JP4840875B2 - Adhesive composition and concrete joining method - Google Patents

Description

 The present invention relates to an adhesive composition that is applied to a joining surface when a new concrete or mortar is handed over to an existing concrete or mortar base, and more specifically, easily applied to a joining surface by roller brushing or spraying. The present invention relates to an adhesive composition having a low viscosity and good workability, and a concrete joining method using the same.

  Conventionally, when new concrete or mortar is handed over to the ground such as existing concrete or mortar, brittle layers such as the latency layer and cement paste layer of the joint surface are removed by sanding or the like, and then wetted with water. Naive concrete or mortar. However, it is difficult to manage the amount of water dampening, and the water absorption state of the existing concrete or mortar ground is not uniform, so the amount of water dampening is partially insufficient, and new concrete is cast in that part. At that time, the moisture is sucked into the ground such as existing concrete or mortar. For this reason, there was a problem that the amount of water at the casting interface portion on the new concrete side was insufficient, and the cement was hydrated insufficiently, resulting in a decrease in strength.

On the other hand, as the dispersoid, at least one unit selected from an acrylate monomer unit, a methacrylate ester monomer unit, a styrene monomer unit, and a diene monomer unit. A cement mortar joint material made of an aqueous emulsion containing a homopolymer or copolymer consisting of monomer units and a polyvinyl alcohol polymer having a mercapto group at the end as a dispersant is applied to the joint surface. However, it is disclosed that moisture of concrete newly placed due to high alkali resistance of the film is suppressed from moving to the existing concrete side, and the adhesive strength of the new concrete is remarkably improved (Patent Document 1).

  Moreover, it contains an epoxy resin and a polyamine curing agent, or contains an epoxy resin, a polyamine curing agent, a polysulfide polymer, and a tertiary amine compound, and the polyamine curing agent is added to 1 equivalent of the epoxy resin. In addition, a primer composition blended with 0.1 to 0.6 equivalents of primer composition that can be spliced to wet existing concrete and a method of splicing concrete are disclosed (Patent Documents 2 and 3).

  In addition, when a new concrete is handed over to the hardened concrete, a polymer cement, a polymer cement mortar or a polymer cement concrete is placed 3 to 10 cm thick on the joint surface of the hardened concrete, and the new concrete is in contact with the polymer cement. A concrete joining method that suppresses the occurrence of cracks in the joint portion by placing and a hardened concrete body having the joint portion is disclosed (Patent Document 4).

Furthermore, the paste or mortar is a paste or mortar to be used between an existing hardened body and water-permeable concrete to be transferred to the hardened body, and 100 parts by weight of a powder mixture containing cement or cement; Water-permeable concrete comprising 0 to 300 parts by weight of material, 0.5 to 20 parts by weight of polymer, and water blended so that the flow time of the paste or mortar J funnel is 3 to 15 seconds. It has been disclosed that permeable concrete is handed over to existing concrete by applying a jointing paste or mortar to the jointing surface to a thickness of 2 mm to 40 mm, preferably 3 mm to 30 mm (Patent Document 5).
Japanese Patent Laid-Open No. 6-184489 JP 2000-273354 A JP 2000-345101A JP 2003-105972 A Japanese Patent Laid-Open No. 2001-261612

  In Patent Document 1, when the existing concrete surface is dry, the water content of the aqueous emulsion impregnates the existing concrete surface to form a film, but when the existing concrete surface is wet, the applied aqueous emulsion If film formation is not sufficiently performed and new concrete is cast in that state, a portion where film formation is insufficient becomes a fragile layer, and the adhesiveness of old and new concrete at the joint may decrease.

  In Patent Documents 2 and 3, depending on the polyamine type hardener, the hydration of the concrete may be inhibited. In this case, the cement becomes unhydrated at the jointing interface of the newly placed concrete, and the jointing is performed in the same manner as described above. The adhesiveness of the part may decrease. In addition, a puddle is generated on the surface of the base, and in an excessively wet state immediately after the puddle is removed with a waste cloth, the adhesiveness of the joint portion is insufficient.

In Patent Document 4, when polymer cement is cast or applied to existing concrete at 3 cm or more, and Patent Document 5 is at least 2 mm or more, when the specific gravity of polymer cement is about 2.0, m ² coating amount is 2 mm thick. must ² with the coating 60 kg / m is about 4 kg / m 2, ^{3 cm} thickness when in the strike splicing of large area concrete, it is necessary to prepare a large amount of out joint material in out splicing site, burden on the operator Was too heavy and expensive.

  The present invention solves the above-mentioned conventional problems, does not hinder the hydration of newly placed concrete cement, and has a pool of water on the joint surface of the ground such as existing concrete or mortar. Even when the water pool is excessively wet, such as immediately after being removed with a waste cloth, the adhesiveness of the joint is sufficient, and the amount applied to the joint surface is higher than that of the conventional one. It is an object of the present invention to provide an adhesive composition and a concrete joining method, which are remarkably few and have good workability on application to a joining surface.

The invention described in claim 1 is an adhesive composition to be applied to a joint surface when a new concrete or mortar is handed over to an existing concrete or mortar base, comprising an epoxy resin, a water dispersible polyamine epoxy adduct and water. Ri Do from hydraulic cement, water dispersible polyamine epoxy adduct, (a) a polyamine, and monoepoxide in an amount to react with 10-50% of the primary amino groups of the polyamine, 5 residual primary amino groups of the polyamine 0.25 to 4 parts by weight of a water-compatible polyamine-epoxy adduct and (B) a primary amine group and a monoepoxide or polyepoxide formed by addition and reaction of a mixture of an amount of polyepoxide that reacts with 65% 1 part by weight of a resin-compatible polyamine-epoxy adduct obtained by the reaction with The water-compatible polyamine-epoxy adduct and the resin-compatible polyamine-epoxy wherein at least 25% of the residual amino groups of the amine are reacted with formaldehyde and the polyamine is subsequently at least partially neutralized by reaction with an acid. Adhesive composition characterized in that it is a mixture with adducts, without inhibiting the hydration of new concrete or mortar, and even if the existing joint surface of concrete or mortar is wet Provided is an adhesive composition having a high joint strength at the joint, a much smaller amount of application to the joint surface than conventional ones, and good workability for application to the joint surface.

The invention according to claim 2 applies the adhesive composition according to claim 1 to the joint surface of the existing concrete or mortar when the new concrete or mortar is handed over to the existing concrete or mortar base, and the adhesive It is a concrete joining method characterized by placing a new concrete or mortar in contact with the composition, and the joint strength of the joining part is high even if the jointing surface of the ground such as existing concrete or mortar is wet, A concrete joining method is provided in which the amount of coating on the joining surface is small compared to the prior art, and the coating workability on the joining surface is good.

  The adhesive composition of the present invention is an adhesive composition that is applied to a joint surface when a new concrete or mortar is handed over to a ground such as existing concrete or mortar, the epoxy resin and water dispersible polyamine epoxy adduct And a hydraulic cement, wherein the water-dispersible polyamine epoxy adduct reacts with (A) polyamine in an amount of 10-50% of the primary amino group of the polyamine. 0.25-4 parts by weight of a water-compatible polyamine-epoxy adduct formed by addition and reaction of a mixture of polyepoxides in an amount that reacts with 5-65% of the residual primary amino groups of the polyamine and (B) Resin-compatible polyamines obtained by reaction of polyamines with primary amino groups with monoepoxides or polyepoxides. Said water-compatible polyamine-epoxy adduct comprising 1 part by weight of xiaduct, wherein at least 25% of the residual amino groups of the polyamine are reacted with formaldehyde, and the polyamine is subsequently at least partially neutralized by reaction with an acid And the resin-compatible polyamine-epoxy adduct have the effect of not inhibiting the hydration of newly cast concrete or mortar cement.

In addition, even if there is a puddle on the joint surface of the groundwork such as existing concrete or mortar and it is excessively wet just after the puddle is removed with a waste cloth, the bonding strength of the joint portion is high. In addition, the amount applied to the joint surface is much smaller than that of the conventional one, and is usually 0.2 kg / m ^{2 to} 1.0 kg / m ² , preferably 0.3 kg to 0.7 kg / m. ² can be applied with a roller brush or spray applied, and the workability of application to the joint surface is extremely good. Therefore, it is an effective adhesive composition and concrete casting method when casting a ground such as existing concrete or mortar having a large area, and its effect is great.

  The adhesive composition of the present invention is an adhesive composition that is applied to a joint surface when a new concrete or mortar is handed over to a ground such as existing concrete or mortar. A liquid epoxy resin and a water-dispersible polyamine-epoxy This is a mixture of a polymer dispersion forcibly emulsified by mixing an aqueous hardener as an adduct and hydraulic cement.

  The epoxy resin of the present invention may be liquid and can be cured at room temperature. Bisphenol A type epoxy resin, bisphenol F type epoxy resin, phenol novolac type epoxy resin, bisphenol AD type epoxy resin, biphenyl type epoxy resin, naphthalene Type epoxy resin, cycloaliphatic epoxy resin, glycidyl ester type epoxy resin, glycidyl amine type epoxy resin, heterocyclic epoxy resin, diaryl sulfone type epoxy resin, hydroquinone type epoxy resin and their modified products, either alone or in combination Alternatively, it may be liquefied using a diluent. The softening point of the epoxy resin compounded most is preferably 35 ° C. or less. As such a liquid epoxy resin, a liquid bisphenol A type epoxy resin is preferable in terms of versatility and cost.

  Further, the water-based curing agent that is the water-dispersible polyamine epoxy adduct of the present invention may be any one that can be mixed with the epoxy resin and can disperse water well. A) A polyamine is added and reacted with a mixture of a monoepoxide in an amount that reacts with 10 to 50% of the primary amino group of the polyamine and a polyepoxide in an amount that reacts with 5 to 65% of the residual primary amino group of the polyamine. 0.25-4 parts by weight of a water-compatible polyamine-epoxy adduct formed and (B) a resin-compatible polyamine-epoxy adduct obtained by reacting a polyamine having a primary amino group with a monoepoxide or polyepoxide 1 part by weight, at least 25% of the residual amino groups of the polyamine react with formaldehyde A polyamine is a mixture of the water-compatible polyamine-epoxy adduct and the resin-compatible polyamine-epoxy adduct that is subsequently at least partially neutralized by reaction with an acid, and is described in Japanese Patent No. 2661678. It is what. The water-dispersible polyamine epoxy adduct corresponding to this is Joliseal JBX-140B (Eika resin Co., Ltd. epoxy resin curing agent, active hydrogen equivalent 380, solid content 33% aqueous solution, viscosity 90 mPas / 23 ° C., trade name) There is.

  The hydraulic component is cement, and the cement is not particularly limited as long as it is hydraulic. Mixed cements such as Portland cement, blast furnace cement, silica cement, fly ash cement, aluminate calcareous cement, silicic acid aluminate calcareous cement, phosphate cement and the like can be used. In particular, white cement, that is, white Portland cement, is preferable in terms of good fluidity. The blending amount of the hydraulic cement is preferably 50 parts by weight to 250 parts by weight with respect to 100 parts by weight of the epoxy resin, but the effect of the present invention is remarkable, but it is less than 50 parts by weight and more than 250 parts by weight. However, there is no hindrance to the coating workability, and the blending amount can be adjusted within the range if the joining of the joint portion is good.

  As the mixing form of the blend, an epoxy resin, a water-dispersible polyamine epoxy adduct, water, and a hydraulic cement are the main blends. In other words, epoxy resin, water-dispersible polyamine epoxy adduct and water, and hydraulic cement are preferable to prevent inadequate mixing / dispersion, deactivation of characteristics, measurement errors / errors, It doesn't matter.

Although the adhesive compositions of the present invention can be ^0.2 / ^{m 2 ~1.0kg} / m 2 with a coating on concrete beating joint ^{surface, 0.3kg / m 2 ~0.7kg / m} 2 is uniformly joint surface out It is suitable in that it can be applied. It is difficult to uniformly with coating to less than / ^{m 2} in the base 0.2 kg, it is difficult to apply in 1.0kg greater / ^{m 2} in a roller brush or spraying.

Hereinafter, it demonstrates in detail in an Example and a comparative example.

  Jolliseal JBX-140A (epoxy resin, epoxy equivalent 180, solid content 100%, viscosity 1300 mPas / 23 ° C., product name) 100 parts by weight and Joliseal JBX-140B (Aika Industry) Water-dispersible polyamine epoxy adduct, active hydrogen equivalent 380, solid content 33% aqueous solution, viscosity 90 mPas / 23 ° C, trade name) 200 parts by weight, and an adhesive composition containing 150 parts by weight of ordinary Portland cement was prepared. Example 1 was adopted.

Comparative Example 1
In place of Example 1, an acrylic emulsion (Ultrasol CMX-243, manufactured by Ganz Kasei Co., Ltd., trade name: acrylate copolymer emulsion, solid content 45%, PH 5.0, viscosity 20 mPas / 25 ° C.) with water Comparative Example 1 was prepared by diluting and adjusting the solid content to 10%.

Comparative Example 2
The blending amount of the ordinary Portland cement of Example 1 was set to 0 part by weight, and Comparative Example 2 was made using only a mixture of Jolliseal JBX-140A as an epoxy resin and Jolliseal JBX-140B as a water dispersible polyamine epoxy adduct.

Comparative Example 3
In place of Example 1, 400 parts by weight of an epoxy resin (Joliseal JB-8A, manufactured by Aika Industry Co., Ltd., trade name: bisphenol A type epoxy resin 52.5%) and a polyamine curing agent (Jolliseal JB-8B, Made by Aika Kogyo Co., Ltd., trade name: 100% by weight of modified aliphatic polyamine 100% (including metaxylylenediamine 4%, polythiol 20%) in a stirrer (mixture viscosity 5 Pas / 20 ° C., cured product) Specific gravity 1.3) and Comparative Example 3 were used.

  Table 1 shows the results of Examples and Comparative Examples.

Test conditions

Existing concrete foundation: JISA5371 Annex 2 Normal flat plate A 300 × 300 × 60 mm concrete flat surface conforming to the rules of nominal 300 was washed with high pressure water to remove the weak parts of the surface, and used as an existing concrete foundation.

Curing temperature and surface condition: Curing temperature is 5 ° C and 20 ° C, and the surface state of the above normal flat plate is a surface state adjusted so that the value measured with a concrete range with a ket moisture meter HI520 is 5.0% or less. It was set as the dry surface. The wet surface was immersed in water for 7 days and then taken out from the water, and immediately after wiping the water floating on the surface with a waste cloth, the adhesive compositions of Examples and Comparative Examples 1 to 3 were used. After applying and cementing the following cement mortar after a predetermined time, the concrete flat plate was immersed in water from the surface to a portion of 10 mm or less for 28 days.

Placing time: The adhesive compositions of Examples and Comparative Examples 1 to 3 were applied, and after 30 minutes and 2 hours at each temperature, the mortar for repairing concrete on the market was passed. Tuff Ace # 10: Tough Ace Emulsion = 20: 3.5 (weight ratio, product name, manufactured by Lion Corporation) was applied to a thickness of 10 mm with a hammer.

Curing days: After applying the mortar, curing was performed for 28 days.

Evaluation methods

Adhesion strength: Adhesion was evaluated by using a Kenken-type adhesion tester to evaluate the adhesion strength and fracture condition. For the adhesion strength, after curing the mortar for 28 days, the surface is sufficiently polished with sandpaper # 80, and a 40 × 40 mm steel jig is bonded with an epoxy adhesive. After the adhesive was cured, a notch reaching a normal flat plate was made around the steel jig with a diamond cutter, and the adhesion strength was measured with a Kenken-type adhesion tester. The adhesion strength was evaluated as ◯ for 3.0 MPa or more, Δ for 2.0 MPa or more and less than 3.0 MPa, and x for less than 2.0 MPa.

Fracture situation: Visually evaluate the condition of the concrete pieces adhering to the steel jig after measuring the adhesion strength with the Kenken-type adhesion tester. More than 50% of the normal flat pieces are attached to the steel jig side. What was done was set as ◯ as the cohesive failure of the existing concrete, and × at less than 50% or failure at the interface between the normal flat plate and the mortar.

Summary of Adhesion Test Results: The adhesive compositions of the examples have a bonding strength of 3.0 MPa or more on all dry and wet surfaces at 5 ° C. and 20 ° C., and agglomeration of ordinary flat plates with a fracture condition of 50% or more While it was a failure, Comparative Example 1 was evaluated as Δ or ×, and Comparative Example 2 and Comparative Example 3 were evaluated as Δ or × on the wet surface.

Claims (2)

An adhesive composition which with coated on joint surface out when splicing out a new concrete or mortar existing concrete or mortar base, Ri Do epoxy resin and a water dispersible polyamine epoxy adduct and hydraulic cement, water-dispersible Polyamine epoxy adduct is (A) a monoepoxide in an amount that reacts with polyamine in an amount of 10 to 50% of the primary amino groups of the polyamine and an amount of polyepoxide in an amount that reacts with 5 to 65% of the residual primary amino groups of the polyamine A resin obtained by reacting 0.25 to 4 parts by weight of a water-compatible polyamine-epoxy adduct and (B) a monoamine or polyepoxide with a primary amino group, which is formed by addition reaction of Consisting of 1 part by weight of compatible polyamine-epoxy adduct, residual amino groups of polyamine A mixture of the water-compatible polyamine-epoxy adduct and the resin-compatible polyamine-epoxy adduct that is at least 25% reacted with formaldehyde and the polyamine is subsequently at least partially neutralized by reaction with an acid. it adhesive composition characterized. When handing over new concrete or mortar to the existing concrete or mortar base, the adhesive composition according to claim 1 is applied to the joint surface of the existing concrete or mortar, and in contact with the adhesive composition, A concrete joining method characterized by placing mortar.