JP4514693B2 - Evaporation concentration processing equipment - Google Patents

Description

  The present invention relates to an evaporation concentration processing apparatus.

  Conventionally, as a device for removing alkali components and volatile acid components from waste liquid containing alkali components and volatile acid components discharged from a factory that manufactures electronic components and the like, a wastewater treatment device as disclosed in Patent Document 1 It has been known.

  As shown in FIG. 5, a wastewater treatment apparatus disclosed in Patent Document 1 includes a raw water tank 101 that stores waste liquid containing an alkali component and a volatile acid component, and a deaerator 102 that removes alkali components in the waste liquid. And an evaporator 103 for evaporating and condensing the waste liquid.

In order to remove the alkaline component and the volatile acid component from the waste liquid using the wastewater treatment apparatus 100 configured as described above, first, water is used so that the pH of the waste liquid stored in the raw water tank 101 is 4 to 5. Sodium oxide is fed into the waste liquid to produce the sodium salt of the volatile acid component. Next, after removing the alkaline component in the waste liquid in the deaerator 102, the waste liquid is evaporated and concentrated in the evaporator 103, the water vapor generated in the evaporator 103 is condensed and recovered as condensed water, and volatile. The sodium salt of the acid component is recovered as a concentrate.
JP 2002-143850 A

  However, since the wastewater treatment apparatus disclosed in Patent Document 1 is for removing the alkaline component in the waste liquid with a deaerator, it is difficult to sufficiently remove the alkaline component from the waste liquid for treatment. There was a problem.

  In addition, since the waste liquid whose pH is adjusted to 4 to 5 by supplying sodium hydroxide is evaporated and concentrated in the evaporator, the volatile acid component that is not generated as a sodium salt remains in the waste liquid that is evaporated and concentrated. When the waste liquid is evaporated and concentrated in the evaporator, there is also a problem that the volatile acid component in the waste liquid evaporates and shifts to the condensed water. As a result, in order to reuse or drain the condensed water, it is necessary to remove the volatile acid component again from the condensed water, and it is difficult to efficiently remove and process the volatile acid component from the waste liquid. There was also a problem of being.

  The present invention has been made to solve such problems, and an object of the present invention is to provide an evaporative concentration apparatus capable of processing waste liquid efficiently and reliably.

The above-mentioned object of the present invention is an evaporative concentration treatment apparatus for evaporating and concentrating a waste liquid containing an alkali component and a volatile acid component, which contains a volatile acid component by evaporating the waste liquid mixed with a neutralizing acid. A volatile acid component is produced by evaporating a first evaporator that generates and discharges steam, and a neutralized liquid generated by neutralizing and condensing the volatile acid component-containing steam discharged from the first evaporator. A second evaporator that generates and discharges the removed steam, and the second evaporator includes a heat transfer tube through which the volatile acid component-containing steam discharged from the first evaporator passes. An evaporator disposed, an alkaline liquid spraying device for spraying an alkaline liquid for neutralization to a volatile acid component-containing steam passing through the heat transfer tube, and a volatile acid component-containing steam sprayed with an alkaline liquid being transferred to the vaporizer. Neutralization liquid produced by condensation in the heat pipe A volatile acid passing through the heat transfer tube, comprising: a reflux unit that leads to the evaporator; and a supply device that supplies the neutralized liquid guided by the reflux unit and stored in the evaporator to the outer surface of the heat transfer tube By heat exchange between the component-containing steam and the neutralization liquid supplied to the outer surface of the heat transfer tube, the neutralization liquid evaporates on the outer surface of the heat transfer tube to generate steam from which volatile acid components have been removed. This is achieved by an evaporative concentration processor.
The evaporative concentration apparatus further includes a storage tank for storing a waste liquid containing an alkali component and a volatile acid component, and supplies the waste liquid mixed with the neutralizing acid to the first evaporator in the storage tank. It is preferable that it is comprised.

  The apparatus further includes a detection device that measures the pH of the neutralized liquid stored in the evaporator of the second evaporator, and the alkaline liquid spraying device sprays the alkaline liquid based on the measurement value of the detection device. It is preferable to provide an on-off valve for controlling the amount.

  Further, the apparatus further includes a condensing device that generates condensed water by condensing at least a part of the steam discharged from the second evaporator, and the condensing device converts the generated condensed water to the second evaporator. It is preferably configured to be refluxed to the evaporator.

  Further, at least a part of the steam discharged from the second evaporator can be supplied to the first evaporator as a heating source for generating volatile acid component-containing steam in the first evaporator. It is preferable.

  ADVANTAGE OF THE INVENTION According to this invention, the evaporative concentration processing apparatus which can process a waste liquid efficiently and reliably can be provided.

  An evaporative concentration apparatus for evaporating and concentrating water in a waste liquid containing an alkali component and a volatile acid component according to the present invention will be described with reference to the accompanying drawings. FIG. 1 is a schematic configuration diagram of an evaporation concentration processing apparatus according to an embodiment of the present invention. As shown in FIG. 1, the evaporative concentration processing apparatus 1 includes a PH adjusting device 10, an ejector 20, a first evaporator 30, a second evaporator 50, and a condensing device 80.

  The PH adjusting device 10 is a device that adjusts the pH of the waste liquid by neutralizing an alkali component such as ammonia dissolved in the waste liquid supplied from a waste liquid tank (not shown) to generate a neutralized salt. The PH adjusting device 10 includes a storage tank 11, an acid supply device 12, and a stock solution supply pipe 13. The storage tank 11 is a tank for storing a waste liquid containing an alkali component and a volatile acid component supplied from a waste liquid tank (not shown). The acid supply device 12 is a device that supplies an acid for neutralization into the storage tank 11, and an acid storage section 12 a that stores acid and an acid supply path 12 b that guides the acid in the acid storage section 12 a to the storage tank 11. And. The stock solution supply pipe 13 is a pipe that guides the waste liquid mixed with the neutralizing acid in the storage tank 11 to the evaporator 31 of the first evaporator 30.

  As the acid supplied from the acid supply device 12, an acid capable of generating a neutralized salt by neutralizing an alkali component in the waste liquid is employed. When the alkaline component in the waste liquid is, for example, ammonia, for example, sulfuric acid, hydrochloric acid, or nitric acid can be employed as the acid supplied from the acid supply device 12. In particular, it is preferable to employ sulfuric acid from the viewpoint of producing a neutralized salt with low metal corrosivity.

  The ejector 20 is a vapor compression means for sucking and compressing the vapor. The vapor suction side 21 extends from a vapor supply line 23 through which a vapor supplied from a vapor supply source (not shown) flows and the second evaporator 50. A steam reuse line 54 is connected. In addition, a steam supply line 24 for heating that guides the steam compressed by the ejector 20 to the first evaporator 30 is connected to the discharge side 22 of the ejector 20.

  The first evaporator 30 generates a concentrated liquid and a volatile acid component-containing steam by evaporating and concentrating the waste liquid mixed with the neutralizing acid in the PH adjusting device 10, and the volatile acid component-containing steam is generated. It is a device for discharging. The first evaporator 30 includes a sealed evaporator 31, a stock solution spraying device 32, an indirect heater 33, a steam transfer pipe 34, and a condensed water drain pipe 35.

  The bottom part of the evaporator 31 constitutes a storage part for storing waste liquid mixed with the neutralizing acid supplied from the PH adjusting device 10.

  The stock solution spraying device 32 is a supply device that supplies waste liquid stored at the bottom of the evaporator 31 toward the outer surfaces of the plurality of heat transfer tubes 39. The stock solution is disposed on the top of the evaporator 31 and sprays the waste solution. A spray nozzle 36 and a circulation pipe 37 that connects the stock solution spray nozzle 36 and the bottom of the evaporator 31 are provided. A circulation pump 37 a that guides waste liquid stored at the bottom of the evaporator 31 to the stock solution spray nozzle 36 is provided in the middle of the circulation pipe 37. In addition, the circulation line 37 is connected to a concentrate discharge line 38 for discharging the concentrated liquid accumulated at the bottom of the evaporator 31 at the end of the evaporation concentration process to the outside.

  The indirect heater 33 includes a plurality of heat transfer tubes 39 provided inside the evaporator, and a first header 40 and a second header 41 respectively connected to both ends of the plurality of heat transfer tubes 39. The first header 40 is connected to a heating steam supply pipe 24 that guides the steam compressed by the ejector 20 to the heat transfer pipe 39. Connected to the second header 41 is a heating steam discharge pipe 42 that guides the steam guided from the first header 40 through the heat transfer pipe 39 to a condenser 80 described later.

  The vapor transfer pipe 34 is a pipe that discharges the volatile acid component-containing steam generated in the first evaporator 30 and leads it to the indirect heater 53 of the second evaporator 50 described later. And the first header 60 constituting the indirect heater 53 of the second evaporator 50 are connected.

  The condensed water drain conduit 35 is a conduit for discharging condensed water accumulated in the second header 41 of the indirect heater 33, one end of which is connected to the lower portion of the second header 41, and the other end to be described later. It is connected to a condensed water discharge line 82 connected to the condenser 80.

  The second evaporator 50 is a steam and concentrated liquid from which volatile acid components have been removed by evaporating a neutralized liquid generated by neutralizing and condensing the volatile acid component-containing steam discharged from the first evaporator 30. In which the vapor from which the volatile acid component has been removed is discharged.

  The second evaporator 50 includes a sealed evaporator 51, a neutralization liquid spraying device 52, an indirect heater 53, an alkaline liquid spraying device 64, a steam reuse pipe 54 and a neutralization liquid reflux pipe 55. ing. The basic configurations of the evaporator 51, the neutralization liquid spraying device 52 and the indirect heater 53 are the same as the basic configurations of the evaporator 31, the stock solution spraying device 32 and the indirect heater 33 that constitute the first evaporator 30 described above. Therefore, detailed description is omitted. The concentrated liquid discharge pipe 58 branched from the circulation pipe 57 constituting the neutralizing liquid spraying device 52 is branched from the circulation pipe 37 constituting the stock solution spraying apparatus 32 of the first evaporator 30. It is connected to the concentrate discharge line 38.

  The alkaline liquid spraying device 64 is a device that sprays the neutralizing alkaline liquid onto the volatile acid component-containing steam passing through the heat transfer tube 59. The alkaline liquid spraying device 64 includes an alkaline liquid tank 65 that stores the alkaline liquid, and an alkaline liquid spray nozzle that sprays the alkaline liquid guided through the alkaline liquid supply pipe 66 as shown in the enlarged view of the main part of FIG. 67. In the present embodiment, the alkaline liquid spray nozzle 67 is arranged in the vapor transfer pipe 34 so that the sprayed alkaline liquid is supplied into the heat transfer pipe 59 via the first header 60. The installation position of the alkaline liquid spray nozzle 67 is not particularly limited. For example, a configuration in which the alkaline liquid spray nozzle 67 is installed in the first header 60 may be employed.

  Further, the alkaline liquid spraying device 64 is configured to be able to control the spraying amount of the alkaline liquid based on the pH of the neutralizing liquid stored in the evaporator 51 of the second evaporator 50 as described later. Specifically, it is configured to include an on-off valve 68 that controls the amount of alkaline liquid to be sprayed based on the measured value of the PH monitor 69 installed in the circulation line 57 constituting the neutralizing liquid spraying device 52. ing. The PH monitor 69 is a detection device that measures the pH of the neutralized liquid stored in the evaporator 51 and passing through the circulation pipe 57. The on-off valve 68 includes a motor M, and by driving the motor M, the opening degree of the on-off valve 68 can be adjusted to control the amount of alkaline liquid to be sprayed.

  The neutralizing alkaline liquid sprayed from the alkaline liquid spraying device 64 is an alkali capable of neutralizing a volatile acid component contained in the steam led from the first evaporator 30 to generate a neutralized salt. Adopt liquid. When the volatile acid component is, for example, formic acid, for example, an aqueous sodium hydroxide solution or an aqueous calcium hydroxide solution can be employed as the alkaline solution. In particular, from the viewpoint of producing a neutralized salt having high solubility, it is preferable to employ an aqueous sodium hydroxide solution as the alkaline solution.

  The steam reuse pipe 54 serves as a heat source for generating at least a part of the steam discharged from the second evaporator 50 in the first evaporator 30 as a heat source for generating volatile acid component-containing steam. This is a pipe for supplying the gas, and connects the upper part of the evaporator 51 and the suction side 21 of the ejector 20. In the middle of the steam reuse pipe 54, a condensing steam pipe 70 is connected to guide the steam from which the volatile acid component generated in the second evaporator 50 has been removed to a condenser 80 described later. . The condensing steam line 70 is connected to a heating steam discharge line 62 extending from the second header 61, passes through the articulated heater 53, and condenses the steam that has not been converted into the neutralizing liquid. 80 so that it can be led to 80.

  The neutralization liquid reflux pipe 55 is formed by condensing the volatile acid component-containing vapor passing through the heat transfer pipe 59 while passing through the heat transfer pipe 59, and the neutralization liquid collected in the second header 61. This is a conduit that leads to the evaporator 51, and connects the lower part of the second header 61 and the lower part of the evaporator 51.

  The condensing device 80 is a device that generates condensed water by cooling and condensing the steam guided from the first evaporator 30 and the second evaporator 50, and the steam recycling pipe 54 of the second evaporator 50. A condensing steam line 70 branched from the cooling water, a cooling water supply line 81 through which cooling water is guided, and a condensed water discharge line 82 for discharging the generated condensed water to the outside are connected. As the cooling water guided to the condensing device 80 through the cooling water supply pipe 81, industrial water cooled by a cooling tower (not shown), cold water (chiller water) cooled by a refrigeration device, or the like can be used. In the middle of the condensed water discharge line 82, a makeup water line 83 connected to the bottom of the evaporator 51 of the second evaporator 50 is connected, and the condensed water generated in the condensing device 80 is condensed into the second evaporator 50. The bottom of the evaporator 51 can be recirculated and replenished. A condensed water drain line 35 extending from the lower part of the second header 41 of the first evaporator 30 is connected to the condensed water discharge line 82.

  A method for treating a waste liquid containing an alkali component and a volatile acid component using the evaporation concentration treatment apparatus 1 configured as described above will be described below. The case where the alkaline component contained in the waste liquid is ammonia, the volatile acid component is formic acid, and the waste liquid as a whole exhibits alkalinity will be described. A case will be described in which sulfuric acid is used as the acid mixed in the PH adjusting device 10 and a sodium hydroxide aqueous solution is used as the alkaline liquid sprayed from the alkaline liquid spraying device 64 of the second evaporator 50.

  First, waste liquid containing ammonia and formic acid is supplied from a waste liquid tank (not shown) to the storage tank 11 of the PH adjusting device 10. Then, sulfuric acid is supplied from the acid supply device 12 to the storage tank 11, and the ammonia contained in the waste liquid stored in the storage tank 11 is neutralized to generate ammonia sulfate (neutralized salt). At this time, from the viewpoint of reliably recovering ammonia contained in the waste liquid as ammonia sulfate, the amount of sulfuric acid supplied is adjusted so that the pH of the waste liquid after PH adjustment is 4 to 5. The waste liquid mixed with sulfuric acid is guided to the bottom of the evaporator 31 of the first evaporator 30 via the stock solution supply line 13.

  The waste liquid stored at the bottom of the evaporator 31 of the first evaporator 30 passes through the circulation pipe 37 by the action of the circulation pump 37 a and is supplied to the stock solution spray nozzle 36. The waste liquid supplied to the stock solution spray nozzle 36 is sprayed to the outer surface of each heat transfer tube 39 in the indirect heater 33 by the stock solution spray nozzle 36, supplied via the heating steam supply pipe 24, and supplied to the heat transfer tube 39. Heat is exchanged with steam passing through the interior. By this heat exchange, part of the water in the waste liquid evaporates and steam is generated. At this time, formic acid contained in the waste liquid is also vaporized along with the evaporation of water. The formic acid gas-containing steam generated in this way is guided to the second evaporator 50 through the steam transfer pipe 34 connected to the upper portion of the evaporator 31.

  Waste liquid that has not evaporated on the outer surface of each heat transfer tube 39 flows down along the outer surface of each heat transfer tube 39, returns to the waste liquid stored at the bottom of the evaporator 31, and passes through the circulation pipe 37 again. To the stock solution spray nozzle 36. The waste liquid at the bottom of the evaporator 31 is circulated through the circulation line 37 until the evaporation and concentration process is completed. At the end of the evaporative concentration process, the concentrated liquid accumulated at the bottom of the evaporator 31 is discharged to the outside through the concentrated liquid discharge line 38.

  The steam supplied through the heating steam supply pipe 24 is cooled by heat exchange with the waste liquid sprayed on the outer surface of the heat transfer pipe 39 to become condensed water, and is below the second header 41 of the indirect heater 33. It will be accumulated in. The condensed water is guided to the condensed water discharge pipe 82 via the condensed water drain pipe 35. The steam that has not been converted into condensed water is guided to the condensing device 80 via the heating steam discharge pipe 42.

  The waste liquid stored in the evaporator 31 contains ammonia sulfate and sulfuric acid in addition to formic acid vaporized by the heating action of the heat transfer tube 39, but the ammonia sulfate and sulfuric acid are not vaporized by the heating action of the heat transfer tube 39. Therefore, it accumulates at the bottom of the evaporator 31 and is discharged to the outside through the concentrate discharge pipe 38 as a concentrate at the end of the evaporation and concentration process of the first evaporator 30. That is, the ammonia contained in the waste liquid can be reliably removed from the waste liquid as ammonia sulfate.

  The formic acid gas-containing steam discharged from the first evaporator 30 and led to the second evaporator 50 through the steam transfer pipe 34 passes through the heat transfer pipe 59 of the indirect heater 53. The formic acid gas-containing vapor that passes through the inside of the heat transfer tube 59 is stored in advance at the bottom of the evaporator 51 of the second evaporator 50 and is heated with water sprayed from the neutralizing liquid spray nozzle 56 onto the outer surface of the heat transfer tube 59. By exchange, it is converted into condensed water, collected in the second header 61, and guided to the bottom of the evaporator 51 of the second evaporator 50 via the neutralizing liquid reflux pipe 55. Formic acid dissolves in the generated condensed water.

  At this time, since the aqueous sodium hydroxide solution is sprayed from the alkaline liquid spraying device 64 into the heat transfer tube 59, the formic acid gas contained in the steam passing through the heat transfer tube 59 or the heat transfer tube 59 is used. Formic acid contained in the generated condensed water is neutralized to produce sodium formate (neutralized salt). That is, the condensed water accumulated in the second header 61 becomes a neutralized liquid containing sodium formate. From the viewpoint of reliably recovering the formic acid gas-containing steam and the formic acid in the condensed water generated in the heat transfer tube 59 as sodium formate, the alkaline liquid spraying device 64 so that the measured value by the PH monitor 69 is, for example, 10-11. It is preferable to control the amount of the alkaline liquid sprayed by adjusting the opening degree of the on-off valve 68.

  The neutralized liquid introduced to the bottom of the evaporator 51 of the second evaporator 50 through the neutralized liquid reflux pipe 55 passes from the neutralized liquid spray nozzle 56 through the circulation pipe 57 to the outer surface of the heat transfer pipe 59. Sprayed on. The neutralized liquid sprayed on the outer surface of the heat transfer tube 59 exchanges heat with the formic acid gas-containing steam passing through the heat transfer tube 59 and is converted into steam on the outer surface of the heat transfer can 59. A part of the steam generated on the outer surface of the heat transfer tube 59 is discharged through the steam reuse pipe 54 and led to the first evaporator 30 as a heating source of the first evaporator 30. The remaining steam is guided to the condensing device 80 via the condensing steam line 70 and converted into condensed water.

  The neutralization liquid guided by the neutralization liquid reflux line 55 and stored in the evaporator 51 contains sodium formate and sodium hydroxide which is an alkali for neutralization. These sodium formate and sodium hydroxide are included. Is not vaporized by the heating action of the heat transfer pipe 59, and therefore accumulates at the bottom of the evaporator 51 and is discharged to the outside as a concentrated liquid via the concentrated liquid discharge pipe 58 at the end of the evaporation and concentration process of the second evaporator 50. . That is, formic acid contained in the waste liquid can be reliably removed from the waste liquid as sodium formate.

  Next, steam led from the second header 41 of the indirect heater 33 of the first evaporator 30 to the condensing device 80 via the heating steam discharge pipe 42, from above the evaporator 51 of the second evaporator 50. The steam guided to the condensing device 80 via the steam reuse pipe 54 and the condensing steam pipe 70, and the heating steam discharge pipe 62 from the second header 61 of the indirect heater 53 of the second evaporator 50. The steam guided to the condensing device 80 via the condensing steam pipe 70 is converted into condensed water by heat exchange with the cooling water passing through the cooling water supply pipe 81 in the condensing apparatus 80, and the condensed water discharge pipe. It is discharged to the outside through the path 82. A part of the condensed water passing through the condensed water discharge pipe 82 is guided to the bottom of the evaporator 51 of the second evaporator 50 via a makeup water pipe 83 provided in the middle of the condensed water discharge pipe 82. By the heating action of the indirect heater 53 of the second evaporator 50, it is converted into steam as a heating source of the first evaporator 30. The amount of condensed water led to the bottom of the evaporator 51 of the second evaporator 50 via the makeup water pipe 83 is provided, for example, by providing a level sensor inside the evaporator 51 of the second evaporator 50. It is preferable to adjust so that the liquid volume of the liquid mixture of the neutralization liquid stored in the evaporator 51 and condensed water may become constant based on the detected value from.

  Thus, according to the evaporative concentration treatment apparatus 1 according to the present embodiment, the first evaporator 30 can reliably remove the alkali component in the waste liquid as a neutralized salt concentrate, and the second evaporator At 50, the volatile acid component in the waste liquid can be reliably removed as a concentrated solution of neutralized salt. As a result, since the alkali component and the volatile acid component in the waste liquid are not transferred to the steam discharged from the second evaporator 50, the condensed water generated by cooling the steam in the condensing device is effectively recycled. It can be used or drained to the outside as it is.

  Further, in the present embodiment, before the waste liquid containing an alkali component and a volatile acid component stored in a waste liquid tank (not shown) is guided to the first evaporator 30, neutralization is performed in the storage tank 11 of the PH adjusting device 10. Since the acid is mixed with the waste liquid, the neutralized salt of the alkali component and the neutralizing acid in the waste liquid removed as the concentrated liquid in the first evaporator 30 can be generated efficiently and reliably. it can.

  In the present embodiment, the pH of the neutralized liquid stored in the evaporator 51 of the second evaporator 50 is measured by the PH monitor 69 installed in the circulation line 57, and the alkaline liquid is measured based on the measured value. Since the amount of the neutralizing alkaline liquid sprayed from the spraying device 64 can be controlled, all the volatile acid components contained in the neutralizing liquid stored in the evaporator 51 are removed as neutralized salts. It is possible to reliably spray an amount of alkali liquid that can be obtained.

  Further, the second evaporator 50 causes the neutralized liquid generated in the heat transfer pipe 59 to flow back to the evaporator 51 through the neutralized liquid reflux pipe 55, and this neutralized liquid is supplied by the neutralized liquid spraying device 52. Since the heat transfer tube 59 is configured to be able to be dispersed on the outer surface, the neutralized liquid generated in the heat transfer tube 59 is used as a refrigerant to be used for heat exchange with the steam passing through the heat transfer tube 59. can do. Since the neutralized liquid produced in the heat transfer tube 59 contains water contained in the waste liquid evaporated by the first evaporator 30, steam contained in the waste liquid flows through the heat transfer pipe 59. Therefore, it can be effectively used as a refrigerant for heat exchange.

  Furthermore, since the second evaporator 50 includes a steam reuse pipe line 54 that connects the upper portion of the evaporator 51 and the ejector 20, at least a part of the steam generated in the second evaporator 50 is supplied to the first evaporator 50. It can lead to the evaporator 30 and can be utilized as a heating source for generating a volatile acid component-containing vapor. As a result, it is possible to increase the energy efficiency and efficiently perform the evaporation concentration process. Since the steam generated in the second evaporator 50 is obtained by changing the state of the water contained in the waste liquid, the water contained in the waste liquid can be effectively used as a heat medium for the first evaporator 30. Become.

  Further, in the present embodiment, at least a part of the condensed water generated in the condensing device 80 is recirculated to the bottom of the evaporator 51 of the second evaporator 50 via the makeup water pipe 83, and the condensed water is supplied to the The two evaporators 50 are configured to evaporate. As described above, at least a part of the generated steam is guided to the first evaporator 30 via the steam reuse pipe 54, and a heating source for generating the volatile acid component-containing steam. Therefore, the condensed water generated in the condensing device 80 can be effectively used as a heat medium for the first evaporator 30.

  As mentioned above, although one Embodiment of this invention was described, the specific aspect of this invention is not limited to the said embodiment. For example, in the present embodiment, the PH adjustment device 10 includes a storage tank 11 and employs a configuration in which the storage tank 11 is mixed with a neutralizing acid, but the storage tank 11 is omitted and the first evaporation is performed. A configuration in which the neutralizing acid is directly mixed in the evaporator 31 of the vessel 30 may be employed.

  In the present embodiment, the PH monitor 69 for measuring the pH of the neutralized liquid stored in the evaporator 41 of the second evaporator 50 is configured to be installed in the circulation line 57. For example, a configuration in which the PH monitor 69 is installed in the evaporator 51 of the second evaporator 50 may be employed.

  Further, as shown in FIG. 3, partition members 40 a and 41 b for partitioning the inside of the first header 40 and the second header 41 of the indirect heater 33 constituting the first evaporator 30 are installed, and the inside of the first header 40 After being introduced to the second header 41 through the heat transfer tube 39a, the steam introduced into the first header 40 is introduced into the first header 40 through the heat transfer tube 39b, and further through the heat transfer tube 39c. It may be configured to be guided. With such a configuration, it is possible to increase the distance that the steam passes through the heat transfer tube 39, and thus it is possible to efficiently generate the volatile acid component-containing steam. Similarly, in the second evaporator 50, partition members 60a and 61a may be installed. In this case, it is preferable that the condensed water accumulated on the partition members 60a and 61a is guided to the evaporator 51 of the second evaporator.

  Moreover, as shown in FIG. 4, you may employ | adopt the structure further provided with the aeration apparatus 90 which isolate | separates alcohol gas from the aqueous solution containing alcohol, and the alcohol absorption apparatus 91 which absorbs and collect | recovers alcohol gas. In the case of adopting such a configuration, partition members 60a and 61a for partitioning the inside of the first header 60 and the second header 61 of the indirect heater 53 of the second evaporator 50 are installed, and the steam transfer pipe 34 is provided. After the volatile acid component-containing steam introduced into the first header 60 is guided to the second header 61 via the heat transfer pipe 59a, the steam is further guided to the first header 60 via the heat transfer pipe 59b. The second header 61 is led through the heat transfer pipe 59c and then led to the alcohol absorption device 91 through the alcohol-containing steam supply pipe 92. Further, the condensed water containing alcohol accumulated on the partition member 61 a installed in the second header 61 is configured to be guided to the aeration apparatus 90 via the alcohol-containing water supply pipe 93.

  By adopting such a configuration, for example, even when the waste liquid containing ammonia and formic acid further contains alcohol, it is possible to reliably remove ammonia, formic acid and alcohol from the waste liquid. More specifically, the waste liquid containing ammonia, formic acid and alcohol is converted into steam containing formic acid gas and alcohol gas by the heating action of the heat transfer tube 39 in the first evaporator 30, and is passed through the steam transfer line 34. Guided to the second evaporator 50. Ammonia contained in the waste liquid is removed as a concentrated ammonium sulfate solution.

  Since the formic acid component contained in the steam guided to the second evaporator 50 is removed by the neutralization reaction with the alkaline liquid sprayed from the alkaline liquid spraying device 64 when passing through the heat transfer tube 59a, the formic acid gas The alcohol gas-containing steam from which the gas has been removed passes through the heat transfer pipes 59b and 59c of the second evaporator 50 and is led to the alcohol absorbing device via the alcohol-containing steam supply pipe 92. In addition, a part of the steam containing alcohol is cooled and converted into condensed water containing alcohol when passing through the heat transfer tube 59. However, since alcohol has a lower condensation temperature than water, Almost no alcohol is contained in the condensed water produced by the heat tubes 59a and 59b, and alcohol is contained in the condensed water produced by the heat transfer tube 59c.

  The alcohol gas in the alcohol gas-containing steam guided to the alcohol absorption device 91 is absorbed and removed by the alcohol absorption device 91. Further, the condensed water generated in the heat transfer pipe 59c is accumulated on the partition member 61a provided in the second header 61, and is led to the aeration device 90 through the alcohol-containing water supply pipe 93, and alcohol gas is extracted from the condensed water. Are separated. The separated alcohol gas is guided to the alcohol absorption device 91 and absorbed and removed.

  In this way, by adopting the configuration shown in FIG. 4, even if the waste liquid containing the alkali component and the volatile acid component further contains an alcohol component, the alkali component, volatile property from the waste liquid is obtained. The acid component and the alcohol component can be reliably removed.

It is a schematic block diagram which shows the evaporative concentration processing apparatus which concerns on this invention. It is a principal part enlarged view of the alkaline liquid dispersion | spreading apparatus which comprises the evaporative concentration processing apparatus shown in FIG. It is a schematic block diagram which shows the modification of the evaporative concentration processing apparatus shown in FIG. It is a schematic block diagram which shows the modification of the evaporative concentration processing apparatus shown in FIG. It is a schematic block diagram which shows the conventional waste water treatment equipment.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Evaporation concentration processing apparatus 30 1st evaporator 50 2nd evaporator 51 Evaporation can 52 Condensate spraying apparatus 55 Condensate reflux pipe 59 Heat transfer pipe 64 Alkaline liquid spraying apparatus

Claims (5)

An evaporative concentration apparatus for evaporating and concentrating a waste liquid containing an alkali component and a volatile acid component,
A first evaporator that generates and discharges a volatile acid component-containing vapor by evaporating the waste liquid mixed with the neutralizing acid;
The second evaporation that generates and discharges the vapor from which the volatile acid component is removed by evaporating the neutralized liquid generated by neutralizing and condensing the volatile acid component-containing vapor discharged from the first evaporator. And equipped with
The second evaporator includes an evaporator in which a heat transfer tube through which the volatile acid component-containing steam discharged from the first evaporator passes is disposed;
An alkaline liquid spraying device for spraying an alkaline liquid for neutralization to the volatile acid component-containing steam passing through the heat transfer tube;
Reflux means for guiding the neutralized liquid generated by condensing the volatile acid component-containing steam, in which the alkali liquid is dispersed, in the heat transfer tube to the evaporator,
A supply device for supplying the neutralized liquid guided by the reflux means and stored in the evaporator to the outer surface of the heat transfer tube;
Due to the heat exchange between the volatile acid component-containing steam passing through the heat transfer tube and the neutralization solution supplied to the outer surface of the heat transfer tube, the neutralization solution evaporates on the outer surface of the heat transfer tube, and the volatile acid An evaporative concentration apparatus that generates steam from which components have been removed.   The apparatus further comprises a storage tank that stores waste liquid containing an alkali component and a volatile acid component, and is configured to supply waste liquid mixed with neutralizing acid to the first evaporator in the storage tank. The evaporation concentration processing apparatus according to claim 1. A detector for measuring the pH of the neutralized liquid stored in the evaporator of the second evaporator;
The evaporative concentration treatment apparatus according to claim 1, wherein the alkaline liquid spraying device includes an on-off valve that controls an amount of alkaline liquid sprayed based on a measurement value of the detection device. Further comprising a condensing device for generating condensed water by condensing at least a part of the steam discharged from the second evaporator,
The evaporative concentration apparatus according to any one of claims 1 to 3, wherein the condensing device is configured to recirculate the generated condensed water to an evaporator of the second evaporator. At least a part of the steam discharged from the second evaporator is configured to be supplied to the first evaporator as a heating source for generating volatile acid component-containing steam in the first evaporator. The evaporative concentration processing apparatus according to any one of claims 1 to 4.

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