JP4844034B2 - Rubber composition - Google Patents
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- JP4844034B2 JP4844034B2 JP2005217256A JP2005217256A JP4844034B2 JP 4844034 B2 JP4844034 B2 JP 4844034B2 JP 2005217256 A JP2005217256 A JP 2005217256A JP 2005217256 A JP2005217256 A JP 2005217256A JP 4844034 B2 JP4844034 B2 JP 4844034B2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
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Description
本発明は、ゴム組成物に関し、更に詳しくは耐摩耗性を損なうことなくウェットスキッド性能や転がり抵抗が改良されたゴム組成物並びにそれを用いた空気入りタイヤに関する。 The present invention relates to a rubber composition, and more particularly to a rubber composition having improved wet skid performance and rolling resistance without impairing wear resistance, and a pneumatic tire using the same.
ゴム組成物にシリカを配合することによりウェットスキッド性能を向上させ、転がり抵抗を低くする技術が従来から知られており、実用化されていることは周知の通りである。近年、ウェットスキッド性能や転がり抵抗を更に改良すべく、例えば極性フィラー配合によって同様な効果を得る試みがなされている。しかし補強性の低い極性粒子（例えばクレー、カオリナイトなど）の配合によってウェットスキッド性能の改良は得られるようであるが、そのような極性フィラーを配合するとは摩耗性能が大幅に悪化するという問題がある（例えば特許文献１〜３参照）。 It is well known that a technique for improving wet skid performance and lowering rolling resistance by blending silica in a rubber composition has been known and put into practical use. In recent years, in order to further improve wet skid performance and rolling resistance, an attempt has been made to obtain the same effect by, for example, blending a polar filler. However, it seems that wet skid performance can be improved by blending polar particles (for example, clay, kaolinite, etc.) with low reinforcing properties. However, when such polar filler is blended, there is a problem that the wear performance is greatly deteriorated. Yes (for example, see Patent Documents 1 to 3).
従って、本発明の目的は、耐摩耗性を損なうことなく、ゴム組成物のウェットスキッド性能や転がり抵抗を改良することにある。 Accordingly, an object of the present invention is to improve wet skid performance and rolling resistance of a rubber composition without impairing wear resistance.
本発明に従えば、スチレン−ブタジエン共重合体ゴム（ＳＢＲ）を含むジエン系ゴム１００重量部、シリカ、平均粒子サイズ１〜１００μｍの珪酸カルシウム粉体５〜３５重量部で且つシリカとの合計量が２０〜１２０重量部及び珪酸カルシウム粉体とシリカの合計量の１〜１５重量％の２級脂肪族アミンを含んでなるゴム組成物及びそれを用いた空気入りタイヤが提供される。 According to the present invention, 100 parts by weight of diene rubber containing styrene-butadiene copolymer rubber (SBR), silica, 5 to 35 parts by weight of calcium silicate powder having an average particle size of 1 to 100 μm, and the total amount with silica There are provided a rubber composition comprising 20 to 120 parts by weight of a secondary aliphatic amine and 1 to 15% by weight of the total amount of calcium silicate powder and silica, and a pneumatic tire using the rubber composition.
本発明によれば、ウォラストナイトなどの珪酸カルシウム粉体及び２級脂肪族アミンを配合することにより耐摩耗性の低下を抑制しつつ、ペイン効果を低減（即ちシリカの分散を向上させ）、低温ｔａｎδを高く、高温ｔａｎδを低くすることが可能となり、このゴムをトレッド部に用いて空気入りタイヤを製造することによって、耐摩耗性を低下させることなく、ウェットスキッドと低転がり抵抗とを両立させることができる。また、アミン化合物は一般にスコーチを促進させる傾向にあるが、２級脂肪族アミン化合物の使用によりスコーチの抑制も達成できる。 According to the present invention, by reducing the wear resistance by blending calcium silicate powder such as wollastonite and secondary aliphatic amine , the pain effect is reduced (that is, silica dispersion is improved), It is possible to increase the low temperature tan δ and decrease the high temperature tan δ. By manufacturing pneumatic tires using this rubber in the tread part, both wet skid and low rolling resistance can be achieved without reducing wear resistance. Can be made. In addition, amine compounds generally tend to promote scorch, but the use of secondary aliphatic amine compounds can also suppress scorch.
本発明者らは前記課題を解決すべく研究を進めた結果、珪酸カルシウム粉体、例えばウォラストナイトをゴム組成物に配合することによりウェットスキッド性能及び転がり抵抗性能を改良することが可能となるが、耐摩耗性の面で未だ改良の余地がある。本発明ではＳＢＲ主体とするジエン系ゴムにシリカ、珪酸カルシウム粉体（例えばウォラストナイト）及び２級脂肪族アミンを配合することにより耐摩耗性を損なうことなく、ウェットスキッド性能及び転がり抵抗性能を改良することができる。 As a result of researches to solve the above problems, the present inventors can improve wet skid performance and rolling resistance performance by blending calcium silicate powder such as wollastonite into a rubber composition. However, there is still room for improvement in terms of wear resistance. In the present invention, wet skid performance and rolling resistance performance can be achieved without impairing wear resistance by blending silica, calcium silicate powder (for example, wollastonite) and secondary aliphatic amine into diene rubber mainly composed of SBR. It can be improved.
本発明によれば、ゴム成分としてスチレン−ブタジエン共重合体ゴム（ＳＢＲ）を含むジエン系ゴム１００重量部に対し、シリカ、平均粒子サイズが１〜１００μｍ、好ましくは１〜５０μｍの珪酸カルシウムの粉体を５〜３５重量部、好ましくは５〜２０重量部でリカとの合計量で２０〜１２０重量部、好ましくは３５〜１００重量部配合し、更に、並びに珪酸カルシウム粉体の１〜１５重量％の脂肪族アミンを配合する。上記脂肪族アミンとしては２級脂肪族アミンを使用するのが好ましく（１級アミンではスコーチが起こるおそれがある）、また２級脂肪族アミンの脂肪酸部分の炭素数は８〜３６であるのが好ましい。本発明者らの解釈によれば、本発明の範囲をこれに限定するものではないが、２級脂肪族アミンによりウォラストナイトなどの珪酸カルシウム粉体のシラン化が促進され、また脂肪酸によるフィラー分散が向上される。この２級脂肪族アミンの配合量が多くなるとスコーチが起こるおそれがあり、逆に、配合量が少ないと所望の改良効果が認められないので好ましくない。本発明で使用する２級脂肪族アミンの具体例としては、これらに限定するものではないが、ジアルキルアミン（Ｒ 2 ＮＨで、ＲがＣ 8 〜Ｃ 18 のアルキル）などをあげることができる。 According to the present invention, silica and an average particle size of 1 to 100 μm, preferably 1 to 50 μm of calcium silicate powder with respect to 100 parts by weight of diene rubber containing styrene-butadiene copolymer rubber (SBR) as a rubber component 5 to 35 parts by weight of the body, preferably 5 to 20 parts by weight, and 20 to 120 parts by weight, preferably 35 to 100 parts by weight in total with Rica, and 1 to 15 parts by weight of calcium silicate powder % Aliphatic amine. As the aliphatic amine, a secondary aliphatic amine is preferably used (a scorch may occur with a primary amine), and the fatty acid portion of the secondary aliphatic amine has 8 to 36 carbon atoms. preferable. According to the interpretation of the present inventors, the scope of the present invention is not limited to this, but the silanization of calcium silicate powder such as wollastonite is promoted by the secondary aliphatic amine , and the filler by fatty acid is used. Dispersion is improved. If the blending amount of the secondary aliphatic amine is increased, scorching may occur. Conversely, if the blending amount is small, a desired improvement effect is not recognized, which is not preferable. Specific examples of the secondary aliphatic amine used in the present invention include, but are not limited to, (in R 2 NH, R is alkyl of C 8 -C 18) dialkyl amines can be mentioned etc. .
本発明において使用するＳＢＲ以外のジエン系ゴムとしては、例えば天然ゴム、ポリイソプレンゴム、ポリブタジエンゴム、クロロプレン、アクリロニトリル−ブタジエンゴム、ブチルゴムなどをあげることができ、本発明においてはゴム成分の３０重量％以上がＳＢＲであり、かつＳＢＲとＢＲとの合計量がゴムの総重量の６０重量％以上であることがが好ましい。 Examples of diene rubbers other than SBR used in the present invention include natural rubber, polyisoprene rubber, polybutadiene rubber, chloroprene, acrylonitrile-butadiene rubber, and butyl rubber. In the present invention, 30% by weight of the rubber component. The above is SBR, and the total amount of SBR and BR is preferably 60% by weight or more of the total weight of the rubber.
本発明において使用するシリカはタイヤ用などに使用する任意のシリカを用いることができ、例えば天然シリカ、合成シリカ、特に乾式シリカ、湿式シリカなどを用いることができる。 As the silica used in the present invention, any silica used for tires and the like can be used. For example, natural silica, synthetic silica, particularly dry silica, wet silica and the like can be used.
本発明において使用する珪酸カルシウム粉体としては例えばウォラストナイトを使用することができる。ウォラストナイト（Ｗｏｌｌａｓｔｏｎｉｔｅ）（珪灰石）は化学式ＣａＳｉＯ3で示される珪酸塩鉱物であり、天然鉱物として産出されるウォラストナイトは、石灰石と花崗岩の接触部で変成作用を受けて発達した鉱物で、色はガラス光沢のある白色、帯灰色、帯褐色を呈し、結晶形態は針状、塊状をなしている。主成分はＳｉＯ2とＣａＯをほぼ等量含有し、微量成分としてＡｌ2Ｏ3，Ｆｅ2Ｏ3等を含有しており、天然に産出される低温型（β型）と合成の高温型（α型）がある。なお、ウォラストナイトは、例えばＮＹＣＯ（株）や巴工業（株）より各種グレードが市販されており、本発明においてはこれらの市販品のうち、平均粒子サイズが１〜１００μｍのものを使用する。通常、ウォラストナイトは乾式法で粉砕されるため、平均粒子径を１μｍ未満にするのは困難である。平均粒子サイズが大き過ぎると補強性や耐摩耗性が低下するので好ましくない。その他の珪酸塩鉱物としては孤立型のネソ珪酸塩、２個連結型のソロ珪酸塩、リング状のサイクロ珪酸塩、チェーン状のイノ珪酸塩、シート状のフィロ珪酸塩、網状のテクト珪酸塩などがあげられる。前記平均粒径Ｄ５０及びアスペクト比のものを使用することができる。 As the calcium silicate powder used in the present invention, for example, wollastonite can be used. Wollastonite (wollastonite) is a silicate mineral represented by the chemical formula CaSiO 3 , and wollastonite produced as a natural mineral is a mineral developed by metamorphism at the contact portion between limestone and granite. The color is glassy white, grayish-brown, brownish, and the crystal form is needle-like or lump-like. The main component contains almost equal amounts of SiO 2 and CaO, and contains trace amounts of Al 2 O 3 , Fe 2 O 3, etc., and the naturally produced low temperature type (β type) and synthetic high temperature type ( α type). In addition, various grades of wollastonite are commercially available from, for example, NYCO Co., Ltd. and Sakai Kogyo Co., Ltd. In the present invention, among these commercial products, those having an average particle size of 1 to 100 μm are used. . Since wollastonite is usually pulverized by a dry method, it is difficult to make the average particle size less than 1 μm. If the average particle size is too large, the reinforcing property and wear resistance are lowered, which is not preferable. Other silicate minerals include isolated nesosilicates, double-connected solo silicates, ring-shaped cyclosilicates, chain-shaped innosilicates, sheet-form phyllosilicates, and reticulated tectosilicates. Can be given. The thing with the said average particle diameter D50 and an aspect-ratio can be used.
前述の如く、本発明のゴム組成物に使用される珪酸カルシウム粉体の配合量は、ジエン系ゴム１００重量部に対し５〜３５重量部で、シリカとの合計量で２０〜１２０重量部である。この配合量が少ないとウェットスキッド性能及び低転がり抵抗性能が低下するので好ましくなく、また多いと耐摩耗性が悪化するので好ましくない。 As described above, the amount of calcium silicate powder used in the rubber composition of the present invention is 5 to 35 parts by weight with respect to 100 parts by weight of the diene rubber, and 20 to 120 parts by weight in total with silica. is there. When the blending amount is small, wet skid performance and low rolling resistance performance are deteriorated, which is not preferable. When the blending amount is large, wear resistance is deteriorated, which is not preferable.
本発明に係るゴム組成物には、前記した成分に加えて、カーボンブラックなどのその他の補強剤（フィラー）、シランカップリング剤、加硫又は架橋剤、加硫又は架橋促進剤、各種オイル、老化防止剤、可塑剤などのタイヤ用、その他のゴム組成物用に一般的に配合されている各種添加剤を配合することができ、かかる添加剤は一般的な方法で混練して組成物とし、加硫又は架橋するのに使用することができる。これらの添加剤の配合量は本発明の目的に反しない限り、従来の一般的な配合量とすることができる。 In addition to the components described above, the rubber composition according to the present invention includes other reinforcing agents (fillers) such as carbon black, silane coupling agents, vulcanization or crosslinking agents, vulcanization or crosslinking accelerators, various oils, Various additives that are generally blended for tires such as anti-aging agents and plasticizers and other rubber compositions can be blended, and such additives are kneaded by a general method to form a composition. Can be used for vulcanization or crosslinking. As long as the amount of these additives is not contrary to the object of the present invention, a conventional general amount can be used.
以下、実施例によって本発明を更に説明するが、本発明の範囲をこれらの実施例に限定するものでないことはいうまでもない。 EXAMPLES Hereinafter, although an Example demonstrates this invention further, it cannot be overemphasized that the scope of the present invention is not limited to these Examples.
標準例、実施例１〜２、参考例１〜４及び比較例１〜７
サンプルの調製
表Ｉ及び表ＩＩに示す配合において、加硫促進剤と硫黄を除く成分を３リットルの密閉型ミキサーで５分間混練し、１４５±５℃に達したときに放出してマスターバッチを得た。このマスターバッチに加硫促進剤と硫黄をオープンロールで混練し、ゴム組成物を得た。このゴム組成物を用いて以下に示す試験法で未加硫物性を評価した。結果は表Ｉ及び表ＩＩに示す。
Standard Example, Examples 1-2, Reference Examples 1-4, and Comparative Examples 1-7
Sample preparation In the formulations shown in Table I and Table II, the ingredients other than the vulcanization accelerator and sulfur were kneaded for 5 minutes in a 3 liter closed mixer, and when the temperature reached 145 ± 5 ° C, the master batch was released. Obtained. A vulcanization accelerator and sulfur were kneaded with this master batch with an open roll to obtain a rubber composition. Using this rubber composition, unvulcanized physical properties were evaluated by the following test methods. The results are shown in Table I and Table II.
次に得られたゴム組成物を１５×１５×０．２cmの金型中で１６０℃で３０分間加硫して加硫ゴムシートを調製し、以下に示す試験法で加硫ゴムの物性を測定した。結果は表Ｉ及び表ＩＩに示す。 Next, the resulting rubber composition was vulcanized in a 15 × 15 × 0.2 cm mold at 160 ° C. for 30 minutes to prepare a vulcanized rubber sheet. The physical properties of the vulcanized rubber were measured by the following test methods. It was measured. The results are shown in Table I and Table II.
ゴム物性評価試験法
ムーニースコーチ：ＪＩＳ Ｋ６３００に準拠して測定し、標準例の値を１００として指数表示した。この値が大きいほど加工性に優れている。
Rubber physical property evaluation test method Mooney scorch: Measured according to JIS K6300, and the value of the standard example was set to 100 and indicated as an index. The larger this value, the better the workability.
ｔａｎδ（０℃）（ウェットスキッド性能）及びｔａｎδ（６０℃）（転がり抵抗）：東洋精機製作所製粘弾性スペクトロメーターを用いて周波数２０Hz、初期歪１０％、振幅±２％の条件で０℃及び６０℃のｔａｎδを測定し、標準例の値を１００として指数表示した。ｔａｎδ（０℃）の値が大きいほどウェットスキッド性能に優れ、ｔａｎδ（６０℃）の値が小さいほど転がり抵抗に優れていることを示す。 tan δ (0 ° C.) (wet skid performance) and tan δ (60 ° C.) (rolling resistance): using a viscoelastic spectrometer manufactured by Toyo Seiki Seisakusho at 0 ° C. under conditions of frequency 20 Hz, initial strain 10%, amplitude ± 2% The tan δ at 60 ° C. was measured, and the value of the standard example was set to 100 and indicated as an index. The larger the value of tan δ (0 ° C.), the better the wet skid performance, and the smaller the value of tan δ (60 ° C.), the better the rolling resistance.
耐摩耗性：ランボーン摩耗試験機にて、温度２０℃、負荷荷重２．４５Ｎ、スリップ率２０％、試験時間５分の条件でランボーン摩耗量を測定した。この値を標準例の値を１００として指数表示した。この値が大きいほど耐摩耗性に優れることを表す。 Abrasion resistance: A Lambourn abrasion tester was used to measure the Lambourn abrasion amount under the conditions of a temperature of 20 ° C., a load of 2.45 N, a slip rate of 20%, and a test time of 5 minutes. This value was expressed as an index with the value of the standard example being 100. It represents that it is excellent in abrasion resistance, so that this value is large.
ペイン効果：アルファーテクノロジーズ社製ＲＰＡ２０００を用いて、１７０℃×１０分で加硫した後、周波数６cpm、せん断歪０．２８〜３０％の条件でせん断弾性率Ｇ’の歪依存性を測定した。歪量０．２８％時のＧ’と歪量３０％時のＧ’の比Ｇ’（０．２８％）／Ｇ’（３０％）をペイン効果の尺度とした。結果は標準例の値を１００として指数表示した。この値が小さいほど分散性に優れることを表す。 Payne effect: After vulcanization at 170 ° C. for 10 minutes using RPA2000 manufactured by Alpha Technologies, the strain dependence of the shear modulus G ′ was measured under conditions of a frequency of 6 cpm and a shear strain of 0.28 to 30%. The ratio G ′ (0.28%) / G ′ (30%) of G ′ when the strain amount is 0.28% and G ′ when the strain amount is 30% was used as a measure of the Payne effect. The results are shown as an index with the value of the standard example being 100. The smaller this value, the better the dispersibility.
表Ｉ表ＩＩ脚注
＊１：ＳＢＲ（Ｎｉｐｏｌ９５２８Ｒ、日本ゼオン（株）製）
＊２：ＢＲ（ＮｉｐｏｌＢＲ１２２０、日本ゼオン（株）製）
＊３：シリカ（１６５ＧＲ、ローディア社製）
＊４：ウォラストナイト（ＮＹＡＤ１２５０、ＮＹＣＯ社製）
＊５：シランカップリング剤（Ｓｉ６９、デグッサ社製）
＊６：ＨＡＦ（ショウブラックＮ３３９、昭和キャボット（株）製）
＊７：６Ｃ（ＳＡＮＴＯＦＬＥＸ ６ＰＰＤ、ＦＬＥＸＳＹＳ社製）
＊８：ＲＤ（ＶＵＬＫＡＮＯＸ ＨＳ／ＬＧ、バイエル社製）
＊９：亜鉛華（銀嶺、東邦亜鉛（株）製）
＊１０：ステアリン酸（ビーズステアリン酸、日本油脂（株）製）
＊１１：プロセスオイル（Ｘ−１４０、ジャパンエナジー（株）製）
＊１２：加硫促進剤１（ノクセラーＮＳ−Ｐ、大内新興化学工業（株）製）
＊１３：加硫促進剤２（サンセラーＤ−Ｇ、住友化学（株）製）
＊１４：硫黄（油処理硫黄、細井化学工業（株）製）
＊１５：１級アミン−１（アーミン１２Ｄ、ライオン・アクゾ（株）製）
＊１６：１級アミン−２（アーミン１８Ｄ、ライオン・アクゾ（株）製）
＊１７：１級アミン−３（アーミン０Ｄ、ライオン・アクゾ（株）製）
＊１８：１級アミン−４（アーミンＨＴＤ、ライオン・アクゾ（株）製）
＊１９：２級アミン−１（アーミン２Ｃ、ライオン・アクゾ（株）製）
＊２０：２級アミン−２（アーミン２ＨＴ、ライオン・アクゾ（株）製）
＊２１：３級アミン−１（アーミンＤＭ１２Ｄ、ライオン・アクゾ（株）製）
＊２２：３級アミン−２（アーミンＤＭ１８Ｄ、ライオン・アクゾ（株）製）
＊２３：３級アミン−３（アーミンＤＭＯＣ、ライオン・アクゾ（株）製）
＊２４：３級アミン−４（アーミンＤＭＴＤＣ、ライオン・アクゾ（株）製）
Table I Table II Footnote * 1: SBR (Nipol 9528R, manufactured by Nippon Zeon Co., Ltd.)
* 2: BR (Nipol BR1220, manufactured by Nippon Zeon Co., Ltd.)
* 3: Silica (165GR, manufactured by Rhodia)
* 4: Wollastonite (NYAD1250, manufactured by NYCO)
* 5: Silane coupling agent (Si69, manufactured by Degussa)
* 6: HAF (Show Black N339, Showa Cabot Co., Ltd.)
* 7: 6C (SANTOFLEX 6PPD, manufactured by FLEXSYS)
* 8: RD (VULKANOX HS / LG, manufactured by Bayer)
* 9: Zinc flower (Ginren, manufactured by Toho Zinc Co., Ltd.)
* 10: Stearic acid (bead stearic acid, manufactured by NOF Corporation)
* 11: Process oil (X-140, manufactured by Japan Energy Co., Ltd.)
* 12: Vulcanization accelerator 1 (Noxeller NS-P, manufactured by Ouchi Shinsei Chemical Co., Ltd.)
* 13: Vulcanization accelerator 2 (Sunceller DG, manufactured by Sumitomo Chemical Co., Ltd.)
* 14: Sulfur (oil-treated sulfur, manufactured by Hosoi Chemical Co., Ltd.)
* 15: Primary amine-1 (Armin 12D, manufactured by Lion Akzo Co., Ltd.)
* 16: Primary amine-2 (Armin 18D, manufactured by Lion Akzo Co., Ltd.)
* 17: Primary amine-3 (Armin 0D, manufactured by Lion Akzo Co., Ltd.)
* 18: Primary amine-4 (Armin HTD, manufactured by Lion Akzo Co., Ltd.)
* 19: Secondary amine-1 (Armin 2C, manufactured by Lion Akzo Co., Ltd.)
* 20: Secondary amine-2 (Armin 2HT, manufactured by Lion Akzo Co., Ltd.)
* 21: Tertiary amine-1 (Armin DM12D, manufactured by Lion Akzo Co., Ltd.)
* 22: Tertiary amine-2 (Armin DM18D, manufactured by Lion Akzo Co., Ltd.)
* 23: Tertiary amine-3 (Armin DMOC, manufactured by Lion Akzo Co., Ltd.)
* 24: Tertiary amine-4 (Armin DMTDC, manufactured by Lion Akzo Co., Ltd.)
以上の通り、本発明に従えば、ゴム組成物にウォラストナイトなどの珪酸カルシウム粉体、シリカ及び２級脂肪族アミンを配合することにより耐摩耗性の低下を抑制しつつ、ペイン効果を低減（即ちシリカの分散が向上し）、低温ｔａｎδを高く、高温ｔａｎδを低くすることが可能となった。このゴム組成物は、タイヤトレッド部用ゴム組成物として用いてタイヤを製造することによって、耐摩耗性の低下をきたすことなく、ウェットスキッドと低転がり抵抗とを両立させることができるので、空気入りタイヤ、特にそのキャップトレッド用ゴム組成物として有用である。 As described above, according to the present invention, the Payne effect is reduced while suppressing a decrease in wear resistance by blending calcium silicate powder such as wollastonite, silica and a secondary aliphatic amine into the rubber composition. (In other words, silica dispersion was improved), and it was possible to increase the low temperature tan δ and decrease the high temperature tan δ. Since this rubber composition can be used as a tire tread portion rubber composition to produce a tire, both wet skid and low rolling resistance can be achieved without reducing wear resistance. It is useful as a rubber composition for tires, particularly cap treads thereof.
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| Application Number | Priority Date | Filing Date | Title |
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| JP2005217256A JP4844034B2 (en) | 2005-07-27 | 2005-07-27 | Rubber composition |
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| JP2005217256A JP4844034B2 (en) | 2005-07-27 | 2005-07-27 | Rubber composition |
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| JP2007031578A JP2007031578A (en) | 2007-02-08 |
| JP4844034B2 true JP4844034B2 (en) | 2011-12-21 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5379370B2 (en) * | 2007-11-07 | 2013-12-25 | 株式会社ブリヂストン | Rubber composition |
| DE102009003764A1 (en) * | 2009-04-08 | 2010-10-14 | Continental Reifen Deutschland Gmbh | rubber compound |
| JP4930629B2 (en) * | 2010-08-27 | 2012-05-16 | 横浜ゴム株式会社 | Thermoplastic resin composition |
| CN113166480B (en) | 2018-11-30 | 2023-09-05 | 花王株式会社 | rubber composition |
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|---|---|---|---|---|
| JP3384787B2 (en) * | 2000-07-14 | 2003-03-10 | 住友ゴム工業株式会社 | Tread rubber composition for tire |
| JP3902107B2 (en) * | 2001-10-05 | 2007-04-04 | 株式会社ブリヂストン | Rubber composition |
| JP2003160696A (en) * | 2001-11-26 | 2003-06-03 | Bridgestone Corp | Rubber composition and pneumatic tires using the same |
| JP2003213046A (en) * | 2002-01-23 | 2003-07-30 | Bridgestone Corp | Rubber composition and tire using the same |
| JP4350973B2 (en) * | 2003-05-19 | 2009-10-28 | 東洋ゴム工業株式会社 | Rubber composition for tire and studless tire |
| JP2005068194A (en) * | 2003-08-26 | 2005-03-17 | Yokohama Rubber Co Ltd:The | Rubber composition for tire and pneumatic tire using the same |
| JP2006232916A (en) * | 2005-02-23 | 2006-09-07 | Yokohama Rubber Co Ltd:The | Rubber composition for tire tread |
| JP2007023101A (en) * | 2005-07-13 | 2007-02-01 | Yokohama Rubber Co Ltd:The | Rubber composition for tire tread |
| JP2007031581A (en) * | 2005-07-27 | 2007-02-08 | Yokohama Rubber Co Ltd:The | Rubber composition |
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