JP4520660B2 - Metal sheet and rubber product using flat wire - Google Patents
Metal sheet and rubber product using flat wire Download PDFInfo
- Publication number
- JP4520660B2 JP4520660B2 JP2001115896A JP2001115896A JP4520660B2 JP 4520660 B2 JP4520660 B2 JP 4520660B2 JP 2001115896 A JP2001115896 A JP 2001115896A JP 2001115896 A JP2001115896 A JP 2001115896A JP 4520660 B2 JP4520660 B2 JP 4520660B2
- Authority
- JP
- Japan
- Prior art keywords
- wire
- metal sheet
- steel
- flat
- flat wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Landscapes
- Woven Fabrics (AREA)
Description
【0001】
【発明の属する技術分野】
本発明は、熱間圧延された線材を伸線加工によって、より細い線径に加工し、これらを複数本を撚って製造される、スチールコード、釣り糸、カットワイヤ、放電加工ワイヤ、及び、ホースワイヤを用いて製造される金属シート、並びに耐圧ホース、タイヤなどのゴム製品等に関する。
【0002】
【従来の技術】
一般に、スチールコードなど伸線された高炭素鋼極細線は、必要に応じて熱間圧延した後に調整冷却した直径4.0〜6.0mmの線材を一次伸線加工後、最終パテンティング処理を行ない、その後ブラスメッキ処理をへて最終湿式伸線加工により製造されている。このような極細鋼線の多くは、2本撚り、5本撚りなどの撚り線加工を施した状態でスチールコードとして使用されている。これらのスチールコードにおいては、
1)より高強度であること、
2)高速伸線性が優れていること、
3)疲労特性が優れていること、
4)高速撚り線性が優れること、
などの特性を具備しなければならない。このため、従来から上述した特性を有する高品質の鋼材が開発されている。
【0003】
例えば、特開昭60−204865号公報には、Mn含有量を0.3%未満に規制して鉛パテンティング後の過冷組織の発生を抑え、C,Si,Mn等の元素量を規制することによって、撚り線時の断線が少なく高強度および高靭延性の極細線およびスチールコード用高炭素鋼線材が開示されており、また、特開昭63−24046号公報には、Si含有量を1.00%以上とすることによって鉛パテンディング材の引張強さを高くして伸線加工率を小さくした高靭性高延性極細線用線材が開示されている。
【0004】
しかし、より高強度の高張力鋼線の開発と共に、軽量化が計れるスチール補強の方法が望まれている。
【0005】
【発明が解決しようとする課題】
本発明の課題は、スチールコード、ホースワイヤなどに用いられる0.15〜0.35mmの高強度鋼線において、より高速で伸線加工が施された線材を更に加工した扁平ワイヤを更に織物加工した金属シート、また、金属シートをゴムに埋め込んだゴム製品を提供することにある。
【0006】
【課題を解決するための手段】
本発明は上記課題を解決するために示されたもので、その要旨は次のとおりである。
(1)質量%で、C:0.6〜1.3%、Si:0.1〜1.0%、Mn:0.1〜1.0%、P:≦0.02%、S:≦0.02%を含有し、残部がFe及び不可避的不純物からなる鋼であって、引張強さ:3.0GPa 以上、絞り:30%以上を有し、かつ横断面の形状が、幅W、厚みtとした時、W/t≧2を有することを特徴とする扁平ワイヤを織物加工によりシート状としたことを特徴とする金属シート。
【0007】
(2)前記扁平ワイヤが、幅W、厚みtとした時、W/t≧2となるように平圧加工により製造されたことを特徴とする上記(1)記載の金属シート。
【0008】
(3)前記扁平ワイヤが、質量%で、更に、Cr:0.05〜2.0%を含有する鋼であることを特徴とする上記(1)又は(2)記載の金属シート。
【0009】
(4)上記(1)〜(3)の何れかに記載の金属シートを構成する扁平ワイヤ同士に隙間を設けたことを特徴とする金属シート。
【0010】
(5)上記(1)〜(4)の何れかに記載の金属シートをゴムの補強に用いたことを特徴とするゴム製品。
【0011】
【発明の実施の形態】
まず、鋼組成の限定理由について説明する。成分は全て質量%である。
Cは強化に有効な元素であり高強度の鋼線を得るためにはC量を0.6%以上とすることが必要であるが、高すぎると初析セメンタイトが析出しやすいため、延性が低下し、かつ伸線性が劣化するのでその上限は1.3%とする。
【0012】
Siは鋼の脱酸のために必要な元素であり、従ってその含有量があまりに少ないとき、脱酸効果が不十分になるので0.1%以上添加する。また、Siは熱処理後に形成されるパーライト中のフェライト相に固溶しパテンティング後の強度を上げるが、反面、熱処理性を阻害するので2.0%以下とする。
Mnは鋼の焼き入れ性を確保するために0.1%以上のMnを添加する。しかし、多量のMnの添加は、パテンティングの際の変態時間を長くしすぎるので2.0%以下とする。
【0013】
Crは鋼の強度を高めるために添加する。添加する場合には、その効果の発揮される0.05%以上添加し、鋼線の延性を引き起こすことの無い1.5%以下とする。
従来の極細鋼線と同様に延性を確保するためSの含有量を0.02%以下とし、PもSと同様に線材の延性を害するのでその含有量を0.02%以下とする。
【0014】
必要に応じて以下の元素、Ni,V,Nb,Mo,Cu,Al,Ti,B,Ca,Mg,REMなどを添加する事ができる。
次に扁平ワイヤの形状の規定に関して説明する。従来のゴムの補強に用いられるスチールコードは丸線を撚り線加工するか丸線を束ねてるか織ってホースワイヤの補強などに使用されている。より軽量かつ補強ゴムを薄くするには補強用のスチールコードの強度を上げるなどの方法があるが、丸線で有る以上一定の厚みが必要となる。
【0015】
そこで、本発明者らは幅W、厚みtとした時、W/tが2となる平圧加工をワイヤに施すことを考案した。平圧加工されたワイヤはワイヤを織る際にもねじれなどが入らないため織りやすく、単位断面積あたりの補強線の面積を確保するためにもW/tを2以上とする。
さらに、このゴムシートをタイヤなどに使用した場合にも、シートの厚みが薄く均一であるためより軽量なタイヤが安価に製造可能となる。織り加工をした場合には、シートを薄く作製できるのでより軽量な耐圧ホースなどを作製するのに都合が良い。
【0016】
織る際にも扁平ワイヤの間隔を調整することにより単位断面積あたりの補強線の面積を調整する事が可能となる。
このように本発明の扁平ワイヤは、様々な耐圧ホース、コンベアベルト、タイミングベルトなどのゴム製品に利用可能である。
【0017】
【実施例】
以下に実施例に基づいて本発明を詳細に説明する。表1に試作に用いた供試鋼の化学成分を示す。表1に示す鋼を溶製し、連続鋳造で鋳造した後、熱間圧延でビレットした。このビレットを再加熱後、線材圧延により直径5.5mmの線材とし、ステルモアング処理を行った。この線材を酸洗した後、ブラスめっき処理した。その後、5.5mmから3.0mmまでの伸線加工を行った。この後、表2に示すa〜cは伸線加工により2mmの線径として平圧加工を行い幅約2mm、厚み0.1mmの平圧ワイヤとした。またd〜fは伸線加工により線径0.6mmとした後、平圧加工により、幅0.6mm、厚み0.3mmの平圧ワイヤとした。
【0018】
これらのワイヤの引張強さ、絞り、伸びの値を表2に示す。
比較法として丸線として同じ強度のスチールワイヤを製造した。比較法gは本発明法a〜cと同じ強度を持つ同じ断面積のワイヤとした。比較法hは本発明法d〜fと同じ強度を持つ同じ断面積のワイヤとした。
表2に示すように本発明法は比較法と比べスチールの厚みが半分となっており、ゴム等の厚みを薄くできることが判る。
【0019】
【表1】
【0020】
【表2】
【0021】
【発明の効果】
本発明を用いることで、ゴムなどの補強に使用できる鋼材の密度が上げられるのでゴム等の厚さを容易に薄くする事ができる。
【図面の簡単な説明】
【図1】本発明による扁平ワイヤを金属シートに織った場合の例を示す図である。[0001]
BACKGROUND OF THE INVENTION
The present invention is a steel cord, fishing line, cut wire, electric discharge machined wire, which is produced by processing a hot-rolled wire into a thinner wire diameter by wire drawing, and twisting a plurality of these . metal sheet produced using Hosuwai ya, and pressure hose, to rubber products such as such as tires.
[0002]
[Prior art]
Generally, high-carbon steel wires such as steel cords are subjected to final patenting treatment after primary wire drawing of a wire with a diameter of 4.0 to 6.0 mm that has been hot-rolled and adjusted and cooled as necessary. After that, it is manufactured by final wet wire drawing after brass plating. Many of such ultra fine steel wires are used as steel cords in a state in which stranded wire processing such as two strands and five strands is performed. In these steel cords,
1) higher strength,
2) Excellent high-speed wire drawing,
3) Excellent fatigue characteristics,
4) Excellent high-speed stranded wire property,
It must have the following characteristics. For this reason, high-quality steel materials having the above-described characteristics have been developed.
[0003]
For example, in Japanese Patent Application Laid-Open No. 60-204865, the Mn content is restricted to less than 0.3% to suppress the occurrence of supercooled structure after lead patenting, and the amount of elements such as C, Si, Mn is regulated. By doing so, a high-strength and high ductility ultrafine wire and a high carbon steel wire for steel cord with less breakage at the time of stranded wire are disclosed, and JP-A 63-24046 discloses Si content. A high toughness and highly ductile wire for a fine wire in which the tensile strength of the lead patenting material is increased to reduce the wire drawing rate by setting the content to 1.00% or more is disclosed.
[0004]
However, with the development of higher strength and high strength steel wire, a steel reinforcement method that can reduce the weight is desired.
[0005]
[Problems to be solved by the invention]
An object of the present invention, a steel cord, in the high strength steel wire 0.15~0.35mm used like a hose wire, further processed flat wire ya more wire drawing is performed at high speed yet textile processing metal sheets, also certain metals sheets to provide a rubber product embedded in rubber.
[0006]
[Means for Solving the Problems]
The present invention has been presented in order to solve the above problems, and the gist thereof is as follows.
(1) By mass%, C: 0.6 to 1.3%, Si: 0.1 to 1.0%, Mn: 0.1 to 1.0%, P: ≤ 0.02%, S: ≦ 0.02% of steel , the balance being Fe and inevitable impurities , having a tensile strength of 3.0 GPa or more, a drawing: 30% or more, and a cross-sectional shape having a width W A metal sheet characterized in that a flat wire characterized by having W / t ≧ 2 when the thickness is t is formed into a sheet shape by weaving .
[0007]
(2) The metal sheet according to (1), wherein the flat wire is manufactured by flat pressure processing so that W / t ≧ 2 when the width W and the thickness t are satisfied .
[0008]
( 3 ) The metal sheet according to the above (1) or (2) , wherein the flat wire is steel containing, in mass%, Cr: 0.05 to 2.0% .
[0009]
(4 ) A metal sheet, wherein a gap is provided between the flat wires constituting the metal sheet according to any one of (1) to (3) .
[0010]
( 5 ) A rubber product, wherein the metal sheet according to any one of ( 1) to (4) is used for rubber reinforcement.
[0011]
DETAILED DESCRIPTION OF THE INVENTION
First, the reason for limiting the steel composition will be described. All components are in weight percent.
C is an element effective for strengthening, and in order to obtain a high-strength steel wire, the C content needs to be 0.6% or more. However, if it is too high, proeutectoid cementite is likely to be precipitated. The upper limit is set to 1.3% because the wire drawability deteriorates.
[0012]
Si is an element necessary for deoxidation of steel. Therefore, when its content is too small, the deoxidation effect becomes insufficient, so 0.1% or more is added. Si is dissolved in the ferrite phase in the pearlite formed after the heat treatment to increase the strength after patenting.
Mn is added in an amount of 0.1% or more in order to ensure the hardenability of the steel. However, the addition of a large amount of Mn makes the transformation time during patenting too long, so it is made 2.0% or less.
[0013]
Cr is added to increase the strength of the steel. When added, 0.05% or more where the effect is exerted is added to 1.5% or less without causing ductility of the steel wire.
The content of S for as with conventional ultrafine steel wire to secure the ductility and 0.02% or less, P be you content thereof more than 0.02% since impair the ductility of the S as well as the wire.
[0014]
The following elements, Ni, V, Nb, Mo, Cu, Al, Ti, B, Ca, Mg, REM, etc. can be added as required.
Next, the definition of the shape of the flat wire will be described. Conventional steel cords used to reinforce rubber are used to reinforce hose wires by twisting round wires, bundling round wires, or weaving them. There are methods such as increasing the strength of the reinforcing steel cord to make the reinforcing rubber lighter and thinner, but a certain thickness is required as long as it is a round wire.
[0015]
Therefore, the present inventors have devised that the wire is subjected to flat pressure processing with W / t being 2 when the width is W and the thickness is t. The flat-pressed wire is easy to weave because it does not twist when the wire is woven, and W / t is set to 2 or more in order to secure the area of the reinforcing wire per unit cross-sectional area.
Further, even when this rubber sheet is used for a tire or the like, a lighter tire can be manufactured at a low cost because the thickness of the sheet is thin and uniform. When weaving, the sheet can be made thin, which is convenient for making a lighter pressure-resistant hose and the like.
[0016]
Even when weaving, the area of the reinforcing wire per unit cross-sectional area can be adjusted by adjusting the interval between the flat wires.
Thus, the flat wire of this invention can be utilized for rubber products, such as various pressure | voltage resistant hoses, a conveyor belt, and a timing belt.
[0017]
【Example】
Hereinafter, the present invention will be described in detail based on examples. Table 1 shows the chemical composition of the test steel used in the trial production. The steel shown in Table 1 was melted and cast by continuous casting, and then billeted by hot rolling. The billet was reheated, and then a wire rod having a diameter of 5.5 mm was formed by wire rolling, and a steer moaning treatment was performed. The wire was pickled and then subjected to brass plating. Thereafter, wire drawing from 5.5 mm to 3.0 mm was performed. Thereafter, a to c shown in Table 2 were subjected to flat pressure processing by drawing to a wire diameter of 2 mm to obtain a flat pressure wire having a width of about 2 mm and a thickness of 0.1 mm. In addition, d to f were flattened wires having a width of 0.6 mm and a thickness of 0.3 mm by flattening after a wire diameter of 0.6 mm was obtained by drawing.
[0018]
Table 2 shows the values of tensile strength, drawing and elongation of these wires.
As a comparison method, a steel wire having the same strength as a round wire was manufactured. The comparative method g was a wire having the same strength as the inventive methods a to c and having the same cross-sectional area. The comparison method h was a wire with the same cross-sectional area having the same strength as the methods d to f of the present invention.
As shown in Table 2, it can be seen that the method of the present invention has half the thickness of the steel compared to the comparative method, so that the thickness of rubber or the like can be reduced.
[0019]
[Table 1]
[0020]
[Table 2]
[0021]
【The invention's effect】
By using the present invention, the density of a steel material that can be used for reinforcement of rubber or the like can be increased, so that the thickness of rubber or the like can be easily reduced.
[Brief description of the drawings]
FIG. 1 is a view showing an example in which a flat wire according to the present invention is woven into a metal sheet.
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001115896A JP4520660B2 (en) | 2001-04-13 | 2001-04-13 | Metal sheet and rubber product using flat wire |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001115896A JP4520660B2 (en) | 2001-04-13 | 2001-04-13 | Metal sheet and rubber product using flat wire |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2002309347A JP2002309347A (en) | 2002-10-23 |
JP4520660B2 true JP4520660B2 (en) | 2010-08-11 |
Family
ID=18966722
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001115896A Expired - Fee Related JP4520660B2 (en) | 2001-04-13 | 2001-04-13 | Metal sheet and rubber product using flat wire |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4520660B2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK2993246T3 (en) * | 2013-04-30 | 2019-05-13 | Nippon Steel & Sumitomo Metal Corp | FLAT STEEL WIRE |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06344714A (en) * | 1993-06-03 | 1994-12-20 | Goodyear Tire & Rubber Co:The | Large-load pneumatic tire |
JPH07113119A (en) * | 1993-10-15 | 1995-05-02 | Kobe Steel Ltd | Production of extra fine steel wire having high strength and high toughness and ductility |
JPH11217779A (en) * | 1997-11-19 | 1999-08-10 | Bridgestone Corp | Material for reinforcing rubber product and pneumatic tire |
JP2000301913A (en) * | 1999-04-16 | 2000-10-31 | Yokohama Rubber Co Ltd:The | Pneumatic radial tire |
-
2001
- 2001-04-13 JP JP2001115896A patent/JP4520660B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06344714A (en) * | 1993-06-03 | 1994-12-20 | Goodyear Tire & Rubber Co:The | Large-load pneumatic tire |
JPH07113119A (en) * | 1993-10-15 | 1995-05-02 | Kobe Steel Ltd | Production of extra fine steel wire having high strength and high toughness and ductility |
JPH11217779A (en) * | 1997-11-19 | 1999-08-10 | Bridgestone Corp | Material for reinforcing rubber product and pneumatic tire |
JP2000301913A (en) * | 1999-04-16 | 2000-10-31 | Yokohama Rubber Co Ltd:The | Pneumatic radial tire |
Also Published As
Publication number | Publication date |
---|---|
JP2002309347A (en) | 2002-10-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5162875B2 (en) | High strength wire rod excellent in wire drawing characteristics and method for producing the same | |
JP2735647B2 (en) | High strength and high ductility steel wire and method for producing high strength and high ductility extra fine steel wire | |
JP2500786B2 (en) | Hot rolled steel wire rod, extra fine steel wire and twisted steel wire, and method for producing extra fine steel wire | |
KR100194431B1 (en) | Excellent high strength steel wire and high strength steel wire with fatigue characteristics | |
WO2008044356A1 (en) | High-strength steel wire excelling in ductility and process for producing the same | |
JP2003082437A (en) | High strength steel wire having excellent strain age embrittlement resistance and longitudinal crack resistance, and production method therefor | |
JPH02210078A (en) | Fishing line | |
JP2609387B2 (en) | High-strength high-toughness ultrafine steel wire wire, high-strength high-toughness ultrafine steel wire, twisted product using the ultrafine steel wire, and method for producing the ultrafine steel wire | |
JP5304323B2 (en) | Wire material for high-strength steel wire, high-strength steel wire, and production method thereof | |
JP3283332B2 (en) | High-strength ultrafine steel wire with excellent stranded wire workability and method for producing the same | |
JP3001572B1 (en) | High-strength, high-ductility ultrafine steel wire, stranded wire, and method for producing the same | |
JP4520660B2 (en) | Metal sheet and rubber product using flat wire | |
JP3814070B2 (en) | High-strength ultrafine steel wire and method for producing the same | |
JP3267833B2 (en) | High-strength extra-fine steel wire with excellent fatigue properties and method for producing the same | |
JP3061918B2 (en) | Method of manufacturing steel cord with excellent fatigue properties | |
JPH06271937A (en) | Production of high strength and high toughness hyper-eutectoid steel wire | |
JP3984393B2 (en) | High-strength steel wire without delamination and method for producing the same | |
JP2003334606A (en) | Production method for high strength extra-fine steel wire | |
JP3388012B2 (en) | Method of manufacturing steel wire for steel cord with reduced delamination | |
JPH06145895A (en) | High sterength and high toughness steel wire rod, extra fine steel wire using the same steel wire rod, production therefor and straded steel wire | |
JPH062039A (en) | Production of extra fine wire of medium carbon steel | |
JP2888727B2 (en) | Steel wire for steel cord having excellent fatigue strength and method for producing the same | |
JP3036393B2 (en) | High strength and high toughness hot-dip galvanized steel wire and method for producing the same | |
JPH06312209A (en) | Ultra-fine steel wire excellent in wire-drawability and fatigue strength and its manufacture | |
JP3428502B2 (en) | Steel wire, extra fine steel wire and twisted steel wire |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070903 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20090821 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090901 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091027 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100511 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100521 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130528 Year of fee payment: 3 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 4520660 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130528 Year of fee payment: 3 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140528 Year of fee payment: 4 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
LAPS | Cancellation because of no payment of annual fees |