JP4622736B2 - Laminated steel sheet for 2-piece cans, 2-piece can manufacturing method, and 2-piece laminate cans - Google Patents

Description

  The present invention relates to a laminated steel plate suitable for manufacturing a two-piece can having a high degree of processing such as an aerosol can, for example, and a two-piece laminated can having a high degree of processing.

  There are roughly two-piece cans and three-piece cans for aerosol metal containers. The two-piece can has a beautiful appearance due to the absence of a seam portion (welded portion), but generally has a high degree of processing. The three-piece can has a seam portion, and its appearance is inferior to that of the two-piece can. However, the degree of processing is generally low. For this reason, in the market, two-piece cans are often used for small-scale and high-end products, and three-piece cans are often used for large-capacity and low-priced products.

  The metal material in the aerosol two-piece can is generally made of expensive and thick aluminum or the like, and inexpensive and thin steel plate materials such as tinplate and tin-free steel are hardly used. The reason is that the aerosol two-piece can has a high degree of processing, so that it is difficult to apply drawing or DI processing, and aluminum is manufactured by applying impact molding applicable to a soft metal material. Under such circumstances, industrial significance is very large if steel sheets such as tinplate and tin-free steel that are inexpensive and thin but have high strength can be used.

  Conventionally, various methods of drawing and DI processing of laminated steel sheets have been proposed, but a method of manufacturing a can body having a high drawing ratio and a high degree of drawing in the can height direction, such as an aerosol two-piece can, has been proposed. Not.

  For example, Patent Documents 1 to 3 disclose a processing method for drawing and drawing ironing of a resin-coated metal plate, but the degree of processing described in Patent Documents 1 to 3 (the drawing ratio in Patent Documents 1 to 3). ) Is in a range lower than that defined in the present invention. This is because Patent Documents 1 to 3 target beverage cans, food cans, and the like, and beverage cans and food cans are can bodies having a processing degree lower than the range of processing degrees defined in the present invention.

  Patent Documents 2 and 3 describe that heat treatment is performed during processing and / or in the middle of processing, or in the final stage, with the intention of preventing peeling of the resin layer and barrier properties after processing. In No. 2, an oriented thermoplastic resin is used, and in Patent Document 3, a compound material of saturated polyester and ionomer is used.

  Patent Documents 4 and 5 alleviate internal stress mainly by applying a heat treatment at a temperature equal to or higher than the melting point of the resin, and describe that it is applied at a stage after can molding. In addition, the degree of processing of the can is low as far as the description of the specification and the examples are concerned.

Patent Document 2 proposes a heat treatment for relaxing internal stress and promoting orientation crystallization, and is currently a method commonly used in beverage cans and the like. Although there is no clear description in the patent literature, oriented crystallization is promoted at a temperature below the melting point, so the heat treatment temperature is estimated to be below the melting point. In addition, as far as the description of the text and the examples is concerned, it can be seen that, when compared with the workability specified in the present invention, those having a workability lower than that are targeted.
Japanese Examined Patent Publication No. 7-106394 Japanese Patent No. 2526725 JP 2004-148324 A Japanese Patent Publication No.59-35344 Japanese Examined Patent Publication No. 61-22626

  In the prior art, there has been no proposal for a method of manufacturing a can body that uses a laminated steel plate to form a high-working degree like an aerosol two-piece can. Therefore, the inventors manufactured a two-piece can with a high degree of processing that uses a laminated steel plate to form a bottomed cylindrical shape by drawing ironing and then reduces the diameter of the vicinity of the opening. A problem occurred, specifically, there was a problem of peeling and breaking of the resin layer. As a result of investigations by the inventors, heat treatment was qualitatively effective, but that was not sufficient, and peeling of the resin layer was inevitable in a high workability region. Therefore, even if the prior art is simply applied, the problem of the resin layer peeling cannot be solved. In addition, there is a problem that the workability of the resin layer deteriorates in the steps after the heat treatment step.

  The object of the present invention is to solve the above-mentioned problems and to provide a two-piece laminated steel sheet and two-piece can that can prevent the peeling and breakage of the laminated resin layer even if a highly processed can body such as an aerosol two-piece can is manufactured. It is to provide a method for manufacturing a can. Moreover, the subject of this invention is providing the can body of the high workability like the aerosol 2 piece can which used the laminated steel plate.

  It is considered that an important characteristic required for the resin layer in processing at a high degree of processing is ease of deformation. According to the study by the inventors, it has been found that a polyethylene terephthalate copolymer system or a polybutylene terephthalate copolymer system is promising. And when producing a two-piece can by multi-stage forming the laminated steel sheet coated with this resin, it is possible to prevent exfoliation and breakage of the resin layer by heat-treating under specific conditions in the middle of the forming process. It was found that a two-piece can was manufactured. The present invention is based on this finding.

  Means of the present invention for solving the above-mentioned problems are as follows.

  (1) The height h, maximum radius r, and minimum radius d (including the case where r and d are the same) of the final molded body are compared with the radius R of the circular plate before molding in which the weight is equivalent to the final molded body. A laminated steel plate used for manufacturing a two-piece can satisfying the relationship of 0.1 ≦ d / R ≦ 0.25 and 1.5 ≦ h / (R−r) ≦ 4, Obtained by polycondensation of a dicarboxylic acid component and a diol component on one side. The dicarboxylic acid component is mainly composed of terephthalic acid, and the other copolymer component includes or does not include an isophthalic acid component. And / or a resin comprising butylene glycol as a main component and other copolymer components containing or not containing diethylene glycol and cyclohexanediol, wherein the copolymer components are less than 8 mol% in molar ratio. , Two-piece can for laminated steel sheet, wherein a plane orientation coefficient has a 0.06 or less of the polyester resin coating layer (first invention).

  (2) The circular plate of the laminated steel sheet is formed in multiple stages, and the height h, the maximum radius r, and the minimum radius d (including the case where r and d are the same) of the final molded body are equivalent to the weight of the final molded body. To produce a final molded body satisfying the relationship of 0.1 ≦ d / R ≦ 0.25 and 1.5 ≦ h / (R−r) ≦ 4 with respect to the radius R of the circular plate before molding. When manufacturing, the laminated steel plate of Claim 1 is used as a laminated steel plate, The manufacturing method of 2 piece cans (2nd invention) characterized by the above-mentioned.

  (3) When producing the final molded article according to (2), at a middle stage of molding, the molded body is heated once or more so that the temperature is 150 ° C. or higher and the melting point of the polyester resin or lower. A method for producing a two-piece can (third invention).

  (4) In the heat treatment, the height h, the maximum radius r, and the minimum radius d (including the case where r and d are the same) of the intermediate molded body are before the drawing process corresponding to the tip of the opening of the final molded body. For the radius R of the circular plate position, performing in an intermediate stage satisfying the relationship of 0.2 ≦ d / R ≦ 0.5 and 1.5 ≦ h / (R−r) ≦ 2.5 A method for producing a two-piece can according to (3), which is characterized (fourth invention).

  (5) A two-piece laminate can manufactured by the method according to any one of (2) to (4) (fifth invention).

  When a two-piece can is manufactured using the laminated steel sheet of the present invention, it is possible to manufacture a two-piece can with a high degree of processing by preventing the resin layer from peeling and breaking. When producing a two-piece can having a high workability as defined in the present invention by multi-stage forming the laminated steel sheet of the present invention, in the intermediate stage of molding, the molded body has a temperature of 150 ° C. or higher and a melting point of the polyester resin or lower. It is possible to prevent the resin layer from being peeled off and broken by performing the heat treatment to be heated once or more. The two-piece can manufactured by the method of the present invention can be used for applications such as an aerosol two-piece can that requires a high degree of processing.

  The embodiment of the present invention and the reason for limitation will be described.

  FIG. 1 is a diagram for explaining an embodiment of a can manufacturing process according to the present invention, in which a circular blank is formed into a bottomed cylindrical formed body by drawing (including DI processing), and the formed body is further described. The order of steps for manufacturing a two-piece can in which the vicinity of the opening is reduced in diameter and the vicinity of the opening is reduced is shown.

  In FIG. 1, 1 is a disc-shaped blank (blank sheet) before processing, 2 is a base portion and a straight wall portion of the molded body (a straight wall portion not subjected to diameter reduction processing in Step D), 3 is a dome-shaped portion, Reference numeral 4 denotes a straight wall portion that has been reduced in diameter by the neck shape portion, and reference numeral 5 denotes a tapered shape portion that is a tapered wall portion after the diameter reduction processing.

  First, one or a plurality of stages of drawing (including DI processing) is performed on the circular plate blank 1 to form a bottomed cylindrical molded body having a predetermined can diameter (radius r; radius of can outer surface) ( Step A). Next, the bottom of the molded body is formed in a convex shape upward to perform dome processing for forming the dome-shaped portion 3 (step B), and the opening side end of the molded body is trimmed (step C). Next, one or more stages of diameter reduction processing are performed on the opening side portion of the molded body to reduce the diameter of the opening side portion of the molded body to a predetermined can diameter (radius d: radius of the can outer surface). A molded body (2-piece can) is obtained. In the figure, R0 is the radius of the circular blank 1 before molding, h, r, and d are the height of the molded body or final molded body in the middle of molding, the maximum radius, the minimum radius, and R is the final molded body, respectively. And the radius R of the circular plate before molding that is equivalent to the weight R and the radius of the circular plate before molding that is equivalent in weight to the final molded body. In the manufacturing process of the two-piece can, the maximum radius and the minimum radius of the process A are the same, that is, r = d, and the process D is r> d.

  The radius R of the circular plate before molding that is equivalent in weight to the final molded body is determined based on the measured weight of the final molded body. That is, the weight of the final molded body is measured, the dimension (radius) of the circular plate before molding that becomes the same weight as this weight is obtained, and this is the circular shape before molding in which the weight is equivalent to the final molded body. Let it be the radius R of the plate. The can end is trimmed during the manufacturing process of the can body, but the radius R of the circular plate before molding, which is equivalent in weight to the final molded body, is more appropriate because the influence of trim is eliminated. The degree of processing can be evaluated.

  Thus, in a two-piece can created by applying drawing (including DI processing) and diameter reduction processing to a circular plate blank, the resin layer is stretched in the height direction and contracted in the circumferential direction. . When the degree of processing is high, the amount of deformation of the resin increases, leading to the breakage of the resin layer. In the present invention, not only the parameter d / R indicating the degree of shrinkage but also the parameter h / (R−r) related to the elongation in the can height direction is used as an index of the degree of processing. This is because, in the high workability region, it is necessary to consider the elongation amount in addition to the drawing ratio in order to express the workability. That is, by defining the degree of processing by the degree of shrinkage and the degree of elongation, the degree of deformation of the resin layer is quantified. Since the resin layer extends in the height direction and shrinks in the circumferential direction, it becomes easy to peel off. In addition to the degree of shrinkage, the amount of elongation in the height direction is an important factor.

  In the present invention, regarding the degree of processing of the finally manufactured can body (final molded body), the height h, the maximum radius r, and the minimum radius d of the final molded body are set so that the weight is equivalent to that of the final molded body. Is defined in a range satisfying the can diameter of 0.1 ≦ d / R ≦ 0.25 and 1.5 ≦ h / (R−r) ≦ 4.

  As described above, an object of the present invention is to make it possible to manufacture a can body having a high workability, which has been difficult with the prior art, by using a laminated steel plate. In the prior art, using a laminated steel sheet, the parameter d / R that defines the degree of shrinkage satisfies 0.25 or less, and the parameter h / (R−r) that defines the degree of elongation is 1.5 or more. At the same time, it was difficult to produce a can with a high degree of processing that was satisfactory. Therefore, in the present invention, the working degree d / R of the can body to be manufactured is regulated to 0.25 or less, and h / (R−r) is regulated to 1.5 or more.

  Molding is possible when the parameter d / R that defines the degree of shrinkage is 0.1 or less, or the parameter h / (R−r) that defines the degree of elongation is a high degree of processing exceeding 4. This is because the number of forming steps increases unnecessarily, or the elongation limit of the plate is reached with work hardening, and the plate breaks. Therefore, in the present invention, the degree of processing of the can body to be manufactured is defined as 0.1 ≦ d / R and h / (R−r) ≦ 4.

  Note that the multi-stage forming that is the subject of the present invention is any one of drawing, drawing / ironing, diameter reduction, or a combination of these. When the diameter reduction process is included, the dimension d of the final molded body is r> d. When the diameter reduction processing is not included, the size of the final molded body is r = d (r and d are can diameters of the final molded body).

  In this invention, the laminated steel plate which coat | covered the polyester resin is prescribed | regulated as a raw material metal plate used for manufacture of the above-mentioned 2 piece can.

The reason why the base metal material is a steel plate is that it is cheaper and more economical than aluminum. As the steel plate, it is preferable to use general tin-free steel or tinplate. Tin-free steel, for example, a metal layer of chromium coating weight 50-200 mg / ^{m 2} on the surface, the adhesion amount of metal chromium conversion preferably has an chromium oxide layer of 3 to 30 mg / ^{m 2.} The tinplate preferably has a plating amount of 0.5 to 15 g / m ² . Although plate | board thickness is not specifically limited, For example, the thing of the range of 0.15-0.30 mm is applicable. Moreover, this technology can be simply applied to an aluminum material if economic efficiency is not taken into consideration.

  The important characteristic required for the resin layer in the above-described high processing degree is considered to be easy to deform, and according to the study by the inventors, it is obtained by condensation polymerization of a carboxylic acid component and a diol component, The dicarboxylic acid component is mainly composed of terephthalic acid, and the other copolymer components are either composed of or not including the isophthalic acid component, the diol component is composed of ethylene glycol and / or butylene glycol as the main component, and other copolymer components. Further, it has been found that a polyester resin containing or not containing diethylene glycol and cyclohexanediol is promising. Therefore, in this invention, the resin seed | species of the resin layer was prescribed | regulated to said resin.

  However, it has been found that when the copolymer ratio is high, the polyester resin tends to generate internal stress as compared with a low copolymer ratio, and as a result, the resin tends to be peeled off. Although the detailed cause is unknown, it is considered that the ease of orientation and difficulty are involved. By can molding, the resin shrinks in the circumferential direction, undergoes deformation in the height direction, and tends to be oriented in the can height direction. At this time, it is considered that the simple molecular shape is easier to arrange smoothly than the complicated one, and as a result, internal stress is less likely to occur. That is, when subjected to equivalent deformation, it is considered that the internal stress generated during deformation is less likely to increase when the low copolymerization ratio with a simple molecular shape is higher than when the molecular shape is high. From this viewpoint, in the present invention, the ratio of the copolymerization component is defined as less than 8 mol%.

  Further, it has been found that the initial orientation of the resin layer of the laminated steel sheet is also important in order for the resin layer to follow the molding with a high workability specified in the present invention. That is, the film produced by biaxial stretching or the like is oriented in the plane direction. However, if the orientation is high after lamination, it cannot follow the processing and breaks. From such a viewpoint, in the present invention, the plane orientation coefficient is defined as 0.06 or less. In order to produce such a laminated steel sheet using a biaxially stretched film having a high plane orientation coefficient, it is only necessary to raise the temperature during lamination and sufficiently melt the oriented crystals. Or since the film produced by the extrusion method is almost non-orientated, it is suitable from this viewpoint. Similarly, a direct laminating method in which a molten resin is directly laminated on a steel plate is also suitable for the same reason.

  The laminated steel sheet defined in the present invention may be used by adding additives such as pigments, lubricants and stabilizers in the resin layer, or a resin layer having other functions in addition to the resin layer defined in the present invention. You may arrange | position in the intermediate | middle layer with an upper layer or a base steel plate.

  As the thickness of the resin layer increases, the increase in internal stress increases and the peelability becomes severe. However, when the resin layer defined in the present invention is used, even a thick resin layer can be suitably used. The resin thickness may be appropriately selected according to the degree of processing and other required characteristics. For example, a resin thickness of 10 μm or more and 50 μm or less can be suitably used. Particularly in the range where the resin layer of 20 μm or more is thick, this is a region where the effect of the present invention is greatly contributed.

  In the laminated steel sheet defined in the present invention, it suffices that at least one surface of the steel sheet is coated with the resin layer defined in the present invention.

  The method of laminating to the steel plate is not particularly limited, but is appropriately selected such as a thermocompression bonding method in which a biaxially stretched film or an unstretched film is thermocompression bonded, and an extrusion method in which a resin layer is directly formed on the steel plate using a T die. It has been confirmed that sufficient effects can be obtained.

  When producing a can body having a high degree of processing defined in the present invention, the adhesion force is reduced depending on processing conditions and resin types. Therefore, it is necessary to ensure the necessary adhesion according to the use and specifications of the can body. In this case, the temperature of the molded body is 150 ° C. or higher and the melting point of the polyester resin or lower in the middle of multistage molding. It is effective to perform the heat treatment for heating at least once. This heat treatment is intended to relieve internal stress caused by processing, but has the effect of improving adhesion by relieving internal stress. That is, the high workability can body defined in the present invention has a large degree of strain in the resin layer and tends to generate large internal stress. As a result, the resin layer may peel off using this internal stress as a driving force. When an appropriate heat treatment is performed in the middle of molding, the internal stress is relaxed, and a decrease in adhesion can be suppressed. However, this heat treatment has a negative aspect in which the oriented crystallization of the resin proceeds and the processability of the resin layer is lowered. In particular, in a high workability region defined by the present invention, processing may be necessary even after heat treatment, and in that processing, the resin is easily broken by orientation crystallization of the resin, and the orientation crystal is harmful. .

  From such a viewpoint, in the present invention, in addition to the limitation of the resin type, the heat treatment conditions and the heat treatment timing are determined.

  In the present invention, the heat treatment condition is defined as heating the molded body so that its temperature is 150 ° C. or higher and the melting point of the polyester resin or lower in an intermediate stage. When the heat treatment temperature exceeds the melting point of the polyester resin, adverse effects such as rough skin on the surface and adhesion of the resin to the contact material appear. On the other hand, the lower limit of the heat treatment temperature is determined in consideration of the efficiency of internal stress relaxation. That is, relaxation of the internal stress proceeds at a temperature equal to or higher than the glass transition point Tg of the polyester resin, but if it is too low, it takes too much time for relaxation. From this viewpoint, the lower limit temperature is set to 150 ° C. Therefore, in a production process where the processing time does not become a problem, a heat treatment temperature of less than 150 ° C. can be selected using the technical idea of the present invention, but generally the productivity is deteriorated. A more desirable heat treatment temperature is 170 ° C. or higher and the melting point of the polyester resin is −20 ° C. or lower.

  In the present invention, the timing at which the heat treatment is performed is a drawing in which the height h, maximum radius r, and minimum radius d (including the case where r and d are the same) of the intermediate molded body correspond to the tip of the opening of the final molded body. At an intermediate stage satisfying the relationship of 0.2 ≦ d / R ≦ 0.5 and 1.5 ≦ h / (R−r) ≦ 2.5 with respect to the radius R of the circular plate position before processing Specify what to do.

  The reason for setting the heat treatment timing as described above is that the heat treatment is most effectively performed when the degree of processing is within the above range. In other words, the heat treatment is performed at a moderate degree of processing because the internal stress is relaxed at a stage where the internal stress is not high, and thus the above-described effect is small. In addition, the heat treatment performed at a stage where the degree of processing is too high may result in a late loss because adhesion may be reduced and peeling may occur as a result. From such a viewpoint, the upper limit and the lower limit of the working degree are determined as described above.

  The heat treatment can be performed in one or both of step A and step D. Regarding the timing of the heat treatment described above, the case where r and d are the same includes the case where the heat treatment is performed in step A in the manufacturing process of the can including the diameter reducing process or does not include the diameter reducing process. This is because r and d have the same diameter in the can manufacturing process. The heat treatment may be performed in two or more intermediate stages depending on the need for internal stress relaxation.

  The heat treatment method is not particularly limited, and it has been confirmed that the same effect can be obtained with an electric furnace, a gas oven, an infrared furnace, an induction heater, or the like. The heating rate, heating time, and cooling time may be appropriately selected in consideration of both the positive effect due to relaxation of internal stress and the negative effect due to orientation crystallization. However, the higher the heating rate, the more efficient the heating time. Is approximately 15 to 60 seconds, but is not limited to this range. Further, if the cooling time is slow, the amount of spherulite produced increases, which is not preferable in terms of quality. Therefore, the faster the cooling time, the better.

  Examples of the present invention will be described below.

"Production of laminated steel sheet"
T4CA and TFS (metal Cr layer: 120 mg / m ² , Cr oxide layer: 10 mg / m ^{2 in} terms of metal Cr) having a thickness of 0.20 mm were used as the base metal plate. Various resin layers were formed using a film thermocompression bonding method) or a direct laminating method (direct extrusion method). In addition, about the film lamination, two types, what used the biaxially stretched film and what used the unstretched film, were implemented. A film having a thickness of 25 μm was laminated on both surfaces of the metal plate.

  The plane orientation coefficient of the laminate film of the laminated steel sheet produced above was calculated as follows.

"Measurement of plane orientation coefficient"
Using an Abbe refractometer, the refractive index was measured under the conditions that the light source was sodium / D line, the intermediate solution was methylene iodide, and the temperature was 25 ° C. The refractive index Ny and the refractive index Nz in the thickness direction of the film were determined, and the plane orientation coefficient Zs was calculated from the following formula.
Planar orientation coefficient (Ns) = (Nx + Ny) / 2−Nz

Table 1 shows the production method of the laminated steel sheet and the contents of the produced laminated steel sheet. The resin types listed in Table 1 are as follows.
PET: Polyethylene terephthalate PET-I: Polyethylene terephthalate-isophthalate copolymer (isophthalic acid copolymerization ratio 12 mol%)
PET-PBT (60): Polyethylene terephthalate-butylene terephthalate copolymer (butylene terephthalate copolymer ratio 60 mol%)
PET-DEG: Polyethylene terephthalate-diethylene glycol copolymer PET-CHDM: Polyethylene terephthalate-cyclohexanediol copolymer.

The laminating method is as follows.
Film thermocompression bonding method 1: A film prepared by the biaxial stretching method was subjected to thermocompression bonding with a nip roll in a state where the steel sheet was heated to the melting point of the resin + 10 ° C., and then cooled by water cooling within 7 seconds.
Film thermocompression bonding method 2: An unstretched film was thermocompression bonded with a nip roll in a state where the steel sheet was heated to the melting point of the resin + 10 ° C., and then cooled by water cooling within 7 seconds.
Direct extrusion method: resin pellets are kneaded and melted with an extruder, coated on a running steel plate from a T-die, and then the resin-coated steel plate is nip-cooled with an 80 ° C. cooling roll, and further water-cooled Cooled by.

"Can body molding"
Using the produced test steel plate, a can body (final formed body) was produced according to the following procedure in accordance with the production process shown in FIG. Table 2 shows the shapes of the intermediate molded body (process C) and the final molded body (process D). The drawing process of the process A was performed in 5 stages, and the diameter reduction process of the process D was performed in 7 stages. The heat treatment was performed in the middle of steps A to D, the can body was heated using an infrared heating furnace, and water-cooled after the heat treatment. Table 3 shows the timing of heat treatment (the degree of processing of the can during heat treatment) and the heat treatment conditions.

  In Table 2, h, r, d, ha, hc, and R of the final molded body (step D) are the height to the open end of the final molded body, the diameter of the base portion 2, and the diameter of the neck shape portion 3, respectively. The height of the base body 2, the height of the neck-shaped portion 3, and the radius of the circular plate blank before molding that is equivalent in weight to the final molded body (see FIG. 1). The radius R of the circular plate blank was determined as follows. Measure the weight of the blank sheet before molding and the weight of the final molded body after the trimming process. Based on the measurement results, determine the radius of the blank sheet before molding that is equivalent to the weight of the final molded body. It was set as the radius R of the circular plate blank before shaping | molding in which a body and a weight became equivalent.

1) Blanking (66-94mmφ)
2) Drawing and ironing (process A)
Cans having a radius r and a height h of r / R: 0.24 to 0.34 and h / (R−r): 1.84 to 3.09 in five stages of drawing. A body (intermediate molded body) was produced. Moreover, in order to produce a desired can body, the ironing process was also used together suitably.

3) Dome shape processing of can bottom (process B)
A hemispherical overhanging process having a depth of 6 mm was performed on the bottom of the can.
4) Trim processing (Process C)
The upper end of the can was trimmed by about 2 mm.
5) Diameter reduction of the upper part of the cylinder (Process D)
The upper part of the cylinder is subjected to warping processing, specifically, the die neck method in which the diameter of the opening is pressed against the inner tapered die to reduce the diameter, and the final can body shape shown in Table 2 is obtained. A can body was produced.

  The adhesion, workability, and appearance of the film layer of the can body produced by the above procedure were evaluated as follows. The evaluation results are also shown in Table 3.

"Adhesion test"
The can body was sheared into a substantially rectangular shape in the can height direction so as to have a width of 15 mm in the circumferential direction, and only the steel sheet was sheared linearly in the circumferential direction at a position 10 mm from the bottom surface in the can height direction. As a result, a test piece consisting of a 10 mm portion and the remaining portion on the bottom surface side in the can height direction with the shearing position as a boundary was created. A steel plate having a width of 15 mm and a length of 60 mm is connected to a 10 mm portion (welding), and the 60 mm steel plate portion is held to peel the remaining portion of the film about 10 mm from the breaking position. A peel test was performed in the 180 ° direction using the part where the film was peeled off and the 60 mm steel plate part as a margin. The minimum value of the observed peel strength was used as an index of adhesion.
"Peel strength"
Less than 5N / 15mm: ×
5N / 15mm or more and less than 7N / 15mm: ○
7N / 15mm or more: ◎

"Film processability evaluation"
The outer surface side of the resin layer after the can was visually and optically observed to confirm whether the film had any breakage. A sample with a normal appearance was marked with ◯, and a sample with a confirmed fracture or crack was marked with ×.

"Evaluation results"
Can bodies C1 to C15 and C21 to C33 are examples of the present invention, and the film processability and adhesion showed good values.

  The cans C16 to C20 are examples of the present invention, but are not subjected to the heat treatment specified in the third invention or the fourth invention. Although both film processability and adhesion were acceptable, the evaluation was only ○.

  Since the cans C34 to C36 were comparative steel plates in which the copolymerization ratio of isophthalic acid was outside the scope of the present invention, the adhesion was x.

  Since can body C37 is a comparative steel plate whose plane orientation coefficient is outside the range of the present invention, the workability is x.

  The laminated steel sheet of the present invention can be used to produce a two-piece can with a high workability that can prevent peeling and breaking of the laminated resin layer. The method for producing a two-piece can of the present invention can be used as a method for producing a two-piece can having a high degree of processing by preventing the laminate resin layer from peeling and breaking. The two-piece laminate can produced by the method of the present invention can be used for applications such as aerosol cans that require a high degree of processing.

It is a figure explaining one Embodiment of the manufacturing process of the can of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Blank sheet 2 Base | substrate part 3 Dome shape part 4 Neck shape part 5 Tapered shape part

Claims (5)

The height h, the maximum radius r, and the minimum radius d (including the case where r and d are the same) of the final molded body are 0 with respect to the radius R of the circular plate before molding in which the weight is equivalent to the final molded body. 1 ≦ d / R ≦ 0.25 and 1.5 ≦ h / (R−r) ≦ 4 is a laminated steel plate used for the production of a two-piece can, and at least on one side of the steel plate, Obtained by polycondensation of a dicarboxylic acid component and a diol component, the dicarboxylic acid component is mainly composed of terephthalic acid, and other copolymer components include or do not include an isophthalic acid component, and diol components include ethylene glycol and / or , A resin containing butylene glycol as a main component and other copolymer components containing diethylene glycol and cyclohexanediol or not containing the copolymer component in a molar ratio of less than 8 mol%. Laminated steel sheet for 2-piece cans, wherein a direction coefficient has a 0.06 or less of the polyester resin coating layer. Before forming the circular plate of the laminated steel sheet into a multi-stage, the final molded body height h, maximum radius r, and minimum radius d (including the case where r and d are the same) are equivalent to the final molded body in weight. When producing a final molded body satisfying the relationship of 0.1 ≦ d / R ≦ 0.25 and 1.5 ≦ h / (R−r) ≦ 4 with respect to the radius R of the circular plate of A method for producing a two-piece can, wherein the laminated steel plate according to claim 1 is used as the laminated steel plate. When producing the final molded body according to claim 2, heat treatment for heating the molded body so that the temperature is 150 ° C. or higher and the melting point of the polyester resin or lower is performed at least once in an intermediate stage of molding. A method for producing a two-piece can. In the heat treatment, the circular plate before drawing corresponding to the height h, the maximum radius r, and the minimum radius d (including the case where r and d are the same) of the intermediate molded body corresponds to the end of the opening of the final molded body. It is characterized in that it is performed in an intermediate stage satisfying the relationship of 0.2 ≦ d / R ≦ 0.5 and 1.5 ≦ h / (R−r) ≦ 2.5 with respect to the radius R of the position. The manufacturing method of the 2 piece can of Claim 3. A two-piece laminate can manufactured by the method according to claim 2.

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