JP4724920B2 - Compression molding device for preformed body for blow molding container - Google Patents

Compression molding device for preformed body for blow molding container Download PDF

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Publication number
JP4724920B2
JP4724920B2 JP2001004489A JP2001004489A JP4724920B2 JP 4724920 B2 JP4724920 B2 JP 4724920B2 JP 2001004489 A JP2001004489 A JP 2001004489A JP 2001004489 A JP2001004489 A JP 2001004489A JP 4724920 B2 JP4724920 B2 JP 4724920B2
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Japan
Prior art keywords
mold
mold means
mouth
neck
blow
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JP2001004489A
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JP2002210808A (en
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誠 江藤
和伸 渡辺
恒夫 今谷
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Toyo Seikan Kaisha Ltd
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Toyo Seikan Kaisha Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • B29C43/42Moulds for making articles of definite length, i.e. discrete articles for undercut articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B11/00Making preforms
    • B29B11/06Making preforms by moulding the material
    • B29B11/12Compression moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/20Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
    • B29C2949/22Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at neck portion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/20Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
    • B29C2949/24Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at flange portion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/20Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
    • B29C2949/26Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at body portion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/20Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
    • B29C2949/28Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at bottom portion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/30Preforms or parisons made of several components
    • B29C2949/3024Preforms or parisons made of several components characterised by the number of components or by the manufacturing technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/30Preforms or parisons made of several components
    • B29C2949/3032Preforms or parisons made of several components having components being injected
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/30Preforms or parisons made of several components
    • B29C2949/3056Preforms or parisons made of several components having components being compression moulded
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2001/00Articles provided with screw threads

Description

【0001】
【発明の属する技術分野】
本発明は、環状口頸部とこの口頸部から垂下する有底筒状ブロー成形部とから構成され、ブロー成形部をブロー成形して容器にせしめられる合成樹脂製前成形体を圧縮成形する装置に関する。
【0002】
【従来の技術】
飲料等のための容器として、ポリエチレンテレフタレートの如き適宜の合成樹脂から形成された合成樹脂製容器が広く実用に供されている。かような合成樹脂製容器は、一般に、環状口頸部とこの口頸部から垂下する有底筒状ブロー成形部とから成る前成形体を射出成形し、次いでかかる前成形体のブロー成形部をブロー成形或いは延伸ブロー成形することによって製造される。前成形体の口頸部は容器の口頸部を規定し、その外周面には通常サポートリングが形成されている。容器内に内容物を充填した後に口頸部に蓋を装着して容器を密封する際には、このサポートリングの下面を支持することによって容器が保持される。
【0003】
而して、合成樹脂製容器の従来の製造様式には、前成形体の射出成形における成形効率に限度があり、高成形効率で前成形体を成形することができない、という問題がある。高成形効率で前成形体を成形するためには、射出成形に代えて圧縮成形を採用することが意図される。しかしながら、前成形体を圧縮成形する場合には、次のとおりの解決すべき問題がある。即ち、圧縮成形の場合には、成形型を閉じて成形型空洞を規定する前に、成形型に合成樹脂素材を充填することが必要である。かかる合成樹脂素材の充填は、例えば押出機から軟化或いは溶融状態の合成樹脂素材を押し出し、かかる合成樹脂素材を押出機の押出口から切り離すことによって遂行されるが、押出機による押出量の変動等に起因して合成樹脂素材の充填量を充分精密に制御することは著しく困難であり、通常の場合、合成樹脂素材の充填量には0.5乃至1.0%程度の誤差が存在する。かかる合成樹脂素材量の誤差は、成形型を構成している第一の成形型手段と第二の成形型手段とを相互に接近する方向に移動せしめて閉状態にせしめ、両者間にて合成樹脂素材を圧縮成形した時の、第一の成形型手段と第二の成形型手段との相互間隔を変動せしめる。それ故に、通常、圧縮成形された前成形体全体の厚さ、外径等の寸法に若干の変動を生成せしめる。前成形体のブロー成形部における寸法の若干の変動は特に問題を生成せしめることはないが、口頸部の高さ、内外径等の主要寸法に若干の変動が生成されると、(イ)口頸部に蓋を装着した時に蓋に配設されているシール手段が密接せしめられる部位の寸法変動に起因して、所要とおりの密封特性が達成されない、(ロ)サポートリングの下面から口頸部の先端までの高さの変動に起因して、口頸部に蓋を装着する蓋自動装着操作に種々の障害が発生する、等の許容し得ない問題が発生する虞が少なくない。
【0004】
特開平10−337769号公報には、前成形体を圧縮成形する際の上述したとおりの問題を解決するために、前成形体の形態をそのサポートリングの下面の内周縁部に環状溝が形成された形態にせしめ、合成樹脂素材の充填量の変動に応じてブロー成形部の肉厚と共に上記環状溝の深さが変化せしめられるようになすことによって、合成樹脂素材の充填量の変動にかかわらず、口頸部の形状及び寸法を一定にせしめる圧縮成形様式が開示されている。
【0005】
【発明が解決しようとする課題】
然るに、特開平10−337769号公報に開示されている上述したとおりの圧縮成形様式も未だ充分に満足し得るものではなく、次のとおりの問題を有する。即ち、サポートリングに環状溝が形成される故に、特に環状溝の深さが比較的深い場合、サポートリング乃至その近傍の強度が過小になり、ブロー成形に先立って前成形体を延伸する際或いは前成形体のブロー成形部をブローする際に前成形体が変形乃至破損されてしまう虞がある。
【0006】
本発明は上記事実に鑑みてなされたものであり、その主たる技術的課題は、局部的に低強度の部分を前成形体に生成せしめることなく、合成樹脂素材の充填量の変動にかかわらず、前成形体の口頸部の形状及び寸法を一定にせしめると共に前成形体の全高を一定にせしめることができる、前成形体を圧縮成形するための新規且つ改良された装置を提供することである。
【0010】
【課題を解決するための手段】
発明によれば、上記主たる技術的課題を達成する圧縮成形装置として、環状口頸部と該口頸部から垂下する有底筒状ブロー成形部とから構成され、該ブロー成形部をブロー成形して容器とするブロー成形容器用前成形体の圧縮成形装置で、
該口頸部の上端面と共に、該口頸部の外周面の、少なくとも下部以外の部分を規定する第一の成形型手段と、該ブロー成形部の外面を規定する第二の成形型手段と、該第一の成形型手段に形成されている中央貫通開口に移動自在に挿通せしめられ、少なくとも該ブロー成形部の内面を規定する第三の成形型手段とを具備し、
該第二の成形型手段内に軟化或いは溶融状態の合成樹脂素材が充填され、次いで該第一の成形型手段、該第二の成形型手段及び第三の成形型手段が相互に協働して仮成形型空洞を規定する状態に閉じられ、しかる後に該第一の成形型手段と該第二の成形型手段との関係は変化せしめられることなく維持されるが、該第三の成形型手段が該第一の成形型手段及び該第二の成形型手段に対して移動せしめられて、該仮成形型空洞における該ブロー成形部を規定している部分の厚さが低減せしめられる、ことを特徴とする装置が提供される。
【0011】
好適実施形態においては、該第三の成形型手段は、該ブロー成形部の内面と共に、該口頸部の内周面の下部を規定し、該第一の成形型手段は、該口頸部の外周面の、少なくとも下部以外の部分を規定する第一の型部材と、該口頸部の該上端面と共に、該口頸部の内周面の、該下部以外の部分を規定する第二の型部材とを有する。他の好適実施形態においては、該第三の成形型手段は、該ブロー成形部の内面と共に、該口頸部の内周面の全体を規定し、該第一の成形型手段は、該口頸部の外周面の、少なくとも下部以外の部分を規定する第一の型部材と、該口頸部の該上端面を規定する第二の型部材とを有する。
【0012】
【発明の実施の形態】
以下、本発明に従って構成された圧縮成形装置の好適実施形態について、添付図面を参照して更に詳細に説明する。
【0013】
図1には、本発明の圧縮成形装置の好適実施形態によって成形される前成形体の典型例が図示されている。ポリエチレンテレフタレートの如き適宜の合成樹脂から圧縮成形されている、全体を番号2で示す前成形体は、環状口頸部4とこの口頸部4から垂下する有底筒状ブロー成形部6とから構成されている。口頸部4は全体として略円筒形状であり、その外周面上部には雄螺条8が形成されている。口頸部4の下部には半径方向外方に突出せしめられた環状サポートリング12が形成されている。口頸部4に続くブロー成形部6は、下方に向かって延びる略円筒形状の胴部14と半球状の底部16とを含んでいる。図示実施形態における前成形体2においては、口頸部4の内周面下端部からブロー成形部6の内周面上端部に渡る領域に、下方に向かって内径が若干減少する円錐台形状部17が存在する。図1に二点鎖線で示す如く、ブロー成形部6にはブロー成形が加えられ或いは延伸成形が加えられた後にブロー成形が加えられ、かくして所要形状の容器が形成される。
【0014】
図2は前成形体2を圧縮成形するための圧縮成形装置を図示している。図示の圧縮成形装置は第一の成形型手段18、第二の成形型手段20及び第三の成形型手段22を含んでいる。第一の成形型手段18及び第三の成形型手段22は、昇降動せしめられる可動基板24に装着されている。一方、第二の成形型手段20は静止基板(図示していない)に装着されている。所望ならば、第一の成形型手段18及び第三の成形型手段22を可動基板24に装着することに代えて或いはこれに加えて、第二の成形型手段20を可動基板に装着し、第一の成形型手段18及び第三の成形型手段22に対して第二の成形型手段20を相対的に昇降動せしめることもできる。
【0015】
図示実施形態における第一の成形型手段18は、第一の型部材26と第二の型部材28とを有する。第二の型部材28は周方向に間隔をおいて配設された複数本の懸架ロッド29を介して可動基板24から懸架せしめられており、可動基板24の昇降動に応じて昇降動せしめられる。第一の型部材26は第二の型部材28の下端部に組み合わされている。第一の型部材26は180度の角度に渡って延在する円弧状の2個の部分26a及び26bから構成されており、周方向に移動せしめるための移動手段(図示していない)が付設されている。従って、第一の型部材26は、可動基板24の昇降動に応じて昇降せしめられると共に、かかる昇降動とは別個に周方向に移動せしめられる。第一の型部材26は、前成形体2における口頸部4の外周面の、下部以外の部分、更に詳しくは口頸部4の外周面におけるサポートリング12の下面外周縁部と共にサポートリング12の下面よりも上方の部分を規定する内周面30を有する。第二の型部材28は下方に突出する薄肉円筒形状の突出部32を有し、かかる突出部32の外周面34は前成形体2における口頸部4の内周面上部を規定する。また、第二の型部材28における突出部32の基端に位置する下方に向いた環状肩面36は前成形体2における口頸部4の上端面を規定する。
【0016】
第二の成形型手段20は全体として円柱形状であり、その上面中央部には上方に突出する薄肉円筒形状の突出部38が形成されている。かかる突出部38の内側には下方に延びる盲穴40が形成されている。突出部38の上面42は、前成形体2における口頸部4の外周面に形成されているサポートリング12の下面内周縁部を規定する。盲穴40の内面44は、前成形体2における口頸部4の内周面下部(更に詳細には外周面に形成されているサポートリング12の下面よりも下方の部分)と共に、ブロー成形部6の外面を規定する。
【0017】
第一の成形型手段18の第二の型部材28には、その中央部を貫通して延びる中央貫通開口46が形成されており、第三の成形型手段22はかかる中央貫通開口46に移動自在に挿通せしめられている細長い円柱形状部材から構成されている。かかる第三の成形型手段22の外周面中間部には上方を向いた肩面48が形成されており、肩面48より上方の部分の外周面50は実質上鉛直に延びる円筒形状である。外周面50の外径は上記中央貫通開口46の内径に対応せしめられている。肩面48よりも下方の部分の外周面52は実質上鉛直に延びる円筒形状部と、これに続いて下方に向かって内径が若干減少する円錐台形状部と、更にこれに続いて実質上鉛直に延びる円筒形状部を有し、下端部は半球面形状である。第三の成形型手段22における肩面48よりも下方の外周面は、前成形体2における口頸部4の内周面下部と共にブロー成形部6の内面を規定する。第三の成形型手段22の上端には、可動基板24に対して第三の成形型手段22を昇降動せしめる昇降動手段54(その一部のみを図示している)が付設されている。昇降動手段54は油圧乃至空気圧シリンダ機構の如き適宜の手段から形成することができる。第三の成形型手段22は、第一の成形型手段18に対して、肩面48が第一の成形型手段18の第二の型部材28に形成されている突出部32の下端面に当接せしめられる上昇位置(図1に図示する位置)から下方に相対的に昇降動せしめられる。
【0018】
上述したとおりの圧縮成形装置による前成形体2の圧縮成形方法について説明すると、次のとおりである。圧縮成形を開始する際には、図2に図示する如く、可動基板24は上昇位置に移動せしめられており、第一の成形型手段18及び第三の成形型手段22は第二の成形型手段20に対して上方に離隔せしめられている。そして、第二の成形型手段20の盲穴40内に軟化或いは溶融状態の合成樹脂素材56が充填される。ポリエチレンテレフタレート等の合成樹脂素材56は、押出機(図示していない)の押出口から押し出し、押出口から切り離すことによって好都合に充填することができる。当業者には周知の如く、合成樹脂素材56の充填量を充分精密に制御することは不可能ではないにしても著しく困難であり、通常、0.5乃至1.0%程度の誤差が生じる。本発明に従う圧縮成形方法の好適実施形態においては、可動基板24を下降せしめて第二の成形型手段20に対して第一の成形型手段18を最下降位置まで下降せしめた時(第三の成形型手段22は第一の成形型手段18に対して最上位置に位置せしめられており第一の成形型手段18と共に下降せしめられる)に規定される仮成形空洞(即ち図3に示す状態で規定される仮成形空洞)の容積V1よりも若干大きい体積V2の合成樹脂素材56を充填する。
【0019】
次いで、可動基板24を下降せしめて、第二の成形型手段20に対して第一の成形型手段18及び第三の成形型手段22を下降せしめ(この際には第三の成形型手段22は第一に成形型手段18に対しては最上位置に位置せしめられている)、合成樹脂素材56を漸次圧縮する。而して、上述したとおり、充填された合成樹脂素材56の体積V2は第二の成形型手段20に対して第一に成形型手段18を最下降位置まで下降せしめた時に規定される仮成形空洞の容積V1よりも大きく、それ故に可動基板24を所要圧力で下降せしめても、圧縮成形の初期段階においては第一の成形型手段18及び第三の成形型手段22を図3に図示する位置まで下降せしめることができず、第一の成形型手段18及び第三の成形型手段22は図3に図示する位置よりも若干だけ上方に位置せしめられる。時間の経過と共に充填された合成樹脂素材56が冷却せしめられ漸次収縮されると、これに応じて第一の成形型手段18及び第三の成形型手段22が漸次下降せしめられる。そして、合成樹脂素材56の体積が仮成形空洞の容積V1まで低減せしめられると、第一の成形型手段18及び第三の成形型手段22は図3に図示する位置まで下降せしめられ、仮成形空洞が規定される。
【0020】
しかる後においても、合成樹脂素材56は冷却され続けその体積は漸次減少せしめられる。本発明に従って構成された圧縮成形方法及び装置においては、上述したとおりにして仮成形空洞が規定された後においては、合成樹脂素材56の収縮に応じて第三の成形型手段22が所定圧力で下降せしめられる。図3と図4を比較参照することによって理解される如く、仮成形空洞が規定されている図3に図示する状態から図4に図示する状態に向けて第三の成形型手段22が漸次下降せしめられると、仮成形空洞内における前成形体2の口頸部4を規定する部分の形状及び寸法は実質上変化せしめられないが、ブロー成形部6を規定する部分の厚さ、特にブロー成形部6の下端部を規定する部分が漸次低減せしめられる。かくして、合成樹脂素材56が充分に冷却されるまで第三の成形型手段22が漸次下降されて図4に図示する状態に至り、前成形体2が成形される。第一の成形型手段18に対して第三の成形型手段22を下降せしめると、図3及び図4を比較参照することによって理解される如く、第一の成形型手段18における第二の型部材28に形成されている突出部32の下端面と第三の成形型手段22の肩48との間が離間せしめられ、両者間に若干の間隙58が生成される。しかしながら、第三の成形型手段22が下降される際には、特に前成形体2の口頸部4を規定する部分においては合成樹脂素材56が相当低い温度まで冷却されており、本発明者等の経験によれば上記間隙58に合成樹脂素材56が流入することはない(仮に、上記間隙58に合成樹脂素材56が若干流入したとしても、上記間隙は前成形体2の口頸部4における内周面の下部に対応して位置する故に、口頸部4の密封性に悪影響が及ぼされることはない)。
【0021】
上述したとおりの圧縮成形においては次の事実が注目されるべきである。即ち、充填された合成樹脂素材56の体積に若干の変動が存在していても、図3に図示する状態は必ず確立され、合成樹脂素材56の充填量の変動は図3に図示する状態からの第三の成形型手段22の下降量の変動によって補償される。従って、前成形体2の口頸部4の形状及び寸法を実質上変動せしめることなく、ブロー成形部6の肉厚を変動せしめることによって合成樹脂素材56の充填量の変動が補償される。
【0022】
所要形状に圧縮成形された合成樹脂素材56が充分に冷却された後においては、可動基板24を上昇せしめて第二の成形型手段20から成形された前成形体2を離脱せしめる。次いで、第一の成形型手段18に対して第三の成形型手段22を上昇せしめると共に第一の成形型手段18における第一の型部材26を構成している2個の部分26a及び26bを半径方向外方に移動せしめ、第一の成形型手段18及び第三の成形型手段22からも前成形体2を離脱せしめ、かくして圧縮成形された前成形体2を取り出すことができる。
【0023】
図5乃至7図は圧縮成形方法及び装置の変形例を図示している。図5乃至図7に図示する変形例においては、第一の成形型手段118における第二の型部材128は薄肉円筒形状の突出部(図2における突出部32を参照されたい)が存在しない。従って、第一の成形型手段118の第二の型部材128は、前成形体2における口頸部4の上端面のみを規定し、口頸部4の内周面を規定することはない。図5乃至図7に図示する変形例においては、第三の成形型手段122の外周面に肩面(図2における肩面48を参照されたい)が存在せす、第三の成形型手段122の外周面上半部は実質上鉛直に延びる円筒形状であり、第三の成形型手段122は、前成形体2における口頸部4の全内周面とブロー成形部6の全内面とを規定している。図5乃至図7に図示する変形例においては、仮成形空洞を規定している図6に図示する状態から、第一の成形型手段118に対して第三の成形型手段122を下降せしめても、成形空洞の内側に間隙(図4における間隙58を参照されたい)が生成されることがない。他方、図5乃至図7に図示する変形例においては、前成形体2の口頸部4が所要とおりの形状にせしめられたが、合成樹脂素材156が未だ充分に冷却されない状態の時に、口頸部4の内周面下部のみならず、口頸部4の密封性にとって比較的重要であることが少なくない内周面上部に対して第三の成形型手段122が移動せしめられて両者間に、回避することが望ましい滑りが生成される。図5乃至図7に図示する圧縮成形装置及びこれを使用した圧縮成形方法の上述した点以外は図2乃至図4に図示する圧縮成形装置及びこれを使用した圧縮成形方法と実質上同一である。
【0024】
【発明の効果】
本発明の圧縮成形装置によれば、局部的に低強度の部分を前成形体に生成せしめる等の問題を付随せしめることなく、合成樹脂素材の充填量の変動にかかわらず、前成形体の口頸部の形状及び寸法を一定にせしめると共に前成形体の全高を一定にせしめることができる。
【図面の簡単な説明】
【図1】 図1は、本発明の圧縮成形装置の好適実施形態において成形される前成形体の典型例を図示する半断面図。
【図2】 本発明の圧縮成形装置の好適実施形態を、圧縮成形工程の初期状態で示す断面図。
【図3】 図2に図示する圧縮成形装置を、圧縮成形工程の中間状態で示す断面図。
【図4】 図2に図示する圧縮成形装置を、圧縮成形工程の最終状態で示す断面図。
【図5】 本発明の圧縮成形装置の変形例を、圧縮成形工程の初期状態で示す断面図。
【図6】 図5に図示する圧縮成形装置を、圧縮成形工程の中間状態で示す断面図。
【図7】 図5に図示する圧縮成形装置を、圧縮成形工程の最終状態で示す断面図。
【符号の説明】
2:前成形体
4:前成形体の口頸部
6:前成形体のブロー成形部
18:第一の成形型手段
20:第二の成形型手段
22:第三の成形型手段
56:合成樹脂素材
118:第一の成形型手段
120:第二の成形型手段
122:第三の成形型手段
156:合成樹脂素材
[0001]
BACKGROUND OF THE INVENTION
The present invention is composed of an annular mouth-neck portion and a bottomed cylindrical blow-molded portion depending from the neck-and-neck portion, and compression-molds a synthetic resin preform that is blow-molded into a container. that on the equipment.
[0002]
[Prior art]
As containers for beverages and the like, synthetic resin containers made of an appropriate synthetic resin such as polyethylene terephthalate are widely used in practice. Such a synthetic resin container is generally formed by injection-molding a preformed body comprising an annular mouth-neck portion and a bottomed cylindrical blow-molded portion depending from the neck-and-neck portion, and then the blow-molded portion of the preformed body. Is produced by blow molding or stretch blow molding. The mouth-and-neck portion of the preformed body defines the mouth-and-neck portion of the container, and a support ring is usually formed on the outer peripheral surface thereof. When the container is sealed by attaching a lid to the mouth and neck after filling the contents in the container, the container is held by supporting the lower surface of the support ring.
[0003]
Thus, the conventional manufacturing mode of the synthetic resin container has a problem that the molding efficiency in the injection molding of the preform is limited, and the preform cannot be molded with high molding efficiency. In order to mold the preform with high molding efficiency, it is intended to adopt compression molding instead of injection molding. However, when the pre-molded body is compression molded, there are problems to be solved as follows. That is, in the case of compression molding, it is necessary to fill the mold with a synthetic resin material before closing the mold and defining the mold cavity. The filling of the synthetic resin material is performed by, for example, extruding a softened or molten synthetic resin material from an extruder and separating the synthetic resin material from the extrusion port of the extruder. Due to this, it is extremely difficult to control the filling amount of the synthetic resin material with sufficient precision, and there is usually an error of about 0.5 to 1.0% in the filling amount of the synthetic resin material. Such an error in the amount of the synthetic resin material is caused by moving the first mold means and the second mold means constituting the mold in a direction close to each other so that they are closed, and the synthetic resin material is synthesized between the two. The mutual distance between the first mold means and the second mold means when the resin material is compression molded is varied. Therefore, usually, a slight variation is generated in the dimensions such as the thickness and the outer diameter of the entire pre-formed body that has been compression-molded. Slight fluctuations in the dimensions of the blow molded part of the pre-molded body do not cause any particular problem, but if slight fluctuations are generated in the main dimensions such as the height of the mouth and neck, the inner and outer diameters, When the lid is attached to the mouth and neck, due to the dimensional variation of the part where the sealing means disposed on the lid is brought into close contact, the required sealing characteristics cannot be achieved. (B) From the lower surface of the support ring to the mouth and neck There are many possibilities that unacceptable problems such as various obstacles occur in the automatic lid mounting operation for mounting the lid on the mouth and neck due to the fluctuation of the height to the tip of the section.
[0004]
In Japanese Patent Laid-Open No. 10-337769, an annular groove is formed on the inner peripheral edge of the lower surface of the support ring in order to solve the problems as described above when compression molding the preform. In this way, the depth of the annular groove can be changed along with the thickness of the blow-molded part according to the fluctuation of the filling amount of the synthetic resin material, thereby changing the filling amount of the synthetic resin material. First, a compression molding mode is disclosed in which the shape and dimensions of the mouth and neck are made constant.
[0005]
[Problems to be solved by the invention]
However, the compression molding mode as described above disclosed in JP-A-10-337769 is still not fully satisfactory and has the following problems. That is, since an annular groove is formed in the support ring, particularly when the depth of the annular groove is relatively deep, the strength of the support ring or the vicinity thereof is excessively low, and when the preform is stretched prior to blow molding or When the blow molded part of the preform is blown, the preform may be deformed or damaged.
[0006]
The present invention has been made in view of the above-mentioned facts, and the main technical problem thereof is that the low-strength portion is not locally generated in the pre-molded body, regardless of the variation in the filling amount of the synthetic resin material. by providing the overall height of the can allowed to constant, new and improved equipment for compression molding preform of the preform with allowed to the shape and dimensions of the neck of the preform constant is there.
[0010]
[Means for Solving the Problems]
According to the present invention, as a compression molding apparatus that achieves the main technical problem, the compression molding apparatus includes an annular mouth-neck portion and a bottomed cylindrical blow-molded portion depending from the neck-and-neck portion, and the blow-molded portion is blow-molded. In a compression molding device for a preform for a blow molded container to be a container,
A first mold means for defining at least a portion other than the lower part of the outer peripheral surface of the mouth neck together with the upper end surface of the mouth neck; and a second mold means for defining the outer surface of the blow molded part A third mold means that is movably inserted into the central through opening formed in the first mold means and defines at least the inner surface of the blow-molded portion,
The second mold means is filled with a soft or molten synthetic resin material, and then the first mold means, the second mold means, and the third mold means cooperate with each other. Is closed in a state defining the temporary mold cavity, and then the relationship between the first mold means and the second mold means is maintained without being changed . Means is moved relative to the first mold means and the second mold means to reduce the thickness of the portion defining the blow mold in the temporary mold cavity; Is provided.
[0011]
In a preferred embodiment, the third mold means defines a lower portion of the inner peripheral surface of the mouth and neck portion together with the inner surface of the blow molded portion, and the first mold means includes the mouth and neck portion. A first mold member that defines at least a portion other than the lower portion of the outer peripheral surface of the first portion, and a second portion that defines a portion other than the lower portion of the inner peripheral surface of the mouth and neck portion together with the upper end surface of the mouth and neck portion. And a mold member. In another preferred embodiment, the third mold means defines the entire inner peripheral surface of the mouth neck together with the inner surface of the blow molded part, and the first mold means comprises the mouth A first mold member that defines at least a portion of the outer peripheral surface of the neck portion other than the lower portion; and a second mold member that defines the upper end surface of the mouth neck portion.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, a preferred embodiment of a compression formed KatachiSo location constructed according to the present invention will be described in detail with reference to the accompanying drawings.
[0013]
1 shows a typical example of the preform to be molded with a preferred embodiment of a compression formed KatachiSo location of the present invention is illustrated. A pre-molded body generally indicated by numeral 2 and compression-molded from an appropriate synthetic resin such as polyethylene terephthalate is composed of an annular mouth-neck portion 4 and a bottomed cylindrical blow-molded portion 6 depending from the mouth-neck portion 4. It is configured. The mouth-and-neck part 4 has a substantially cylindrical shape as a whole, and a male thread 8 is formed at the upper part of the outer peripheral surface. An annular support ring 12 is formed at the lower part of the mouth-and-neck portion 4 so as to protrude outward in the radial direction. The blow molding part 6 following the mouth / neck part 4 includes a substantially cylindrical body part 14 and a hemispherical bottom part 16 extending downward. In preform 2 in the illustrated embodiment, the region ranging from the inner peripheral surface lower part of the neck 4 to the inner peripheral surface upper portion of the blow molding unit 6, frustoconical inner diameter downward is reduced slightly Part 17 exists. As shown by a two-dot chain line in FIG. 1, blow molding is applied to the blow molding portion 6 or blow molding is applied after stretch molding is performed, and thus a container having a required shape is formed.
[0014]
FIG. 2 illustrates a compression molding apparatus for compression molding the preform 2. The illustrated compression molding apparatus includes a first mold means 18, a second mold means 20, and a third mold means 22. The first mold means 18 and the third mold means 22 are mounted on a movable substrate 24 that can be moved up and down. On the other hand, the second mold means 20 is mounted on a stationary substrate (not shown). If desired, instead of or in addition to mounting the first mold means 18 and the third mold means 22 on the movable substrate 24, the second mold means 20 is mounted on the movable substrate, The second mold means 20 can be moved up and down relatively with respect to the first mold means 18 and the third mold means 22.
[0015]
First molding die means 18 in the illustrated embodiment includes a first mold member 26 and a second mold member 28. The second mold member 28 is suspended from the movable substrate 24 via a plurality of suspension rods 29 arranged at intervals in the circumferential direction, and is moved up and down in accordance with the movement of the movable substrate 24. . The first mold member 26 is combined with the lower end portion of the second mold member 28. The first mold member 26 is composed of two arc-shaped portions 26a and 26b extending over an angle of 180 degrees, and is provided with a moving means (not shown) for moving in the circumferential direction. Has been. Therefore, the first mold member 26 is moved up and down in accordance with the up and down movement of the movable substrate 24 and is moved in the circumferential direction separately from the up and down movement. The first mold member 26 is a portion of the outer periphery of the mouth-and-neck portion 4 in the preform 2 other than the lower part, more specifically, the lower peripheral edge of the support ring 12 on the outer-periphery of the mouth-and-neck portion 4. An inner peripheral surface 30 that defines a portion above the lower surface of the inner peripheral surface. The second mold member 28 has a thin cylindrical protrusion 32 protruding downward, and the outer peripheral surface 34 of the protrusion 32 defines the upper part of the inner peripheral surface of the mouth neck 4 in the preform 2. Further, the downwardly facing annular shoulder surface 36 located at the base end of the protruding portion 32 in the second mold member 28 defines the upper end surface of the mouth and neck portion 4 in the preformed body 2.
[0016]
The second mold means 20 has a columnar shape as a whole, and a thin cylindrical protruding portion 38 protruding upward is formed at the center of the upper surface. A blind hole 40 extending downward is formed inside the protrusion 38. The upper surface 42 of the protrusion 38 defines the inner peripheral edge of the lower surface of the support ring 12 formed on the outer peripheral surface of the mouth-and-neck portion 4 in the preform 2. The inner surface 44 of the blind hole 40 is, together with the lower part of the inner peripheral surface of the mouth-and-neck part 4 in the pre-formed body 2 (more specifically, the part below the lower surface of the support ring 12 formed on the outer peripheral surface). 6 outer surface is defined.
[0017]
The second mold member 28 of the first mold means 18 is formed with a central through opening 46 extending through the central portion thereof, and the third mold means 22 moves to the central through opening 46. It is comprised from the elongate column-shaped member inserted freely. A shoulder surface 48 facing upward is formed in the middle portion of the outer peripheral surface of the third mold means 22, and the outer peripheral surface 50 of the portion above the shoulder surface 48 has a cylindrical shape extending substantially vertically. The outer diameter of the outer peripheral surface 50 is made to correspond to the inner diameter of the central through opening 46. The outer peripheral surface 52 of the portion below the shoulder surface 48 has a cylindrical part extending substantially vertically, followed by a truncated cone part with an inner diameter slightly decreasing downward, and subsequently followed by a substantially vertical part. The lower end portion has a hemispherical shape. The outer peripheral surface below the shoulder surface 48 in the third mold means 22 defines the inner surface of the blow-molded portion 6 together with the lower portion of the inner peripheral surface of the mouth-and-neck portion 4 in the front molded body 2. Elevating / lowering means 54 (only a part of which is shown) is attached to the upper end of the third mold means 22 for moving the third mold means 22 up and down with respect to the movable substrate 24. The elevating / lowering means 54 can be formed from an appropriate means such as a hydraulic or pneumatic cylinder mechanism. With respect to the first mold means 18, the third mold means 22 has a shoulder surface 48 on the lower end surface of the protruding portion 32 formed on the second mold member 28 of the first mold means 18. It is moved up and down relatively from the ascending position (position shown in FIG. 1) where it abuts.
[0018]
The compression molding method of the preform 2 by the compression molding apparatus as described above will be described as follows. When starting the compression molding, as shown in FIG. 2, the movable substrate 24 is moved to the raised position, and the first mold means 18 and the third mold means 22 are the second mold. It is spaced upwardly from the means 20. Then, the soft resin or molten synthetic resin material 56 is filled into the blind hole 40 of the second mold means 20. The synthetic resin material 56 such as polyethylene terephthalate can be conveniently filled by extruding from an extrusion port of an extruder (not shown) and separating from the extrusion port. As is well known to those skilled in the art, it is extremely difficult if not impossible to control the filling amount of the synthetic resin material 56 with sufficient precision, and usually an error of about 0.5 to 1.0% occurs. . In a preferred embodiment of the compression molding method according to the present invention, when the movable substrate 24 is lowered and the first mold means 18 is lowered to the lowest position relative to the second mold means 20 (third in the mold section 22 the state shown in the first tentative molding cavity that is defined in the allowed are) lowered with the first mold unit 18 has been brought located at the uppermost position with respect to the mold means 18 (i.e. 3 A synthetic resin material 56 having a volume V2 slightly larger than the volume V1 of the provisional molding cavity) is filled.
[0019]
Next, the movable substrate 24 is lowered, and the first mold means 18 and the third mold means 22 are lowered with respect to the second mold means 20 (in this case, the third mold means 22). Is first positioned at the uppermost position with respect to the mold means 18), and the synthetic resin material 56 is gradually compressed. Thus, as described above, the volume V2 of the filled synthetic resin material 56 is defined by provisional molding that is defined when the mold means 18 is first lowered to the lowest position relative to the second mold means 20. The first mold means 18 and the third mold means 22 are shown in FIG. 3 in the initial stage of compression molding even if the volume V1 of the cavity is larger and therefore the movable substrate 24 is lowered at the required pressure. The first mold means 18 and the third mold means 22 cannot be lowered to the position, and are positioned slightly above the position shown in FIG. When the filled synthetic resin material 56 is cooled and gradually contracted over time, the first mold means 18 and the third mold means 22 are gradually lowered accordingly. When the volume of the synthetic resin material 56 is reduced to the volume V1 of the temporary molding cavity, the first mold means 18 and the third mold means 22 are lowered to the positions shown in FIG. A cavity is defined.
[0020]
Even after that, the synthetic resin material 56 continues to be cooled and its volume is gradually reduced. In the compression molding method and apparatus constructed according to the present invention, after the provisional molding cavity is defined as described above, the third mold means 22 is at a predetermined pressure in response to the shrinkage of the synthetic resin material 56. Can be lowered. As can be understood by comparing FIGS. 3 and 4, the third mold means 22 gradually descends from the state shown in FIG. 3 where the provisional cavity is defined toward the state shown in FIG. When squeezed, the shape and size of the portion defining the mouth and neck portion 4 of the preform 2 in the temporary molding cavity are not substantially changed, but the thickness of the portion defining the blow molded portion 6, particularly blow molding. The part defining the lower end of the part 6 is gradually reduced. Thus, until the synthetic resin material 56 is sufficiently cooled, the third mold means 22 is gradually lowered to reach the state shown in FIG. 4, and the preform 2 is molded. When the third mold means 22 is lowered with respect to the first mold means 18, the second mold in the first mold means 18 is understood by comparing and referring to FIGS. The lower end surface of the protrusion 32 formed on the member 28 and the shoulder 48 of the third mold means 22 are separated from each other, and a slight gap 58 is generated between them. However, when the third mold means 22 is lowered, the synthetic resin material 56 is cooled to a considerably low temperature, particularly in the portion that defines the mouth-and-neck portion 4 of the preform 2. According to such experience, the synthetic resin material 56 does not flow into the gap 58 (even if the synthetic resin material 56 slightly flows into the gap 58, the gap is formed in the mouth neck 4 of the preform 2. Therefore, the sealing performance of the mouth / neck portion 4 is not adversely affected).
[0021]
The following facts should be noted in compression molding as described above. That is, even if there is a slight variation in the volume of the filled synthetic resin material 56, the state illustrated in FIG. 3 is always established, and the variation in the filling amount of the synthetic resin material 56 is from the state illustrated in FIG. The third mold means 22 is compensated for by the variation of the descending amount. Therefore, the variation in the filling amount of the synthetic resin material 56 is compensated for by changing the thickness of the blow molded portion 6 without substantially changing the shape and size of the mouth-and-neck portion 4 of the preform 2.
[0022]
After the synthetic resin material 56 compression-molded to the required shape is sufficiently cooled, the movable substrate 24 is raised and the pre-molded body 2 molded from the second mold means 20 is released. Next, the third mold means 22 is raised with respect to the first mold means 18, and the two portions 26a and 26b constituting the first mold member 26 in the first mold means 18 are moved. The preformed body 2 can be removed from the first mold means 18 and the third mold means 22 by moving outward in the radial direction, and the compacted preform 2 can be taken out.
[0023]
5 to 7 show a modification of the compression molding method and apparatus. In the modification shown in FIGS. 5 to 7, the second mold member 128 in the first mold means 118 does not have a thin cylindrical protrusion (see the protrusion 32 in FIG. 2). Therefore, the second mold member 128 of the first mold means 118 defines only the upper end surface of the mouth-and-neck portion 4 in the preform 2 and does not define the inner peripheral surface of the mouth-and-neck portion 4. In the modification shown in FIGS. 5 to 7, the third mold means 122 has a shoulder surface (see the shoulder surface 48 in FIG. 2) on the outer peripheral surface of the third mold means 122. The upper half of the outer peripheral surface has a cylindrical shape that extends substantially vertically, and the third mold means 122 includes the entire inner peripheral surface of the mouth-and-neck portion 4 and the entire inner surface of the blow-molded portion 6 in the preform 2. It prescribes. 5 to FIG. 7, the third mold means 122 is lowered with respect to the first mold means 118 from the state shown in FIG. However, no gap (see gap 58 in FIG. 4) is created inside the mold cavity. On the other hand, in the modification shown in FIGS. 5 to 7, the mouth-and-neck portion 4 of the pre-molded body 2 is shaped as required, but when the synthetic resin material 156 is still not sufficiently cooled, The third mold means 122 is moved not only between the lower part of the inner peripheral surface of the neck 4 but also the upper part of the inner peripheral surface which is relatively important for the sealing performance of the mouth and neck part 4. In addition, slips are generated that are desirable to avoid. Except for the above-described points of the compression molding apparatus shown in FIGS. 5 to 7 and the compression molding method using the same, the compression molding apparatus shown in FIGS. 2 to 4 and the compression molding method using the same are substantially the same. .
[0024]
【The invention's effect】
According to the compression forming KatachiSo location of the present invention, locally without allowed to accompany the problems such as allowed to produce a portion of the low strength preform, despite variations in the filling amount of the synthetic resin material, preform It is possible to make the shape and size of the neck and neck of the body constant and to make the total height of the preformed body constant .
[Brief description of the drawings]
FIG. 1 is a half cross-sectional view illustrating a typical example of a preform to be molded in a preferred embodiment of a compression formed KatachiSo location of the present invention.
FIG. 2 is a sectional view showing a preferred embodiment of the compression molding apparatus of the present invention in an initial state of a compression molding process.
3 is a cross-sectional view showing the compression molding apparatus shown in FIG. 2 in an intermediate state of a compression molding process.
4 is a sectional view showing the compression molding apparatus shown in FIG. 2 in a final state of a compression molding process.
FIG. 5 is a cross-sectional view showing a modification of the compression molding apparatus of the present invention in an initial state of a compression molding process.
6 is a cross-sectional view showing the compression molding apparatus shown in FIG. 5 in an intermediate state in a compression molding process.
7 is a sectional view showing the compression molding apparatus shown in FIG. 5 in the final state of the compression molding process.
[Explanation of symbols]
2: Pre-molded body 4: Mouth neck portion 6 of preformed body 6: Blow-molded section 18 of preformed body 18: First mold means 20: Second mold means 22: Third mold means 56: Synthesis Resin material 118: First mold means 120: Second mold means 122: Third mold means 156: Synthetic resin material

Claims (3)

環状口頸部と該口頸部から垂下する有底筒状ブロー成形部とから構成され、該ブロー成形部をブロー成形して容器とするブロー成形容器用前成形体の圧縮成形装置で、
該口頸部の上端面と共に、該口頸部の外周面の、少なくとも下部以外の部分を規定する第一の成形型手段と、該ブロー成形部の外面を規定する第二の成形型手段と、該第一の成形型手段に形成されている中央貫通開口に移動自在に挿通せしめられ、少なくとも該ブロー成形部の内面を規定する第三の成形型手段とを具備し、
該第二の成形型手段内に軟化或いは溶融状態の合成樹脂素材が充填され、次いで該第一の成形型手段、該第二の成形型手段及び第三の成形型手段が相互に協働して仮成形型空洞を規定する状態に閉じられ、しかる後に該第一の成形型手段と該第二の成形型手段との関係は変化せしめられることなく維持されるが、該第三の成形型手段が該第一の成形型手段及び該第二の成形型手段に対して移動せしめられて、該仮成形型空洞における該ブロー成形部を規定している部分の厚さが低減せしめられる、ことを特徴とする装置。
It is composed of an annular mouth-neck part and a bottomed cylindrical blow-molded part that hangs down from the mouth-neck part.
A first mold means for defining at least a portion other than the lower part of the outer peripheral surface of the mouth neck together with the upper end surface of the mouth neck; and a second mold means for defining the outer surface of the blow molded part A third mold means that is movably inserted into the central through opening formed in the first mold means and defines at least the inner surface of the blow-molded portion,
The second mold means is filled with a soft or molten synthetic resin material, and then the first mold means, the second mold means, and the third mold means cooperate with each other. Is closed in a state defining the temporary mold cavity, and then the relationship between the first mold means and the second mold means is maintained without being changed . Means is moved relative to the first mold means and the second mold means to reduce the thickness of the portion defining the blow mold in the temporary mold cavity; A device characterized by.
該第三の成形型手段は、該ブロー成形部の内面と共に、該口頸部の内周面の下部を規定し、該第一の成形型手段は、該口頸部の外周面の、少なくとも下部以外の部分を規定する第一の型部材と、該口頸部の該上端面と共に、該口頸部の内周面の、該下部以外の部分を規定する第二の型部材とを有する、請求項記載の装置。The third mold means defines the lower part of the inner peripheral surface of the mouth and neck part together with the inner surface of the blow molded part, and the first mold means includes at least the outer peripheral surface of the mouth and neck part. A first mold member that defines a part other than the lower part; and a second mold member that defines a part other than the lower part of the inner peripheral surface of the mouth and neck part together with the upper end surface of the mouth and neck part. The apparatus of claim 1 . 該第三の成形型手段は、該ブロー成形部の内面と共に、該口頸部の内周面の全体を規定し、該第一の成形型手段は、該口頸部の外周面の、少なくとも下部以外の部分を規定する第一の型部材と、該口頸部の該上端面を規定する第二の型部材とを有する、請求項記載の装置。The third mold means defines the entire inner peripheral surface of the mouth / neck portion together with the inner surface of the blow-molded portion, and the first mold means includes at least the outer peripheral surface of the mouth / neck portion. having a first mold member defining a portion other than the bottom, and a second mold member defining the upper end surface of the mouth neck apparatus according to claim 1.
JP2001004489A 2001-01-12 2001-01-12 Compression molding device for preformed body for blow molding container Expired - Fee Related JP4724920B2 (en)

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JP2000025729A (en) * 1998-07-09 2000-01-25 Ueno Hiroshi Preform for blow molding and production thereof

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Publication number Priority date Publication date Assignee Title
JP2000025729A (en) * 1998-07-09 2000-01-25 Ueno Hiroshi Preform for blow molding and production thereof

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