JP4390831B2 - Sealed water evaporation inhibitor composition - Google Patents

Sealed water evaporation inhibitor composition Download PDF

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JP4390831B2
JP4390831B2 JP2007305592A JP2007305592A JP4390831B2 JP 4390831 B2 JP4390831 B2 JP 4390831B2 JP 2007305592 A JP2007305592 A JP 2007305592A JP 2007305592 A JP2007305592 A JP 2007305592A JP 4390831 B2 JP4390831 B2 JP 4390831B2
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JP2009127355A (en
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隆雄 五十嵐
浩悠基 吉本
秀樹 浦辺
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隆雄 五十嵐
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本発明は、排水口部や配管等に取り付けられる水封型排水トラップの封水の蒸発防止剤組成物及び該組成物を用いた封水の蒸発防止方法に関し、より詳しくは、封水となる水と混合されて使用され該封水の蒸発を防止可能な蒸発防止剤組成物及び蒸発防止方法に関する。   The present invention relates to an anti-evaporation agent composition for sealing water in a water-sealed drain trap attached to a drain outlet, piping, and the like, and a method for preventing evaporation of sealed water using the composition. The present invention relates to an evaporation inhibitor composition that is used by being mixed with water and can prevent evaporation of the sealed water, and an evaporation prevention method.

従来より、浴槽、浴室、洗面台、流し台など使用によって排水が生じる各種の排水機器には、使用によって生じた排水を床下配管など下水側等に排出する排水装置が取り付けられている。これらの排水装置には、一般に下水側からの臭気や、害虫や小動物類が屋内側に侵入することを防止する機能を有する水封型排水トラップが備えられる。この水封型排水トラップは、排水流路中に水封部という排水が溜まる部分を設けて、下水側からの臭気や害虫や小動物が屋内に入ることを防止する。かかる水封型排水トラップの種類としては、以下に述べるものを例としてあげることができる。例えば、図5(a)の洗面台10においては、水道栓12の出口から出る水を受けるシンク14の排水の吸い込み口の直下の管をS字型にし、水封部を設け封水18を溜めたSトラップ型の水封型排水トラップが用いられている。このSトラップ型の水封型排水トラップを過ぎた配管20は、鉛直下方向に伸びている。また、図5(b)では、Pトラップ型の水封型排水トラップを用いる排水系40が示されている。漏斗のような排水を受ける受け部42は、P字を横に倒したような形で曲げられた配管44においては、同様に下に凸の屈曲部に水封部が設けられ、封水46が溜められている。これにより、排水管のその先48から来る臭気等を遮断することができる。また、図5(c)では、U字型に配管を屈曲させて封水を溜めたUトラップ型の水封型排水トラップを用いる排水系60が示されている。ここでも同様に、U字型の配管が水封部を形成し、溜められた封水64により、配管の左側62と右側66が遮断されている。   2. Description of the Related Art Conventionally, various drainage devices that generate drainage by using a bathtub, bathroom, washstand, sink, and the like have been attached with a drainage device that discharges the drainage generated by use to the sewage side such as an underfloor pipe. These drainage devices are generally provided with a water-sealed drain trap having a function of preventing odors from the sewage side, pests and small animals from entering the indoor side. This water-sealed drain trap is provided with a portion of water drainage in the drainage channel where water is collected, and prevents odors, pests and small animals from the sewage side from entering the room. Examples of such water-sealed drain traps include those described below. For example, in the wash basin 10 of FIG. 5 (a), the pipe immediately below the suction port for drainage of the sink 14 that receives water from the outlet of the water tap 12 is formed into an S-shape, and a water seal is provided to provide the sealed water 18 A stored S-trap water-sealed drain trap is used. The pipe 20 that has passed this S-trap type water-sealed drain trap extends vertically downward. FIG. 5B shows a drainage system 40 using a P-trap water-sealed drain trap. In the pipe 44 bent in such a manner that the P-shaped side is tilted sideways, the receiving portion 42 that receives drainage such as a funnel is similarly provided with a water-sealing portion at a downwardly convex bent portion, and the sealing water 46 Is accumulated. Thereby, the odor etc. which come from the tip 48 of a drain pipe can be interrupted | blocked. FIG. 5C shows a drainage system 60 that uses a U-trap type water-sealed drain trap in which pipes are bent in a U-shape to store sealed water. Here, similarly, the U-shaped pipe forms a water sealing portion, and the left side 62 and the right side 66 of the pipe are blocked by the stored sealing water 64.

また、図5(d)に示すように、水洗便器80も一種の水封型排水トラップであるといえる。便器82の凹部には、封水84が溜められ、仕切り板86により、その先の排水管86からの臭気等を遮断している。更に、図5(e)には、台所の流し台、浴室の床などの排水口などで使用されている水封型排水トラップ100を示している。このような排水口は、上方が開放された有底筒状の本体106の底部のほぼ中央位置に配水管110を侵入させて立ち上がり部を設けている。この立ち上がり部の上から、下方開放の椀状又は吊りがね(ベル)状キャップ体104が被せられている。立ち上がり部と、有底筒状の本体106とにより、封水108を溜めることができる貯留部を形成し、キャップ体104の側壁により、臭気等を遮断する封水部を形成する。尚、キャップ体104の上には排水に混入した固形物を取り除くため、多数個の開口を有する円盤状の目皿102が配置されている。かかる水封型排水トラップ100は、通常、キャップ体104の形状がベル状(吊りがね状)または椀状を成すことからベルトラップまたはワントラップと称される。   Moreover, as shown in FIG.5 (d), it can be said that the flush toilet 80 is also a kind of water-sealed drain trap. Sealed water 84 is stored in the concave portion of the toilet 82, and the partition plate 86 blocks odors and the like from the drain pipe 86 ahead. Further, FIG. 5 (e) shows a water-sealed drain trap 100 used in a kitchen sink, a drain outlet such as a bathroom floor. Such a drain outlet is provided with a rising portion by allowing the water distribution pipe 110 to enter the substantially central position of the bottom of the bottomed cylindrical main body 106 opened upward. From above the rising portion, a cap member 104 having a hook-like shape or a hook-shaped (bell) shape that is open downward is covered. The rising portion and the bottomed cylindrical main body 106 form a storage portion that can store the sealing water 108, and the side wall of the cap body 104 forms a sealing portion that blocks odors and the like. A disc-shaped eye plate 102 having a large number of openings is disposed on the cap body 104 in order to remove solid matter mixed in the drainage. Such a water-sealed drain trap 100 is usually referred to as a belt wrap or one trap because the shape of the cap body 104 is bell-shaped (hanging-shaped) or hook-shaped.

上述のように、水封型排水トラップにおいては、封水として用いられる水が臭気等を遮断するために重要な役割を果たしている。これらの水封型排水トラップにおいては、排水毎にその一部を水封部に貯留させて水封を行っているため、頻繁に排水が行われている場合には問題がないが、排水頻度が少なくなると、封水としての水の自然蒸発により、臭気等を遮断する機能を有しなくなるおそれがある。特に図5(e)で示したベルトラップ型またはワントラップ型の水封型排水トラップは、水封される水の量が少なく、かつ開口部の面積が大きい為、封水の蒸発が激しく夏季などは短期間でトラップの役目を果たせなくなってしまうおそれがある。特に、長期間旅行等で自宅を留守にしていた場合、賃貸住宅の長期間契約が決まらず空室だった場合、長期間使用しない別荘等の場合では、水の蒸発による機能低下は頻繁に起きており、部屋中が不快な下水の悪臭で満ちてしまったり、夥しい数の害虫や小動物類が室内に侵入したりといった実害が生じた事例もある。更に、ボイラー室や発電室などの高温雰囲気下の屋内に設置された排水トラップでは、封水の蒸発速度が早くなるため比較的短い期間に上述のようなことが生じる。   As described above, in the water-sealed drain trap, water used as sealed water plays an important role in order to block odors and the like. In these water-sealed drain traps, a part of each drainage is stored in the water-sealed part and sealed, so there is no problem when draining frequently. When the amount of water is reduced, there is a possibility that the function of blocking odors or the like may not be provided due to natural evaporation of water as sealed water. In particular, the belt-wrap type or one-trap type water-sealed drain trap shown in FIG. 5 (e) has a large amount of water to be sealed and a large area of the opening. There is a risk that it will not be able to serve as a trap in a short period of time. In particular, if you are away from home for long periods of time, if the long-term contract for rental housing is not vacant, or if you are not in a villa that is not used for a long period of time, the function deterioration due to water evaporation will frequently occur. In some cases, the room was filled with unpleasant sewage odors, and a large number of pests and small animals entered the room. Further, in a drain trap installed indoors in a high-temperature atmosphere such as a boiler room or a power generation room, the above-mentioned phenomenon occurs in a relatively short period because the evaporation rate of the sealed water is increased.

従って、定期的に水封型排水トラップの封水を監視し、減少した封水を適宜補充する必要があるが、賃貸住宅の空室を定期的に循環訪問したり、わざわざ使用していない別荘を訪問したりして、多数ある排水トラップすべての封水の減少を点検し、補充するには、多大な労力がかかり、経済的にも好ましいものではない。そのため、例えば特許文献1では、水封型排水トラップの水封部分の封水が蒸発して無くなっても悪臭の侵入を遮断できるように、排水吸込口を密閉封鎖可能な構成とした排水トラップが開示されている。更に、特許文献2には、水封型排水トラップの封水の蒸発による減少分を自動的に補水して封水を長期間維持するための自動補水器が開示されている。
特開2000−328625号公報 特開2004−332472号公報
Therefore, it is necessary to regularly monitor the sealed water in the water-sealed drain trap and replenish the reduced sealed water as appropriate, but periodically visit the vacant space of the rental housing or do not bother to use it. In order to check and replenish the sealing water of all the drain traps, it takes a lot of labor and is not economically preferable. Therefore, for example, in Patent Document 1, there is a drain trap that has a configuration in which the drain suction port can be hermetically sealed so that the intrusion of bad odor can be blocked even if the sealed water in the water seal portion of the water sealed drain trap evaporates and disappears. It is disclosed. Further, Patent Document 2 discloses an automatic water replenisher for automatically replenishing a decrease caused by evaporation of the sealed water in a water-sealed drain trap and maintaining the sealed water for a long period of time.
JP 2000-328625 A JP 2004-332472 A

しかし、特許文献1に開示された排水トラップは、封水減少による臭気を防止するもので、水封型排水トラップの機能自体を回復させるものではない。この技術では、臭気を防止する機能が十分ではないだけでなく、通常の排水口としての機能を阻害する。即ち、排水の都度に排水吸込口の開閉操作を毎回行う必要がある。従って、誤って排水吸込口を開口せずに排水してしまうと排水がなされず、排水口付近で水があふれてしまうおそれがある。   However, the drain trap disclosed in Patent Document 1 prevents odor due to a decrease in seal water, and does not restore the function of the water seal drain trap itself. In this technique, not only the function of preventing odor is not sufficient, but also the function as a normal drain is hindered. That is, it is necessary to open and close the drain suction port every time drainage is performed. Therefore, if the water is accidentally drained without opening the drain suction port, the drainage is not performed, and there is a possibility that the water overflows in the vicinity of the drain port.

また、特許文献2に開示された封水自動補水器は、排水トラップの封水の蒸発による減少分を自動的に補水して封水を長期間維持するための装置であるが、水の蒸発を停止するものではないのでいずれ自動封水補水器の水もなくなり、水封型排水トラップの機能を失うことになる。仮に、より長期に維持しようとすれば、封水自動補水器は大型にならざるを得ず、設置の容易さ、コストにおいて十分な解決になっていない。特に、通常1軒の家屋の中には、浴室、浴槽、洗面台、流し台等少なくとも3〜4ヶ所の排水トラップがあり、一つ一つかかる封水自動補水器を備えられるとなれば、設置の労力も多大になってしまう。   In addition, the automatic water sealer disclosed in Patent Document 2 is a device for automatically replenishing the decrease due to evaporation of the sealing water in the drain trap and maintaining the sealed water for a long time. Since there is no stoppage, the water in the automatic water-sealing water replenisher will eventually disappear and the function of the water-sealed drain trap will be lost. If it is to be maintained for a longer period of time, the automatic water sealer must be large, and is not a sufficient solution in terms of ease of installation and cost. In particular, a house usually has at least 3 to 4 drainage traps such as a bathroom, a bathtub, a wash basin, a sink, etc. The labor of will also become enormous.

以上のような課題に鑑みて、本発明では、水封型排水トラップの封水部の封水の蒸発を効果的に防止できる蒸発防止剤組成物を提供する。また、かかる組成物を用いて、封水部の封水の蒸発を効果的に防止できる方法を提供する。   In view of the above problems, the present invention provides an evaporation inhibitor composition that can effectively prevent evaporation of the sealing water in the sealing portion of the water-sealed drain trap. Moreover, the method which can prevent effectively the evaporation of the sealing water of a sealing part using this composition is provided.

本発明の水封型排水トラップの封水蒸発防止剤組成物は、封水として用いられる水と混合して使用され、水封型排水トラップにおける水の蒸発を効果的に防止できるものである。また、かかる封水蒸発防止剤組成物を水と混合して、排水口から流すことにより、容易に水封型排水トラップの封水としての水の蒸発を効果的に防止することができる。   The sealing water evaporation inhibitor composition of the water-sealed drain trap of the present invention is used by mixing with water used as sealing water, and can effectively prevent water evaporation in the water-sealed drain trap. Moreover, by evaporating the sealed water evaporation inhibitor composition from water and flowing it from the drain port, it is possible to effectively prevent evaporation of water as the sealed water of the water-sealed drain trap.

この封水蒸発防止剤組成物は、比重が水よりも小さく、蒸気圧が水よりも小さい油系成分を主成分とする。更に、封水蒸発防止剤組成物は、界面活性剤を含んでよい。また、封水の蒸発を防止する方法は、所定量の封水蒸発防止剤組成物を所定の割合で水と混合し、撹拌後、排水口へ流すことを特徴とする。 This sealed water evaporation inhibitor composition has as its main component an oil-based component having a specific gravity smaller than that of water and a vapor pressure smaller than that of water. Furthermore, the sealed water evaporation inhibitor composition may contain a surfactant. Moreover, the method for preventing evaporation of the sealing water is characterized in that a predetermined amount of the sealing water evaporation inhibitor composition is mixed with water at a predetermined ratio, and after stirring, is allowed to flow to a drain outlet.

具体的には、以下のようなものを提供することができる。
(1)比重が1.0未満で、蒸気圧が水よりも低い油系成分と、水系成分とを含む排水トラップの封水蒸発防止剤組成物。
Specifically, the following can be provided.
(1) A sealant evaporation inhibitor composition for a drain trap, comprising an oil component having a specific gravity of less than 1.0 and a vapor pressure lower than that of water, and an aqueous component.

(2)更に、界面活性剤を含む上記(1)記載の封水蒸発防止剤組成物。 (2) The sealant evaporation inhibitor composition according to (1), further comprising a surfactant.

(3)油系成分は、油脂、流動パラフィン、アルコール、ケトン、アルデヒド、エステル、シリコーン、炭化水素から少なくとも1種類以上を含むことを特徴とする上記(1)又は(2)に記載の封水蒸発防止剤組成物。 (3) Sealed water as described in (1) or (2) above, wherein the oil component contains at least one or more of fats, liquid paraffin, alcohol, ketone, aldehyde, ester, silicone and hydrocarbon An evaporation inhibitor composition.

(4)比重が1.0未満で、蒸気圧が水よりも低い油系成分と、水系成分とを混合し、撹拌して、排水トラップに投入する排水トラップの封水蒸発防止方法。 (4) A method for preventing evaporation of sealed water in a drain trap, in which an oil-based component having a specific gravity of less than 1.0 and a vapor pressure lower than that of water and an aqueous component are mixed, stirred, and introduced into a drain trap.

(5)更に、界面活性剤とを混合し、撹拌して、排水トラップに投入する上記(4)に記載の封水蒸発防止方法。 (5) The sealing water evaporation prevention method according to the above (4), further mixed with a surfactant, stirred, and put into a drain trap.

ここで、当該封水蒸発防止剤組成物中において、上記油系成分を1〜99質量%含むことが好ましい。また、上記水系成分については、1〜99質量%含むことが好ましい。従って、この封水蒸発防止剤組成物は、上記油系成分を1〜99質量%含み残部を上記水系成分としてもよい。 Here, in the said sealing water evaporation inhibitor composition, it is preferable to contain 1-99 mass% of said oil-based components . Moreover, about the said aqueous component, it is preferable to contain 1-99 mass%. Therefore, the sealed water evaporation inhibitor composition may contain 1 to 99% by mass of the oil component and the balance may be the water component.

また、当該封水蒸発防止剤組成物中において、更に、上記界面活性剤を0.001〜30質量%含むことが好ましい。そして、当該封水蒸発防止剤組成物中において、上記油系成分及び上記水系成分が合わせて70〜99質量%となり、残部を上記界面活性剤としてもよい。 Moreover, in the said sealing water evaporation inhibitor composition, it is preferable to contain 0.001-30 mass% of said surfactant further. And in the said sealing water evaporation inhibitor composition, the said oil-based component and the said water-system component are 70-99 mass% in total, and it is good also considering the remainder as the said surfactant.

また、当該封水蒸発防止剤組成物は、上記油系成分、上記水系成分、又は上記界面活性剤の何れにも属さない成分を含んでよい。例えば、色素、防腐剤等の所定の機能を果たす液体又はこの封水蒸発防止剤組成物に溶解若しくは十分に分散する固体成分を含んでよい。 Moreover, the said sealing water evaporation inhibitor composition may contain the component which does not belong to any of the said oil-type component , the said water-system component, or the said surfactant. For example, it may contain a liquid that performs a predetermined function such as a dye or a preservative, or a solid component that is dissolved or sufficiently dispersed in the sealed water evaporation inhibitor composition.

上記油系成分は、油脂類、流動パラフィン類、アルコール類、ケトン類、アルデヒド類、エステル類、シリコーン類、炭化水素類から少なくとも1種類以上を含んでよい。特に、油脂類、流動パラフィン類、シリコーン類が好ましい。ここで流動パラフィンは、常温では無色の液体で非揮発性であるが、わずかに臭うものである。水には不溶である。第3種有機溶剤で引火性があり危険物に該当する。化学的に安定な物質で、通常の条件では酸化を受けない。乳化しやすくのびや浸透性に優れる。純度は紫外光の吸光度により計測できる。流動パラフィンは、例えば、ヌジョール(nujol)、ミネラルスピリット、ミネラルターペン、ホワイトスピリット、ホワイト油、白色鉱油、石油スピリット、ミネラルシンナー、ペトロリウムスピリット、水パラフィン、ミネラルオイル、ミネラルオイルホワイト、医療用パラフィン(medicinal paraffin)、パラフィンファックス、saxol、USP mineral oil、adepsine oil、Albolene、glymol等を含んでよい。 The oil component may contain at least one or more of oils and fats, liquid paraffins, alcohols, ketones, aldehydes, esters, silicones, and hydrocarbons. In particular, oils and fats, liquid paraffins, and silicones are preferable. Here, liquid paraffin is a colorless liquid and non-volatile at room temperature, but has a slight odor. Insoluble in water. It is a Class 3 organic solvent and is flammable. It is a chemically stable substance and does not undergo oxidation under normal conditions. It is easy to emulsify and has excellent spread and permeability. Purity can be measured by the absorbance of ultraviolet light. Liquid paraffin is, for example, nujol, mineral spirit, mineral turpentine, white spirit, white oil, white mineral oil, petroleum spirit, mineral thinner, petrolium spirit, water paraffin, mineral oil, mineral oil white, medical paraffin ( medical paraffin), paraffin fax, saxol, USP mineral oil, adepine oil, Albolene, glymol, and the like.

また、シリコーン(silicone)は、シロキサン結合を骨格とした高分子有機化合物(ポリマー)である。比較的分子量の小さいものはポリシロキサン(polysiloxane)とも呼ばれる。構造的にはケトンの主鎖の炭素がケイ素に置き換わった分子であり、本来はシリカケトン(silica ketone)であるが、略称としてシリコーンと呼ばれている。   Silicone is a high molecular organic compound (polymer) having a siloxane bond as a skeleton. Those having a relatively low molecular weight are also called polysiloxanes. Structurally, it is a molecule in which the carbon of the main chain of the ketone is replaced by silicon, and is originally a silica ketone, but is abbreviated as silicone.

排水トラップの封水蒸発防止方法においては、排水トラップにおける既に貯留されている封水と空気(相)との界面の間に、不揮発性の層を形成することを特徴とすることができる。しかしながら、排水トラップにおいて、排水口側の封水と空気(相)との界面へは容易にアクセスできるが、下水側の封水と空気(相)との界面へは容易にアクセスできない。排水口側であれば、排水口から不揮発性の層を形成する水よりも比重が小さい油系成分等を投入すればよい。しかしながら、下水側には直接アクセスする手段がなく、敢えて行えるとすれば、可曲性のパイプ若しくはチューブを下水側まで差し込みそのパイプ若しくはチューブにかかる油系成分を投入することができる。この場合であっても、パイプ若しくはチューブ内に封水が流れ込まないようにしなければならない。流れ込んだ封水がかかる油系成分が下水側に移動することを妨げるからである。本発明の封水蒸発防止方法においては、このような比重が低い油系成分を水系成分と混合し分散させることにより、分散された混合物の見かけの比重が水の比重に近く、排水口から投入される勢いにより、封水トラップの底部近傍若しくはそれを越えて下水側になるところまで、かかる分散された混合物を移動させることができる。その後、浮力により油系成分が分離して、封水の表面まで上昇するが、既に底部若しくは下水側に移動しているので、少なくとも一部は、下水側の封水と空気(相)との界面へ到達し、封水と空気(相)との直接接触を防止できる。例えば、比重1.0未満、蒸気圧が水よりも低い油系成分(1〜99質量%)と、水系成分(1〜99質量%)とを混合し、分散させて、排水トラップに投入する。分散をより容易にするために、界面活性剤(0.001〜30質量%)を更に加え、撹拌などで分散させることがより好ましい。 In the method for preventing sealing water evaporation of the drain trap, a non-volatile layer can be formed between the interface between the seal water already stored in the drain trap and air (phase). However, in the drain trap, the interface between the sealed water on the drain outlet side and the air (phase) can be easily accessed, but the interface between the sealed water on the sewage side and the air (phase) cannot be easily accessed. On the drain outlet side, an oil component or the like having a specific gravity smaller than that of water forming a nonvolatile layer may be introduced from the drain outlet. However, if there is no means for direct access to the sewage side, and if it can be done deliberately, a bendable pipe or tube can be inserted into the sewage side and oil-based components applied to the pipe or tube can be introduced. Even in this case, it is necessary to prevent the sealing water from flowing into the pipe or tube. It is because the oil-based component which the sealed water which flowed in prevents from moving to the sewage side. In the sealed water evaporation prevention method of the present invention, by mixing and dispersing the oil-based component having such a low specific gravity with the water-based component, the apparent specific gravity of the dispersed mixture is close to the specific gravity of water, and is introduced from the drain outlet. Due to the momentum applied, such dispersed mixture can be moved to the vicinity of the bottom of the sealing trap or beyond it to the sewage side. Thereafter, the oil-based components are separated by buoyancy and rise to the surface of the sealed water, but have already moved to the bottom or the sewage side, so at least a part of the sewage side sealed water and air (phase) It reaches the interface and can prevent direct contact between the sealed water and air (phase). For example, an oil component (1-99% by mass) having a specific gravity of less than 1.0 and a vapor pressure lower than that of water and an aqueous component (1-99% by mass) are mixed, dispersed, and put into a drain trap. . In order to make the dispersion easier, it is more preferable to further add a surfactant (0.001 to 30% by mass) and disperse by stirring or the like.

ここで、上記油系成分の沸点は、水の沸点以上であることが好ましい。油系成分とは、実質的に水に溶解しないものであればよい。例えば、多少溶解しても、不溶部分が溶解せずに残り、混合、乳化の後にこの不溶部分が相分離できればよい。尚、水に対する溶解度が、室温で1%以下であることがより好ましい。蒸気圧が低いとは、蒸発し難いことを意味することができる。例えば、室温で、蒸気圧が20mmHg以下であると好ましい。更に好ましくは、10mmHg以下である。そして、1mmHg以下であればより一層好ましい。この油系成分は、液体である。また、その比重は、水よりも小さいものが好ましく、例えば、0.999以下が好ましい。また、より好ましくは、0.95以下である。素早い相分離という観点から、0.9以下であればより一層好ましい。しかしながら、比重があまりに小さく、また、撥水性の高い流体の場合は、相分離が急速に起こるおそれがあり、また、分散が十分に行われないおそれがある。尚、このような油系成分は、2以上の化合物を混合することにより物理的に及び/又は化学的に生成されてもよい。また、水の表面にその層を広げやすい比較的粘度の低いものが好ましい。また、水が拡散して表面に出難いように、被覆性が高い方が好ましい。 Here, the boiling point of the oil component is preferably equal to or higher than the boiling point of water. The oil component may be any component that does not substantially dissolve in water. For example, even if it dissolves to some extent , the insoluble part remains undissolved, and it is sufficient that the insoluble part can be phase-separated after mixing and emulsification. The solubility in water is more preferably 1% or less at room temperature. A low vapor pressure can mean that it is difficult to evaporate. For example, it is preferable that the vapor pressure is 20 mmHg or less at room temperature. More preferably, it is 10 mmHg or less. And it is still more preferable if it is 1 mmHg or less. This oil component is a liquid. Further, the specific gravity is preferably smaller than water, for example, 0.999 or less. More preferably, it is 0.95 or less. From the viewpoint of quick phase separation, 0.9 or less is even more preferable. However, when the specific gravity is too small and the fluid has high water repellency, phase separation may occur rapidly, and dispersion may not be sufficiently performed. Such oil-based components may be physically and / or chemically generated by mixing two or more compounds. Moreover, the thing with a comparatively low viscosity which can spread the layer on the surface of water is preferable. Further, it is preferable that the covering property is high so that water is difficult to diffuse and come out on the surface.

本発明による水封型排水トラップの封水蒸発防止剤組成物は特別な装置も必要とせず、長期間封水の蒸発を防止し、本来の水封型排水トラップの機能を長期間維持することが可能である。   The sealing water evaporation inhibitor composition of the water-sealed drain trap according to the present invention does not require any special equipment, prevents evaporation of the sealing water for a long time, and maintains the function of the original water-sealed drain trap for a long time. Is possible.

以下、図面を参照しつつ、本発明の実施例について詳しく説明するが、これは本発明を理解するために記述されるのであって、本発明の範囲を限定するものではない。   Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. However, the embodiments are described for understanding the present invention and do not limit the scope of the present invention.

図1(a)から(e)は、本発明の封水蒸発防止剤組成物を適用した排水システムを図解する。排水システムの基本構成は、上述する図5(a)から(e)と共通するため、ここでは重複する説明は省略する。図1(a)において、封水18は、封水部に溜められているが、大気と接する自由表面に相当する部分に、本発明の封水蒸発防止剤組成物から構成される成分22が層状に広がっている。この成分は液体であり、水18よりも比重が小さく、水18の表面に層を形成する。この成分は、水よりも蒸発がし難く、長時間大気中に曝されても蒸発により、層が薄くなり難い。例えば、水よりも常温において蒸気圧が低い、又は、水よりも沸点が高い。また、その下にある水がかかる層内を拡散して、表面にでて蒸発することがし難いように、水の層内の拡散が低い成分となっている。このように封水18が蒸発する経路をかかる成分により蓋をするため、封水18の蒸発が極めて低く抑えられる。   FIGS. 1 (a) to (e) illustrate a drainage system to which the sealed water evaporation inhibitor composition of the present invention is applied. Since the basic configuration of the drainage system is the same as that shown in FIGS. 5A to 5E described above, redundant description is omitted here. In FIG. 1 (a), the sealed water 18 is stored in the sealed water portion, but the component 22 composed of the sealed water evaporation inhibitor composition of the present invention is formed on the portion corresponding to the free surface in contact with the atmosphere. It spreads in layers. This component is a liquid and has a specific gravity smaller than that of the water 18 and forms a layer on the surface of the water 18. This component is harder to evaporate than water, and even if it is exposed to the atmosphere for a long time, the layer does not easily become thin due to evaporation. For example, the vapor pressure is lower at room temperature than water, or the boiling point is higher than water. In addition, the diffusion of water in the layer is a low component so that the water underneath is difficult to diffuse in the layer and evaporate on the surface. Thus, since the path | route in which the sealing water 18 evaporates is covered with this component, the evaporation of the sealing water 18 can be suppressed to an extremely low level.

図1(b)、(c)、(d)、(e)において、それぞれ、同様な成分50、68、88、112がやはり封水46、64、84、108の表面を覆い、その蒸発を効果的に防いでいる。そのため、封水46、64、84、108の蒸発が極めて低く抑えられる。従って、水封型排水トラップの機能を長期間維持することが可能である。   In FIGS. 1 (b), (c), (d), and (e), similar components 50, 68, 88, and 112 also cover the surfaces of the sealed water 46, 64, 84, and 108, respectively. It is effectively preventing. Therefore, evaporation of the sealing waters 46, 64, 84, and 108 can be suppressed to an extremely low level. Therefore, it is possible to maintain the function of the water-sealed drain trap for a long time.

図2は、洗面台10を例にとり、本発明の封水蒸発防止剤組成物を適用する方法を図解するものである。水及び封水蒸発防止剤組成物に不活性な材質からなる容器200に所定量の封水蒸発防止剤組成物202が入っている。そこに、水道等の管204から水206を所定の割合で混合する。そして容器200の封をし、しばらく静置すると、下から水の相206、封水蒸発防止剤組成物の相202、空気の相208ができる。これを容器ごと上下に撹拌すると、分離していた下から水の相206及び封水蒸発防止剤組成物の相202が混ざり合って乳化した液体210ができる。容器200の蓋を開け、洗面台10のシンク14に流すと、既に封水18が溜められた封水部に、この混合物が流れ込む。投入される乳化した液体210が大量の場合は、図2の左下(b)のように、封水部に乳化した液体210が入れ替わって溜まる。しばらく時間が経つと、比重がより低い封水蒸発防止剤組成物が表面に広がり、封水の表面を覆い、蒸発を防止する(図1(a))。   FIG. 2 illustrates a method of applying the sealed water evaporation inhibitor composition of the present invention, taking the wash basin 10 as an example. A predetermined amount of the seal water evaporation inhibitor composition 202 is contained in a container 200 made of a material inert to the water and seal water evaporation inhibitor composition. There, water 206 is mixed from a pipe 204 such as a water supply at a predetermined ratio. When the container 200 is sealed and allowed to stand for a while, a water phase 206, a sealed water evaporation inhibitor composition phase 202, and an air phase 208 are formed from below. When this is stirred up and down together with the container, the water phase 206 and the phase 202 of the sealing water evaporation inhibitor composition are mixed together from below, and an emulsified liquid 210 is formed. When the lid of the container 200 is opened and poured into the sink 14 of the wash basin 10, this mixture flows into the sealed water portion where the sealed water 18 has already been stored. When a large amount of the emulsified liquid 210 is charged, the emulsified liquid 210 is exchanged and collected in the sealed portion as shown in the lower left (b) of FIG. After a while, the sealing water evaporation inhibitor composition having a lower specific gravity spreads on the surface, covers the surface of the sealing water, and prevents evaporation (FIG. 1 (a)).

一方、投入される乳化した液体210が少量の場合は、図2の右下(c)のように、封水部に溜められた封水に乳化した液体210が入り込み、封水部の底部を越えて、下水側に達する。しばらく時間が経つと、既に溜められた水と、投入により新たに加えられた水が合体し水相を底部に形成し、比重がより低い封水蒸発防止剤組成物は表面に広がる。このようにして、下水側にも投入された水に分散されて一体となって一緒に移動した封水蒸発防止剤組成物が封水の下水側の表面をも覆い、両側で封水の蒸発を防止する(図1(a))。   On the other hand, when the amount of the emulsified liquid 210 to be added is small, as shown in the lower right (c) of FIG. 2, the emulsified liquid 210 enters the sealed water stored in the sealed water portion, and the bottom of the sealed water portion is removed. It reaches over to the sewage side. After a while, the already accumulated water and the newly added water merge to form an aqueous phase at the bottom, and the sealed water evaporation inhibitor composition having a lower specific gravity spreads on the surface. In this way, the seal evaporation inhibitor composition that has been dispersed and moved together with the water introduced into the sewage side also covers the surface of the sewage on the sewage side, and the seal water evaporates on both sides. Is prevented (FIG. 1A).

封水の表面を何らかの方法で覆えば、蒸発を防げることは考え付くことができるが、狭い配水管の中、しかもS字に屈曲している反対側まで、封水の表面を覆うことは、物理的には極めて困難であったが、この方法では、容易に封水の表面を覆うことができ、しかも、覆っている組成物が液体であり、配水管を詰まらせることなく容易に流すことができる。また、油系成分を含む封水蒸発防止剤組成物であっては、BOD若しくはCODを悪化させるおそれもあり、図2(c)のように少量の封水蒸発防止剤組成物で封水の蒸発を防ぐことがより好ましい。   It can be thought that evaporation can be prevented if the surface of the sealed water is covered by any method. However, covering the surface of the sealed water up to the opposite side bent into the S-shape in a narrow water distribution pipe Although this method was extremely difficult, this method can easily cover the surface of the sealed water, and the covering composition is a liquid and can easily flow without clogging the water pipe. it can. Moreover, in the sealing water evaporation inhibitor composition containing an oil-based component, BOD or COD may be deteriorated. As shown in FIG. 2 (c), the sealing water may be sealed with a small amount of the sealing water evaporation inhibitor composition. More preferably, evaporation is prevented.

ここで、本発明の封水蒸発防止剤組成物に含まれる成分について、より詳しく述べる。本発明の封水蒸発防止剤組成物の主成分は、比重が水よりも小さく、蒸気圧が水よりも小さい油系成分である。通常食用としている各種の油脂類、流動パラフィン等の油系物質の他に、アルコール類、ケトン類、アルデヒド類、エステル類、シリコーン類(例えば、環状ポリアルキルシロキサン等)、各種精油類、炭化水素類等の油系物質があげられる。これらは、匂いの無いものまたは微弱なものか、不快な匂いでないものがその用途から考えると望ましい。これらは単体で用いても、二種以上の混合物で用いてもよい。即ち、図2において、水と混ぜる段階で、比重が水よりも小さく、蒸気圧が水よりも小さい水不溶性のものを生成すればよいため、化学反応等により、1又はそれ以上の種類の化合物を用いてもよい。このような主成分は、封水蒸発防止剤組成物中で、1〜99質量%の割合で配合される。この配合量が1質量%未満では目的とする蒸発防止能力に乏しくなるおそれがある。このような組成物を水なしで封水部に適用することも可能であるが、多くの場合油系の液体であるので、環境への負荷の面から少ない方が好ましい。
Here, the components contained in the sealed water evaporation inhibitor composition of the present invention will be described in more detail. The main component of the sealed water evaporation inhibitor composition of the present invention is an oil-based component having a specific gravity smaller than that of water and a vapor pressure smaller than that of water . In addition to various oils and fats, liquid paraffin and other oil-based substances that are usually used for food , alcohols, ketones, aldehydes, esters, silicones (eg, cyclic polyalkylsiloxanes), various essential oils, And oil-based substances such as hydrocarbons. From the viewpoint of use, it is desirable that these have no odor, are weak, or do not have an unpleasant odor. These may be used alone or in a mixture of two or more. That is, in FIG. 2, at the stage of mixing with water, a water-insoluble material having a specific gravity smaller than that of water and a vapor pressure smaller than that of water may be generated. May be used. Such a main component is mix | blended in the ratio of 1-99 mass% in a sealing water evaporation inhibitor composition. If the blending amount is less than 1% by mass, there is a possibility that the intended ability to prevent evaporation is poor. Although it is possible to apply such a composition to a sealing part without water, since it is an oil-based liquid in many cases, the smaller one is preferable from the surface of environmental load.

また、図2に示すように後から水を加えるのではなく、予め水系の液体と混ぜてそのまま排水管に流すことができる封水蒸発防止剤組成物とすることもできる。このような場合は、主成分としての油系成分は、環境への負荷の面から2〜30質量%が望ましい。この混ぜられる水系成分は、純水、軟水、蒸留水、通常の水道水等を例として挙げることができる。これらは単独で用いても、2種以上を組み合わせて用いてもよい。経済性、貯蔵安定性の点から、水道水、イオン交換水が好ましい。この水系成分は、封水蒸発防止剤組成物中で1〜99質量%の割合で配合されてよい。より好ましくは、10〜70質量%である。   Further, as shown in FIG. 2, it is also possible to prepare a sealed water evaporation inhibitor composition that is not added with water later but can be mixed with an aqueous liquid in advance and allowed to flow as it is into a drain pipe. In such a case, the oil component as the main component is preferably 2 to 30% by mass from the viewpoint of environmental load. Examples of the water-based component to be mixed include pure water, soft water, distilled water, and normal tap water. These may be used alone or in combination of two or more. From the viewpoints of economy and storage stability, tap water and ion-exchanged water are preferable. This aqueous component may be blended in the ratio of 1 to 99% by mass in the sealed water evaporation inhibitor composition. More preferably, it is 10-70 mass%.

本発明の封水型防止剤組成物には、更に、界面活性剤を含んでもよい。この界面活性剤は、主成分の油系成分と、後から加えられる水(封水蒸発防止剤組成物に水を加えて使用する場合)若しくは上述の水系成分(封水蒸発防止剤組成物をそのまま適用できる場合)と、を使用前に軽く上下に振るだけで内容物の油系成分が水中に乳化・分散できるものが好ましい。即ち、水封部分に投入する際に簡単な撹拌で、すばやく均一に混合できるようにする為に配合される。また、長期間放置される排水トラップ内の汚れを洗浄する効果を持たせることもできる。また、長期間放置される排水トラップに汚れが付着するのを防止するような効果を持たせることも可能である。更に、長期間放置された排水トラップを通常の使用状況に戻す際に、軽く水を流すだけで油系成分がすばやく排水トラップ中から排出されるようにする効果を持たせることもできる。このような界面活性剤としては、陰イオン界面活性剤、陽イオン界面活性剤、非イオン界面活性剤、両性界面活性剤のいずれも用いることができる。このような界面活性剤は、単体で用いても、二種以上の混合物で用いてもよい。上述する主成分である油系成分と、後から加えられる水(封水蒸発防止剤組成物に水を加えて使用する場合)若しくは上述の水系成分(封水蒸発防止剤組成物をそのまま適用できる場合)と、を排水トラップ中に投入する際に攪拌または振盪することにより、ほぼ均一に乳化・分散可能となるような量の界面活性剤を加えることが好ましい。即ち、油系成分と水系成分がほぼ均一に乳化・分散し、排水口に投入できる状態にできる界面活性剤の量であれば特に限られることはないが、一般には、0.001質量%以上が好ましく、30質量%以下が好ましい。更に好ましくは、5質量%以下である。   The water-sealing type inhibitor composition of the present invention may further contain a surfactant. This surfactant is composed of an oil component as a main component and water added later (when water is added to a sealant evaporation inhibitor composition) or the above-mentioned water component (sealed sealant composition). In which the oil component of the contents can be emulsified and dispersed in water by simply shaking it up and down before use. That is, it is blended so that it can be mixed quickly and uniformly with simple stirring when it is put into the water seal portion. In addition, it is possible to provide an effect of cleaning dirt in the drain trap that is left for a long time. It is also possible to provide an effect of preventing dirt from adhering to the drain trap that is left for a long period of time. Furthermore, when returning the drain trap that has been left for a long period of time to normal use, it is possible to provide an effect that the oil-based component is quickly discharged from the drain trap by simply flowing water. As such a surfactant, any of an anionic surfactant, a cationic surfactant, a nonionic surfactant, and an amphoteric surfactant can be used. Such a surfactant may be used alone or in a mixture of two or more. The oil component that is the main component described above and water added later (when water is added to the seal water evaporation inhibitor composition) or the above water component (sea seal water evaporation inhibitor composition) can be applied as it is. In a case where the surfactant is added to the drain trap, the surfactant is preferably added in such an amount that it can be emulsified and dispersed almost uniformly. That is, the amount of the surfactant is not particularly limited as long as the oil-based component and the water-based component are emulsified and dispersed almost uniformly, and can be put into the drain, but generally 0.001% by mass or more Is preferable, and 30 mass% or less is preferable. More preferably, it is 5 mass% or less.

また、本発明の排水トラップ封水蒸発防止剤組成物には、上記成分に加え本発明の目的を阻害しない範囲で必要に応じて、さらに、色素、香料、精油、顔料、顔料分散剤、防腐剤、防黴剤、殺菌剤、金属イオン封鎖剤、増粘剤、油系/水系の分離促進剤、防虫剤、害虫忌避剤、殺虫剤、漂白剤、アルカリ、酸、無機塩類、有機塩類、溶剤、植物抽出エキス、消臭剤、除臭剤、蛋白分解や油脂分解酵素などの酵素類、酸化剤、還元剤、研磨剤、高分子吸水剤、バクテリアや酵母の賦活剤等を一種または二種以上自由に配合することができる。   Further, in the drain trap sealing water evaporation inhibitor composition of the present invention, in addition to the above-described components, if necessary, the pigment, fragrance, essential oil, pigment, pigment dispersant, antiseptic, as long as the object of the present invention is not impaired. Agent, fungicide, disinfectant, sequestering agent, thickener, oil / water separation accelerator, insecticide, insect repellent, insecticide, bleach, alkali, acid, inorganic salt, organic salt, Solvents, plant extracts, deodorants, deodorants, enzymes such as proteolytic and oil-degrading enzymes, oxidizing agents, reducing agents, abrasives, polymeric water-absorbing agents, bacteria and yeast activators, etc. More than one species can be blended freely.

本発明の封水蒸発防止剤組成物は、ポリエチレンボトル等に充填し封水の蒸発防止剤として供されてもよい。封水の蒸発防止に使用する時は、使用前に上下に振って油系成分と水性成分が乳化又は分散した状態にして水封型排水トラップの封水に投入して使用する。投入された封水蒸発防止剤組成物は封水と適度に混合し、まんべんなく封水に行き渡る。時間の経過と共に油系成分が上部に分離し油成分が封水の表面をカバーする。これにより封水の蒸発を長期間防止する効果が得られ、水封型排水トラップの機能を長期間維持することができる。また、本来の使用状況になった場合においても、配合されている界面活性剤の力で油系成分が簡単に乳化分散して流れる為、油系成分の固着が起き難い。   The sealed water evaporation inhibitor composition of the present invention may be filled in a polyethylene bottle or the like and used as an evaporation inhibitor for sealed water. When used to prevent evaporation of the sealed water, it is shaken up and down before use to make the oil-based component and aqueous component emulsified or dispersed and put into the sealed water of the water-sealed drain trap. The charged sealing water evaporation inhibitor composition is mixed with the sealing water in a moderate amount, and evenly spreads to the sealing water. As time passes, the oil component separates into the upper part, and the oil component covers the surface of the sealed water. As a result, the effect of preventing evaporation of the sealed water for a long period of time can be obtained, and the function of the water-sealed drain trap can be maintained for a long period of time. Further, even when the actual use state is reached, the oil component is easily emulsified and dispersed by the power of the blended surfactant, so that the oil component is hardly fixed.

本発明の封水蒸発防止剤組成物は、上記のようにボトルに充填して製品化しても良いが、耐水性のポリエチレン等の袋に充填しても良い、またエアゾールに充填しても良い、耐水性の紙パックに充填しても良いなどその商品形態は自由に選定することができる。   The sealed water evaporation inhibitor composition of the present invention may be filled into a bottle and commercialized as described above, but may be filled into a bag of water-resistant polyethylene or the like, or may be filled into an aerosol. The product form can be freely selected, such as filling in a water-resistant paper pack.

(実験1)
以下、具体的な実験例を説明する。表1に示す材料をそれぞれの配合割合に従い、混合し、実施例1から3及び比較例1をそれぞれ500cc準備し、ガラス容器に充填した。尚、各材料の商品名、一般名称、メーカ名を表2にまとめる。これらの混合物を充填した容器を密封し、それぞれ上下に20回激しく振り、静置し、10秒後に乳化の状態を目視で観察した。その結果を表1にまとめる。油剤、界面活性剤、防腐剤、色素、そして水を混ぜた実施例1は、乳化状態が非常に良好であった。油剤、界面活性剤、そして水を混ぜた実施例2も乳化状態が非常に良好であった。油剤、及び水だけを加えた実施例3では、乳化状態がやや良であったが、静置後直ぐに分離が始まっていた。
(Experiment 1)
Hereinafter, specific experimental examples will be described. The materials shown in Table 1 were mixed according to the respective blending ratios, and 500 cc of each of Examples 1 to 3 and Comparative Example 1 were prepared and filled in a glass container. The product names, general names, and manufacturer names of each material are summarized in Table 2. The containers filled with these mixtures were sealed, shaken vigorously up and down 20 times respectively, allowed to stand, and the state of emulsification was visually observed after 10 seconds. The results are summarized in Table 1. Example 1 in which an oil agent, a surfactant, a preservative, a pigment, and water were mixed had a very good emulsified state. The emulsified state was also very good in Example 2 in which an oil agent, a surfactant, and water were mixed. In Example 3 to which only the oil and water were added, the emulsified state was slightly good, but separation started immediately after standing.

次に、図3に示すS字管300に撹拌後の上記組成物を投入し、下水側への油系成分の移動が行われるかを調べた。透明な塩化ビニル製のパイプ及び継ぎ手を加工してS字排水トラップ300を試作した。まず、水を投入し、通常の使用状況と同じように封水18を溜めた。実施例1から3及び比較例1の組成物210を、それぞれ20回上下に激しく振り、それぞれ50ccずつ排水口側から投入し、組成物が下水側の水面に達するかを目視で観察した。その結果、表1に示すように、実施例1及び2は油系成分が十分下水側に移動することがわかった。実施例3では、わずかに油系成分が下水側に移動することが認められた。比較例1は油系成分を含まないので、評価の対象外となった。   Next, the above-mentioned composition after stirring was put into an S-shaped tube 300 shown in FIG. 3, and it was examined whether or not the oil component was moved to the sewage side. An S-shaped drain trap 300 was manufactured by processing a transparent vinyl chloride pipe and a joint. First, water was added, and the sealed water 18 was collected in the same manner as in normal use. Each of the compositions 210 of Examples 1 to 3 and Comparative Example 1 was shaken vigorously up and down 20 times, and 50 cc of each was poured from the drain outlet side, and it was visually observed whether the composition reached the water surface on the sewage side. As a result, as shown in Table 1, in Examples 1 and 2, it was found that the oil component sufficiently moved to the sewage side. In Example 3, it was recognized that the oil component slightly moved to the sewage side. Since Comparative Example 1 did not contain an oil-based component, it was excluded from the evaluation.

次に、封水を溜めた上記透明塩化ビニル製S字排水トラップに、実施例1から3及び比較例1の組成物210を、それぞれ20回上下に激しく振り、それぞれ50ccずつ排水口側から投入し、直後の下水側の水位に目印を付けておき、3週間室温で保存した後に、水位の減少を測定した。その結果、表1のように実施例1及び2は、水の水位が殆ど低下していないことがわかった。実施例3では、11mm低下していたが、比較例1の22mmの半分であり、実施例3の組成物投入の効果が認められた。   Next, each of the compositions 210 of Examples 1 to 3 and Comparative Example 1 was shaken vigorously up and down 20 times in the transparent vinyl chloride S-shaped drainage trap in which the sealed water was stored, and 50 cc each was charged from the drain outlet side. Then, the water level on the sewage side immediately after was marked and stored at room temperature for 3 weeks, and then the decrease in the water level was measured. As a result, as shown in Table 1, in Examples 1 and 2, it was found that the water level was hardly lowered. In Example 3, although it was 11 mm lower, it was half of 22 mm of Comparative Example 1, and the effect of introducing the composition of Example 3 was recognized.

Figure 0004390831
Figure 0004390831

Figure 0004390831
Figure 0004390831

(実験2)
図4は、次の実験例で用いた水封型排水トラップの模式図である。内径30mmの透明塩化ビニル製の配水管からなる試作した水封型排水トラップ330は、排水口332を鉛直上方に開口し、250mmほぼ垂直下側に伸び、そこで約90度屈曲し水封型排水トラップ330の底部を幅130mm形成した後、鉛直に140mm上方に伸び、そこで90度屈曲して水平に下水側336に伸びる。このようにして形成される封水部334には、封水量約190mlを貯留可能である。このような試作水封型排水トラップ330を5つ用意し、それぞれ封水部334に封水18を貯留させた。また、上記実施例1と同じ組成物をそれぞれ10ml、20ml、30ml、40ml、50mlメスシリンダーで測り取り、それぞれ実施例4、5、6、7、8とした。この実験2では、これら実施例4から8の組成物を、容器200内でよく撹拌し、油系成分及び水系成分を分散させて、それぞれ5つの試作水封型排水トラップ330の排水口332より投入した。
(Experiment 2)
FIG. 4 is a schematic diagram of a water-sealed drain trap used in the next experimental example. A prototype water-sealed drain trap 330 consisting of a transparent polyvinyl chloride water pipe with an inner diameter of 30 mm opens the drain port 332 vertically upward and extends approximately 250 mm vertically downward, where it bends approximately 90 degrees and is water-sealed drain. After forming the bottom of the trap 330 with a width of 130 mm, the trap 330 is vertically extended 140 mm upward, bent 90 degrees there, and horizontally extended to the sewage side 336. The sealed water portion 334 thus formed can store a sealed water amount of about 190 ml. Five such trial water-sealed drain traps 330 were prepared, and the sealed water 18 was stored in the sealed water portion 334, respectively. Moreover, the same composition as the said Example 1 was measured with the 10 ml, 20 ml, 30 ml, 40 ml, and 50 ml graduated cylinder, respectively, and was set as Examples 4, 5, 6, 7, and 8, respectively. In Experiment 2, the compositions of Examples 4 to 8 were thoroughly stirred in the container 200 to disperse the oil-based component and the water-based component, and from the drain ports 332 of the five prototype water-sealed drain traps 330, respectively. I put it in.

その結果、実施例4から8のいずれも、分散組成物202が、水封型排水トラップ330の底部を通って、下水側336に流入した。そして、1時間後には、下水側及び排水口側の封水と空気との界面(即ち封水の表面)に油膜が形成された。従って、実施例4のように10mlの組成物でも十分油膜を形成し蒸発を防止できるが、作業者の熟練度、自然落下によるか噴射によるか等の投入方法の影響を考えれば、実施例5又は6の20から30mlの投入が好ましいと考えられる。更に配管内部の汚れの影響等を加味すれば、また、より完全な油膜形成を望むならば、より多い50mlの投入が望ましい。しかしながら、環境負荷を考えれば、少ない方が好ましい。   As a result, in all of Examples 4 to 8, the dispersion composition 202 flowed into the sewage side 336 through the bottom of the water-sealed drain trap 330. After 1 hour, an oil film was formed at the interface between the sealed water and the air on the sewage side and the drain outlet side (that is, the surface of the sealed water). Therefore, 10 ml of the composition as in Example 4 can sufficiently form an oil film to prevent evaporation, but considering the influence of the charging method such as whether the operator is skilled or due to natural fall or injection, Example 5 Alternatively, an input of 20 to 30 ml of 6 is considered preferable. Furthermore, if the influence of dirt inside the piping is taken into account, and if a more complete oil film formation is desired, a larger amount of 50 ml is desirable. However, considering the environmental load, the smaller one is preferable.

このように最適投入量は、投入される組成物の成分、物性等により異なり、また、対象となる水封型排水トラップの封水量、形状、汚れ等により異なり、また、気温、蒸発を防止すべき期間によっても異なる。しかしながら、190mlの封水量に対して、概ね5%以上、より好ましくは10%以上と考えることもできる。また、環境負荷、コスト等を考えれば少なければ少ない方が好ましい。本実験例の場合についていえば、190mlの封水量に対して、概ね10から20%の投入量が好ましいと考えられる。   As described above, the optimum input amount varies depending on the composition, physical properties, etc. of the composition to be input, and also varies depending on the sealing amount, shape, dirt, etc. of the target water-sealed drain trap, and also prevents temperature and evaporation. It depends on the power period. However, it can be considered that the amount is approximately 5% or more, more preferably 10% or more, with respect to the amount of sealed water of 190 ml. Moreover, if there are few environmental loads, cost, etc., it is preferable that there are few. In the case of this experimental example, it is considered that an input amount of approximately 10 to 20% is preferable with respect to a sealed water amount of 190 ml.

以上のように、本発明の排水トラップ封水蒸発防止剤組成物では、長期間封水の蒸発を防止し、本来の水封型排水トラップの機能を長期間維持することが可能であった。また、界面活性剤の働きにより、油系成分がより容易に乳化・分散され、既に封水が溜まっているところに少量の排水トラップ封水蒸発防止剤組成物を投入しても、下水側の封水の表面まで油系成分が移動し、表面を覆って、封水の蒸発を防止することができる。また、防腐剤を混ぜることにより、組成物自体の保存性が増すばかりでなく、投入後の封水への防腐効果も期待できる。   As described above, in the drainage trap sealing water evaporation inhibitor composition of the present invention, it was possible to prevent the sealing water from evaporating for a long period of time and maintain the function of the original water-sealed drain trap for a long period of time. In addition, even when a small amount of drainage trap seal evaporation inhibitor composition is added to the place where the oil-based components are more easily emulsified and dispersed by the action of the surfactant and the seal water has already accumulated, The oil-based component moves to the surface of the seal water and covers the surface, thereby preventing the seal water from evaporating. Moreover, not only the preservability of the composition itself is increased by mixing an antiseptic, but also an antiseptic effect on the sealed water after the addition can be expected.

本発明の実施例の組成物を水封型排水トラップに適用したときの状態を示す模式図である。It is a schematic diagram which shows a state when the composition of the Example of this invention is applied to a water-sealed drain trap. 本発明の実施例の組成物を適用する封水の蒸発防止方法を図解する。FIG. 2 illustrates a method for preventing evaporation of sealed water to which a composition of an example of the present invention is applied. 本発明の実験例1を図解する図である。It is a figure which illustrates Experimental example 1 of this invention. 本発明の実験例2を図解する図である。It is a figure illustrating Experimental example 2 of the present invention. 従来の水封型排水トラップを用いた排水系の模式図である。It is a schematic diagram of the drainage system using the conventional water-sealed drain trap.

符号の説明Explanation of symbols

10 洗面台
16、44、62、86、110 排水管
18、46、64、84、108 封水
22、50、68、88、112、202 排水トラップ封水蒸発防止剤組成物
100、330 水封型排水トラップ
200 容器
210 撹拌により乳化・分散した液体
300 S字管
10 Wash basin 16, 44, 62, 86, 110 Drain pipe 18, 46, 64, 84, 108 Seal water 22, 50, 68, 88, 112, 202 Drain trap seal water evaporation inhibitor composition 100, 330 Water seal Drainage trap 200 Container 210 Liquid 300 S-shaped tube emulsified and dispersed by stirring

Claims (8)

比重が1.0未満で、蒸気圧が水よりも低い油系成分と、水系成分とを含む排水トラップの封水蒸発防止剤組成物であって、
当該封水蒸発防止剤組成物が乳化又は分散された後、下水側及び排水口側に空気との界面を持つ排水トラップに溜められた封水へ排水口側から投入されると、
前記油系成分が下水側にも移動し、分離し、前記下水側及び排水口側の封水の表面をカバーする封水蒸発防止剤組成物。
A sealant evaporation inhibitor composition for a drain trap containing an oil component having a specific gravity of less than 1.0 and a vapor pressure lower than that of water, and an aqueous component,
After the sealed water evaporation inhibitor composition is emulsified or dispersed, when the sealed water stored in a drain trap having an interface with air on the sewage side and the drain port side is introduced from the drain port side,
The oil-based component also moves the sewage side, separated, water sealing evaporation inhibitor composition covering the surface of the sealing water in the sewage-side and water outlet side.
更に、界面活性剤を含む請求項1記載の封水蒸発防止剤組成物。   Furthermore, the sealing water evaporation inhibitor composition of Claim 1 containing surfactant. 前記油系成分は、油脂、流動パラフィン、アルコール、ケトン、アルデヒド、エステル、シリコーン、炭化水素から少なくとも1種類以上を含むことを特徴とする請求項1又は2に記載の封水蒸発防止剤組成物。 The said oil-based component contains at least 1 or more types from fats and oils, liquid paraffin, alcohol, a ketone, an aldehyde, ester, silicone, and a hydrocarbon, The sealing water evaporation inhibitor composition of Claim 1 or 2 characterized by the above-mentioned. . 比重が1.0未満で、蒸気圧が水よりも低い油系成分と、水系成分とを混合し、撹拌して乳化若しくは分散させて、排水トラップに溜められた封水へ排水口側から投入し、該封水と下水側及び排水口側の空気との間に不揮発性の層を形成させる排水トラップの封水蒸発防止方法。 An oil-based component having a specific gravity of less than 1.0 and a vapor pressure lower than that of water and an aqueous component are mixed, stirred, emulsified or dispersed, and charged to the sealed water stored in the drain trap from the drain outlet side. And a method for preventing sealing water evaporation of a drain trap, wherein a non-volatile layer is formed between the sealed water and air on the sewage side and the drain port side. 更に、界面活性剤とを混合し、撹拌して、排水トラップに投入する請求項4に記載の封水蒸発防止方法。   Furthermore, the sealing water evaporation prevention method of Claim 4 which mixes with surfactant and stirs and throws into a waste_water | drain trap. 乳化された状態が撹拌10秒後に認められることを特徴とする請求項1から3のいずれかに記載の封水蒸発防止剤組成物。 4. The sealed water evaporation inhibitor composition according to claim 1 , wherein the emulsified state is observed after 10 seconds of stirring. 前記油系成分は、2〜30質量%であることを特徴とする請求項1から3のいずれかに記載の封水蒸発防止剤組成物。 The said oil-based component is 2-30 mass%, The sealing water evaporation inhibitor composition in any one of Claim 1 to 3 characterized by the above-mentioned. 前記油系成分及び水系成分が混合され、撹拌されて乳化若しくは分散されたものを、前記封水の下水側へ移動させることを特徴とする請求項4又は5に記載の封水蒸発防止方法。 6. The method for preventing sealing water evaporation according to claim 4, wherein the oil-based component and the water-based component are mixed, stirred and emulsified or dispersed to move to the sewage side of the sealed water.
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