590], the biaxial optical element satisfies the following formula (3).

10 nm <Rth [590] <Re [590] (3)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively.

  In the present invention, the biaxial optical element is used together with the positive C plate to reduce light leakage in the oblique direction of the liquid crystal panel. The liquid crystal panel of the present invention can reduce the amount of light leakage by using the positive C plate and the biaxial optical element in a specific positional relationship. As a result, the liquid crystal panel has a high contrast ratio in the oblique direction. A display device can be obtained.

  Referring to FIGS. 2A and 2B, the biaxial optical element 40 is disposed between the liquid crystal cell 10 and the positive C plate 30. The biaxial optical element 40 is arranged so that the slow axis direction thereof is substantially parallel to the absorption axis direction of the first polarizer 21. In this specification, “substantially parallel” means that the angle formed by the slow axis direction of the biaxial optical element and the absorption axis direction of the first polarizer 21 is 0 ° ± 2.0 °. And is preferably 0 ° ± 1.0 °, more preferably 0 ° ± 0.5 °. According to such an embodiment, the long first polarizer, the long positive C plate, and the long biaxial optical element can be sequentially and continuously attached by roll-to-roll. Therefore, manufacturing efficiency can be greatly improved. A liquid crystal display device with a higher contrast ratio in the front and oblique directions can be obtained as the angle difference between the slow axis direction of the biaxial optical element and the absorption axis direction of the first polarizer is smaller.

E-1. Re [590] of the optical properties the biaxial optical element biaxial optical element is greater than 10 nm, and a 2 50 nm or less, particularly preferably 140Nm～230nm. By setting Re [590] in the above range, a liquid crystal display device having a high contrast ratio in an oblique direction can be obtained.

  Rth [590] of the biaxial optical element is smaller than Re [590], preferably 60 nm to 170 nm, more preferably 70 nm to 150 nm, and particularly preferably 110 nm to 130 nm. By setting Rth [590] in the above range, a liquid crystal display device having a high contrast ratio in an oblique direction can be obtained.

  The difference between Rth [590] and Re [590] of the biaxial optical element (Rth [590] −Re [590]) is less than −10 nm, preferably −150 nm to −15 nm, more preferably It is −130 nm to −20 nm, particularly preferably −120 nm to −30 nm. By setting the difference between Rth [590] and Re [590] of the biaxial optical element in the above range, a liquid crystal display device having a high contrast ratio in an oblique direction can be obtained.

  In the biaxial optical element, the Nz coefficient represented by Rth [590] / Re [590] preferably satisfies the following formula (4).

0.2 ≦ Rth [590] / Re [590] ≦ 0.9 (4)
The Nz coefficient is more preferably 0.3 to 0.9, particularly preferably 0.4 to 0.8, and most preferably 0.5 to 0.8. By setting the Nz coefficient in the above range, a liquid crystal display device having a high contrast ratio in an oblique direction can be obtained.

E-2. Arrangement Means of Biaxial Optical Element Referring to FIG. 1, any appropriate method may be adopted as a method of arranging the biaxial optical element 40 depending on the purpose. Preferably, an adhesive layer (not shown) is provided between the biaxial optical element 40 and the positive C plate 30, and between the biaxial optical element 40 and the liquid crystal cell 10, respectively. These optical elements are attached to each other. In this way, by filling the gaps between the optical elements with the adhesive layer, the optical axes of the optical elements can be prevented from shifting when they are incorporated into a liquid crystal display device, or the optical elements can be rubbed and damaged. Can be prevented. Furthermore, since the adverse effects of reflection and refraction generated at the interface between the layers of each optical element can be reduced, a liquid crystal display device capable of displaying a clear image can be obtained.

  The thickness of the adhesive layer can be appropriately selected depending on the purpose. The thickness of the adhesive layer is usually 0.1 μm to 50 μm. By setting the thickness of the adhesive layer in the above range, the optical element and the polarizer to be joined do not float or peel off, and an adhesive force and an adhesive time that do not have a practically adverse effect can be obtained. As a material for forming the adhesive layer, for example, an appropriate material can be appropriately selected from those exemplified in the items C-2 and D-2.

E-3. Configuration of Biaxial Optical Element The configuration (laminated structure) of the biaxial optical element used in the present invention is not particularly limited as long as it satisfies the optical characteristics described in the above section E-1. Specifically, the biaxial optical element may be a retardation film alone or a laminate composed of two or more retardation films. Preferably, the biaxial optical element is composed of a single retardation film. By using a biaxial optical element composed of a single retardation film, a liquid crystal display device having a high contrast ratio in an oblique direction can be obtained. When the biaxial optical element is a laminate, an adhesive layer may be included. When the laminate includes two or more retardation films, these retardation films may be the same or different. Details of the retardation film will be described later in Section E-4.

  Re [590] and Rth [590] of the retardation film used in the biaxial optical element can be appropriately selected depending on the number of retardation films used. For example, when the biaxial optical element is composed of a single retardation film, Re [590] and Rth [590] of the retardation film are Re [590] and Rth [590 of the biaxial optical element. It is preferable to make each equal. Therefore, for example, the retardation value of the adhesive layer used when the biaxial optical element is laminated on the polarizer is preferably as small as possible. For example, when the biaxial optical element is a laminate including two or more retardation films, the sum of Re [590] and Rth [590] of each retardation film is the biaxial optical element. It is preferable to design the device so as to be equal to Re [590] and Rth [590], respectively.

  Specifically, a biaxial optical element having Re [590] of 200 nm and Rth [590] of 120 nm is obtained by using a retardation film having Re [590] of 100 nm and Rth [590] of 60 nm. , And can be obtained by laminating two so that the respective slow axis directions are parallel to each other. In addition, for the sake of simplicity, only the case where the number of retardation films is two or less is illustrated, but it goes without saying that the present invention can also be applied to a laminate including three or more retardation films.

  The total thickness of the biaxial optical element is usually 20 μm to 200 μm, although it varies depending on the configuration.

E-4. Retardation film used for a biaxial optical element Arbitrary appropriate things can be used as a retardation film used for a biaxial optical element. The retardation film is preferably a film that is excellent in transparency, mechanical strength, thermal stability, moisture shielding properties, and the like and is less likely to cause optical unevenness due to strain.

  The thickness of the retardation film can vary depending on the number of laminated films. Typically, the total thickness of the obtained biaxial optical element is preferably set to 20 μm to 200 μm. For example, when the biaxial optical element is composed of a single retardation film, the thickness of the retardation film is preferably 20 μm to 200 μm (that is, equal to the total thickness of the biaxial optical element). ). Also, for example, when the biaxial optical element is a laminate of two retardation films, the thickness of each retardation film is as long as the total is the preferred overall thickness of the biaxial optical element. Any suitable thickness can be employed. Therefore, the thickness of each retardation film may be the same or different. In one embodiment in the case of laminating two retardation films, the thickness of one retardation film is preferably 10 μm to 100 μm.

  The transmittance of the retardation film measured with light having a wavelength of 590 nm at 23 ° C. is usually 80% or more, and preferably 90% or more. The biaxial optical element preferably has the same light transmittance. The theoretical upper limit of the transmittance is 100%, and the realizable upper limit is 96%.

The absolute value (C [590] (m ² / N)) of the photoelastic coefficient of the retardation film is preferably 1 × 10 ^{−12 to} 100 × 10 ⁻¹² , and more preferably 1 × 10 ⁻¹² to 80 × 10 ⁻¹² , particularly preferably 1 × 10 ^{−12 to} 60 × 10 ⁻¹² . By using a photoelastic coefficient whose absolute value is in the above range, a liquid crystal display device excellent in display uniformity can be obtained.

  The variation in the angle of the slow axis (also referred to as the orientation angle) of the retardation film is such that the range of the orientation angle variation at the five measurement points provided at equal intervals in the film width direction is ± 2 ° to ± 1 °. Some are preferably used. More preferably, it is ± 1 ° to ± 0.5 °. By setting the orientation angle in the above range, a liquid crystal display device having excellent display uniformity and capable of displaying a clear image can be obtained. The orientation angle can be appropriately adjusted depending on the stretching means, stretching method, stretching temperature, and stretching ratio described later.

  Preferably, the biaxial optical element used in the present invention includes a retardation film containing a thermoplastic resin exhibiting positive intrinsic birefringence. In this specification, the term “thermoplastic resin exhibiting positive intrinsic birefringence” refers to a direction (slow axis) in which the in-plane refractive index increases when a polymer film containing the resin is stretched in one direction. Direction) is substantially parallel to the stretching direction. If such a polymer film containing a thermoplastic resin exhibiting positive intrinsic birefringence is used, for example, an optical material having the optical characteristics described in the above section E-1 by a stretching method using a shrinkable film described later. An element can be manufactured efficiently.

  Examples of the thermoplastic resin exhibiting positive intrinsic birefringence include general-purpose plastics such as polyolefin resins, cycloolefin resins, polyvinyl chloride resins, cellulose resins, and polyvinylidene chloride resins; polyamide resins and polyacetal resins. General-purpose engineering plastics such as polycarbonate resins, modified polyphenylene ether resins, polybutylene terephthalate resins, polyethylene terephthalate resins; polyphenylene sulfide resins, polysulfone resins, polyether sulfone resins, polyether ether ketone resins, poly Examples thereof include super engineering plastics such as arylate resins, liquid crystalline resins, polyamideimide resins, polyimide resins, and polytetrafluoroethylene resins. Said thermoplastic resin is used individually or in combination of 2 or more types. The thermoplastic resin can be used after any appropriate polymer modification. Examples of the polymer modification include modifications such as copolymerization, crosslinking, molecular terminals, and stereoregularity.

  More preferably, the biaxial optical element used in the present invention includes a retardation film containing a polycarbonate-based resin. The polycarbonate resin can be obtained by a reaction between one or more dihydric phenol compounds and a carbonate precursor. Examples of the method for obtaining the polycarbonate resin include a phosgene method in which phosgene is blown into a dihydric phenol compound in the presence of a caustic alkali and a solvent, or a transesterification of a dihydric phenol compound and bisaryl carbonate in the presence of a catalyst. Examples include a transesterification method.

  Any appropriate compound can be selected as the dihydric phenol compound. Examples of the divalent phenol compound include 2,2-bis (4-hydroxyphenyl) propane, 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane, bis (4-hydroxyphenyl) methane, , 1-bis (4-hydroxyphenyl) ethane, 2,2-bis (4-hydroxyphenyl) butane, 2,2-bis (4-hydroxy-3,5-dipropylphenyl) propane, 1,1-bis (4-hydroxyphenyl) cyclohexane, 1,1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane and the like can be mentioned.

  Any appropriate carbonate precursor can be selected. Examples of the carbonate precursor include phosgene, bischloroformate, diphenyl carbonate, di-p-tolyl carbonate, phenyl-p-tolyl carbonate, di-p-chlorophenyl carbonate, dinaphthyl carbonate, and the like.

  Commercially available polycarbonate resins can be used as they are. Or what carried out arbitrary appropriate polymer modification | denaturation to the commercially available polycarbonate-type resin can be used. Examples of the commercially available polycarbonate-based resin include Panlite series manufactured by Teijin Chemicals Ltd., Caliber series (trade name; 1080DVD) manufactured by Sumitomo Dow Co., Ltd., and the like.

  The thermoplastic resin exhibiting positive intrinsic birefringence preferably has a weight average molecular weight (Mw) measured by a gel permeation chromatograph (GPC) method using a tetrahydrofuran solvent, and is 20,000 to 500,000. More preferably, it is 30,000-200,000. When the weight average molecular weight is in the above range, a material having excellent mechanical strength, good solubility, moldability, and casting operability can be obtained.

  The glass transition temperature (Tg) of the thermoplastic resin exhibiting positive intrinsic birefringence is preferably 110 ° C. to 185 ° C., more preferably 120 ° C. to 170 ° C., and particularly preferably 125 ° C. to 150 ° C. is there. If Tg is 110 ° C. or higher, a film having good thermal stability is easily obtained, and if it is 185 ° C. or lower, in-plane and thickness direction retardation values are easily controlled by stretching. The glass transition temperature (Tg) can be determined by a DSC method according to JIS K7121.

  Any appropriate molding method can be adopted as a method for obtaining a polymer film containing a thermoplastic resin exhibiting positive intrinsic birefringence. Examples of the molding process include compression molding, transfer molding, injection molding, extrusion molding, blow molding, powder molding, FRP molding, and solvent casting. Preferably, the molding method is a solvent casting method. This is because a polymer film excellent in smoothness and optical uniformity can be obtained.

  Specifically, the solvent casting method includes defoaming a concentrated solution (dope) obtained by dissolving a resin composition containing a resin as a main component, an additive, and the like in a solvent, on the surface of an endless stainless belt or a rotating drum, In this method, the film is cast uniformly in a sheet form and the solvent is evaporated. Appropriate conditions can be appropriately selected as conditions employed during film formation depending on the purpose.

  The polymer film containing a thermoplastic resin exhibiting positive intrinsic birefringence may further contain any appropriate additive. Examples of the additive include a plasticizer, a heat stabilizer, a light stabilizer, a lubricant, an antioxidant, an ultraviolet absorber, a flame retardant, a colorant, an antistatic agent, a compatibilizer, a crosslinking agent, and a thickener. Etc. The content (weight ratio) of the additive can be appropriately set according to the purpose. Preferably, the content (weight ratio) of the additive is more than 0 and 20 or less with respect to 100 parts by weight of the thermoplastic resin exhibiting positive intrinsic birefringence.

  The thickness of the polymer film can be appropriately selected depending on the mechanical strength, the retardation value to be designed, and the like. The thickness of the polymer film is usually 20 μm to 200 μm. If it is said range, it is excellent in mechanical strength and can obtain the optical characteristic described in the said E-1 term.

  A commercially available film can be used as it is as the polymer film containing the thermoplastic resin exhibiting positive intrinsic birefringence. Alternatively, a commercially available film that has been subjected to secondary processing such as stretching and / or shrinking can be used. As polymer films containing commercially available polycarbonate resins, Kaneka Corporation Elmec Series (trade name; R film), Teijin Chemicals Co., Ltd. Pure Ace Series (trade name; WR), Nippon GE Plastics Examples include the Illuminex series.

  The retardation film used in the biaxial optical element is, for example, a shrinkable film bonded on both sides of a polymer film containing a thermoplastic resin exhibiting positive intrinsic birefringence, and is uniaxially longitudinally by a roll stretching machine. It can be obtained by heating and stretching by a stretching method. The shrinkable film is used for imparting a shrinkage force in a direction perpendicular to the stretching direction at the time of heat stretching and increasing a refractive index (nz) in the thickness direction. As a method for bonding the shrinkable film to both surfaces of the polymer film, an appropriate method can be appropriately employed. Preferably, a method in which an acrylic pressure-sensitive adhesive layer having an acrylic polymer as a base polymer is bonded between the polymer film and the shrinkable film is excellent in productivity, workability, and economic efficiency. preferable.

  An example of a method for producing the retardation film will be described with reference to FIG. FIG. 5 is a schematic diagram showing a concept of a typical production process of a retardation film used for the second optical element. For example, the polymer film 502 containing a thermoplastic resin exhibiting positive intrinsic birefringence is fed out from the first feeding unit 501, and the second rolls 507 and 508 are used to form the second film on both surfaces of the polymer film 502. The shrinkable film 504 including the pressure-sensitive adhesive layer fed out from the feeding portion 503 and the shrinkable film 506 including the pressure-sensitive adhesive layer fed out from the third feeding portion 505 are bonded together. The polymer film having the shrinkable film attached to both sides is given a tension in the longitudinal direction of the film by rolls 510, 511, 512, and 513 having different speed ratios while being held at a constant temperature by the heating means 509 ( At the same time, the film is subjected to a stretching treatment while being given a tension in the thickness direction by the shrinkable film. The stretched film 518 is stripped of the shrinkable films 504 and 506 together with the pressure-sensitive adhesive layer in the first winding unit 514 and the second winding unit 515, and is wound in the third winding unit 519. It is done.

  The shrinkable film is preferably a stretched film such as a biaxially stretched film or a uniaxially stretched film. The shrinkable film can be obtained, for example, by stretching an unstretched film formed into a sheet by an extrusion method in the longitudinal and / or transverse direction at a predetermined magnification with a simultaneous biaxial stretching machine or the like. The molding and stretching conditions can be appropriately selected depending on the composition, type and purpose of the resin used.

  Examples of the material used for the shrinkable film include polyester, polystyrene, polyethylene, polypropylene, polyvinyl chloride, and polyvinylidene chloride. Preferably, the shrinkable film is a biaxially stretched film containing polypropylene. Since such a shrinkable film is excellent in shrinkage uniformity and heat resistance, a target retardation value can be obtained, and a retardation film excellent in optical uniformity can be obtained.

In one embodiment, the shrinkage ratio in the film longitudinal direction at 140 ° C. of the shrinkable film: S ¹⁴⁰ [MD] is preferably 4.6% to 6.8%, and S ¹⁴⁰ [TD]. Is 6.1% to 9.1%. In another embodiment, the shrinkage ratio in the longitudinal direction of the shrinkable film at 160 ° C .: S ¹⁶⁰ [MD] is preferably 14.4% to 21.6%, and S ¹⁶⁰ [TD] is 28.6. % To 42.8%. By setting the shrinkage rate at each temperature of the shrinkable film within the above range, a retardation film having a target retardation value and excellent in uniformity can be obtained.

In one embodiment, the difference between the shrinkage in the width direction and the shrinkage in the longitudinal direction at 140 ° C. of the shrinkable film: ΔS ¹⁴⁰ = S ¹⁴⁰ [TD] −S ¹⁴⁰ [MD] is preferably 1.5. % To 2.3%. In another embodiment, the difference between the shrinkage in the width direction and the shrinkage in the longitudinal direction at 160 ° C. of the shrinkable film: ΔS ¹⁶⁰ = S ¹⁶⁰ [TD] −S ¹⁶⁰ [MD] is preferably 14.2. % To 21.2%. If the shrinkage rate in the MD direction is large, in addition to stretching tension, the shrinking force of the shrinkable film may be applied to a stretching machine, making uniform stretching difficult. By setting the shrinkage rate of the shrinkable film in the above range, uniform stretching can be performed without applying an excessive load to equipment such as a stretching machine.

The shrinkage stress in the width direction at 140 ° C. of the shrinkable film: T ¹⁴⁰ [TD] is preferably 0.36 N / 2 mm to 0.54 N / 2 mm. The shrinkage stress in the width direction at 150 ° C. of the shrinkable film: T ¹⁵⁰ [TD] is preferably 0.45 N / 2 mm to 0.67 N / 2 mm. By setting the shrinkage rate of the shrinkable film in the above range, a retardation film having a target retardation value and excellent in optical uniformity can be obtained.

  The shrinkage rates S [MD] and S [TD] can be determined according to the method of heating shrinkage rate A of JIS Z 1712-1997 (however, the heating temperature is 140 ° C (or 160 ° C) instead of 120 ° C). And a load of 3 g was added to the test piece). Specifically, five test pieces each having a width of 20 mm and a length of 150 mm were taken from the vertical [MD] and horizontal [TD] directions, and a test piece with a mark at a distance of about 100 mm was prepared at the center of each. To do. The test piece is suspended vertically in an air circulation type drying oven maintained at a temperature of 140 ° C. ± 3 ° C. (or 160 ° C. ± 3 ° C.) under a load of 3 g, heated for 15 minutes, and then taken out. Further, after being left in the standard state (room temperature) for 30 minutes, the distance between the gauge points is measured using a caliper specified in JIS B 7507, and the average value of the five measured values is obtained. Shrinkage is expressed by the following equation: S (%) = [[Distance between gauge points before heating (mm) −Distance between gauge points after heating (mm)] / Distance between gauge points before heating (mm)] × 100 Can be calculated.

In addition, the shrinkable film can be used for general packaging, food packaging, pallet packaging, shrinkage label, cap seal, and electrical insulation as long as the object of the present invention is satisfied. A commercially available shrinkable film can be appropriately selected and used. These commercially available shrinkable films may be used as they are, or after being subjected to secondary processing such as stretching treatment or shrinkage treatment. Examples of commercially available shrinkable films include, for example, Oji Paper Co., Ltd., Alfane Series (trade name; Alphan P, Alphan S, Alphan H, etc.), Gunze Co., Ltd., Fancy Top Series (trade name; Fancy). Top EP1, Fancy Top EP2, etc.) Toray Industries BO series (trade name; 2570, 2873, 2500, 2554, M114, M304, etc.) manufactured by Toray Industries, Inc., Santox Co., Ltd. Santox-OP series (PA20, PA21) And Tosero OP series (trade names; OPU-0, OPU-1, OPU-2, etc.) and the like.

  The temperature in the stretching oven (also referred to as the stretching temperature) when heating and stretching the laminate of the polymer film containing the thermoplastic resin exhibiting positive intrinsic birefringence and the shrinkable film is the target retardation value, It can be appropriately selected according to the type and thickness of the polymer film used. The stretching temperature is preferably Tg + 1 ° C. to Tg + 30 ° C. with respect to the glass transition temperature (Tg) of the polymer film. By setting it as said temperature range, the retardation value of a retardation film becomes easy to become uniform, and it becomes difficult to crystallize (white turbidity) a film. Specifically, the stretching temperature is usually 110 ° C to 185 ° C. The glass transition temperature (Tg) can be determined by a DSC method according to JIS K 7121-1987.

  Furthermore, the stretching ratio (stretching ratio) when stretching a laminate of a polymer film containing a thermoplastic resin exhibiting positive intrinsic birefringence and a shrinkable film is the target retardation value, the polymer used. It can be appropriately selected according to the type and thickness of the film. The draw ratio is usually more than 1 and less than 2 times the original length. The feeding speed during stretching is usually 1 m / min to 20 m / min from the viewpoint of mechanical accuracy and stability of the stretching apparatus. If it is said extending | stretching conditions, not only the optical characteristic of the said E-1 term can be satisfied, but the retardation film excellent in optical uniformity can be obtained.

F. Liquid Crystal Display Device FIG. 6 is a schematic cross-sectional view of a liquid crystal display device according to a preferred embodiment of the present invention. It should be noted that, for the sake of easy understanding, the ratio of the vertical, horizontal, and thickness of each component shown in FIG. 6 is different from the actual ratio. The liquid crystal display device 200 includes a liquid crystal panel 100, protective layers 60 and 60 'disposed on both sides of the liquid crystal panel 100, and surface treatment layers 70 and 70' disposed further outside the protective layers 60 and 60 '. And a backlight unit 80 disposed on the outside (backlight side) of the surface treatment layer 70 ′. The backlight unit 80 includes a backlight 81, a reflection film 82, a diffusion plate 83, a prism sheet 84, and a brightness enhancement film 85. By using these optical members, a liquid crystal display device having further excellent display characteristics can be obtained. In addition, as long as the effect of the present invention is obtained, a part of the optical member illustrated in FIG. 6 can be omitted depending on the application, such as the illumination method of the liquid crystal display device and the driving mode of the liquid crystal cell, or Other optical members can be substituted.

  Any appropriate layer can be adopted as the protective layer. The protective layer is used for preventing the polarizer from contracting and expanding, and preventing deterioration due to ultraviolet rays. The protective layer is preferably a polymer film containing a cellulose resin or a norbornene resin. The thickness of the polymer film is usually 10 μm to 200 μm. In addition, the said protective layer may serve as the base film of the surface treatment layer mentioned later. As the protective layer, a commercially available polymer film can be used as it is. Alternatively, a commercially available polymer film can be used after being subjected to a surface treatment described later. Examples of the polymer film containing a commercially available cellulose resin include Fujitac series manufactured by Fuji Photo Film Co., Ltd., and trade name “KC8UX2M” manufactured by Konica Minolta Opto. Examples of the polymer film containing a commercially available norbornene-based resin include Arton series manufactured by JSR Corporation, Zeonore series manufactured by Optes Corporation.

  As the surface treatment layer, a treatment layer subjected to a hard coat treatment, an antistatic treatment, an antireflection treatment (also referred to as an antireflection treatment), a diffusion treatment (also referred to as an antiglare treatment), or the like is used. These surface treatment layers are used for the purpose of preventing the screen from being soiled or damaged, or preventing the display image from becoming difficult to see due to the reflection of indoor fluorescent light or sunlight on the screen. In general, the surface treatment layer is formed by fixing a treatment agent for forming the treatment layer on the surface of a base film. The base film may also serve as the protective layer. Further, the surface treatment layer may have a multilayer structure in which, for example, a hard coat treatment layer is laminated on an antistatic treatment layer. As the surface treatment layer, a commercially available surface treatment layer can be used as it is. Examples of the commercially available film subjected to the hard coat treatment and the antistatic treatment include “KC8UX-HA” manufactured by Konica Minolta Opto Co., Ltd. Examples of the commercially available surface treatment layer that has been subjected to the antireflection treatment include ReaLook series manufactured by NOF Corporation.

  Any appropriate illumination method can be adopted as the illumination method of the liquid crystal display device in which the liquid crystal panel of the present invention is used. Specific examples of the illumination method include a transmissive type in which a backlight is used as a light source and viewed by irradiating light from the back surface, a reflective type in which external light is applied to the screen, and a transflective type having both properties. It is done. The illumination method is preferably a transmission type. When the direct unit is adopted as the irradiation method, the backlight unit is generally composed of a backlight, a reflection film, a diffusion plate, a prism sheet, and a brightness enhancement film. When the edge light system is adopted, a light guide plate and a light reflector are further used in addition to the configuration of the direct system.

  Any appropriate backlight can be adopted as the backlight. Examples of the backlight include a cold cathode fluorescent tube (CCFL), a light emitting diode (LED), an organic EL (OLED), and a field emission device (FED). In the case where a cold cathode fluorescent tube is employed for the backlight, examples of the irradiation method include “directly underneath” that irradiates from directly below the liquid crystal and “edge light” that irradiates from the lateral end of the liquid crystal. The direct method has an advantage that high luminance can be obtained. The edge light method has an advantage that the liquid crystal display device can be made thinner than the direct light method, and further, the influence of heat from the light source to each component can be reduced. When a light emitting diode is employed for the backlight, the color of the light source may be white or RGB three colors. When an RGB three-color light source is used for the light emitting diode, a field sequential type liquid crystal display device capable of color display without using a color filter can be obtained.

  The reflective film is used to prevent light from being lost to the side opposite to the viewing side of the liquid crystal panel and to make the light of the backlight enter the light guide plate efficiently. As the reflective film, for example, a polyethylene terephthalate film on which silver is vapor-deposited or a laminated film in which a polyester resin is laminated in multiple layers is used. The reflectance of the reflective film is preferably 90% or more over the entire wavelength range of 410 nm to 800 nm. The thickness of the reflective film is usually 50 μm to 200 μm. As the reflective film, a commercially available reflective film can be used as it is. As a commercially available reflective film, for example, Lemon White series manufactured by Kimoto Co., Ltd., Vicuity ESR series manufactured by Sumitomo 3M Co., Ltd. and the like can be mentioned.

  The light guide plate is used to spread light from the backlight over the entire screen. As the light guide plate, for example, an acrylic resin, a polycarbonate resin, a cycloolefin resin, or the like formed into a tapered shape so that the thickness decreases as the distance from the light source increases.

  The diffusion plate is used to guide light emitted from the light guide plate to a wide angle and make the screen uniform brightness. As the diffusion plate, for example, a polymer film that has been subjected to uneven treatment or a polymer film containing a diffusion agent is used. The haze of the diffusion plate is preferably 85% to 92%. Furthermore, the total light transmittance of the diffusing plate is preferably 90% or more. As the diffusion plate, a commercially available diffusion plate can be used as it is. Examples of the commercially available diffusion plate include OPLUS series manufactured by Eiwa Co., Ltd. and Light-up series manufactured by Kimoto Co., Ltd.

  The prism sheet is used to collect light having a wide angle by the light guide plate in a specific direction and improve the luminance in the front direction of the liquid crystal display device. As the prism sheet, for example, a sheet in which a prism layer made of an acrylic resin or a photosensitive resin is laminated on the surface of a base film made of a polyester resin is used. As the prism sheet, a commercially available prism sheet can be used as it is. As a commercially available prism sheet, for example, Mitsubishi Rayon Co., Ltd. Diamond Art Series can be mentioned.

  The said brightness improvement film is used in order to improve the brightness | luminance of the front of a liquid crystal display device, and a diagonal direction. A commercially available brightness enhancement film can be used as it is. Examples of commercially available brightness enhancement films include the NIPOCS PCF series manufactured by Nitto Denko Corporation, the Vicuity DBEF series manufactured by Sumitomo 3M Limited, and the like.

  In the liquid crystal display device including the liquid crystal panel of the present invention, the average value of the contrast ratio in a polar angle of 60 ° and in all directions (0 ° to 360 °) when displaying a black image is preferably 60 or more. Preferably it is 80 or more, Most preferably, it is 100 or more. As the contrast ratio in the oblique direction is increased, a liquid crystal display device having a wide viewing angle can be obtained.

G. Application of Liquid Crystal Panel of the Present Invention A liquid crystal display device comprising the liquid crystal panel of the present invention is used for any appropriate application. Applications include, for example, OA equipment such as personal computer monitors, notebook computers, and copiers, mobile phones, watches, digital cameras, personal digital assistants (PDAs), portable devices such as portable game machines, video cameras, televisions, microwave ovens, etc. Home appliances, back monitors, car navigation system monitors, car audio and other in-vehicle equipment, exhibition equipment such as commercial store information monitors, security equipment such as surveillance monitors, nursing care monitors, medical monitors, etc. Nursing care / medical equipment.

  Preferably, the use of the liquid crystal display device including the liquid crystal panel of the present invention is a television. The screen size of the television is preferably a wide 17 type (373 mm × 224 mm) or more, more preferably a wide 23 type (499 mm × 300 mm) or more, and particularly preferably a wide 26 type (566 mm × 339 mm) or more. Most preferably, it is a wide 32 type (687 mm × 412 mm) or more.

The present invention will be further described using the above examples and comparative examples. In addition, this invention is not limited only to these Examples. In addition, each analysis method used in the Example is as follows.
(1) Measuring method of moisture content of polarizer:
Using a Karl Fascher moisture meter [Kyoto Electronics Industry Co., Ltd., product name “MKA-610”], a sample cut into a size of 10 mm × 30 mm was placed in a heating furnace at 150 ° C. ± 1 ° C., and nitrogen gas (200 ml / min. ) Was bubbled into the titration cell solution and measured.
(2) Measuring method of single transmittance and polarization degree of polarizer:
It measured at 23 degreeC using the spectrophotometer [Murakami Color Research Laboratory Co., Ltd. product name "DOT-3"].
(3) Molecular weight measurement method:
Polystyrene was calculated as a standard sample by the gel permeation chromatograph (GPC) method. Specifically, it measured with the following apparatuses, instruments, and measurement conditions.
・ Analyzer: “HLC-8120GPC” manufactured by TOSOH
Column: TSKgel Super HM-H / H4000 / H3000 / H2000
Column size: 6.0 mmI. D. × 150mm
-Eluent: Tetrahydrofuran-Flow rate: 0.6 ml / min.
・ Detector: RI
-Column temperature: 40 ° C
・ Injection volume: 20 μl
(4) Measuring method of thickness:
When the thickness was less than 10 μm, measurement was performed using a thin film spectrophotometer [manufactured by Otsuka Electronics Co., Ltd., “instant multiphotometry system MCPD-2000”]. When the thickness was 10 μm or more, measurement was performed using an Anritsu digital micrometer “KC-351C type”.
(5) Measuring method of average refractive index of film:
It calculated | required from the refractive index measured with the light of wavelength 589nm in 23 degreeC using the Abbe refractometer [The product name "DR-M4" by Atago Co., Ltd.].
(6) Measuring method of phase difference values (Re, Rth):
It measured with the light of wavelength 590nm in 23 degreeC using the phase difference meter [Oji Scientific Instruments Co., Ltd. product name "KOBRA21-ADH"] based on a parallel Nicol rotation method.
(7) Measuring method of transmittance (T [590]):
It measured with the light of wavelength 590nm in 23 degreeC using the ultraviolet visible spectrophotometer [The product name "V-560" by JASCO Corporation].
(8) Measuring method of absolute value (C [590]) of photoelastic coefficient:
Using a spectroscopic ellipsometer [product name “M-220” manufactured by JASCO Corporation], the sample (size 2 cm × 10 cm) is sandwiched at both ends and stress (5 to 15 N) is applied to the phase difference at the center of the sample. The value (23 ° C./wavelength 590 nm) was measured and calculated from the slope of the function of stress and retardation value.
(9) Measuring method of shrinkage rate of shrinkable film:
It was determined according to the heat shrinkage ratio A method of JIS Z 1712-1997 (however, the heating temperature was changed to 140 ° C. (or 160 ° C.) instead of 120 ° C., and a load of 3 g was added to the test piece). Specifically, five test pieces each having a width of 20 mm and a length of 150 mm were taken from the vertical [MD] and horizontal [TD] directions, and a test piece with a mark at a distance of about 100 mm was prepared at the center of each. To do. The test piece was suspended vertically in an air circulation drying oven maintained at a temperature of 140 ° C. ± 3 ° C. (or 160 ° C. ± 3 ° C.) with a load of 3 g, heated for 15 minutes, taken out, and standard. After standing in the state (room temperature) for 30 minutes, the distance between the gauge points was measured using a caliper specified in JIS B 7507, and the average value of the five measured values was obtained. S (%) = [[[ Distance between gauge points before heating (mm) −Distance between gauge points after heating (mm)] / Distance between gauge points before heating (mm)] × 100.
(10) Measuring method of shrinkage stress of shrinkable film:
Using the following apparatus, the shrinkage stress T ¹⁴⁰ [TD] and the shrinkage stress T ¹⁵⁰ [TD] in the width [TD] direction at 140 ° C. and 150 ° C. were measured by the TMA method.
・ Equipment: “TMA / SS 6100” manufactured by Seiko Instruments Inc.
Data processing: “EXSTAR6000” manufactured by Seiko Instruments Inc.
・ Measurement mode: Constant temperature rise measurement (10 ℃ / min)
・ Measurement atmosphere: In air (23 ℃)
・ Load: 20mN
Sample size: 15mm x 2mm (long side is width [TD] direction)
(11) Measuring method of contrast ratio of liquid crystal display device:
After 30 minutes have passed since the backlight was turned on in a dark room at 23 ° C., a white image at an azimuth angle of 0 ° to 360 ° and a polar angle of 60 ° using a product name “EZ Contrast 160D” manufactured by ELDIM And the Y value of the XYZ display system when displaying a black image was measured. The contrast ratio “YW / YB” in the oblique direction was calculated from the Y value (YW) in the white image and the Y value (YB) in the black image. The long side of the liquid crystal panel was set to an azimuth angle of 0 °, and the normal direction was set to a polar angle of 0 °.

Production of Polarizer [Reference Example 1]
Polymer film mainly composed of polyvinyl alcohol [trade name “9P75R (thickness: 75 μm, average degree of polymerization: 2,400, degree of saponification: 99.9 mol%)” manufactured by Kuraray Co., Ltd.]] at 30 ° C. ± 3 In a dyeing bath containing iodine and potassium iodide held at ° C., the film was uniaxially stretched 2.5 times while dyeing using a roll stretching machine. Subsequently, it was uniaxially stretched so as to be 6 times the original length of the polymer film while performing a crosslinking reaction in an aqueous solution containing boric acid and potassium iodide maintained at 60 ± 3 ° C. The obtained film was dried in an air circulation type thermostatic oven at 50 ° C. ± 1 ° C. for 30 minutes to obtain polarizers P1 and P2. The optical characteristics of the polarizers P1 and P2 are as shown in Table 1.

Preparation of positive C plate [Reference Example 2]
Commercially available polyethylene terephthalate film [trade name “S-27E” manufactured by Toray Industries, Inc. (thickness: 75 μm)] and ethyl silicate solution [manufactured by Colcoat Co., Ltd. (mixed solution of ethyl acetate and isopropyl alcohol, 2 wt%)] is gravure It was coated with a coater and dried in an air circulation type constant temperature oven at 130 ° C. ± 1 ° C. for 1 minute to form a glassy polymer film having a thickness of 0.1 μm on the surface of the polyethylene terephthalate film.

Next, 5 parts by weight of a polymer liquid crystal (weight average molecular weight: 5,000) represented by the following formula (II) and a calamitic liquid crystal compound having two polymerizable functional groups in a part of the molecular structure [manufactured by BSAF, product 20 parts by weight of the name “Pariocolor LC242” (ne = 1.654, no = 1.523)] and 1.25 parts by weight of a photopolymerization initiator [Ciba Specialty Chemicals, Inc., trade name “Irgacure 907”] A solution of the liquid crystalline composition was prepared by dissolving in 75 parts by weight of cyclohexanone. This solution was coated on the glassy polymer film of the polyethylene terephthalate film using a rod coater, dried for 2 minutes in an air circulating constant temperature oven at 80 ° C. ± 1 ° C., and then brought to room temperature (23 ° C.). Then, a solidified layer of a liquid crystalline composition aligned in a homeotropic molecular arrangement was formed on the surface of the polyethylene terephthalate film. Next, the solidified layer was irradiated with ultraviolet rays having an irradiation light amount of 400 mJ / cm ² (in an air atmosphere) to cure the calamitic liquid crystal compound by a polymerization reaction. The polyethylene terephthalate film was peeled off, and a cured layer of a liquid crystalline composition containing a calamitic liquid crystal compound aligned in a homeotropic molecular arrangement was obtained. The said hardened layer is made into retardation film 1-A, and the characteristic is shown in Table 2 together with the film characteristic of the below-mentioned reference examples 3-5. In each of the retardation films obtained in Reference Examples 2 to 5, the refractive index ellipsoid satisfied the relationship of nz> nx≈ny.

[Reference Example 3]
A retardation film 1-B was produced in the same manner as in Reference Example 2 except that the coating thickness of the liquid crystal composition solution was changed. Table 2 shows the properties of the retardation film 1-B.

[Reference Example 4]
A retardation film 1-C was produced in the same manner as in Reference Example 2, except that the coating thickness of the liquid crystal composition solution was changed. Table 2 shows the properties of the retardation film 1-C.

[Reference Example 5]
A retardation film 1-D was produced in the same manner as in Reference Example 2, except that the coating thickness of the liquid crystal composition solution was changed. Table 2 shows the properties of the retardation film 1-D.

Preparation of biaxial optical element [Reference Example 6]
Polymer film containing polycarbonate resin having a thickness of 55 μm [“Elmec” manufactured by Kaneka Corporation (weight average molecular weight = 60,000, average refractive index = 1.53, Tg = 136 ° C., Re [590] = 1. 0 nm, Rth [590] = 3.0 nm)] on both sides of a biaxially stretched film [trade name “Torphan BO2570A” manufactured by Toray Industries, Inc.] containing polypropylene having a thickness of 60 μm and an acrylic pressure-sensitive adhesive layer (thickness 15 μm). ). Thereafter, the film longitudinal direction is maintained with a roll stretching machine, and the film is stretched 1.25 times in an air circulation oven at 140 ° C. After stretching, the biaxially stretched film containing the polypropylene is transformed into the acrylic pressure-sensitive adhesive layer. Then, it was peeled off to produce a retardation film. The retardation film is a retardation film 2-A, and the characteristics thereof are shown in Table 3 together with film characteristics of Reference Examples 7 and 8 described later. In the retardation films obtained in Reference Examples 6 to 8, the refractive index ellipsoid satisfied the relationship of nx>nz> ny. The physical properties of the biaxially stretched film (shrinkable film) containing the polypropylene are shown in Table 4.

[Reference Example 7]
A retardation film 2-B was produced in the same manner as in Reference Example 6 except that the stretching temperature was 145 ° C. and the stretching ratio was 1.23 times. Table 3 shows the characteristics of the retardation film 2-B.

[Reference Example 8]
A retardation film 2-C was produced in the same manner as in Reference Example 6 except that the stretching temperature was 140 ° C. and the stretching ratio was 1.15 times. Table 3 shows the characteristics of the retardation film 2-C.

Preparation of liquid crystal cell [Reference Example 9]
A liquid crystal panel is taken out from a liquid crystal display device including a liquid crystal cell of IPS mode [32V type wide liquid crystal television manufactured by Toshiba Corporation, product name “FACE (model number: 32LC100)”, screen size: 697 mm × 392 mm)]. All of the optical films arranged above and below were removed, and the glass surfaces (front and back) of the liquid crystal cell were washed. The liquid crystal cell thus prepared was designated as liquid crystal cell A.

Production of liquid crystal panel and liquid crystal display device [Example 1]
Retardation film 2-A obtained in Reference Example 6 as a biaxial optical element on the surface on the viewing side of liquid crystal cell A obtained in Reference Example 9 via an acrylic pressure-sensitive adhesive layer (thickness 23 μm). (The refractive index ellipsoid has a relationship of nx>nz> ny), the slow axis direction thereof is substantially parallel to the long side direction of the liquid crystal cell A (0 ° ± 0.5 °). Stuck. Subsequently, the retardation film 1-A (refractive index ellipsoid) obtained in Reference Example 2 was formed as a positive C plate on the surface of the retardation film 2-A through an acrylic pressure-sensitive adhesive layer (thickness: 23 μm). Have a relationship of nz> nx≈ny). Next, the polarizer P1 obtained in Reference Example 1 is used as the first polarizer via the adhesive layer (thickness 1 μm) on the surface of the retardation film 1-A. The liquid crystal cell A was attached so as to be substantially parallel to the long side direction (0 ° ± 0.5 °). At this time, the initial alignment direction of the liquid crystal cell A, the slow axis direction of the retardation film 2-A (biaxial optical element), and the absorption axis direction of the polarizer P1 (first polarizer) Are substantially orthogonal. Next, a triacetylcellulose film [trade name “ZRF80S” manufactured by Fuji Photo Film Co., Ltd.] is used as a protective layer on the backlight side surface of the liquid crystal cell A via an acrylic adhesive layer (thickness: 23 μm). (Average refractive index = 1.48, thickness 80 μm, Re [590] = 1.0 nm, Rth [590] = 3.1 nm)]. Subsequently, the polarizer P2 obtained in Reference Example 1 is used as the second polarizer through the adhesive layer (thickness 1 μm) on the surface of the protective layer. It was stuck so as to be substantially orthogonal (90 ° ± 0.5 °) to the long side direction. At this time, the absorption axis direction of the polarizer P1 and the absorption axis direction of the polarizer P2 are substantially orthogonal. The initial alignment direction of the liquid crystal cell A and the absorption axis direction of the polarizer P2 (second polarizer) are substantially parallel. A triacetylcellulose film [Fuji Photo Film Co., Ltd. Fujitac UZ (Fuji Photo Film Co., Ltd.) is provided as a protective layer on the outside of the polarizers P1 and P2 (on the side opposite to the liquid crystal cell) through an adhesive layer (thickness 1 μm). Each having a thickness of 80 μm).

  The liquid crystal panel A thus produced has a configuration shown in FIG. The liquid crystal panel A was combined with a backlight unit to produce a liquid crystal display device A. The liquid crystal display device A immediately after turning on the backlight had good display uniformity over the entire surface. After 30 minutes had passed since the backlight was turned on, the contrast ratio in the oblique direction of the liquid crystal display device A was measured. The characteristics of the obtained liquid crystal display device A are shown in Table 5 below together with the characteristics of Examples 2 to 5 and Comparative Examples 1 and 2 described later.

[Example 2]
A liquid crystal panel B was produced in the same manner as in Example 1 except that the retardation film 2-B obtained in Reference Example 7 was used as the biaxial optical element. The liquid crystal panel B thus produced has a configuration shown in FIG. This liquid crystal panel B was combined with a backlight unit to produce a liquid crystal display device B. The characteristics of the liquid crystal display device B are as shown in Table 5.

[Example 3]
Example 1 except that the retardation film 1-B obtained in Reference Example 3 was used as the positive C plate, and the retardation film 2-C obtained in Reference Example 8 was used as the biaxial optical element. A liquid crystal panel C was produced in the same manner as described above. The liquid crystal panel C produced in this way has a configuration shown in FIG. This liquid crystal panel C was combined with a backlight unit to produce a liquid crystal display device C. The characteristics of the liquid crystal display device C are as shown in Table 5.

[Example 4]
Example 1 except that the retardation film 1-C obtained in Reference Example 4 was used as the positive C plate, and the retardation film 2-C obtained in Reference Example 8 was used as the biaxial optical element. A liquid crystal panel D was produced in the same manner as described above. The liquid crystal panel D thus produced has a configuration shown in FIG. The liquid crystal panel D was combined with a backlight unit to produce a liquid crystal display device D. The characteristics of the liquid crystal display device D are as shown in Table 5.

[Example 5]
Example 1 except that the retardation film 1-D obtained in Reference Example 5 was used as the positive C plate, and the retardation film 2-C obtained in Reference Example 8 was used as the biaxial optical element. A liquid crystal panel E was produced in the same manner as described above. The liquid crystal panel E produced in this way has a configuration shown in FIG. This liquid crystal panel E was combined with a backlight unit to produce a liquid crystal display device E. The characteristics of the liquid crystal display device E are as shown in Table 5.

[Comparative Example 1]
The biaxial optical element is the same as that of Example 1 except that the slow axis direction is arranged so as to be substantially orthogonal (90 ° ± 0.5 °) to the absorption axis direction of the first polarizer. The liquid crystal panel L was produced by this method. The liquid crystal panel L thus produced has the configuration shown in FIG. This liquid crystal panel L was combined with a backlight unit to produce a liquid crystal display device L. The characteristics of the liquid crystal display device L are as shown in Table 5.

[Comparative Example 2]
A liquid crystal panel M was produced in the same manner as in Example 1 except that the biaxial optical element was not used. The liquid crystal panel M thus produced has a configuration shown in FIG. This liquid crystal panel M was combined with a backlight unit to produce a liquid crystal display device M. The characteristics of the liquid crystal display device M are as shown in Table 5.

[Comparative Example 3]
A liquid crystal panel N was produced in the same manner as in Example 1 except that the positive C plate was not used. The liquid crystal panel N thus produced has a configuration shown in FIG. The liquid crystal panel N was combined with a backlight unit to produce a liquid crystal display device N. The characteristics of the liquid crystal display device N are as shown in Table 5.

[Evaluation]
As shown in Examples 1 to 5, a positive C plate in which a refractive index ellipsoid has a relationship of nz> nx≈ny between a liquid crystal cell and a polarizer disposed on one side of the liquid crystal cell; A liquid crystal display device including a liquid crystal panel using a biaxial optical element having a refractive index ellipsoid having a relationship of nx>nz> ny in a specific positional relationship has a high contrast ratio in an oblique direction. On the other hand, as shown in Comparative Example 1, a liquid crystal display device using a liquid crystal panel in which the slow axis direction of the biaxial optical element and the absorption axis direction of the first polarizer are substantially orthogonal is an oblique direction. The contrast ratio was low. Further, as shown in Comparative Examples 2 and 3, the liquid crystal display device that does not use one of the biaxial optical element and the positive C plate also has a low contrast ratio in the oblique direction.

  As described above, according to the liquid crystal panel of the present invention, since the contrast ratio in the oblique direction can be increased, it can be said that it is extremely useful for improving the display characteristics of the liquid crystal display device. A liquid crystal display device comprising the liquid crystal panel of the present invention is suitably used for a liquid crystal television.

It is a schematic sectional drawing of the liquid crystal panel by preferable embodiment of this invention. (A) is a schematic perspective view in case the liquid crystal panel of FIG. 1 employ | adopts O mode, (b) is a schematic perspective view in case the liquid crystal panel of FIG. 1 employ | adopts E mode. It is a schematic diagram which shows the concept of the typical manufacturing process of the polarizer used for this invention. It is a schematic diagram which shows the concept of the typical manufacturing process of the positive C plate used for this invention. It is a schematic diagram which shows the concept of the typical manufacturing process of the biaxial optical element used for this invention. 1 is a schematic cross-sectional view of a liquid crystal display device according to a preferred embodiment of the present invention. 6 is a schematic perspective view of a liquid crystal panel used in Comparative Example 1. FIG. 10 is a schematic perspective view of a liquid crystal panel used in Comparative Example 2. FIG. 10 is a schematic perspective view of a liquid crystal panel used in Comparative Example 3. FIG.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 Liquid crystal cell 11, 11 'Board | substrate 12 Liquid crystal layer 21 1st polarizer 22 2nd polarizer 30 Positive C plate 40 Biaxial optical element 60, 60' Protective layer 70, 70 'Surface treatment layer 80 Backlight unit 81 Backlight 82 Reflective film 83 Diffusion plate 84 Prism sheet 85 Brightness enhancement film 100, 101, 102 Liquid crystal panel 200 Liquid crystal display device 300 Feeding section 310 Iodine aqueous solution bath 320 Aqueous solution bath containing boric acid and potassium iodide 330 Iodination Aqueous solution bath 340 containing potassium Drying means 350 Polarizer 360 Winding unit 401, 404 Feeding unit 405, 408 Drying unit 407 Coater 410 Ultraviolet irradiation unit 411 Temperature control unit 412 Ultraviolet lamp 414 Winding unit 501, 503, 505 Feeding unit 514 516, 519 It takes part 504,506 shrinkable film 507, 508 laminate roll 509 heating means

Claims (11)

A liquid crystal cell; a first polarizer disposed on one side of the liquid crystal cell; and a liquid crystal cell disposed between the liquid crystal cell and the first polarizer via an adhesive layer At least a bonded positive C plate, a biaxial optical element disposed between the liquid crystal cell and the positive C plate, and a second polarizer disposed on the other side of the liquid crystal cell. Prepared,
The absorption axis direction of the first polarizer is substantially perpendicular to the absorption axis direction of the second polarizer;
The positive C plate has a refractive index ellipsoid of nz> nx≈ny,
In the biaxial optical element, the refractive index ellipsoid has a relationship of nx>nz> ny, Re [590] is greater than 10 nm and less than or equal to 250 nm, and the slow axis direction thereof is the first polarized light. Ri absorption axis direction substantially parallel der child,
It said liquid crystal cell, Ru comprises a liquid crystal layer containing liquid crystal molecules an electric field is oriented in homogeneous molecular alignment in the absence of a liquid crystal panel:
However, Re [590] is an in-plane retardation value measured with light having a wavelength of 590 nm at 23 ° C., the refractive index in the slow axis direction is nx, the refractive index in the fast axis direction is ny, and the thickness direction is The refractive index is nz. The initial alignment direction of the liquid crystal cell, a second polarizer substantially parallel to the absorption axis direction of the liquid crystal panel according to claim 1. The liquid crystal panel according to claim 1 or 2 , wherein the positive C plate satisfies the following formulas (1) and (2):
Re [590] <10 nm (1)
Rth [590] <− 10 nm (2)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively. The positive C plate includes a solidified layer or cured layer of a liquid crystal composition containing a calamitic liquid crystal compound is oriented in homeotropic arrangement, the liquid crystal panel according to any one of claims 1 to 3. The positive C plate includes a polymer film containing a cellulose resin, a liquid crystal panel according to any one of claims 1 to 4. The biaxial optical element satisfies the following formula (3), the liquid crystal panel according to any one of claims 1 5:
10 nm <Rth [590] <Re [590] (3)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively. The biaxial optical element satisfies the following formula (4), the liquid crystal panel according to any one of claims 1 to 6:
0.2 ≦ Rth [590] / Re [590] ≦ 0.9 (4)
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively. The difference between Rth [590] and Re [590] of the biaxial optical element (Rth [590] −Re [590]) is less than −10 nm and not less than −130 nm, and any one of claims 1 to 7 LCD panel described in:
However, Re [590] and Rth [590] are an in-plane retardation value and a thickness direction retardation value measured with light having a wavelength of 590 nm at 23 ° C., respectively. The biaxial optical element comprises a retardation film containing a polycarbonate resin, a liquid crystal panel according to any one of claims 1 to 8. A liquid crystal panel according to any of claims 1 to 9, the liquid crystal display device. The liquid crystal display device according to claim 10 used in a television.