JP4590336B2 - Fuel gas purification equipment - Google Patents

Description

  The present invention relates to a fuel gas purification facility that removes impurities from a raw material gas to obtain a fuel gas.

  In recent years, there has been a demand for effective use of resources and reduction of waste, and it is considered to use biomass partial combustion gas and waste partial combustion gas as fuel gas. Since various fuel gases contain impurities that affect the environment, a technology for refining fuel gas with improved quality by removing multi-component impurities has been conventionally proposed (for example, Patent Document 1). 2).

For example, Patent Document 1 proposes a method and apparatus for recycling organic waste that removes impurities in the reducing gas using wet gas purification. That is, the technique disclosed in Patent Document 1 is based on the removal of water-soluble acidic gas and dust by a scrubber using an alkaline cleaning liquid, the conversion of CO into H ₂ by a CO conversion device (catalytic reactor), and the wet desulfurization device. A process of removing H ₂ S and CO ₂ is provided. In this technique, a fuel gas having a composition suitable for ammonia synthesis is obtained from a waste gasifier for an ammonia synthesis process containing H ₂ .

  Patent Document 2 proposes a gas purification method and gas purification equipment for removing impurities in the reducing gas. That is, the technique disclosed in Patent Document 2 is a technique for removing hydrogen chloride and ammonia contained in the coal gasification gas as solids by an ammonium chloride purification reaction at a low temperature. This technology makes it possible to apply coal gasification gas as fuel gas.

  On the other hand, as an exhaust gas treatment apparatus that removes multi-component impurities that affect the environment from exhaust gas that is released into the atmosphere, for example, a technique that explicitly describes dust removal and impurity removal (Patent Document 3). Patent Document 4 and Patent Document 5) are known. In the field of exhaust gas treatment, since the first purpose is that specific components are not discharged into the environment, technical ideas differ with respect to fuel gas purification, which is the quality of the gas after treatment.

Japanese Patent Laid-Open No. 10-236801 JP-A-11-57402 JP 2002-13311 A JP 2002-210328 A JP 2001-137663 A

  In the field of refining fuel gas, it is possible to obtain a fuel gas from which impurities affecting the environment have been removed. However, it is possible to reduce the use and disposal amount of the impurity remover and to recycle combustible impurities. No consideration is given to obtaining a fuel gas from which impurities are removed to the maximum by using a small amount of impurity removing agent, such as repeatedly using resources used for the impurity removing agent.

  The present invention has been made in view of the above situation, and an object of the present invention is to provide a fuel gas refining facility capable of obtaining a fuel gas from which impurities are removed to the maximum by using a small amount of impurity removing agent.

In order to achieve the above object, the fuel gas purification facility of the present invention according to claim 1 absorbs the raw material gas obtained by the raw material gas supply means and the raw material gas supply means for obtaining the raw material gas by partially burning the fuel. The first impurity fixing means for fixing the pyrolyzable impurities of the raw material gas by blowing the adsorbent, and the thermal decomposable impurities fixed to the adsorbent by the first impurity fixing means are physically absorbed together with the adsorbent. The first physical removal means to be removed by simple filtration and the thermally decomposable impurities that have been absorbed and adsorbed by the absorbent / adsorbent and recovered by the first physical removal means are put together with the absorbent / adsorbent into the raw material gas supply means. Re-input means, second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means, and second impurity fixing means With absorbent A second physical removal means for removing the fixed hydrogen halide together with the absorbent by physical filtration; and a reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility. was it it said.

In the present invention according to claim 1, the thermally decomposable impurities recovered by the first physical removal means are reintroduced into the raw material gas supply means to recycle the combustible impurities, and recovered by the second physical removal means. The absorbed absorbent is transported to a reprocessing facility so that the resources used for the impurity remover can be used repeatedly, and the amount of impurities removed and the amount of waste are reduced. Obtain the removed fuel gas.

The fuel gas purification facility of the present invention according to claim 2 is the fuel gas purification facility according to claim 1, wherein the absorbent that is blown by the second impurity fixing means is reprocessed by the reprocessing means. it characterized in that it is.

In this invention which concerns on Claim 2, the absorber used for the impurity removal agent collect | recovered by the 2nd physical removal means can be repeatedly used in an installation.

Further, the fuel gas purification facility of the present invention according to claim 3 is the fuel gas purification facility according to claim 1 or 2, wherein the fuel gas purification facility of the present invention is a derivation means for detecting the halogen concentration in the raw material gas sent to the second impurity fixing means. you characterized with an adjusting means for adjusting the blowing amount of the absorbent in accordance with the status of the detected halogen concentration in deriving means.

With the present invention according to claim 3, it is possible to appropriately adjust the blowing amount of the absorbent in accordance with the halogen concentration in the raw material gas fed to the second impurity fixing means.

Moreover, the fuel gas purification equipment of this invention which concerns on Claim 4 is a fuel gas purification equipment as described in any one of Claims 1-3 . The raw material from which the hydrogen halide was removed by the 2nd physical removal means gas is fed, you comprising the suction removal means having a solid adsorbent for adsorbing heavy metals in the feed gas.

In the present invention according to claim 4, heavy metals in the raw material gas can be removed.

Moreover, the fuel gas purification equipment of this invention which concerns on Claim 5 is a fuel gas purification equipment as described in any one of Claims 1-3. WHEREIN: A sulfur compound is injected by blowing an impurity removal agent in a raw material gas supply means. it comprising the furnace desulfurization means for discharging with the slag.

In this invention which concerns on Claim 5, a sulfur compound can be discharged | emitted from a raw material gas supply means with slag.

Moreover, the fuel gas purification equipment of this invention which concerns on Claim 6 was equipped with the sulfur conversion means which removes an organic sulfur compound in the fuel gas purification equipment as described in any one of Claims 1-3. It shall be the.

In this invention which concerns on Claim 6, an organic sulfur compound can be removed.

The fuel gas purification facility of the present invention according to claim 7 is the fuel gas purification facility according to any one of claims 1 to 3 , wherein the hydrogen halide is removed by the second physical removal means. from the gas, you comprising the precision removal means for more precisely remove the hydrogen halide.

In the present invention according to claim 7, hydrogen halide can be precisely removed.

In order to achieve the above object, the fuel gas purification facility of the present invention according to claim 8 comprises a raw material gas supply means for obtaining a raw material gas by partially burning fuel, and an impurity remover blown into the raw material gas supply means. In-furnace desulfurization means for discharging sulfur compounds together with slag, first impurity fixing means for fixing thermally decomposable impurities in the raw material gas by blowing absorption / adsorbent into the raw material gas obtained by the raw material gas supply means, A first physical removal means for removing thermally decomposable impurities fixed to the absorbent / adsorbent by one impurity fixing means by physical filtration together with the absorbent / adsorbent; and first absorbed and adsorbed by the absorbent / adsorbent Re-introducing means for introducing the thermally decomposable impurities recovered by the physical removing means into the raw material gas supply means together with the absorbent / adsorbent; and the absorbent for the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means Second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing, and second physical removal for removing hydrogen halide fixed to the absorbent by the second impurity fixing means together with the absorbent by physical filtration Means, a reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility, a system for blowing the absorbent reprocessed by the reprocessing means into the second impurity fixing means, raw material gas hydrogen halide is removed by the second physical removal means is sent, it characterized in that a suction removal means having a solid adsorbent for adsorbing heavy metals in the feed gas.

In the present invention according to claim 8, the thermally decomposable impurities recovered by the first physical removal means are reintroduced into the raw material gas supply means to recycle the combustible impurities, and recovered by the second physical removal means. The absorbed absorbent is transported to the reprocessing facility so that the resources used for the impurity removal agent can be used repeatedly in the facility, heavy metals in the raw material gas are removed by adsorption removal means, and sulfur compounds are slag by furnace desulfurization means. At the same time, the fuel gas is discharged from the raw material gas supply means, and the amount of the impurity remover used and discarded is reduced to obtain a fuel gas from which impurities are removed to the maximum by using a small amount of impurity remover.

In order to achieve the above object, the fuel gas refining facility of the present invention according to claim 9 absorbs the raw material gas obtained by the raw material gas supply means obtained by the raw material gas supply means and the raw material gas supply means by partially burning the fuel. The first impurity fixing means for fixing the pyrolyzable impurities of the raw material gas by blowing the adsorbent, and the thermal decomposable impurities fixed to the adsorbent by the first impurity fixing means are physically absorbed together with the adsorbent. The first physical removal means to be removed by simple filtration and the thermally decomposable impurities absorbed and adsorbed by the absorption / adsorbent and recovered by the first physical removal means are put together with the absorption / adsorbent into the raw material gas supply means. Re-input means, second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means, and second impurity fixing means With absorbent A second physical removal means for removing the fixed hydrogen halide together with the absorbent by physical filtration; a reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility; A system for blowing the absorbent reprocessed by the processing means into the second impurity fixing means and a raw material gas from which hydrogen halide has been removed by the second physical removing means are sent to adsorb heavy metals in the raw material gas. a suction removal means having a solid adsorbent, material gas heavy metals have been removed is sent by the suction removal means, you comprising the sulfur conversion means for removing organic sulfur compounds in the feed gas.

In the present invention according to claim 9, the thermally decomposable impurities recovered by the first physical removal means are reintroduced into the source gas supply means to recycle the combustible impurities and recovered by the second physical removal means. The used absorbent is transported to the reprocessing facility so that the resources used for the impurity remover can be used repeatedly in the facility, heavy metals in the raw material gas are removed, organic sulfur compounds are removed, and the use of the impurity remover The fuel gas from which impurities are removed to the maximum is obtained by reducing the amount and waste amount and using a small amount of impurity remover.

In order to achieve the above object, the fuel gas purification facility of the present invention according to claim 10 absorbs the raw material gas obtained by the raw material gas supply means and the raw material gas supply means for obtaining the raw material gas by partially burning the fuel. The first impurity fixing means for fixing the pyrolyzable impurities of the raw material gas by blowing the adsorbent, and the thermal decomposable impurities fixed to the adsorbent by the first impurity fixing means are physically absorbed together with the adsorbent. The first physical removal means to be removed by simple filtration and the thermally decomposable impurities absorbed and adsorbed by the absorption / adsorbent and recovered by the first physical removal means are put together with the absorption / adsorbent into the raw material gas supply means. Re-input means, second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means, and second impurity fixing means Absorbed by A second physical removal means for removing the hydrogen halide fixed to the absorbent together with an absorbent by physical filtration; a reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility; The raw material gas from which hydrogen halide has been removed by the second physical removal means is sent, and the adsorption gas removing means having a solid adsorbent that adsorbs the heavy metal in the raw material gas, and the raw material gas from which the heavy metal has been removed by the adsorption removal means A precise removal means for precisely removing hydrogen halide, and a sulfur conversion means for removing the raw material gas from which the hydrogen halide has been precisely removed by the precise removal means and removing organic sulfur compounds in the raw material gas. was it it said.

In the present invention according to claim 10, the thermally decomposable impurities recovered by the first physical removal means are reintroduced into the raw material gas supply means to recycle the combustible impurities, and recovered by the second physical removal means. The absorbed absorbent is transported to the reprocessing facility so that the resources used for the impurity removal agent can be used repeatedly in the facility, heavy metals in the raw material gas are removed, hydrogen halide is precisely removed, and organic sulfur compounds are removed. Thus, a fuel gas from which impurities are removed to the maximum is obtained by using a small amount of the impurity removing agent by reducing the amount of the impurity removing agent used or discarded.

The fuel gas purification facility of the present invention according to claim 11 is the fuel gas purification facility according to any one of claims 1 to 10, wherein the raw material gas supply means partially burns biomass / waste. it is the biomass / waste gasifier to obtain a raw material gas you characterized.

In this invention which concerns on Claim 11, fuel gas can be refine | purified from the raw material gas obtained by carrying out partial combustion of biomass and a waste material.

The fuel gas purification facility of the present invention according to claim 12 is the fuel gas purification facility according to any one of claims 1 to 11, wherein the fuel gas purification facility is absorbed and adsorbed by the first impurity fixing means on the absorbent / adsorbent. that thermally decomposable impurities, hydrocarbons, you wherein the carbon impurities, organic chlorine compounds, is at least one of the basic gas.

In the present invention according to claim 12, at least one of hydrocarbons, carbon-based impurities, organochlorine compounds, and basic gases can be re-introduced into the raw material gas supply means, and the combustible impurities can be reused.

  The fuel gas purification facility of the present invention can be a fuel gas purification facility capable of obtaining a fuel gas from which impurities are removed to the maximum by using a small amount of impurity removing agent.

  FIG. 1 is a table showing the relationship between the removal target impurities and the impurity removal agent suitable for each recycling technology, and FIGS. 2 to 4 show a schematic system of a fuel gas purification facility according to an embodiment of the present invention. .

  A feature of the fuel gas purification facility of the present invention is a recycle type gas purification facility. That is, not only removing impurities, but also reducing the amount of waste and removal of impurities remover, reusing flammable impurities as fuel, and repeatedly using resources for impurity remover This is a gas refining facility to which recycling technology including recycling is applied.

  In order to realize the above-mentioned recycling-type gas purification equipment, a removal process suitable for recycling technology is constructed by classifying means for removing impurities to be removed from the following viewpoints.

  Non-separation removal: A means of removing impurities that can be reused, reused, or disposed of even when mixed with other impurities that are removed at the same time and does not need to be recovered alone.

  Separation / removal: A means for removing impurities that must be recovered separately from other impurities for reuse, repeated use, and disposal.

Recycling technology for removed impurities or impurity removers Fuel pyrolysis cycle (reuse of fuel components: reuse): Re-injecting unburned components contained in impurities and flammable spent impurity removers into the raw material gas supply device , The fuel utilization rate is improved.

  Thermally decomposable impurity cycle (reduction of the amount of impurities removed: reduction): Impurity remover containing the collected impurities is re-supplied to the raw material gas supply device, and the impurity remover and impurities themselves are thermally decomposed (detoxified) By doing so, the amount of used impurity remover discarded is reduced and the cost of impurity treatment is reduced.

  Impurity remover recycling (repeated use of impurity remover: recycle): By collecting and recycling used impurity remover, the raw material of the absorbent is recycled to reduce the cost of the absorbent and effectively use resources. I am trying.

  Effective use of impurity remover (reduction of use amount of impurity remover: reduce): By supplying an appropriate amount of appropriate impurity remover according to the type and load of impurities, effective use of impurity remover and reduction of use amount At the same time, the amount of waste such as used impurities remover is reduced to reduce the environmental burden.

  The combination of the impurity to be removed and the impurity remover will be described with reference to FIG.

  An example of a specific combination of an impurity to be removed and an impurity removing agent for applying the recycling technique of the impurity removing agent is shown in FIG. FIG. 1 shows a table showing a relationship between combinations of impurities to be removed and impurity removal agents suitable for each recycling technique.

  (1) The fuel pyrolysis cycle is intended for reuse of fuel components, and is non-separation removal that does not separate impurities and impurity removal materials. Removal targets are hydrocarbons (Tar) and carbon-based solid impurities (Char). Impurity removal agents (absorbents and adsorbents) are nonflammable absorbents (inorganic porous materials) and combustible adsorbents (activated carbon powder). used.

(2) The thermal decomposable impurity cycle is intended to reduce the waste amount of the impurity remover, and is non-separation removal that does not separate the impurity and the impurity removal material. The removal target is an organic chlorine compound (DXN) and a basic gas (NH ₃ ), and an incombustible adsorbent (inorganic porous material) or an incombustible adsorbent is used as the impurity remover (absorbent or adsorbent).

  (3) Impurity remover recycling is intended for repeated use of an impurity remover (absorbent). The impurity remover is separated and removed to separate the impurity and the impurity remover, and the separated impurity remover is recycled. The removal target is hydrogen halide (HCl, HF), and an absorbent (Na-based) is blown.

  (4) Effective use of the impurity remover is intended to reduce the amount of the impurity remover (absorbent) used. The impurity remover is separated and removed to separate the impurity remover, and the separated impurity remover is recycled. . The removal target is hydrogen halide (HCl, HF), and an absorbent (Na-based or Ca-based) is blown.

  (5) The effective use of the impurity remover is intended to reduce the cost of the impurity remover (absorbent). The impurity remover is separated and removed to separate the impurity and the impurity remover, and the separated impurity remover is recycled. The removal target is hydrogen halide (HCl, HF), and an absorbent (Na-based and Ca-based) and a molded absorbent (Na-based) are used in combination.

  (6) The separation and removal of heavy metals is intended to reduce the disposal cost of the impurity remover, and fixed bed type means are applied. The object to be removed is heavy metal (Hg), and a solid adsorbent (impregnated activated carbon) is used as a remover.

  A first embodiment of the gas purification facility of the present invention will be described.

  FIG. 2 shows a schematic system of a gas purification facility according to the first embodiment of the present invention. The first embodiment is an example of a gas purification facility for supplying fuel gas obtained from a biomass / waste gasification furnace 1 as a raw material gas supply means to a gas engine 2.

  A feature of the present embodiment is that a recycling type gas purification facility is constructed by combining a technology for simultaneously removing various impurities with a dust removing device as a core and a recycling technology.

  This feature is achieved by removing various flammable or pyrolyzable impurities without separating them by blowing various impurity removers into filtration devices (bag filters and ceramic filters) that are generally used as dust removal devices. This can be achieved by re-introducing the waste gasifier 1 or by providing a separate removal device in the downstream to recycle the impurity remover.

The present embodiment is also characterized in that multi-component impurities derived from various raw materials for producing the raw material gas can be removed at once. In other words, the impurities listed below can be removed at once.
(a) Acid gases such as halides and sulfur compounds
(b) Basic gas such as ammonia
(c) Solid impurities such as dust and blown absorbent
(d) Heavy metals such as heavy metals such as mercury and gaseous compounds containing heavy metals
(e) Organochlorine compounds such as dioxins
(f) Volatile light metals such as alkali metals and alkaline earth metals
(g) Unsaturated hydrocarbons such as tar and aromatic hydrocarbons

  This feature is realized by a combination of a method for adjusting the type and amount of the impurity removing agent blown into the filtration device and various impurity removal devices combined in the downstream of the filtration device.

  The first embodiment will be specifically described below with reference to FIG. In FIG. 2, parenthesized numbers in the recycling technique in FIG. 1 described above are associated with each other.

As shown in the figure, a biomass / waste gasifier 1 is provided as a raw material gas supply means for obtaining raw material gas by partially burning fuel using biomass and waste as fuel. As the raw material gas obtained in the biomass / waste gasifier 1, for example, HCl + HF is 500 ppmv, H ₂ S + COS is 500 ppmv, dust (Ash) + carbon impurities (Char) is 1 g / m ³ N, hydrocarbons ( Tar) is 100 mg / m ³ N, organochlorine compound (DXN) is 10 ng TEQ / m ³ N, heavy metal (Hg) is 100 μg / m ³ N, and basic gas (NH ₃ ) is 1000 ppmv.

The biomass / waste gasification furnace 1 is provided with an in-furnace desulfurization means 3, and sulfur compounds (H ₂ S, COS) are discharged together with slag by blowing an impurity removing agent. The raw material gas obtained in the biomass / waste gasifier 1 is sent to the first impurity fixing means 4, and activated carbon powder and inorganic porous material (adsorbent, absorbent) are blown into the first impurity fixing means 4. In the first impurity fixing means 4, Ash, Char, Tar, DXN, and NH _{3 that} are thermally decomposable impurities are fixed.

A first physical removal means 5 is provided downstream of the first impurity fixing means 4, and Ash, Char, Tar, DXN, NH ₃ fixed to the absorbent / adsorbent by the first impurity fixing means 4 are the first. It is removed by physical filtration together with the absorbent / adsorbent by the physical removing means 5. The Ash, Char, Tar, DXN, and NH ₃ recovered together with the absorbent / adsorbent by the first physical removing means 5 are combined with the absorbent / adsorbent in the biomass / waste gasifier 1 through the circulation path 6 as the re-input means. The fuel component is partially burned again, and the waste amount of the impurity remover is reduced.

The source gas from which the thermally decomposable impurities (Ash, Char, Tar, DXN, NH ₃ ) have been removed by the first physical removing means 5 is sent to the second impurity fixing means 7. The second impurity fixing means 7 is injected with Na-based blowing absorbent, which is an absorbent, Ca-based blowing absorbent, or a mixture of Na-based and Ca-based blowing absorbent, and hydrogen halide (HCl, HF). Is absorbed. The absorbent in which HCl and HF have been absorbed by the second impurity fixing means 7 is sent to the second physical removal means 8, and the absorbent in which HCl and HF have been absorbed is removed by physical filtration.

  The absorbent recovered by the second physical removal means 8 is transported to a reprocessing facility (not shown) by the reprocessing means 11, and the reprocessed absorbent is passed through the second impurity fixing means 7 by the recharging system 12. 2 Blow into the physical removal means 8. That is, the impurity remover can be used repeatedly, the amount of the impurity remover used can be reduced, and the cost of the impurity remover can be reduced.

  It is also possible to detect (derived) the halogen concentration in the raw material gas sent to the second physical removal means 8 and adjust the amount of the absorbent blown based on the detection result. As a result, the absorbent can be used more accurately, and the amount of use and cost can be reduced. When the halogen concentration in the source gas is known in advance, a certain amount of absorbent can be blown. In any case, in order to perform backwashing for removing the blown absorbent deposited on the filter medium, the optimum timing is determined by detecting the pressure difference at the inlet / outlet of the first physical removal means 5.

  The raw material gas from which HCl and HF have been removed by the second physical removal means 8 is sent to the adsorption removal means 13 where heavy metal (Hg) is adsorbed and removed by the impregnated activated carbon that is a solid adsorbent. The raw material gas from which Hg has been removed by the adsorption removing means 13 is made into a fuel gas and supplied to the gas engine 2.

Therefore, combustible impurities such as Tar tar (Tar: hydrocarbons) and char (Char: carbon impurities), and dioxins (DXN: organochlorine compounds) and ammonia (NH ₃ : basic gas) The thermally decomposable impurities are fixed in the first impurity fixing means 4 by an impurity removing agent (activated carbon or the like), removed by the first physical removing means 5 (bag filter), and then returned to the biomass / waste gasifier 1. It is. As a result, combustible impurities such as tar and char can be used as the fuel, so that the reuse of fuel components by the fuel pyrolysis cycle is achieved.

  Further, a pyrolyzable impurity such as dioxins can be pyrolyzed in the biomass / waste gasifier 1 after being immobilized with an impurity remover. In addition, the activated carbon used as a removing agent can be used as a fuel for the biomass / waste gasifier 1. By recycling the removed ash to the biomass / waste gasifier 1, the ash can be discharged as slag, so that the volume of discharged ash can be reduced.

  The fuel gas purification facility described above has the following advantages. In other words, in the removal of dioxins with ordinary activated carbon, since a large amount of activated carbon containing dioxins becomes waste, the treatment cost becomes enormous, and the activated carbon is treated without any effective use. However, there was a difficulty in generating new waste. By using the above-described fuel gas purification equipment, reduction of waste containing dioxins and reuse of impurities remover can be achieved at the same time.

  In the fuel gas purification facility described above, the filtration device is divided into two systems of the first physical removal means 5 and the second physical removal means 8, and the system of the first physical removal means 5 is the above-described system. Removal of flammable impurities and thermally decomposable impurities to achieve a thermally decomposable impurity cycle is performed. The raw material gas that has passed through the first physical removal means 5 includes sulfur compounds generated from the fuel introduced into the biomass / waste gasification furnace 1, halides, and halides generated by the pyrolyzable impurity cycle of dioxins. included.

  Also, regarding the removal of sulfur compounds, a gas engine is discharged from the biomass / waste gasifier 1 together with slag by blowing and fixing a calcium-based impurity remover into the biomass / waste gasifier 1. 2 to a level that does not cause a problem.

  These halides (acid gases) are fixed by blowing an impurity removing agent, and then separated by the second system of the second physical removal means 8 and removed from the source gas. The impurity removing agent in which hydrogen halide is immobilized is recovered, treated at a factory, regenerated as an impurity removing agent, and repeatedly used. As a result, a part of the impurity removing agent is reused, so that repeated use of the impurity removing agent by recycling the absorbent is achieved.

  The fuel gas purification facility described above has the following advantages. In other words, the halide removal method by blowing the calcium-based impurity remover (slaked lime) of the prior art can reduce hydrogen halide only to about 50 ppm, and is applicable to applications such as MCFC requiring a low concentration of 5 ppm or less. could not. In order to remove the halide to 5 ppm, it was necessary to reduce it with a separate removal device in which a fixed sodium bed was filled with an expensive sodium-based absorbent. On the other hand, in the facility of the present embodiment, the halide can be reduced to a concentration of about 5 ppm while a sodium-based absorbent is blown, and a part of the expensive absorbent is recycled. There is a merit that can be used repeatedly. Even if the fixed bed type absorbent is replaced with a batch type, a part of the absorbent can be reused, but the absorbent on the fixed bed outlet side is recycled without being used, so there is a lot of waste of the absorbent. If it is the installation of this embodiment, since the used absorbent can always be recycled, the absorbent can be effectively used.

  Further, in the facility of this embodiment, mercury is separated and removed from other impurities. Thereby, the quantity of the impurity removal agent containing the collected mercury can be reduced as much as possible, and the processing cost can be reduced.

  Next, the second embodiment will be specifically described with reference to FIG. In addition, the same code | symbol is attached | subjected to the member same as the member shown in FIG. 2, and the overlapping description is abbreviate | omitted.

  The fuel gas purification facility shown in FIG. 3 is a recycle type fuel gas purification facility for MCFC, and an example of a fuel gas purification facility for supplying the fuel gas obtained from the biomass / waste gasification furnace 1 to the MCFC 21. It is.

As shown in the figure, in order to reliably remove sulfur compounds, a fixed bed type desulfurization apparatus (conversion desulfurization apparatus) is installed in the downstream of the adsorption removing means 13 instead of the impurity removing agent blowing method. Yes. In other words, in order to remove organic sulfur compounds such as carbonyl sulfide (COS), a desulfurization means is provided which includes a sulfur conversion means 31 for converting a COS to H ₂ S by installing a catalyst upstream, and desulfurizing the converted H ₂ S. 32. The raw material gas from which all sulfur compounds including organic sulfur compounds are removed by the desulfurization means 32 is supplied to the MCFC 21 as fuel gas.

  The fuel gas purification facility of the second embodiment has the following advantages. That is, the removal method by blowing a general calcium-based impurity removing agent (slaked lime) can reduce hydrogen halide only to about 50 ppm, and cannot be applied to applications such as MCFC requiring a low concentration of 5 ppm or less. . In order to remove the halide to 5 ppm, it was necessary to reduce it with a separate removing device in which a fixed sodium bed was filled with an expensive sodium-based absorbent. On the other hand, in the equipment of this embodiment, while a sodium-based absorbent is blown, halide can be reduced to a concentration of about 5 ppm and a part of the expensive absorbent is recycled. There is a merit that can be used repeatedly. Even if the fixed bed type absorbent is replaced with a batch type, a part of the absorbent can be reused, but the absorbent on the fixed bed outlet side is recycled without being used, so there is a lot of waste of the absorbent. If it is the installation of this embodiment, since the used absorbent can always be recycled, the absorbent can be effectively used.

  Next, the third embodiment will be specifically described with reference to FIG. The same members as those shown in FIGS. 2 and 3 are denoted by the same reference numerals, and redundant description is omitted.

  The fuel gas purification facility shown in FIG. 4 is another example of a recyclable fuel gas purification facility for MCFC, and the fuel obtained from the biomass / waste gasifier 1 is the same as the facility shown in FIG. This is an example of a fuel gas refining facility for supplying gas to the MCFC 21, and is intended to reduce the cost and amount of the impurity remover by using a blown impurity remover and a fixed bed impurity remover in combination.

  As shown in the figure, between the adsorption removal means 13 and the sulfur conversion means 31, there is provided a fixed bed type precision removal means 41 to which the raw material gas from which mercury has been removed by the adsorption removal means 13 is sent. In the precision removing means 41, the halide in the raw material gas from which mercury has been removed is further removed.

  In the figure, the halide removing apparatus is a facility for removing halides by using a second impurity fixing means 7 of the impurity removing agent blowing method similar to that of FIG. The amount of the impurity removing agent to be introduced is controlled by the blowing-type second impurity fixing means 7 in accordance with the concentration of the halide contained in the partial combustion gas (crude gas). Further, by using a calcium-based and a sodium-based in combination as the blowing impurity removing agent by the second impurity fixing means 7, the halide concentration is set to about 5 ppm. The impurity removal agent of the downstream fixed bed type precision removal means 41 can reduce the halide concentration at the outlet to 1 ppm or less.

  When the fixed bed type precision removing means 41 is used in combination, an inexpensive calcium-based impurity removing agent is mainly used to reduce the load of halide on the expensive sodium-based fixed bed impurity removing agent, and the extremely high 1 ppm. A low halide concentration can be achieved. As a result, the cost of the impurity removing agent can be reduced, and it can be used not only for MCFC21 but also for applications such as fuel synthesis requiring a higher level of purification.

  The fuel gas purification facility of the third embodiment has the following advantages. That is, by simply using a calcium-based impurity removing agent (slaked lime) blowing method and a sodium-based fixed bed impurity removing agent in combination, a sodium-based fixing that is 500 to 1000 times more expensive than a blowing-type absorbent. Since a large amount of the floor impurity remover is used, there is a disadvantage that the absorbent cost is enormous. In this embodiment, the amount of fixed bed impurity remover used can be reduced to about 1/10, so that the absorbent cost can be reduced by nearly 90% and the amount of used impurity remover discarded can be reduced by about 20%. can do.

  The fuel gas purification facility described above can be a fuel gas purification facility that can obtain a fuel gas from which impurities have been removed to the maximum by using a small amount of impurity removing agent.

  INDUSTRIAL APPLICABILITY The present invention can be used in the industrial field of fuel gas purification equipment that removes impurities from a raw material gas to obtain a fuel gas.

It is a table | surface showing the relationship of the combination of the removal object impurity suitable for each recycling technique, and an impurity removal agent. 1 is a schematic system diagram of a gas purification facility according to a first embodiment of the present invention. It is a schematic system diagram of the gas purification equipment which concerns on the 2nd Example of this invention. It is a schematic system diagram of the gas purification equipment which concerns on the example of 3rd Embodiment of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Biomass / waste gasifier 2 Gas engine 3 In-furnace desulfurization means 4 1st impurity fixation means 5 1st physical removal means 6 Circulation path 7 2nd impurity fixation means 8 2nd physical removal means 11 Reprocessing means 12 Re-injection system 13 Adsorption removal means 21 MCFC
31 Sulfur conversion means 32 Desulfurization means 41 Precision removal means

Claims (12)

Raw material gas supply means for obtaining raw material gas by partially burning fuel;
First impurity fixing means for fixing thermally decomposable impurities of the source gas by blowing an absorbent / adsorbent into the source gas obtained by the source gas supply means;
First physical removal means for removing thermally decomposable impurities fixed to the absorbent / adsorbent by the first impurity fixing means by physical filtration together with the absorbent / adsorbent;
A recharging means for charging the thermally decomposable impurities absorbed and adsorbed by the absorbent / adsorbent and recovered by the first physical removal means to the raw material gas supply means together with the absorbing / adsorbing agent;
Second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means;
Second physical removal means for removing hydrogen halide fixed to the absorbent by the second impurity fixing means together with the absorbent by physical filtration;
And a reprocessing means for transporting the absorbent recovered by the second physical removal means to the reprocessing equipment. The fuel gas refining equipment according to claim 1, wherein the absorbent blown by the second impurity fixing means is an absorbent reprocessed by the reprocessing means. Deriving means for detecting the halogen concentration in the source gas sent to the second impurity fixing means;
The fuel gas refining equipment according to claim 1 or 2, further comprising: an adjusting unit that adjusts the amount of the absorbent blown in accordance with the state of the halogen concentration detected by the deriving unit. Raw material gas hydrogen halide is removed by the second physical removal means is fed, according to claim 1, characterized in that with a suction removal means having a solid adsorbent for adsorbing heavy metals in the raw material gas The fuel gas refinery | purification equipment as described in any one . The fuel gas purification equipment according to any one of claims 1 to 3, further comprising an in-furnace desulfurization unit that discharges a sulfur compound together with the slag by blowing an impurity removing agent into the raw material gas supply unit. The fuel gas purification facility according to any one of claims 1 to 3, further comprising a sulfur conversion means for removing the organic sulfur compound. The apparatus according to any one of claims 1 to 3 , further comprising precision removing means for precisely removing hydrogen halide from the source gas from which hydrogen halide has been removed by the second physical removing means. fuel gas purification equipment. Raw material gas supply means for obtaining raw material gas by partially burning fuel;
In-furnace desulfurization means for discharging a sulfur compound together with slag by blowing an impurity removing agent into the raw material gas supply means;
First impurity fixing means for fixing thermally decomposable impurities of the source gas by blowing an absorbent / adsorbent into the source gas obtained by the source gas supply means;
First physical removal means for removing thermally decomposable impurities fixed to the absorbent / adsorbent by the first impurity fixing means by physical filtration together with the absorbent / adsorbent;
A recharging means for charging the thermally decomposable impurities absorbed and adsorbed by the absorbent / adsorbent and recovered by the first physical removal means to the raw material gas supply means together with the absorbing / adsorbing agent;
Second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means;
Second physical removal means for removing hydrogen halide fixed to the absorbent by the second impurity fixing means together with the absorbent by physical filtration;
Reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility;
A system for blowing the absorbent reprocessed by the reprocessing means into the second impurity fixing means;
A fuel gas refining facility, comprising: a solid adsorbent that has a solid adsorbent that adsorbs a heavy metal in the raw material gas to which the raw material gas from which hydrogen halide has been removed by the second physical removal unit is sent. Raw material gas supply means for obtaining raw material gas by partially burning fuel;
First impurity fixing means for fixing thermally decomposable impurities of the source gas by blowing an absorbent / adsorbent into the source gas obtained by the source gas supply means;
First physical removal means for removing thermally decomposable impurities fixed to the absorbent / adsorbent by the first impurity fixing means by physical filtration together with the absorbent / adsorbent;
A recharging means for charging the thermally decomposable impurities absorbed and adsorbed by the absorbent / adsorbent and recovered by the first physical removal means to the raw material gas supply means together with the absorbing / adsorbing agent;
Second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means;
Second physical removal means for removing hydrogen halide fixed to the absorbent by the second impurity fixing means together with the absorbent by physical filtration;
Reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility;
A system for blowing the absorbent reprocessed by the reprocessing means into the second impurity fixing means;
A source gas from which hydrogen halide has been removed by the second physical removal unit is sent, and an adsorption removal unit having a solid adsorbent that adsorbs heavy metals in the source gas;
A fuel gas refining facility, comprising: a sulfur conversion means for sending a raw material gas from which heavy metals have been removed by the adsorption removing means and removing organic sulfur compounds in the raw material gas. Raw material gas supply means for obtaining raw material gas by partially burning fuel;
First impurity fixing means for fixing thermally decomposable impurities of the source gas by blowing an absorbent / adsorbent into the source gas obtained by the source gas supply means;
First physical removal means for removing thermally decomposable impurities fixed to the absorbent / adsorbent by the first impurity fixing means by physical filtration together with the absorbent / adsorbent;
A recharging means for charging the thermally decomposable impurities absorbed and adsorbed by the absorbent / adsorbent and recovered by the first physical removal means to the raw material gas supply means together with the absorbing / adsorbing agent;
Second impurity fixing means for fixing hydrogen halide of the raw material gas by blowing an absorbent into the raw material gas from which the thermally decomposable impurities have been removed by the first physical removing means;
Second physical removal means for removing hydrogen halide fixed to the absorbent by the second impurity fixing means together with the absorbent by physical filtration;
Reprocessing means for transporting the absorbent recovered by the second physical removal means to a reprocessing facility;
A source gas from which hydrogen halide has been removed by the second physical removal unit is sent, and an adsorption removal unit having a solid adsorbent that adsorbs heavy metals in the source gas;
A raw material gas from which heavy metals have been removed by the adsorption removing means is sent, and a precision removing means for precisely removing hydrogen halide,
A fuel gas refining facility comprising a sulfur conversion means for removing a raw material gas from which hydrogen halide has been precisely removed by a precision removing means and removing organic sulfur compounds in the raw material gas. The fuel gas purification facility according to any one of claims 1 to 10, wherein the raw material gas supply means is a biomass / waste gasification furnace that partially burns biomass and waste to obtain raw material gas. . Thermally decomposable impurities absorbed and adsorbed to the absorption and the adsorbent in the first impurity fastening means, hydrocarbons, claims, characterized in that at least either of carbon impurities, organic chlorine compounds, basic gases The fuel gas purification equipment as described in any one of 1-11 .

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