JP4796654B1 - Biodegradable container manufacturing method and biodegradable container manufactured by the method - Google Patents

Biodegradable container manufacturing method and biodegradable container manufactured by the method Download PDF

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JP4796654B1
JP4796654B1 JP2010173761A JP2010173761A JP4796654B1 JP 4796654 B1 JP4796654 B1 JP 4796654B1 JP 2010173761 A JP2010173761 A JP 2010173761A JP 2010173761 A JP2010173761 A JP 2010173761A JP 4796654 B1 JP4796654 B1 JP 4796654B1
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慎一 小林
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Nissei Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

【課題】生分解性材料を水蒸気発泡させて焼成する際に生分解性材料の余剰分を発生させずに済む生分解性容器の製造方法を提供すること。
【解決手段】生分解性容器の製造方法は、ヒータを内蔵した嵌合可能な一対の雄型と雌型からなる発泡成形用の金型を用い、水分を含んだ生分解性材料を介在させて雄型と雌型を嵌合させ、金型内で生分解性材料を加熱し水蒸気発泡させて焼成することにより底部、胴部および開口縁部を有する容器状の発泡基材層を成形する工程を備え、雄型と雌型は完全に嵌合した際に互いに当接して第1蒸気抜き孔を形成する当接部をそれぞれ有すると共に少なくとも一方に第2蒸気抜き孔が形成され、金型内で生分解性材料を加熱する前記工程は、雄型と雌型の当接部が所定の間隔を空けて対向するように雄型と雌型を所定時間だけ予備的に嵌合させた後、前記当接部が互いに当接するように雄型と雌型を完全に嵌合させ第1および第2蒸気抜き孔から水蒸気を放散させながら焼成する工程である。
【選択図】図8
The present invention provides a method for producing a biodegradable container that does not generate a surplus of biodegradable material when the biodegradable material is fired by steam foaming.
A method of manufacturing a biodegradable container uses a foam molding mold comprising a pair of male and female molds that can be fitted with a heater and interposes a biodegradable material containing moisture. Then, a male and female molds are fitted together, and a biodegradable material is heated in a mold, steam-foamed and fired to form a container-like foamed base material layer having a bottom part, a body part and an opening edge part. A male mold and a female mold each having a contact portion that forms a first steam vent when they are fully fitted, and a second steam vent is formed on at least one of the molds. The step of heating the biodegradable material within the pre-fitting of the male mold and the female mold for a predetermined time so that the abutting portions of the male mold and the female mold face each other with a predetermined gap therebetween The first and second steam vent holes are formed by completely fitting the male mold and the female mold so that the abutting portions abut each other. A step of firing while dissipating water vapor.
[Selection] Figure 8

Description

この発明は、生分解性容器の製造方法およびその方法で製造された生分解性容器に関し、詳しくは生分解性材料を発泡成形して生分解性容器を製造する方法とその方法により製造された生分解性容器に関する。   The present invention relates to a method for producing a biodegradable container and a biodegradable container produced by the method, and more particularly, a method for producing a biodegradable container by foaming a biodegradable material and the method. It relates to a biodegradable container.

この発明に関連する従来技術としては、ヒータを内蔵した一対の雄型と雌型からなる発泡成形用の金型を用い、水分を含んだ生分解性材料を介在させて一対の雄型と雌型を嵌合させ、金型内で生分解性材料を加熱して水蒸気発泡させ、雌型の上部と側面または下部に形成された蒸気抜き孔から水蒸気を放散させながら生分解性材料を焼成し容器状の発泡基材層を得る生分解性容器の製造方法が知られている(例えば、特許文献1参照)。   As a prior art related to the present invention, a pair of male mold and female mold is formed by using a foaming mold comprising a pair of male mold and female mold with a built-in heater, and interposing a biodegradable material containing moisture. The mold is fitted, the biodegradable material is heated in the mold and steam-foamed, and the biodegradable material is baked while dissipating water vapor from the vent holes formed in the upper, side and lower parts of the female mold. A method for producing a biodegradable container for obtaining a container-like foamed base material layer is known (see, for example, Patent Document 1).

また、この発明に関連する従来技術としては、パルプ繊維層からなる容器を真空引きが可能な成形型に設置した後、容器の上方に樹脂フィルムを配置し、ヒータを備えたプラグで樹脂フィルムを容器内に押し込みつつ容器のパルプ繊維層を介して真空引きすることにより容器の内面を樹脂フィルムで被覆する断熱容器の製造方法が知られている(例えば、特許文献2参照)。   In addition, as a related art related to the present invention, after placing a container made of a pulp fiber layer on a mold capable of evacuation, a resin film is arranged above the container, and the resin film is placed with a plug provided with a heater. There is known a manufacturing method of a heat insulating container in which an inner surface of a container is covered with a resin film by evacuating through the pulp fiber layer of the container while being pushed into the container (see, for example, Patent Document 2).

韓国特許第10−0866940号公報Korean Patent No. 10-0866940 特許第4039908号公報Japanese Patent No. 4039908

二酸化炭素の削減や資源循環型社会の構築など、近年の環境問題に対する意識の高まりをうけ、使い捨て容器の分野においても石油資源に頼らない製品が求められている。
そのような中、植物由来のバイオマスを原料とした生分解性容器が注目されている。植物由来のバイオマスは大気中の二酸化炭素を吸収して成長しているため、廃棄後の生分解や焼却の際に二酸化炭素が排出されても、それは原料のバイオマスに吸収されていた二酸化炭素が再び大気中に排出されたこととなり、製造から廃棄までをトータルでみると大気中の二酸化炭素を増加させることにはならない。このような性質はカーボンニュートラルと呼ばれ、環境問題を考えるうえで重要なキーワードとなっている。
In response to growing environmental awareness in recent years, such as the reduction of carbon dioxide and the establishment of a resource recycling society, products that do not rely on petroleum resources are also required in the field of disposable containers.
Under such circumstances, biodegradable containers using plant-derived biomass as a raw material have attracted attention. Plant-derived biomass absorbs carbon dioxide in the atmosphere and grows. Therefore, even if carbon dioxide is discharged during biodegradation or incineration after disposal, it is absorbed by the raw material biomass. It was discharged into the atmosphere again, and the total amount of carbon dioxide in the atmosphere does not increase from the total production to disposal. Such a property is called carbon neutral and is an important keyword when considering environmental issues.

バイオマスを原料とする生分解性容器としては、澱粉を主原料とする生分解性材料を発泡・焼成して得られた発泡基材層の内面を耐水性フィルムで被覆したものが提案されている。つまり、発泡基材層は澱粉を主原料とする多孔質の焼成物であるため吸水性を有し水に容易に溶解するが、少なくとも容器の内面を耐水性フィルムで被覆すれば通常の容器と同様に使用できる。   Biodegradable containers made from biomass have been proposed in which the inner surface of a foamed substrate layer obtained by foaming and firing a biodegradable material made mainly from starch is covered with a water-resistant film. . In other words, the foamed base material layer is a porous baked product made of starch as a main raw material, so it absorbs water and dissolves easily in water. However, if at least the inner surface of the container is covered with a water-resistant film, It can be used similarly.

このような生分解性容器の製造方法としては、ヒータを備えた一対の雄型と雌型とからなる発泡成形用の金型を用い、生分解性材料を介在させて雄型と雌型を嵌合させ、金型内で生分解性材料を加熱し水蒸気発泡させて焼成することにより容器状の発泡基材層を成形した後、得られた発泡基材層を耐水性フィルムと共に真空引きが可能な成形型に配置し、発泡基材層を介して真空引きすることにより発泡基材層の内面を耐水性フィルムで被覆するという方法が一般的である。   As a method for manufacturing such a biodegradable container, a mold for foam molding comprising a pair of male mold and female mold equipped with a heater is used, and a male mold and a female mold are interposed with a biodegradable material interposed. After fitting and forming the container-shaped foam base material layer by heating the biodegradable material in the mold, foaming it with water vapor and firing it, the resulting foam base material layer can be vacuum drawn together with the water resistant film. A method of covering the inner surface of the foamed substrate layer with a water-resistant film by placing it in a possible mold and drawing a vacuum through the foamed substrate layer is common.

上記方法において、金型内で生分解性材料を加熱し水蒸気発泡させて焼成する際には、雄型と雌型の当接部に形成された複数の蒸気抜き孔から水蒸気を外部へ放散させつつ焼成することになる。この際、水蒸気発泡した生分解性材料の余剰分が蒸気抜き孔から外部へ吹き出し発泡基材層の開口縁部に繋がった状態で固化する。
このため、得られた発泡基材層を真空引き用の成形型に設置する前に、開口縁部に繋がった余剰分を予め切り落とす必要があり、これが生分解性容器の生産性を悪化させる要因の一つとなっている。
In the above method, when the biodegradable material is heated and steam-foamed and fired in the mold, the steam is diffused to the outside from a plurality of steam vent holes formed in the contact portion of the male mold and the female mold. While firing. At this time, the surplus of the steam-decomposable biodegradable material blows out from the steam vent hole and solidifies in a state where it is connected to the opening edge of the foam base material layer.
For this reason, before installing the obtained foam base material layer in a mold for vacuuming, it is necessary to cut off the excess connected to the opening edge portion in advance, which causes the productivity of the biodegradable container to deteriorate It has become one of the.

この発明は以上のような事情を考慮してなされたもので、生分解性材料を水蒸気発泡させて焼成する際に生分解性材料の余剰分を発生させずに済む生分解性容器の製造方法を提供するものである。   The present invention has been made in consideration of the above circumstances, and a method for producing a biodegradable container that does not generate a surplus of biodegradable material when the biodegradable material is foamed with water vapor and fired. Is to provide.

この発明は、ヒータを内蔵した嵌合可能な一対の雄型と雌型からなる発泡成形用の金型を用い、水分を含んだ生分解性材料を介在させて雄型と雌型を嵌合させ、金型内で生分解性材料を加熱し水蒸気発泡させて焼成することにより底部、胴部および開口縁部を有する容器状の発泡基材層を成形する工程を備え、雄型と雌型は完全に嵌合した際に互いに当接して第1蒸気抜き孔を形成する当接部をそれぞれ有すると共に少なくとも一方に第2蒸気抜き孔が形成され、金型内で生分解性材料を加熱する前記工程は、雄型と雌型の当接部が所定の間隔を空けて対向するように雄型と雌型を所定時間だけ予備的に嵌合させた後、前記当接部が互いに当接するように雄型と雌型を完全に嵌合させ第1および第2蒸気抜き孔から水蒸気を放散させながら焼成する工程であることを特徴とする生分解性容器の製造方法を提供するものである。   The present invention uses a mold for foam molding consisting of a pair of male and female molds that can be fitted with a heater, and mates the male and female molds with a biodegradable material containing moisture. And heating the biodegradable material in a mold, steam-foaming and firing to form a container-shaped foam base material layer having a bottom, a body and an opening edge, and a male mold and a female mold Each has a contact portion that forms a first steam vent when they are completely fitted together, and a second steam vent is formed in at least one of them to heat the biodegradable material in the mold. In the step, the male part and the female mold are preliminarily fitted with each other for a predetermined time so that the male part and the female part are opposed to each other with a predetermined interval, and then the abutting part comes into contact with each other. In this way, the male mold and female mold are completely fitted, and the water vapor is dissipated from the first and second vapor vent holes while firing. There is provided a method for producing a biodegradable container, characterized in that the step of.

この発明によれば、雄型と雌型を所定時間だけ予備的に嵌合させることにより生分解性材料に含まれる水分を適度に放散させてから雄型と雌型を完全に嵌合させるので、雄型と雌型を完全に嵌合させた際における金型内の生分解性材料に含まれる水分の量は従来よりも少なくなる。
生分解性材料が水蒸気発泡することによる金型内の内圧の上昇は生分解性材料に含まれる水分の量に比例するので、この発明では生分解性材料を水蒸気発泡させた際の金型内の内圧の上昇が適度に抑えられる。
このため、生分解性材料を蒸気抜き孔から押し出そうとする力は従来よりも弱くなる。
According to the present invention, the male mold and the female mold are completely fitted to each other after the male mold and the female mold are preliminarily fitted to each other for a predetermined time so that moisture contained in the biodegradable material is appropriately dissipated. The amount of moisture contained in the biodegradable material in the mold when the male mold and the female mold are completely fitted is smaller than that in the prior art.
Since the increase in the internal pressure in the mold due to steam foaming of the biodegradable material is proportional to the amount of moisture contained in the biodegradable material, in the present invention, in the mold when the biodegradable material is steam foamed. The increase in the internal pressure of is moderately suppressed.
For this reason, the force which pushes out biodegradable material from a steam vent hole becomes weaker than before.

また、雄型と雌型が完全に嵌合した際における金型内の生分解性材料に含まれる水分の量が従来よりも少なくなるので、焼成時に金型内から外部へ放散させる水蒸気の絶対量も少なくなる。
このため、水蒸気を放散させるのに必要な蒸気抜き孔の断面積を小さく設定でき、しかも本発明では第1蒸気抜き孔と第2蒸気抜き孔に分散して設けるので、第1および第2蒸気抜き孔の各々の断面積を生分解性材料が吹き出さない程度に小さく設定できる。
In addition, since the amount of moisture contained in the biodegradable material in the mold when the male mold and female mold are completely fitted is smaller than before, the absolute amount of water vapor that diffuses from the mold to the outside during firing The amount is also reduced.
For this reason, the cross-sectional area of the steam vent hole required to dissipate the water vapor can be set small, and in the present invention, the first steam vent hole and the second steam vent hole are provided in a distributed manner. The cross-sectional area of each of the punch holes can be set so small that the biodegradable material does not blow out.

そして、生分解性材料に含まれる水分が減少し、かつ金型内の内圧が適度に抑えられた状態で、断面積の小さな第1および第2蒸気抜き孔の双方から水蒸気を放散させながら焼成することにより、生分解性材料の余剰分が蒸気抜き孔から吹き出すことを防止しつつ生分解性材料を良好に焼成できる。
この結果、生分解性材料の余剰分を発生させることなく生分解性容器を生産性よく製造できる。
Then, in a state where moisture contained in the biodegradable material is reduced and the internal pressure in the mold is moderately suppressed, firing is performed while dissipating water vapor from both the first and second vapor vent holes having a small cross-sectional area. By doing so, the biodegradable material can be satisfactorily fired while preventing surplus of the biodegradable material from being blown out from the vapor vent hole.
As a result, the biodegradable container can be manufactured with high productivity without generating surplus of the biodegradable material.

本発明の実施形態に係る製造方法により製造された生分解性容器の斜視図である。It is a perspective view of the biodegradable container manufactured by the manufacturing method which concerns on embodiment of this invention. 図1に示される生分解性容器のA−A矢視断面図である。It is AA arrow sectional drawing of the biodegradable container shown by FIG. 図2のB部の拡大図である。It is an enlarged view of the B section of FIG. 図2のC部の拡大図である。It is an enlarged view of the C section of FIG. 本発明の実施形態に係る製造方法に用いられる発泡成形用の金型の斜視図である。It is a perspective view of the metal mold | die for foam molding used for the manufacturing method which concerns on embodiment of this invention. 図5に示される金型のD−D断面図である。It is DD sectional drawing of the metal mold | die shown by FIG. 図6に示される金型が嵌合した状態を示す断面図である。It is sectional drawing which shows the state which the metal mold | die shown by FIG. 6 fitted. 本発明の実施形態に係る生分解性容器の製造方法を説明する工程図である。It is process drawing explaining the manufacturing method of the biodegradable container which concerns on embodiment of this invention. 本発明の実施形態に係る生分解性容器の製造方法を説明する工程図である。It is process drawing explaining the manufacturing method of the biodegradable container which concerns on embodiment of this invention. 本発明の実施形態に係る生分解性容器の製造方法を説明する工程図である。It is process drawing explaining the manufacturing method of the biodegradable container which concerns on embodiment of this invention. 本発明の実施形態に係る生分解性容器の製造方法を説明する工程図である。It is process drawing explaining the manufacturing method of the biodegradable container which concerns on embodiment of this invention. 図10(f)のE部の拡大図である。It is an enlarged view of the E section of Drawing 10 (f).

この発明による生分解性容器の製造方法は、ヒータを内蔵した嵌合可能な一対の雄型と雌型からなる発泡成形用の金型を用い、水分を含んだ生分解性材料を介在させて雄型と雌型を嵌合させ、金型内で生分解性材料を加熱し水蒸気発泡させて焼成することにより底部、胴部および開口縁部を有する容器状の発泡基材層を成形する工程を備え、雄型と雌型は完全に嵌合した際に互いに当接して第1蒸気抜き孔を形成する当接部をそれぞれ有すると共に少なくとも一方に第2蒸気抜き孔が形成され、金型内で生分解性材料を加熱する前記工程は、雄型と雌型の当接部が所定の間隔を空けて対向するように雄型と雌型を所定時間だけ予備的に嵌合させた後、前記当接部が互いに当接するように雄型と雌型を完全に嵌合させ第1および第2蒸気抜き孔から水蒸気を放散させながら焼成する工程であることを特徴とする。   The method for producing a biodegradable container according to the present invention uses a foam molding mold comprising a pair of male and female molds that can be fitted with a heater, and interposes a biodegradable material containing moisture. A step of forming a container-like foamed base material layer having a bottom part, a body part, and an opening edge part by fitting a male mold and a female mold, heating a biodegradable material in a mold, steam-foaming and firing The male mold and the female mold each have a contact portion that forms a first steam vent when they are fully fitted to each other, and at least one of the second steam vent is formed in the mold. In the step of heating the biodegradable material, the male mold and the female mold are preliminarily fitted with each other for a predetermined time so that the male mold and the female mold are opposed to each other with a predetermined interval. The first and second steam vent holes are formed by completely fitting the male mold and the female mold so that the abutting portions abut each other. Characterized in that it is a step of firing while dissipating Luo steam.

この発明による生分解性容器の製造方法において、ヒータを内蔵した嵌合可能な一対の雄型と雌型とからなる発泡成形用の金型とは、嵌合時に容器の形状に対応したキャビティを形成し、該キャビティ内で生分解性材料を加熱し発泡させた際に生じるガスや水蒸気を外部へ適宜放出させることができるように構成された金型を意味する。ヒータは雄型と雌型にそれぞれ設けられ金型を所望の温度に維持する。   In the biodegradable container manufacturing method according to the present invention, the foam molding mold comprising a pair of matable male and female molds with a built-in heater has a cavity corresponding to the shape of the container at the time of mating. It means a mold that is formed and configured so that gas or water vapor generated when the biodegradable material is heated and foamed in the cavity can be appropriately discharged to the outside. A heater is provided for each of the male mold and the female mold to maintain the mold at a desired temperature.

当接部とは、雄型と雌型が完全に嵌合した際に互いに当接して雄型と雌型の位置決めを図り、キャビティに通ずる第1蒸気抜き孔を形成する部分を意味し、雄型と雌型にそれぞれ形成される。
第1蒸気抜き孔とは、雄型と雌型の当接部により形成されキャビティ内で発生したガスや水蒸気を外部へ放散させるための通路を意味する。
第2蒸気抜き孔とは、雄型および雌型の少なくとも一方に形成され、第1蒸気抜き孔と同様にキャビティ内で発生したガスや水蒸気を外部へ放散させるための通路を意味する。
The abutting portion means a portion where the male mold and the female mold are in contact with each other when the male mold and the female mold are completely fitted, thereby positioning the male mold and the female mold and forming a first steam vent hole that communicates with the cavity. A mold and a female mold are formed respectively.
The first vapor vent hole means a passage that is formed by the male and female abutting portions and diffuses gas and water vapor generated in the cavity to the outside.
The second vapor vent hole is formed in at least one of the male mold and the female mold, and means a passage for dissipating gas and water vapor generated in the cavity to the outside like the first vapor vent hole.

生分解性材料とは、生分解性容器の骨格をなす発泡基材層の材料であって発泡成形用の金型で成形できるように水分を含んで調製されたものを意味する。   The biodegradable material means a material for the foam base material layer that forms the skeleton of the biodegradable container, and is prepared by containing moisture so that it can be molded with a mold for foam molding.

この発明による生分解性容器の製造方法において、雄型は、発泡基材層の胴部と対応する部分の表面に当接部へ向かって延びる複数の縦溝が形成されていてもよい。
このような構成によれば、金型と焼成中の発泡基材層との間に残留する水蒸気を第1蒸気抜き孔の付近まで導いて、第1蒸気抜き孔から外部へ放散させることができる。
これにより、金型と焼成中の発泡基材層との密着性が向上し、金型の形状が正確に再現されるばかりでなく、発泡基材層の表面が非常に滑らかになる。
In the biodegradable container manufacturing method according to the present invention, the male mold may be formed with a plurality of longitudinal grooves extending toward the abutting portion on the surface of the portion corresponding to the body portion of the foamed base material layer.
According to such a configuration, the water vapor remaining between the mold and the foamed base material layer being fired can be guided to the vicinity of the first vapor vent hole and diffused to the outside from the first vapor vent hole. .
This improves the adhesion between the mold and the foamed base material layer during firing, and not only accurately reproduces the shape of the mold, but also makes the surface of the foam base material layer very smooth.

この発明による生分解性容器の製造方法において、雌型は、発泡基材層の胴部と対応する部分の表面に当接部へ向かって延びるひだ状の凹凸が形成されてもよい。   In the method for producing a biodegradable container according to the present invention, the female mold may be formed with pleated irregularities extending toward the contact portion on the surface of the portion corresponding to the body portion of the foam base layer.

このような構成によれば、雌型に形成されたひだ状の凹凸により胴部と対応する部分に肉厚の厚い部分と薄い部分が交互に形成されることから、金型内における生分解性材料の急激な流動が抑えられ、生分解性材料が金型内に満注していく際に急激に伸びてちぎれることを防止できる。
これにより、満注不良により発泡基材層に部分的な欠けが生じることを防止できるという好ましい効果が得られる。
According to such a configuration, the thick and thin portions are alternately formed in the portion corresponding to the body portion by the pleated unevenness formed in the female mold, so that biodegradability in the mold is achieved. The rapid flow of the material is suppressed, and it is possible to prevent the biodegradable material from suddenly extending and tearing when the biodegradable material is fully poured into the mold.
Thereby, the preferable effect that it can prevent that a partial crack is produced in a foaming base material layer by defective filling is acquired.

この発明による生分解性容器の製造方法において、第1蒸気抜き孔は雄型と雌型の当接部に部分的に形成される隙間により複数の第1蒸気抜き孔に分割して形成されてもよい。
このような構成によれば、第1蒸気抜き孔が複数の第1蒸気抜き孔に分割して形成されるので、各第1蒸気抜き孔を生分解性材料が溢れ出し難い適切な大きさと形状に設計し易くなる。
In the method of manufacturing a biodegradable container according to the present invention, the first steam vent hole is formed by being divided into a plurality of first steam vent holes by a gap partially formed in the contact portion between the male mold and the female mold. Also good.
According to such a configuration, since the first steam vent hole is formed by being divided into a plurality of first steam vent holes, each first steam vent hole has an appropriate size and shape that prevents the biodegradable material from overflowing. It becomes easy to design.

この発明による生分解性容器の製造方法において、雌型は複数のモールド片からなり、第2蒸気抜き孔は隣接するモールド片の隙間により発泡基材層の底部と対応する部分の縁に沿って環状に形成されてもよい。
このような構成によれば、第2蒸気抜き孔は、雄型と雌型の当接部に形成される第1蒸気抜き孔から離れた発泡基材層の底部と対応する部分の縁に沿って形成されるので、金型内の水蒸気を均一に放散させることができ、金型内の内圧を効果的に抑えることができる。
In the method for producing a biodegradable container according to the present invention, the female mold is composed of a plurality of mold pieces, and the second steam vent hole is along the edge of the portion corresponding to the bottom of the foam base material layer by the gap between the adjacent mold pieces. It may be formed in an annular shape.
According to such a configuration, the second steam vent hole is along the edge of the portion corresponding to the bottom portion of the foam base material layer that is separated from the first steam vent hole formed in the contact portion between the male mold and the female mold. Therefore, the water vapor in the mold can be dissipated uniformly, and the internal pressure in the mold can be effectively suppressed.

この発明による生分解性容器の製造方法において、雄型と雌型を予備的に嵌合させる所定時間は約3〜15秒の範囲内とすることができる。   In the method for producing a biodegradable container according to the present invention, the predetermined time for preliminarily fitting the male mold and the female mold can be in the range of about 3 to 15 seconds.

つまり、雄型と雌型を予備的に嵌合させる時間が短くなり過ぎると、生分解性材料に含まれる水分を適度な量まで事前に放散させるのが難しくなり、雄型と雌型を完全に嵌合させて焼成する工程において生分解性材料に含まれる水分を第1および第2蒸気抜き孔から十分に放散させることができず、発泡基材層に生焼けが生ずる恐れがある。
一方、雄型と雌型と予備的に嵌合させる時間が長くなり過ぎると、生分解性材料に含まれる水分を必要以上に放散させてしまい、雄型と雌型を完全に嵌合させた際に生分解性材料に含まれる水分の量が少なくなり過ぎ、キャビティ内の内圧が十分に高まらず生分解性材料の満注不良により発泡基材層に部分的な欠けが生ずる恐れがある。
このような観点からして、雄型と雌型を予備的に嵌合させる時間には適切な範囲があり、生分解性材料に含まれる水分の量や金型の温度にもよるが、予備的に嵌合させる時間は約3〜15秒程度が適切な範囲といえる。
In other words, if the time for pre-mating the male mold and female mold becomes too short, it becomes difficult to dissipate the moisture contained in the biodegradable material to an appropriate amount in advance, and the male mold and female mold are completely separated. The water contained in the biodegradable material cannot be sufficiently dissipated from the first and second steam vent holes in the step of fitting and firing, and there is a risk that the foamed base material layer will be burnt.
On the other hand, if the time for pre-mating the male mold and female mold becomes too long, the moisture contained in the biodegradable material is dissipated more than necessary, and the male mold and female mold are completely fitted. In some cases, the amount of moisture contained in the biodegradable material is too small, and the internal pressure in the cavity is not sufficiently increased, and the foam base material layer may be partially chipped due to poor filling of the biodegradable material.
From this point of view, there is an appropriate range for the time for which the male mold and female mold are preliminarily fitted, and depending on the amount of moisture contained in the biodegradable material and the temperature of the mold, About 3 to 15 seconds can be said to be an appropriate range for the fitting time.

この発明による生分解性容器の製造方法において、生分解性材料は少なくとも澱粉、パルプおよび水を混練してなる混練物であってもよい。
このような構成によれば、植物由来の材料である澱粉とパルプが主原料となるので、生分解性に優れ、環境負荷の低い生分解性容器を製造できるようになる。
In the method for producing a biodegradable container according to the present invention, the biodegradable material may be a kneaded product obtained by kneading at least starch, pulp and water.
According to such a configuration, since starch and pulp, which are plant-derived materials, are the main raw materials, a biodegradable container having excellent biodegradability and low environmental impact can be produced.

ここで、澱粉とは、澱粉またはその誘導体を意味し、特に限定されるものではないが、例えば、馬鈴薯、トウモロコシ、タピオカ、米、小麦、さつまいもなど、主要穀物として世界的に生産されている農産物から得られる澱粉を挙げることができ、特定の農産物から製造されたものであってもよいし、複数の農産物から製造されたものを混合したものであってもよい。
また、上記の澱粉の誘導体は、生分解性を阻害しない範囲で澱粉を修飾したものを指し、例えば、α化澱粉、架橋澱粉、変性澱粉等を挙げることができる。
さらに、上記の修飾されていない澱粉と上記の澱粉の誘導体とを混合した混合物が用いられてもよい。
Here, starch means starch or a derivative thereof, and is not particularly limited. For example, potato, corn, tapioca, rice, wheat, sweet potato, and other agricultural products that are produced worldwide as main grains. The starch obtained from can be mentioned, The thing manufactured from the specific agricultural product may be used, and the thing manufactured from the several agricultural products may be mixed.
Further, the starch derivatives mentioned above refer to those obtained by modifying starch within a range that does not inhibit biodegradability, and examples thereof include pregelatinized starch, crosslinked starch, and modified starch.
Furthermore, a mixture obtained by mixing the unmodified starch and the starch derivative may be used.

また、パルプとは、植物由来の繊維の集合体を意味し、特に限定されるものではないが、例えば、木材パルプや非木材パルプを挙げることができる。   The pulp means an aggregate of plant-derived fibers and is not particularly limited, and examples thereof include wood pulp and non-wood pulp.

この発明は別の観点からみると、この発明による上述の製造方法によって製造された生分解性容器を提供するものでもある。   From another viewpoint, the present invention also provides a biodegradable container manufactured by the above-described manufacturing method according to the present invention.

また、この発明は更に別の観点からみると、この発明による上述の製造方法によって製造された生分解性容器を用い、前記容器を真空引きが可能な成形型に配置すると共に前記容器の上方に耐水性フィルムを載置し、前記容器の発泡基材層を介して真空引きすることにより発泡基材層の内面と開口縁部を前記耐水性フィルムで被覆する工程を備える生分解性容器の製造方法を提供するものでもある。   From another viewpoint, the present invention uses a biodegradable container manufactured by the above-described manufacturing method according to the present invention, and arranges the container in a mold that can be evacuated and above the container. Production of a biodegradable container comprising a step of covering the inner surface and the opening edge of the foamed base material layer with the water resistant film by placing a water resistant film and evacuating the foamed base material layer of the container It also provides a method.

本発明では、上述のとおり、蒸気抜き孔から溢れ出した余剰分を発生させることなく生分解性容器を製造できるので、製造された生分解性容器を成形型に配置するにあたって余剰分を切り落とす必要がなく、被覆工程を効率よく進めることができる。   In the present invention, as described above, since the biodegradable container can be produced without generating the surplus overflowed from the steam vent, it is necessary to cut off the surplus when the produced biodegradable container is placed in the mold. Therefore, the coating process can be performed efficiently.

なお、発泡基材層の内面を耐水性フィルムで被覆する上述の本発明において、耐水性フィルムとは発泡基材層の表面に耐水性を付与できるものであればよく、生分解性の有無は問わない。よって、本発明において耐水性フィルムとしては生分解性プラスチックからなる生分解性フィルムや、通常のプラスチックからなる非生分解性フィルムを用いることができる。   In addition, in the above-mentioned present invention in which the inner surface of the foam base material layer is coated with a water resistant film, the water resistant film may be any material that can impart water resistance to the surface of the foam base material layer. It doesn't matter. Therefore, in the present invention, as the water resistant film, a biodegradable film made of biodegradable plastic or a non-biodegradable film made of ordinary plastic can be used.

また、この発明は更に別の観点からみると、この発明による上述の製造方法によって製造された生分解性容器であって、内面と開口縁部が耐水性フィルムで被覆されてなる生分解性容器を提供するものでもある。   From another viewpoint, the present invention is a biodegradable container manufactured by the above-described manufacturing method according to the present invention, wherein the inner surface and the opening edge are covered with a water-resistant film. It is also what provides.

以下、図面に基づいてこの発明の実施形態に係る生分解性容器の製造方法について説明する。なお、以下に説明する複数の実施形態において同じ部材には同じ符号を付して説明する。   Hereinafter, the manufacturing method of the biodegradable container which concerns on embodiment of this invention based on drawing is demonstrated. In addition, in the several embodiment demonstrated below, the same code | symbol is attached | subjected and demonstrated to the same member.

本発明の実施形態に係る生分解性容器の製造方法について図1〜12に基づいて説明する。図1は本発明の実施形態に係る製造方法により製造された生分解性容器の斜視図、図2は図1のA−A断面図、図3は図2のB部拡大図、図4は図2のC部拡大図である。   The manufacturing method of the biodegradable container which concerns on embodiment of this invention is demonstrated based on FIGS. 1 is a perspective view of a biodegradable container manufactured by a manufacturing method according to an embodiment of the present invention, FIG. 2 is a cross-sectional view taken along the line AA in FIG. 1, FIG. 3 is an enlarged view of a portion B in FIG. It is the C section enlarged view of FIG.

図1〜4に示されるように、本発明の実施形態に係る製造方法によって製造された生分解性容器1は、底部2a、胴部2bおよび開口縁部2cを有し生分解性容器1の骨格をなす容器状の発泡基材層2と、発泡基材層2の内面2dと開口縁部2cを被覆する耐水性フィルム3とから構成されている。
発泡基材層2は内面2dと開口縁部2cが耐水性フィルム3で被覆されることにより耐水性が付与され、また発泡基材層2の優れた断熱性により熱湯などを入れて使用することも可能な構成となっている。
1-4, the biodegradable container 1 manufactured by the manufacturing method which concerns on embodiment of this invention has the bottom part 2a, the trunk | drum 2b, and the opening edge part 2c, and the biodegradable container 1 of FIG. It is comprised from the container-like foaming base material layer 2 which makes | forms frame | skeleton, and the water resistant film 3 which coat | covers the inner surface 2d of the foaming base material layer 2, and the opening edge part 2c.
The foamed base material layer 2 is provided with water resistance by covering the inner surface 2d and the opening edge 2c with a water resistant film 3, and is used with hot water or the like due to the excellent heat insulating property of the foamed base material layer 2. Is also possible.

図2に示されるように、本実施形態において、発泡基材層2の開口縁部2cは、直径R1が約151mm、厚さT1が約2mmである。また、発泡基材層2の底部2aから開口縁部2cまでの高さH1は74.8mmである。
図1に示されるように発泡基材層2の胴部2bの外面には底部2aから開口縁部2cへ向かって延びるひだ状の凹凸2fが形成される。これにより胴部2bには厚みの厚い部分と薄い部分が交互に形成され、図2に示される厚い部分の厚みT2は約2mm、薄い部分の厚みT3は約1.5mmである。また、底部2aの厚みT4は約2mmである。
As shown in FIG. 2, in this embodiment, the opening edge 2c of the foam base material layer 2 has a diameter R1 of about 151 mm and a thickness T1 of about 2 mm. Moreover, height H1 from the bottom part 2a of the foaming base material layer 2 to the opening edge part 2c is 74.8 mm.
As shown in FIG. 1, pleated irregularities 2f extending from the bottom 2a toward the opening edge 2c are formed on the outer surface of the body 2b of the foam base material layer 2. As a result, thick portions and thin portions are alternately formed on the body portion 2b. The thick portion T2 shown in FIG. 2 has a thickness T2 of about 2 mm, and the thin portion has a thickness T3 of about 1.5 mm. Further, the thickness T4 of the bottom 2a is about 2 mm.

図1に示される生分解性容器1の製造方法に用いられる発泡成形用の金型について図5〜7に基づいて説明する。図5は本発明の実施形態に係る生分解性容器の製造方法で用いられる金型の斜視図、図6は図5に示される金型のD−D矢視断面図、図7は図5に示される金型が嵌合した状態を示す断面図である。
図5〜7に示されるように、本実施形態では成形すべき容器の形状に対応したキャビティ10(図7参照)を形成するための一対の雄型4と雌型5とからなる発泡成形用の金型6が用いられる。雄型4と雌型5は図示しない電熱ヒータを内蔵しており、後述する発泡基材層2の成形工程ではいずれも約200℃に維持される。
A foam molding die used in the method for producing the biodegradable container 1 shown in FIG. 1 will be described with reference to FIGS. 5 is a perspective view of a mold used in the method for manufacturing a biodegradable container according to the embodiment of the present invention, FIG. 6 is a cross-sectional view of the mold shown in FIG. It is sectional drawing which shows the state which the metal mold | die shown by FIG. Fits.
As shown in FIGS. 5 to 7, in this embodiment, for foam molding comprising a pair of male mold 4 and female mold 5 for forming a cavity 10 (see FIG. 7) corresponding to the shape of the container to be molded. The mold 6 is used. The male mold 4 and the female mold 5 incorporate an electric heater (not shown), and both are maintained at about 200 ° C. in the molding process of the foam base material layer 2 described later.

図5および図6に示されるように、雄型4と雌型5は完全に嵌合した際に互いに当接する当接部4a,5aを有し、雌型5の当接部5aには10本の溝状の凹部5bが形成される。
当接部4a,5aが互いに当接すると凹部5bに対応してキャビティ10へ通ずる10本のスリット状の第1蒸気抜き孔11(図7参照)が発泡基材層2の開口縁部2cの端面2e(図1および図2参照)に面するように形成される。
図5に示されるように、各凹部5bは幅W1が16mm、高さH2が0.2mmであるため、各第1蒸気抜き孔11は3.2mm2の断面積を有することとなる。
As shown in FIGS. 5 and 6, the male mold 4 and the female mold 5 have contact portions 4 a and 5 a that contact each other when completely fitted. A groove-shaped recess 5b is formed.
When the contact portions 4a and 5a contact each other, ten slit-shaped first steam vent holes 11 (see FIG. 7) that lead to the cavity 10 corresponding to the concave portions 5b are formed on the opening edge portion 2c of the foam base material layer 2. It is formed so as to face the end face 2e (see FIGS. 1 and 2).
As shown in FIG. 5, each recess 5b has a width W1 of 16 mm and a height H2 of 0.2 mm. Therefore, each first steam vent 11 has a cross-sectional area of 3.2 mm 2 .

上述のとおり、開口縁部2cは直径R1が151mm、厚さT1が2mmであるので、開口縁部2cの端面2eの表面積は948.28mm2となる。
一方、上述のとおり各第1蒸気抜き孔11の断面積は3.2mm2であるため、10本の第1蒸気抜き孔11の総断面積は32mm2となる。
したがって、開口縁部2cの端面2eの表面積に対する第1蒸気抜き孔11の総断面積の比率は約3.4%であり、これは従来よりも低い値である。つまり、本実施形態では生分解性材料7の余剰分が第1蒸気抜き孔11を通じて吹き出すことを防止するため、従来よりも断面積が小さく設定され蒸気が抜け難い。
As described above, since the opening edge 2c has a diameter R1 of 151 mm and a thickness T1 of 2 mm, the surface area of the end surface 2e of the opening edge 2c is 948.28 mm 2 .
On the other hand, since the cross-sectional area of each first vapor vent hole 11 is 3.2 mm 2 as described above, the total cross-sectional area of the ten first vapor vent holes 11 is 32 mm 2 .
Therefore, the ratio of the total cross-sectional area of the first vapor vent hole 11 to the surface area of the end face 2e of the opening edge 2c is about 3.4%, which is a lower value than before. That is, in this embodiment, in order to prevent the surplus portion of the biodegradable material 7 from being blown out through the first steam vent hole 11, the cross-sectional area is set smaller than the conventional one, and the steam is difficult to escape.

そこで、断面積の小さい第1蒸気抜き孔11を補助するため、図6および図7に示されるように本実施形態では雌型5の底部5cにもその周縁に沿って第2蒸気抜き孔12が環状に形成される。
第2蒸気抜き孔12は雌型5を構成するモールド片8,9の隙間により形成され、外径R2が75.6mm、内径R3が75.4mmである。このような第2蒸気抜き孔12の断面積は23.7mm2であり、これは第1蒸気抜き孔11の総断面積よりもさらに小さく、やはり蒸気の抜けはよくない。
Therefore, in order to assist the first steam vent hole 11 having a small cross-sectional area, the second steam vent hole 12 is also provided along the periphery of the bottom 5c of the female die 5 in this embodiment as shown in FIGS. Is formed in a ring shape.
The second steam release hole 12 is formed by a gap between the mold pieces 8 and 9 constituting the female mold 5, and has an outer diameter R2 of 75.6 mm and an inner diameter R3 of 75.4 mm. The cross-sectional area of the second steam vent hole 12 is 23.7 mm 2 , which is smaller than the total cross-sectional area of the first steam vent hole 11, and the steam does not escape well.

このように、本実施形態では、第1蒸気抜き孔11に加え、第2蒸気抜き孔12が形成されるが、いずれも断面積は非常に小さく、決して蒸気の抜けがよいものではない。
そこで、本実施形態では、図5に示されるように雄型4の側面4bに底部4cの周縁から当接部4aへ向かって延びる16本の縦溝4dが側面4bの周囲に等間隔に形成され、キャビティ10の表面と焼成中の発泡基材層2との間に残留する水蒸気を第1蒸気抜き孔11の近傍に導くように構成されている。
As described above, in this embodiment, the second steam vent hole 12 is formed in addition to the first steam vent hole 11, but all of them have a very small cross-sectional area, and the escape of steam is never good.
Therefore, in the present embodiment, as shown in FIG. 5, 16 vertical grooves 4d extending from the periphery of the bottom 4c toward the contact portion 4a are formed at equal intervals around the side 4b on the side 4b of the male mold 4. The water vapor remaining between the surface of the cavity 10 and the foamed base material layer 2 being fired is guided to the vicinity of the first vapor vent hole 11.

また、図5および図6に示されるように、雌型5は発泡基材層2の胴部2bと対応する側面5dに底部5cから当接部5aへ向かって縦に延びるひだ状の凹凸5eが形成される。つまり、ひだ状の凹凸5eによりキャビティ10内では間隙が大きい部分と小さい部分が交互に形成される。
これにより、雄型4と雌型5が嵌合した際にキャビティ10内で生分解性材料7が急激に流動することが抑えられ、生分解性材料7がキャビティ10内で伸びていく際にちぎれることが防止される。
As shown in FIGS. 5 and 6, the female mold 5 has a pleat-shaped unevenness 5e extending vertically from the bottom 5c toward the contact portion 5a on the side surface 5d corresponding to the body portion 2b of the foam base material layer 2. Is formed. That is, the pleated unevenness 5e alternately forms a portion having a large gap and a portion having a small gap in the cavity 10.
Thereby, when the male mold 4 and the female mold 5 are fitted, the biodegradable material 7 is prevented from flowing rapidly in the cavity 10, and when the biodegradable material 7 extends in the cavity 10. It is prevented from tearing.

以下、本実施形態に係る生分解性容器1を上述の金型6を用いて製造する方法について、図8〜12に基づいて説明する。図8〜11は本発明の実施形態に係る生分解性容器の製造方法を説明する工程図、図12は図10(f)のE部の拡大図である。   Hereinafter, a method for manufacturing the biodegradable container 1 according to the present embodiment using the above-described mold 6 will be described with reference to FIGS. FIGS. 8-11 is process drawing explaining the manufacturing method of the biodegradable container which concerns on embodiment of this invention, FIG. 12 is an enlarged view of the E section of FIG.10 (f).

まず、図8(a)に示されるように、雌型5の底に生分解性材料7を投入する。生分解性材料7はパルプおよび水の溶解物に澱粉を混合した後、加熱してα化したものである。本実施形態において、生分解性材料7に占める水の比率(水分値)は50〜65重量%であり、生分解性材料7の性状は非加圧状態で流動性のないドウ状である。
なお、生分解性材料7には、焼成後の金型6との離型性を高めるために若干量の離型剤が混合されてもよい。離型剤としては、グリセリン脂肪酸エステル、植物性油脂、ステアリン酸マグネシウム、ステアリン酸カルシウム等を用いることができる。
First, as shown in FIG. 8A, the biodegradable material 7 is put into the bottom of the female mold 5. The biodegradable material 7 is obtained by mixing starch with a melt of pulp and water, and then heat-treating it. In this embodiment, the ratio (moisture value) of water to the biodegradable material 7 is 50 to 65% by weight, and the property of the biodegradable material 7 is a dough shape having no fluidity in a non-pressurized state.
The biodegradable material 7 may be mixed with a slight amount of a release agent in order to enhance the releasability from the fired mold 6. As the mold release agent, glycerin fatty acid ester, vegetable oil, magnesium stearate, calcium stearate and the like can be used.

次いで、図8(b)に示されるように、雄型4と雌型5の当接部4a,5aが5mm程度の間隔D1を空けて対向するように雄型4と雌型5を6秒程度にわたって予備的に嵌合させる。
この際、生分解性材料7は予備的に嵌合した雄型4と雌型5の間隙に流動しながら加熱され、生分解性材料7に含まれる水分の一部が水蒸気となって雄型4と雌型5との隙間から外部へ放散される。
Then, as shown in FIG. 8 (b), the male mold 4 and the female mold 5 are placed in a 6 second period so that the contact portions 4a, 5a of the male mold 4 and the female mold 5 face each other with a gap D1 of about 5 mm. Preliminarily fit to the extent.
At this time, the biodegradable material 7 is heated while flowing in the gap between the male mold 4 and the female mold 5 that are preliminarily fitted, and a part of the water contained in the biodegradable material 7 is converted into water vapor to form the male mold. It is dissipated outside through the gap between 4 and the female mold 5.

次いで、図9(c)に示されるように、雄型4と雌型5を完全に嵌合させ、ヒータで約200℃に保たれた金型6内で生分解性材料を加熱して水蒸気発泡させ約80秒にわたって焼成する。
この焼成の際、生分解性材料7から発生する水蒸気は第1および第2蒸気抜き孔11,12の双方から外部へ放散されるが、上述の通り、第1および第2蒸気抜き孔11,12はその断面積が非常に小さく蒸気の抜けはよくない。
しかし、雄型4と雌型5を予備的に嵌合させる先の工程によって生分解性材料7に含まれる水分の量そのものが減少していることと、予備的に嵌合させた際の加熱により生分解性材料7の温度が高まっており、嵌合すると直ちに水蒸気発泡が始まってキャビティ10(図7参照)内の内圧が速やかに高まることにより、水分を抜くのに効果的な焼成の初期段階で生分解性材料7に含まれる水分の大半を放散させることができる。
Next, as shown in FIG. 9 (c), the male mold 4 and the female mold 5 are completely fitted, and the biodegradable material is heated in the mold 6 maintained at about 200 ° C. by the heater, thereby Foam and fire for about 80 seconds.
During the firing, water vapor generated from the biodegradable material 7 is diffused to the outside from both the first and second steam vent holes 11 and 12, but as described above, the first and second steam vent holes 11, No. 12 has a very small cross-sectional area, and the escape of steam is not good.
However, the amount of moisture contained in the biodegradable material 7 itself is reduced by the previous process of preliminarily fitting the male mold 4 and the female mold 5, and the heating when preliminarily fitted. As a result, the temperature of the biodegradable material 7 is increased. As soon as the biodegradable material 7 is fitted, the foaming of water vapor starts and the internal pressure in the cavity 10 (see FIG. 7) increases rapidly. Most of the water contained in the biodegradable material 7 can be dissipated at the stage.

また、上記焼成中に水蒸気発泡した生分解性材料7が第1および第2蒸気抜き孔11,12から外部へ吹き出すこともない。
というのは、上述の通り、第1および第2蒸気抜き孔11,12はその断面積が非常に小さいため、水蒸気発泡した生分解性材料7は物理的に第1および第2蒸気抜き孔11,12を通り抜け難く、また、雄型4と雌型5を予備的に嵌合させる先の工程で生分解性材料7に含まれる水分の量が減少しているため、水蒸気発泡によるキャビティ10内の内圧上昇は適度に抑えられ、第1および第2蒸気抜き孔11,12から生分解性材料7を外部へ押し出す程まで、キャビティ10内の内圧が高くならないからである。
In addition, the biodegradable material 7 that is steam-foamed during the firing does not blow out from the first and second steam vent holes 11 and 12.
This is because, as described above, since the first and second vapor vent holes 11 and 12 have a very small cross-sectional area, the water-foamed biodegradable material 7 is physically formed by the first and second vapor vent holes 11. 12, and the amount of moisture contained in the biodegradable material 7 is reduced in the previous step of preliminarily fitting the male mold 4 and the female mold 5. This is because the internal pressure in the cavity 10 is not increased to the extent that the biodegradable material 7 is pushed out from the first and second vapor vent holes 11 and 12 to an appropriate extent.

また、上述のとおり雌型5の側面5dにひだ状の凹凸5e(図5参照)が形成されているので、水蒸気発泡時に生分解性材料7が急激に流動してちぎれることが防止され、生分解性材料7はキャビティ10内に適切に満注する。   Further, as described above, the pleated irregularities 5e (see FIG. 5) are formed on the side surface 5d of the female die 5, so that the biodegradable material 7 is prevented from flowing and tearing at the time of steam foaming. The degradable material 7 is properly filled in the cavity 10.

次いで、図9(d)に示されるように、金型6を開放し焼成された発泡基材層2を取り出す。取り出された発泡基材層2は、その開口縁部2cに生分解性材料7の余剰分が発生していないため、耐水性が要求されない用途であれば、このまま生分解性容器として出荷することも可能である。しかし、本実施形態では、発泡基材層2に耐水性を付与するため、発泡基材層2の内面2dと開口縁部2cを耐水性フィルム3で被覆する。   Next, as shown in FIG. 9D, the mold 6 is opened and the fired foamed base material layer 2 is taken out. The taken-out foam base material layer 2 is shipped as a biodegradable container as long as the water resistance is not required because the surplus of the biodegradable material 7 is not generated at the opening edge 2c. Is also possible. However, in this embodiment, in order to impart water resistance to the foam base material layer 2, the inner surface 2 d and the opening edge 2 c of the foam base material layer 2 are covered with the water resistance film 3.

まず、図10(e)に示されるように、上述の工程を経て得られた発泡基材層2を内面2dと開口縁部2cに接着剤を塗布したうえで真空引きが可能な成形型15に配置する。成形型15は上型13と下型14とから構成され、接着剤が塗布された発泡基材層2は下型14に配置される。この際、上述の通り、発泡基材層2の開口縁部2cには生分解性材料7の余剰分が発生していないため、余剰分を切り落とすなどの後処理を施すことなく成形型15に配置できる。
発泡基材層2を下型14に配置した後、上型13と下型14の間に耐水性フィルム3が配置され、熱風またはヒータ(図示せず)からの輻射熱により155〜180℃程度まで予熱される。
耐水性フィルム3は、生分解性芳香族ポリエステル樹脂(アペクサ(登録商標))を2軸延伸して厚さ約50μmのフィルム状に成形したものであり、生分解性を有する。
First, as shown in FIG. 10 (e), a mold 15 that can be evacuated after an adhesive is applied to the inner surface 2d and the opening edge 2c of the foamed base material layer 2 obtained through the above-described steps. To place. The mold 15 is composed of an upper mold 13 and a lower mold 14, and the foamed base material layer 2 coated with an adhesive is disposed on the lower mold 14. At this time, as described above, since the surplus portion of the biodegradable material 7 is not generated in the opening edge portion 2c of the foam base material layer 2, the mold 15 is not subjected to post-treatment such as cutting off the surplus portion. Can be placed.
After disposing the foam base material layer 2 on the lower mold 14, the water resistant film 3 is disposed between the upper mold 13 and the lower mold 14, and is heated to about 155 to 180 ° C. by radiant heat from hot air or a heater (not shown). Preheated.
The water-resistant film 3 is a biodegradable aromatic polyester resin (Apexa (registered trademark)) biaxially stretched and formed into a film having a thickness of about 50 μm and has biodegradability.

次いで、図10(f)および図11(g)に示されるように上型13と下型14を嵌合させ、発泡基材層2を介して真空引きする。発泡基材層2は生分解性材料7を水蒸気発泡させて焼成した焼成物であり通気性を有するため、真空引きにより発泡基材層2と耐水性フィルム3との間は瞬時に負圧となり、予熱により軟化した耐水性フィルム3は発泡基材層2の内面2dと開口縁部2cに速やかに密着する。
また、この際、図12に示されるように、開口縁部2cの裏側と下型14との間に形成される空間も真空引きにより負圧となり、予熱により軟化した耐水性フィルム3は負圧力により延伸させられ開口縁部2cの裏側にも密着する。
Next, as shown in FIG. 10 (f) and FIG. 11 (g), the upper mold 13 and the lower mold 14 are fitted and evacuated through the foam base material layer 2. The foam base material layer 2 is a fired product obtained by firing the biodegradable material 7 by steam foaming and has air permeability, so that a negative pressure is instantaneously generated between the foam base material layer 2 and the water-resistant film 3 by evacuation. The water-resistant film 3 softened by preheating quickly adheres to the inner surface 2d of the foam base material layer 2 and the opening edge 2c.
At this time, as shown in FIG. 12, the space formed between the back side of the opening edge 2c and the lower mold 14 also becomes negative pressure by evacuation, and the water-resistant film 3 softened by preheating has a negative pressure. It is made to extend | stretch by this and it adheres also to the back side of the opening edge part 2c.

その後、図11(h)に示されるように成形型15を開放して内面2dと開口縁部2cが耐水性フィルム3で被覆された発泡基材層2を取り出し、開口縁部2cの裏側にて耐水性フィルム3を切断することにより、図1〜4に示される生分解性容器1が完成する。   Thereafter, as shown in FIG. 11 (h), the mold 15 is opened, and the foamed base material layer 2 in which the inner surface 2d and the opening edge 2c are covered with the water-resistant film 3 is taken out, and on the back side of the opening edge 2c. Then, the water-resistant film 3 is cut to complete the biodegradable container 1 shown in FIGS.

このように、本実施形態では、発泡基材層2の開口縁部2cに生分解性材料7の余剰分を発生させることなく発泡基材層2を成形できるので、余剰分を切り落とすなどの後処理を施すことなく発泡基材層2の成形工程から耐水性フィルム3の被覆工程にスムーズに移行でき、生分解性容器1を生産性よく製造することができる。   Thus, in this embodiment, since the foaming base material layer 2 can be shape | molded without generating the surplus part of the biodegradable material 7 in the opening edge part 2c of the foaming base material layer 2, after cutting off the surplus part, etc. It is possible to smoothly shift from the molding process of the foam base material layer 2 to the coating process of the water-resistant film 3 without performing the treatment, and the biodegradable container 1 can be manufactured with high productivity.

なお、本実施形態では、耐水性フィルム3として生分解性を有するものを用いたが、生分解性を備えないものを耐水性フィルム3として用いても構わない。   In the present embodiment, the water-resistant film 3 having biodegradability is used, but a film having no biodegradability may be used as the water-resistant film 3.

比較例1
この発明の実施形態に対する比較例1として、雄型4と雌型5を予備的に嵌合させる工程を省いた事例について説明する。
雄型4と雌型5を予備的に嵌合させる工程を省いた場合、生分解性材料7に多くの水分が含まれたまま雄型4と雌型5が完全に嵌合するので、生分解性材料7が吹き出さないように断面積が小さく設定された第1および第2蒸気抜き孔11,12から水蒸気を十分に放散させることができず、第1および第2蒸気抜き孔11,12の近傍のみが焼成され他の部分は生焼けとなる。
Comparative Example 1
As Comparative Example 1 for the embodiment of the present invention, an example in which the step of preliminarily fitting the male mold 4 and the female mold 5 is omitted will be described.
When the step of preliminarily fitting the male mold 4 and the female mold 5 is omitted, the male mold 4 and the female mold 5 are completely fitted while the biodegradable material 7 contains a large amount of moisture. Water vapor cannot be sufficiently dissipated from the first and second steam vent holes 11 and 12 having a small cross-sectional area so that the decomposable material 7 does not blow out, and the first and second steam vent holes 11 and 12 Only the vicinity of 12 is fired, and the other parts are burnt.

この現象について詳しく述べると、雄型4と雌型5を予備的に嵌合させる工程を省いているため、雄型4と雌型5が完全に嵌合した際の生分解性材料7の温度は上述の実施形態よりも低くなる。
このため、雄型4と雌型5が嵌合してから水蒸気発泡が始まるまでの時間が上述の実施形態よりも長くなり、生分解性材料7に含まれる水分を抜くのに効果的な焼成の初期段階で多くの水分を抜くことができない。
When this phenomenon is described in detail, since the step of preliminarily fitting the male mold 4 and the female mold 5 is omitted, the temperature of the biodegradable material 7 when the male mold 4 and the female mold 5 are completely fitted is determined. Is lower than in the above embodiment.
For this reason, the time from when the male mold 4 and the female mold 5 are fitted to when the steam foaming starts is longer than that in the above-described embodiment, and the firing is effective for removing moisture contained in the biodegradable material 7. A lot of moisture cannot be removed in the initial stage.

また、生分解性材料7に含まれる水分が抜けていくに従い、キャビティ10内の内圧が下がり始め、水分を外部へ押し出そうとする力が弱まるため第1蒸気抜き孔および第2蒸気抜き孔11,12の近傍のみ焼成が進む。
第1および第2蒸気抜き孔11,12の近傍のみ焼成が進むと、それ以外の部分に含まれる水分の放散経路が焼成の済んだ部分に塞がれた形となり、さらに水分が抜け難くなるという悪循環に陥る。
Further, as the moisture contained in the biodegradable material 7 is released, the internal pressure in the cavity 10 starts to decrease, and the force for pushing the moisture to the outside weakens, so the first steam vent hole and the second steam vent hole Baking proceeds only in the vicinity of 11 and 12.
When the firing proceeds only in the vicinity of the first and second vapor vent holes 11 and 12, the moisture diffusion path contained in the other portions becomes blocked by the fired portion, and the moisture becomes difficult to escape. Falls into a vicious circle.

そして、焼成が不安定に進行するため、焼成が進んだ部分であっても局部的に水分が残り、クレータ状の凹凸が発生する。
以上のことから、雄型4と雌型5を予備的に嵌合させる工程を設けることが、生分解性材料の余剰分を発生させずに焼成するうえで効果的であることが分かる。
And since baking advances unstablely, a water | moisture content remains locally even in the part which baking advanced, and a crater-like unevenness | corrugation generate | occur | produces.
From the above, it can be seen that provision of a step of preliminarily fitting the male mold 4 and the female mold 5 is effective in firing without generating surplus of the biodegradable material.

比較例2
この発明の実施形態に対する比較例2として、雄型4と雌型5を予備的に嵌合させる時間を20秒に延長した事例について説明する。
雄型4と雌型5を予備的に嵌合させる時間を20秒まで延長すると、雄型4と雌型5を完全に嵌合させた時点で生分解性材料7に含まれる水分の量が少なくなり過ぎ、キャビティ10内で内圧が十分に上がらない。
このため、生分解性材料7をキャビティ10内に満注させる力が弱くなり、生分解性材料7がキャビティ10内に満注せず、発泡基材層2に欠けが発生する。
Comparative Example 2
As Comparative Example 2 for the embodiment of the present invention, an example in which the time for preliminarily fitting the male mold 4 and the female mold 5 is extended to 20 seconds will be described.
If the time for pre-mating the male mold 4 and the female mold 5 is extended to 20 seconds, the amount of moisture contained in the biodegradable material 7 at the time when the male mold 4 and the female mold 5 are completely fitted is increased. The internal pressure does not increase sufficiently in the cavity 10 because the pressure is too small.
For this reason, the force for filling the biodegradable material 7 into the cavity 10 is weakened, the biodegradable material 7 is not filled into the cavity 10, and the foam base material layer 2 is chipped.

また、キャビティ10内の内圧が十分に高まらないため、キャビティ10の形状が発泡基材層2にきれいに再現されず、軽度の焼成ムラが表面全体に発生する。
さらには、雄型4と雌型5を予備的に嵌合させているうちに、生分解性材料7のうち雌型5の底部5dと接触している部分が部分的に先行して焼成され、この部分に重度の焼成ムラが発生する。
以上のことから、雄型4と雌型5を予備的に嵌合させる時間には一定の適切な範囲があることが分かる。
In addition, since the internal pressure in the cavity 10 is not sufficiently increased, the shape of the cavity 10 is not clearly reproduced in the foamed base material layer 2, and a slight firing unevenness occurs on the entire surface.
Furthermore, while the male mold 4 and the female mold 5 are preliminarily fitted, the portion of the biodegradable material 7 that is in contact with the bottom 5d of the female mold 5 is partially fired in advance. Severe baking unevenness occurs in this part.
From the above, it can be seen that there is a certain appropriate range for the time for which the male mold 4 and the female mold 5 are preliminarily fitted.

1 生分解性容器
2 発泡基材層
2a,4c,5c 底部
2b 胴部
2c 開口縁部
2d 内面
2e 端面
2f,5e 凹凸
3 耐水性フィルム
4 雄型
4a,5a 当接部
4b,5d 側面
4d 縦溝
5 雌型
5b 凹部
6 金型
7 生分解性材料
8,9 モールド片
10 キャビティ
11 第1蒸気抜き孔
12 第2蒸気抜き孔
13 上型
14 下型
15 成形型
DESCRIPTION OF SYMBOLS 1 Biodegradable container 2 Foaming base material layer 2a, 4c, 5c Bottom part 2b Trunk part 2c Opening edge part 2d Inner surface 2e End surface 2f, 5e Concavity and convexity 3 Water resistant film 4 Male type | mold 4a, 5a Contact part 4b, 5d Side surface 4d Vertical Groove 5 Female mold 5b Recess 6 Mold 7 Biodegradable material 8, 9 Mold piece 10 Cavity 11 First steam vent 12 Second steam vent 13 Upper mold 14 Lower mold 15 Mold

Claims (10)

ヒータを内蔵した嵌合可能な一対の雄型と雌型からなる発泡成形用の金型を用い、水分を含んだ生分解性材料を介在させて雄型と雌型を嵌合させ、金型内で生分解性材料を加熱し水蒸気発泡させて焼成することにより底部、胴部および開口縁部を有する容器状の発泡基材層を成形する工程を備え、雄型と雌型は完全に嵌合した際に互いに当接して第1蒸気抜き孔を形成する当接部をそれぞれ有すると共に少なくとも一方に第2蒸気抜き孔が形成され、金型内で生分解性材料を加熱する前記工程は、雄型と雌型の当接部が所定の間隔を空けて対向するように雄型と雌型を所定時間だけ予備的に嵌合させた後、前記当接部が互いに当接するように雄型と雌型を完全に嵌合させ第1および第2蒸気抜き孔から水蒸気を放散させながら焼成する工程であることを特徴とする生分解性容器の製造方法。   Using a mold for foam molding consisting of a pair of matable male and female molds with a built-in heater, the male mold and female mold are fitted together with a biodegradable material containing moisture. It has a process of forming a container-like foaming base material layer having a bottom, a body part and an opening edge by heating a biodegradable material, steam-foaming and firing within, and the male and female molds are completely fitted The steps of heating the biodegradable material in the mold, each having a contact portion that forms a first steam vent when they are joined together, and a second steam vent is formed in at least one of the two, The male mold and the female mold are preliminarily fitted with each other for a predetermined time so that the male mold and the female mold are opposed to each other with a predetermined gap, and then the male mold is formed so that the abutting sections are in contact with each other. In the process of firing while completely fitting the female mold and the first and second steam vent holes to dissipate water vapor. Method for producing a biodegradable container characterized by Rukoto. 雄型は、発泡基材層の胴部と対応する部分の表面に当接部へ向かって延びる複数の縦溝が形成されてなる請求項1に記載の生分解性容器の製造方法。   The method for producing a biodegradable container according to claim 1, wherein the male mold is formed with a plurality of vertical grooves extending toward the contact portion on the surface of the portion corresponding to the body portion of the foam base material layer. 雌型は、発泡基材層の胴部と対応する部分の表面に当接部へ向かって延びるひだ状の凹凸が形成されてなる請求項1又は2に記載の生分解性容器の製造方法。   The method for producing a biodegradable container according to claim 1 or 2, wherein the female mold is formed with pleated irregularities extending toward the contact portion on the surface of the portion corresponding to the body portion of the foamed base material layer. 第1蒸気抜き孔は雄型と雌型の当接部に部分的に形成される隙間により複数の第1蒸気抜き孔に分割して形成される請求項1〜3のいずれか1つに記載の生分解性容器の製造方法。   The first steam vent hole is formed by dividing the first steam vent hole into a plurality of first steam vent holes by a gap partially formed at the contact portion between the male mold and the female mold. Of manufacturing biodegradable container. 雌型は複数のモールド片からなり、第2蒸気抜き孔は隣接するモールド片の隙間により発泡基材層の底部と対応する部分の縁に沿って環状に形成される請求項1〜4のいずれか1つに記載の生分解性容器の製造方法。   The female mold is composed of a plurality of mold pieces, and the second steam vent is formed in an annular shape along the edge of the portion corresponding to the bottom of the foam base material layer by the gap between the adjacent mold pieces. The manufacturing method of the biodegradable container as described in any one. 雄型と雌型を予備的に嵌合させる所定時間が3〜15秒の範囲内である請求項1〜5のいずれか1つに記載の生分解性容器の製造方法。   The method for producing a biodegradable container according to any one of claims 1 to 5, wherein a predetermined time for preliminarily fitting the male mold and the female mold is within a range of 3 to 15 seconds. 生分解性材料は少なくとも澱粉、パルプおよび水を混練してなる混練物である請求項1〜6のいずれか1つに記載の生分解性容器の製造方法。   The method for producing a biodegradable container according to any one of claims 1 to 6, wherein the biodegradable material is a kneaded product obtained by kneading at least starch, pulp and water. 請求項1〜7のいずれか1つに記載の方法で製造された生分解性容器。   A biodegradable container manufactured by the method according to claim 1. 請求項1〜7のいずれか1つに記載の方法で製造された生分解性容器を用い、前記容器を真空引きが可能な成形型に配置すると共に前記容器の上方に耐水性フィルムを載置し、前記容器の発泡基材層を介して真空引きすることにより発泡基材層の内面と開口縁部を前記耐水性フィルムで被覆する工程を備える生分解性容器の製造方法。   Using the biodegradable container manufactured by the method according to any one of claims 1 to 7, the container is placed in a mold that can be evacuated and a water-resistant film is placed above the container. And the manufacturing method of a biodegradable container provided with the process of coat | covering the inner surface and opening edge part of a foaming base material layer with the said water-resistant film by evacuating through the foaming base material layer of the said container. 請求項9に記載の方法で製造された生分解性容器であって、内面と開口縁部が耐水性フィルムで被覆されてなる生分解性容器。   A biodegradable container manufactured by the method according to claim 9, wherein the inner surface and the opening edge are covered with a water-resistant film.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10249948A (en) * 1997-03-14 1998-09-22 Mitsubishi Chem Basf Co Ltd Foam molding and its molding method
JP2003334825A (en) * 2002-03-13 2003-11-25 Nissei Co Ltd Method for manufacturing biodegradable molding and molding mold used in method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10249948A (en) * 1997-03-14 1998-09-22 Mitsubishi Chem Basf Co Ltd Foam molding and its molding method
JP2003334825A (en) * 2002-03-13 2003-11-25 Nissei Co Ltd Method for manufacturing biodegradable molding and molding mold used in method

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