JP4723333B2 - Anti-allergen cleaning textile - Google Patents

Description

  The present invention relates to a cleaning fiber product in which a fiber is impregnated with an oil as an adsorbent, and more specifically, an anti-allergen cleaning fiber product capable of reducing the allergenicity of an allergen and / or allergen-containing material adsorbed on the fiber. It is about.

  Allergic diseases such as atopic dermatitis, asthma, fever, eczema and urticaria have plagued many people for many years. In particular, mite allergy is known to be involved in atopic dermatitis and bronchial asthma (author: Mitsumi Mitsumi et al. “1-3 Research results on research on the search for factors involved in the development of bronchial asthma and the development of testing methods. ”Environmental Conservation Organization website, 4th period research (http://www.erca.go.jp/asthma2/library/investigate/index.html) (Non-patent Document 1)), atopic skin It is important to get rid of indoor ticks in the prevention of fire and bronchial asthma. Japanese Patent Laid-Open No. 10-75924 (Patent Document 1) discloses a drug having an acaricidal activity and / or an activity of suppressing mite proliferation in order to suppress the proliferation of mites adsorbed and held on the surface and inside of a cleaning tool. A cleaning tool subjected to the above process is described. However, mite-derived allergens are also contained in mite carcasses and feces, and in order to reduce allergenicity, cleaning tools using anti-allergen agents that inactivate mite-derived allergens are used. Desired.

  Furthermore, many studies on allergic diseases have been conducted, and various substances that reduce or inactivate allergenicity by acting on the causative substances (allergens) of the allergic diseases as described above have been clarified. . Japanese Patent Application Laid-Open No. 2002-326944 (Patent Document 2) describes that tannic acid is suitable as an allergen deactivator, and the allergen deactivator is applied to a filter of a vacuum cleaner and adhered to the filter. It is described to inactivate allergens.

JP-A-10-75924 JP 2002-326944 A Author: Mitsufumi Miyu, etc. “1-3 Research Results on the Search of Factors Associated with the Development of Bronchial Asthma and the Development of Test Methods” Independent Administrative Institution, Environmental Conservation Organization Home Page, 4th Survey Research (http: //www.erca .go.jp / asthma2 / library / investigate / index.html)

  Patent Document 1 describes a cleaning tool that has been treated with a drug having acaricidal activity and / or a tick growth-inhibiting activity, but mite-derived allergens are also contained in mite carcasses. In addition, it is contained in tick feces. That is, in order to suppress mite-derived allergenicity, it is necessary not only to eliminate mites that contain allergens, but also to inactivate or reduce the activity of allergens contained in mite carcasses and feces. . However, the conventional cleaning tool as described in Patent Document 1 contains a drug having an acaricidal activity and / or an activity of suppressing the growth of mites, and does not reduce the activity of the allergen itself. It was. Therefore, allergens contained in mite carcasses and feces etc. may be detached from conventional textile products for cleaning and may act on humans as allergens. Accordingly, a first object of the present invention is to provide a cleaning textile product comprising an anti-allergen agent that inactivates various allergens.

  Patent Document 2 describes a vacuum cleaner in which an allergen inactive agent is applied to a filter. However, the filter of the vacuum cleaner needs to maintain a predetermined flow rate, and the mesh of the filter is made considerably small. However, it was difficult to remove fine allergens such as tick feces and pollen. Furthermore, the adsorptive power to the filter is weak, and it has been difficult for the allergen inactivating agent to adhere to the filter surface for a time sufficient for the allergen inactivating agent to reduce the activity of the allergen. . Accordingly, the object of the present invention is to ensure that various allergen substances are adsorbed to the fibers constituting the cleaning fiber product and to keep the allergen and allergen-containing substance adsorbed while the allergen is decomposed by the anti-allergen agent. And providing a cleaning textile product that does not release allergens again.

  The present invention has been proposed in order to solve the above-described problems. The first aspect of the present invention is a cleaning textile product in which fibers are impregnated with an adsorbent containing at least an oil agent. In addition, it is a cleaning textile product in which one or more kinds of anti-allergen agents are carried on the fibers and the allergenicity of allergens and / or allergen-containing materials adsorbed on the fibers is reduced.

  According to a second aspect of the present invention, in a cleaning fiber product in which fibers are impregnated with an adsorbent containing at least an oil agent and a surfactant, at least one antiallergen agent is supported on the fibers in addition to the adsorbent. This is a cleaning fiber product that reduces the allergenicity of the allergen and / or allergen-containing material adsorbed on the fiber.

  A third aspect of the present invention is a cleaning textile product according to the first or second aspect, wherein the anti-allergen agent is a water-soluble substance.

  The 4th form of this invention is a textile product for cleaning which is the component in which the said anti-allergen agent was extracted from the plant in the 1st, 2nd or 3rd form.

  The 5th form of this invention is the textile product for cleaning whose allergen is an allergen derived from a tick in any one of the 1st-4th form.

  A sixth aspect of the present invention is the cleaning textile product according to any one of the first to fifth aspects, wherein the adsorbent contains a fungicide and / or an antibacterial agent.

  According to a seventh aspect of the present invention, in any one of the first to sixth aspects, the oil agent is 5 to 50 parts by weight and the anti-allergen agent is 0.01 parts by weight with respect to 100 parts by weight of the fiber. It is a textile product for cleaning carried by 10 parts by weight.

  According to an eighth aspect of the present invention, in any of the first to sixth aspects, the oil agent is 5 to 50 parts by weight and the surfactant is 0.01 parts by weight with respect to 100 parts by weight of the fiber. It is a textile product for cleaning on which 1 to 3 parts by weight and 0.01 to 10 parts by weight of an antiallergen agent are carried.

According to the first aspect of the present invention, since at least one kind of anti-allergen agent is carried on the fiber in addition to the adsorbent containing at least the oil agent, the adsorbent contains dust and dust together with allergen and allergen-containing material. It can adsorb | suck to the said fiber reliably, and can reduce the allergenic property of the said allergen and / or allergen containing material with high efficiency. The liquid in which the anti-allergen agent is dispersed or dissolved may be sprayed on the fiber carrying the adsorbent to carry the anti-allergen agent on the fiber, and the fiber or the textile product for cleaning is immersed in the liquid. The anti-allergen agent can be supported on the fibers by stirring and soaking. Further, the addition of anti-allergen agent to the adsorbent, an anti-allergen agent with the carrier of the adsorbent may be supported on the fibers. The textile product for cleaning according to the present invention includes textile products used for all cleaning tools such as mops, mats, cloths, and scraps. By using the cleaning tool, a clean living environment can be provided and a consumer can be provided. Can prevent allergic diseases. The textile products for cleaning are made of cotton, rayon, polyester, nylon, acrylic, vinylon and other synthetic fabrics, mop-like products made of piled fibers, rayon, vinylon, nylon, polyethylene, polypropylene, etc. Nonwoven fabric, pulp, vinylon, rayon, and other synthetic fibers are used.
Allergens derived from mites (such as mites, mite carcasses, feces), pet hair and epithelium, mold-derived allergens, plant-derived allergens (such as pollen), house dust, etc. can be collected in the adsorbent. Examples of the anti-allergen agent capable of reducing these allergenic properties include polyphenols (Japanese Patent Laid-Open No. 2002-326944), and more specifically, tannic acid, gallotannin, gallic acid, epicatechin epicacatechin, Examples include epigallocatechin gallate and oleuropein. Further, chlorpheniramine, diphenhydramine, carbinoxamine, pyrilamine, tripelenamine, brompheniramine, hydroxyzine, cyclidine, promethazine, terfenadine, astemizole, dimene hydrinate, or a salt thereof (Japanese Patent Publication No. 9-510976) Can be mentioned. Thus, these various anti-allergen agent selected suitably 1 or more, wherein it is possible to carry the fibers, it is possible to reduce the variety of allergenic.

According to the second aspect of the present invention, the adsorbent includes at least an oil agent and a surfactant, and the fiber is impregnated with an adsorbent in which the oil agent is emulsified with the surfactant. Since the anti-allergen agent is carried on the fiber, the adsorbent can be reliably and firmly carried on the fiber, and the allergen is more reliably adsorbed to the cleaning fiber product and the allergen is absorbed by the anti-allergen agent. Can be reduced. In other words, without the adsorbent is desorbed from the fibers, the allergen and / or allergen-containing substance can be reliably adsorbed, it is possible to reduce these allergenicity efficiently. Preferably as the surfactant, cationic surfactants, anionic surfactants, among the nonionic surfactants and amphoteric surfactants, one or two or more surfactants are used.
Furthermore, as in the first embodiment, mite-derived allergens (mites, mite carcasses, feces, etc.), pet hair and epithelium, mold-derived allergens, plant-derived allergens (pollen etc.), house dust, etc. It can be collected in the adsorbent and can carry polyphenols as an antiallergen. In addition, chlorpheniramine, diphenhydramine, carbinoxamine, pyrilamine, tripelenamine, brompheniramine, hydroxyzine, cyclidine, promethazine, terfenadine, astemizole, dimene hydrinate or their salts are supported as one or more anti-allergen agents. Can do.

  According to the third aspect of the present invention, since the anti-allergen agent is a water-soluble substance, the anti-allergen agent can be dissolved in water to produce an anti-allergen solution, and the fiber is added to the anti-allergen solution. By soaking, the adsorbent and the antiallergen can be easily and efficiently carried. Alternatively, an adsorbent may be added to the anti-allergen solution, and the adsorbent and the anti-allergen agent may be simultaneously supported on the fiber. The adsorbent is added to the anti-allergen solution, and the anti-allergen is added to the adsorbent. An agent may be added and supported on the fiber. Furthermore, the anti-allergen solution can be easily carried on the fibers by spraying the anti-allergen solution onto the fibers. That is, when the anti-allergen agent is a water-soluble substance, the anti-allergen agent can be easily carried on the fiber, so that a cleaning fiber product having an allergenicity-reducing effect can be provided at low cost.

  According to the fourth aspect of the present invention, since the anti-allergen agent is a component extracted from a plant, the anti-allergen agent can be easily and safely generated, and the textile product for cleaning having an allergenicity-reducing effect. Can be provided at low cost. Moreover, it is not necessary to synthesize the anti-allergen agent, the use of various chemical substances and the production of by-products in the synthesis process can be suppressed, and environmental pollution and the like can be prevented. Furthermore, the anti-allergen agent contained in the natural product has a low possibility of causing harm to the human body and may prevent side effects and the like on the human body due to the anti-allergen agent. Camellia tea, urchinaceae nulde, liliaceae lotus, bamboo and bamboo of grass family, subfamily olive genus olive, aceae genus ibota, maimaibota, oibaibota, saikokuibota, murine mochi, sushi mochi, etc. Ingredients extracted from herbs (eg, Lamiaceae rosemary) are used as the anti-allergen agent, and the anti-allergen agent is extracted from fresh leaves, fruits or dry powder of leaves and fruits, etc. It can be supported. For example, in the case of tea, anti-allergens such as catechin can be extracted from tea leaves for commercially available green tea, and tea leaves, olives, herbs, bamboo, strawberries, etc. have been used for various purposes by humans for many years. And is highly safe for the human body.

  According to the fifth aspect of the present invention, since the allergen is inactivated by carrying the anti-allergen agent that reliably reduces mite-derived allergenicity on the fiber, the atopic property caused by the mite-derived allergen is caused. The onset of dermatitis and bronchial asthma can be prevented. For example, allergens such as Dermatophagoides farinae and Dermatophagoides pteronyssinus have allergenic properties such as feces and their carcasses, and it is known that allergenicity cannot be removed simply by killing mites. The allergens derived from the feces of the dust mite are called Derf1 and Derp1, respectively, and the allergens derived from worms are called Der2 and are distinguished. The fiber product for anti-allergen cleaning according to the present invention reliably adsorbs Derf1, Derp1, Der2, etc. contained in house dust together with mite feces and insect bodies and does not detach from the fiber for a long time. The adsorption state can be maintained, and the allergenicity can be effectively reduced by the anti-allergen agent supported on the fiber. Further, the anti-allergen cleaning fiber product according to the present invention reliably adsorbs mites (Kenagakonadani, Tibikonadani, Ayudanite, Mite, etc.) containing various allergens other than the above, feces, carcasses thereof, and the like, and is a suitable antiallergen agent. Can be reduced in the mite-derived allergenicity. In addition, preferable anti-allergen agents for mite allergens include tea extracts such as tannic acid, gallic acid, propyl gallate, and hydroxyapatite.

  According to the sixth aspect of the present invention, since the fungicide and / or antibacterial agent is contained in the adsorbent, it is possible to simultaneously prevent the growth of mold and fungi. Furthermore, in the case of fungi and / or fungi that can release allergens, not only the growth of fungi and fungi but also the activity of allergens contained in fungi and / or fungi is reduced by the anti-allergen agent. The onset of sex diseases can be prevented.

  According to the seventh aspect of the present invention, since 5 parts by weight to 50 parts by weight of the oil agent is impregnated with respect to 100 parts by weight of the fiber, house dust, allergens contained therein and allergen-containing materials are efficiently contained. Can be adsorbed with high efficiency, and the allergenicity of the adsorbed allergen and the allergen-containing material can be suitably reduced by supporting 0.01 to 10 parts by weight of the anti-allergen agent. These numerical ranges are derived from the experiences of the present inventors. If the numerical value range of the oil agent is 5 parts by weight or less, the dust absorption efficiency of the house dust is reduced, and if it is 50 parts by weight or more, there is a high possibility that the oil agent will transfer to the surface to be cleaned even if dust is absorbed. Further, when the numerical value range of the surfactant is 0.01 parts by weight or less, the emulsion of the oil agent is reduced, and when it is 3 parts by weight or more, excessive addition is caused to increase the cost of the surfactant. Increase the production cost of textile products for allergen cleaning.

  According to the eighth aspect of the present invention, the oil agent is supported by 5 to 50 parts by weight and the surfactant is supported by 0.01 to 3 parts by weight with respect to 100 parts by weight of the fiber. Similarly to the seventh embodiment, it is possible to provide a cleaning textile product that can impart a suitable dust absorption efficiency to the fiber and hardly transfer the oil to the surface to be cleaned. Furthermore, if the numerical range of the anti-allergen agent is 0.01 parts by weight or less, the action of reducing the allergenicity is reduced, and if it is 10 parts by weight or more, it becomes excessively loaded and the cost of the anti-allergen agent is rapidly increased.

  The textile product for anti-allergen cleaning according to the present invention includes all cleaning tools in which fibers are used, and the fibers include natural fibers and synthetic fibers including paper, woven fabrics, knitted fabrics, nonwoven fabrics, Other fiber molded bodies are included. Hereinafter, the present invention will be specifically described by taking a mop and mat as examples of the anti-allergen cleaning fiber product, but the present invention is not limited to this example.

  FIG. 1 is a perspective view of a mop 1 that is Embodiment 1 of a textile product for anti-allergen cleaning according to the present invention. The mop 1 is composed of a base fabric 2 and a pile 2a. The mop 1 is impregnated with an adsorbent and carries an antiallergen agent. Moreover, you may carry | support an allergen agent only to the pile 2a. A surfactant is added to the oil to produce an oil emulsion and the fibers are impregnated. At this time, a water-soluble anti-allergen agent is put into the emulsion liquid. Further, the emulsion liquid is adjusted to the acidic side with a pH adjuster, and the emulsion particles are adsorbed on the mop 1 to be subjected to oil impregnation treatment. The treated mop is dehydrated with an electric washing machine, and after drying, the mop 1 is completed. Moreover, as Comparative Example 1, a mop in which an anti-allergen agent is not loaded and an acaricide is added to the oil is produced.

  FIG. 2 shows a mop that has been subjected to oil impregnation treatment and anti-allergen treatment (Example 1), a mop that has been impregnated with oil impregnation treatment and an acaricide (Comparative Example 1), and an anti-allergen agent only (no oil impregnation treatment). It is a comparison figure of the allergenicity reduction effect | action with respect to the mite allergen of the mop (comparative example 2) which was made. The mop of Comparative Example 2 is sprayed onto a mop that has not been treated with an oil-impregnated solution. Each cut mop piece was inoculated with mite leopard mite. This is stored under conditions of 25 ° C. and a relative humidity of about 75%, and the amount of the allergen (Derf1) of the mushroom mite is measured. In FIG. 2, compared to a mop (blank) in which neither an adsorbent nor an antiallergen is supported, the Derf1 amount is 80% or more lower, ◎, 50% to 80% reduced, ○, 20% △ is reduced by -50%, and x is a reduction rate of 20% or less. As shown in FIG. 2, a remarkable mite allergen reduction of 80% or more was measured in the mop (Example 1) in which an antiallergen agent was loaded in addition to the adsorbent. On the other hand, in the mop (Comparative Example 1) in which an acaricide was added to the adsorbent, only a decrease in Derf1 of 20% or less was measured. On the other hand, in the comparative example 2 which consists only of an antiallergen agent, the allergen reduction rate of 20%-50% was obtained. That is, it was found that when the adsorbent is supported on the fiber, a further mite allergen reducing effect is exhibited.

  FIG. 3 shows mite allergens treated with anti-allergen treatment (Example 2), mats carrying a tick control agent (Comparative Example 3), and mats carrying only an anti-allergen agent (Comparative Example 4). It is a comparison figure of an allergenicity reduction effect. Similarly to the mop in FIG. 2, the mat of Example 2 is impregnated with an oil agent in fibers constituting the mat. Furthermore, the mat of Comparative Example 4 is sprayed on a mat that has not been treated with an oil-impregnated solution. As shown in FIG. 3, in the mat (Example 2) in which the anti-allergen agent is loaded in addition to the adsorbent, a remarkable mite allergen reduction of 80% or more is measured. In addition, as in FIG. 2, compared to a mat (blank) in which an adsorbent and an anti-allergen agent are not supported, the Derf1 amount is 80% or more lower than ◎, and 50% to 80% reduced. ○, 20% to 50% reduction is indicated by Δ, and 20% or less is indicated by ×. In the mat (Comparative Example 3) to which an acaricide was added in addition to the adsorbent, only a decrease in Derf1 of 20% or less was measured, and furthermore, a comparison in which no adsorbent was supported and only an anti-allergen agent was supported. In Example 4, only a reduction effect of 20% to 50% was obtained. Therefore, it has been proved that the reduction effect is the highest when the adsorbent and the anti-allergen agent are simultaneously loaded in the mat.

  The anti-allergen cleaning textile product according to the present invention is used in all cleaning tools such as mops, mats, cloths, and oysters, and has been used for many years including allergic diseases such as atopic dermatitis, asthma, fever, eczema and urticaria. It is possible to effectively reduce the allergenic activity of allergens that have plagued people over a long period of time.

It is a perspective view of the mop 1 which is the Example of the textile product for anti-allergen cleaning which concerns on this invention. Reduction of allergenicity to mite allergens in a mop treated with anti-allergen oil impregnation (Example 1), a mop loaded with an acaricide (Comparative Example 1) and a mop loaded with only an anti-allergen agent (Comparative Example 2) It is a comparison figure of an operation. Allergenicity reduction of mite allergens in mats treated with anti-allergen oil impregnation (Example 2), mats carrying a tick control agent (Comparative Example 3) and mats carrying only an anti-allergen agent (Comparative Example 4) It is a comparison figure of an operation.

Explanation of symbols

1 Mop 2 Base fabric 2a Pile 4 Holding part

Claims (7)

In a cleaning textile product in which fibers are impregnated with an adsorbent containing at least an oil agent, the cleaning textile product is a mop or mat, and in addition to the adsorbent, at least one antiallergen agent comprising a water-soluble substance is The amount of allergen held by the mop or the mat is 100% when the amount of allergen retained by the untreated mop or untreated mat on which the adsorbent and the anti-allergen agent are not supported is defined as 100%. A fiber product for anti-allergen cleaning, which is 50% or less of the treated mop or the untreated mat . In a cleaning textile product in which fibers are impregnated with an adsorbent containing at least an oil agent and a surfactant, the cleaning textile product is a mop or a mat, and one or more types of anti- resistant comprising a water-soluble substance in addition to the adsorbent. When the amount of allergen held by the untreated mop or untreated mat on which the allergen agent is carried on the fiber and the adsorbent and the anti-allergen agent are taken as 100%, the allergen held by the mop or mat An anti-allergen cleaning textile, wherein the amount is 50% or less of the untreated mop or the untreated mat . The textile product for anti-allergen cleaning according to claim 1 or 2 , wherein the anti-allergen agent is a component extracted from a plant. The textile product for anti-allergen cleaning according to any one of claims 1 , 2 and 3, wherein the allergen is an allergen derived from mites. The textile product for cleaning according to any one of claims 1 to 4 , wherein the adsorbent contains a fungicide and / or an antibacterial agent. With respect to the fiber 100 parts by weight, the oil is 5 to 50 parts by weight, the anti-allergen according to any one of claims 1 to 5 in which the anti-allergen agent is 10 parts by carrying 0.01 part by weight Textile products for cleaning. Wherein the fiber 100 parts by weight, the oil is 5 to 50 parts by weight, the surfactant is 0.01 parts by weight to 3 parts by weight, the anti-allergen agent is 0.01 to 10 parts by weight carrying The textile product for anti-allergen cleaning according to any one of claims 2 to 5 .

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