JP4590910B2 - Battery - Google Patents

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Publication number
JP4590910B2
JP4590910B2 JP2004116293A JP2004116293A JP4590910B2 JP 4590910 B2 JP4590910 B2 JP 4590910B2 JP 2004116293 A JP2004116293 A JP 2004116293A JP 2004116293 A JP2004116293 A JP 2004116293A JP 4590910 B2 JP4590910 B2 JP 4590910B2
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battery
spacer
outer peripheral
cylindrical
peripheral side
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JP2004335452A (en
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利明 小貫
健介 後藤
幸太郎 池田
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Shin Kobe Electric Machinery Co Ltd
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Shin Kobe Electric Machinery Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Battery Mounting, Suspending (AREA)

Description

本発明は、集合電池に係り、特に、正極、負極の間にセパレータを介在させた電極群と電解液とを円筒容器に収容した円柱状電池を複数個組み合わせた集合電池に関する。   The present invention relates to an assembled battery, and more particularly to an assembled battery in which a plurality of columnar batteries each having an electrode group in which a separator is interposed between a positive electrode and a negative electrode and an electrolytic solution are contained in a cylindrical container are combined.

従来、円柱状電池を複数個組み合わせて集合電池を構成するために、電池ホルダに円柱状電池を保持したり(例えば、特許文献1参照)、円柱状電池の直径より大きな内径を持つ筒状電池ホルダに円柱状電池を挿入し、その筒状電池ホルダ両端面に円柱状電池間を電気的に接続する金属片を溶接、又はネジ締結し、この接合力で電池を固定する技術が開示されている。   Conventionally, in order to construct an assembled battery by combining a plurality of cylindrical batteries, a cylindrical battery is held in a battery holder (see, for example, Patent Document 1), or a cylindrical battery having an inner diameter larger than the diameter of the cylindrical battery. A technique is disclosed in which a cylindrical battery is inserted into a holder, metal pieces that electrically connect the cylindrical batteries are welded or screwed to both end faces of the cylindrical battery holder, and the battery is fixed with this joining force. Yes.

特開平第10−270006号公報(図8、段落番号「0032」〜「0040」)JP-A-10-270006 (FIG. 8, paragraph numbers “0032” to “0040”)

しかしながら、上記特許文献1の技術では、電池ホルダが複雑なためコスト高となる。また、電池ホルダの電池を保持する部位が電池側面と同形状に湾曲しており電池の組立作業が煩雑化する。更に、電池を固定した集合電池をリサイクルする際に、解体作業が煩雑化し廃棄部材の量が増加する、という問題が生ずる。   However, the technique disclosed in Patent Document 1 is expensive because the battery holder is complicated. In addition, the battery holder portion of the battery holder is curved in the same shape as the battery side surface, which complicates battery assembly. Furthermore, when recycling the assembled battery to which the battery is fixed, there arises a problem that the dismantling work becomes complicated and the amount of discarded members increases.

また、筒状電池ホルダ内に円柱状電池を挿入する技術では、電池ホルダがコスト高となるだけでなく、電池ホルダの接合力により円柱状電池を固定し電気的接続を担うために、金属片の体積が大きくなってしまい、その分集合電池の重量が増加する。   Further, in the technique of inserting a cylindrical battery into the cylindrical battery holder, not only the battery holder becomes expensive, but also a metal piece for fixing the cylindrical battery by the joining force of the battery holder and carrying out electrical connection. The volume of the battery increases, and the weight of the assembled battery increases accordingly.

本発明は、上記事案に鑑み、組立性及び体積、重量効率に優れた集合電池を提供することを課題とする。   In view of the above-described case, an object of the present invention is to provide an assembled battery excellent in assembling property, volume, and weight efficiency.

上記課題を解決するために、本発明は、正極、負極の間にセパレータを介在させた電極群と電解液とを円筒容器に収容した円柱状電池を複数個組み合わせた集合電池において、前記円柱状電池の外周側面に、この外周側面に接する一面以外の対面が平面状の第1のスペーサが配置されており、前記第1のスペーサは前記外周側面に接する面が1面のみで構成されているとともに前記対面がすべて平面であり、前記円柱状電池は少なくとも前記対面が固定面とされ組み合わされている。 In order to solve the above-described problems, the present invention provides an assembled battery in which a plurality of columnar batteries each containing an electrode group in which a separator is interposed between a positive electrode and a negative electrode and an electrolytic solution are housed in a cylindrical container. A first spacer having a flat surface other than one surface in contact with the outer peripheral side surface is disposed on the outer peripheral side surface of the battery, and the first spacer has only one surface in contact with the outer peripheral side surface. In addition, the facing surfaces are all flat, and the cylindrical battery is combined with at least the facing surface as a fixed surface.

本発明では、円柱状電池の外周側面に第1のスペーサが配置され、第1のスペーサは外周側面に接する面が1面のみで構成されているとともに対面がすべて平面で、第1のスペーサの円柱状電池に接する一面以外の対面が平面状のため、少なくとも第1のスペーサの対面を固定面とすることができるので、円柱状電池の組立性を向上させることができると共に、第1のスペーサが占める体積、重量の増加を抑制でき、集合電池の体積、重量効率を向上させることができる。 In the present invention, the first spacer is disposed on the outer peripheral side surface of the cylindrical battery, and the first spacer is composed of only one surface in contact with the outer peripheral side surface, and all the facing surfaces are flat . Since the facing surface other than the one surface in contact with the cylindrical battery is flat, at least the facing surface of the first spacer can be a fixed surface, so that the assemblability of the cylindrical battery can be improved and the first spacer The volume and weight increase occupied by the battery can be suppressed, and the volume and weight efficiency of the assembled battery can be improved.

本発明において、円柱状電池の第1のスペーサが配置された外周側面の反対側面に、この反対側面に接する以外の対面が平面状で第1のスペーサと同形状の第2のスペーサを更に配置すれば、第1及び第2のスペーサの固定面で円柱状電池を固定して組み合わせることができる。また、第1のスペーサを、断面略コ字状とし、円柱状電池の外周側面に接する面に円柱状電池の位置決めをするための窪みを形成すれば、円柱状電池と第1のスペーサとの一体化を容易かつ確実に行うことができる。更に、第1のスペーサを断面略矩形状の枠とし、枠に円柱状電池を装入すれば、部材数が円柱状電池にあたり1個と少ないため、コストを低減することができると共に、円柱状電池に4個の固定面を形成することができる。 In the present invention, a second spacer having the same shape as the first spacer is provided on the opposite side surface of the outer peripheral side surface where the first spacer of the cylindrical battery is disposed, and the opposite surface other than the one surface in contact with the opposite side surface is planar. Furthermore, if it arrange | positions, a cylindrical battery can be fixed and combined with the fixed surface of a 1st and 2nd spacer. In addition, if the first spacer has a substantially U-shaped cross section and a recess for positioning the cylindrical battery is formed on a surface in contact with the outer peripheral side surface of the cylindrical battery, the cylindrical battery and the first spacer Integration can be performed easily and reliably. Furthermore, if the first spacer is a frame having a substantially rectangular cross section and a cylindrical battery is inserted into the frame, the number of members is as small as one per cylindrical battery, so that the cost can be reduced and the cylindrical shape can be reduced. Four fixed surfaces can be formed on the battery.

また、第1のスペーサが断面略三角形状であり、円柱状電池の外周側面に接する面に窪みが形成され、円柱状電池は窪みが形成された面以外の2面のうち少なくとも1面が固定面とされ組み合わされるようにしてもよく、更に、円柱状電池の第1のスペーサが配置された外周側面の反対側面に、第1のスペーサと同形状の第2のスペーサが更に配置されており、円柱状電池は更に第2のスペーサの窪みが形成された面以外の2面のうち少なくとも1面が固定面とされ組み合わされようにしてもよい。これらの形態では、より集合電池の小型化を実現することができる。また、スペーサ及び円柱状電池を、熱収縮した筒状体で被覆すれば、加熱して形状変形する筒状体を収縮させることで円柱状電池とスペーサとを一体とすることができるので、組立性を向上させることができる。   In addition, the first spacer has a substantially triangular cross section, a depression is formed on a surface in contact with the outer peripheral side surface of the cylindrical battery, and at least one of the two surfaces of the cylindrical battery other than the surface where the depression is formed is fixed. In addition, a second spacer having the same shape as the first spacer is further arranged on the side surface opposite to the outer peripheral side surface where the first spacer of the cylindrical battery is arranged. Further, the cylindrical battery may be combined with at least one of the two surfaces other than the surface where the recess of the second spacer is formed as a fixed surface. In these forms, it is possible to further reduce the size of the assembled battery. If the spacer and the cylindrical battery are covered with a heat-shrinkable cylindrical body, the cylindrical battery and the spacer can be integrated by shrinking the cylindrical body that is deformed by heating. Can be improved.

本発明によれば、円柱状電池の外周側面に第1のスペーサが配置され、第1のスペーサは外周側面に接する面が1面のみで構成されているとともに対面がすべて平面で、第1のスペーサの円柱状電池に接する一面以外の対面が平面状のため、少なくとも第1のスペーサの対面を固定面とすることができるので、円柱状電池の組立性を向上させることができると共に、第1のスペーサが占める体積、重量の増加を抑制でき、集合電池の体積、重量効率を向上させることができる、という効果を得ることができる。 According to the present invention, the first spacer is disposed on the outer peripheral side surface of the cylindrical battery, and the first spacer is composed of only one surface in contact with the outer peripheral side surface, and all the facing surfaces are flat. Since the facing surface of the spacer other than the one in contact with the cylindrical battery is flat, at least the facing surface of the first spacer can be a fixed surface, so that the assembly of the cylindrical battery can be improved and the first The increase in volume and weight occupied by the spacers can be suppressed, and the volume and weight efficiency of the assembled battery can be improved.

(第1実施形態)
以下、図面を参照して、本発明に係る集合電池の第1の実施の形態について説明する。
(First embodiment)
Hereinafter, a first embodiment of an assembled battery according to the present invention will be described with reference to the drawings.

(構成)
図1(A)、(B)に示すように、本実施形態の集合電池28は、2行4列に配設された8個の個縛済電池5cを備えている。
(Constitution)
As shown in FIGS. 1 (A) and 1 (B), the assembled battery 28 of this embodiment includes eight individual batteries 5c arranged in two rows and four columns.

図2及び図3に示すように、各個縛済電池5cは、円筒型リチウムイオン二次電池(以下、二次電池と略称する。)1がその外周側面に板状の合成樹脂製スペーサ4aが配置されており、二次電池1及びスペーサ4aが合成樹脂製で筒状の熱収縮チューブ9に被覆されて個縛、密着されている。スペーサ4aは、二次電池1の外周側面に接する面に、二次電池1の位置決めをするための円弧状窪み24aが形成されている。また、スペーサ4aの窪み24aが形成された面の対面は、平面状とされており、両角部にR付けがなされている。このため、個縛済電池5cは、この対面に形成された1個の平面状の固定接着面6cと、固定接着面6cと交差する2個の平面状の固定接着面6dとを有している。   As shown in FIGS. 2 and 3, each individually bound battery 5 c includes a cylindrical lithium ion secondary battery (hereinafter abbreviated as a secondary battery) 1 and a plate-like synthetic resin spacer 4 a on the outer peripheral side surface thereof. The secondary battery 1 and the spacer 4a are made of synthetic resin, covered with a cylindrical heat-shrinkable tube 9, and are individually bound and closely attached. In the spacer 4 a, an arcuate recess 24 a for positioning the secondary battery 1 is formed on the surface in contact with the outer peripheral side surface of the secondary battery 1. Further, the surface of the spacer 4a where the recess 24a is formed is a flat surface, and both corners are rounded. For this reason, the individual battery 5c has one flat fixed adhesive surface 6c formed on the opposite surface and two flat fixed adhesive surfaces 6d intersecting the fixed adhesive surface 6c. Yes.

二次電池1は、正極及び負極をリチウムイオンの通過を許容するポリエチレン製微多孔薄膜のセパレータを介してガラスフィラが30%混入したポリプロピレン製中空棒状の軸芯の周りに捲回した電極群と非水電解液とが円筒状の有底電池缶内に収容され、電池内圧が所定圧に到達するとガスを開放するガス開放弁を有する上蓋キャップ2が絶縁体を介してカシメ封口されカシメ部3が形成されている(図2参照)。上蓋キャップ2、電池缶の底面は、それぞれ二次電池1の正、負極端子となる。   The secondary battery 1 includes an electrode group in which a positive electrode and a negative electrode are wound around a polypropylene hollow rod-shaped shaft core mixed with 30% glass filler through a polyethylene microporous thin film separator that allows lithium ions to pass through. The non-aqueous electrolyte is accommodated in a cylindrical bottomed battery can, and when the internal pressure of the battery reaches a predetermined pressure, the upper lid cap 2 having a gas release valve that releases the gas is caulked and sealed through an insulator, and the caulking portion 3 Is formed (see FIG. 2). The upper lid cap 2 and the bottom surface of the battery can serve as positive and negative terminals of the secondary battery 1, respectively.

正極は、活物質のマンガン酸リチウム(LiMn)粉末100重量部に、導電剤として平均粒径20μmの鱗片状黒鉛10重量部、結着剤のポリフッ化ビニリデン(PVDF)10重量部を添加し、これに分散溶媒のN−メチルピロリドンを添加、混練して得たスラリをアルミニウム箔の両表面に塗布、乾燥、プレス、裁断して得られたものである。 In the positive electrode, 100 parts by weight of an active material lithium manganate (LiMn 2 O 4 ) powder, 10 parts by weight of scaly graphite having an average particle diameter of 20 μm as a conductive agent, and 10 parts by weight of polyvinylidene fluoride (PVDF) as a binder are used. The slurry obtained by adding, kneading, and kneading the dispersion solvent N-methylpyrrolidone was applied to both surfaces of the aluminum foil, dried, pressed and cut.

一方、負極は、グラファイト粉末100重量部に、結着剤としてPVDF10重量部を添加し、これに分散溶媒のN−メチルピロリドンを添加、混練して得たスラリを圧延銅箔の両面に塗布、乾燥、プレス、裁断して得られたものである。   On the other hand, the negative electrode was added to 10 parts by weight of PVDF as a binder to 100 parts by weight of graphite powder, and N-methylpyrrolidone as a dispersion solvent was added to this, and a slurry obtained by kneading was applied to both sides of the rolled copper foil. It was obtained by drying, pressing and cutting.

非水電解液には、例えば、6フッ化リン酸リチウム(LiPF)や4フッ化ホウ酸リチウムをエチレンカーボネート(EC)、ジメチルカーボネート(DMC)などの有機溶媒に1モル/リットル程度溶解した電解液が用いられている。 In the non-aqueous electrolyte, for example, lithium hexafluorophosphate (LiPF 6 ) or lithium tetrafluoroborate was dissolved in an organic solvent such as ethylene carbonate (EC) or dimethyl carbonate (DMC) at about 1 mol / liter. An electrolyte is used.

図1に示すように、個縛済電池5cは、隣接する二次電池1の正、負極端子が上下方向を交互にして固定接着面6c同士及び隣接する固定接着面6d同士が接着され組み合わされている。すなわち、固定接着面6c、6dは、個縛済電池5c同士の固定面となる。   As shown in FIG. 1, the bound battery 5 c is formed by adhering the positive and negative terminals of the adjacent secondary battery 1 alternately in the vertical direction and adhering the fixed adhesive surfaces 6 c and the adjacent fixed adhesive surfaces 6 d to each other. ing. That is, the fixed adhesive surfaces 6c and 6d are fixed surfaces between the individually bound batteries 5c.

二次電池1の正、負極端子は、板状の金属製接続ブスバ7で隣接する二次電池の異極同士に接続されており、二次電池1全体として直列に接続され、集合電池28が構成されている。なお、接続ブスバ7の両端部に図示を省略した十字状の溶接用貫通穴(プロジェクション)が形成されており、正、負極端子はそれぞれ貫通穴を介して接続ブスバ7にスポット溶接されている。   The positive and negative terminals of the secondary battery 1 are connected to different polarities of the adjacent secondary batteries by a plate-shaped metal connection bus bar 7, connected in series as the entire secondary battery 1, and the assembled battery 28 is It is configured. A cross-shaped welding through hole (projection) (not shown) is formed at both ends of the connection bus bar 7, and the positive and negative terminals are spot welded to the connection bus bar 7 through the through holes, respectively.

(集合電池の作製)
次に、本実施形態の集合電池28の作製手順について説明する。
(Production of assembled battery)
Next, a manufacturing procedure of the assembled battery 28 of the present embodiment will be described.

二次電池1の外周側面にスペーサ4aを配置し、熱収縮チューブ9で二次電池1及びスペーサ4aを被覆する。次に、熱収縮チューブ5aを熱収縮させて二次電池1及びスペーサ4aを個縛、密着する。これにより、個縛済電池5cが作製される。   A spacer 4 a is arranged on the outer peripheral side surface of the secondary battery 1, and the secondary battery 1 and the spacer 4 a are covered with a heat shrinkable tube 9. Next, the heat-shrinkable tube 5a is heat-shrinked so that the secondary battery 1 and the spacer 4a are tied and adhered. Thereby, the individual battery 5c is produced.

複数の個縛済電池5cを作製した後、接着される個縛済電池5c同士の一方の固定接着面6c、6dに接着剤を塗布した後、固定治具中に隣接する電池の上下を逆にして挿入し、固定接着面6c、6d同士を接着して個縛済電池5cを組み合わせる。個縛済電池5cの正、負極端子と隣接する個縛済電池5cの異極同士とを接続ブスバ7の溶接用貫通穴を介してスポット溶接し、集合電池28の作製が完了する。   After producing a plurality of individually bound batteries 5c, an adhesive is applied to one of the fixed adhesive surfaces 6c and 6d of the individually bound batteries 5c to be bonded, and then the adjacent batteries in the fixing jig are turned upside down. Then, the fixed adhesive surfaces 6c and 6d are bonded together to combine the individually bound batteries 5c. The positive and negative terminals of the individually bound battery 5c and the adjacent different electrodes of the individually bound battery 5c are spot-welded through the welding through holes of the connection bus bar 7 to complete the production of the assembled battery 28.

(作用)
次に、本実施形態の集合電池28の作用等について説明する。
(Function)
Next, the operation and the like of the assembled battery 28 of the present embodiment will be described.

本実施形態の集合電池28では、二次電池1の外周側面にスペーサ4aが配置されており、個縛済電池5cの固定接着面6c、6dが平面状とされている。このため、固定接着面6c、6dを個縛済電池5c同士の固定面とすることができるので、二次電池1の組立性を向上させることができる。また、スペーサ4aが板状の形状を有していると共にスペーサ4a及び絶縁チューブ9が共に合成樹脂製で軽量のため、スペーサ4aが占める体積、重量の増加を抑制できるので、集合電池28の体積、重量効率を向上させることができる。更に、複雑でコスト高となる電池ホルダが不要となるので、集合電池28の低コスト化を図ることができる。   In the assembled battery 28 of this embodiment, the spacer 4a is arrange | positioned at the outer peripheral side surface of the secondary battery 1, and the fixed adhesion surfaces 6c and 6d of the individually bound battery 5c are planar. For this reason, since the fixed adhesion surfaces 6c and 6d can be used as a fixed surface between the bound batteries 5c, the assemblability of the secondary battery 1 can be improved. Further, since the spacer 4a has a plate-like shape and the spacer 4a and the insulating tube 9 are both made of synthetic resin and light in weight, an increase in the volume and weight occupied by the spacer 4a can be suppressed. , Weight efficiency can be improved. Furthermore, since the battery holder which is complicated and expensive is unnecessary, the cost of the assembled battery 28 can be reduced.

また、本実施形態の集合電池28では、集合電池28をリサイクルするために解体する場合や、直並列接続に変更がある場合に、熱収縮チューブ9を破断するだけで、簡単に解体することができる。また、スペーサ4aは、解体作業後に繰り返し利用することができるので、リサイクル性に優れた集合電池28とすることができる。   Further, in the assembled battery 28 of the present embodiment, when the assembled battery 28 is disassembled for recycling or when the series-parallel connection is changed, the heat-shrinkable tube 9 can be simply disassembled by simply breaking. it can. Moreover, since the spacer 4a can be repeatedly used after the dismantling operation, the assembled battery 28 having excellent recyclability can be obtained.

更に、本実施形態の集合電池28では、スペーサ4a及び二次電池1を被覆するために、熱収縮チューブ9が用いられている。このため、熱収縮チューブ9を加熱して収縮させることで、二次電池1とスペーサ4aとを一体とすることができるので、更に組立性を向上させることができる。また、スペーサ4a及び熱収縮チューブ9が合成樹脂製とされているため、各二次電池1同士を絶縁することができる。   Furthermore, in the assembled battery 28 of this embodiment, the heat shrinkable tube 9 is used to cover the spacer 4a and the secondary battery 1. For this reason, since the secondary battery 1 and the spacer 4a can be united by heating and shrinking the heat-shrinkable tube 9, assembly property can be further improved. Moreover, since the spacer 4a and the heat shrinkable tube 9 are made of synthetic resin, the secondary batteries 1 can be insulated from each other.

また更に、本実施形態の集合電池28では、スペーサ4aの二次電池1の外周側面に接する面に円弧状窪み24aが形成されている。このため、組立時に二次電池1とスペーサ4aとの一体化を容易かつ確実に行うことができる。   Furthermore, in the assembled battery 28 of the present embodiment, an arcuate recess 24a is formed on the surface of the spacer 4a that contacts the outer peripheral side surface of the secondary battery 1. For this reason, the secondary battery 1 and the spacer 4a can be integrated easily and reliably at the time of assembly.

そして、本実施形態の集合電池28では、各二次電池1を固定接着面6c、6dで接着した後、正、負極端子に接続ブスバ7をスポット溶接し直列接続するため、接続作業が容易となる。   And in the assembled battery 28 of this embodiment, since each secondary battery 1 is adhere | attached by the fixed adhesion | attachment surfaces 6c and 6d, since the connection bus bar 7 is spot-welded and connected in series to a positive / negative electrode terminal, connection work is easy. Become.

なお、本実施形態では、固定接着面6c、6dが平面状とされ個縛済電池5c同士の固定面とされている例を示したが、少なくとも固定接着面6cが平面状とされていれば、2個の二次電池1を組み合わせることができる。   In the present embodiment, the fixed adhesive surfaces 6c and 6d are flat and the fixed surfaces of the bound batteries 5c are shown. However, if at least the fixed adhesive surface 6c is flat. Two secondary batteries 1 can be combined.

また、本実施形態では、8個の二次電池1が組み合わされ直列に接続された集合電池28を例示したが、二次電池1の組み合わせ及び接続はこれらに限定されず、例えば、2個の二次電池1を並列接続し、並列接続した電池を8個直列に接続するようにしてもよい。   Further, in the present embodiment, the assembled battery 28 in which the eight secondary batteries 1 are combined and connected in series is illustrated, but the combination and connection of the secondary batteries 1 are not limited to these, for example, two batteries The secondary batteries 1 may be connected in parallel, and eight batteries connected in parallel may be connected in series.

(第2実施形態)
次に、本発明を集合電池に適用した第2の実施の形態について説明する。本実施形態では、二次電池1の外周側面の反対側面に第1実施形態に示したスペーサ4aと同形状のスペーサ14aを更に配置し絶縁チューブ9で被覆して個縛済電池とするものである。なお、本実施形態以降の実施形態において、上述した第1実施形態と同一の部材には同一の符号を付してその説明を省略し、異なる箇所のみ説明する。
(Second Embodiment)
Next, a second embodiment in which the present invention is applied to an assembled battery will be described. In the present embodiment, a spacer 14a having the same shape as the spacer 4a shown in the first embodiment is further arranged on the opposite side of the outer peripheral side surface of the secondary battery 1 and is covered with an insulating tube 9 to form an individual battery. is there. In the following embodiments, the same members as those in the first embodiment described above are denoted by the same reference numerals, description thereof is omitted, and only different portions will be described.

図4に示すように、本実施形態の集合電池8は、1行4列に配設された4個の個縛済電池5aを備えている。   As shown in FIG. 4, the assembled battery 8 of the present embodiment includes four individually bound batteries 5 a arranged in one row and four columns.

図5に示すように、個縛済電池5aは、二次電池1の外周側面の反対側面にスペーサ14aが更に配置されており、スペーサ4a、14aを介して二次電池1が熱収縮チューブ9に被覆されて個縛、密着されている。このため、個縛済電池5aは、スペーサ4a、14aの二次電池1に接する面のそれぞれ対面に平面状の固定接着面6aを有している。個縛済電池5aは、隣接する二次電池1の正、負極端子が上下方向を交互にして固定接着面6a同士が接着され一列に組み合わされている。すなわち、固定接着面6aは、個縛済電池5a同士の固定面となる。   As shown in FIG. 5, in the individual battery 5a, a spacer 14a is further arranged on the opposite side of the outer peripheral side surface of the secondary battery 1, and the secondary battery 1 is connected to the heat shrinkable tube 9 via the spacers 4a and 14a. Covered individually and tied tightly. For this reason, the individual bound battery 5a has a flat fixed adhesive surface 6a on each side of the surfaces of the spacers 4a and 14a that are in contact with the secondary battery 1. In the bound battery 5a, the positive and negative terminals of the adjacent secondary battery 1 are combined in a line by adhering the fixed adhesive surfaces 6a with the vertical direction alternately. That is, the fixed adhesive surface 6a is a fixed surface between the individually bound batteries 5a.

二次電池1の外周側面と反対側面に、スペーサ4a、14aを配設し、熱収縮チューブ9で二次電池1及びスペーサ4a、14aを被覆する。次に、熱収縮チューブ5aを熱収縮させて二次電池1及びスペーサ4a、14aを個縛、密着する。これにより、個縛済電池5aが作製される。   Spacers 4 a and 14 a are disposed on the side opposite to the outer peripheral side surface of the secondary battery 1, and the secondary battery 1 and the spacers 4 a and 14 a are covered with the heat shrinkable tube 9. Next, the heat-shrinkable tube 5a is heat-shrinked so that the secondary battery 1 and the spacers 4a and 14a are tied and adhered. Thereby, the individual bound battery 5a is produced.

複数の個縛済電池5aを作製した後、接着される個縛済電池5a同士の一方の固定接着面6aに接着剤を塗布した後、固定治具中に隣接する電池の上下を逆にして挿入し、固定接着面6a同士を接着して個縛済電池5aを組み合わせ、接続ブスバ7を接続し集合電池8を作製する。   After producing a plurality of individually bound batteries 5a, an adhesive is applied to one fixed adhesive surface 6a of the individually bound batteries 5a to be bonded, and then the adjacent batteries in the fixing jig are turned upside down. Then, the fixed adhesive surfaces 6a are bonded together to combine the individually bound batteries 5a, and the connection bus bar 7 is connected to produce the assembled battery 8.

本実施形態の集合電池8では、二次電池1のスペーサ4aが配置された外周側面の反対側面に、スペーサ14aが配置されている。このため、それぞれスペーサ4a、14aの固定接着面6aで個縛済電池5a同士を接着して組み合わせることができる。固定接着面6aが固定接着面6dより大きく接合力が大きいので、振動等の外力に強い集合電池8とすることができる。   In the assembled battery 8 of this embodiment, the spacer 14a is arrange | positioned on the opposite side surface of the outer peripheral side surface where the spacer 4a of the secondary battery 1 is arrange | positioned. For this reason, the individually bound batteries 5a can be bonded and combined with each other at the fixed adhesive surfaces 6a of the spacers 4a and 14a. Since the fixed adhesive surface 6a is larger than the fixed adhesive surface 6d and the bonding force is large, the assembled battery 8 that is resistant to external forces such as vibration can be obtained.

なお、上記(第1、第2)実施形態では、二次電池1に接する面が円弧状のスペーサ4a(14a)を用いる例を示したが、図8(A)、(B)に示すように、二次電池1の外周側面に接する面に位置決めするための略コ字状窪み24bが形成された合成樹脂製で板状のスペーサ4bを二次電池1あたり1個又は2個用いるようにしてもよい。例えば、図7(A)、(B)に示すように、二次電池1の外周側面にスペーサ4bが配置されており、この外周側面の反対側面にスペーサ4bと同形状のスペーサ14bが配置された個縛済電池5bを構成してもよい。図6に示すように、個縛済電池5bは、外側面に2個の略矩形平面状の固定接着面6bを有している。このため、固定接着面6bで個縛済電池5bを組み合わせることができると共に、スペーサ4a、14aを用いる場合に比べスペーサの重量を低減させることができるので、集合電池8の重量効率を更に向上させることができる。   In the above (first and second) embodiments, the example in which the spacer 4a (14a) whose surface in contact with the secondary battery 1 is arc-shaped is shown, but as shown in FIGS. 8 (A) and 8 (B). In addition, one or two plate-like spacers 4b made of synthetic resin in which a substantially U-shaped depression 24b for positioning on a surface in contact with the outer peripheral side surface of the secondary battery 1 is formed per secondary battery 1 are used. May be. For example, as shown in FIGS. 7A and 7B, a spacer 4b is arranged on the outer peripheral side surface of the secondary battery 1, and a spacer 14b having the same shape as the spacer 4b is arranged on the opposite side surface of the outer peripheral side surface. Alternatively, the tied battery 5b may be configured. As shown in FIG. 6, the bound battery 5b has two substantially rectangular planar fixed adhesive surfaces 6b on the outer surface. For this reason, the individually bound battery 5b can be combined with the fixed adhesive surface 6b, and the weight of the spacer can be reduced as compared with the case where the spacers 4a and 14a are used. Therefore, the weight efficiency of the assembled battery 8 is further improved. be able to.

また、本実施形態では、二次電池1の外周側面及び反対側面に同形状のスペーサ4a、14aが配設される例を示したが、反対側面にスペーサ4bを配置するようにしても同様に個縛済電池を組み合わせることができる。   Further, in the present embodiment, the example in which the spacers 4a and 14a having the same shape are disposed on the outer peripheral side surface and the opposite side surface of the secondary battery 1 is shown, but similarly, the spacer 4b may be disposed on the opposite side surface. Individually bound batteries can be combined.

(第3実施形態)
本実施形態では、図9に示すように、スペーサ4a、14aを用いる代わりに断面略矩形状の枠6eが用いられている。個縛済電池5dは、枠6e内に二次電池1が装入されている。個縛済電池5dの外面には、4個の平面状の固定接着面6eが形成されている。
(Third embodiment)
In this embodiment, as shown in FIG. 9, a frame 6e having a substantially rectangular cross section is used instead of using the spacers 4a and 14a. In the individually bound battery 5d, the secondary battery 1 is inserted in the frame 6e. Four planar fixed adhesive surfaces 6e are formed on the outer surface of the individually bound battery 5d.

本実施形態の集合電池では、個縛済電池5dは枠6e内に二次電池1が装入されて構成されている。このため、熱収縮チューブ9を熱収縮させる必要がないので、熱硬化時間が不要となるため、更に組立性を向上させることができる。   In the assembled battery of the present embodiment, the individually bound battery 5d is configured by inserting the secondary battery 1 into a frame 6e. For this reason, since it is not necessary to heat-shrink the heat-shrinkable tube 9, a heat curing time is not required, so that the assemblability can be further improved.

また、本実施形態の集合電池では、個縛済電池5dの外面に4個の平面状の固定接着面6eを有している。このため、個縛済電池5dを一方向だけでなく二方向に配列して組み合わせることができると共に、第2実施形態と同様に固定接着面6eが固定接着面6dより大きく接合力が大きいので、振動等の外力に強い集合電池とすることができる。   Moreover, in the assembled battery of this embodiment, it has the four planar fixed adhesion surfaces 6e on the outer surface of the bound battery 5d. For this reason, it is possible to arrange the combined batteries 5d not only in one direction but also in two directions and combine them, and the fixed adhesive surface 6e is larger than the fixed adhesive surface 6d and has a larger bonding force as in the second embodiment. The assembled battery can withstand external forces such as vibration.

更に、本実施形態の集合電池では、二次電池1あたり1個の枠6eで個縛済電池5dが構成されている。このため、二次電池1あたりの部材数を減少させることができるため、コストを低減させることができる。   Furthermore, in the assembled battery according to the present embodiment, the single battery 6d is constituted by one frame 6e per secondary battery 1. For this reason, since the number of members per secondary battery 1 can be reduced, cost can be reduced.

(第4実施形態)
本実施形態では、図10に示すように、集合電池38が、2行4列に配設された8個の個縛済電池5eを備えている。
(Fourth embodiment)
In the present embodiment, as shown in FIG. 10, the assembled battery 38 includes eight individually bound batteries 5e arranged in two rows and four columns.

図11に示すように、二次電池1の外周側面に沿うように断面形状が略三角形をなす柱状の合成樹脂製スペーサ4eを配置し、熱収縮チューブ9で二次電池1及びスペーサ4eを被覆する。次に、熱収縮チューブ9を熱収縮させて二次電池1及びスペーサ4eを個縛、密着する。これにより、個縛済電池5eが作製される。   As shown in FIG. 11, columnar synthetic resin spacers 4 e having a substantially triangular cross section are arranged along the outer peripheral side surface of the secondary battery 1, and the secondary battery 1 and the spacer 4 e are covered with the heat shrinkable tube 9. To do. Next, the heat-shrinkable tube 9 is heat-shrinked so that the secondary battery 1 and the spacer 4e are tied and adhered. Thereby, the individually bound battery 5e is produced.

従って、本実施形態では、スペーサ4e、二次電池1の外周側面に接する面に、二次電池1の位置決めをするための円弧状窪み24eが形成されている。個縛済電池5eは、このスペーサ4eと熱収縮チューブ9により、この外周延長部に2個の平面状の固定接着面6fを有している。   Therefore, in the present embodiment, the arcuate recess 24e for positioning the secondary battery 1 is formed on the spacer 4e and the surface in contact with the outer peripheral side surface of the secondary battery 1. The individually bound battery 5e has two planar fixed adhesive surfaces 6f on the outer peripheral extension portion by the spacer 4e and the heat shrinkable tube 9.

個縛済電池5eは、隣接する二次電池1の正、負極端子が上下方向を交互に隣接し、固定接着面6fは一方の行を成す二次電池の固定接着面6fとが相対するよう配置される。この配置作業時には相対する固定接着面6fに接着剤を塗布しておき、固定治具に配列保持して固定接着する。固定接着完了後、二次電池1の正、負極端子は、板状の金属製接続ブスバ7で隣接する二次電池の異極同士を接続し、二次電池1全体として直列に接続して集合電池38を完成させる。   In the bound battery 5e, the positive and negative terminals of the adjacent secondary battery 1 are alternately adjacent in the vertical direction, and the fixed adhesive surface 6f is opposed to the fixed adhesive surface 6f of the secondary battery forming one row. Be placed. At the time of this arrangement work, an adhesive is applied to the opposing fixed adhesive surface 6f, and is held in an array on a fixing jig and fixed and bonded. After fixing and bonding, the positive and negative terminals of the secondary battery 1 are assembled by connecting the different polarities of adjacent secondary batteries with a plate-shaped metal connection bus bar 7 and connecting them in series as the entire secondary battery 1. The battery 38 is completed.

図10に示すように、本実施形態では、固定接着面6fが集合電池38の内部空間に位置するため、さらに集合電池38の小型化が実現できる。   As shown in FIG. 10, in the present embodiment, the fixed adhesive surface 6 f is located in the internal space of the assembled battery 38, so that the assembled battery 38 can be further downsized.

(第5実施形態)
本実施形態では、二次電池1の外周側面の反対側面に第4実施形態に示したスペーサ4eと同形状のスペーサ14eを更に配置し絶縁チューブ9で被覆して個縛済電池とするものである。なお、本実施形態において、上述した第4実施形態と同一の部材には同一の符号を付してその説明を省略し、異なる箇所のみ説明する。
(Fifth embodiment)
In the present embodiment, a spacer 14e having the same shape as the spacer 4e shown in the fourth embodiment is further arranged on the opposite side of the outer peripheral side surface of the secondary battery 1 and covered with an insulating tube 9 to form an individual battery. is there. In the present embodiment, the same members as those in the fourth embodiment described above are denoted by the same reference numerals, the description thereof is omitted, and only different portions will be described.

図12に示すように、本実施形態の集合電池48は、3行3列に配設された6個の個縛済電池5eと3個の個縛済電池5fを備えている。   As shown in FIG. 12, the assembled battery 48 of the present embodiment includes six individually bound batteries 5e and three individually bound batteries 5f arranged in 3 rows and 3 columns.

図13に示すように、個縛済電池5fは、二次電池1の外周側面の反対側面にスペーサ14eが更に配置されており、スペーサ4e、14eを介して二次電池1を熱収縮チューブ9で被覆した後、熱収縮させて個縛、密着させる。このため、個縛済電池5fは、スペーサ4e、14eおよび熱収縮チューブ9にて、この二次電池1の外周延長部に4個の平面状の固定接着面6gを有している。   As shown in FIG. 13, in the individual battery 5f, a spacer 14e is further disposed on the side surface opposite to the outer peripheral side surface of the secondary battery 1, and the secondary battery 1 is connected to the heat-shrinkable tube 9 via the spacers 4e and 14e. After covering with, heat shrink to tie up and stick. For this reason, the individually bound battery 5f has four flat fixed adhesive surfaces 6g on the outer peripheral extension of the secondary battery 1 by the spacers 4e and 14e and the heat shrinkable tube 9.

個縛済電池5eは、隣接する二次電池1の正、負極端子が上下方向を交互に配置し、次いで隣の行を成す個縛済電池5fも同様に正、負極端子が上下方向で交互となるよう配置した後、再度、個縛済電池5eを上記同様に配置して第3の行を構成する。このとき、固定接着面6gと固定接着面6fが相対する面にはあらかじめ接着剤を塗布しておき、固定治具に配列保持して固定接着を完了させる。なお、この配置順番は一例であり、この配置順番に従わなくても集合電池48を作製できることは云うまでもない。   In the individually bound battery 5e, the positive and negative terminals of the adjacent secondary battery 1 are alternately arranged in the vertical direction, and in the same way, the individual battery 5f in the adjacent row is also alternately positive and negative in the vertical direction. Then, again, the individually bound batteries 5e are arranged in the same manner as described above to constitute the third row. At this time, an adhesive is applied in advance to the surface where the fixed adhesive surface 6g and the fixed adhesive surface 6f face each other, and the fixed adhesive is completed by being held in an array on a fixing jig. Note that this arrangement order is merely an example, and it goes without saying that the assembled battery 48 can be manufactured without following this arrangement order.

これら固定接着面6gと固定接着面6fの対面は個縛済電池5eおよび個縛済電池5fの固定面となる。固定接着完了後、二次電池1の正、負極端子は、板状の金属製接続ブスバ7で隣接する二次電池の異極同士を接続し、二次電池1全体として直列に接続して集合電池48を完成させる。   The opposite surfaces of the fixed adhesive surface 6g and the fixed adhesive surface 6f are fixed surfaces of the individually bound battery 5e and the individually bound battery 5f. After fixing and bonding, the positive and negative terminals of the secondary battery 1 are assembled by connecting the different polarities of adjacent secondary batteries with a plate-shaped metal connection bus bar 7 and connecting them in series as the entire secondary battery 1. The battery 48 is completed.

本実施形態の集合電池48では、二次電池1のスペーサ4eが配置された外周側面の反対側面に、スペーサ14eが配置されている。このため、それぞれスペーサ4e、14eの固定接着面6f、6gで個縛済電池5e、個縛済電池5fを接着して組み合わせることができる。また、固定接着面6f、6gが集合電池48の内部空間に位置するため、3行以上の集合電池の小型化が実現できる。   In the assembled battery 48 of this embodiment, the spacer 14e is arrange | positioned on the opposite side surface of the outer peripheral side surface where the spacer 4e of the secondary battery 1 is arrange | positioned. For this reason, the individually bound battery 5e and the individually bound battery 5f can be bonded and combined with the fixed adhesive surfaces 6f and 6g of the spacers 4e and 14e, respectively. Further, since the fixed adhesive surfaces 6f and 6g are located in the internal space of the assembled battery 48, it is possible to reduce the size of the assembled battery of three or more rows.

本発明は組立性及び体積、重量効率に優れた集合電池を提供し、集合電池の製造、販売に寄与するため、産業上の利用可能性を有する。   The present invention provides an assembled battery excellent in assemblability, volume and weight efficiency and contributes to the manufacture and sale of the assembled battery, and thus has industrial applicability.

本発明が適用可能な第1実施形態の集合電池を示し、(A)は平面図、(B)は正面図である。The assembled battery of 1st Embodiment which can apply this invention is shown, (A) is a top view, (B) is a front view. 第1実施形態の個縛済電池を示し、(A)は平面図、(B)は正面図である。1 shows an individual-bound battery according to a first embodiment, where (A) is a plan view and (B) is a front view. 第1実施形態の個縛済電池のスペーサを示し、(A)は平面図、(B)は正面図である。The spacer of the bound battery of 1st Embodiment is shown, (A) is a top view, (B) is a front view. 第2実施形態の集合電池を示し、(A)は平面図、(B)は正面図である。The assembled battery of 2nd Embodiment is shown, (A) is a top view, (B) is a front view. 第2実施形態の個縛済電池を示し、(A)は平面図、(B)は正面図である。FIG. 2 shows an individually bound battery according to a second embodiment, wherein (A) is a plan view and (B) is a front view. 本発明が適用可能な他の実施形態の集合電池を示し、(A)は平面図、(B)は正面図である。The assembled battery of other embodiment which can apply this invention is shown, (A) is a top view, (B) is a front view. 他の実施形態の個縛済電池を示し、(A)は平面図、(B)は正面図である。The bound battery of other embodiment is shown, (A) is a top view, (B) is a front view. 他の実施形態の個縛済電池のスペーサを示し、(A)は平面図、(B)は正面図である。The spacer of the bound battery of other embodiment is shown, (A) is a top view, (B) is a front view. 第3実施形態の個縛済電池を示し、(A)は平面図、(B)は正面図である。The individually bound battery of 3rd Embodiment is shown, (A) is a top view, (B) is a front view. 第4実施形態の集合電池の平面図である。It is a top view of the assembled battery of 4th Embodiment. 第4実施形態の個縛済電池の分解斜視図である。It is a disassembled perspective view of the individually bound battery of 4th Embodiment. 第5実施形態の集合電池の平面図である。It is a top view of the assembled battery of 5th Embodiment. 第5実施形態の個縛済電池の分解斜視図である。It is a disassembled perspective view of the individually tied battery of 5th Embodiment.

符号の説明Explanation of symbols

1 円筒型リチウムイオン二次電池(円柱状電池)
4a、4b、4e スペーサ(第1のスペーサ)
14a、14b、14e スペーサ(第2のスペーサ)
4d 枠
5a、5b、5c、5d、5e、5f 個縛済電池
6a、6b、6c、6d、6e、6f、6g 固定接着面(固定面)
9 熱収縮チューブ(筒状体)
24a、24b、24c、24d 窪み
8、18、28、38、48 集合電池
1 Cylindrical lithium ion secondary battery (cylindrical battery)
4a, 4b, 4e Spacer (first spacer)
14a, 14b, 14e Spacer (second spacer)
4d Frame 5a, 5b, 5c, 5d, 5e, 5f Individual battery 6a, 6b, 6c, 6d, 6e, 6f, 6g Fixed adhesive surface (fixed surface)
9 Heat shrinkable tube (cylindrical body)
24a, 24b, 24c, 24d Indentation 8, 18, 28, 38, 48 Collective battery

Claims (7)

正極、負極の間にセパレータを介在させた電極群と電解液とを円筒容器に収容した円柱状電池を複数個組み合わせた集合電池において、前記円柱状電池の外周側面に、この外周側面に接する一面以外の対面が平面状の第1のスペーサが配置されており、前記第1のスペーサは前記外周側面に接する面が1面のみで構成されているとともに前記対面がすべて平面であり、前記円柱状電池は少なくとも前記対面が固定面とされ組み合わされたことを特徴とする集合電池。 In an assembled battery in which a plurality of columnar batteries each containing an electrode group in which a separator is interposed between a positive electrode and a negative electrode and an electrolytic solution are contained in a cylindrical container, the outer peripheral side surface of the cylindrical battery is in contact with the outer peripheral side surface. A first spacer having a planar shape other than the first spacer is disposed, and the first spacer is composed of only one surface in contact with the outer peripheral side surface, and all the facing surfaces are planar. An assembled battery, wherein the battery is combined with at least the facing surface as a fixed surface. 前記円柱状電池の前記第1のスペーサが配置された外周側面の反対側面に、この反対側面に接する一面以外の複数の対面が平面状の第1のスペーサと同形状の第2のスペーサが更に配置されており、前記円柱状電池は更に前記第2のスペーサの対面が固定面とされ組み合わされたことを特徴とする請求項1に記載の集合電池。   A second spacer having the same shape as the first spacer having a plurality of opposite surfaces other than one surface in contact with the opposite side surface is further provided on the opposite side surface of the outer peripheral side surface where the first spacer of the cylindrical battery is disposed. The assembled battery according to claim 1, wherein the cylindrical battery is combined with the second spacer facing the fixed surface as a fixed surface. 前記第1のスペーサは、断面略コ字状であり、前記円柱状電池の外周側面に接する面に前記円柱状電池の位置決めするための窪みが形成されたことを特徴とする請求項1又は請求項2に記載の集合電池。   2. The first spacer according to claim 1, wherein the first spacer has a substantially U-shaped cross section, and a recess for positioning the cylindrical battery is formed on a surface in contact with an outer peripheral side surface of the cylindrical battery. Item 3. The assembled battery according to Item 2. 前記第1のスペーサは断面略矩形状の枠であり、前記枠に前記円柱状電池が装入されたことを特徴とする請求項1に記載の集合電池。   The assembled battery according to claim 1, wherein the first spacer is a frame having a substantially rectangular cross section, and the cylindrical battery is inserted into the frame. 前記第1のスペーサは断面略三角形状であり、前記円柱状電池の外周側面に接する面に窪みが形成され、前記円柱状電池は前記窪みが形成された面以外の2面のうち少なくとも1面が固定面とされ組み合わされたことを特徴とする請求項1に記載の集合電池。   The first spacer has a substantially triangular cross section, and a recess is formed on a surface in contact with an outer peripheral side surface of the cylindrical battery, and the cylindrical battery has at least one of two surfaces other than the surface where the recess is formed. The assembled battery according to claim 1, wherein the fixed surfaces are combined. 前記円柱状電池の前記第1のスペーサが配置された外周側面の反対側面に、前記第1のスペーサと同形状の第2のスペーサが更に配置されており、前記円柱状電池は更に前記第2のスペーサの窪みが形成された面以外の2面のうち少なくとも1面が固定面とされ組み合わされたことを特徴とする請求項5に記載の集合電池。   A second spacer having the same shape as the first spacer is further disposed on the side surface of the cylindrical battery opposite to the outer peripheral side surface on which the first spacer is disposed, and the cylindrical battery further includes the second spacer. The assembled battery according to claim 5, wherein at least one of the two surfaces other than the surface on which the spacer recess is formed is combined as a fixed surface. 前記スペーサ及び前記円柱状電池は、熱収縮した筒状体で被覆されたことを特徴とする請求項1乃至請求項6のいずれか1項に記載の集合電池。   The assembled battery according to claim 1, wherein the spacer and the cylindrical battery are covered with a heat-shrinkable cylindrical body.
JP2004116293A 2003-04-17 2004-04-12 Battery Expired - Fee Related JP4590910B2 (en)

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JPH08106888A (en) * 1994-09-30 1996-04-23 Kenwood Corp Combination battery, and structure of battery holder for equipment
JPH09147819A (en) * 1995-11-24 1997-06-06 Kokusai Electric Co Ltd Battery pack unit

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08106888A (en) * 1994-09-30 1996-04-23 Kenwood Corp Combination battery, and structure of battery holder for equipment
JPH09147819A (en) * 1995-11-24 1997-06-06 Kokusai Electric Co Ltd Battery pack unit

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