JP4526410B2 - Powder decoloring auxiliary composition and hair decoloring agent containing the composition - Google Patents
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- 239000003795 chemical substances by application Substances 0.000 title claims description 108
- 239000000203 mixture Substances 0.000 title claims description 43
- 239000000843 powder Substances 0.000 title description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 43
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 33
- 239000003051 hair bleaching agent Substances 0.000 claims description 31
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 18
- 239000004115 Sodium Silicate Substances 0.000 claims description 17
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 17
- 239000011780 sodium chloride Substances 0.000 claims description 17
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 17
- 239000002671 adjuvant Substances 0.000 claims description 11
- 238000004061 bleaching Methods 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- 150000005846 sugar alcohols Chemical class 0.000 claims description 8
- 239000004375 Dextrin Substances 0.000 claims description 6
- 229920001353 Dextrin Polymers 0.000 claims description 6
- 235000019425 dextrin Nutrition 0.000 claims description 6
- 229940009662 edetate Drugs 0.000 claims description 6
- 239000007844 bleaching agent Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 description 26
- 238000005187 foaming Methods 0.000 description 18
- 230000020169 heat generation Effects 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000004042 decolorization Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 7
- 239000003513 alkali Substances 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- -1 etc. Chemical compound 0.000 description 6
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 6
- 239000008213 purified water Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 235000019795 sodium metasilicate Nutrition 0.000 description 4
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000001099 ammonium carbonate Substances 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229960003893 phenacetin Drugs 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229920003169 water-soluble polymer Polymers 0.000 description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 229940124274 edetate disodium Drugs 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007854 depigmenting agent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、粉末状脱色補助剤組成物および該脱色補助剤組成物を含有した毛髪脱色剤に関する。 The present invention relates to a powdery bleaching aid composition and a hair bleaching agent containing the bleaching aid composition.
毛髪脱色剤は、一般に、使用時に過酸化水素とアルカリ剤を混合させ、過酸化水素の分解により生じた酸素により、毛髪中のメラニン色素を酸化分解することによって毛髪を脱色する。また、短時間で優れた脱色力を発揮させるために、毛髪脱色剤に脱色補助剤として過硫酸塩が併用された毛髪脱色剤も知られている。このような、過硫酸塩が併用された毛髪脱色剤としては、過硫酸塩を含有する粉末状の第１剤と、過酸化水素を含有する液状又はクリーム状の第２剤とからなる二剤式の毛髪脱色剤や、アルカリ剤を含有する液状又はクリーム状の第１剤、過酸化水素を含有する液状又はクリーム状の第２剤、及び過硫酸塩を含有する粉末状の第３剤とからなる三剤式の毛髪脱色剤がある。 In general, a hair bleaching agent mixes hydrogen peroxide and an alkaline agent at the time of use, and decolorizes hair by oxidizing and decomposing melanin pigment in hair with oxygen generated by the decomposition of hydrogen peroxide. Also known is a hair bleaching agent in which a persulfate is used in combination with a hair bleaching agent in order to exert an excellent bleaching power in a short time. As such a hair bleaching agent combined with persulfate, two agents comprising a powdery first agent containing persulfate and a liquid or cream-like second agent containing hydrogen peroxide. A hair bleaching agent of the formula, a liquid or creamy first agent containing an alkaline agent, a liquid or creamy second agent containing hydrogen peroxide, and a powdery third agent containing persulfate There are three-part hair bleaching agents.
（１）過硫酸塩を含有する粉末状の剤は、製造作業時や混合使用時に粉末の飛散の問題がある。（２）また、過硫酸塩は凝集しやすく、保存中に吸湿してケーキングを起こしたり、ダマが生じたりする問題もある。（３）更には、脱色補助剤を併用した毛髪脱色剤は、酸化剤の分解反応を加速させるために、混合使用時に激しく発泡や発熱が生じる問題がある。 (1) A powdered agent containing a persulfate has a problem of powder scattering at the time of manufacturing operation or mixing. (2) In addition, persulfate easily aggregates, and there is a problem that moisture is absorbed during storage to cause caking or to cause lumps. (3) Furthermore, the hair bleaching agent used in combination with the bleaching auxiliary agent has a problem in that foaming and heat generation are severely generated during mixing in order to accelerate the decomposition reaction of the oxidizing agent.
上記（１）や（２）の問題を解決するために、酸化剤と、ステアリン酸カルシウムやステアリン酸マグネシウムなどの分散剤を配合した粉末脱色・脱染剤組成物（特許文献１及び特許文献２参照）や、過硫酸塩とステアリン酸金属塩を含有した粉末状脱色、脱染剤組成物（特許文献３参照）などが提案されている。また、上記（３）の問題をも解決するものとして、メタケイ酸アルミン酸マグネシウムを配合した毛髪脱色剤が提案されている（特許文献４参照）。 In order to solve the above problems (1) and (2), a powder decoloring / destaining agent composition containing an oxidizing agent and a dispersant such as calcium stearate or magnesium stearate (see Patent Document 1 and Patent Document 2) ), And powder-like decolorization and decoloring agent compositions (see Patent Document 3) containing persulfate and metal stearate have been proposed. Further, as a solution to the above problem (3), a hair bleaching agent containing magnesium aluminate metasilicate has been proposed (see Patent Document 4).
しかし、ステアリン酸カルシウムやメタケイ酸アルミン酸マグネシウムなどを配合して粉末状の剤とすると、剤の分散性や流動性を向上させることができるものの、用時混合時に水に対する溶解性が低いことから、均一混合し難く、ままこの原因となり、依然として混合時の発泡や発熱の問題があった。そこで、本発明者らが鋭意研究を行った結果、脱色補助剤である過硫酸塩に塩化ナトリウムを添加して粉末状脱染、脱色剤組成物とすると、分散性や流動性を維持しつつ、水に対する溶解性をも向上することができ、その結果、毛髪脱色剤としての混合使用時に均一混合が容易であり、発泡や発熱を効果的に抑制することができることを見出し、本発明を完成するに至った。 However, blending calcium stearate or magnesium aluminate metasilicate into a powdery agent can improve the dispersibility and fluidity of the agent, but because it has low solubility in water during mixing, It was difficult to mix uniformly, causing this problem, and there were still problems of foaming and heat generation during mixing. Therefore, as a result of intensive studies conducted by the present inventors, it is possible to maintain dispersibility and fluidity by adding sodium chloride to a persulfate that is a decoloring aid to form a powder decoloring and decoloring agent composition. The solubility in water can also be improved, and as a result, it has been found that uniform mixing is easy at the time of mixing and use as a hair bleaching agent, and foaming and heat generation can be effectively suppressed, and the present invention is completed. It came to do.
すなわち、本発明は、
〔１〕 ２０〜９０重量％の過硫酸塩と、５〜２０重量％の塩化ナトリウムとを含有することを特徴とする粉末状脱色補助剤組成物、
〔２〕 ケイ酸ナトリウムを含有することを特徴とする前記〔１〕に記載の粉末状脱色補助剤組成物、
〔３〕 ケイ酸ナトリウムと塩化ナトリウムとの重量含有比（ケイ酸ナトリウム：塩化ナトリウム）が、１：２〜１：７であることを特徴とする前記〔２〕に記載の粉末状脱色補助剤組成物、
〔４〕 前記〔１〜３〕のいずれかに記載の粉末状脱色補助剤組成物を含有することを特徴とする毛髪脱色剤、
〔５〕 前記〔１〜３〕のいずれかに記載の粉末状脱色補助剤組成物を含有する第１剤と、過酸化水素を含有する第２剤とからなることを特徴とする毛髪脱色剤、
〔６〕 アルカリ剤を含有する第１剤と、過酸化水素を含有する第２剤と、前記〔１〜３〕のいずれかに記載の粉末状脱色補助剤組成物を含有する第３剤とからなることを特徴とする毛髪脱色剤、
〔７〕 糖アルコール、デキストリン及びエデト酸塩の群からなる１種以上を含有しないことを特徴とする前記｛４〜６｝のいずれかに記載の毛髪脱色剤、並びに
〔８〕 アプリケータ内で混合調合される前記〔４〜７〕のいずれかに記載の毛髪脱色剤、
に関する。
That is, the present invention
[1] A powdery decoloring adjuvant composition comprising 20 to 90% by weight of persulfate and 5 to 20% by weight of sodium chloride ,
[2] The powdery decoloring adjuvant composition as described in [ 1 ] above, comprising sodium silicate,
[3] The powder-like decolorization auxiliary according to [ 2 ] above, wherein the weight content ratio of sodium silicate and sodium chloride (sodium silicate: sodium chloride) is from 1: 2 to 1: 7. Composition,
[4] A hair bleaching agent comprising the powdery bleaching adjuvant composition according to any one of [ 1 to 3 ] above,
[5] A hair bleaching agent comprising a first agent containing the powdery bleaching agent composition according to any one of [ 1 to 3 ] and a second agent containing hydrogen peroxide. ,
[6] A first agent containing an alkali agent, a second agent containing hydrogen peroxide, and a third agent containing the powdery decolorization auxiliary composition according to any one of [ 1 to 3 ] above A hair bleaching agent, characterized by comprising
[7] The hair bleaching agent according to any one of the above { 4 to 6 }, which does not contain one or more of the group consisting of sugar alcohol, dextrin and edetate, and [8] In the applicator The hair bleaching agent according to any one of the above [ 4-7 ], which is mixed and prepared,
About.
本発明の粉末状脱色補助剤組成物によれば、過硫酸塩に塩化ナトリウムを添加しているものであることから、分散性や流動性を維持しつつ、水に対する溶解性をも向上することができる。
また、本発明の粉末状脱色補助剤組成物を含有して毛髪脱色剤とすると、該粉末状脱色補助剤組成物の水に対する溶解性が良好なことから、アルカリ剤や過酸化水素を含有する液状乃至はクリーム状の剤との混合使用時に均一混合が容易であり、激しい発泡や発熱を効果的に抑制することができる。
更に、本発明の毛髪脱色剤に糖アルコール、デキストリン及びエデト酸塩の群からなる１種以上を含有しないことにより、混合使用時の発泡や発熱をより効果的に抑制することができる。
According to the powdery decoloring auxiliary composition of the present invention, sodium chloride is added to persulfate, so that dispersibility and fluidity are maintained, and solubility in water is also improved. Can do.
Moreover, when it contains the powder-like decoloring adjuvant composition of the present invention and is used as a hair bleaching agent, it contains an alkali agent and hydrogen peroxide because the powder-like bleaching adjuvant composition has good solubility in water. When mixed with a liquid or creamy agent, uniform mixing is easy, and intense foaming and heat generation can be effectively suppressed.
Furthermore, the hair bleaching agent of the present invention does not contain one or more of the group consisting of sugar alcohol, dextrin and edetate, so that foaming and heat generation during mixing can be more effectively suppressed.
本発明に係る粉末状脱色補助剤組成物には、必須成分として、過硫酸塩と塩化ナトリウムを含有する。かかる構成を有することで、分散性や流動性を維持しつつ、水に対する溶解性をも向上することができる。 The powdery decolorization auxiliary composition according to the present invention contains persulfate and sodium chloride as essential components. By having such a configuration, water solubility can be improved while maintaining dispersibility and fluidity.
用いられる過硫酸塩としては、例えば、過硫酸アンモニウム、過硫酸ナトリウム、過硫酸カリウム等を例示することができる。その含有量は、本発明の効果を発揮すれば特に限定されないが、粉末状脱色補助剤組成物中２０〜９０重量％とするのが好ましく、３０〜８０重量％とするのがより好ましい。２０重量％未満の含有量では、十分な毛髪脱色力を有することができないために、また、９０重量％を超えて含有した場合、混合操作中に過剰な発熱、発泡が生ずるおそれがあるために、いずれの場合にも好ましくない。 Examples of the persulfate used include ammonium persulfate, sodium persulfate, and potassium persulfate. The content is not particularly limited as long as the effect of the present invention is exerted, but it is preferably 20 to 90% by weight, more preferably 30 to 80% by weight in the powdery decolorization auxiliary composition. If the content is less than 20% by weight, sufficient hair bleaching power cannot be obtained, and if it exceeds 90% by weight, excessive heat generation and foaming may occur during the mixing operation. In either case, it is not preferable.
塩化ナトリウムの含有量は、本発明の効果を発揮すれば特に限定されないが、好ましくは、粉末状脱色補助剤組成物中５〜２０重量％であり、５〜１５重量％とするのがより好ましい。５重量％未満の含有量では、十分な分散性や流動性を得ることができないために、また、２０重量％を超えて含有すると、頭髪への塗布時にざらつきを感じるうえ、仕上がり後の風合いに劣ることがあるため、いずれの場合にも好ましくない。 The content of sodium chloride is not particularly limited as long as the effect of the present invention is exerted, but is preferably 5 to 20% by weight, more preferably 5 to 15% by weight in the powdery decolorization auxiliary composition. . If the content is less than 5% by weight, sufficient dispersibility and fluidity cannot be obtained. If the content is more than 20% by weight, it feels rough when applied to the hair, and the texture after finishing is felt. Since it may be inferior, it is not preferable in any case.
また、粉末状脱色補助剤組成物の流動性、脱染・脱色力をより向上させるために、ケイ酸ナトリウムを更に含有させることができる。ケイ酸ナトリウムの含有量は特に限定されないが、好ましくは、粉末状脱色補助剤組成物中１〜１５重量％であり、１〜１０重量％とするのがより好ましい。１重量％未満の含有量では、十分な分散性、流動性を得ることができないために、また、１５重量％を超えて含有すると、酸化剤の分解を促進し過ぎ、過剰な発泡や発熱を生じる場合があるため、いずれの場合にも好ましくない。 Moreover, in order to improve the fluidity | liquidity of a powder-form decoloring adjuvant composition, and the decoloring and decoloring power, sodium silicate can further be contained. Although content of sodium silicate is not specifically limited, Preferably, it is 1 to 15 weight% in a powder-form decoloring adjuvant composition, and it is more preferable to set it as 1 to 10 weight%. If the content is less than 1% by weight, sufficient dispersibility and fluidity cannot be obtained. If the content exceeds 15% by weight, the decomposition of the oxidizing agent is promoted excessively, and excessive foaming and heat generation are caused. Since it may occur, it is not preferable in any case.
尚、本発明の粉末状脱色補助剤組成物の水に対する溶解性を良好にし、後述するアルカリ剤や過酸化水素を含有する剤との混合性を良好にするためには、ケイ酸ナトリウムと塩化ナトリウムとの含有比が、重量比（ケイ酸ナトリウム：塩化ナトリウム）で１：２〜１：７であることが好ましく、１：２〜１：５であることがより好ましい。塩化ナトリウムの含有比が、ケイ酸ナトリウム１重量部に対して２重量部未満の場合、流動性に劣り充填不良が発生しやすくなるために、また、塩化ナトリウムの含有比が７重量部を超える場合には、分散性の低下により、頭髪への塗布時にざらつきを感じるため、いずれの場合にも好ましくない。 In order to improve the solubility of the powdery decoloring auxiliary composition of the present invention in water and to improve the mixing property with an alkali agent or an agent containing hydrogen peroxide described later, sodium silicate and chloride are used. The content ratio with sodium is preferably 1: 2 to 1: 7 by weight ratio (sodium silicate: sodium chloride), more preferably 1: 2 to 1: 5. When the content ratio of sodium chloride is less than 2 parts by weight with respect to 1 part by weight of sodium silicate, the fluidity is poor and filling failure tends to occur, and the content ratio of sodium chloride exceeds 7 parts by weight. In some cases, the dispersibility is lowered, and a rough surface is felt when applied to the hair.
次に、本発明に係る粉末状脱色補助剤組成物は、脱染、脱色補助剤として用いられることから、粉末状脱色補助剤組成物と過酸化水素を含有する剤とを用時に混合する必要がある。このような毛髪脱色剤の形態としては、前記粉末状脱色補助剤組成物を含有する脱染、脱色補助剤を第１剤とし、過酸化水素を含有する剤を第２剤とする二剤式の毛髪脱色剤が挙げられる。また、アルカリ剤を含有する剤を第１剤とし、過酸化水素を含有する剤を第２剤とし、前記粉末状脱色補助剤組成物を含有する剤を第３剤とする三剤式の毛髪脱色剤も挙げられる。 Next, since the powdery decoloring auxiliary composition according to the present invention is used as a decoloring and decoloring auxiliary, it is necessary to mix the powdery decoloring auxiliary composition and the hydrogen peroxide-containing agent at the time of use. There is. As a form of such a hair decoloring agent, a two-component type in which the decoloring and decoloring auxiliary agent containing the powdery decoloring auxiliary composition is the first agent and the hydrogen peroxide-containing agent is the second agent Hair decoloring agents. In addition, a three-part hair having an agent containing an alkaline agent as a first agent, an agent containing hydrogen peroxide as a second agent, and an agent containing the powdery decolorization auxiliary composition as a third agent. Also included are depigmenting agents.
上記二剤式又は三剤式いずれの形態で使用する場合でも、脱染、脱色力を促進させるためにアルカリ剤を含有することができる。含有するアルカリ剤は、いずれの場合も、第１剤に配合すればよい。 Even when used in any of the two-part or three-part forms, an alkali agent can be contained in order to promote decolorization and decolorization power. The alkaline agent to be contained may be blended with the first agent in any case.
二剤式の形態で用いる場合、用いられるアルカリ剤は、炭酸ナトリウム、炭酸水素ナトリウム、炭酸マグネシウム、炭酸アンモニウム、メタケイ酸ナトリウム等を例示することができ、脱色効果の観点からメタケイ酸ナトリウムを用いるのが好ましい。 When used in a two-part form, the alkali agent used can be exemplified by sodium carbonate, sodium hydrogen carbonate, magnesium carbonate, ammonium carbonate, sodium metasilicate, etc., and sodium metasilicate is used from the viewpoint of decoloring effect. Is preferred.
アルカリ剤の含有量は特に限定されないが、第１剤中４〜３０重量％とすると良く、１０〜２５重量％とするのが好ましい。含有量が４重量％未満の場合、毛髪の脱色効果に劣るために、また、３０重量％を超えて含有すると、第２剤との混合時に発泡や発熱が激しく生じる場合があるために、いずれの場合にも好ましくない。 The content of the alkali agent is not particularly limited, but is preferably 4 to 30% by weight in the first agent, and preferably 10 to 25% by weight. When the content is less than 4% by weight, the effect of decoloring hair is inferior. When the content exceeds 30% by weight, foaming and heat generation may occur severely when mixed with the second agent. This is also not preferable.
尚、脱染、脱色補助剤中には、脱色効果を損なわない範囲で、界面活性剤、水溶性高分子等を目的に応じて適宜配合することができる。 In the destaining and decoloring aid, a surfactant, a water-soluble polymer, and the like can be appropriately blended depending on the purpose within a range not impairing the decoloring effect.
第２剤には、過酸化水素が必須の成分として含有される。用いられる過酸化水素は、通常、過酸化水素水が用いられる。過酸化水素含有量は、第２剤中０．１〜１０重量％とするのが好ましく、１〜６重量％とするのがより好ましい。０．１重量％未満の含有量では、毛髪の脱色効果に劣るために、また、１０重量％を超えて含有しても、それ以上の効果が望めないばかりか、皮膚刺激等の安全性に問題が生ずるために、いずれの場合にも好ましくない。 The second agent contains hydrogen peroxide as an essential component. As the hydrogen peroxide used, a hydrogen peroxide solution is usually used. The hydrogen peroxide content is preferably 0.1 to 10% by weight in the second agent, and more preferably 1 to 6% by weight. If the content is less than 0.1% by weight, the effect of decoloring the hair is inferior. If the content exceeds 10% by weight, not only a further effect can be expected, but also safety such as skin irritation can be achieved. In either case, it is not preferable because of problems.
尚、第２剤中には、脱色効果を損なわない範囲で、水溶性高分子、多価アルコール、シリコーン類、界面活性剤、保湿剤、過酸化水素の安定剤、有機酸又は無機酸、ｐＨ調整剤、水等を目的に応じて適宜配合することができる。 In the second agent, water-soluble polymers, polyhydric alcohols, silicones, surfactants, humectants, hydrogen peroxide stabilizers, organic acids or inorganic acids, pH, as long as the decolorization effect is not impaired. A regulator, water, and the like can be appropriately blended depending on the purpose.
二剤式の毛髪脱色剤とする場合は、第１剤を粉末状とし、第２剤を液状乃至はクリーム状とすることが好ましく、使用時に各剤を均一に混合して使用される。混合は、第１剤中に第２剤を、また、第２剤中に第１剤を投入すれば良いが、通常、４０〜１００重量部の第２剤が充填されたアプリケータ内に２０〜６０重量部の第１剤を投入し密閉して振とうすることにより均一に混合される。 In the case of a two-component hair bleaching agent, the first agent is preferably powdered and the second agent is preferably liquid or creamy, and each agent is used by uniformly mixing at the time of use. For mixing, the second agent may be charged into the first agent and the first agent into the second agent. Usually, 20 to 20 parts in an applicator filled with 40 to 100 parts by weight of the second agent. The mixture is uniformly mixed by adding ~ 60 parts by weight of the first agent, sealing and shaking.
次に、三剤式の形態で用いる場合、第１剤に配合されるアルカリ剤としては、例えば、アンモニア、イソプロパノールアミン、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、２−アミノ−２−メチル−１−プロパノール、水酸化ナトリウム、炭酸ナトリウム、炭酸アンモニウム、炭酸水素アンモニウム、炭酸水素ナトリウム等を挙げることができる。 Next, when used in the form of three agents, examples of the alkaline agent blended in the first agent include ammonia, isopropanolamine, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1 -Propanol, sodium hydroxide, sodium carbonate, ammonium carbonate, ammonium hydrogen carbonate, sodium hydrogen carbonate and the like can be mentioned.
その含有量は特に限定されないが、第１剤中２〜１５重量％とするのが好ましく、５〜１５重量％とするのが好ましい。含有量が２重量％未満の場合、充分な脱色効果が得られず、また、１５重量％を超えて含有すると、混合操作中の異常な発泡や発熱、皮膚刺激や毛髪損傷が生ずる場合があるために、いずれの場合にも好ましくはない。 The content is not particularly limited, but is preferably 2 to 15% by weight, and preferably 5 to 15% by weight in the first agent. When the content is less than 2% by weight, a sufficient decoloring effect cannot be obtained. When the content exceeds 15% by weight, abnormal foaming or heat generation during the mixing operation, skin irritation or hair damage may occur. Therefore, it is not preferable in either case.
尚、第１剤中には、脱色効果を損なわない範囲で、油性成分、界面活性剤、シリコーン類、多価アルコール、水溶性高分子、保湿剤、動物及び植物エキス、香料、水等を目的に応じて適宜配合することができる。 The purpose of the first agent is oily ingredients, surfactants, silicones, polyhydric alcohols, water-soluble polymers, humectants, animal and plant extracts, fragrances, water, etc., as long as the decolorization effect is not impaired. Depending on the case, it can be blended appropriately.
第２剤に用いられる過酸化水素は、二剤式の形態で用いられる第２剤と同じものを用いれば良い。また、第３剤には、二剤式の形態で用いられる第１剤と同じものであっても良い。 Hydrogen peroxide used for the second agent may be the same as the second agent used in a two-part form. Further, the third agent may be the same as the first agent used in a two-part form.
このような三剤式の毛髪脱色剤は、第１剤及び第２剤を液状乃至はクリーム状とし、第３剤を粉末状とすることが好ましく、使用時に各剤を均一に混合して使用される。混合は、第１剤中に第２剤を、また、第２剤中に第１剤を投入し、その間又はその後に第３剤を混合すれば良い。通常、８〜２０重量部の第２剤が充填されたアプリケータ内に１〜６重量部の第３剤を投入したのち、４〜１２重量部の第１剤を加えて密閉して振とうすることにより均一に混合される。 In such a three-part hair bleaching agent, the first agent and the second agent are preferably in liquid or cream form, and the third agent is preferably in powder form. Is done. The mixing may be performed by adding the second agent into the first agent and the first agent into the second agent, and mixing the third agent during or after that. Usually, after adding 1 to 6 parts by weight of the third agent in an applicator filled with 8 to 20 parts by weight of the second agent, 4 to 12 parts by weight of the first agent is added and sealed to shake. By mixing, it is mixed uniformly.
ところで、過硫酸塩を含有する毛髪脱色剤には、粉末状の剤の流動性を向上させるために、ソルビット等の糖アルコールやデキストリンなどが配合される場合がある。また、残存する微量金属による過硫酸塩の分解等の触媒作用を防止する目的でエデト酸塩等の金属イオン封鎖剤が配合される場合もある。しかし、これら成分を毛髪脱色剤中に存在させると、各剤の混合時に激しい発泡や発熱の原因となる場合があることが判明した。このことから、混合時の激しい発泡や発熱を更に防止する観点から、毛髪脱色剤中のいずれの剤においても、糖アルコール、デキストリン及びエデト酸塩の１種以上が含有されていない毛髪脱色剤とするのが好ましく、糖アルコール、デキストリン及びエデト酸塩のいずれもが含有されていない毛髪脱色剤とするのがより好ましい。 By the way, in order to improve the fluidity | liquidity of a powder-form agent, sugar alcohol, dextrin, etc., such as sorbitol, may be mix | blended with the hair bleaching agent containing a persulfate. In some cases, a sequestering agent such as edetate is added for the purpose of preventing catalytic action such as decomposition of persulfate by trace metals remaining. However, it has been found that the presence of these components in the hair bleaching agent may cause severe foaming or heat generation when the respective agents are mixed. From this, from the viewpoint of further preventing intense foaming and heat generation during mixing, any agent in the hair decoloring agent includes a hair decoloring agent that does not contain one or more of sugar alcohol, dextrin and edetate. It is preferable to use a hair bleaching agent that does not contain any sugar alcohol, dextrin, or edetate.
以下、本発明を実施例に基づいて更に詳細に説明するが、本発明はかかる実施例のみに限定されるものではない。尚、配合量は特記しない限り、重量％である。 EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to this Example. The blending amount is wt% unless otherwise specified.
（試験例１；流動性）
表１に記した組成に従い、各化合物をボールミルを用いて粉砕後、８．６メッシュ（目開き２.００ｍｍ）のふるいに通した後、全量２０ｇづつに小分け充填して粉末状脱色補助剤組成物を調製した。充填時の流動性について、下記評価基準に従って評価した。結果を表１に記す。
＜評価基準＞
○：流動性が良い
×：流動性に劣る
(Test Example 1 fluidity)
According to the composition described in Table 1, each compound was pulverized using a ball mill, passed through a sieve of 8.6 mesh (aperture 2.00 mm), then subdivided into 20 g total amount, and powdered decoloring adjuvant composition A product was prepared. The fluidity during filling was evaluated according to the following evaluation criteria. The results are shown in Table 1.
<Evaluation criteria>
○: Good fluidity ×: Inferior fluidity
表１の結果から、過硫酸塩に塩化ナトリウムを添加して粉末状脱色補助剤組成物とすると、充填時の流動性に優れることが分かる。 From the results shown in Table 1, it can be seen that when sodium chloride is added to persulfate to form a powder-type decolorization auxiliary composition, the fluidity at the time of filling is excellent.
（試験例２；混合性）
下記組成により調製した液状の第２剤１０重量部をアプリケータ内に充填し、表２に記した組成の各粉末状の第３剤４重量部を加えて振とうし、クリーム状の第１剤５重量部を投入し、混合性について下記評価基準に従って目視で評価した。結果を表２に記す。
＜評価基準＞
○：２０回以内の振とうで第３剤が均一に溶解混合する
△：２１回以上４０回以内の振とうで第３剤が均一に溶解混合する
×：４０回以内の振とうでは第３剤が均一に溶解混合しない
(Test Example 2: Mixability)
10 parts by weight of a liquid second agent prepared according to the following composition is filled in the applicator, and 4 parts by weight of each powdery third agent having the composition shown in Table 2 is added and shaken. 5 parts by weight of the agent was added, and the mixing property was visually evaluated according to the following evaluation criteria. The results are shown in Table 2.
<Evaluation criteria>
○: The third agent is uniformly dissolved and mixed by shaking within 20 times. Δ: The third agent is uniformly dissolved and mixed by shaking within 21 times or more and 40 times. ×: Third when shaking within 40 times. The agent does not dissolve and mix uniformly
（試験例３；発泡・発熱性）
試験例２の混合操作時における発泡の程度および発熱の程度について、下記評価基準に従って目視で評価した。結果を表２に記す。
＜発泡の評価基準＞
○：殆ど発泡しない
△：やや発泡する
×：激しく発泡する
＜発熱の評価基準＞
○：系の温度は４０℃以下である
△：系の温度は４０℃超〜６０℃に上昇した
×：系の温度は６０℃超に上昇した
(Test Example 3; foaming and heat generation)
The degree of foaming and the degree of heat generation during the mixing operation in Test Example 2 were visually evaluated according to the following evaluation criteria. The results are shown in Table 2.
<Evaluation criteria for foaming>
○: hardly foamed Δ: slightly foamed ×: foamed vigorously <Evaluation criteria for heat generation>
○: The temperature of the system is 40 ° C. or less Δ: The temperature of the system has risen to over 40 ° C. to 60 ° C. x: The temperature of the system has risen to over 60 ° C.
＜第１剤＞
アンモニア水（２８％） １０．０
セタノール ５．０
ポリオキシエチレンセチルエーテル（40E.O.） ４．５
ポリオキシエチレンセチルエーテル（２E.O.） ２．０
プロピレングリコール ３．５
塩化ステアリルトリメチルアンモニウム ７．０
エデト酸二ナトリウム １．０
精製水 残 余
合 計 １００．０
<First Agent>
Ammonia water (28%) 10.0
Cetanol 5.0
Polyoxyethylene cetyl ether (40E.O.) 4.5
Polyoxyethylene cetyl ether (2E.O.) 2.0
Propylene glycol 3.5
Stearyltrimethylammonium chloride 7.0
Edetate disodium 1.0
Purified water residue total 100.0
＜第２剤＞
過酸化水素（３５％） １７．０
フェナセチン １．０
リン酸 ０．５
精製水 残 余
合 計 １００．０
<Second agent>
Hydrogen peroxide (35%) 17.0
Phenacetin 1.0
Phosphoric acid 0.5
Purified water residue total 100.0
表２の結果から、本発明の毛髪脱色剤は、混合使用時に均一混合が容易であり、激しい発泡や発熱を効果的に抑制することができることが分かる。 From the results shown in Table 2, it can be seen that the hair bleaching agent of the present invention can be easily uniformly mixed at the time of mixing and can effectively suppress severe foaming and heat generation.
実施例５
＜第１剤：クリーム状＞
流動パラフィン ２．０
ステアリルアルコール ７．０
ポリオキシエチレンステアリルエーテル ４．０
プロピレングリコール ８．０
塩化ベヘニルトリメチルアンモニウム ３．０
アスコルビン酸ナトリウム １．０
エデト酸二ナトリウム ０．５
高重合シリコーン ３．０
アンモニア水（２８％） ６．０
香料 適 量
精製水 残 余
合 計 １００．０
＜第２剤：液状＞
プロピレングリコール ７．０
フェナセチン ０．５
リン酸 １．０
過酸化水素（３５％） １７．０
精製水 残 余
合 計 １００．０
＜第３剤：粉末状＞
過硫酸カリウム ４５．０
過硫酸アンモニウム １０．０
メタケイ酸ナトリウム １０．０
ケイ酸ナトリウム ３．０
塩化ナトリウム １０．０
ステアリン酸マグネシウム ７．０
無水ケイ酸 １５．０
合 計 １００．０
Example 5
<First Agent: Cream>
Liquid paraffin 2.0
Stearyl alcohol 7.0
Polyoxyethylene stearyl ether 4.0
Propylene glycol 8.0
Behenyltrimethylammonium chloride 3.0
Sodium ascorbate 1.0
Edetate disodium 0.5
Highly polymerized silicone 3.0
Ammonia water (28%) 6.0
Perfume appropriate amount
Purified water residue total 100.0
<Second agent: Liquid>
Propylene glycol 7.0
Phenacetin 0.5
Phosphoric acid 1.0
Hydrogen peroxide (35%) 17.0
Purified water residue total 100.0
<Third agent: powder>
Potassium persulfate 45.0
Ammonium persulfate 10.0
Sodium metasilicate 10.0
Sodium silicate 3.0
Sodium chloride 10.0
Magnesium stearate 7.0
Silicic anhydride 15.0
Total 100.0
アプリケータ内に充填した第２剤１０重量部中に第３剤４重量部を加えて、第１剤５重量部を投入して混合性を確認した結果、２０回以内の振とうで均一に混合された。また、混合操作時に発泡や発熱は殆ど無かった。 As a result of adding 4 parts by weight of the third agent to 10 parts by weight of the second agent filled in the applicator and adding 5 parts by weight of the first agent and confirming the mixing property, it was uniformly shaken within 20 times. Mixed. Also, there was almost no foaming or heat generation during the mixing operation.
実施例６
＜第１剤：粉末状＞
過硫酸カリウム ３０．０
過硫酸ナトリウム １５．０
過硫酸アンモニウム １５．０
メタケイ酸ナトリウム １２．０
炭酸マグネシウム ８．０
ケイ酸ナトリウム ５．０
塩化ナトリウム １２．０
無水ケイ酸 ２．５
群青 ０．５
合 計 １００．０
＜第２剤：クリーム状＞
セタノール １０．０
ポリオキシエチレンオレイルエーテル ５．０
ステアリルアルコール ４．０
ポリオキシエチレン硬化ヒマシ油 ２．０
塩化ステアリルトリメチルアンモニウム ７．０
グリセリン ９．０
クエン酸 １．０
フェナセチン ０．５
過酸化水素 ９．０
精製水 残 余
合 計 １００．０
Example 6
<First agent: powder>
Potassium persulfate 30.0
Sodium persulfate 15.0
Ammonium persulfate 15.0
Sodium metasilicate 12.0
Magnesium carbonate 8.0
Sodium silicate 5.0
Sodium chloride 12.0
Silicic anhydride 2.5
Ultramarine 0.5
Total 100.0
<Second agent: Cream>
Cetanol 10.0
Polyoxyethylene oleyl ether 5.0
Stearyl alcohol 4.0
Polyoxyethylene hydrogenated castor oil 2.0
Stearyltrimethylammonium chloride 7.0
Glycerin 9.0
Citric acid 1.0
Phenacetin 0.5
Hydrogen peroxide 9.0
Purified water residue total 100.0
アプリケータ内に充填した第２剤６重量部中に第１剤１重量部を加えて混合性を確認した結果、２０回以内の振とうで均一に混合された。また、混合操作時に発泡や発熱は殆ど無かった。 As a result of adding 1 part by weight of the first agent to 6 parts by weight of the second agent filled in the applicator and confirming the mixing property, the mixture was uniformly mixed by shaking within 20 times. Also, there was almost no foaming or heat generation during the mixing operation.
本発明の粉末状脱色補助剤組成物は、分散性や流動性が良く、水に対する溶解性にも優れるものであるから、毛髪脱色剤に好適に使用することができる。また、本発明の毛髪脱色剤は、混合使用時に均一混合が容易であり、激しい発泡や発熱を効果的に抑制することができるものであるから、脱色補助剤として過硫酸塩を用いた二剤式又は三剤式の毛髪脱色剤に好適に使用することができる。
Since the powdery decoloring auxiliary composition of the present invention has good dispersibility and fluidity and is excellent in water solubility, it can be suitably used as a hair decoloring agent. Moreover, since the hair bleaching agent of the present invention is easy to uniformly mix at the time of use and can effectively suppress severe foaming and heat generation, two agents using persulfate as a bleaching aid It can be suitably used for a formula or three-component hair bleaching agent.
Claims (8)
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| JP5986750B2 (en) * | 2012-01-20 | 2016-09-06 | ホーユー株式会社 | Hair decolorization / destaining agent composition |
| JP5961388B2 (en) * | 2012-01-20 | 2016-08-02 | ホーユー株式会社 | Hair decolorization / destaining agent composition |
| JP5800868B2 (en) * | 2013-07-23 | 2015-10-28 | 株式会社マンダム | Hair bleach |
| EP3815671A1 (en) | 2019-10-31 | 2021-05-05 | Kao Germany GmbH | Bleaching composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63162616A (en) * | 1986-12-10 | 1988-07-06 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Powdery oxidative dyestuff |
| JP2001288062A (en) * | 2000-03-31 | 2001-10-16 | Kobayashi Pharmaceut Co Ltd | Artificial tooth detergent |
| WO2003041531A1 (en) * | 2001-11-14 | 2003-05-22 | The Procter & Gamble Company | Method for the cosmetic treatment of hair and implement for carrying out the same |
| WO2004045333A1 (en) * | 2002-11-14 | 2004-06-03 | The Procter & Gamble Company | Implement and method for treating strands of hair |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63162616A (en) * | 1986-12-10 | 1988-07-06 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Powdery oxidative dyestuff |
| JP2001288062A (en) * | 2000-03-31 | 2001-10-16 | Kobayashi Pharmaceut Co Ltd | Artificial tooth detergent |
| WO2003041531A1 (en) * | 2001-11-14 | 2003-05-22 | The Procter & Gamble Company | Method for the cosmetic treatment of hair and implement for carrying out the same |
| JP2005519658A (en) * | 2001-11-14 | 2005-07-07 | ザ プロクター アンド ギャンブル カンパニー | Method for cosmetic treatment of hair and tools for carrying out this method |
| WO2004045333A1 (en) * | 2002-11-14 | 2004-06-03 | The Procter & Gamble Company | Implement and method for treating strands of hair |
| JP2006506180A (en) * | 2002-11-14 | 2006-02-23 | ザ プロクター アンド ギャンブル カンパニー | Tools and methods for treating hair strands |
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