JP4803482B2 - Gas divergence bag - Google Patents

Gas divergence bag Download PDF

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JP4803482B2
JP4803482B2 JP2005164480A JP2005164480A JP4803482B2 JP 4803482 B2 JP4803482 B2 JP 4803482B2 JP 2005164480 A JP2005164480 A JP 2005164480A JP 2005164480 A JP2005164480 A JP 2005164480A JP 4803482 B2 JP4803482 B2 JP 4803482B2
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outer bag
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JP2006335447A (en
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昭男 合田
高 柴田
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Taiko Pharmaceutical Co Ltd
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Description

この発明は、微量のガスを長期間にわたって発散させることのできるガス発散袋状体に関するものである。   The present invention relates to a gas diffusing bag-like body capable of diffusing a very small amount of gas over a long period of time.

従来、この種のガス発散袋状体は、滅菌、消臭剤として、例えば図4に示したように、亜塩素酸塩および水中でこの亜塩素酸塩と反応して二酸化塩素を発生しうる化合物とを密封してなるガス透過性外袋11内に、水性媒質を密封する易破断性の内袋12を収納してなるものが存在する(特許文献1)。   Conventionally, this type of gas-diffusing bag-like body can generate chlorine dioxide as a sterilizing and deodorizing agent, for example, as shown in FIG. 4, by reacting with chlorite and this chlorite in water. There is a gas permeable outer bag 11 formed by sealing a compound with an easily breakable inner bag 12 for sealing an aqueous medium (Patent Document 1).

このように構成された従来の滅菌、消臭剤は、種々の対象物に簡便かつ安全に装着使用できると共に、二酸化塩素をその場で容易に発生させることができるという効果を有している。しかも、二酸化塩素の発生期間も、封入した化合物や水性溶媒の組成や比率の調整により簡便にコントロールすることができ、残留毒性の問題も生じないという効果を有している。   The conventional sterilization and deodorant configured as described above has an effect that it can be used easily and safely on various objects and chlorine dioxide can be easily generated on the spot. Moreover, the generation period of chlorine dioxide can be easily controlled by adjusting the composition and ratio of the encapsulated compound and the aqueous solvent, and there is an effect that the problem of residual toxicity does not occur.

さらに、この種のガス発散袋状体は、酸素発生袋として、例えば図5に示したように、所定の衝撃により破裂する程度の強度に設定した内袋21内に過酸化物の分解溶液または懸濁液からなる分解剤22を封入し、この内袋21と酸素発生剤23としての過酸化物とを水分不透過性の中袋24に密封すると共に、前記中袋24に所定数の微細通気孔25を穿設し、さらにこの中袋24を水分不透過性でかつ気体透過性を備える外装袋26内に密封してなるものが存在する(特許文献2)。   Further, this type of gas-diffusing bag-like body is an oxygen-generating bag, for example, as shown in FIG. 5, a peroxide decomposition solution or an inner bag 21 set to a strength that can be ruptured by a predetermined impact. A decomposing agent 22 made of a suspension is sealed, and the inner bag 21 and the peroxide as the oxygen generating agent 23 are sealed in a water-impermeable inner bag 24 and a predetermined number of fine particles are contained in the inner bag 24. There is one in which a vent hole 25 is formed and the inner bag 24 is sealed in an outer bag 26 that is impermeable to moisture and gas permeable (Patent Document 2).

このように構成された従来の酸素発生袋は、内袋21の破裂時における衝撃を中袋24で緩衝することができ外装袋26のシール破損などを確実に阻止することができるという効果を有している。また、中袋24で発生した酸素ガスを微細通気孔25を介して一旦外装袋26内に滞留した後、外装袋26の気体透過作用によりその全面から放出するようにしたので、外装袋26の単位面積当たりの酸素ガス圧力が軽減され、従って、破裂事故などを確実に回避することができるだけでなく、外装袋26の素材も従来より安価なものを使用できるので製造コストの軽減を図ることが可能となるという効果を有している。   The conventional oxygen generating bag configured as described above has an effect that the impact when the inner bag 21 is ruptured can be buffered by the inner bag 24 and the outer bag 26 can be reliably prevented from being damaged. is doing. Further, the oxygen gas generated in the inner bag 24 is once retained in the outer bag 26 through the fine vent 25, and then released from the entire surface by the gas permeation of the outer bag 26. Oxygen gas pressure per unit area is reduced, so that it is possible not only to avoid a rupture accident, but also to reduce the manufacturing cost because the outer bag 26 can be made of less expensive materials. It has the effect of becoming possible.

また、この種のガス発散袋状体は、炭酸ガス供給装置として、例えば図6に示したように、炭水化物を含んだ水31を収納した袋32と、乾燥した酵母33を含んだ担持体34と、脱臭剤35を含み前記袋32および担持体34を収納した断熱性袋36と、炭酸ガス透過性を有し前記断熱性袋36を収納した袋37よりなるものが存在する(特許文献3)。   Further, this type of gas diffusing bag-like body is a carbon dioxide gas supply device, for example, as shown in FIG. 6, a bag 32 containing water 31 containing carbohydrates and a carrier 34 containing dried yeast 33. And a heat insulating bag 36 containing the deodorizer 35 and containing the bag 32 and the carrier 34, and a bag 37 having carbon dioxide permeability and containing the heat insulating bag 36 (Patent Document 3). ).

このように構成された従来の炭酸ガス供給装置は、高圧ボンベのような高価で操作方法の複雑な容器を用いることなく、廉価で取扱いの容易な安全な装置で、食品保存に必要な炭酸ガスを供給し、同時に雰囲気中の酸素を吸収するという効果を有している。さらに、構造が簡単で小型軽量であるため、食品と同封して冷蔵庫で保存できるという効果も有している。
実公平6−10996号公報(第1、3頁、第1図) 実開平3−50025号公報(第1頁、第1図) 特公昭61−7306号公報(第1、2頁、第1図)
The conventional carbon dioxide supply apparatus configured as described above is a safe apparatus that is inexpensive and easy to handle without using expensive and complicated containers such as high-pressure cylinders. At the same time as absorbing oxygen in the atmosphere. Furthermore, since the structure is simple and small and light, it has the effect that it can be enclosed in food and stored in a refrigerator.
Japanese Utility Model Publication No. 6-10996 (pages 1, 3 and 1) Japanese Utility Model Publication No. 3-50025 (first page, FIG. 1) Japanese Examined Patent Publication No. 61-7306 (pages 1, 2 and 1)

上記従来のガス発散袋状体においては、二酸化塩素、酸素、炭酸ガスなどのガスを発生させるには、図4に示したものでは、ガス透過性外袋11に掌や指などにより圧力を加え、内部に収納した内袋12を破断して、その内袋12の内容物とガス透過性外袋11の内容物とを反応させることにより、図5に示したものでは、気体透過性を備える外装袋26に同様にして圧力を加え、内部に収納した内袋21を破断して、その内袋21の内容物と中袋24の内容物とを反応させることにより、図6に示したものでは、炭酸ガス透過性を有する袋37に同様にして圧力を加え、内部に収納した袋32を破断して、その袋32の内容物と担持体34の担持物とを反応させることにより、それぞれ行っている。   In the conventional gas diffusion bag-like body, in order to generate a gas such as chlorine dioxide, oxygen, carbon dioxide, etc., in the case shown in FIG. 4, pressure is applied to the gas permeable outer bag 11 with a palm or a finger. In the case shown in FIG. 5, the inner bag 12 housed therein is broken and the contents of the inner bag 12 and the contents of the gas permeable outer bag 11 are reacted to provide gas permeability. As shown in FIG. 6, by applying pressure to the outer bag 26 in the same manner, breaking the inner bag 21 housed inside, and reacting the contents of the inner bag 21 and the contents of the inner bag 24. Then, pressure is similarly applied to the bag 37 having carbon dioxide gas permeability, the bag 32 accommodated in the bag is broken, and the contents of the bag 32 and the carrier 34 are reacted, Is going.

しかしながら、上記従来のガス発散袋状体においては、ガス透過性外袋11の内部に収納した内袋12、外装袋26の内部に収納した内袋21、袋37の内部に収納した袋32が、いずれも外部からは目で確認することができないため、掌や指などにより圧力を加えても、これら内袋12、内袋21、袋32が完全に破断されているのかどうかが判らず不便であるという問題点を有していた。また、これら内袋12、内袋21、袋32を完全に破断させるために、掌や指などにより余り強い圧力を加え過ぎると、ガス透過性外袋11、外装袋16、袋37までも破断するしてしまう虞れがあるという問題点を有していた。   However, in the conventional gas diffusion bag-like body, the inner bag 12 housed in the gas permeable outer bag 11, the inner bag 21 housed in the outer bag 26, and the bag 32 housed in the bag 37 are included. In any case, since it cannot be visually confirmed from the outside, it is inconvenient even if pressure is applied with a palm or a finger, and it is not known whether the inner bag 12, the inner bag 21, and the bag 32 are completely broken. It had the problem of being. Further, in order to completely break the inner bag 12, the inner bag 21, and the bag 32, if too much pressure is applied by a palm or a finger, the gas permeable outer bag 11, the outer bag 16, and the bag 37 are also broken. There was a problem that there was a possibility of doing.

そこで、この発明は、上記従来の問題点を解決するものであり、二酸化塩素、酸素、炭酸ガスなどのガスを発生させる物質どうしの混合状態を目で確認できて便利なものとなり、またその混合操作が行い易いので、掌や指などにより余り強い圧力を加え過ぎて外袋までも破断してしまう虞れのないガス発散袋状体を提供することを目的としてなされたものである。   Therefore, the present invention solves the above-mentioned conventional problems, and makes it possible to visually confirm the mixed state of substances that generate gases such as chlorine dioxide, oxygen, carbon dioxide, etc. Since the operation is easy, the purpose of the present invention is to provide a gas-dissipating bag-like body that does not cause the outer bag to break due to excessive pressure applied by a palm or a finger.

そのため、この発明のガス発散袋状体は、表裏面の少なくとも何れか一面を透光性とすると共に気体透過性で液体不透過性とし、所定の圧力をかけても周縁部1aが開封しないようにした外袋状体1内に、液体不透過性とし、所定の圧力をかけたときに周縁部2aの少なくとも一部が開封するようにした内袋状体2を収容してなるものとし、前記外袋状体1には第一収容物M1 を収容し、内袋状体2には第二収容物M)を収容し、これら第一収容物M1 と第二収容物M2 は混合したときにガスを発生する物質とし、これら第一収容物M1 と第二収容物M2 のうち少なくとも第二収容物M2 は液状物質としたものとし、前記外袋状体1を、気体透過性で液体不透過性の合成樹脂材を不織布3に層状加工したものとしている。 Therefore, the gas diffusing bag-like body of the present invention makes at least one of the front and back surfaces translucent and gas permeable and liquid impermeable so that the peripheral edge 1a does not open even when a predetermined pressure is applied. In the outer bag-shaped body 1, the inner bag-shaped body 2 that is liquid-impermeable and is designed to open at least a part of the peripheral edge 2a when a predetermined pressure is applied, When the first container M1 is stored in the outer bag 1 and the second container M) is stored in the inner bag 2, the first container M1 and the second container M2 are mixed. It is assumed that at least the second container M2 of the first container M1 and the second container M2 is a liquid substance, and the outer bag 1 is gas-permeable and liquid-free. A permeable synthetic resin material is layered on the nonwoven fabric 3 .

そして、この発明のガス発散袋状体は、前記気体透過性で液体不透過性の合成樹脂材を、マイクロホール加工をした薄手の気液不透過性の合成樹脂材としたものとしている。 In the gas divergence bag-like body of the present invention, the gas-permeable and liquid-impermeable synthetic resin material is a thin gas-liquid impermeable synthetic resin material that is microhole processed .

この発明のガス発散袋状体は、以上に述べたように構成されているので、二酸化塩素、酸素、炭酸ガスなどのガスを発生させる物質どうしの混合状態を目で確認できて便利なものとなり、またその混合操作が行い易いので、掌や指などにより余り強い圧力を加え過ぎて外袋までも破断してしまう虞れのないものとなる。   Since the gas-diffusing bag-like body of the present invention is configured as described above, it is convenient to visually confirm the mixed state of substances that generate gases such as chlorine dioxide, oxygen, and carbon dioxide. In addition, since the mixing operation is easy to perform, there is no possibility that the outer bag is broken by applying too much pressure with a palm or a finger.

以下、この発明のガス発散袋状体の実施の形態を、図面に基づいて詳細に説明する。   Hereinafter, embodiments of the gas-diverging bag-like body of the present invention will be described in detail based on the drawings.

この発明のガス発散袋状体は、図1に示したように、表裏面の少なくとも何れか一面を透光性とした外袋状体1内に、内袋状体2を収容したものとしている。なお、図示した外袋状体1は、表面を透光性とし裏面を不透光性としているが、表面を不透光性とし裏面を透光性としても、表裏面の両面とも透光性としてもよい。また、内袋状体2は、表裏面を透光性とするのが好ましいが、表裏面の何れか一面を透光性としても、表裏面を不透光性としてもよい。   As shown in FIG. 1, the gas diffusing bag-like body of the present invention has an inner bag-like body 2 accommodated in an outer bag-like body 1 in which at least one of the front and rear surfaces is made transparent. . In addition, although the illustrated outer bag-like body 1 has a light-transmitting surface and a light-transmitting back surface, both the front and back surfaces are light-transmitting even if the surface is light-transmitting and the back surface is light-transmitting. It is good. Moreover, although it is preferable that the inner bag-like body 2 makes the front and back surfaces translucent, either one of the front and back surfaces may be translucent or the front and back surfaces may be opaque.

前記外袋状体1は、その周縁部1aを強接着するなどして、掌で叩いたり、指で押し付けるなどして、所定の圧力をかけても、その外袋状体1の周縁部1aが開封しないようにしている。さらに、前記外袋状体1は、表裏面の少なくとも何れか一面を気体透過性で液体不透過性としている。すなわち、前記外袋状体1は、表面を気体透過性で液体不透過性とし裏面を気液不透過性としても、表面を気液不透過性とし裏面を気体透過性で液体不透過性としても、表裏面の両面とも気体透過性で液体不透過性としてもよい。   The outer bag 1 has a peripheral edge 1a even when a predetermined pressure is applied, for example, by strongly bonding the peripheral edge 1a, hitting it with a palm, or pressing it with a finger. Is not opened. Furthermore, the outer bag-like body 1 has at least one of the front and back surfaces made gas permeable and liquid impermeable. That is, the outer bag 1 has a gas permeable and liquid impermeable surface and a gas and liquid impermeable back surface, and a gas and liquid impermeable surface and gas permeable and liquid impermeable back surface. Alternatively, both the front and back surfaces may be gas permeable and liquid impermeable.

前記内袋状体2は、その周縁部2aの少なくとも一部を弱接着した部分2bとするなどして、掌で叩いたり、指で押し付けるなどして、所定の圧力をかけたときに、その内袋状体2の弱接着した部分2bが開封するようにしている。また、この内袋状体2は、その周縁部2aのすべてを弱接着した部分2bとすることもできる。さらに、前記内袋状体2は、表裏面を気液不透過性とするのが好ましいが、表裏面を気体透過性で液体不透過性としてもよい。   When the inner bag-like body 2 is applied with a predetermined pressure by hitting it with a palm or pressing it with a finger, for example, by making at least a part of its peripheral edge 2a a weakly bonded portion 2b, The weakly bonded portion 2b of the inner bag-like body 2 is opened. Moreover, this inner bag-shaped body 2 can also be made into the part 2b which weakly adhere | attached all the peripheral parts 2a. Further, the inner bag-like body 2 preferably has gas / liquid impermeable surfaces on the front and back surfaces, but the front and back surfaces may be gas permeable and liquid impermeable.

前記外袋状体1の周縁部1aおよび内袋状体2の周縁部2aは、ヒートシール、超音波シール、接着剤などによって接着するものとしており、シールの形状や状態、使用する接着剤の種類などによってその接着強度に差をつけ、前記内袋状体2の周縁部2aの少なくとも一部の接着強度を、外袋状体1の周縁部1aの接着強度より小さくしている。したがって、外袋状体1を掌で叩いたり、指で押し付けるなどして、所定の圧力をかけると、外袋状体1の周縁部2aは開封しないが、内袋状体2の周縁部2aの少なくとも一部は開封することになる。   The peripheral edge 1a of the outer bag-shaped body 1 and the peripheral edge 2a of the inner bag-shaped body 2 are bonded by heat sealing, ultrasonic sealing, adhesive, etc., and the shape and state of the seal, the adhesive used The adhesive strength is varied depending on the type or the like, and the adhesive strength of at least a part of the peripheral edge 2a of the inner bag-like body 2 is made smaller than the adhesive strength of the peripheral edge 1a of the outer bag-like body 1. Therefore, when a predetermined pressure is applied by hitting the outer bag 1 with a palm or pressing it with a finger, the peripheral edge 2a of the outer bag 1 is not opened, but the peripheral edge 2a of the inner bag 2 is not opened. At least a part of will be opened.

前記外袋状体1には、第一収容物M1 を収容し、内袋状体2には、第二収容物M2 を収容し、これら第一収容物M1 と第二収容物M2 は混合したときにガスを発生する物質としている。また、これら第一収容物M1 と第二収容物M2 のうち少なくとも第二収容物M2 は液状物質としている。図示したものは、第一収容物M1 を顆粒や粉体などの固体物質としており、第二収容物M2 を液体やコロイドなどの液状物質としているが、第一収容物M1 も第二収容物M2 と同様に液状物質としてもよい。さらに、前記内袋状体2と第一収容物M1 を合わせた容積を、外袋状体1の内容積に対して80%以下にしている。このようにすると、前記外袋状体1内の内袋状体2の容積比率が小さくなって、掌で叩いたり、指で押し付けるなどして外袋状体1に圧力をかけたときに、この圧力が内袋状体2にかかり易くなり外袋状体1が破れ難くなる。また、前記第一収容物M1 と第二収容物M2 が混合して化学反応が始まると変色し、化学反応が終了してガスが発生しなくなったときに化学反応時とは異なる色に変色する場合や、化学反応が始まっても変色しないが、化学反応が終了したときに元の色とは異なる色に変色する場合には、前記外袋状体1の透光性とした表裏面の少なくとも一面の一部に、化学反応終了時の色と同じ色を印刷したり、同じ色のシールを貼っておくことができる。このようにすれば、前記外袋状体1を通して化学反応時の色を目で確認できるので、その色が外袋状体1に印刷した色やシールの色と同じになれば、化学反応が終了したことがわかり、ガスの発生終了時期を知ることができる。   The outer bag 1 contains the first container M1, the inner bag 2 contains the second container M2, and the first container M1 and the second container M2 are mixed. It is a substance that sometimes generates gas. In addition, at least the second container M2 of the first container M1 and the second container M2 is a liquid substance. In the figure, the first container M1 is a solid substance such as a granule or a powder, and the second container M2 is a liquid substance such as a liquid or a colloid, but the first container M1 is also a second substance M2. It is good also as a liquid substance like. Furthermore, the total volume of the inner bag-like body 2 and the first container M1 is 80% or less with respect to the inner volume of the outer bag-like body 1. In this way, when the volume ratio of the inner bag-like body 2 in the outer bag-like body 1 is reduced and the outer bag-like body 1 is pressurized by hitting it with a palm or pressing it with a finger, This pressure is easily applied to the inner bag-shaped body 2 and the outer bag-shaped body 1 is not easily broken. Further, when the first container M1 and the second container M2 are mixed and a chemical reaction starts, the color changes, and when the chemical reaction ends and no gas is generated, the color changes to a color different from that during the chemical reaction. In this case, when the chemical reaction is started, the color does not change, but when the chemical reaction is finished, the color changes to a color different from the original color, at least the front and back surfaces of the outer bag-like body 1 are made translucent. The same color as the color at the end of the chemical reaction can be printed or a sticker of the same color can be pasted on a part of one side. In this way, since the color at the time of the chemical reaction can be visually confirmed through the outer bag-shaped body 1, if the color is the same as the color printed on the outer bag-shaped body 1 or the color of the seal, the chemical reaction is performed. Knowing that it has ended, you can know when the gas has ended.

前記外袋状体1の表裏面の少なくとも何れか一面を気体透過性で液体不透過性とするには、ポリエチレン樹脂、ポリプロピレン樹脂、ポリブタジエン樹脂などの合成樹脂材からなるものとすればよい。また、前記内袋状体2を気液不透過性とするには、アクリルニトリルスチレン(AS)樹脂、アクリルニトリルブタジエンスチレン(ABS)樹脂、エチレンビニールアルコール(EVOH)樹脂、塩化ビニル樹脂などの合成樹脂材からなるものとすればよい。なお、前記外袋状体1の表裏面の何れか一面を気液不透過性とするには、その面を前記内袋状体2と同様の合成樹脂材からなるものとすればよいのはいうまでもない。   In order to make at least one of the front and back surfaces of the outer bag-like body 1 gas permeable and liquid impermeable, the outer bag 1 may be made of a synthetic resin material such as polyethylene resin, polypropylene resin, or polybutadiene resin. In order to make the inner bag-like body 2 impermeable to gas and liquid, synthesis of acrylonitrile styrene (AS) resin, acrylonitrile butadiene styrene (ABS) resin, ethylene vinyl alcohol (EVOH) resin, vinyl chloride resin, etc. It may be made of a resin material. In addition, in order to make any one of the front and back surfaces of the outer bag-shaped body 1 gas-liquid impermeable, it is only necessary that the surface is made of the same synthetic resin material as the inner bag-shaped body 2. Needless to say.

さらに、前記外袋状体1は、AS樹脂、ABS樹脂、EVOH樹脂、塩化ビニル樹脂などの前記気液不透過性の合成樹脂材にマイクロホール加工をして、気体のみを透過性としたものとしてもよい。このとき、厚手の気液不透過性の合成樹脂材にマイクロホール加工すれば、その外袋状体1は、強度性に優れたものとなる。なお、薄手の気液不透過性の合成樹脂材にマイクロホール加工すれば、その外袋状体1は、強度性に劣ったものとなるが、そのマイクロホール加工をした薄手の気液不透過性の合成樹脂材を不織布3に層状加工したものにすれば、強度性に優れたものとなる。すなわち、前記外袋状体1は、前記気体透過性で液体不透過性の合成樹脂材を不織布3に層状加工することにより、強度性に優れたものとなる。   Furthermore, the outer bag-like body 1 is made by making a microhole process on the gas-liquid impermeable synthetic resin material such as AS resin, ABS resin, EVOH resin, vinyl chloride resin, etc. to make only gas permeable. It is good. At this time, if microhole processing is performed on a thick gas-liquid impermeable synthetic resin material, the outer bag-like body 1 becomes excellent in strength. If the thin gas-liquid impervious synthetic resin material is microhole processed, the outer bag-like body 1 becomes inferior in strength, but the microhole processed thin gas-liquid impermeable. If the synthetic resin material is made into a layered process on the nonwoven fabric 3, it will have excellent strength. That is, the outer bag-like body 1 is excellent in strength by layering the non-woven fabric 3 with the gas-permeable and liquid-impermeable synthetic resin material.

この発明のガス発散袋状体において、例えば、二酸化塩素ガスを発生させる場合には、第一収容物M1 をサラシ粉とし、第二収容物M2 を亜塩素酸ナトリウム溶液とすることができる。酸素を発生させる場合には、第一収容物M1 を過炭酸ナトリウムの粉体とし、第二収容物M2 を硫酸マンガンを添加した水溶液とすることができる。炭酸ガスを発生させる場合には、第一収容物M1 をビ−ル酵母などの酵母乾燥粉とし、第二収容物M2 をペプトン、ブドウ糖などの炭水化物水溶液とすることができる。   In the gas-spreading bag-like body of the present invention, for example, when chlorine dioxide gas is generated, the first container M1 can be made of powdered saliva and the second container M2 can be made of a sodium chlorite solution. In the case of generating oxygen, the first contents M1 can be a sodium percarbonate powder, and the second contents M2 can be an aqueous solution to which manganese sulfate is added. When carbon dioxide gas is generated, the first contents M1 can be yeast dry powder such as beer yeast, and the second contents M2 can be an aqueous carbohydrate solution such as peptone or glucose.

以上のように構成したこの発明のガス発散袋状体は、ガスを発散させない不使用時には必要に応じて、透光性または不透光性の化粧袋(図示せず)に収納しておき、ガスを発散させる時にはこの化粧袋を取り外し、液状物質とした第二収容物M2 を収納した内袋状体2を、外袋状体1の上から掌で叩いたり、指で押し付けて、内袋状体2に所定の圧力をかけると、内袋状体2の周縁部2aの弱接着した部分2bが開封し、第二収容物M2 が外袋状体1内に流れ込み、外袋状体1内の第一収容物M1 と混合し、二酸化塩素ガス、酸素、炭酸ガスなどの所定のガスを発生することになる。この場合、外袋状体1に余り強い圧力を加え過ぎても、外袋状体1を、気体透過性で液体不透過性の合成樹脂材を不織布3に層状加工したものであれば、この外袋状体2が破断してしまうようなことはない。そして、この発生したガスは、外袋状体2の気体透過性で液体不透過性とした表裏面の少なくとも何れか一面から、外袋状体1外部へ長期間にわたって発散することになる。   The gas-diffusing bag-like body of the present invention configured as described above is stored in a light-transmitting or non-light-transmitting cosmetic bag (not shown), if necessary, when not in use when gas is not diffused, When the gas is emitted, the cosmetic bag is removed and the inner bag-like body 2 containing the second container M2 in a liquid substance is struck with a palm from above the outer bag-like body 1 or pressed with a finger. When a predetermined pressure is applied to the body 2, the weakly bonded portion 2 b of the peripheral edge 2 a of the inner bag 2 is opened, and the second container M 2 flows into the outer bag 1, and the outer bag 1 A predetermined gas such as chlorine dioxide gas, oxygen, carbon dioxide gas is generated by mixing with the first container M1. In this case, even if too much pressure is applied to the outer bag-like body 1, if the outer bag-like body 1 is formed by laminating a gas-permeable and liquid-impermeable synthetic resin material on the nonwoven fabric 3, The outer bag 2 is not broken. The generated gas is emitted from the outer bag-like body 2 to the outside of the outer bag-like body 1 from at least one of the front and back surfaces that are gas-permeable and liquid-impermeable.

さらに、前記外袋状体1は、表裏面の少なくとも何れか一面を透光性としているので、この外袋状体1に収納した第一収容物M1 を袋外部から見ることができ、内袋状体2の周縁部2aの弱接着した部分2bが開封したとき、前記第一収容物M1 に第二収容物M2 が混合した状態を目で確認できる。前記内袋状体2の表裏面を透光性としたものでは、内袋状体2の周縁部2aの弱接着した部分2bが開封したとき、この第二収容物M2 が内袋状体2内から外袋状体1側に完全に流出してしまったかどうかを確認することができ、便利なものとなる。また、発生させるガスの種類によっては、前記第一収容物M1 に第二収容物M2 が混合すると、化学反応が始まって変色し、長期間にわたってガスを発生した後に、化学反応が終わって退色する場合があるが、このような場合にも変色してから退色するまでを目で確認できるので、ガスの発生終了時期を知ることができ、便利なものとなる。さらに、前記化学反応が始まって変色し、化学反応が終了してガスが発生しなくなったときに化学反応時とは異なる色に変色する場合や、化学反応が始まっても変色しないが、化学反応が終了したときに元の色とは異なる色に変色する場合には、前記したように透光性とした外袋状体1に化学反応終了時の色と同じ色を印刷したり、同じ色のシールを貼っておけば、このような場合にも化学反応時の色を目で確認できるので、その色が外袋状体1に印刷した色やシールの色と同じになれば、化学反応が終了したことがわかり、ガスの発生終了時期を知ることができ、便利なものとなる。   Further, since the outer bag-shaped body 1 has at least one of the front and back surfaces being translucent, the first container M1 stored in the outer bag-shaped body 1 can be seen from the outside of the bag, When the weakly bonded portion 2b of the peripheral edge 2a of the shaped body 2 is opened, the state where the second container M2 is mixed with the first container M1 can be visually confirmed. In the case where the front and back surfaces of the inner bag-like body 2 are translucent, when the weakly bonded portion 2b of the peripheral edge 2a of the inner bag-like body 2 is opened, the second container M2 becomes the inner bag-like body 2. It can be confirmed whether it has completely flowed out from the inside to the outer bag-like body 1 side, which is convenient. Also, depending on the type of gas to be generated, when the second container M2 is mixed with the first container M1, the chemical reaction starts and discolors, and after the gas is generated over a long period of time, the chemical reaction ends and the color fades. In such a case, since it is possible to visually confirm the color change and the color fading, it is possible to know the gas generation end time, which is convenient. Furthermore, when the chemical reaction starts and changes color, when the chemical reaction ends and gas is no longer generated, the color changes to a color different from that at the time of the chemical reaction. When the color is changed to a color different from the original color when the process is completed, the same color as the color at the end of the chemical reaction is printed on the outer bag-like body 1 that is made transparent as described above. In this case, the color at the time of the chemical reaction can be visually confirmed. If the color is the same as the color printed on the outer bag 1 or the color of the seal, the chemical reaction This is convenient because it is possible to know the end of gas generation and the end time of gas generation.

したがって、この発明のガス発散袋状体は、二酸化塩素、酸素、炭酸ガスなどのガスを発生させる物質どうしの混合状態を目で確認できて便利なものとなり、またその混合操作が行い易いので、掌や指などにより余り強い圧力を加え過ぎて、外袋を破断してしまう虞れがないものとなる。   Therefore, the gas-diffusing bag-like body of the present invention is convenient because the mixing state of substances that generate gas such as chlorine dioxide, oxygen, and carbon dioxide gas can be visually confirmed, and the mixing operation is easy to perform. There is no possibility that the outer bag will be broken by applying too much pressure with a palm or a finger.

この発明のガス発散袋状体のガス発生前の要部断面斜視図である。It is a principal part cross-sectional perspective view before the gas generation | occurrence | production of the gas diffusion bag-like body of this invention. この発明のガス発散袋状体を裏面から見た斜視図である。It is the perspective view which looked at the gas diffusion bag-like body of this invention from the back. この発明のガス発散袋状体のガス発生時における要部断面斜視図である。It is a principal part section perspective view at the time of gas generation of the gas diffusion bag-like object of this invention. 従来のガス発散袋状体の一例を示すガス発生前の要部断面斜視図である。It is a principal part section perspective view before gas generation which shows an example of the conventional gas diffusion bag-like object. 従来のガス発散袋状体の他の例を示すガス発生前の断面図である。It is sectional drawing before the gas generation | occurrence | production which shows the other example of the conventional gas divergence bag-like body. 従来のガス発散袋状体のさらに他の例を示すガス発生前の断面図である。It is sectional drawing before the gas generation | occurrence | production which shows the other example of the conventional gas diffusion bag-like body.

符号の説明Explanation of symbols

1 外袋状体
1a 周縁部
2 内袋状体
2a 周縁部
3 不織布
M1 第一収容物
M2 第一収容物
DESCRIPTION OF SYMBOLS 1 Outer bag-shaped body 1a Peripheral part 2 Inner bag-shaped body 2a Peripheral part 3 Nonwoven fabric M1 1st accommodation M2 1st accommodation

Claims (2)

表裏面の少なくとも何れか一面を透光性とすると共に気体透過性で液体不透過性とし、所定の圧力をかけても周縁部(1a)が開封しないようにした外袋状体(1)内に、液体不透過性とし、所定の圧力をかけたときに周縁部(2a)の少なくとも一部が開封するようにした内袋状体(2)を収容してなるものとし、前記外袋状体(1)には第一収容物(M1 )を収容し、内袋状体(2)には第二収容物(M2 )を収容し、これら第一収容物(M1 )と第二収容物(M2 )は混合したときにガスを発生する物質とし、これら第一収容物(M1 )と第二収容物(M2 )のうち少なくとも第二収容物(M2 )は液状物質としたガス発散袋状体であって、前記外袋状体(1)を、気体透過性で液体不透過性の合成樹脂材を不織布(3)に層状加工したものとしたことを特徴とするガス発散袋状体。 Inside the outer bag-like body (1) in which at least one of the front and back surfaces is made transparent, gas permeable and liquid impermeable so that the peripheral edge (1a) is not opened even when a predetermined pressure is applied. And an inner bag-like body (2) that is liquid-impermeable and that opens at least a part of the peripheral edge (2a) when a predetermined pressure is applied. The body (1) contains the first container (M1), the inner bag (2) contains the second container (M2), the first container (M1) and the second container. (M2) is a substance that generates gas when mixed, and of these first container (M1) and second container (M2), at least the second container (M2) is a liquid- dissipating bag. The outer bag-like body (1) is formed by laminating a gas-permeable and liquid-impermeable synthetic resin material into a nonwoven fabric (3). Gas diverging bag-like body, characterized in that the the. 前記気体透過性で液体不透過性の合成樹脂材を、マイクロホール加工をした薄手の気液不透過性の合成樹脂材としたことを特徴とする請求項1記載のガス発散袋状体。 2. The gas-diffusing bag-like body according to claim 1, wherein the gas-permeable and liquid-impermeable synthetic resin material is a thin gas-liquid impermeable synthetic resin material subjected to microhole processing .
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